WO2019222949A1 - Module solaire à effet pid réduit - Google Patents

Module solaire à effet pid réduit Download PDF

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Publication number
WO2019222949A1
WO2019222949A1 PCT/CN2018/088117 CN2018088117W WO2019222949A1 WO 2019222949 A1 WO2019222949 A1 WO 2019222949A1 CN 2018088117 W CN2018088117 W CN 2018088117W WO 2019222949 A1 WO2019222949 A1 WO 2019222949A1
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WO
WIPO (PCT)
Prior art keywords
frame
solar module
stack
glass
solar
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PCT/CN2018/088117
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English (en)
Inventor
Ruqi Chen
Heiko Hocke
Dongbo ZHAO
Yan Deng
Min Tang
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Covestro Deutschland Ag
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Application filed by Covestro Deutschland Ag filed Critical Covestro Deutschland Ag
Priority to PCT/CN2018/088117 priority Critical patent/WO2019222949A1/fr
Publication of WO2019222949A1 publication Critical patent/WO2019222949A1/fr

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042—PV modules or arrays of single PV cells
    • H01L31/048—Encapsulation of modules
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S30/00—Structural details of PV modules other than those related to light conversion
    • H02S30/10—Frame structures
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy

Definitions

  • the present invention concerns a new type of solar module comprising at least a stack made of pane (s) of glass, two layers of encapsulation polymer, silicon cells and wiring, and optionally a back sheet.
  • the stack is framed by a non ⁇ coated profile of polymeric composite materials based on aliphatic polyisocyanates and optionally a sealant.
  • the new type of solar module is characterized by an excellent long term weathering resistance, high durability, low maintenance efforts and a high resistance to potential induced degradation processes.
  • solar modules based on monocrystalline or polycrystalline silicon cells.
  • solar modules are built up as a stack of several layers.
  • the upper side of the module facing the sun light is formed by a pane of glass, which needs to be highly transparent in order to capture the light.
  • the pane works as a barrier to oxygen and moisture as well as a mechanical support.
  • an encapsulating material e.g. a polymer sheet made of ethylene ⁇ vinyl acetate copolymer, polysilicone or polyethylene derivatives, which is also transparent and protects the electrically interconnected silicon cells.
  • encapsulation material and another barrier which may be a polymeric back sheet or another pane of glass completes the stack. All layers are well bonded to one another by a lamination process and form a unit (stack) .
  • the edge of the stack is surrounded by a frame that provides mechanical support to the module (especially stiffness) , protects the edges of the pane of glass from damage by hits during installation and transport, and functions as support element in the installation of the module.
  • the connection between the stack and the frame is achieved by using an elastic polymer sealant, often a silicone.
  • This frame sealant also acts as barrier on the edges of the stack and ideally prevents the ingress of moisture or oxygen.
  • the frame sealant must provide sufficient flexibility to compensate for the different thermal expansion of the stack material, especially the pane of glass, and the frame material during temperature cycles.
  • the frame should have at least the same or better lifetime (durability) as the stack.
  • the durability should be achieved without further maintenance over the life cycle of the module in all environments (sea side, urban areas, desert, tropics, buildings close to life stock areas etc) .
  • the coefficient of linear thermal expansion (CLTE) of the frame and the stack along the edges should be same or similar to reduce the stress on the frame sealant during temperature cycles, e.g. day and night in a desert or usage in different climate zones. This also improves the barrier function of the frame sealant and consequently improves the lifetime of the solar module.
  • CLTE coefficient of linear thermal expansion
  • the frame should provide sufficient stiffness to enhance the mechanical overall performance of the module, e.g. in case of snow or wind load, and protect the stack edges against damages during transportation and installation of the module.
  • the frame should provide sufficient support to install the module, e.g. by clamping on a base frame.
  • the frame should be electrically non ⁇ conductive. That significantly decreases the susceptibility for potential induced degradation (PID) , an effect caused by harmful leakage currents over an extended period of time, and that may reduce the performance of crystalline silicon photovoltaic modules up to 30%.
  • PID potential induced degradation
  • the frame should be easy to recycle and should have a low carbon foot print.
  • the frame should fit esthetically, e.g. color, to the stack and the environment especially for building integrated photovoltaic modules.
  • aluminium is widely used as frame material especially for solar modules. It combines very good mechanical properties with good weathering fastness for most environments (requirement c, partly a) .
  • the frame protects the glass pane effectively and serves also as support to clamp the module onto a rack or any other assembly device (d) .
  • the aluminium is usually surface treated, e.g. by anode oxidation. Nevertheless, in salt water environment or mist aluminium will gradually react with water (misses partly item a) .
  • an expensive coating must be applied if colors other than the “typical” aluminium silver are desired (misses item g) .
  • Another serious disadvantage is the high electrical conductivity of aluminium for solar modules (misses item e) .
  • the electrical conductive aluminium frame brings the high electric potential to ground in close proximity of the silicon wafer and in direct contact with the glass pane.
  • potential induced degradation was observed in such solar modules (source: Photon 12/2010) .
  • the coefficient of linear thermal expansion of aluminium is significant higher than that of glass (misses item b) .
  • This difference leads to challenges especially for the edge sealing in larger solar modules over expanded time periods.
  • the costs for aluminium are rather high, and the carbon footprint is high due to its energy consumption during the production (misses partly item f) .
  • polymeric composites have been proposed by A. Raymond ET CIE (WO 2013/010091) , Bayer MaterialScience (US 2011/030767) and others as frames for solar modules. These composites have been often thermoplastic or thermoset based polymers as matrix materials and glass fibers as reinforcing fillers.
  • matrix materials are polybutyleneterephthalate (PBT) and blends thereof as well as polyurethanes based on aromatic polyisocyanates (WO 2009/121502A2) .
  • the edges of a solar module are very critical areas for the life time and performance of the module.
  • Current approaches address the problems to a different degree but no approach provides an overall satisfying solution.
  • Either the mechanical protection of the edges and weathering fastness are good but the PID effect and difference in CLTE between stack and frame are issues (aluminium frame) , or the mechanical and PID protection is good but the weathering fastness and durability is a problem (current coated polymeric frames) .
  • the problem underlying the present invention was the provision of a solution that provides all desired features (mechanical protection of the module edges, suppressing the PID effect, excellent weathering fastness and durability, edge sealing, freedom of color, support for mounting the module, e.g. by commonly use clamping) at the same time and at reasonable costs.
  • the present invention relates to a solar module A comprising
  • At least one stack B comprising pane (s) of glass, a polymeric encapsulation material, silicon cell (s) , electrical wiring and optionally a back sheet;
  • a frame C made of a non ⁇ coated thermoset polymeric composite material comprising a polymer matrix which is based on at least 50 wt. ⁇ %of an aliphatic polyisocyanate;
  • the solar module A comprises at least one stack B, one frame made of polymeric composite material and optionally one sealant D that connects the stack B with the frame C.
  • the frame C stabilizes the stack B mechanically and optionally offers further elements to mount the solar module A onto a base frame. It may surround the stack B completely or partly. However, it is essential that cumulated at least 25 %, more preferred at least 50 %and even more preferred at least 75 %of the circumference of stack B are embedded into the frame C.
  • the solar module A comprises a stack B that is completely surrounded on the edge by a frame C made of polymeric weather resistant polymeric composite, and optionally a sealant which connects the stack B with the frame C.
  • the size and shape as well as the weight of the solar module A are important for good and economic handling and installation. If the module A is too big or heavy, handling during installation will be difficult and the stiffness of the materials might be not sufficient to guarantee the mechanical stability. If the size of the module A is too small the cost for handling as calculated nominal solar power/handling cost and material costs for frame are too expensive. Therefore, a balance of size with regard to handling and material costs as well as nominal power output per module is needed.
  • the solar module A has a rectangular shape.
  • the side length of this rectangular shape is between 45 cm and 300 cm, more preferred between 60 cm and 250 cm and most preferred between 95 cm and 185 cm.
  • the longest side of the rectangular shaped module A is between 95 cm and 300 cm, more preferred between 130 cm and 200 cm and most preferred between 155 cm and 185 cm.
  • the solar module A has a surface area at the front side (facing the sun) between 0.50 m 2 and 2.0 m 2 , more preferred between 1.0 m 2 and 2.0 m 2 and most preferred between 1.25 m 2 and 1.90 m 2 .
  • the weight of solar module A is between 5 kg and 30 kg, more preferred between 10 kg and 28 kg and most preferred between 15 kg and 20 kg.
  • the solar module A is at least partially exposed to outdoor conditions.
  • Preferably at least a part of the frame C is exposed to rain and/or solar radiation without any type of screen which protects the exposed part of the frame C or module A from said exposure.
  • the solar module A is completely exposed to outdoor conditions and exposed to weather conditions of the surrounding area.
  • the solar panel A if exposed to accelerated weathering tests (thermal cycling test 10.11, humidity freeze test 10.12, damp heat test 10.13) as required by certification of solar modules (standard IEC 61215: 2005) will pass the tests at least once, preferably at least twice and more preferably at least 3 times without any significant visible changes or decrease of its performance.
  • Significant decrease of performance of module A is given if the DC output power (nominal power) under standard test conditions (STC: irradiance of 1,000 W/m 2 , solar spectrum of AM 1.5 and module temperature at 25 °C) decreases by 20 %.
  • STC irradiance of 1,000 W/m 2 , solar spectrum of AM 1.5 and module temperature at 25 °C
  • the solar module A is exposed to outdoor conditions in sum at least 10 years, preferably at least 15 years, more preferably at least 20 years and most preferably at least 25 years.
  • a solar module is often not used as standalone unit but connected with more modules to form a photovoltaic array of a photovoltaic system.
  • the produced DC power is for better transportation and usage converted to AC power by an inverter.
  • modules are wired in series to have up to several hundreds of volts DC power in an array.
  • source Photon 12/2010; presentation of SOLON SE at PVSEC inValencia 2010
  • solar module A is used as part of a photovoltaic array where modules are connected in a serial fashion and the array has a DC voltage of at least 600 Volt, more preferred at least 900 Volt, even more preferred of 1400 Volt and most preferred of 1550 Volt or higher. It is understood that due to technical restrictions the voltage in the photovoltaic array should not exceed 5000 Volt in order to avoid short cuts in the wiring.
  • stack B used in the solar module A may have different combinations of materials but the general assembly and function of layers are same or comparable.
  • stack B comprises 5 layers:
  • the pane of glass A1 is preferably made of solar glass, a special grade for solar industry that is low on iron content and provides a high transmittance of light within the range favorable for the working of the silicon cells. It may be treated on the outside with a special anti ⁇ reflective coating (ARC) to harvest more light. Further functions of the pane of glass are to provide mechanical stability to the module and barrier properties against moisture or oxygen ingress.
  • the second layer is a transparent encapsulating polymer A2.
  • Said polymer A2 is preferably based on an ethylene ⁇ vinyl acetate ⁇ copolymer. Also suitable are encapsulating materials made from polymers derived from silicone or ethylene. The function of the encapsulating layer is to protect the silicon cells and wiring from mechanical impact and chemicals (corrosion) .
  • encapsulating polymers A2 and A4 have the same composition.
  • encapsulating polymers A2 and A4 fix the positions of the silicon cells (third layer) and work as adhesive to connect all layers in stack B. Silicon cells together with the wiring form the third layer A3 and are embedded in the encapsulation layers A2 and A4.
  • the silicon cells are made of crystalline silicon which may be monocrystalline or polycrystalline silicon, connected by wires to form a circuit and are the actual photovoltaic active component of the solar panel. The cells convert the light into direct current.
  • the fifth layer is a back sheet A5.
  • the polymeric back sheet can comprise one or more individual layers of different polymers such as polyamide (PA) , polyethylene terephthalate (PET) , polyolefin and fluorinated polymers (PTFE, PVDF) .
  • PA polyamide
  • PET polyethylene terephthalate
  • PTFE polyolefin and fluorinated polymers
  • PVDF polyolefinated polymers
  • the function of the back sheet is to provide mechanical protection and barrier properties especially against moisture and oxygen. It may or may not be transparent. Both moisture and oxygen are harmful to the inner layers such as the encapsulating material or the metal wires and may cause degradation of the polymers or corrosion of the electrical contacts that finally impact the performance and life time of the module.
  • the stack B used in the solar module A has a thickness between 2 mm and 20 mm, preferably between 3.0 mm and 10 mm, more preferably between 3.5 mm and 8 mm and most preferably between 4.0 mm and 7.0 mm.
  • the surface area of the stack B is at least 0.5 m 2 , preferably at least 1.0 m 2 , more preferably at least 1.25 m 2 and most preferably at least 1.5 m 2 .
  • the surface area is not larger than 2.0 m 2 .
  • the surface area is defined as the front side area of the stack B (directed to the sun) , and that is not covered by the frame C.
  • the advantages (similar CLTE of the stack B and frame C) of the new solar module A are especially emphasized if the stack B of the module A is large.
  • Large in the meaning of the invention means that the circumference of stack B is at least 2.0 m, preferably more than 3.0 m, more preferably more than 4.0 m, and most preferably more than 5.0 m, while having the surface area defined in the paragraph above.
  • the circumference is not larger than 7.0 m for practical reasons.
  • the pane of solar glass as main part of stack B is determining the coefficient of linear thermal expansion (CLTE) of the stack. Therefore, the CLTE measured according TM 900026 ( ⁇ 20 °C, 100 °C) of the stack B is between 1.0*10 ⁇ 6 K ⁇ 1 and 15*10 ⁇ 6 K ⁇ 1 , preferably between 2.0*10 ⁇ 6 K ⁇ 1 and 11.0*10 ⁇ 6 K ⁇ 1 , more preferably between 3.0*10 ⁇ 6 K ⁇ 1 and 10.0*10 ⁇ 6 K ⁇ 1 and most preferably between 4.0*10 ⁇ 6 K ⁇ 1 and 9.0*10 ⁇ 6 K ⁇ 1 .
  • the frame C is shaped to surround at least a part of the circumference of stack B. This means that the frame C covers at least a part of the edge of stack B and optionally a part of the surface adjacent to said edge so that pane B is moved into its intended position and kept in this position by orientating frame C.
  • a preferred shape for this purpose is a profile with a notch or an indention into which the edge of stack B can be inserted so that stack B is friction ⁇ locked with frame C or form ⁇ locked.
  • the actual shape of the frame C is determined by the shape of the edges of stack B. If the optional sealant D is present, the required notch in the profile is large enough to insert stack B as well as the required amount of sealant while meeting the requirements of friction ⁇ lock or form ⁇ lock.
  • At least 25 %of the circumference of stack B are surrounded by frame C. More preferably at least 50 %and even more preferably at least 75 %of the circumference of stack B are surrounded by frame C. Most preferably stack B is completely surrounded by frame C.
  • Frame C consists of a non ⁇ coated composite material comprising inorganic fibers embedded in a polymer matrix.
  • Said composite material is, preferably, electrically insulating.
  • the electrical resistivity of frame C is therefore preferably at least 10 9 Ohm, more preferably at least 10 12 Ohm and even more preferably at least 10 14 Ohm measured according to standard ASTM D257.
  • coated means that there is an additional layer or covering of material applied on top of the surface of the substrate (core material, composite) .
  • This layer has a distinct thickness and a boundary that separates this layer from the substrate.
  • the chemical composition of this layer is different from the resin of the composite.
  • the layer is applied to the composite surface after forming the composite part, and often even in a separate process step.
  • the coating usually fulfills functional requirements such as protection, surface modification of mechanical or chemical nature, or simply decorative appearance.
  • non ⁇ coated means that such layer does not exist on at least 20 %, preferably at least 50 %and more preferably at least 75 %of the composite part. Most preferred is that no such layer, i.e. no coating, is applied to frame C.
  • the inorganic fibers may be glass fibers or basalt fibers, however, glass fibers are preferred in order to match the CLTE of stack B best.
  • the composite material of frame C has a fiber content between 40 wt. ⁇ %and 95 wt. ⁇ %, more preferably between 50 wt. ⁇ %and 90 wt. ⁇ %and even more preferably between 60 wt. ⁇ %and 90 wt. ⁇ %.
  • Most preferred is a glass fiber content of frame C between 70 wt. ⁇ %and 85 wt. ⁇ %. The content of glass fiber is given with respect to the overall weight of the composite material.
  • the coefficient of linear thermal expansion (CLTE) as measured according to TM 900026 in axial direction should be preferably same or at least similar for stack B and frame C. Therefore variances of temperature which are typically encountered in outdoor conditions due to seasonal changes and the night ⁇ day ⁇ rhythm cause less stress on the connection of the stack B with the frame C or sealant D. In addition, more freedom of design and higher accuracy of the parts and consequently better appearance of solar module A are advantageous side effects.
  • the CLTE of the frame C in axial direction, i.e. parallel to the fiber orientation, is between 1.0*10 ⁇ 6 K ⁇ 1 and 17*10 ⁇ 6 K ⁇ 1 , preferably between 2.0*10 ⁇ 6 K ⁇ 1 and 11.0*10 ⁇ 6 K ⁇ 1 , more preferably between 3.0*10 ⁇ 6 K ⁇ 1 and 10.0*10 ⁇ 6 K ⁇ 1 and most preferably between 4.0*10 ⁇ 6 K ⁇ 1 and 9.0*10 ⁇ 6 K ⁇ 1 (measured according to TM 900026; ⁇ 20 °C, 100 °C) .
  • the difference of CLTE of stack B and of frame C measured in axial direction according to TM 900026, i.e. parallel to the fiber orientation and along the edge of stack B is not more than 1000 %, preferably not more than 400 %, more preferably not more than 200 %, even more preferably not more than 100 %and most preferably not more than 50 %.
  • the difference is calculated as follows: absolute value (CLTE of pane of glass of stack B minus CLTE of frame C) divided by CLTE of pane of glass of stack B multiplied by 100 %.
  • polymeric composite material refers to a material made of inorganic fibers, particularly glass or basalt fibers, which are embedded into a polymer matrix.
  • the polymeric composite material is produced by the pultrusion process which is well known in the art.
  • the matrix material of frame C might be any thermoset or thermoplastic polymeric material that has excellent weathering fastness.
  • examples for such polymers are thermoplastic fluorinated polymers such as polytetrafluoroethylene (PTFE) or polyvinylidene difluoride (PVDF) and thermoplastic or thermoset polyurethanes or polyisocyanurates.
  • PTFE polytetrafluoroethylene
  • PVDF polyvinylidene difluoride
  • thermoset or thermoset polyurethanes or polyisocyanurates Preferred is a thermoset material due to its better creep performance over the intended application time of the frame. Even more preferred is a thermoset material based on aliphatic polyisocyanates.
  • Such thermoset materials are produced from aliphatic polyisocyanates resins containing at least 50 wt. ⁇ %, more preferably at least 70 wt. ⁇ %and even more preferably at least 80 wt.
  • Aliphatic and cycloaliphatic polyisocyanates useful for manufacturing the polymer matrix are monomeric polyisocyanates as well as oligomeric polyisocyanates.
  • the reaction mixture used for manufacturing the polymer matrix does not contain more than 40 wt. ⁇ %, preferably not more than 20 wt. ⁇ %, more preferably not more than 10 wt. ⁇ %, even more preferably not more than 5 wt. ⁇ %and most preferably not more than 1 wt. ⁇ %aromatic and araliphatic polyisocyanates.
  • Aliphatic polyisocyanates which are suitable for the manufacture of the polymer matrix are 1, 4 ⁇ diisocyanatobutane (BDI) , 1, 5 ⁇ diisocyanatopentane (PDI) , 1, 6 ⁇ diisocyanatohexane (HDI) , 2 ⁇ methyl ⁇ 1, 5 ⁇ diisocyanatopentane, 1, 5 ⁇ diisocyanato ⁇ 2, 2 ⁇ dimethylpentane, 2, 2, 4 ⁇ or 2, 4, 4 ⁇ trimethyl ⁇ 1, 6 ⁇ diisocyanatohexane, 1, 10 ⁇ diiisocyanatodecane, 1, 3 ⁇ and 1, 4 ⁇ diisocyanatocyclohexane, 1, 4 ⁇ diisocyanato ⁇ 3, 3, 5 ⁇ trimethylcyclohexane, 1, 3 ⁇ diisocyanato ⁇ 2 ⁇ methylcyclohexane, 1, 3 ⁇ diisocyanato ⁇ 4 ⁇ methylcyclohexane, 1 ⁇ isocyanato ⁇
  • Said aliphatic may be used as such, i.e. as monomeric polyisocyanates, for manufacturing the polymeric composite material. However, they may be also used as oligomeric polyisocyanates obtained from the reaction of two monomeric polyisocyanates. This oligomerization leads to oligomeric polyisocyanates linked by at least one structure selected from the group consisting of uretdione, isocyanurate, allophanate, biuret, iminooxadiazinedione and/or oxadiazinetrione structures.
  • the ratio of aliphatic polyisocyanates and isocyanate reactive compounds other than the short chain polyols defined below in the reaction mixture is at least 5 : 1 (weight/weight) , preferably at least 10 : 1 (weight/weight) and most preferably at least 20 : 1 (weight/weight) .
  • An “isocyanate reactive compound” as understood in the present application is any compound which carries at least one hydroxyl, thiol or amino group.
  • Short chain polyols which are suitable for manufacturing a polymer matrix according to the present invention have an average functionality of at least two and an OH content between 25 %by weight and 60 %by weight, preferably between 30 %by weight and 60 %by weight and more preferably between 35 %by weight and 60 %by weight.
  • Preferred short chain polyols are glycerol, 1, 1, 1 ⁇ trimethylolpropane, 1, 1, 1 ⁇ trimethylolethane, pentaerythritol, 1, 2, 10 ⁇ decanetriol, 1, 2, 8 ⁇ octanetriol and sugar alcohols. Particularly preferred is glycerol.
  • the polymer matrix is preferably manufactured from a reaction mixture comprising aliphatic isocyanates as defined above and short chain polyols as defined above, wherein the molar ratio between isocyanate groups and hydroxyl groups of the short chain polyols in the reaction mixture is at least 0.8 : 1.0, preferably 0.9 : 1.0, more preferably 1.1 : 1.0, even more preferably 1.3 : 1.0 and most preferably 1.5 : 1, 0.
  • the formation of the polymer matrix is not dependent on the formation of urethane groups but can also be mediated by the formation of are isocyanurate groups, uretdione groups, biuret groups, iminooxadiazinedione and oxadiazintrione groups.
  • the molar ratio of isocyanate groups to all groups reactive with isocyanate groups in the reaction mixture used for manufacturing the polymer matrix is at least 2 : 1, preferably at least 5 : 1 and more preferably at least 10 : 1.
  • the amount of any isocyanate reactive compound –including short chain polyols – is limited in this embodiment of the present invention.
  • the polymer matrix is predominantly crosslinked by functional groups which are formed by the reaction of one isocyanate group with another isocyanate group.
  • functional groups are isocyanurate groups, uretdione groups, biuret groups, iminooxadiazinedione and oxadiazintrione groups.
  • Useful catalysts for manufacturing the composite material from a reaction mixture with a low content of isocyanate reactive groups are typical trimerisation catalysts.
  • catalysts that comprises potassium acetate or potassium octoate and polyethylene glycol are particularly useful.
  • the polyethylene glycol preferably has a polydispersity of less than 5.
  • This catalyst has sufficient solubility or dispersibility in the reaction mixture in the amounts that are required for initiation of the crosslinking reaction.
  • the trimerization catalyst is therefore preferably added to the polyisocyanate resin composition in neat form.
  • “Addition of the trimerization catalyst in neat form” means that the metal salt is dissolved or at least suspended in the polyether.
  • the proportion of the metal salt in this solution is less than 50 %by weight, preferably less than 25 %by weight, more preferably less than 20 %by weight or less than 15 %by weight, and especially less than 10 %by weight. However, the proportion is in any case greater than 0.01 %by weight. The aforementioned proportions are based on the total weight of metal salt and polyether.
  • the crosslinking is preferably effected at temperatures between 80 °C and 350 °C, more preferably between 100 °C and 300 °C and most preferably between 150 °C and 250 °C.
  • any catalyst which mediates the formation of urethane groups can be used. Suitable catalysts can be found, for example, in Becker /Braun, Kunststoffhandbuch Band 7, Polyurethane [Plastics handbook, Volume 7, Polyurethanes] , chapter 3.4.
  • a particular catalyst that can be used is a compound selected from the group of the amines and organylmetal compounds, preferably from the group of the organyltin compounds and of the organylbismuth compounds, and particularly preferably dibutyltin dilaurate (DBTL) .
  • the quantity of catalyst added depends on the catalyst used and the reaction conditions such as temperature and time applied.
  • a suitable concentration using DBTL is from 0.0001 to 0.500 %by weight, preferably from 0.002 to 0.050 %by weight and particularly preferably from 0.005 to 0.030 %by weight.
  • the solar module A additionally comprises a sealant D which ensures a good connection between the frame C and the embedded stack B.
  • the sealant D may also act as barrier to prevent moisture or air ingress and as buffer to compensate differences in CLTE between the stack B and frame C during temperature cycles.
  • sealant D comprises a polymeric, elastic material that is based on polysilicone, polyesters, polyethers, polyurethans, polyacrylics, thermoplastic elastomers, thermoplastic olefins or rubber polymers. Suitable materials and their properties are well known in the art and commercially available. Starting materials for sealants may include but are not limited to isocyanates, epoxies, acrylates, silicones, olefins, amines, alcohols and carboxylic acids and their derivatives.
  • additional fillers such as carbonates, silicates, sulfates, graphite or carbon blacks and other inorganic fillers are used in quite substantial amounts to lower the price, enhance the durability and improve or optimize the mechanical properties.
  • sealants can be used that exhibits a good weather fastness and provide the required mechanical performance for the sealing of stack B and frame C.
  • the appropriate sealant can be easily selected and purchased from the recommendations given by the producers.
  • the sealant D is based on silicone or polyurethanes, preferred are silicones. These are easy to handle and commercially available from different companies, for example Du Pont, Dow Corning, Momentive, Lord, Henkel and Sika.
  • the present invention relates to a photovoltaic array comprising at least 5, more preferred at least 15 and most preferred at least 25 of the above ⁇ defined solar panels connected in a serial fashion, wherein said photovoltaic array has a DC voltage of at least 600 V, more preferred at least 900 Volt, even more preferred of 1400 Volt and most preferred of 1550 Volt or higher. It is understood that due to technical restrictions the voltage in the photovoltaic array should not exceed 5000 Volt in order to avoid short cuts in the wiring..
  • photovoltaic array refers to a plurality of individual solar modules which are electrically connected to each other. Said connection may be arranged in a serial or in a parallel fashion. It is, however, essential that at least 12 of the individual modules in the photovoltaic array are connected in a serial fashion because this arrangement is necessary in order to achieve high voltages.
  • the present invention relates to the use of a reaction mixture comprising at least 50 wt. ⁇ %of an aliphatic isocyanates as defined above and glass fibers in a pultrusion process for manufacturing a frame of a solar module.
  • the term “pultrusion” is well known to the person skilled in the art. It refers to a process for manufacturing composite materials comprising the steps of (i) wetting long fibers of a filler with a reaction mixture and (ii) pulling said wetted fibers through a heated, shaped device, whereby the reaction mixture is cured to give the polymer matrix of the composite material, and the composite material has the shape defined by the shape of the heated device.
  • N 3600 is an HDI trimer (NCO functionality > 3) with an NCO content of 23.0 %by weight from Covestro AG.
  • the viscosity is about 1200 mPas at 23 °C (DIN EN ISO 3219/A. 3) .
  • Glycerol (1, 2, 3 ⁇ Propantriol) with a purity of 99, 0 %was sourced from Calbiochem.
  • PUL 20PL05 is a mixture of polyols and auxiliaries from Covestro AG and is used for production of glass fibre ⁇ containing profiles composed of polyurethane in the pultrusion process.
  • the viscosity is about 1600 mPas at 20 °C (DIN 53019) .
  • PUL 10PL01 is a mixture of diphenylmethane 4, 4 ‘ ⁇ diisocyanate (MDI) with isomers and higher ⁇ functionality homologs having an NCO content of about 31 %by weight from Covestro AG and is used for production of glass fibre ⁇ containing profiles composed of polyurethane in the pultrusion process.
  • MDI diphenylmethane 4, 4 ‘ ⁇ diisocyanate
  • the viscosity is 160 ⁇ 240 mPas at 25 °C (2011 ⁇ 0248603 ⁇ 94) .
  • Dibutyltin dilaurate (DBTL) was sourced with a purity of > 99 %by weight from ACROS under the BL277 name.
  • Polyethylene glycol 400 was sourced with a purity of > 99%by weight from ACROS.
  • Potassium acetate was sourced with a purity of > 99%by weight from ACROS.
  • Zinc stearate was acquired from SysKem Chemie GmbH.
  • the glass fiber was glass fiber bundles with standard size for UP, VE and epoxy resins with the product name ‘Advantex 399’ with 4800 tex from 3B ⁇ fibreglass. According to the datasheet, the glass fibers have a diameter of 24 micrometres, are boron ⁇ free and consist of E ⁇ CR glass.
  • the tensile modulus is 81 ⁇ 83 GPa, the tensile strength 2200 ⁇ 2400 MPa and the density 2.62 g/cm 3 .
  • the solar glass pane was purchased from Flat Glass Group, type low iron pattern glass, 3.2 mm thickness.
  • the solar back sheet was purchased from Jolywood, type TPT ⁇ 3501.
  • the encapsulant material was EVA purchased from First Applied Materials, type F406.
  • the sealant was a silicone sealant from Tonsan, type Tonsan 1527.
  • Potassium acetate (50.0 g) was stirred in the PEG 400 (950.0 g) at room temperature until all of it had been dissolved. In this way, a 5 %by weight solution of potassium acetate in PEG 400 was obtained and was used as catalyst without further treatment.
  • the isocyanate was initially charged in an open vessel at room temperature and stirred by means of a and dissolver disc at 100 revolutions per minute (rpm) . Subsequently, first the separating agent (and optionally the and then the catalyst were added, the stirrer speed was increased to 300 rpm and the whole mixture was stirred for a further 10 min, so as to form a homogeneous mixture. This mixture was used without further treatment for the pultrusion.
  • a profile for a frame was pultruded using Desmodur N 3600 (8.56 kg) , glycerine (1.38 kg) , release agent INT ⁇ 1940 RTM (0.30 kg) , DBTL (0.008 kg) and glass fiber rovings.
  • the rovings were pulled into an injection box in which the resin mixture was pumped, and impregnated. Afterwards, the wetted fibers were passed through a heated dye (temperature 200 °C) . The pulling speed was 0.3 m/min. The resulting profile was used without further treatment.
  • a profile for a frame was pultruded using Desmodur N 3600 (9.45 kg) , release agent INT ⁇ 1940 RTM (0.30 kg) , trimerisation catalyst KOAc in PEG (0.2 kg) , zinc stearate (0.05 kg) and glass fiber rovings.
  • the rovings were pulled into an injection box in which the resin mixture was pumped, and impregnated. Afterwards, the wetted fibers were passed through a heated dye (temperature 200 °C) . The pulling speed was 0.3 m/min. The resulting profile was used without further treatment.
  • Example for solar module A (inventive example 3)
  • a sandwich stack consisting of a pane of glass (solar glass, 3.2mm, 1.60 m x 1.00 m) , EVA ⁇ sheet, wired solar cells, EVA ⁇ sheet and a back sheet was assembled by vacuum lamination process as well known in the industry. The whole circumference of the stack was enclosed by the frame C of example 2 and using a silicone sealant. The finished solar module assembly was subjected to the tests according to standard IEC 61215: 2005 and passed these. In addition, the finished solar module was put outdoors (Shanghai) for more than 12 months without any change of appearance.
  • Example for solar module A (inventive example 4)
  • a sandwich stack consisting of a pane of glass (solar glass, 3.2mm, 1.60 m x 1.00 m) , EVA ⁇ sheet, wired solar cells, EVA ⁇ sheet and a back sheet was assembled by vacuum lamination process as well known in the industry. The whole circumference of the stack was enclosed by the frame C of example 1 and using a silicone sealant. The finished solar module was put outdoors (Shanghai) for more than 12 months without any change of appearance.
  • Aromatic PU frame (Non ⁇ inventive example for frame)
  • a profile for a frame was pultruded using PUL 20PL05, PUL 10PL01 and release agent 4 wt. ⁇ %and glass fiber.
  • the rovings were pulled into an injection box in which the resin mixture was pumped, and impregnated. Afterwards, the wetted fibers were passed through a heated dye (temperature 160 °C) . The pulling speed was 0.6 m/min. The resulting profile was used without further treatment.
  • the samples after performing the weathering test showed strong surface changes such as exposed pristine glass fibers on the surface and discoloration.
  • the aromatic polyurethane matrix has not the necessary chemical stability under these test conditions.
  • the test according to SAE J 2527 was already stopped after 1000 h due to sample degradation.
  • the profile showed no required weathering fastness for a solar frame and could not be used for making a solar module.
  • non ⁇ inventive example showed clearly that non ⁇ coated aromatic polyurethane based frames alone are not durable enough for the requirements of frames for solar modules, and need additional protection e.g. by coatings.
  • frames based on a reaction mixture comprising at least 50 wt. ⁇ %aliphatic polyisocyanate are durable enough and passed the accelerated weathering tests without any degradation or change.

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Photovoltaic Devices (AREA)

Abstract

La présente invention concerne un module solaire A comprenant au moins un empilement B en vitre(s) de verre, un matériau d'encapsulation polymère, une ou des cellules de silicium cristallin et éventuellement une feuille arrière, un cadre C constitué de matériaux composites polymères à base de polyisocyanates aliphatiques et éventuellement un agent d'étanchéité D. Il est caractérisé par une excellente résistance aux intempéries à long terme, une durabilité élevée, des efforts de maintenance réduits et une faible perceptibilité au PID.
PCT/CN2018/088117 2018-05-24 2018-05-24 Module solaire à effet pid réduit WO2019222949A1 (fr)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5578142A (en) * 1994-07-07 1996-11-26 Sunstar Engineering Inc. Solar-cell module and process for producing the same
CN102057498A (zh) * 2008-04-04 2011-05-11 拜尔材料科学股份公司 光伏太阳能模块
WO2014019959A1 (fr) * 2012-07-31 2014-02-06 Bayer Materialscience Ag Élément de support de modules photovoltaïques
CN105131571A (zh) * 2015-09-18 2015-12-09 江苏众成复合材料有限责任公司 一种聚氨酯复合材料太阳能光伏组件框架及其制备方法
CN106469762A (zh) * 2016-12-01 2017-03-01 梁结平 一种抗pid效应的太阳能电池组件
CN106751737A (zh) * 2015-11-23 2017-05-31 万华化学（北京）有限公司 热固性聚氨酯复合物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5578142A (en) * 1994-07-07 1996-11-26 Sunstar Engineering Inc. Solar-cell module and process for producing the same
CN102057498A (zh) * 2008-04-04 2011-05-11 拜尔材料科学股份公司 光伏太阳能模块
WO2014019959A1 (fr) * 2012-07-31 2014-02-06 Bayer Materialscience Ag Élément de support de modules photovoltaïques
CN105131571A (zh) * 2015-09-18 2015-12-09 江苏众成复合材料有限责任公司 一种聚氨酯复合材料太阳能光伏组件框架及其制备方法
CN106751737A (zh) * 2015-11-23 2017-05-31 万华化学（北京）有限公司 热固性聚氨酯复合物
CN106469762A (zh) * 2016-12-01 2017-03-01 梁结平 一种抗pid效应的太阳能电池组件

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