WO2019200796A1 - 一种环保型哑光面涂及其制备工艺 - Google Patents

一种环保型哑光面涂及其制备工艺 Download PDF

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WO2019200796A1
WO2019200796A1 PCT/CN2018/101624 CN2018101624W WO2019200796A1 WO 2019200796 A1 WO2019200796 A1 WO 2019200796A1 CN 2018101624 W CN2018101624 W CN 2018101624W WO 2019200796 A1 WO2019200796 A1 WO 2019200796A1
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parts
mixture
stirring
matting powder
surface coating
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PCT/CN2018/101624
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English (en)
French (fr)
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黄新波
姜欣
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南通康尔乐复合材料有限公司
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Publication of WO2019200796A1 publication Critical patent/WO2019200796A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • the invention relates to the technical field of surface coating preparation, in particular to an environment-friendly matte surface coating and a preparation process thereof.
  • the traditional matte finish is to add matting powder to the resin liquid to achieve the desired matte effect, but the coating surface is not uniform and not delicate due to the inability to control the arrangement and agglomeration of the matting powder.
  • Another process is that the matte type resin is generally water-based, and the particle size of the resin emulsified particles is matched with the wavelength of the light to form a diffuse reflection to bring about a matte visual effect. Both processes have their pros and cons.
  • an environment-friendly matte topcoat the surface coating component comprises 10-20 parts of a special acrylic polymer by weight, and the polyester modified polysiloxane 5-15 4 parts, low viscosity dimethyl silicone oil, 2-8 parts of matting powder, 3-9 parts of diatomaceous earth, 3-9 parts of hardening anti-wear agent, 4-10 parts of polyethylene wax emulsion and water-based fluorocarbon Resin 6-12 parts.
  • the preferred distribution ratio of the topcoat component comprises 15 parts of a special acrylic polymer, 10 parts of a polyester modified polysiloxane, 7 parts of a low viscosity dimethicone, 5 parts of a matting powder, and 6 parts of diatomaceous earth. 6 parts of hardening anti-wear agent, 7 parts of polyethylene wax emulsion and 9 parts of water-based fluorocarbon resin.
  • the matting powder is coated with silica using silazane.
  • the preparation process comprises the following steps:
  • the stirring speed is 200-400 rpm, and the time is 5 min-10 min.
  • the mixture C was filtered through a 200-300 mesh screen to obtain a matte finish.
  • the preparation process of the invention is simple, and the prepared surface coating film has soft gloss, uniform smoothness, good wear resistance and strong adhesion at the same time.
  • the matting powder is coated with silazane, and the silazane is less likely to cause agglomeration, and has a defoaming effect in the coating.
  • the added polyether modified polysiloxane utilizes the reaction of its end groups to the silazane coated on the surface of the matting powder to influence and intervene in the arrangement of the matting powder, so that it tends to be neat.
  • the low-viscosity dimethicone oil added in the present invention solves the phenomenon of whitening after the matting powder is applied.
  • Embodiment 1 is a diagrammatic representation of Embodiment 1:
  • the top coat component includes 10 parts of special acrylic polymer, 5 parts of polyester modified polysiloxane, 4 parts of low viscosity dimethicone, 2 parts of matting powder, 3 parts of diatomaceous earth, and hardening resistance. 3 parts of a grinding agent, 4 parts of a polyethylene wax emulsion, and 6 parts of an aqueous fluorocarbon resin.
  • the mixture C was filtered through a 200 mesh screen to obtain a matte finish.
  • Embodiment 2 is a diagrammatic representation of Embodiment 1:
  • the top coat component comprises 20 parts of special acrylic polymer, 15 parts of polyester modified polysiloxane, 10 parts of low viscosity dimethicone, 8 parts of matting powder, 9 parts of diatomaceous earth, and hardening resistance. 9 parts of a grinding agent, 10 parts of a polyethylene wax emulsion, and 12 parts of an aqueous fluorocarbon resin.
  • the mixture C was filtered through a 300 mesh screen to obtain a matte finish.
  • Embodiment 3 is a diagrammatic representation of Embodiment 3
  • the top coat component includes 12 parts of special acrylic polymer, 7 parts of polyester modified polysiloxane, 5 parts of low viscosity dimethicone, 3 parts of matting powder, 4 parts of diatomaceous earth, and hardening resistance. 4 parts of a grinding agent, 5 parts of a polyethylene wax emulsion, and 7 parts of an aqueous fluorocarbon resin.
  • A a special acrylic polymer, polyester modified polysiloxane, low viscosity dimethyl silicone oil was mixed and added to a stirred tank at low speed stirring, stirring rate of 250 rpm, time is 6min, to obtain a mixture A;
  • the mixture C was filtered through a 220 mesh screen to obtain a matte finish.
  • Embodiment 4 is a diagrammatic representation of Embodiment 4:
  • the topcoat component comprises 18 parts of special acrylic polymer, 13 parts of polyester modified polysiloxane, 8 parts of low viscosity dimethicone, 7 parts of matting powder, 8 parts of diatomaceous earth, and hardening resistance. 8 parts of a grinding agent, 7 parts of a polyethylene wax emulsion, and 10 parts of an aqueous fluorocarbon resin.
  • the mixture C was filtered through a 300 mesh screen to obtain a matte finish.
  • Embodiment 5 is a diagrammatic representation of Embodiment 5:
  • A a special acrylic polymer, polyester modified polysiloxane, low viscosity dimethyl silicone oil was mixed and added to a stirred tank at low speed stirring, stirring rate of 340 rpm, time is 5min, to obtain a mixture A;
  • the mixture C was filtered through a 200 mesh screen to obtain a matte finish.
  • the surface coating component comprises 15 parts of special acrylic polymer, 10 parts of polyester modified polysiloxane, 7 parts of low viscosity dimethicone, 5 parts of matting powder, 6 parts of diatomaceous earth, and hardening resistance. 6 parts of a grinding agent, 7 parts of a polyethylene wax emulsion, and 9 parts of an aqueous fluorocarbon resin.
  • the mixture C was filtered through a 250 mesh screen to obtain a matte finish.
  • the added polyether modified polysiloxane utilizes the reaction of its end groups on the silazane coated on the surface of the matting powder to influence and intervene the arrangement of the matting powder to make it tidy; the added in the present invention
  • the low-viscosity dimethyl silicone oil solves the phenomenon of whitish after the matting powder coating; the preparation process of the invention is simple, and the prepared surface coating film has soft gloss, uniform smoothness, good wear resistance and strong at the same time. Adhesion.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

提供一种环保型哑光面涂及其制备工艺，其中该面涂组分按重量份数包括特种丙烯酸聚合物10-20份、聚酯改性聚硅氧烷5-15份、低粘度二甲基硅油4-10份、消光粉2-8份、硅藻土3-9份、增硬耐磨剂3-9份、聚乙烯蜡乳液4-10份和水性氟碳树脂6-12份。该面涂制备工艺简单；制得的面漆涂膜光泽度柔和、均匀光滑平整，耐磨性好，具有较强的附着力。

Description

一种环保型哑光面涂及其制备工艺 技术领域
本发明涉及面涂制备技术领域，具体为一种环保型哑光面涂及其制备工艺。
背景技术
传统的哑光面涂是在树脂液中添加消光粉来达到所需的哑光效果，但由于无法控制消光粉的排列及团聚导致涂层面不均匀、不细腻。另一种工艺是采用消光型的树脂一般是水性，采用树脂乳化颗粒的粒径与光的波长进行匹配，形成漫反射从而带来消光的视觉效果。两种工艺各有利弊。
发明内容
本发明的目的在于提供一种环保型哑光面涂及其制备工艺，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：一种环保型哑光面涂,面涂组分按重量份数包括特种丙烯酸聚合物10-20份、聚酯改性聚硅氧烷5-15份、低粘度二甲基硅油4-10份、消光粉2-8份、硅藻土3-9份、增硬耐磨剂3-9份、聚乙烯蜡乳液4-10份和水性氟碳树脂6-12份。
优选的，面涂组分优选的成分配比包括特种丙烯酸聚合物15份、聚酯改性聚硅氧烷10份、低粘度二甲基硅油7份、消光粉5份、硅藻土6份、增硬耐磨剂6份、聚乙烯蜡乳液7份和水性氟碳树脂9份。
优选的，所述消光粉采用硅氮烷包裹二氧化硅。
优选的，其制备工艺包括以下步骤：
A、将特种丙烯酸聚合物、聚酯改性聚硅氧烷、低粘度二甲基硅油混合后加入搅拌罐中低速搅拌，搅拌速率为200-400转/分，时间为5min-10min，得到混合物A；
B、在混合物A中加入消光粉、硅藻土、增硬耐磨剂，混合后加入分散机进行搅拌，分散机转速为1500-2000转/分，分散时间为20min-40min，得到 混合物B；
C、在混合物B中加入聚乙烯蜡乳液和水性氟碳树脂，充分混合后加入反应釜中加热搅拌，加热温度为45℃-55℃，搅拌速率为400-800转/分，时间为4min-10min，得到混合物C；
D、将混合物C采用200-300目滤网过滤，即得到哑光面涂。
与现有技术相比，本发明的有益效果是：
(1)本发明制备工艺简单，制得的面涂漆膜光泽度柔和、均匀光滑平整，耐磨性好，同时具有较强的附着力。
(2)本发明中，消光粉采用硅氮烷包裹二氧化硅，硅氮烷不易造成团聚，且在涂层中有消泡的作用。
(3)本发明中，添加的聚醚改性聚硅氧烷，利用其端基对消光粉表面包裹的硅氮烷的反应来影响和干预消光粉的排列，使其趋于整齐。
(4)本发明中添加的低粘度二甲基硅油，解决了消光粉涂布后发白的现象。
具体实施方式
下面对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
本发明提供如下技术方案：一种环保型哑光面涂,面涂组分按重量份数包括特种丙烯酸聚合物10-20份、聚酯改性聚硅氧烷5-15份、低粘度二甲基硅油4-10份、消光粉2-8份、硅藻土3-9份、增硬耐磨剂3-9份、聚乙烯蜡乳液4-10份和水性氟碳树脂6-12份；其中，消光粉采用硅氮烷包裹二氧化硅，硅氮烷不易造成团聚，且在涂层中有消泡的作用。
实施例一：
面涂组分按重量份数包括特种丙烯酸聚合物10份、聚酯改性聚硅氧烷5 份、低粘度二甲基硅油4份、消光粉2份、硅藻土3份、增硬耐磨剂3份、聚乙烯蜡乳液4份和水性氟碳树脂6份。
本实施例的制备工艺包括以下步骤：
A、将特种丙烯酸聚合物、聚酯改性聚硅氧烷、低粘度二甲基硅油混合后加入搅拌罐中低速搅拌，搅拌速率为200转/分，时间为5min，得到混合物A；
B、在混合物A中加入消光粉、硅藻土、增硬耐磨剂，混合后加入分散机进行搅拌，分散机转速为1500转/分，分散时间为20min，得到混合物B；
C、在混合物B中加入聚乙烯蜡乳液和水性氟碳树脂，充分混合后加入反应釜中加热搅拌，加热温度为45℃，搅拌速率为400转/分，时间为4min，得到混合物C；
D、将混合物C采用200目滤网过滤，即得到哑光面涂。
实施例二：
面涂组分按重量份数包括特种丙烯酸聚合物20份、聚酯改性聚硅氧烷15份、低粘度二甲基硅油10份、消光粉8份、硅藻土9份、增硬耐磨剂9份、聚乙烯蜡乳液10份和水性氟碳树脂12份。
本实施例的制备工艺包括以下步骤：
A、将特种丙烯酸聚合物、聚酯改性聚硅氧烷、低粘度二甲基硅油混合后加入搅拌罐中低速搅拌，搅拌速率为400转/分，时间为10min，得到混合物A；
B、在混合物A中加入消光粉、硅藻土、增硬耐磨剂，混合后加入分散机进行搅拌，分散机转速为2000转/分，分散时间为40min，得到混合物B；
C、在混合物B中加入聚乙烯蜡乳液和水性氟碳树脂，充分混合后加入反应釜中加热搅拌，加热温度为55℃，搅拌速率为800转/分，时间为10min，得到混合物C；
D、将混合物C采用300目滤网过滤，即得到哑光面涂。
实施例三：
面涂组分按重量份数包括特种丙烯酸聚合物12份、聚酯改性聚硅氧烷7份、低粘度二甲基硅油5份、消光粉3份、硅藻土4份、增硬耐磨剂4份、聚乙烯蜡乳液5份和水性氟碳树脂7份。
本实施例的制备工艺包括以下步骤：
A、将特种丙烯酸聚合物、聚酯改性聚硅氧烷、低粘度二甲基硅油混合后加入搅拌罐中低速搅拌，搅拌速率为250转/分，时间为6min，得到混合物A；
B、在混合物A中加入消光粉、硅藻土、增硬耐磨剂，混合后加入分散机进行搅拌，分散机转速为1600转/分，分散时间为25min，得到混合物B；
C、在混合物B中加入聚乙烯蜡乳液和水性氟碳树脂，充分混合后加入反应釜中加热搅拌，加热温度为47℃，搅拌速率为450转/分，时间为5min，得到混合物C；
D、将混合物C采用220目滤网过滤，即得到哑光面涂。
实施例四：
面涂组分按重量份数包括特种丙烯酸聚合物18份、聚酯改性聚硅氧烷13份、低粘度二甲基硅油8份、消光粉7份、硅藻土8份、增硬耐磨剂8份、聚乙烯蜡乳液7份和水性氟碳树脂10份。
本实施例的制备工艺包括以下步骤：
A、将特种丙烯酸聚合物、聚酯改性聚硅氧烷、低粘度二甲基硅油混合后加入搅拌罐中低速搅拌，搅拌速率为350转/分，时间为9min，得到混合物A；
B、在混合物A中加入消光粉、硅藻土、增硬耐磨剂，混合后加入分散机进行搅拌，分散机转速为1900转/分，分散时间为38min，得到混合物B；
C、在混合物B中加入聚乙烯蜡乳液和水性氟碳树脂，充分混合后加入反应釜中加热搅拌，加热温度为54℃，搅拌速率为700转/分，时间为9min，得到混合物C；
D、将混合物C采用300目滤网过滤，即得到哑光面涂。
实施例五：
面涂组分按重量份数包括特种丙烯酸聚合物16份、聚酯改性聚硅氧烷12份、低粘度二甲基硅油5份、消光粉7份、硅藻土4份、增硬耐磨剂8份、聚乙烯蜡乳液6份和水性氟碳树脂9份。
本实施例的制备工艺包括以下步骤：
A、将特种丙烯酸聚合物、聚酯改性聚硅氧烷、低粘度二甲基硅油混合后加入搅拌罐中低速搅拌，搅拌速率为340转/分，时间为5min，得到混合物A；
B、在混合物A中加入消光粉、硅藻土、增硬耐磨剂，混合后加入分散机进行搅拌，分散机转速为1560转/分，分散时间为32min，得到混合物B；
C、在混合物B中加入聚乙烯蜡乳液和水性氟碳树脂，充分混合后加入反应釜中加热搅拌，加热温度为46℃，搅拌速率为750转/分，时间为5min，得到混合物C；
D、将混合物C采用200目滤网过滤，即得到哑光面涂。
实施例六：
面涂组分按重量份数包括特种丙烯酸聚合物15份、聚酯改性聚硅氧烷10份、低粘度二甲基硅油7份、消光粉5份、硅藻土6份、增硬耐磨剂6份、聚乙烯蜡乳液7份和水性氟碳树脂9份。
本实施例的制备工艺包括以下步骤：
A、将特种丙烯酸聚合物、聚酯改性聚硅氧烷、低粘度二甲基硅油混合后加入搅拌罐中低速搅拌，搅拌速率为300转/分，时间为8min，得到混合物A；
B、在混合物A中加入消光粉、硅藻土、增硬耐磨剂，混合后加入分散机进行搅拌，分散机转速为1750转/分，分散时间为30min，得到混合物B；
C、在混合物B中加入聚乙烯蜡乳液和水性氟碳树脂，充分混合后加入反应釜中加热搅拌，加热温度为50℃，搅拌速率为600转/分，时间为7min， 得到混合物C；
D、将混合物C采用250目滤网过滤，即得到哑光面涂。
本发明中，添加的聚醚改性聚硅氧烷，利用其端基对消光粉表面包裹的硅氮烷的反应来影响和干预消光粉的排列，使其趋于整齐；本发明中添加的低粘度二甲基硅油，解决了消光粉涂布后发白的现象；本发明制备工艺简单，制得的面涂漆膜光泽度柔和、均匀光滑平整，耐磨性好，同时具有较强的附着力。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。

Claims (4)

  1. 一种环保型哑光面涂,其特征在于：面涂组分按重量份数包括特种丙烯酸聚合物10-20份、聚酯改性聚硅氧烷5-15份、低粘度二甲基硅油4-10份、消光粉2-8份、硅藻土3-9份、增硬耐磨剂3-9份、聚乙烯蜡乳液4-10份和水性氟碳树脂6-12份。
  2. 根据权利要求1所述的一种环保型哑光面涂,其特征在于：面涂组分优选的成分配比包括特种丙烯酸聚合物15份、聚酯改性聚硅氧烷10份、低粘度二甲基硅油7份、消光粉5份、硅藻土6份、增硬耐磨剂6份、聚乙烯蜡乳液7份和水性氟碳树脂9份。
  3. 根据权利要求1所述的一种环保型哑光面涂,其特征在于：所述消光粉采用硅氮烷包裹二氧化硅。
  4. 实现权利要求1所述的一种环保型哑光面涂的制备工艺,其特征在于：其制备工艺包括以下步骤：
    A、将特种丙烯酸聚合物、聚酯改性聚硅氧烷、低粘度二甲基硅油混合后加入搅拌罐中低速搅拌，搅拌速率为200-400转/分，时间为5min-10min，得到混合物A；
    B、在混合物A中加入消光粉、硅藻土、增硬耐磨剂，混合后加入分散机进行搅拌，分散机转速为1500-2000转/分，分散时间为20min-40min，得到混合物B；
    C、在混合物B中加入聚乙烯蜡乳液和水性氟碳树脂，充分混合后加入反应釜中加热搅拌，加热温度为45℃-55℃，搅拌速率为400-800转/分，时间为4min-10min，得到混合物C；
    D、将混合物C采用200-300目滤网过滤，即得到哑光面涂。
PCT/CN2018/101624 2018-04-16 2018-08-22 一种环保型哑光面涂及其制备工艺 WO2019200796A1 (zh)

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