WO2019197615A1

WO2019197615A1 - Active ingredient combinations with fungicides, insecticides and acaricidal properties

Info

Publication number: WO2019197615A1
Application number: PCT/EP2019/059434
Authority: WO
Inventors: Reiner Fischer; Holger Weckwert; Matthias Haas; Stefan Herrmann; Marita JOHN
Original assignee: Bayer Aktiengesellschaft
Priority date: 2018-04-13
Filing date: 2019-04-12
Publication date: 2019-10-17

Abstract

The invention relates to the use of active ingredient combinations comprising at least one compound of formula (I) and at least one compound (B) from the classes (1) to (15) listed in the description for controlling animal and microbial pests.

Description

Active ingredient combinations with fungicidal, insecticidal and acaricidal properties

The present invention relates to novel drug combinations which consist of known compounds of the formula (I) on the one hand and other known fungicidal active compounds on the other hand and are very suitable for controlling animal and / or microbial pests such as phytopathogenic fungi, insects and / or unwanted acarids.

The compounds of the formula (I) are known from WO 06/089633, which describes their use for controlling animal pests. However, the efficacy and / or range of action and / or the plant tolerance of this compound, in particular to crops, is not always sufficient.

Also known are mixtures of compounds of formula (I) with other insecticides and / or acaricides, z.Bsp. WO 2009/039951.

It has now been found that active substance combinations comprising at least one compound of the formula (I)

in which

W and Y are independently hydrogen, C _| - ('4-alkyl, chlorine, bromine, iodine or fluorine,

X is Ct-C ^ alkyl, C _| - (' _[ -alkoxy, chlorine, bromine or iodine,

D is hydrogen or methyl,

A, B and the carbon atom to which they are attached are C ^ -C ^ -cycloalkyl in which optionally one ring member is replaced by nitrogen and which is optionally monosubstituted by C _t-C alkoxy, or

A, B and the carbon atom to which they are bonded, represent O _j -C ^ -cycloalkyl, which by an optionally by C _| - is substituted (' _[ -alkyl or C 1 -C 4 -alkoxy-C 1 -C 2 -alkyl-substituted alkylenedioxy group which forms a 5-membered or 6-membered ketal with the carbon atom to which it is attached, G is hydrogen (a) or one of the groups

stand,

in which

E is a metal ion or an ammonium ion,

M is oxygen or sulfur,

R 1 is straight-chain or branched C 1 -C 8 -alkyl,

represents straight-chain or branched C _j -Cg-alkyl

and at least one further compound (B) selected from the following groups (classes): 1) inhibitors of ergosterol biosynthesis,

2) inhibitors of the respiratory chain on complex I or II,

3) inhibitors of the respiratory chain on complex PI,

4) inhibitors of mitosis and cell division,

5) compounds that can act in several places ("multisite action"),

6) Compounds capable of inducing host defense responses

7) inhibitors of amino acid and / or protein biosynthesis,

8) inhibitors of ATP production,

9) inhibitors of cell wall synthesis,

10) inhibitors of lipid and membrane synthesis,

11) inhibitors of melanin biosynthesis,

12) inhibitors of nucleic acid synthesis,

13) inhibitors of signal transmission, 14) compounds that can act as decouplers,

15) further fungicides have very good fungicidal, insecticidal and / or acaricidal properties.

In one embodiment, the active compound combinations according to the invention comprise, in addition to at least one of the compounds of the formula (I), at least one further compound (B) selected from the following groups (classes):

1) inhibitors of ergosterol biosynthesis, for example (1,001) cyproconazole, (1,002) difenoconazole, (1,003) epoxiconazole, (1,004) fenhexamide, (1,005) fenpropidin, (1,006) fenpropimorph, (1,007) fenpyrazamine, (1,008) fluquinconazole, (1.009 ) Flutriafol, (1,010) hnazalil, (1,011) imazalil sulfate, (1,012) ipconazole, (1,013) metconazole, (1,014) myclobutanil, (1,015) paclobutrazole, (1,016) prochloraz, (1,017) propiconazole, (1,018) prothioconazole, (1,019 ) Pyrisoxazole, (1,020) spiroxamine, (1,021) tebuconazole, (1,022) tetraconazole, (1,023) triadimenol, (1,024) tridemorph, (1,025) triticonazole, (1,026) (IR, 2S, 5S) -5 - (4-chlorobenzyl ) -2- (chloromethyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol, (1.027) (IS, 2R, 5R) -5- (4-chlorobenzyl) -2- (chloromethyl) -2-methyl-1- (1H-l, 2,4-triazol-1-ylmethyl) cyclopentanol, (1.028) (2R) -2- (1-chlorocyclopropyl) -4 - [(lR 2,2,2-dichlorocyclopropyl] -1- (1H-1,2,4-triazol-1-yl) butan-2-ol, (1029) (2R) -2- (1-chlorocyclopropyl) -4- [(1S) -2,2-dichloro cyclopropyl] - 1 - (1H-1,2,4-triazol-1-yl) butan-2-ol, (1.030) (2R) -2- [4- (4-chlorophenoxy) -2- (trifluoro- methyl) phenyl] -1- (1H-1,2,4-triazol-1-yl) -propan-2-ol, (1.031) (2S) -2- (1-chlorocyclopropyl) -4 - [(1R ) -2,2-dichlorocyclopropyl] -1 - (1H-1,2,4-triazol-1-yl) butan-2-ol, (1032) (2S) -2- (1-chlorocyclopropyl) -4- [(1S) -2,2-dichlorocyclopropyl] -1- (1H-1,2,4-triazol-1-yl) butan-2-ol, (1033) (2S) -2- [4- (4 -Chlorphenoxy) -2-

(trifluoromethyl) phenyl] -1- (1H-1,2,4-triazol-1-yl) propan-2-ol, (1034) (R) - [3- (4-Chloro-2-fluorophenyl) - 5 - (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (1.035) (S) - [3- (4-chloro-2-fluorophenyl) -5 - (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (1.036) [3- (4-chloro-2-fluorophenyl) -5- (2,4 (difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (1.037) 1 - ({(2R, 4S) -2- [2-chloro-4- (4-chlorophenoxy) phenyl] -4-methyl-1,3-dioxolan-2-yl-methyl) -1 H -1, 2,4-triazole, (1038) 1 - ({(2S, 4S) -2- [2-chloro 4- (4-chlorophenoxy) phenyl] -4-methyl-1,3-dioxolan-2-yl} methyl) -1 H -1, 2,4-triazole, (1.039) 1 - {[3- (2- Chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole-5-thyl-thiocyanate, (1040) 1 - {[rel (2R, 3R) - 3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-l, 2,4-triazol-5-ylthiocyanate, (1.041) 1 - {[rel (2R , 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole-5-thyl-thiocyanate, (1.04 2) 2- [(2R, 4R, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1, 2,4-triazole-3-thione, (1043) 2 - [(2R, 4R, 5S) -l- (2,4-)

Dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thione, (1.044) 2- [(2R, 4S , 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione , (1.045) 2 - [(2R, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H- l, 2,4-triazole-3-thione, (1.046) 2 - [(2S, 4R, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6- trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (1047) 2- [(2S, 4R, 5S) -1- (2,4-)

Dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thione, (1048) 2- [(2S, 4S , 5R) -l- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane-4-yl] -2,4-dihydro-3H-l, 2,4-triazol-

3-thione, (1.049) 2 - [(2S, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro -3H-l, 2,4-triazole-3-thione, (1050) 2- [1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2, 4-dihydro-3H-1,2,4-triazole-3-thione, (1.051) 2- [2-chloro-4- (2,4-dichlorophenoxy) phenyl] -1 - (1H-

1,2,4-triazol-1-yl) propan-2-ol, (1.052) 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1H-1, 2,4-triazole) 1-yl) butan-2-ol, (1.053) 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1H-1,2,4-triazol-1-yl) butan-2-ol, (1.054) 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1H-1,2,4-triazol-1-yl) pentan-2-one ol, (1.055) 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1H-1,2,4-triazol-1-yl) propan-2-ol, (1.056 )

2- {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-l, 2,4-triazole-3-thione, (1.057) 2- {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-

1,2,4-triazole-3-thione, (1.058) 2- {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} - 2,4-dihydro-3H-l, 2,4-triazole-3-thione, (1.059) 5- (4-chlorobenzyl) -2- (chloromethyl) -2-methyl-1- (1H-1,2-dione) , 4-triazol-1-ylmethyl) cyclopentanol, (1.060) 5- (allylsulfanyl) -1 - {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} - 1H-1,2,4-triazole, (1.061) 5- (allylsulfanyl) -1 - {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2 -yl] methyl} -1 H -1, 2,4-triazole, (1.062) 5 - (allylsulfanyl) -1 - {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2, 4-difluorophenyl) oxiran-2-yl] methyl} -1H-l, 2,4-triazole, (1.063) N '- (2,5-dimethyl-4- {[3- (1,1,2,2 tetrafluoroethoxy) phenyl] sulfanyl} phenyl) -N-ethyl-N-methylimidoformamide, (1.064) N '- (2,5-dimethyl-4- {[3- (2,2,2-trifluoroethoxy) phenyl] sulfanyl} phenyl) -N-ethyl-N-methylimidoformamide, (1.065) N '- (2,5-dimethyl-4- {[3- (2,2,3,3-tetrafluoropropoxy) phenyl] sulfanyl} phenyl) -N-ethyl-N-methylimidoformamide, (1.066) N '- (2,5-dimethyl-4- {[3- (pe ntafluoroethoxy) - phenyl] sulfanyl} phenyl) -N-ethyl-N-methylimidoformamide, (1.067) N '- (2,5-dimethyl-4- {3- [(1,1,2,2-tetrafluoroethyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide, (1.068) N '- (2,5-dimethyl-

4- {3 - [(2,2,2-trifluoroethyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide, (1.069) N '- (2.5-

Dimethyl 4- {3 - [(2,2,3,3-tetrafluoropropyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide, (1.070) N '- (2,5-dimethyl-4- { 3 - [(pentafluoroethyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide, (1.071) N '- (2,5-dimethyl-4-phenoxyphenyl) -N-ethyl-N-methylimidoformamide, (1.072) N '- (4- {[3- (Difluoromethoxy) phenyl] sulfanyl} -2,5-dimethylphenyl) -N-ethyl-N-methylimidoformamide, (1.073) N' - (4- {3 - [(Difluoromethyl) sulfanyl ] phenoxy} -2,5-dimethylphenyl) -N-ethyl-N-methylimidoformamide, (1.074) N '- [5-bromo-6- (2,3-dihydro-1H-inden-2-yloxy) -2- methylpyridine

3-yl] -N-ethyl-N-methylimidoformamide, (1.075) N '- {4 - [(4,5-dichloro-l, 3-thiazol-2-yl) oxy] -2,5-dimethylphenyl} - N-ethyl-N-methylimidoformamide, (1.076) N '- {5-bromo-6 - [(1R) -l- (3,5-difluorophenyl) -ethoxy] -2-methylpyridin-3-yl} -N- ethyl N -methylimidoformamide, (1.077) N '- {5-bromo-6 - [(1S) -1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl- N-methylimidoformamide, (1.078) N '- {5-bromo-6- [(cis-4-isopropylcyclohexyl) oxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (1.079) N' - {5-bromo-6 - [(trans-4-isopropylcyclohexyl) oxy] -2-methylpyridin-3-yl} -N-ethyl-N- methylimidoformamide, (1080) N '- {5-bromo-6- [1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (1,081) mefentrifluconazole, (1,082) Ipfentrifluconazole.

2) respiratory chain inhibitors on complex I or P, for example (2,001) benzovindiflupyr, (2,002) bixafen, (2,003) boscalid, (2,004) carboxin, (2,005) fluopyram, (2,006) flutolanil, (2,007) fluxapyroxad, (2,008 ) Furametpyr, (2.009) isofetamide, (2.010) isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), (2.011) isopyrazam (anti-epimeric enantiomer 1S, 4R, 9R), (2.012) isopyrazam (anti-epimeric racemate 1RS, 4SR, 9SR), (2.013) isopyrazam (mixture of syn-epimeric racemate 1RS, 4SR, 9RS and anti-epimeric racemate 1RS, 4SR, 9SR), (2.014) isopyrazam (syn-epimeric enantiomer 1R, 4S, 9R), ( 2.015) isopyrazam (syn-epimeric enantiomer 1S, 4R, 9S), (2.016) isopyrazam (syn-epimeric racemate 1RS, 4SR, 9RS), (2.017) penflufen, (2.018) penthiopyrad, (2.019)

Pydiflumetofen, (2,020) pyrazolium, (2,021) sedaxane, (2,022) 1,3-dimethyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole 4-carboxamide, (2.023) l, 3-dimethyl-N - [(3R) -l, l, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4 carboxamide, (2.024) 1,3-dimethyl-N - [(3S) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, ( 2.025) 1-methyl-3- (trifluoromethyl) -N- [2'- (trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (2.026) 2-fluoro-6- (trifluoromethyl) -N (l, 1, 3-trimethyl-2,3-dihydro-1H-inden-4-yl) benzamide, (2.027) 3- (difluoromethyl) -1-methyl-N- (1, 1, 3-trimethyl-

2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.028) 3- (difluoromethyl) -1-methyl-N - [(3R) -

1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] - 1H-pyrazole-4-carboxamide, (2.029) 3 - (difluoromethyl) -1-methyl-N - [(3S) -l, l, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.030) 3-

(Difluoromethyl) -N- (7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1-methyl-1H-pyrazole-4-carboxamide, (2.031) 3 - (Difluoromethyl) - N - [(3R) -7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1-methyl-1H-pyrazole-4-carboxamide , (2.032) 3- (difluoromethyl) -N - [(3S) -7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -l-methyl-1H pyrazole-4-carboxamide, (2.033) 5,8-difluoro-N- [2- (2-fluoro-4- {[4- (trifluoromethyl) pyridin-2-yl] oxy} phenyl) ethyl] quinazoline-4 amine, (2.034) N- (2-cyclopentyl-5-fluorobenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.035) N- (2 tert -butyl-5-methylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.036) N- (2-tert-butylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.037) N- (5-chloro-2-ethylbenzyl) -N-cyclopropyl-3- (difluoromethyl ) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.038) N- (5-chloro-2-isopropylbenzyl) -N-cyclopropyl-3- (difluoro-methyl) -5-fluoro-1 methyl-lH-pyrazol- 4-carboxamide, (2.039) N - [(IR, 4S) -9- (dichloromethylene) -l, 2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl] -3- (difluoromethyl) -l -methyl-1H-pyrazole-4-carboxamide, (2.040) N - [(IS, 4R) -9- (dichloromethylene) -1,3,3,4-tetrahydro-1,4-methanonaphthalen-5-yl] - 3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.041) N- [1- (2,4-dichlorophenyl) -1-methoxypropan-2-yl] -3-

(difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.042) N- [2-chloro-6- (trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-one methyl-1H-pyrazole-4-carboxamide, (2.043) N- [3-chloro-2-fluoro-6- (trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl- 1H-pyrazole-4-carboxamide, (2.044) N- [5-chloro-2- (trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H- pyrazole-4-carboxamide, (2.045) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-N- [5-methyl-2- (trifluoromethyl) benzyl] -1H-pyrazole-4-carboxamide, (2.046) N-Cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-fluoro-6-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.047) N -cyclopropyl-3 -

(difluoromethyl) -5-fluoro-N- (2-isopropyl-5-methylbenzyl) -l-methyl-1H-pyrazole-4-carboxamide, (2.048) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N - (2-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carbothioamide, (2.049) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -l-methyl-1H- pyrazole-4-carboxamide, (2.050) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (5-fluoro-2-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, ( 2.051) N-Cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-4,5-dimethylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.052) N-cyclopropyl-3 - (difluoromethyl) - N - (2-ethyl-5-fluorobenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.053) N-cyclopropyl-3- (difluoromethyl) -N- (2 -ethyl-5-methylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.054) N-cyclopropyl-N- (2-cyclopropyl-5-fluorobenzyl) -3- (difluoromethyl) -5 fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.055) N-cyclopropyl-N- (2-cyclopropyl-5-methylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H- pyrazole-4-carboxamide, (2.056) N-cycl O-propyl N- (2-cyclopropylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide.

3) respiratory chain inhibitors on complex PI, for example (3,001) ametoctradine, (3,002)

Amisulbrom, (3.003) Azoxystrobin, (3.004) Coumethoxystrobin, (3.005) Coumoxystrobin, (3.006) Cyazofamide, (3.007) Dimoxystrobin, (3.008) Enoxastrobin, (3.009) Famoxadone, (3.010) Fenamidon, (3.011) Flufenoxystrobin, (3.012) Fluoxastrobin, (3.013) kresoxim-methyl, (3.014) metominostrobin, (3.015) orysastrobin, (3.016) picoxystrobin, (3.017) pyraclostrobin, (3.018) pyrametostrobin, (3.019) pyraoxystrobin, (3.020) trifloxystrobin, (3.021) (2E) -2- {2 - [({[(IE) -l- (3 - {[(E) -1-Fluoro-2-phenylvinyl] oxy} phenyl) ethylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylacetamide, (3.022) (2E, 3Z) -5- {[1- (4-chlorophenyl) -1H-pyrazol-3-yl] oxy} -2- (methoxyimino) -N, 3- dimethylpent-3-enamide, (3.023) (2R) -2- {2 - [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, (3.024) (2S) -2- {2 [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, (3.025) (3S, 6S, 7R, 8R) -2-methylpropanoic acid 8-benzyl-3 - [({3- [(isobutyryloxy) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9-dioxo-l, 5-dioxonane -7-yl ester, (3.026) 2- {2 - [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, (3.027) N- (3-ethyl-3,5,5 -trimethylcyclohexyl) -3-formamido-2-hydroxybenzamide, (3.028) (2E, 3Z) -5 - {[1- (4-chloro-2-fluorophenyl) -1H-pyrazol-3-yl] oxy} -2- (methoxyimino) -N, 3-dimethylpent-3-enamide, (3.029) methyl {5- [3- (2,4-dimethylphenyl) -1H-pyrazol-1-yl] -2-methylbenzyl-carbamate.

4) inhibitors of mitosis and cell division, for example (4,001) carbendazim, (4,002) diethofencarb,

(4.003) ethaboxam, (4.004) fluopicolide, (4.005) pencycuron, (4.006) thiabendazole, (4.007) thiophanate-methyl, (4.008) zoxamide, (4.009) 3-chloro-4- (2,6-difluorophenyl) -6 -methyl-5-phenylpyridazine, (4.010) 3-chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine, (4,011) 3-chloro-5- (6-chloropyridine) 3-yl) -6-methyl-4- (2,4,6-trifluorophenyl) pyridazine, (4.012) 4- (2-bromo-4- fluorophenyl) -N- (2,6-difluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4.013) 4- (2-bromo-4-fluorophenyl) -N- (2-bromo-6 -fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4.014) 4- (2-bromo-4-fluoropiperiyl) -N- (2-bromophenyl) -l, 3-dimethyl-1H-pyrazole -5-amine, (4.015) 4- (2-bromo-4-fluorophenyl) -N- (2-chloro-6-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4.016) 4 - (2-bromo-4-fluorophenyl) -N- (2-chlorophenyl) -

1,3-dimethyl-1H-pyrazol-5-amine, (4.017) 4- (2-bromo-4-fluorophenyl) -N- (2-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4.018) 4- (2-Chloro-4-fluorophenyl) -N- (2,6-difluorophenyl) -1,3-dimethyl-1H-pyrazole

5-amine, (4.019) 4- (2-Chloro-4-fluorophenyl) -N- (2-chloro-6-fluorophenyl) -1,3-dimethyl-1H-pyrazole-5-amine, (4,020) 4- (2-chloro-4-fluorophenyl) -N- (2-chlorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4,021) 4- (2-chloro-4-fluorophenyl) -N- ( 2-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4.022) 4- (4-chlorophenyl) -5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, (4.023) N - (2-bromo-6-fluorophenyl) -4- (2-chloro-4-fluorophenyl) -1,3-dimethyl-1H-pyrazole-5-amine, (4,024) N- (2-bromophenyl) -4- (2-chloro-4-fluorophenyl) -

1,3-dimethyl-1H-pyrazol-5-amine, (4.025) N- (4-chloro-2,6-difluorophenyl) -4- (2-chloro-4-fluorophenyl) -1,3-dimethyl-1H-pyrazole -5-amine.

5) Multisite action compounds, for example (5,001) Bordeaux mixture, (5,002) captafol, (5,003) captan, (5,004) chlorothalonil, (5,005) copper hydroxide, (5,006) copper naphthenate , (5.007) copper oxide, (5.008) copper oxychloride, (5.009) copper (2+) sulfate, (5.010) dithianone, (5.011) dodin, (5.012) folpet, (5.013) mancozeb, (5.014) maneb, (5.015) Metiram, (5.016) Metiram Zinc, (5.017) Oxine Copper, (5.018) Propineb, (5.019) Sulfur and Sulfur Preparations including Calcium Polysulfide, (5.020) Thiram, (5.021) Zineb, (5.022) Ziram, (5.023)

6-ethyl-5,7-dioxo-6,7-dihydro-5H-pyrrolo [3 ^, 4 ^, 5,6] [1,4] dithiino [2,3-c] [1,2] thiazole 3-carbonitrile.

6) Compounds capable of inducing host defense responses, for example (6,001) acibenzolar-S-methyl, (6,002) isotianil, (6,003) probenazole, (6,004) tiadinil.

7) inhibitors of amino acid and / or protein biosynthesis, for example (7,001) cyprodinil, (7,002) kasugamycin, (7,003) kasugamycin hydrochloride hydrate, (7,004) oxytetracycline, (7,005) pyrimethanil, (7,006) 3- (5-fluoro) 3,3,4,4-tetramethyl-3,4-dihydroisoquinoline-l-yl) quinoline.

8) inhibitors of ATP production, for example (8,001) silthiofam.

9) inhibitors of cell wall synthesis, for example, (9.001) benthi- avalicarb, (9.002) benthiavalicarbisopropyl, (9.003) dimethomorph, (9.004) flumorph, (9.005) iprovalicarb, (9.006) mandipropamide, (9.007) pyrimorph, (9.008) valproate, (9.009) (2E) -3- (4-tert-butylphenyl) -3- (2-chloropyridin-4-yl) -1- (morpholin-4-yl) prop-2-en-1-one, 9,010) (2Z) -3- (4-tert-butylphenyl) -3- (2-chloropyridin-4-yl) -1- (morpholin-4-yl) prop-2-en-1-one.

10) inhibitors of lipid and membrane synthesis, for example (10,001) propamocarb, (10,002) propamocarb hydrochloride, (10,003) tolclofos-methyl. 11) Inhibitors of melanin biosynthesis, for example, (11.001) tricyclazole, (11.002) [3-methyl-1 - [(4-methylbenzoyl) amino] butan-2-yl} carbamic acid 2,2,2-trifluoroethyl ester.

12) inhibitors of nucleic acid synthesis, for example (12.001) benalaxyl, (12.002) benalaxyl-M (kiralaxyl), (12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam).

13) inhibitors of signal transduction, for example (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) proquinazide, (13.005) quinoxyfen, (13.006) vinclozolin.

14) Compounds which may act as decouplers, for example (14.001) fluazinam, (14.002) meptyldinocap.

15) Further compounds, for example (15.001) abscisic acid, (15.002) benthiazole, (15.003) bethoxazine, (15.004) capsimycin, (15.005) carvone, (15.006) quinomethionate, (15.007) Cufraneb, (15.008) cyflufenamid, (15.009) Cymoxanil, (15.010) cyprosulfamide, (15.011) flutianil, (15.012) fosetyl-aluminum, (15.013) fosetyl-calcium, (15.014) fosetyl-sodium, (15.015) methyl-isothiocyanate, (15.016) metrafenone, (15.017) mildiomycin, (15.018) natamycin, (15.019) nickel dimethyldithiocarbamate, (15.020) nitrothal isopropyl, (15.021) oxamocarb, (15.022) oxathiapiproline, (15.023) oxyfenthiine, (15.024) pentachlorophenol and salts, (15.025) phosphorous acid and its salts, (15,026) propamocarb-fosetylate, (15,027) pyriofenone (Chlazafenone), (15,028) tebufloquine, (15,029) tecloftalam, (15,030) tolnifanide, (15,031) 1- (4- {4 - [(5R) -5- (2 , 6-difluorophenyl) -4,5-dihydro-

1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, (15.032) 1- (4- [4 - [(5S) -5- (2,6-Difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazole-2 -yl} - piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, (15.033) 2- (6-benzylpyridin-2-yl) quinazoline, (15.034) 2,6-dimethyl-1H, 5H- [1,4] dithiino [2,3-c: 5,6-c '] dipyrrole-l, 3,5,7 (2H, 6H) -tetrone, (15.035) 2- [3,5-bis (difluoromethyl) -H-pyrazol-1-yl] - 1 - [4- (4- {5- [2- (prop-2-yn-1-yloxy) -phenyl ] -4,5-dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1-yl] ethanone, (15,036) 2- [3,5-bis (difluoromethyl ) - 1 H -pyrazol-1-yl] - 1 - [4- (4- {5- [2-chloro-6- (prop-2-yn-1-yloxy) phenyl] -4,5-dihydro- 1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidine-1-yl-ylanone, (15.037) 2- [3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] -l- [4- (4- {5- [2- fluoro-6- (prop-2-yn-1-ynyloxy) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} - 1, 3-thiazol-2-yl) piperidin-1-yl] ethanone, (15.038) 2- [6- (3-fluoro 4-methoxyphenyl) -5-methylpyridin-2-yl] quinazoline, (15.039) Methanesulfonic acid 2 - [(5R) -3- [2- (1 - {[3,5-bis (difluoromethyl) -1H-pyrazole -l-yl] acetyl} piperidin-4-yl) -

1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl-3-chlorophenyl ester, (15.040) methanesulfonic acid -2- {(5S) -3- [2- (1H) [[3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5-dihydro-

1,2-oxazol-5-yl-3-chlorophenyl ester, (15.041) 2- {2- [(7,8-difluoro-2-methylquinolin-3-yl) oxy] -6-fluorophenyl} propan-2-yl ol, (15.042) 2- {2-Fluoro-6 - [(8-fluoro-2-methylquinolin-3-yl) oxy] phenyl} propan-2-ol, (15.043) Methanesulfonic acid -2- {3- [2 - (1 - {[3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] acetyl] piperidin-4-yl) -1,3-thiazol-4-yl] -4,5-dihydro-1 , 2-oxazol-5-yl-3-chlorophenyl ester, (15.044) methanesulfonic acid -2- [3- [2- (1 - [[3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] -acetyl } piperidin-4-yl) -l, 3-thiazol-4-yl] -4,5-dihydro- l, 2-oxazol-5-yl} phenyl ester, (15.045) 2-phenylphenol and salts, (15.046) 3- (4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl ) quinoline, (15.047) 3- (4,4-difluoro-3,3-dimethyl-3,4-dihydro-isoquinolin-1-yl) quinoline, (15.048) 4-amino-5-fluoropyrimidin-2-ol ( tautomeric form: 4-amino-5-fluoropyrimidine-2 (1H) -one), (15.049) 4-oxo-4 - [(2-phenylethyl) amino] butanoic acid, (15.050) 5-amino-1, 3,4 thiadiazole-2-thiol, (15.051) 5-chloro-N'-phenyl-N '- (prop-2-yn-1-yl) thiophene-2-sulfonohydrazide, (15.052) 5-fluoro-2 - [( 4-fluorobenzyl) oxy] pyrimidin-4-amine, (15.053) 5-fluoro-2 - [(4-methylbenzyl) oxy] pyrimidiii-4-amine, (15.054) 9-fluoro-2,2-dimethyl-5 - (quinolin-3-yl) -2,3-dihydro-l, 4-benzoxazepine, (15.055) {6- [({[(Z) - (1-methyl-1H-tetrazol-5-yl) ( phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} -carbamic acid but-3-yn-1-yl ester, (15.056) (2Z) -3-amino-2-cyano-3-phenylacrylic acid ethyl ester, (15.057) phenazine - 1-carboxylic acid, (15.058) 3,4,5-trihydroxybenzoic acid propyl ester, (15.059) quinoline-8-o l, (15,060) quinoline-8-olsulfate (2: 1), (15,061) {6 - [({[(1-methyl-1H-tetrazol-5-yl) (phenyl) -methylene] -amino} oxy) -methyl ] pyridin-2-yl} -carbamic acid tert-butyl ester, (15.062) 5-Fluoro-4-imino-3-methyl-1- [(4-methylphenyl) sulfonyl] -3,4-dihydropyrimidine-2 (1H) -one.

The active ingredients specified here by their "common name" are known and described, for example, in the "Pesticide Manual" (16th edition British Crop Protection Council) or searchable on the Internet (for example: http://www.alanwood.net/pesticides).

All of the above-mentioned mixture partners of classes (1) to (15), if they are capable of doing so on the basis of their functional groups, may optionally form salts with suitable bases or acids. All of the mentioned fungicidal mixture partners of classes (1) to (15) may optionally include tautomeric forms.

Preference is given to active compound combinations comprising compounds of the formula (I) in which the radicals have the following meaning:

W is preferably methyl,

X is preferably chlorine or methyl, (highlighted for methyl),

Y is preferably chlorine, bromine or methyl,

D is preferably hydrogen,

A, B and the carbon atom to which they are attached are preferably saturated C 1-6 cycloalkyl which is substituted with an alkylenedioxy group having a 5-ring or 6-ring ketal with the carbon atom to which it is attached forms,

G is preferably hydrogen (a) or one of the groups

in which

M stands for oxygen,

E is a metal ion equivalent or an ammonium ion (highlighted for sodium or potassium)

Rl preferably represents geradkettigtes or branched C _| - ('q-alkyl, preferably represents straight-chain or branched C _| - (' q-alkyl.

Particularly preferred are the compounds of formula (I) with G = hydrogen.

Very particular preference is given to active compound combinations comprising compounds of the formula (I) in which the radicals have the following meaning:

Particular preference is given to active ingredient combinations comprising the compound of the formula (I-2) and at least one further compound (B) of the classes (1) to (15) described above.

Particularly preferred are combinations of active substances containing the compound of the formula (1-2) and at least one further compound (B) selected from:

(1,002) difenoconazole, (1,010) hnazalil, (1,012) ipconazole, (1,018) prothioconazole, (1,020) spiroxamine, (1,021) tebuconazole, (1,026) (1R, 2S, 5S) -5- (4-chlorobenzyl) -2 (chloromethyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol, (1.027) (IS, 2R, 5R) -5- (4-chlorobenzyl) -2- ( chloromethyl) -2-methyl-1 - (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol, (1.059) 5- (4-chlorobenzyl) -2- (chloromethyl) -2-methyl-1-one (lH-l, 2,4-triazol-1-ylmethyl) cyclopentanol, (1.081) Mefentrifluconazole, (1.082) Ipfentrifluconazole,

(2.001) benzovindiflupyr, (2.002) bixafen, (2.005) fluopyram, (2.007) fluxapyroxad, (2.017) penflufen, (2.018) penthiopyrad, (2.019) pydiflumetofen, (2.021) sedaxanes, (2.027) 3- (difluoromethyl) - l -methyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.030) 3-

(Difluoromethyl) -N- (7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1-methyl-1H-pyrazole-4-carboxamide, (2.038) N - (5-chloro-2-isopropylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide,

(3.003) azoxystrobin, (3.012) fluoxastrobin, (3.016) picoxystrobin, (3.017) pyraclostrobin, (3.020) trifloxystrobin, (3.025) (3S, 6S, 7R, 8R) -2-methylpropanoic acid 8-benzyl-3 - [( {3-

[(isobutyryloxy) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9-dioxo-l, 5-dioxonan-7-yl ester, (3.026) 2- {2 - [( 2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide,

(4.005) Pencycuron, (4.007) thiophanate-methyl, (4.012) 4- (2-bromo-4-fluorophenyl) -N- (2,6-difluorophenyl) -1,3-dimethyl-1H-pyrazole-5- amine, (4.015) 4- (2-bromo-4-fluorophenyl) -N- (2-chloro-6-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4.025) N- (4 -Chloro-2,6-difluorophenyl) -4- (2-chloro-4-fluorophenyl) -1,3-dimethyl-1-1H-pyrazole-5-amine,

(5.004) chlorothalonil, (5.011) dodine, (5.012) folpet, (5.013) mancozeb, (5.018) propineb,

(6.002) Isotianil, (7.005) pyrimethanil,

(12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam),

(13.001) fludioxonil, (13.004) proquinazide,

(14.001) Fluazinam, (14.002) Meptyldinocap, (15.008) Cyflufenamid, (15.027) Pyriofenone (Chlazafenone), (15.047) 3- (4,4-Difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl ) quinoline, (15.048) 4-amino-5-fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidin-2 (1H) -one), (15.052) 5-fluoro-2 - [(4- fluorberrzyl) oxy] pyrimidirr-4-amine, (15.053) 5-fluoro-2- [(4-methylbenzyl) oxy] pyrimidin-4-amine, (15.062) 5-fluoro-4-imino-3-methyl-1 [(4-methylphenyl) sulforryl] -3,4-dihydropyrimidine-2 (1H) -orr. Particular preference is given to active compound combinations comprising the compound of the formula (I-2) and at least one further compound (B) selected from:

(1,012) ipconazole, (1,018) prothioconazole, (1,020) spiroxamine, (1,021) tebuconazole,

(2.002) Bixafen, (2.005) Fluopyram, (2.017) Penflufen, (2.027) 3- (difluoromethyl) -l-methyl-N- (l, l, 3-trimethyl-2,3-dihydro-1 H-indene 4-yl) -1 H -pyrazole-4-carboxamide, (2.038) N- (5-chloro-2-isopropylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole -4-carboxamide,

(3.020) Trifloxystrobin, (3.025) (3S, 6S, 7R, 8R) -2-methylpropanoic acid 8-benzyl-3 - [({3- [(isobutyryloxy) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9-dioxo-l, 5-dioxonan-7-yl-ester,

(4.005) Pencycuron, (5.004) Chlorothalonil, (5.013) Mancozeb, (5.018) Propineb,

(12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam),

(13.001) fludioxonil, (13.004) proquinazide,

(15.008) Cyflufenamide, (15.047) 3- (4,4-Difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline.

Particularly noteworthy are combinations of active substances containing the compound of formula (1-2) and isotianil.

The active compound combinations according to the invention contain the compounds of the formula (I) and the mixing partners (B) of the classes (1) to (15) as described above, preferably in synergistically effective amounts. The weight ratios of the compounds in the active substance combinations can be varied within a relatively wide range. In general, the combinations according to the invention contain compounds of the formula (I) and the mixing partners (B) of the classes (1) to (15) as described above in the following mixing ratios:

3000: 1 to 1: 3000, 1000: 1 to 1: 1000, 750: 1 to 1: 750, 500: 1 to 1: 500, 250: 1 to 1: 250, 200: 1 to 1: 200, 100: 1 to 1: 100, 95: 1 to 1:95, 90: 1 to 1:90, 85: 1 to 1:85, 80: 1 to 1:80, 75: 1 to 1:75, 70: 1 to 1:70, 65: 1 to 1:65, 60: 1 to 1:60, 55: 1 to 1:55, 45: 1 to 1:45, 40: 1 to 1:40, 35: 1 to 1: 35, 30: 1 to 1:30, 20: 1 to 1:20, 15: 1 to 1:15, 10: 1 to 1:10, 9: 1 to 1: 9, 8: 1 to 1: 8, 7: 1 to 1: 7, 6: 1 to 1: 6, 5: 1 to 1: 5, 4: 1 to 1: 4, 3: 1 to 1: 3, 2: 1 to 1: 2, 1: 1, 1: 1.25, 0.001: 1 to 1: 0.001.

Preference is given to active compound combinations comprising the compound of the formula (I-2) and isotianil in the mixing ratio of 10: 1 to 1:10.

Particularly preferred are combinations of active ingredients containing the compound of formula (1-2) and isotianil in the mixing ratio 5: 1-1: 5.

Very particular preference is given to active ingredient combinations comprising the compound of the formula (I-2) and isotianil in the mixing ratio 3: 1 to 1: 3.

Highlighted are active ingredient combinations containing the compound of formula (1-2) and isotianil in the mixing ratio 1: 1.25. In the context of the present invention, the term "active ingredient combination" stands for different combinations of compounds of the formula (I) and the mixing partner (B), for example in the form of a single ready-mix, in a combined spray mixture composed of separate formulations of the individual active ingredients, e.g. a tank mix or in a combined use of the individual active ingredients when applied sequentially, e.g. successively within a reasonably short period of time, e.g. a few hours or days. According to a preferred embodiment, the order of application of the active compounds of the formula (I) and the mixing partner (B) is not critical to the practice of the present invention.

Methods and applications

The active compound combinations according to the invention have a potent microbicidal activity and / or a high potential for plant defense modulating. They can be used to control unwanted microorganisms such as unwanted fungi and bacteria. They are particularly suitable for plant protection (they control micro-organisms that cause plant diseases) or for the protection of materials (eg technical materials, timber, stored Goods), as described in more detail below. More specifically, the active compound combinations according to the invention can be used to protect against undesired microorganisms seeds, germinating seeds, accumulated seedlings, plants, plant parts, fruits, crops and / or the soil in which the plants grow.

As used herein, the control encompasses the protective, curative and eradicative treatment of undesirable microorganisms. The undesirable microorganisms may be pathogenic bacteria, pathogenic viruses, pathogenic oomycetes or pathogenic fungi, specific phytopathogenic bacteria, phytopathogenic viruses, phytopathogenic oomycetes or phytopathogenic fungi. As described in detail below, these phytopathogenic microorganisms are the causative agents of a wide variety of plant diseases.

More specifically, the active compound combinations according to the invention can be used as fungicides. In the description, the term "fungicide" refers to a compound or composition which can be used in crop protection for controlling undesired fungi such as Plasmodiophoromycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes and / or for controlling Oomycetes.

The active compound combinations according to the invention can also be used as antibacterial agent. They can be used in particular in crop protection, for example for controlling undesired bacteria such as Pseudomonadaceae, Rhizobiaceae, Xanthomonadaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.

The active compound combinations according to the invention can also be used as an antiviral agent in crop protection. For example, the compound of the present invention and the composition of the present invention may have effects on diseases of plant viruses such as Tobacco Mosaic Virus (TMV), Tobacco Rattle Virus, Tobacco Stunt Virus (TStuV), Tobacco Leaf Curl Virus (VLCV), Tobacco Nervilia Mosaic Virus (TVBMV), Tobacco Necrotic Dwarf Virus (TNDV), Tobacco Streak Virus (TSV), Potato Virus X (PVX), Potato Viruses Y, S, M, and A, Potato Acuba Mosaic Virus (PAMV), Potato Mop-Top Virus (PMTV), Potato Leaf Roll Virus (PLRV), Alfalfa Mosaic Virus (AMV), Cucumber Mosaic Virus (CMV), Cucumber Green Mottlemosaic Virus (CGMMV), Cucumber Yellows Virus (CuYV), Watermelon Mosaic Virus (WMV), Tomato Spotted Wilt Virus (TSWV ), Tomato Ringspot Virus (TomRSV), Sugarcane Mosaic Virus (SCMV), Rice Dwarf Virus, Rice Stripe Virus, Rice Black-Streaked Dwarf Virus, Strawberry Mottle Virus (SMoV), Strawberry Vein Banding Virus (SVBV), Strawberry Mild Yellow Edge Virus (SMYEV), Strawberry Crinkle Virus (SCrV), Broad Bean Wil t Virus (BBWV) and Melon Necrotic Spot Virus (MNSV). The present invention also relates to a method for controlling unwanted microorganisms such as undesirable fungi, oomycetes and bacteria, which comprises the step of applying at least one active ingredient combination according to the invention to the microorganisms and / or their habitat (to the plants, plant parts, seeds, fruits or soil in which the plants grow).

Typically, when the drug combinations of the present invention are used in curative or protective methods for controlling phytopathogenic fungi and / or phytopathogenic oomycetes, an effective and plant compatible amount thereof is provided to the plants, plant parts, fruits, seeds or soil or substrates in which: the plants grow out. Suitable substrates that can be used to cultivate plants include inorganic based substrates such as mineral wool, especially rockwool, perlite, sand or pebbles; organic substrates such as peat, pine bark or sawdust; and petroleum-based substrates such as polymeric foams or plastic beads. Effective and plant-compatible amount means an amount sufficient to control or destroy the fungi present or occurring on the cultivated land, and which does not induce significant symptoms of phytotoxicity in the crops. Such an amount may vary widely depending on the fungus to be controlled, the crop type, the growth stage of the crop, the climatic conditions and the active compound combinations of the present invention used. This amount can be determined by systematic field trials familiar to the person skilled in the art.

pathogens

Nonlimiting examples of pathogens of fungal diseases which can be treated according to the invention include:

Diseases caused by downy mildew pathogens, for example Blumeria species, for example Blumeria graminis; Podosphaera species, for example Podosphaera leucotrichcr, Sphaerotheca species, for example Sphaerotheca fuliginecr, Uncinula species, for example Uncinula necator;

Diseases caused by rust pathogens, for example, Gymnosporangium species, for example, Gymnosporangium sabinae; Hemileia species, for example Hemileia vastatrix; Phakopsora species, for example Phakopsora pachyrhizi or Phakopsora meibomiae, Puccinia species, for example Puccinia recondita, Puccinia graminis or Puccinia striiformis; Uromyces species, for example Uromyces appendiculatus, are caused; Diseases caused by pathogens from the group of the Oomycetes, for example Albugo species, for example Albugo candida) Bremia species, for example Bremia lactucae; Peronospora species, for example Peronospora pisi or P. brassicae, Phytophthora species, for example Phytophthora infestan; Plasmopara species, for example Plasmopara viticola; Pseudoperonospora species, for example Pseudoperonospora humuli or Pseudoperonospora cubensis; Pythium species, for example Pythium ultimum, are caused;

Leaf spot diseases and leaf withering, the z. Alternaria species, for example Alternaria solani; Cercospora species, for example Cercospora beticola; Cladiosporium species, for example Cladiosporium cucumerinum; Cochliobolus species, for example Cochliobolus sativus (conidia form: Drechslera, Syn: Helminthosporium) or Cochliobolus miyabeanus; Colletotrichum species, for example Colletotrichum lindemuthanium; Corynespora species, for example Corynespora cassiicola; Cycloconium species, for example cycloconium oleaginum; Diaporthe species, for example Diaporthe citri; Citeranoe species, for example Elsinoe fawcettiv, Gloeosporium species, for example Gloeosporium laeticolor, Glomerella species, for example Glomerella cingulata; Guignardia species, for example Guignardia bidwelli; Leptosphaeria species, for example Leptosphaeria maculans; Magnaporthe species, for example Magnaporthe grisea Microdochium species, for example Microdochium nivale; Mycosphaerella species, for example Mycosphaerella graminicola, Mycosphaerella arachidicola or Mycosphaerella fijiensis; Phaeosphaeria species, for example Phaeosphaeria nodorum; Pyrenophora species, for example Pyrenophora teres or Pyrenophora tritici repentis; Ramularia species, for example Ramularia collo-cygni or Ramularia areola; Rhynchosporium species, for example Rhynchosporium secalis; Sepiorza species, for example Septoria apii or Septoria lycopersici; Stagonospora species, for example Stagonospora nodorum; Typhula species, for example Typhula incarnata; Profita species, for example, Venturia inaequalis are caused;

Root and stem diseases, the z. Corticium species, for example Corticium graminearum Fusarium species, for example Fusarium oxysporum; Gaeumannomyces species, for example Gaeumannomyces graminis; Plasmodiophora species, for example Plasmodiophora brassicae, Rhizoctonia species, for example Rhizoctonia solani; Sarocladium species, for example Sarocladium oryzae; Sclerotium-Alten, for example Sclerotium oryzae; Tapesm species, for example Tapesia acuformis; Thielaviopsis species, for example Thielaviopsis basicola, are caused;

Ear and panicle diseases (including corncob), the z. Alternaria species, for example Alternaria spp. Aspergillus species, for example Aspergillus flavus Cladosporium species, for example Cladosporium cladosporioides; C / av / cepi species, for example Claviceps purpurea; Fusarium species, for example Fusarium culmorum; Gibberella species, for example Gibberella zeae; Monographella species, for example Monographella nivalis, Stagnospora species, for example Stagnospora nodorum are caused; Diseases caused by gangrenous fungi, for example sphacelotheca species, for example Sphacelotheca reiliana; Tilletia species, for example Tilletia caries or Tilletia controverscr, Urocystis species, for example Urocystis occulta Ustilago species, for example Ustilago nuda;

Fruit rot, the z. Aspergillus species, for example Aspergillus flavus Botrytis species, for example Botrytis cinerea; Monilinia species, for example Monilinia laxa Penicillium species, for example Penicillium expansum or Penicillium purpurogenum; Rhizopus species, for example Rhizopus stolonifer, Sclerotinia species, for example Sclerotinia sclerotiorum; Verticilium species, for example Verticilium alboatrum is caused; seed- and soil-borne rots and wilting as well as casserole diseases, the z. Alternaria species, for example Alternaria brassicicola; Aphanomyces species, for example Aphanomyces euteiches; Ascochyta species, for example Ascochyta lentis; Aspergillus species, for example Aspergillus flavus, Cladosporium species, for example Cladosporium herbarum; Cochliobolus species, for example Cochliobolus sativus (conidia form: Drechslera, Bipolaris Syn: Helminthosporium); Colletotrichum species, for example Colletotrichum coccodes; Fusarium species, for example Fusarium culmorum; Gibberella species, for example Gibberella zeae; Macrophomina species, for example Macrophomina phaseolina; Microdochium species, for example Microdochium nivale; Monographella species, for example Monographella nivalis, Penicillium species, for example Penicillium expansum; Phoma species, for example Phoma Hungary; Phomopsis species, for example Phomopsis soyae phytophthora lals, for example Phytophthora cactorum; Pyrenophora species, for example Pyrenophora graminea; Pyricularia species, for example Pyricularia oryzae; Pythium species, for example Pythium ultimum, Rhizoctonia species, for example Rhizoctonia solani; Rhizopus species, for example Rhizopus oryzae; Sclerotium species, for example Sclerotium rolfsii, Septoria species, for example Septoria nodorum; Typhula species, for example Typhula incarnata; Verticillium species, for example Verticillium dahliae are caused;

Cancers, galls and witches brooms, the z. Caused by Nectria species, for example Nectria galligena;

Wilting diseases, e.g. Verticillium species, for example Verticillium longisporum; Fusarium species, for example Fusarium oxysporum are caused;

Deformations of leaves, flowers and fruits, the z. B. Exobasidium species, for example Exobasidium vexans; Taphrina species, for example, Taphrina deformans are caused;

Degenerative diseases of woody plants, the z. From foca species, for example Phaeomoniella chlamydospora, Phaeoacremonium aleophilum or Fomitiporia mediterranea; Ganoderma species, for example Ganoderma boninense be caused; Diseases of plant tubers, the z. From Rhizoctonia species, for example Rhizoctonia solani; Helminthosporium species, for example Helminthosporium solani;

Diseases caused by bacterial agents, eg. Xanthomonas species, for example Xanthomonas campestris pv. Oryzae Pseudomonas species, for example Pseudomonas syringae pv. Lachryman; Erwinia species, for example Erwinia amylovora; Liberibacter species, for example Liberibacter asiaticu; Xyella species, for example Xylella fastidiosa Ralstonia species, for example Ralstonia solanacearum; Dickeya species, for example Dickeya solani; Clavibacter species, for example Clavibacter michiganensis; Streptomyces species, for example Streptomyces scabies are caused.

Diseases of soybeans:

Fungal diseases on leaves, stems, pods and seeds, the z. Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatuni), brown spot disease (Septoria glycines), Cercoipora purple spot disease (Cercospora kikuchii), Choanephora leaf-blight (Choanephora infundibulifera trispora (Choanephora infundibulifera trispora). Syn.j), Dactuliophora-heuf-Spot (Dactuliophora glycines), downy mildew (Peronospora manshurica), Drechslera blight (Drechsler glycini), Cen ospora shrimp (Cercospora sojina), Feptosphaerulina leaf vascular disease (Leptosphaerulina trifolii), P / ry / Zorf / ca-blotch disease (Phyllosticta sojaecola), Pod and Star Blight (Phomopsis sojae), Powdery mildew (Microsphaera diffusa), Pyrenoc / iaeta leaf spot disease (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage and Web Blight (Rhizoctonia solani), rust (Phakopsora pachyrhizi, Phakopsora meibomiae), scab (Sphaceloma glycines), stemphyllium Leaf Blight (Stemphylium botryosum), Sudden Death Syndrome (Fusarium virguliforme), target spot (Corynespora cassiicola) are caused;

Fungal diseases on roots and the stem base, the z. Black Root Red (Calonectria crotalariae), Black Rot (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Red, and Pod and Collar Red (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Red (Mycoleptodiscus terrestris ), Neocosmospora (Neocosmospora vasinfecta), Pod and Star Blight (Diaporthe phaseolorum), Stem Crab (Diaporthe phaseolorum var. Caulivora), Phytophthora rot. (Phytophthora megasperma), Brown Star Red (Phialophora gregata), Pythium rot (Pythium aphanidermatum, Pythium irregular, Pythium debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Red, Star Decay and Damping off (Rhizoctonia solani), Sclerotinia star Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis root rot (Thielaviopsis basicola). mycotoxins

In addition, the active compound combinations according to the invention can reduce the mycotoxin content in the crop and the food and feed produced therefrom. Specifically, mycotoxins include, but are not limited to, the following: desoxynivalenol (DON), nivalenol, 15-Ac-DON, 3-Ac-DON, T2 and HT2 toxin, fumonisins, zearalenone, moniliformin, fusarin, diaceotoxyscirpenol (DAS), beauvericin, enniatine, fusaroproliferin, fusarenol, ochratoxins, patulin, ergot alkaloids and aflatoxins, which can be produced, for example, by the following fungi: Fusarium spec., Such as F. acuminatum, F. asiaticum, F. avenaceum, F. crookwellense, F. culmorum, F. graminearum (Gibberella zeae), F. equiseti, F. fujikoroi, F. musarum, F. oxysporum, F. proliferatum, F. poae, F. pseudograminearum, F. sambucinum, F. scirpi, F. semitectum, F. solani, F. sporotrichoid, F. langsethiae, F. subglutinans, F. tricinctum, F. verticillioides, etc., and also by Aspergillus spec. such as A. flavus, A. parasiticus, A. nomius, A. ochraceus, A. clavatus, A. terreus, A. versicolor, Penicillium spec. as P. verrucosum, P. viridicatum, P. citrinum, P. expansum, P. claviforme, P. roqueforti, Claviceps spec. as C. purpurea, C. fusiformis, C. paspali, C. africana, Stachybotrys spec. and other.

Methods and uses

The invention also relates to methods for controlling animal pests, in which the active ingredient combinations according to the invention are allowed to act on animal pests and / or their Eebensraum. The control of animal pests is preferably carried out in forestry and material protection. Excluded therefor are preferably methods for the surgical or therapeutic treatment of the human or animal body and diagnostic methods that are performed on the human or animal body.

The invention further relates to the use of the active compound combinations according to the invention as pesticides, in particular crop protection agents.

In the context of the present application, the term pest control always always includes the term pesticides.

The active compound combinations according to the invention are suitable for plant protection, favorable warm-blooded toxicity and good environmental compatibility for the protection of plants and plant organs against biotic and abiotic stress factors, for increasing crop yields, improving the quality of the crop and for controlling animal pests, in particular insects, arachnids, helminths, especially nematodes, and mollusks that occur in agriculture, horticulture, forests, gardens and recreational facilities. The active compound combinations according to the invention can preferably be used as

Pesticides are used. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The above mentioned pests include:

Pests from the strain of Arthropoda, in particular from the class of Arachnida z. Acarus spp., E.g. Acarus siro, Aceria kuko, Aceria sheldoni, Aculops spp., Aculus spp., E.g. Aculus fockeui, Aculus badendali, Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp., E.g. B. Brevipalpus phenicis, Bryobia graminum, Bryobia praetiosa, Centruroides spp., Chorioptes spp., Dermanyssus gallinae, Dermatophagoides pteronyssinus, Dermatophagoides farinae, Dermacentor spp., Eotetranychus spp. Eotetranychus hicoriae, Epitrimerus pyri, Eutetranychus spp., E.g. Eutetranychus banksi, Eriophyes spp., E.g. B. Eriophyes pyri, Glycyphagus domesticus, Halotydeus destructor, Hemitarsonemus spp., Z. B. Hemitarsonemus latus (= Polyphagotarsonemus latus), Hyalomma spp., Ixodes spp., Latrodectus spp., Loxosceles spp., Neutrombicula autumnalis, Nuphersa spp., Oligonychus spp., Z. Oligonychus coffeae, Oligonychus coniferarum, Oligonychus ilicis, Oligonychus indicus, Oligonychus mangiferus, Oligonychus pratensis, Oligonychus punicae, Oligonychus yothersi, Ornithodorus spp., Ornithonyssus spp., Panonychus spp., E.g. Panonychus citri (= Metatetranychus citri), Panonychus ulmi (= Metatetranychus ulmi), Phyllocoptruta oleivora, Platytetranychus multidigituli, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Steneotarsonemus spp. Steneotarsonemus spinki, Tarsonemus spp. Tarsonemus confusus, Tarsonemus pallidus, Tetranychus spp., E.g. Tetranychus canadensis, Tetranychus cinnabarinus, Tetranychus turkestani, Tetranychus urticae, Trombicula alfreddugesi, Vaejovis spp., Vasates lycopersici; from the class of Chilopoda z. Geophilus spp., Scutigera spp .; from the order or class of Collembola z. B. Onychiurus armatus; Sminthurus viridis; from the class of Diplopoda z. B. Blaniulus guttulatus; from the class of the Insecta, z. B. from the order of Blattodea z. Blatta orientalis, Blattella asahinai, Blattella germanica, Leucophaea maderae, Loboptera decipiens, Neostylopyga rhombifolia, Panchlora spp., Parcoblatta spp., Periplaneta spp., E.g. Periplaneta americana, Periplaneta australasiae, Pycnoscelus surinamensis, Supella longipalpa; from the order of Coleoptera z. Acalymma vittatum, Acanthoscelides obtectus, Adoretus spp., Aethina tumida, Agelastica alni, Agrilus spp., E.g. Agrilus planipennis, Agrilus coxalis, Agrilus bilineatus, Agrilus anxius, Agriotes spp., E.g. B. Agriotes linneatus, Agriotes mancus, Alphitobius diaperinus, Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Z. B. Anoplophora glabripennis, Anthonomus spp., e.g. Anthonomus grandis, Anthrenus spp., Apion spp., Apogonia spp., Atomaria spp., E.g. Eg Atomaria linearis, Attagenus spp., Baris caerulescens, Bruchidius obtectus, Bruchus spp., E.g. Bruchus pisorum, Bruchus rufimanus, Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp. Ceutorrhynchus assimilis, Ceutorrhynchus quadridens, Ceutorrhynchus rapae, Chaetocnema spp., E.g. Chaetocnema confinis, Chaetocnema denticulata, Chaetocnema ectypa, Cleonus mendicus, Conoderus spp., Cosmopolites spp., E.g. Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., E.g. Curculio caryae, Curculio caryatrypes, Curculio obtusus, Curculio sayi, Cryptolestes ferrugineus, Cryptolestes pusillus, Cryptorhynchus lapathi, Cryptorhynchus mangiferae, Cylindrocopturus spp., Cylindrocopturus adspersus, Cylindrocopturus furnissi, Dendroctonus spp., E.g. Dendroctonus ponderosae, Dermestes spp., Diabrotica spp., E.g. Diabrotica balteata, Diabrotica barberi, Diabrotica undecimpunctata howardi, Diabrotica undecimpunctata undecimpunctata, Diabrotica virgifera virgifera, Diabrotica virgifera zeae, Dichocrocis spp., Dicladispa armigera, Diloboderus spp., Epicaerus spp., Epilachna spp., E.g. Epilachna borealis, Epilachna varivestis, Epitrix spp., E.g. Epitrix cucumeris, Epitrix fuscula, Epitrix hirtipennis, Epitrix subcrinita, Epitrix tuberis, Faustinus spp., Gibbium psylloides, Gnathocerus cornutus, Hellula and alis, Heteronychus arator, Heteronyx spp., Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypomeces squamosus, Hypothenemus spp., z. Hypothenemus hampei, Hypothenemus obscurus, Hypothenemus pubescens, Lachnosterna consanguinea, Lasioderma serricorne, Latheticus oryzae, Lathridius spp., Lema spp., Leptinotarsa decemlineata, Leucoptera spp., E.g. Luperoptera spp., Luperodes spp., Luperomorpha xanthodera, Lyctus spp., Megacyllene spp., E.g. Megacyllene robiniae, Megascelis spp., Melanotus spp., E.g. Melanotus longulus oregonensis, Meligethes aeneus, Melolontha spp., E.g. Melolontha melolontha, Migdolus spp., Monochamus spp., Naupactus xanthographus, Necrobia spp., Neogalerucella spp., Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Oryzaphagus oryzae, Otiorhynchus spp., E.g. Otiorhynchus cribricollis, Otiorhynchus ligustici, Otiorhynchus ovatus, Otiorhynchus rugosostriarus, Otiorhynchus sulcatus, Oulema spp., E.g. Oulema melanopus, Oulema oryzae, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Phyllophaga helleri, Phyllotreta spp., E.g. Phyllotreta armoraciae, Phyllotreta pusilla, Phyllotreta ramosa, Phyllotreta striolata, Popillia japonica, Premnotrypes spp., Prostephanus truncatus, Psylliodes spp., E.g. Psylliodes affinis, Psylliodes chrysocephala, Psylliodes punctulata, Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Rhynchophorus spp., Rhynchophorus ferruginus, Rhynchophorus palmarum, Scolytus spp. Scolytus multistriatus, Sinoxylon perforans, Sitophilus spp., E.g. Sitophilus granarius, Sitophilus linearis, Sitophilus oryzae, Sitophilus zeamais, Sphenophorus spp., Stegobium paniceum, Stemus spp., E.g. Starchus paludatus, Symphyletes spp., Tanymecus spp., E.g. Tanymecus dilaticollis, Tanymecus indicus, Tanymecus palliatus, Tenebrio molitor, Tenebrioides mauretanicus, Tribolium spp., E.g. Tribolium audax, Tribolium castaneum, Tribolium confusum, Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp., E.g. Zabrus tenebrioides; from the order of Dermaptera z. B. Anisolabis maritime, Forficula auricularia, Labidura riparia; from the order of Diptera z. B. Aedes spp., Z. Aedes aegypti, Aedes albopictus, Aedes sticticus, Aedes vexans, Agromyza spp., E.g. Agromyza frontella, Agromyza parvicornis, Anastrepha spp., Anopheles spp., E.g. Anopheles quadrimaculatus, Anopheles gambiae, Asphondylia spp., Bactrocera spp., E.g. Bactrocera cucurbitae, Bactrocera dorsalis, Bactrocera oleae, Bibio hortulanus, Calliphora erythrocephala, Calliphora vicina, Ceratitis capitata, Chironomus spp., Chrysomya spp., Chrysops spp., Chrysozona pluvialis, Cochliomya spp., Contarinia spp., E.g. Contarinia johnsoni, Contarina nasturtii, Contarina pyrivora, Contarinia schulzi, Contarina sorghicola, Contarinia tritici, Cordylobia anthropophaga, Cricotopus sylvestris, Culex spp. Culex pipiens, Culex quinquefasciatus, Culicoides spp., Culiseta spp., Cuterebra spp., Dacus oleae, Dasineura spp., E.g. B. Dasineura brassicae, Delia spp. Delia antiqua, Delia coarctata, Delia florilega, Delia platura, Delia radicum, Dermatobia hominis, Drosophila spp., E.g. Drosophila melanogaster, Drosophila suzukii, Echinocnemus spp., Euleia heraclei, Fannia spp., Gasterophilus spp., Glossina spp., Haematopota spp., Hydrellia spp., Hydrellia griseola, Hylemya spp., Hippobosca spp., Hypoderma spp. Liriomyza spp., E.g. Liriomyza brassicae, Liriomyza huidobrensis, Liriomyza sativae, Lucilia spp., E.g. Lucilia cuprina, Lutzomyia spp., Mansonia spp., Musca spp., E.g. Musca domestica, Musca domestica vicina, Oestrus spp., Oscinella frit, Paratanytarsus spp., Paralauterborniella subcincta, Pegomya or Pegomyia spp., E.g. Pegomya betae, Pegomya hyoscyami, Pegomya rubivora, Phlebotomus spp., Phorbia spp., Phormia spp., Piophila casei, Platyparea poeciloptera, Prodiplosis spp., Psila rosae, Rhagoletis spp., E.g. Rhagoletis cingulata, Rhagoletis completa, Rhagoletis fausta, Rhagoletis indifferens, Rhagoletis mendax, Rhagoletis pomonella, Sarcophaga spp., Simulium spp., E.g. B. Simulium meridionale, Stomoxys spp., Tabanus spp., Tetanops spp., Tipula spp., Z. B. Tipula paludosa, Tipula simplex, Toxotrypana curvicauda; from the order of Hemiptera z. Acizzia acaciaebaileyanae, Acizzia dodonaeae, Acizzia uncatoides, Acrida turrita, Acyrthosipon spp., E.g. Acyrthosiphon pisum, Acrogonia spp., Aeneolamia spp., Agonoscena spp., Aleurocanthus spp., Aleyrodes proletella, Aleurolobus barodensis, Aleurothrixus floccosus, Allocaridara malayensis, Amrasca spp., E.g. Amrasca bigutulla, Amrasca devastans, Anuraphis cardui, Aonidiella spp. Aonidiella aurantii, Aonidiella citrina, Aonidiella inornata, Aphanostigma piri, Aphis spp., E.g. Aphis citricola, Aphis craccivora, Aphis fabae, Aphis forbesi, Aphis glycines, Aphis gossypii, Aphis hederae, Aphis illinoisensis, Aphis middletoni, Aphis nasturtii, Aphis nerii, Aphis pomi, Aphis spiraecola, Aphis viburniphila, Arboridia apicalis, Arytainilla spp. , Aspidiella spp., Aspidiotus spp., E.g. Aspidiotus nerii, Atanus spp., Aulacorthum solani, Bemisia tabaci, Blastopsylla occidentalis, Boreioglycaspis melaleucae, Brachycaudus helichrysi, Brachycolus spp., Brevicoryne brassicae, Cacopsylla spp., E.g. Cacopsylla pyricola, Calligypona marginata, Capulinia spp., Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chondracris rosea, Chromaphis juglandicola, Chrysomphalus aonidum, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus half, Coccus spp., e.g. Coccus hesperidum, Coccus longulus, Coccus pseudomagnoliarum, Coccus viridis, Cryptomyzus ribis, Cryptoneossa spp., Ctenarytaina spp., Dalbulus spp., Dialeurodes chittendeni, Dialeurodes citri, Diaphorina citri, Diaspis spp., Diuraphis spp., Doralis spp. Drosicha spp., Dysaphis spp., Z. Dysaphis apiifolia, Dysaphis plantaginea, Dysaphis tulipae, Dysmicoccus spp., Empoasca spp., E.g. Empaasca abrupta, Empoasca fabae, Empoasca maligna, Empoasca solana, Empoasca stevensi, Eriosoma spp. Eriosoma americanum, Eriosoma lanigerum, Eriosoma pyricola, Erythroneura spp., Eucalyptolyma spp., Euphyllura spp., Euscelis bilobatus, Ferrisia spp., Fiorinia spp., Furcaspis oceanica, Geococcus coffeae, Glycaspis spp., Heteropsylla cubana, Heteropsylla spinulosa, Homalodisca coagulata, Hyalopterus arundinis, Hyalopterus pruni, Icerya spp., E.g. Icerya purchasi, Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., E.g. B. Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., Z. Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., E.g. Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, Macrosteies facifrons, Mahanarva spp., Melanaphis sacchari, Metcalfiella spp., Metcalfa pruinosa, Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., E.g. Myzus ascalonicus, Myzus cerasi, Myzus ligustri, Myzus ornatus, Myzus persicae, Myzus nicotianae, Nasonovia ribisnigri, Neomaskellia spp., Nephotettix spp., E.g. Nephotettix cincticeps, Nephotettix nigropictus, Nettigoniclla spectra, Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Oxya chinensis, Pachypsylla spp., Parabemisia myricae, Paratrioza spp., E.g. Paratrioza cockerelli, Parlatoria spp., Pemphigus spp., E.g. B. Pemphigus bursarius, Pemphigus populivenae, Peregrinus maidis, Perkinsiella spp., Phenacoccus spp., Z. Phenacoccus madeirensis, Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., E.g. Phylloxera devastatrix, Phylloxera notabilis, Pinnaspis aspidistrae, Planococcus spp., E.g. B. Planococcus citri, Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Z. Pseudococcus calceolariae, Pseudococcus comstocki, Pseudococcus longispinus, Pseudococcus maritimus, Pseudococcus viburni, Psyllopsis spp., Psylla spp., E.g. Psylla buxi, Psylla mali, Psylla pyri, Pteromalus spp., Pulvinaria spp., Pyrilla spp., Quadraspidiotus spp., E.g. Quadraspidiotus juglansregiae, Quadraspidiotus ostreaeformis, Quadraspidiotus perniciosus, Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., E.g. Rhopalosiphum maidis, Rhopalosiphum oxyacanthae, Rhopalosiphum padi, Rhopalosiphum rufiabdominal, Saissetia spp., E.g. Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoidus titanus, Schizaphis graminum, Selenaspidus articulatus, Sipha flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonocephela spp., Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., e.g. Toxoptera aurantii, Toxoptera citricidus, Trialeurodes vaporariorum, Trioza spp., E.g. Trioza diospyri, Typhlocyba spp., Unaspis spp., Viteus vitifolii, Zygina spp .; from the subordination of Heteroptera z. Aelia spp., Anasa tristis, Antestiopsis spp., Boisea spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., E.g. Cimex adjunctus, Cimex hemipterus, Cimex lectularius, Cimex pilosellus, Collaria spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., E.g. Eustistus heros, Euschistus servus, Eustistus tristigmus, Euschistus variolarius, Eurydema spp., Eurygaster spp., Halyomorpha halys, Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptocorisa varicornis, Leptoglossus occidentalis, Leptoglossus phyllopus, Lygocoris spp , Lygocoris pabulinus, Lygus spp., E.g. B. Lygus elisus, Lygus hesperus, Lygus lineolaris, Macropes excavatus, Megacopta cribraria, Miridae, Monalonion atratum, Nezara spp., Z. Nezara viridula, Nysius spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., E.g. Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scaptocoris castanea, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp .; from the order of Hymenoptera z. Acromyrmex spp., Athalia spp., E.g. B. Athalia rosae, Atta spp., Camponotus spp., Dolichovespula spp., Diprion spp., Z. B. Diprion similis, Hoplocampa spp., Z. Hoplocampa cookei, Hoplocampa testudinea, Lasius spp., Linepithema (Iridiomyrmex) humile, Monomorium pharaonis, Paratrechina spp., Paravespula spp., Plagiolepis spp., Sirex spp., E.g. Sirex noctilio, Solenopsis invicta, Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., E.g. Vespa crabro, Wasmannia auropunctata, Xeris spp .; from the order of Isopoda z. Armadillidium vulgare, Oniscus asellus, Porcellio scaber; from the order of Isoptera z. B. Coptotermes spp., Z. B. Coptotermes formosanus, Cornitermes cumulans, Cryptotermes spp., Incisitermes spp., Kalotermes spp., Microtermes obesi, Nasutitermis spp., Odontotermes spp., Porotermes spp., Reticulitermes spp., E.g. B. Reticulitermes flavipes, Reticulitermes hesperus; from the order of Lepidoptera z. Achroia grisella, Acronica major, Adoxophyes spp., E.g. Adoxophytes orana, Aedia leucomelas, Agrotis spp., E.g. B. Agrotis segetum, Agrotis ipsilon, Alabama spp., Z. Alabama argillacea, Amyelois transitella, Anarsia spp., Anticarsia spp., E.g. Anticarsia gemmatalis, Argyroploce spp., Autographa spp., Barathra brassicae, Blastodacna atra, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius, Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata , Chilo spp., Z. Chilo plejadellus, Chilo suppressalis, Choreutis pariana, Choristoneura spp., Chrysodixis chalcites, Clysia ambiguella, Cnaphalocerus spp., Cnaphalocrocis medinalis, Cnephasia spp., Conopomorpha spp., Conotrachelus spp., Copitarsia spp., Cydia spp., E.g. Cydia nigricana, Cydia pomonella, Dalaca noctuides, Diaphania spp., Diparopsis spp., Diatraea saccharalis, Dioryctria spp., E.g. B. Dioryctria zimmermani, Earias spp., Ecdytolopha aurantium, Elasmopalpus lignosellus, Eldana saccharina, Ephestia spp., E.g. Ephestia elutella, Ephestia kuehniella, Epinotia spp., Epiphyas postvittana, Erannis spp., Efciella musculana, Etiella spp., Eudocima spp., Eulia spp., Eupoecilia ambiguella, Euproctis spp. Euproctis chrysorrhoea, Euxoa spp., Feltia spp., Galleria mellonella, Gracillaria spp., Grapholitha spp., E.g. B. Grapholita molesta, Grapholita prunivora, Hedylepta spp., Helicoverpa spp., Z. Helicoverpa armigera, Helicoverpa zea, Heliothis spp. Homo. Spp., Hyponomeuta padella, Kakivoria flavofasciata, Lampides spp., Laphygma spp., Laspeyresia molesta, Leucinodes orbonalis, Leucoptera spp., E.g. B. Leucoptera coffeella, Lithocolletis spp., Z. B. Lithocolletis blancardella, Lithophane antennata, Lobesia spp., Z. Lobesia botrana, Loxagrotis albicosta, Lymantria spp., E.g. B. Lymantria dispar, Lyonetia spp., Z. B. Lyonetia clerkella, Malacosoma neustria, Maruca testulalis, Mamestra brassicae, Melanitis leda, Mocis spp., Monopis obviella, Mythimna separata, Nemapogon cloacellus, Nymphula spp., Oiketicus spp., Omphisa spp., Operophtera spp., Oria spp. Orthaga spp., Ostrinia spp. Ostrinia nubilalis, Panolis flammea, Parnara spp., Pectinophora spp., E.g. B. Pectinophora gossypiella, Perileucoptera spp., Phthorimaea spp., Z. Phthorimaea operculella, Phyllocnistis citrella, Phyllonorycter spp., E.g. Phyllonorycter blancardella, Phyllonorycter crataegella, Pieris spp., E.g. Pieris rapae, Platynota stultana, Plodia interpunctella, Plusia spp., Plutella xylostella (= Plutella maculipennis), Podesia spp., E.g. Podesia syringae, Prays spp., Prodenia spp., Protoparce spp., Pseudaletia spp., E.g. B. Pseudaletia unipuncta, Pseudoplusia includens, Pyrausta nubilalis, Rachiplusia nu, Schoenobius spp., Z. Schoenobius bipunctifer, Scirpophaga spp., E.g. Scirpophaga innotata, Scotia segetum, Sesamia spp., E.g. Sesamia inferens, Sparganothis spp., Spodoptera spp., E.g. Spodoptera eradiana, Spodoptera exigua, Spodoptera frugiperda, Spodoptera praefica, Stathmopoda spp., Stenoma spp., Stomopteryx subsecivella, Synanthedon spp., Tecia solanivora, Thaumetopoea spp., Thermesia gemmatalis, Tinea cloacella, Tinea pellionella, Tineola bisselliella, Tortrix spp ., Trichophaga tapetzella, Trichoplusia spp. Trichoplusia ni, Tryporyza incertulas, Tuta absoluta, Virachola spp .; from the order of Orthoptera or Saltatoria z. B. Acheta domesticus, Dichroplus spp., Gryllotalpa spp., Z. Gryllotalpa gryllotalpa, Hieroglyphus spp., Locusta spp., E.g. Locusta migratoria, melanoplus spp., E.g. Melanoplus devastator, Paratlanticus ussuriensis, Schistocerca gregaria; from the order of Phthiraptera z. Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Phylloxera vastatrix, Phthirus pubis, Trichodectes spp .; from the order of Psocoptera z. Lepinotus spp., Liposcelis spp .; from the order of Siphonaptera z. Ceratophyllus spp., Ctenocephalides spp., E.g. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis; from the order of Thysanoptera z. B. Anaphothrips obscurus, Baliothrips biformis, Chaetanaphothrips leeuweni, Drepanothrips reuteri, Enneothrips flavens, Frankliniella spp. Frankliniella fusca, Frankliniella occidentalis, Frankliniella schultzei, Frankliniella tritici, Frankliniella vaccinii, Frankliniella williamsi, Haplothrips spp., Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamomi, Thrips spp., e.g. B. Thrips palmi, Thrips tabaci; from the order of Zygentoma (= Thysanura), z. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus, Thermobia domestica; from the class of Symphyla z. B. Scutigerella spp., Z. B. Scutigerella immaculata;

Pests of the strain of Mollusca, z. B. from the class of Bivalvia, z. B. Dreissena spp .; and from the class of Gastropoda z. B. Arion spp., Z. B. Arion ater rufus, Biomphalaria spp., Bulinus spp., Deroceras spp., Z. B. Deroceras laeve, Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp .;

Plant pests from the strain of Nematoda, d. H. plant parasitic nematodes, especially Aglenchus spp., e.g. Aglenchus agricola, Anguina spp., E.g. Anguina tritici, Aphelenchoides spp., E.g. Aphelenchoides arachidis, Aphelenchoides fragariae, Belonolaimus spp., E.g. Belonolaimus gracilis, Belonolaimus longicaudatus, Belonolaimus nortoni, Bursaphelenchus spp. Bursaphelenchus cocophilus, Bursaphelenchus eremus, Bursaphelenchus xylophilus, Cacopaurus spp., E.g. Cacopaurus pestis, Criconemella spp., E.g. Criconemella curvata, Criconemella onoensis, Criconemella ornata, Criconemella rusium, Criconemella xenoplax (= Mesocriconema xenoplax), Criconemoides spp., E.g. Criconemoides ferniae, Criconemoides onoense, Criconemoides ornatum, Ditylenchus spp., E.g. Ditylenchus dipsaci, Dolichodorus spp., Globodera spp., E.g. B. Globodera pallida, Globodera rostochiensis, Helicotylenchus spp., Z. Helicotylenchus dihystera, Hemicriconemoides spp., Hemicycliophora spp., Heterodera spp., E.g. Heterodera avenae, Heterodera glycines, Heterodera schachtii, Hirschmaniella spp., Hoplolaimus spp., Longidorus spp., E.g. Longidorus africanus, Meloidogyne spp., E.g. Meloidogyne chitwoodi, Meloidogyne fallax, Meloidogyne hapla, Meloidogyne incognita, Meloinema spp., Nacobbus spp., Neotylenchus spp., Paralongidorus spp., Paraphelenchus spp., Paratrichodorus spp., E.g. Paratrichodorus minor, Paratylenchus spp., Pratylenchus spp., E.g. Pratylenchus penetrans, Pseudohalenchus spp., Psilenchus spp., Punctodera spp., Quinisulcius spp., Radopholus spp., E.g. Radopholus citrophilus, Radopholus similis, Rotylenchulus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., E.g. Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp., E.g. Tylenchorhynchus annulatus, Tylenchulus spp., E.g. B. Tylenchulus semipenetrans, Xiphinema spp., Z. B. Xiphinema index.

The active compound combinations according to the invention may optionally in certain con centrations or application rates as herbicides, safeners, growth regulators or agents for improving plant properties, as microbicides or gametocides, for example as Fungicides, antimycotics, bactericides, viricides (including anti-viral agents) or as agents against MLO (Mycoplasma-like-organism) and RLO (Rickettsia-like-organism). If appropriate, they can also be used as intermediates or precursors for the synthesis of further active ingredients.

Formulations

The present invention further relates to formulations and application forms prepared therefrom as pesticides such. B. drench, Drip and spray, comprising at least one active ingredient combination according to the invention. Optionally, the uses include other pesticides and / or effect-improving adjuvants such as penetration enhancers, e.g. As vegetable oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of fatty acids such as rapeseed oil or soybean oil or alkanol alkoxylates and / or spreading agents such as alkyl siloxanes and / or salts, eg. As organic or inorganic ammonium or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or retention-promoting agents such. As dioctyl sulfosuccinate or hydroxypropyl guar polymers and / or humectants such. As glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizer.

Typical formulations are, for example, water-soluble liquids (SF), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS). ; These and other possible formulation types are described, for example, by Crop Fife International and in Pesticide Specifications, Manual on development and use of FAO and WHO specifications for pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576. If appropriate, the formulations contain, in addition to one or more active compound combinations according to the invention, further agrochemical active substances.

They are preferably formulations or use forms which contain auxiliaries, such as extenders, foaming agents, spontaneity promoters, carriers, emulsifiers, dispersants, antifreeze agents, biocides, thickeners and / or further auxiliaries, for example adjuvants. An adjuvant in this context is a component that enhances the biological effect of the formulation without the component itself having a biological effect. Examples of adjuvants are agents that promote retention, spreading behavior, adherence to the leaf surface, or penetration. These formulations are prepared in a known manner, for. Example by mixing the active compound combinations according to the invention with excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surface-active substances. The preparation of the formulations is carried out either in suitable systems or before or during use.

Excipients which can be used are those which are suitable for the formulation of the active compound combinations according to the invention or for the use forms prepared from these formulations (such as, for example, usable pesticides such as spray mixtures or seed dressing), such as certain physical, technical and / or biological properties to rent.

Suitable extenders z. As water, polar and nonpolar organic chemical liquids such. B. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified), the ketones (such as acetone, cyclohexanone ), esters (including fats and oils) and (poly) ethers, simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (such as dimethylsulfoxide), carbonates and nitriles. In the case of using water as an extender z. As well as organic solvents can be used as an auxiliary solvent. Suitable liquid solvents are essentially: aromatics such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, eg. As petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents such as dimethylformamide or dimethyl sulfoxide, carbonates such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, or nitriles such as acetonitrile or propanenitrile.

In principle, all suitable solvents can be used. Suitable solvents are, for example, aromatic hydrocarbons such. As xylene, toluene or alkylnaphthalenes, chlorinated aromatic or chlorinated aliphatic hydrocarbons such. As chlorobenzene, chloroethylene, or methylene chloride, aliphatic hydrocarbons such. As cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils, alcohols such. As methanol, ethanol, iso-propanol, butanol or glycol and their ethers and esters, ketones such. As acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents such as dimethyl sulfoxide, carbonates such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, nitriles such as acetonitrile or propanenitrile, and water. In principle, all suitable carriers can be used. As carriers are in particular question: z. For example, ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic minerals such as finely divided silica, alumina and natural or synthetic silicates, resins, waxes and / or solid fertilizers. Mixtures of such carriers can also be used. Suitable carriers for granules are: z. As broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, paper, coconut shells, corncobs and tobacco stems.

Also, liquefied gaseous diluents or solvents can be used. In particular, are such extenders or carriers which are gaseous at normal temperature and under atmospheric pressure, for. As aerosol propellants such as halogenated hydrocarbons and butane, propane, nitrogen and carbon dioxide.

Examples of emulsifying and / or foaming agents, dispersants or wetting agents having ionic or non-ionic properties or mixtures of these surfactants are salts of polyacrylic acid, salts of lignosulfonic acid, salts of phenolsulfonic acid or naphthalenesulfonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulfosuccinic acid esters, taurine derivatives (preferably alkyl taurates), isethionate derivatives, phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols and derivatives of the compounds containing sulfates, sulfonates and phosphates, e.g. As alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates, protein hydrolysates, lignin liquors and methylcellulose. The presence of a surface-active substance is advantageous if one of the active compound combinations according to the invention and / or one of the inert carriers is not soluble in water and if the application is carried out in water.

As further auxiliaries can in the formulations and the applications derived therefrom dyes such as inorganic pigments, eg. For example, iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and Metallphthalocyaninfarbstoffe and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc may be present.

Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present. It may also contain foam-forming agents or defoamers.

Furthermore, the formulations and their derived use forms as additional auxiliaries also adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-like polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate and natural phospholipids such as cephalins and lecithins and synthetic phospholipids. Other auxiliaries may be mineral and vegetable oils.

Optionally, further auxiliaries may be present in the formulations and in the use forms derived therefrom. Such additives include, for example, fragrances, protective colloids, binders, adhesives, thickeners, thixotropic agents, penetrants, retention promoters, stabilizers, sequestrants, chelants, humectants, spreading agents. Generally, the active compound combinations of this invention can be used with any solid or liquid additive commonly used for formulation purposes , be combined.

As retention promoters are all those substances which reduce the dynamic surface tension such as dioctylsulfosuccinate or increase the visco-elasticity such as hydroxypropyl guar polymers.

In the present context, all those substances which are conventionally used to improve the penetration of agrochemical active substances into plants come into consideration as penetration promoters. Penetration promoters are in this context defined by the fact that they can penetrate from the (usually aqueous) application broth and / or from the spray coating into the cuticle of the plant and thereby increase the mobility of the active ingredients in the cuticle. The method described in the literature (Baur et al., 1997, Pesticide Science 51, 131-152) can be used to determine this property. Examples include alcohol alkoxylates such as coconut oil ethoxylate (10) or isotridecyl ethoxylate (12), fatty acid esters such as rapeseed oil or soybean oil, Fettaminalkoxylate such as tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.

The formulations preferably contain between 0.00000001 and 98% by weight of the active ingredient combination according to the invention, more preferably between 0.01 and 95% by weight of the active ingredient combination according to the invention, very particularly preferably between 0.5 and 90% by weight of the active ingredient combination according to the invention , based on the weight of the formulation.

The content of the active ingredient combination according to the invention in the forms of application prepared from the formulations (in particular pesticides) can vary within wide ranges. The concentration of the active ingredient combination according to the invention in the application forms can usually be between 0.00000001 and 95% by weight of the active ingredient combination according to the invention, preferably between 0.00001 and 1% by weight, based on the weight of the application form. The application is done in a custom forms adapted to the application forms. mixtures

The active compound combinations according to the invention can also be used in admixture with one or more suitable fungicides, bactericides, acaricides, molluscicides, nematicides, insecticides, microbiologicals, beneficials, herbicides, fertilizers, avian repellents, phytotonics, sterilants, safeners, semiochemicals and / or plant growth regulators, in order to: z. B. to broaden the spectrum of action, to extend the duration of action, to increase the rate of action, to prevent repellence or to prevent development of resistance. Furthermore, such drug combinations, plant growth and / or tolerance to abiotic factors such. As high or low temperatures, improve against dryness or increased water or Bodensalzgehalt. Also, flowering and fruiting behavior can be improved, germination and rooting can be improved, harvesting and crop yields increased, maturity can be enhanced, crop quality and / or nutritional value increased, shelf life extended and / or crop productivity improved.

Furthermore, the active compound combinations according to the invention may be present in a mixture with other active substances or semiochemicals, such as attractants and / or avian repellents and / or plant activators and / or growth regulators and / or fertilizers. Likewise, the active compound combinations according to the invention can be used to improve the plant properties such as, for example, growth, yield and quality of the crop.

In a particular embodiment according to the invention, the active compound combinations according to the invention are present in formulations or in the use forms prepared from these formulations in admixture with further compounds, preferably those as described below.

If one of the following compounds can exist in different tautomeric forms, these forms are also included, although they were not explicitly mentioned in each case. In addition, if they are capable of doing so on the basis of their functional groups, all said mixing partners can optionally form salts with suitable bases or acids.

Insecticides / acaricides / nematicides

The active substances mentioned here by their "common name" are known and described, for example, in the Pesticide Handbook ("The Pesticide Manual" 16th ed., British Crop Protection Council 2012) or searchable on the Internet (eg http: //www.alanwood. net / pesticides). The classification is based on the IRAC Mode of Action Classification Scheme valid at the time of filing this patent application. (1) Acetylcholinesterase (AChE) inhibitors, preferably carbamates selected from alanycarb, aldicarb, bendiocarb, benfuracarb, butocarboxime, butoxycarboxime, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, Pirimicarb, propoxur, thiodicarb, thiofanox, triazamate, trimethacarb, XMC and xylylcarb, or organophosphates selected from acephate, azamethiphos, azinphos-ethyl, azinphos-methyl, cadusafos, chloroethoxyfos, chlorfenvinphos, chloroforms, chlorpyrifos-methyl, coumaphos, cyanophos, demeton S-methyl, diazinon, dichlorvos / DDVP, dicrotophos, dimethoate, dimethylvinphos, disulfone, EPN, ethion, ethoprophos, famphur, fenamiphos, fenitrothion, fenthione, fosthiazate, heptenophos, imicyafos, isofenphos, isopropyl-0- (methoxyaminothio-phosphoryl) salicylate , Isoxathione, Malathion, Mecarbam, Methamidophos, Methidathione, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion-methyl, Phe nthoate, Phorat, Phosalon, Phosmet, Phosphamidone, Phoxim, Pirimiphos-methyl, Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, Triclorfon and Vamidothion.

(2) GABA-controlled chloride channel blockers, preferably cyclodiene organochlorines selected from chlordane and endosulfan, or phenylpyrazoles (fiproles) selected from ethiprole and fipronil.

(3) Sodium channel modulators, preferably pyrethroids selected from acrinathrin, allethrin, d-cis-trans-allethrin, d-trans-allethrin, bifenthrin, bioallethrin, bioallethrin-S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta Cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(lR) -trans isomer], deltamethrin, empenthrin [(EZ) (IR) isomer], esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, bniprothrin, kadethrin, momfluorothrin, permethrin, phenothrin [(lR) -trans isomer], prallethrin, pyrethrin (pyrethrum) , Resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(IR) isomer], tralomethrin and transfluthrin, or DDT or methoxychlor.

(4) Competitive modulators of the nicotinic acetylcholine receptor (nAChR), preferably neonicotinoids selected from acetamiprid, clothianidin, dinotefuran, bnidacloprid, nitenpyram, thiacloprid and thiamethoxam, or nicotine, or sufoximines selected from sulfoxaflor, or butenolides selected from flupyradifurone.

(5) Allosteric modulators of the nicotinic acetylcholine receptor (nAChR), preferably spinosyns selected from spinetoram and spinosad.

(6) Allosteric modulators of the glutamate-dependent chloride channel (GluCl), preferably avermectins / milbemycins selected from abamectin, emamectin benzoate, eepimectin and milbemectin. (7) Juvenile hormone mimetics, preferably juvenile hormone analogs selected from hydroprene, kinoprene and methoprene, or fenoxycarb or pyriproxyfen.

(8) Various non-specific (multi-site) inhibitors, preferably alkyl halides selected from methyl bromide and other alkyl halides, or chloropicrin or sulfuryl fluoride or borax or tartaric or methyl isocyanate producers selected from Diazomet and Metam.

(9) TRPV channel modulators of chordotonic organs selected from pymetrozine and pyrifluquinazone.

(10) mite growth inhibitors selected from clofentezine, hexythiazox, diflovidazine and etoxazole.

(11) Insect intestinal membrane microbial disruptors selected from Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis, and Bt plant proteins selected from CrylAb, CrylAc, CrylFa, CrylA.105, Cry2Ab, VIP3A , mCry3A, Cry3Ab, Cry3Bb and Cry34Ab 1/35 Abi.

(12) inhibitors of mitochondrial ATP synthase, preferably ATP disruptors selected from diafenthiuron, or organotin compounds selected from azocyclotine, cyhexatin and fenbutatin oxide, or propargite or tetradifone.

(13) Decoupling of oxidative phosphorylation by perturbation of the proton gradient selected from chlorfenapyr, DNOC, and sulfluramide.

(14) Blocker of the nicotinic acetylcholine receptor channel selected from Bensultap, Cartap hydrochloride, thiocyclam and thiosultap sodium.

(15) Inhibitors of chitin biosynthesis, type 0, selected from bistrifluron, chlorofluorazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.

(16) inhibitors of chitin biosynthesis, type 1 selected from buprofezin.

(17) Skinning disruptor (especially in dipterans, i.e., two-winged) selected from cyromazine.

(18) Ecdysone receptor agonists selected from chromafenozide, halofenozide, methoxyfenozide and tebufenozide.

(19) Octopamine receptor agonists selected from Amitraz. (20) Mitochondrial complex III electron transport inhibitors selected from hydramethylnone, acequinocyl and fluacrypyrim.

(21) Mitochondrial Complex I Electron Transport Inhibitors, preferably META acaricides selected from Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad and Tolfenpyrad, or rotenone (Derris).

(22) Voltage-responsive sodium channel blocker selected from indoxacarb and metaflumizone.

(23) Inhibitors of acetyl-CoA carboxylase, preferably tetronic and tetramic acid derivatives selected from spirodiclofen, spiromesifen and spirotetramat.

(24) inhibitors of mitochondrial complex IV electron transport, preferably phosphines selected from aluminum phosphide, calcium phosphide, phosphine and zinc phosphide, or cyanides selected from calcium cyanide, potassium cyanide and sodium cyanide.

(25) inhibitors of mitochondrial complex II electron transport, preferably beta-ketone nitrile derivatives selected from cyenopyrafen and Cyflumetofen, or carboxanilides selected from Pyflubumid.

(28) ryanodine receptor modulators, preferably diamides selected from chlorantraniliprole, cyantraniliprole and flubendiamide.

(29) Modulators of chordotonic organs (with undefined target structure) selected from flonicamid.

(30) other active substances selected from afidopyropes, afoxolans, azadirachtin, benclothiaz,

Benzoximat, bifenazate, broflanilide, bromopropylate, quinomethionate, chloroprallethrine, cryolite, cyclaniliprole, cycloxapride, cyhalodiamide, dicloromezotiaz, dicofol, epsilon-metofluthrin, epsilon-momfluthrin, flometoquine, fluazaindolizine, fluensulfone, flufenerim, flufenoxystrobin, flufiprole, fluxtaxon, fluopyram, fluralan, Fluxametamid, Fufenozid, Guadipyr, Heptafluthrin, Imidaclothiz, iprodione, kappa-bifenthrin, kappa-tefluthrin, Fotilaner, Meperfluthrin, Paichongding, pyridalyl, Pyrifluquinazon, Pyriminostrobin, Spirobudiclofen, Tetramethylfluthrin, Tetraniliprol, Tetrachlorantraniliprol, Tigolaner, Tioxazafen, Thiofluoximat, Triflumezopyrim and iodomethane; furthermore preparations based on Bacillus firmus (1-1582, BioNeem, Votivo), and the following compounds: 1- {2-fluoro-4-methyl-5 - [(2,2,2-trifluoroethyl) sulfmyl] phenyl} - 3- (trifluoromethyl) -1H-l, 2,4-triazol-5-amine (known from WO02006 / 043635) (CAS 885026-50-6), {1 '- [(2E) -3- (4-

Chlorophenyl) prop-2-en-1-yl] -5-fluorospiro [indole-3,4'-piperidine] -1 (2H) -yl} (2-chloropyridin-4-yl) -methanone (known from WO0200 / 106457 ) (CAS 637360-23-7), 2-chloro-N- [2- {1 - [(2E) -3- (4-chlorophenyl) -prop-2-en-1-yl] -piperidin-4-yl} -4- (trifluoromethyl) phenyl] isonicotinamide (known from WO 02006/003494) (CAS 872999-66-1), 3- (4-chloro-2,6-dimethylphenyl) -4-hydroxy-8-methoxy-1,8 -diazaspiro [4.5] dec-3-en-2-one (known from WO 2010052161) (CAS 1225292-17-0), 3- (4-chloro-2, 6-dimethylphenyl) -8-methoxy-2-oxo-1,8-diazaspiro [4.5] dec-3-ene 4-yl ethyl carbonate (known from EP 2647626) (CAS-1440516-42-6), 4- (but-2-yn-1-yloxy) -6- (3,5-dimethylpiperidin-1-yl) - 5-fluoropyrimidine (known from W02004 / 099160) (CAS 792914-58-0), PF1364 (known from JP2010 / 018586) (CAS Reg. No. 1204776-60-2), N - [(2E) -1- [(6-chloropyridin-3-yl) methyl] pyridine-2 (1H) -ylidene] -2,2,2-trifluoroacetamide (known from

WO2012 / 029672) (CAS 1363400-41-2), (3E) -3- [l - [(6-chloro-3-pyridyl) methyl] -2-pyridylidene] -l, l, l-trifluoropropane-2 on (known from WO2013 / 144213) (CAS 1461743-15-6), N- [3- (benzylcarbamoyl) -4-chlorophenyl] -1-methyl-3- (pentafluoroethyl) -4- (trifluoromethyl) -1 H- pyrazole-5-carboxamide (known from WO2010 / 051926) (CAS 1226889-14-0), 5-bromo-4-chloro-N- [4-chloro-2-methyl-6-

(methylcarbamoyl) phenyl] -2- (3-chloro-2-pyridyl) pyrazole-3-carboxamide (known from CN103232431) (CAS 1449220-44-3), 4- [5- (3,5-dichlorophenyl) -4 , 5-dihydro-5- (trifluoromethyl) -3-isoxazolyl] -2-methyl-N- (cis-1-oxido-3-thietanyl) -benzamide, 4- [5- (3,5-dichlorophenyl) -4, 5-dihydro-5- (trifluoromethyl) -3-isoxazolyl] -2-methyl-N- (trans-1-oxido-3-thietanyl) benzamide and 4 - [(5S) -5- (3,5-dichlorophenyl) -4,5-dihydro-5- (trifluoromethyl) -3-isoxazolyl] -2-methyl-N- (cis-1-oxido-3-thietanyl) benzamide (known from WO 2013/050317 A1) (CAS 1332628-83 -7), N- [3-chloro-1- (3-pyridinyl) -1H-pyrazol-4-yl] -N-ethyl-3- [(3,3,3-trifluoropropyl) sulfinyl] propanamide, (+ ) -N- [3-chloro-1- (3-pyridinyl) -1H-pyrazol-4-yl] -N-ethyl-3- [(3,3,3-trifluoropropyl) sulfinyl] propanamide and (-) - N- [3-chloro-1- (3-pyridinyl) -1H-pyrazol-4-yl] -N-ethyl-3 - [(3,3,3-trifluoropropyl) sulfinyl] propanamide (known from WO 2013/162715 A2, WO 2013/162716 A2, US 2014/0213448 A1) (CAS 1477923-37-7), 5 - [[(2E) -3-chloro-2-propen-1-yl] amino] -1- [2 , 6-dichloro-4- (trifluoromethyl) phenyl l] -4 - [(trifluoromethyl) sulfinyl] -1H-pyrazole-3-carbonitrile (known from CN 101337937 A) (CAS 1105672-77-2), 3-bromo-N- [4-chloro-2-methyl 6

[(Methylamino) thioxomethyl] phenyl] -l- (3-chloro-2-pyridinyl) -lH-pyrazole-5-carboxamide,

(Liudaibenjiaxuanan, known from CN 103109816 A) (CAS 1232543-85-9); N- [4-chloro-2 - [[(1,1-dimethylethyl) amino] carbonyl 1] -6-methylphenyl] -1- (3-chloro-2-pyridinyl) -3- (fluoromethoxy) -1H-pyrazole 5-carboxamide (known from WO 2012/034403 A1) (CAS 1268277-22-0), N- [2- (5-amino-1, 3,4-thiadiazol-2-yl) -4-chloro-6 -methylphenyl] -3-bromo-1- (3-chloro-2-pyridinyl) -1H-pyrazole-5-carboxamide (known from WO 2011/085575 A1) (CAS 1233882-22-8), 4- [3 [2,6-dichloro-4 - [(3,3-dichloro-2-propen-1-yl) oxy] phenoxy] propoxy] -2-methoxy-6- (trifluoromethyl) pyrimidine (known from CN 101337940 A) ( CAS 1108184-52-6); (2E) - and 2 (Z) -2- [2- (4-cyanophenyl) -1- [3- (trifluoromethyl) phenyl] ethylidene] -N- [4- (difluoromethoxy) phenyl] hydrazinecarboxamide (known from CN 101715774 A) (CAS 1232543-85-9); Cyclopropanecarboxylic acid 3- (2,2-dichloroethenyl) -2,2-dimethyl-4- (1H-benzimidazol-2-yl) phenyl ester (known from CN 103524422 A) (CAS 1542271-46-4); (4aS) -7-chloro-2,5-dihydro-2- [[(methoxycarbonyl) [4 - [(trifluoromethyl) thio] phenyl] amino] carbonyl] indeno [1,2-e] [1, 3,4 ] oxadiazine-4a (3H) -carboxylic acid methyl ester (known from CN 102391261 A) (CAS 1370358-69-2); 6-Deoxy-3-0-ethyl-2,4-di-O-methyl-1 - [N- [4- [1 - [4- (1,1,2,2-pentafluoroethoxy) phenyl] - 1 H -1,2,4-triazol-3-yl] phenyl] carbamate] -AL-mannopyranose (known from US 2014/0275503 A1) (CAS 1181213-14-8); 8- (2-Cyclopropylmethoxy-4-trifluoromethylphenoxy) -3- (6-trifluoromethylpyridazin-3-yl) -3- azabicyclo [3.2.1] octane (CAS 1253850-56-4), (8-anti) -8- (2-cyclopropylmethoxy-4-trifluoromethylphenoxy) -3- (6-trifluoromethylpyridazin-3-yl) -3-azabicyclo [ 3.2.1] octane (CAS 933798-27-7), (8-syn) -8- (2-cyclopropylmethoxy-4-trifluoromethylphenoxy) -3- (6-trifluoromethylpyridazin-3-yl) -3-azabicyclo [3.2. 1] octane (known from WO 2007040280 A1, WO 2007040282 A1) (CAS 934001-66-8), N- [3-chloro-1- (3-pyridinyl) -1H-pyrazol-4-yl] -N-ethyl 3 - [(3,3,3-trifluoropropyl) thio] -propanamide (known from WO 2015/058021 A1, WO 2015/058028 A1) (CAS 1477919-27-9) and N- [4- (aminothioxomethyl) -

2-methyl-6 - [(methylamino) carbonyl] phenyl] -3-bromo-1- (3-chloro-2-pyridinyl) -1-pyrazole-5-carboxamide (known from CN 103265527 A) (CAS 1452877 -50-7), 5- (1,3-dioxan-2-yl) -4 - [[4- (trifluoromethyl) phenyl] methoxy] -pyrimidine (known from WO 2013/115391 A1) (CAS 1449021-97- 9)

3- (4-chloro-2,6-dimethylphenyl) -4-hydroxy-8-methoxy-l-methyl-l, 8-diazaspiro [4.5] dec-3-en-2-one

(known from WO 2010/066780 A1, WO 2011/151146 A1) (CAS 1229023-34-0), 3- (4-chloro-2,6-dimethylphenyl) -8-methoxy-1-methyl-1, 8- diazaspiro [4.5] decane-2,4-dione (known from WO 2014/187846 A1) (CAS 1638765-58-8), 3- (4-chloro-2,6-dimethylphenyl) -8-methoxy-1-methyl 2-oxo-l, 8-diazaspiro [4.5] dec-3-en-4-yl-carboxylic acid ethyl ester (known from WO 2010/066780 A1, WO 2011151146 A1) (CAS 1229023-00-0), N- [l [(6-chloro-3-pyridinyl) methyl] -2 (1 //) -pyridinylidenes] -2,2,2-trifluoroacetamides (known from DE 3639877 A1, WO 2012029672 A1) (CAS 1363400-41- 2), [N (£)] - N - [l - [(6-chloro-3-pyridinyl) methyl] -2 (1 //) pyridinylidenes] -2,2,2-trifluoroacetamides (known from WO 2016005276 A1) (CAS 1689566-03-7), [N (Z)] - N- [1- (6-chloro-3-pyridinyl) methyl] -2 (1 //) -pyridinylidenes] -2, 2,2-trifluoroacetamides (CAS 1702305-40-5), 3-io-3- [2-propoxy-4- (trifluoromethyl) phenoxy] -9 - [[5- (trifluoromethyl) -2-pyridinyl] oxy ] -9-azabicyclo [3.3.1] nonane (known from WO 2011/105506 A1, WO 2016/133011 A1) (CAS 1332838-17-1).

Biological pesticides as mixture components

The active compound combinations according to the invention can be combined with biological pesticides.

Biological pesticides include, in particular, bacteria, fungi, yeasts, plant extracts and those products formed by microorganisms, including proteins and secondary metabolites.

Biological pesticides include bacteria such as spore-forming bacteria, root-colonizing bacteria and bacteria that act as biological insecticides, fungicides or nematicides.

Examples of such bacteria which can be used as biological pesticides are:

Bacillus amyloliquefaciens, strain FZB42 (DSM 231179), or Bacillus cereus, in particular B. cereus strain CNCM 1-1562 or Bacillus firmus, strain 1-1582 (Accession number CNCM 1-1582) or Bacillus pumilus, in particular strain GB34 (Accession No. ATCC 700814) and strain QST2808 (Accession No. NRRL B-30087), or Bacillus subtilis, in particular strain GB03 (Accession No. ATCC SD-1397), or Bacillus subtilis strain QST713 (Accession No. NRRL B-21661) or Bacillus subtilis strain OST 30002 (Accession No. NRRL B-50421), Bacillus thuringiensis, in particular Thuringiensis subspecies israelensis (serotype H-14), strain AM65-52 (Accession No. ATCC 1276), or B. thuringiensis subsp. aizawai, in particular strain ABTS-1857 (SD-1372), or B. thuringiensis subsp. kurstaki strain HD-1, or B. thuringiensis subsp. tenebrionis strain NB 176 (SD-5428), Pasteuria penetrans, Pasteuria spp. (Rotylenchulus reniformis nematode) - PR3 (Accession Number ATCC SD-5834), Streptomyces microflavus strain AQ6121 (= QRD 31.013, NRRL B-50550), Streptomyces galbus strain AQ 6047 (Accession Number NRRL 30232).

Examples of fungi and yeasts which can be used as biological pesticides are:

Beauveria bassiana, in particular strain ATCC 74040, coniothyrium minitans, in particular strain CON / M / 91-8 (Accession No. DSM-9660), Lecanicillium spp., In particular strain HRO LEC 12, Lecanicillium lecanii (formerly known as Verticillium lecanii), in particular Strain KV01, Metarhizium anisopliae, in particular strain F52 (DSM3884 / ATCC 90448), Metschnikowia fructicola, in particular strain NRRL Y-30752, Paecilomyces fumosoroseus (new: Isaria fumosorosea), in particular strain IFPC 200613, or strain Apopka 97 (Accesion No. ATCC 20874 ), Paecilomyces lilacinus, in particular P. lilacinus strain 251 (AGAL 89/030550), Talaromyces flavus, in particular strain VI 17b, Trichoderma atroviride, in particular strain SCI (Accession Number CBS 122089), Trichoderma harzianum, in particular T. harzianum rifai T39. (Accession Number CNCM 1-952).

Examples of viruses that can be used or used as biological pesticides are:

Adoxophyes orana (Apple peel winder) Granulosis virus (GV), Cydia pomonella (codling moth) Granulosis virus (GV), Helicoverpa armigera (cotton bollworm) Nuclear polyhedrosis virus (NPV), Spodoptera exigua (mNPV), Spodoptera frugiperda (armyworm) mNPV, Spodoptera littoralis (African Cotton worm) NPV.

It also includes bacteria and fungi that are added as 'inoculant' plants or parts of plants or plant organs and promote by their special properties, plant growth and plant health. Examples are:

Agrobacterium spp., Azorhizobium caulinodans, Azospirillum spp., Azotobacter spp., Bradyrhizobium Spp., Burkholderia spp., in particular Burkholderia cepacia (formerly known as Pseudomonas cepacia), Gigaspora spp., or Gigaspora monosporum, Glomus spp., Laccaria spp., Lactobacillus buchneri, Paraglomus spp., Pisolithus tinctorus, Pseudomonas spp., Rhizobium spp , in particular Rhizobium trifolii, Rhizopogon spp., Scleroderma spp., Suillus spp., Streptomyces spp.

Examples of plant extracts and those products formed by microorganisms, including proteins and secondary metabolites, which can be used as biological pesticides are:

Allium sativum, Artemisia absinthium, Azadirachtin, Biokeeper WP, Cassia nigricans, Celastrus angulatus, Chenopodium anthelminticum, Chitin, Armor Zen, Dryopteris filix-mas, Equisetum arvense, Fortune Aza, Fungastop, Heads Up (Chenopodium quinoa saponin extract), Pyrethrum / Pyrethrins, Quassia amara, Quercus, Quillaja, Regalia, Requiem ™ Insecticide, Rotenone, Ryania / Ryanodine, Symphytum officinale, Tanacetum vulgare, Thymol, Triact 70, TriCon, Tropaeulum majus, Urtica dioica, Veratrin, Viscum album, Brassicacaeen extract , in particular rapeseed or mustard powder.

Safener as a mixture component

The active compound combinations according to the invention can be combined with safeners, for example Benoxacor, Cloquintocet (-mexyl), Cyometrinil, Cyprosulfamide, Dichlormid, Fenchlorazole (- ethyl), Fenclorim, Flurazole, Fluxofenim, Furilazole, Isoxadifen (-ethyl), Mefenpyr (-diethyl ), Naphthalene anhydrides, oxabetrinil, 2-methoxy-N - ({4-

[(methylcarbamoyl) amino] phenyl} sulfonyl) benzamide (CAS 129531-12-0), 4- (dichloroacetyl) -1-oxa-4-azaspiro [4.5] decane (CAS 71526-07-3), 2,2, 5-trimethyl-3- (dichloroacetyl) -1,3-oxazolidine (CAS 52836- 31-4).

Plants and plant parts

According to the invention, all plants and parts of plants can be treated. Plants are understood to mean all plants and plant populations, such as desirable and unwanted wild plants or crops (including naturally occurring crops), for example cereals (wheat, rice, triticale, barley, rye, oats), corn, soybeans, potatoes, sugar beets, sugarcane, tomatoes , Paprika, cucumber, melon, carrot, watermelon, onion, lettuce, spinach, leek, beans, Brassica oleracea (eg cabbage) and other vegetables, cotton, tobacco, rapeseed, as well as fruit plants (with the fruits apples, pears, Citrus fruits and grapes). Crop plants can be plants that can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including by Plant variety rights protectable or non-protectable plant varieties. Plants are to be understood as meaning all stages of development, such as seeds, cuttings, young (unripe) plants and mature plants. Plant parts are understood to mean all aboveground and subterranean parts and organs of plants such as shoot, leaf, flower and root, examples of which include leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes. The plant parts also include harvested plants or harvested plant parts as well as vegetative and generative propagation material, for example cuttings, tubers, rhizomes, offshoots and seeds.

The treatment according to the invention of the plants and plant parts with the active compound combinations according to the invention is carried out directly or by the action of the compounds on the environment, the Eebensraum or Eagerraum after the usual treatment methods, eg. B. by immersion, spraying, evaporation, nebulization, scattering, brushing, injecting and in propagating material, in particular in seeds, further by single or multi-layer wrapping.

As already mentioned above, according to the invention all plants and their parts can be treated. In a preferred embodiment, wild-type or plant species and plant varieties obtained by conventional biological breeding methods such as crossing or protoplast fusion and parts thereof are treated. In a further preferred embodiment, transgenic plants and plant cultivars obtained by genetic engineering, if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated. The term "parts" or "parts of plants" or "plant parts" has been explained above. It is particularly preferred according to the invention to treat plants of the respective commercially available or in use plant cultivars. Plant varieties are understood as meaning plants having new traits which have been obtained by conventional breeding, by mutagenesis or by recombinant DNA techniques. These may be varieties, breeds, biotypes and genotypes.

Transgenic plant

The preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits"). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products. Further and particularly emphasized examples of such properties are an increased resistance of the plants against animal and microbial pests, such as insects, arachnids, nematodes, mites, snails, causes z. By toxins produced in the plants, in particular those produced by the genetic material from Bacillus thuringiensis (eg by the genes CrylA (a), CrylA (b), CrylA (c), CryflA, CrylllA, CryfIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and their combinations) are produced in the plants, further increased resistance of the plants against plant pathogenic fungi, bacteria and / or viruses, causes z. For example, systemically acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins, as well as an increased tolerance of the plants to certain herbicidal active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT "-Gene). The genes which confer the desired properties ("traits") can also be present in combinations with one another in the transgenic plants. Examples of transgenic plants are the important crops such as cereals (wheat, rice, triticale, barley, rye, oats), corn, soy, potato, sugar beets, sugarcane, tomatoes, peas and other vegetables, cotton, tobacco, oilseed rape, and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with emphasis on corn, soy, wheat, rice, potato, cotton, sugar cane, tobacco and oilseed rape. Traits that are particularly emphasized are the increased resistance of the plants to insects, arachnids, nematodes and snails.

Plant protection - types of treatment

The treatment of the plants and plant parts with the active compound combinations according to the invention is carried out directly or by acting on their environment, habitat or storage space according to the usual treatment methods, eg. B. by dipping, spraying, spraying, sprinkling, vaporizing, atomizing, atomizing, scattering, foaming, brushing, spreading, injecting, pouring (drenchen), drip irrigation and propagating material, especially in seeds, further by dry pickling, wet pickling, slurry pickling, encrusting , single or multi-layer encasing, etc. It is also possible to apply the active compound combinations according to the invention by the ultra-low-volume method or to inject the application form or the active compound combinations according to the invention itself into the soil.

A preferred direct treatment of the plants is foliar application, i. H. the active compound combinations according to the invention are applied to the foliage, wherein the treatment frequency and the application rate should be matched to the infestation pressure of the respective pest.

Formula for the kill rate of a combination of two drugs

The expected effect for a given combination of two drugs can be assessed by SR Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15, 20-22, 1967) are calculated as follows:

If X is the kill rate, expressed in% of the untreated control, using the

Active ingredient A at a rate of m g / ha or in a concentration of

m ppm means

Y means the degree of killing, expressed in% of the untreated control, when using the active ingredient B in an application rate of n g / ha or in a concentration of n ppm, and

E means the degree of killing, expressed in% of the untreated control, when using the active compounds A and B at application rates of m and n g / ha or in a concentration of m and n ppm,

X x Y

then E = X + Y -

100

If the actual kill rate is greater than the calculated kill rate (E), the combination is over-additive in its kill, ie it has a synergistic effect.

Example A

Aphis gossypii - Drench test

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration, whereby the volume of the earth into which it is compressed must also be taken into account. It must be ensured that a concentration of 40 ppm emulsifier is not exceeded in the soil. To prepare further test concentrations, it is diluted with water. Cotton plants (Gossypium hirsutum) in soil pots which are heavily infested with the cotton aphid (Aphis gossypii) are infused with an active compound preparation of the desired concentration.

After the desired time the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined mortality values are calculated according to the Colby formula.

In this test, the following active ingredient combinations according to the present application showed a synergistically enhanced effectiveness in comparison to the individually applied active ingredients:

Table A: Aphis gossypii - Drench test

* Found. = found effect, calc. = calculated effect on the Colby formula

Claims

claims

1 combination of active substances containing at least one compound of the formula (I),

in which

W and Y independently of one another represent hydrogen, C 1 -C 4 -alkyl, chlorine, bromine, iodine or fluorine,

X is C1-C4 alkyl, C _| - (^) alkoxy, chlorine, bromine or iodine,

D is hydrogen or methyl,

A, B and the carbon atom to which they are attached are C _j -C -cycloalkyl in which optionally one ring member is replaced by nitrogen and which is optionally monosubstituted by C _t-C alkoxy, or

A, B and the carbon atom to which they are attached are C _j -C ^ -cycloalkyl which is substituted by an optionally C 1 -C ₄ -alkyl or C ₁ -C ₄ -alkoxy-C ₁ -C ₂ -alkyl-sub substituted alkylenedioxy group which forms a 5-membered or 6-membered ketal with the carbon atom to which it is attached,

G is hydrogen (a) or one of the groups

E (d)

stand in which

E is a metal ion or an ammonium ion,

M is oxygen or sulfur,

R1 for straight-chain or branched C _| -C ^ alkyl, for straight-chain or branched C _| -C ^ alkyl and at least one further compound (B) selected from the following groups (classes):

1) inhibitors of ergosterol biosynthesis,

2) inhibitors of the respiratory chain on complex I or II,

3) inhibitors of the respiratory chain on complex PI, 4) inhibitors of mitosis and cell division,

5) compounds that can act in several places ("multisite action"),

6) Compounds capable of inducing host defense responses

7) inhibitors of amino acid and / or protein biosynthesis,

8) inhibitors of ATP production, 9) inhibitors of cell wall synthesis,

10) inhibitors of lipid and membrane synthesis,

11) inhibitors of melanin biosynthesis,

12) inhibitors of nucleic acid synthesis,

13) inhibitors of signal transmission, 14) compounds which can act as decouplers,

15) other lung fungicides.

2. active ingredient combinations containing at least one compound of the formula (I) according to

Claim 1 and at least one further compound (B) selected from the following groups (classes): 1) inhibitors of ergosterol biosynthesis: (1.001) cyproconazole, (1.002) difenoconazole, (1.003)

Epoxiconazole, (1.004) fenhexamid, (1.005) fenpropidin, (1.006) fenpropimorph, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1.009) flutriafol, (1.010) imazalil, (1.011) hnazalilsulfate, (1.012) ipconazole, (1.013) Metconazole, (1.014) Myclobutanil, (1.015)

Paclobutrazole, (1,016) prochlorazole, (1,017) propiconazole, (1,018) prothioconazole, (1,019) pyrisoxazole, (1,020) spiroxamine, (1,021) tebuconazole, (1,022) tetraconazole, (1,023)

Triadiophene, (1,024) tridemorph, (1,025) triticonazole, (1,026) (1R, 2S, 5S) -5- (4-chlorobenzyl) -2- (chloromethyl) -2-methyl-1 - (1H-1, 2 , 4-triazol-1-ylmethyl) cyclopentanol, (1.027) (1S, 2R, 5R) -5 - (4-chlorobenzyl) -2- (chloromethyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol,

(1.028) (2R) -2- (1-Chlorocyclopropyl) -4- [(1R) -2,2-dichlorocyclopropyl] -1- (1H-1,2,4-triazol-1-yl) butane-2 -ol, (1.029) (2R) -2- (1-chlorocyclopropyl) -4 - [(1S) -2,2-dichlorocyclopropyl] -1 - (1H-

1,2,4-triazol-1-yl) butan-2-ol, (1030) (2R) -2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] - 1 -

(1H-1,2,4-triazol-1-yl) propan-2-ol, (1.031) (2S) -2- (1-chlorocyclopropyl) -4 - [(1R) -2,2-dichlorocyclopropyl] - 1 - (1H-1,2,4-triazol-1-yl) butan-2-ol, (1.032) (2S) -2- (1-chlorocyclopropyl) -4- [(1S) -2,2 dichlorocyclopropyl] -1- (1H-1,2,4-triazol-1-yl) butan-2-ol, (1033) (2S) -2- [4- (4-

Chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1H-1,2,4-triazol-1-yl) propan-2-ol, (1034) (R) - [3- (4-Chloro-2 -fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (1035) (S) - [3- (4-chloro-2- fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (1.036) [3- (4-chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (1.037) 1 - ({(2R, 4S) -2- [2-chloro-4- ( 4-chlorophenoxy) phenyl] -4-methyl-1,3-dioxolan-2-yl} methyl) -1 H -1, 2,4-triazole, (1038) 1 - ({(2S, 4S) -2- [2-chloro-4- (4-chlorophenoxy) phenyl] -4-methyl-1,3-dioxolan-2-yl} methyl) -1H-1,2,4-triazole, (1039) 1-{[3 - (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-l, 2,4-triazol-5-ylthiocyanate, (1040) 1- {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole-5-thyl-thiocyanate, (1.041) 1 - { [rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole-5-ylthiocyanate, ( 1,042) 2 - [( 2R, 4R, 5R) -l- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4-triazole 3-thione, (1043) 2 - [(2R, 4R, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro -3H-l, 2,4-triazole-3-thione, (1044) 2-

[(2R, 4S, 5R) -l- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane-4-yl] -2,4-dihydro-3H-

1,2,4-triazole-3-thione, (1.045) 2 - [(2R, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.046) 2- [(2S, 4R, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2 , 6,6-trimethylheptane-4-yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thione,

(1.047) 2- [(2S, 4R, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1 , 2,4-triazole-3-thione, (1048) 2 - [(2S, 4S, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl ] -2,4-dihydro-3H-l, 2,4-triazole-3-thione, (1.049) 2 - [(2S, 4S, 5S) -l- (2,4-)

Dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1, 2,4-triazole-3-thione,

(1.050) 2- [1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-tiazole-3 -thione, (1.051) 2- [2-Chloro-4- (2,4-dichlorophenoxy) phenyl] -1- (1H-1,2,4-triazol-1-yl) -propan-2-ol, ( 1.052) 2- [2-Chloro-4- (4-chlorophenoxy) phenyl] -1- (1H-1,2,4-triazol-1-yl) butan-2-ol, (1.053) 2- [4 - (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1H-1,2,4-triazol-1-yl) butan-2-ol, (1.054) 2- [4- (4-chlorophenoxy ) -2- (trifluoromethyl) phenyl] -1- (1H-1,2,4-triazol-1-yl) pentan-2-ol, (1.055) 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1H-1,2,4-triazol-1-yl) propan-2-ol,

(1.056) 2- {[3- (2-Chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3 -thione, (1.057) 2- {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H 1-l, 2,4-triazole-3-thione, (1.058) 2- {[rel (2R, 3S) -3- (2-chlorophenyl) -2-] (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-l, 2,4-triazole-3-thione, (1.059) 5- (4-

Chlorobenzyl) -2- (chloromethyl) -2-methyl-1 - (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol, (1,060)

5- (allylsulfanyl) -1- [[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole, (1061) 5 - (allylsulfanyl) -l- {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane

2-yl] methyl} -1H-1, 2,4-triazole, (1.062) 5- (allylsulfanyl) -1 - {[rel (2R, 3S) -3- (2-chlorophenyl) -2-

(2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-l, 2,4-triazole, (1063) N '- (2,5-dimethyl-4- {3)

(l, l, 2,2-tetrafluoroethoxy) phenyl] sulfanyl} phenyl) -N-ethyl-N-methylimidoformamide, (1.064) N '- (2,5-dimethyl-4- {[3- (2,2, 2-trifluoroethoxy) phenyl] sulfanyl} phenyl) -N-ethyl-N-methylimidoformamide, (1.065) N '- (2,5-dimethyl-4- {[3- (2,2,3,3-tetrafluoropropoxy) phenyl] ] - sulfanyl} phenyl) -N-ethyl-N-methylimidoformamide, (1.066) N '- (2,5-dimethyl-4- {[3- (pentafluoroethoxy) phenyl] sulfanyl} phenyl) -N-ethyl- N-methylimidoformamide, (1.067) N '- (2,5-dimethyl-4- {3 - [(1, l, 2,2-tetrafluoroethyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide,

(1.068) N '- (2,5-Dimethyl-4- {3 - [(2,2,2-trifluoroethyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide, (1.069) N' - ( 2, 5-Dimethyl-4- {3 - [(2,3,3,3-tetrafluoropropyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide, (1.070) N '- (2,5-dimethyl -4- {3 - [(pentafluoroethyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide, (1.071) N '- (2,5-dimethyl-4-phenoxyphenyl) -N-ethyl-N-methylimidoformamide , (1.072) N '- (4- {[3- (Difluoromethoxy) phenyl] sulfanyl} -2,5-dimethylphenyl) -N-ethyl-N-methylimidoformamide, (1.073) N' - (4- {3- [ (Difluoromethyl) sulfanyl] phenoxy} -2,5-dimethylphenyl) -N-ethyl-N-methylimidoformamide, (1.074) N '- [5-bromo-6- (2,3-dihydro-1H-inden-2-yloxy ) -2-methylpyridine

3-yl] -N-ethyl-N-methylimidoformamide, (1.075) N '- {4- [(4,5-dichloro-1,3-thiazol-2-yl) oxy] -2,5-dimethylphenyl} - N-ethyl-N-methylimidoformamide, (1.076) N '- {5-bromo-6 - [(IR) -1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N ethyl N-methylimidoformamide, (1.077) N '- {5-bromo-6- [(1S) -1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl -N-methylimidoformamid,

(1.078) N '- {5-Bromo-6 - [(cis-4-isopropylcyclohexyl) oxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (1.079) N' - {5- Bromo-6 - [(trans-4-isopropylcyclohexyl) oxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (1080) N '- {5-bromo-6- [1- (3 , 5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (1.081)

Mefentrifluconazole, (1.082) Ipfentrifluconazole.

2) respiratory chain inhibitors on complex I or II: (2.001) benzovindiflupyr, (2.002) bixafen, (2.003) boscalid, (2.004) carboxin, (2.005) fluopyram, (2.006) flutolanil, (2.007) fluxapyroxad, (2.008) furametpyr , (2.009) isofetamide, (2.010) isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), (2.011) isopyrazam (anti-epimeric enantiomer 1S, 4R, 9R), (2.012) isopyrazam (anti-epimeric racemate 1RS, 4SR , 9SR), (2.013) isopyrazam (mixture of synepimeric racemate 1RS, 4SR, 9RS and anti-epimeric racemate 1RS, 4SR, 9SR), (2.014) isopyrazam (syn-epimeric enantiomer 1R, 4S, 9R), (2.015 Isopyrazam (syn-epimeres

Enantiomer 1S, 4R, 9S), (2.016) isopyrazam (syn-epimeric racemate 1RS, 4SR, 9RS), (2.017) Penflufen, (2.018) Penthiopyrad, (2.019) Pydiflumetofen, (2.020) Pyracetlumide, (2.021) Sedaxane, (2.022) l, 3-Dimethyl-N- (l, l, 3-trimethyl-2,3-dihydro-lH- inden-4-yl) -1H-pyrazole-4-carboxamide, (2.023) l, 3-dimethyl-N - [(3R) -l, l, 3-trimethyl-2,3-dihydro-1H-indene-4 -yl] -1H-pyrazole-4-carboxamide, (2.024) l, 3-dimethyl-N - [(3S) -l, l, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] -lH-pyrazole-4-carboxamide, (2.025) 1-methyl-3- (trifluoromethyl) -N- [2'-

(trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (2.026) 2-fluoro-6- (trifluoromethyl) -N- (1, 1, 3-trimethyl-2,3-dihydro-1H- inden-4-yl) benzamide, (2.027) 3- (difluoromethyl) -1-methyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole -4-carboxamide, (2.028) 3-

(Difluoromethyl) -1-methyl-N - [(3R) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.029) 3 - (difluoromethyl) -l-methyl-N - [(3S) -l, l, 3-trimethyl-2,3-dihydro-lH-inden

4-yl] -1H-pyrazole-4-carboxamide, (2.030) 3- (difluoromethyl) -N- (7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl ) -l-methyl-1H-pyrazole-4-carboxamide, (2.031) 3- (difluoromethyl) -N- [(3R) -7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H -inden-4-yl] - 1-methyl-1H-pyrazole-4-carboxamide, (2.032) 3- (difluoromethyl) -N - [(3S) -7-fluoro-1, 1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl] -l-methyl-1H-pyrazole-4-carboxamide, (2.033) 5,8-difluoro-N- [2- (2-fluoro-4- {4 (trifluoromethyl) pyridin-2-yl] oxy} phenyl) ethyl] quinazolin-4-amine, (2.034) N- (2-cyclopentyl-5-fluorobenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro -l-methyl-1H-pyrazole-4-carboxamide, (2.035) N- (2-tert-butyl-5-methylbenzyl) -N-cyclopropyl-3 - (difluoromethyl) -5-fluoro-1-methyl-1 H-pyrazole-4-carboxamide, (2.036) N- (2-tert-butylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.037 ) N- (5-chloro-2-ethylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -

5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.038) N- (5-chloro-2-isopropylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H pyrazole-4-carboxamide, (2.039) N - [(1R, 4S) -9- (dichloromethylene) -1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl] -3- (difluoromethyl ) -l-methyl-1H-pyrazole-4-carboxamide, (2.040) N - [(IS, 4R) -9- (dichloromethylene) -l, 2,3,4-tetrahydro-1,4-methanonaphthalene-5 - yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.041) N- [1- (2,4-dichlorophenyl) -1-methoxypropan-2-yl] -3- ( difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.042) N- [2-chloro-6- (trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-one methyl-1H-pyrazole-4-carboxamide, (2.043) N- [3-chloro-2-fluoro-6- (trifluoromethyl) benzyl] - N -cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl- 1 H-pyrazole-4-carboxamide, (2.044) N- [5-

Chloro-2- (trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.045) N-cyclopropyl-3- (difluoromethyl) -5 fluoro-1-methyl-N- [5-methyl-2- (trifluoromethyl) benzyl] -1H-pyrazole-4-carboxamide, (2.046) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- ( 2-fluoro-6-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.047) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropyl-5-methylbenzyl) - 1-methyl-1H-pyrazole-4-carboxamide, (2.048) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carbothioamide, 2.049) N-Cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -! -methyl-1H-pyrazole-4-carboxamide, (2.050) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (5-fluoro-2-isopropylbenzyl) -l-methyl-1H-pyrazole-4-carboxamide, (2.051) N-cyclopropyl-3- (difluoromethyl) -N- (2) ethyl-4,5-dimethylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.052) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-5-fluorobenzyl) - 5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.053) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-5-methylbenzyl) -5-fluoro-1-methyl-1H pyrazole-4-carboxamide, (2.054) N-cyclopropyl-N- (2-cyclopropyl-5-fluorobenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.055 ) N-Cyclopropyl-N- (2-cyclopropyl-5-methylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.056) N-cyclopropyl-N- (2 -cyclopropylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide.

3) respiratory chain inhibitors on complex PI: (3.001) ametoctradine, (3.002) amisulbrom,

(3.003) azoxystrobin, (3.004) coumethoxystrobin, (3.005) coumoxystrobin, (3.006) cyazofamide, (3.007) dimoxystrobin, (3.008) enoxastrobin, (3.009) famoxadone, (3.010) fenamidone, (3.011) flufenoxystrobin, (3.012) fluoxastrobin, (3.013) kresoxim-methyl, (3.014) metominostrobin, (3.015) orysastrobin, (3.016) picoxystrobin, (3.017) pyraclostrobin, (3.018) pyrametostrobin, (3.019) pyraoxystrobin, (3.020) trifloxystrobin, (3.021) (2E) -2 - {2 - [({[(IE) -l- (3- {[(E) -l-fluoro-2-phenylvinyl] oxy} phenyl) ethylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino ) -N-methylacetamide, (3.022) (2E, 3Z) -5- {[1- (4-chlorophenyl) -1H-pyrazol-3-yl] oxy} -2- (methoxyimino) -N, 3-dimethylpent- 3-enamide, (3.023) (2R) -2- {2 - [(2,5-)

Dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, (3.024) (2S) -2- {2 - [(2,5-)

Dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, (3.025) (3S, 6S, 7R, 8R) -2-

Methylpropanoic acid 8-benzyl-3 - [({3 - [(isobutyryloxy) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9-dioxo-1, 5-dioxonane-7 ethyl ester, (3.026) 2- {2- [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, (3.027) N- (3-ethyl-3,5,5- trimethylcyclohexyl) -3-formamido-2-hydroxybenzamide, (3.028) (2E, 3Z) -5- {[1- (4-chloro-2-fluorophenyl) -1H-pyrazol-3-yl] oxy} -2- ( methoxyimino) -N, 3-dimethylpent-3-enamide, (3.029) [5- [3- (2,4-dimethylphenyl) -1H-pyrazol-1-yl] -2-methylbenzyl} carbamic acid, methyl ester.

4) Inhibitors of Mitosis and Cell Division: (4.001) Carbendazim, (4.002) Diethofencarb, (4.003)

Ethaboxam, (4.004) fluopicolide, (4.005) pencycuron, (4.006) thiabendazole, (4.007) thiophanate-methyl, (4.008) zoxamide, (4.009) 3-chloro-4- (2,6-difluorophenyl) -6-methyl- 5-phenylpyridazine, (4.010) 3-chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine, (4,011) 3-chloro-5- (6-chloropyridin-3-yl ) -6-methyl-4- (2,4,6-trifluorophenyl) pyridazine, (4.012) 4- (2-bromo-4-fluorophenyl) -N- (2,6-difluorophenyl) -1,3-dimethyl 1H-pyrazol-5-amine, (4.013) 4- (2-bromo-4-fluorophenyl) -N- (2-bromo-6-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, ( 4.014) 4- (2-bromo-4-fluorophenyl) -N- (2-bromophenyl) -l, 3-dimethyl-1H-pyrazol-5-amine, (4.015) 4- (2-bromo-4-fluorophenyl) N- (2-chloro-6-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4.016) 4- (2-bromo-4-fluorophenyl) -N- (2-chlorophenyl) - 1,3-dimethyl-1H-pyrazol-5-amine, (4.017) 4- (2-bromo-4- fluorophenyl) -N- (2-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4,018) 4- (2-chloro-4-fluorophenyl) -N- (2,6-difluorophenyl) - l, 3-dimethyl-1H-pyrazol-5-amine, (4.019) 4- (2-chloro-4-fluorophenyl) -N- (2-chloro-6-fluorophenyl) -1,3-dimethyl-1H-pyrazole -5-amine, (4.020) 4- (2-chloro-4-fluorophenyl) -N- (2-chlorophenyl) -1,3-dimethyl-1H-pyrazole-5-amine, (4,021) 4- (2- Chloro-4-fluorophenyl) -N- (2-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4,022) 4- (4-chlorophenyl) -5- (2,6-difluorophenyl) - 3,6-dimethylpyridazine, (4.023) N- (2-bromo-6-fluorophenyl) -4- (2-chloro-4-fluorophenyl) -1,3-dimethyl-1H-pyrazole-5-amine, (4,024) N- (2-bromophenyl) -4- (2-chloro-4-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine, (4,025) N- (4-chloro-2,6-difluorophenyl) -4- (2-chloro-4-fluorophenyl) -1,3-dimethyl-1H-pyrazole-5-amine.

5) Multisite Action Compounds: (5.001) Bordeaux Mixture, (5.002) Captafol, (5.003) Captan, (5.004) Chlorothalonil, (5.005) Copper Hydroxide, (5.006) Copper Napthenate, ( 5.007) copper oxide, (5.008) copper oxychloride, (5.009) copper (2+) sulfate, (5.010) dithianone, (5.011) dodin, (5.012) folpet, (5.013) mancozeb, (5.014) maneb, (5.015) metiram, (5,016) Metiram Zinc, (5,017) Oxine Copper, (5,018) Propineb, (5,019) Sulfur and Sulfur Preparations Including Calcium Polysulfide, (5,020) Thiram, (5,021) Zineb, (5,022) Ziram, (5,023) 6-Ethyl 5,7-dioxo-6,7-dihydro-5H-pyrrolo [3 ', 4': 5,6] [1,4] dithiino [2,3-c] [1,2] thiazole-3-carbonitrile.

6) Compounds capable of inducing host defense responses: (6,001) acibenzolar-S-methyl, (6,002) isotianil, (6,003) probenazole, (6,004) tiadinil.

7) Inhibitors of amino acid and / or protein biosynthesis: (7,001) cyprodinil, (7,002) kasugamycin, (7,003) kasugamycin hydrochloride hydrate, (7,004) oxytetracycline, (7,005) pyrimethanil, (7,006) 3- (5-fluoro-3, 3,4,4-tetramethyl-3,4-dihydroisoquinoline-l-yl) quinoline.

8) Inhibitors of ATP production: (8,001) Silthiofam.

9) Inhibitors of Cell Wall Synthesis: (9.001) Benthiavalicarb, (9.002) Benthiavalicarb-isopropyl, (9.003) Dimethomorph, (9.004) Flumorph, (9.005) Iprovalicarb, (9.006) Mandipropamide, (9.007) Pyrimorph, (9.008) Valifenalate, (9.009 ) (2E) -3- (4-tert-butylphenyl) -3- (2-chloropyridin-4-yl) -1- (morpholin-4-yl) prop-2-en-1-one, (9.010) (2Z) -3- (4-tert-butylphenyl) -3- (2-chloropyridin-4-yl) -1- (morpholin-4-yl) prop-2-en-1-one.

10) Inhibitors of Lipid and Membrane Synthesis: (10,001) Propamocarb, (10,002) Propamocarb hydrochloride, (10,003) Tolclofos-methyl.

11) Inhibitors of melanin biosynthesis: (11.001) tricyclazole, (11.002) {3-methyl-1 - [(4-methylbenzoyl) amino] butan-2-yl} carbamic acid 2,2,2-trifluoroethyl ester. 12) Inhibitors of Nucleic Acid Synthesis: (12.001) Benalaxyl, (12.002) Benalaxyl-M (Kiralaxyl), (12.003) Metalaxyl, (12.004) Metalaxyl-M (Mefenoxam).

13) Inhibitors of signal transduction: (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) proquinazide, (13.005) quinoxyfen, (13.006) vinclozolin.

14) Compounds that may act as decouplers: (14.001) fluazinam, (14.002) meptyldinocap.

15) Further compounds: (15.001) abscisic acid, (15.002) benthiazole, (15.003) bethoxazine,

(15.004) Capsimycin, (15.005) Carvone, (15.006) Quinomethionate, (15.007) Cufraneb, (15.008) Cyflufenamid, (15.009) Cymoxanil, (15.010) Cyprosulfamide, (15.011) Flutianil, (15.012) Fosetyl-Aluminum, (15.013) Fosetyl calcium, (15.014) fosetyl sodium, (15.015) methyl isothiocyanate, (15.016) metrafenone, (15.017) mildiomycin, (15.018) natamycin, (15.019) nickel dimethyldithiocarbamate, (15.020) nitrothal isopropyl, (15.021) oxamocarb, (15.022) Oxathiapiproline, (15.023) Oxyfenthiine, (15.024) Pentachlorophenol and salts, (15.025) Phosphoric acid and its salts, (15.026) Propamocarb-fosetylate, (15.027) Pyriofenone (Chlazafenone), (15.028) Tebufloquine, (15.029) Tecloftalam , (15,030) Tolnifanide, (15,031) 1- (4- {4 - [(5R) -5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1 , 3-thiazol-2-yl, piperidine-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, (15.032) 1- (4- {4- [. (5S) -5- (2,6-

Difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl. Jipiperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H pyrazol-1-yl] ethanone, (15.033) 2- (6-benzylpyridin-2-yl) quinazoline, (15.034) 2,6-dimethyl-1H, 5H- [1,4] dithiino [2,3-c : 5,6-c '] dipyrrole-l, 3,5,7 (2H, 6H) -tetrone,

(15.035) 2- [3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] -1- [4- (4- {5- [2- (prop-2-yn-1-yloxy) -phenyl ] - 4,5-dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1-yl] ethanone, (15.036) 2- [3.5-

Bis (difluoromethyl) -H-pyrazol-1-yl] -1- [4- (4- {5- [2-chloro-6- (prop-2-yn-1-yloxy) -phenyl] -4,5- dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1-yl] ethanone, (15.037) 2- [3,5-

Bis (difluoromethyl) -H-pyrazol-1-yl] -1- [4- (4- {5- [2-fluoro-6- (prop-2-yn-1-yloxy) -phenyl] -4,5- dihydro-1, 2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1-yl] ethanone, (15.038) 2- [6- (3-fluoro-4-methoxyphenyl) -5 -methylpyridin-2-yl] quinazoline, (15.039) methanesulfonic acid 2- {(5R) -3- [2- (1 - {[3,5-bis (difluoromethyl) -H-pyrazol-1-yl] -yl] -acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5-dihydro-

1, 2-oxazol-5-yl} -3-chlorophenyl ester, (15.040) methanesulfonic acid 2- {(5S) -3- [2- (1 - {[3,5-bis (difluoromethyl) -H-pyrazole] 1-yl] acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl-3-chlorophenyl ester, (15.041) 2- {2- [(7,8-Difluoro-2-methylquinolin-3-yl) oxy] -6-fluorophenyl} propan-2-ol, (15.042) 2- {2-fluoro-6 - [(8-fluoro) 2-methylquinolin-3-yl) oxy] phenyl} propan-2-ol, (15.043) methanesulfonic acid 2- {3- [2- (1-{[3,5-bis (difluoromethyl) -H-pyrazole-1 -yl] acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -3-chlorophenyl ester, (15.044) methanesulfonic acid -2 - {3- [2- (1 - {[3,5-bis (difluoromethyl) -1H-pyrazole] 1-yl] acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5-dihydro-l, 2-oxazol-5-yl} phenyl ester, (15.045)

2-phenylphenol and salts, (15.046) 3- (4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline, (15.047) 3- (4,4-difluoro- 3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline, (15.048)

4-amino-5-fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidin-2 (1H) -one), (15.049) 4-oxo-4 - [(2-phenylethyl) amino] butanoic acid, (15,050) 5-Amino-l, 3,4-thiadiazole-2-thiol, (15,051) 5-Chloro-N'-phenyl-N '- (prop-2-yn-1-yl) thiophene-2-sulfonohydrazide , (15.052) 5-Fluoro-2- [(4-fluorobenzyl) oxy] pyrimidin-4-amine, (15.053) 5-Fluoro-2- [(4-methylbenzyl) oxy] pyrimidin-4-amine, (15.054) 9-Fluoro-2,2-dimethyl-5- (quinolin-3-yl) -2,3-dihydro-1,4-benzoxazepine, (15,055) {6 - [({[(Z) - (1-methyl -lH-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} -carbamic acid but-3-yn-1-yl ester, (15.056) (2Z) -3-amino-2- cyano-3-phenylacrylic acid ethyl ester, (15.057) phenazine-1-carboxylic acid, (15.058) propyl 3,4,5-trihydroxybenzoate, (15,059) quinolin-8-ol, (15,060) quinoline-8-olsulfate (2: 1), ( 15.061) tert-butyl {6 - [({[(1-methyl-1H-tetrazol-5-yl) (phenyl) -methylene] oxy) -methyl] -pyridin-2-yl} -carbamic acid, (15.062)

5-Fluoro-4-imino-3-methyl-1 - [(4-methylphenyl) sulfonyl] -3,4-dihydropyrimidine-2 (1 H) -one.

3. active substance combinations according to claim 1, in which W is methyl,

X is chlorine or methyl,

Y is chlorine, bromine or methyl,

D is hydrogen,

A, B and the carbon atom to which they are attached represent saturated C 9 -cycloalkyl which is substituted with an alkylenedioxyl group which forms a 5-membered or 6-membered ketal with the carbon atom to which it is attached .

G is hydrogen (a) or one of the groups

stands in which

M stands for oxygen,

E is a metal ion equivalent or an ammonium ion,

R ^{1 represents} straight-chain or branched C ¹ -C 4 -alkyl, for straight-chain or branched C _| - ('4-LI ky I.

4. active ingredient combinations according to claim 1, wherein the substituents W, X, Y, A, B, D and G have the meanings given in the table:

5 drug combinations according to claim 1, wherein the compound of formula (I) has the structure:

Active substance combinations according to Claim 1, containing the compound of the formula (1-2)

and Isotianil.

7. Use of a combination of active substances according to any one of claims 1, 2, 3, 4, 5 or 6 for controlling animal pests.

Use of a combination of active substances according to one of claims 1, 2, 3, 4, 5 or 6 for controlling unwanted microorganisms.

9. Use of a combination of active substances according to any one of claims 1, 2, 3, 4, 5 or 6 of transgenic plants. 10. A method for controlling animal pests, characterized in that one allows drug combinations according to any one of claims 1, 2, 3, 4, 5 or 6 to act on animal pests and / or their habitat.

11. A process for controlling undesired microorganisms, which comprises allowing active substance combinations according to claim 1, 2, 3, 4, 5 or 6 to act on undesired microorganisms and / or their habitat.

12 A process for the preparation of insecticidal, fungicidal and / or acaricidal agents, characterized in that active compound combinations as defined in any one of claims 1, 2, 3, 4, 5 or 6, mixed with extenders and / or surface-active substances.