WO2019168361A1 - 불연, 방염, 차열, 단열 및 결로방지 효과를 갖는 기능성 수성 페인트 조성물 - Google Patents
불연, 방염, 차열, 단열 및 결로방지 효과를 갖는 기능성 수성 페인트 조성물 Download PDFInfo
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Definitions
- the present invention relates to a functional water-based paint composition having a non-flammable, flame-retardant, thermal insulation, heat insulation and anti-condensation effect, and a method for producing the same, and more particularly, to an aqueous paint composition and its preparation applicable as a non-combustible material, a heat insulating material and a waterproofing material. It is about a method.
- paints give various colors and luster to the objects to beautify them with beautiful colors, as well as to provide the functions of environmental beautification and environmental protection, in which the subjects maintain their beauty by the coating film. It also gives special functions such as antiseptic, fire prevention and heat resistance.
- paints can be divided into water-based and oil-based paints, and both have unique characteristics and uses.
- the water-based paint finish is applied to the outer wall, but the water-based paint is water resistant to perform the function of waterproofing and should be applied at regular additional cost due to damage or dropping of the coating due to the influence of external air such as rain water, and water-based paint.
- the cost burden was caused by the application of a water repellent, which should be applied every two to three years to provide waterproofness to the top.
- oil paint may be applied, but its use is limited due to the danger of fire, the condition of the ground surface, and the regulation of harmful organic compounds. .
- some oil-based waterproofing agents have a problem in that a rubber film is formed on the surface to cause mold on the wall because of no air permeability.
- water-soluble waterproof paints have been developed, but recently, some water-soluble water-based paints are used in the composition of the composition of the existing exterior finishing materials due to the poor breathability to release moisture in the composition or the adhesive strength during repair work As a result, there has been a problem that occurs after the construction is eliminated.
- heat insulating materials generally used in buildings are exposed to fire risks and take up a lot of space, so paints having heat insulating functionality have been developed, but existing heat insulating paints have poor heat insulating performance in order to obtain a desired heat insulating effect. This has been.
- a paint composition comprising a main raw material and a liquid raw material in a weight ratio of 1: 1, wherein the main raw material is 10-30% by weight of calcium sulfur aluminate (3Ca3Al 2 O 3 CaSo 4 ) having a powder degree of 6,000 to 12,000 cm 2 / g, expansion 20-40% by weight of graphite, 10-40% by weight of 325mesh calcium carbonate (CaCo 3 ), 1-2% by weight of blowing agent, 0.1-1% by weight of fluidizing agent, 0.1-1% by weight of antiseptic, 0.1-1% by weight of antifoaming agent 0.01-0.5% by weight methylcellulose or hydroxymethylcellulose with viscosity 5,000-30,000 cps, 10% by weight anhydrous gypsum, 30% by weight microporous ceramics up to 325mesh, 20% by weight phosphorus-based flame retardant and TiO 2 5% %, wherein the liquid raw material comprises 20-50% by weight of a mixture of one or a mixture of epoxy resin
- the present invention also provides
- a liquid raw material by mixing 20-50% by weight of at least one selected from the group consisting of epoxy resins, EVA resins, and acrylic resins, and 50-80% by weight of water, based on the total weight of the liquid raw material; c) providing a method of preparing a paint composition, comprising mixing the main raw material and the liquid raw material in a weight ratio of 1: 1.
- the functional water paint composition according to the present invention is a paint composition which improves heat insulation and non-combustibility and adds water resistance, and it is possible to reduce cooling and heating costs due to reinforcement of non-flammability, as well as prevention of condensation and waterproof effect by excellent heat insulation and heat shielding effect. Do.
- the paint composition can secure the desired thickness by only one coating, thereby compensating for the drawback of failing to increase the thickness of the conventional paint at once and having an economic advantage.
- 1 to 2 is a certified test report of the Korea Institute of Chemical Fusion Testing showing the heat insulation and heat shielding effect of the paint composition according to the present invention.
- the present invention provides a functional water-based paint composition, and has been researched to have a condensation prevention effect and a waterproof effect with excellent heat insulation and heat shielding effect as well as reinforcement of incombustibility.
- the present invention in one embodiment,
- a paint composition comprising a main raw material and a liquid raw material in a weight ratio of 1: 1, wherein the main raw material is 10-30% by weight of calcium sulfur aluminate (3Ca3Al 2 O 3 CaSo 4 ) having a powder degree of 6,000 to 12,000 cm 2 / g, expansion 20-40% by weight of graphite, 10-40% by weight of 325mesh calcium carbonate (CaCo 3 ), 1-2% by weight of blowing agent, 0.1-1% by weight of fluidizing agent, 0.1-1% by weight of antiseptic, 0.1-1% by weight of antifoaming agent 0.01-0.5% by weight methylcellulose or hydroxymethylcellulose with viscosity 5,000-30,000 cps, 10% by weight anhydrous gypsum, 30% by weight microporous ceramics up to 325mesh, 20% by weight phosphorus-based flame retardant and TiO 2 5% %, wherein the liquid raw material comprises 20-50% by weight of a mixture of one or a mixture of epoxy resin
- the paint composition of the present invention is characterized in that it comprises an inorganic additive having a hydraulic reaction in the inorganic additive, in order to compensate for the disadvantage of not increasing the thickness of the existing paint at once.
- the paint composition of the present invention includes calcium sulfur aluminate or alumina cement as an inorganic binder, and may further include anhydrous gypsum, in order to maintain the hardness, waterproofness, adhesion to the subject, and thickness during application of the paint. It is characterized by.
- the inorganic binder may be made of a hydration reaction with water to increase the hardness of the paint, and to react with water and the resin to improve the waterproofness, to make the hydrate to maintain the thickness.
- the paint composition of the present invention is characterized in that it comprises expanded graphite for thermal insulation, in particular for blocking smoke from fire.
- the expanded graphite can protect the flame from being transmitted to the building or structure by expanding the graphite when the heat reaches 200 °C or more.
- the paint composition of the present invention is characterized by including a blowing agent for improving the foaming performance.
- the paint composition of the present invention is characterized in that it comprises a microporous ceramic fired and foamed at a high temperature in order to provide super insulation.
- the microporous ceramic may be plastic foamed at 1200 to 1400 °C.
- the ceramic When firing at a temperature lower than the temperature in the above range, the ceramic may not be calcined or calcined very slowly, and when firing at a temperature higher than the temperature in the above range, the energy loss is high due to unnecessary temperature, which is not good for the firing apparatus. Problems that affect can occur.
- the paint composition of the present invention is characterized in that it comprises a resin for the effect of increasing the adhesive force with the subject and increasing the waterproofing performance by reacting with the inorganic binder in the invention composition.
- a resin for the effect of increasing the adhesive force with the subject and increasing the waterproofing performance by reacting with the inorganic binder in the invention composition.
- adhesive strength such as steel structures
- it may include a two-component epoxy resin
- a concrete building or an appropriate adhesive strength is required it may include a one-component EVA resin or an acrylic resin.
- the present invention is characterized in that in one embodiment, one kind of the resins are included alone or in a mixture of two or more kinds in the paint composition of the present invention.
- the paint composition of the present invention is characterized in that the resin added to the composition of the present invention contains a flame retardant so as not to be affected by a flame and to enhance incombustibility.
- the paint composition of this invention contains an antifoamer, a fluidizing agent, a preservative, etc. as an additive. It is characterized by the above-mentioned.
- the antifoaming agent is used to suppress the generation of bubbles causing surface defects such as crater phenomenon or weakening the coating film in the dry coating film, and controls the amount of air and reduces bubbles. This makes it possible to ensure the stability of the quality, there is an effect to enhance the strength.
- the antifoaming agent used in the present invention may be, for example, Agitan 295, Agitan P803, Agitan P833, and the like, which are generally known, but are not limited thereto. In addition, various types of antifoaming agents may be used.
- the fluidizing agent is a mixing agent for improving and smoothing the flow characteristics of the paint, and is used for dispersing the paint composition particles, and forms a lubricating film between the particles to reduce the mutual adhesion between the components to reduce the quality of the blended paint composition. Improve fluidity while maintaining In addition, the flatness of the lubricating film to be formed is increased, and the workability for forming the lubricating film is improved.
- the fluidizing agent used in the present invention for example, generally known CMC-PC, Peramin SMF30, Peramin Conpac 149S and the like may be used, but are not limited thereto. In addition, various types of fluidizing agents may be used.
- the preservative is used to increase the shelf life of the product.
- the paint composition of the present invention may further include a general pigment to impart color to the paint, and the pigment may be an organic / inorganic pigment, and may be black and colored pigments.
- Functional aqueous paint composition according to the present invention is a main raw material, 25% by weight of high-powder calcium sulfaluminate (3Ca3Al 2 O 3 CaSo 4 ), 7% by weight of anhydrous gypsum, 1300 °C satisfying the powder degree of 6,000 to 12,000cm 2 / g 20% by weight of the microporous ceramic 325mesh pass-through foamed, 30% by weight expanded graphite, 9% by weight of calcium carbonate (CaCo 3 ) 325mesh passthrough, 1.5% by weight foaming agent, 5% by weight phosphorus flame retardant, 0.2% by weight fluidizing agent It was prepared by mixing 0.1% by weight of preservative, 2 % by weight of TiO 2 , 0.18% by weight of antifoam, and 0.02% by weight of methyl cellulose having a viscosity of 5,000 to 30,000 cps.
- preservative 2 % by weight of TiO 2 , 0.18% by weight of antifo
- the functional aqueous paint composition of the present invention was prepared by mixing the prepared main raw material and the liquid raw material in a weight ratio of 1: 1.
- the functional water-based paint composition according to the present invention has a thermal conductivity of 0.078 W / (mk), it can be confirmed that the excellent thermal insulation effect.
- the functional water-based paint composition according to the present invention can be seen that the solar radiation reflectance is 91.5% excellent heat shielding effect.
- KS F ISO 1182 TEST which is a non-combustibility test method of the experimental building material, was performed.
- the functional aqueous paint composition according to the present invention was determined to be a non-combustible material first class.
- the one-time coating thickness of the functional aqueous paint composition prepared in one embodiment of the present invention and the coating thickness and the thermal insulation effect of the commercially available heat insulating waterproof paint composition were evaluated.
- the paint composition of the present invention secures a thickness of about 10 mm with only one coating
- the paint composition of Company A and the paint composition of Company B have to be coated 17 times and 18 times, respectively, to secure a thickness of 10 mm.
- the paint composition of Company A and the paint composition of Company B have to be coated 17 times and 18 times, respectively, to secure a thickness of 10 mm.
- the thermal conductivity was analyzed according to the test method KS L9016: 2010 (plate heat flow method) in the Korea Institute of Chemical Fusion.
- the functional water-based paint composition according to the present invention can reach the coating thickness that can be reached by the conventional paint composition multiple times with only one coating, it can be seen that it has excellent heat insulation and heat shielding effect. .
Abstract
Description
구분 | 실시예 1 | A사 | B사 |
10mm 두께 도달 도장 횟수 | 1회 | 17회 | 18회 |
열전도율 단위:N/(m.k) | 0.65 | 0.74 | 0.68 |
Claims (3)
- 주원료 및 액체 원료를 1:1의 중량비로 포함하는 페인트 조성물로서,상기 주원료는, 분말도 6,000 내지 12,000 cm2/g의 칼슘설퍼알루미네이트(3Ca3Al2O3CaSo4) 10-30 중량%, 팽창흑연 20-40 중량%, 탄산칼슘(CaCo3) 325mesh 통과분 10-40 중량%, 발포제 1-2 중량%, 유동화제 0.1-1 중량%, 방부제 0.1-1 중량%, 소포제 0.1-1 중량%, 점도 5,000 내지 30,000 cps의 메틸셀룰로오스 또는 히드록시메틸셀룰로스 0.01-0.5 중량%, 무수석고 10 이하 중량%, 325mesh 이하의 미세다공질 세라믹 30 이하 중량%, 인계 난연제 20 이하 중량% 및 TiO2 5이하 중량%를 포함하며,상기 액체 원료는, 에폭시수지, EVA수지 및 아크릴수지 중 1종을 단독으로 또는 2종을 혼합한 혼합물 20-50 중량% 및 물 50-80 중량%를 포함하는, 페인트 조성물.
- 제 1 항에 있어서,상기 미세다공질 세라믹은 1200 내지 1400 ℃ 에서 소성 발포된 것인 페인트 조성물.
- a) 주원료 전체 중량에 대하여, 분말도 6,000 내지 12,000cm2/g의 칼슘설퍼알루미네이트(3Ca3Al2O3CaSo4) 10-30 중량%, 팽창흑연 20-40 중량%. 325mesh 이하의 탄산칼슘(CaCo3) 10-40 중량%, 발포제 1-2 중량%, 유동화제 0.1-1 중량%, 방부제 0.1-1 중량%, 소포제 0.1-1 중량%, 점도 5,000 내지 30,000cps의 메틸셀룰로오스 또는 히드록시메틸셀룰로스 0.01-0.5 중량%, 무수석고 10 이하 중량%, 325mesh 이하의 미세다공질 세라믹 30 이하 중량%, 인계 난연제 20 이하 중량% 및 TiO2 5 이하 중량%를 혼합하여 주원료를 제조하는 단계;b) 액체 원료 전체 중량에 대하여, 에폭시수지, EVA수지 및 아크릴수지로 이루어진 군에서 선택된 1종 이상 20-50 중량%, 및 물 50-80 중량%를 혼합하여 액체 원료를 제조하는 단계;c) 상기 주원료 및 액체 원료를 1:1의 중량비로 혼합하는 단계를 포함하는, 페인트 조성물의 제조방법.
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