WO2019168352A1 - Matériau actif d'anode, son procédé de préparation, et batterie secondaire au lithium et d'anode, qui comprennent un matériau actif d'anode - Google Patents

Matériau actif d'anode, son procédé de préparation, et batterie secondaire au lithium et d'anode, qui comprennent un matériau actif d'anode Download PDF

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Publication number
WO2019168352A1
WO2019168352A1 PCT/KR2019/002385 KR2019002385W WO2019168352A1 WO 2019168352 A1 WO2019168352 A1 WO 2019168352A1 KR 2019002385 W KR2019002385 W KR 2019002385W WO 2019168352 A1 WO2019168352 A1 WO 2019168352A1
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sio
active material
negative electrode
silicon
electrode active
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PCT/KR2019/002385
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English (en)
Korean (ko)
Inventor
이수민
김제영
이용주
신선영
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주식회사 엘지화학
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Priority claimed from KR1020190022738A external-priority patent/KR102264739B1/ko
Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to US16/771,350 priority Critical patent/US11764354B2/en
Priority to EP19761325.0A priority patent/EP3709406A4/fr
Priority to CN201980006246.0A priority patent/CN111466044B/zh
Publication of WO2019168352A1 publication Critical patent/WO2019168352A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the present invention relates to a negative electrode active material, a method for producing the negative electrode active material, a negative electrode including the negative electrode active material, and a lithium secondary battery including the negative electrode.
  • a representative example of an electrochemical device using such electrochemical energy is a secondary battery, and its use area is gradually increasing.
  • secondary batteries many studies have been conducted on high energy density, that is, high capacity lithium secondary batteries, and have been commercialized and widely used.
  • the secondary battery is composed of a positive electrode, a negative electrode, an electrolyte, and a separator.
  • the negative electrode includes a negative electrode active material for inserting and detaching lithium ions emitted from the positive electrode, and silicon-based particles having a large discharge capacity may be used as the negative electrode active material.
  • silicon-based particles such as SiO x (0 ⁇ x ⁇ 2), have low initial efficiency and have a large area causing side reactions with the electrolyte due to volume expansion during charge and discharge. This causes a problem that the life of the battery is reduced.
  • the initial efficiency is improved, the development of a negative electrode that can easily suppress the change in volume during the charging and discharging process to improve the life characteristics.
  • the first technical problem of the present invention has a high capacity by including a silicon-based composite in which the polymer is disposed in the pores of SiO x (0 ⁇ x ⁇ 2) containing the pores, the battery It is to provide a negative electrode active material that can improve the initial efficiency and lifespan characteristics of.
  • the second technical problem of the present invention is to provide a method for producing the negative electrode active material.
  • the third technical problem of the present invention is to provide a negative electrode and a lithium secondary battery including the negative electrode active material.
  • the present invention includes a silicon-based composite and a carbon-based material, the silicon-based composite, SiO x containing pores (0 ⁇ x ⁇ 2); A polymer disposed within the pores; And a metal compound disposed on a surface of or in the surface of SiO x (0 ⁇ x ⁇ 2) or on the surface of SiO x (0 ⁇ x ⁇ 2), the metal compound consisting of Li, Mg, Ca, and Al. It provides a negative electrode active material which is a compound containing at least one element selected from the group.
  • the present invention is mixed with at least one element selected from the group consisting of SiO x (0 ⁇ x ⁇ 2) as Li, Mg, Ca and Al, and the first heat treatment, the SiO x (0 ⁇ x ⁇ 2) Disposing a metal compound on a surface or inside and inside the SiO x (0 ⁇ x ⁇ 2); Immersing the first heat treated SiO x (0 ⁇ x ⁇ 2) in an etching solution to form pores in SiO x (0 ⁇ x ⁇ 2); Mixing the SiO x (0 ⁇ x ⁇ 2) having pores with a polymer and performing a second heat treatment to place the polymer in the pores to form a silicon-based composite; And a step of mixing the silicon-based composite and a carbon-based material.
  • the negative electrode active material according to the present invention may improve the initial efficiency and lifespan characteristics of the battery by including a silicon-based composite and a carbon-based material.
  • the negative electrode active material exhibits a high capacity characteristic, the initial efficiency characteristics of the battery can be improved.
  • the thickness change of the electrode may be insignificant due to the pores. It is possible to prevent side reactions between the silicon-based composite and the electrolyte by the polymer disposed in the pores, thereby improving the lifespan characteristics.
  • FIG. 1 is a schematic diagram showing a silicon-based composite of the present invention.
  • Example 2 is a cross-sectional SEM image of the SiO particles prepared in Example 1.
  • the terms “comprise”, “comprise” or “have” are intended to indicate that there is a feature, number, step, component, or combination thereof, that is, one or more other features, It should be understood that it does not exclude in advance the possibility of the presence or addition of numbers, steps, components, or combinations thereof.
  • the negative electrode active material according to the present invention includes a silicon-based composite and a carbon-based material, wherein the silicon-based composite includes: SiO x (0 ⁇ x ⁇ 2) including pores; A polymer disposed within the pores; And to include a metallic compound placed on the surface and inside of the surface or the SiO x (0 ⁇ x ⁇ 2) of said SiO x (0 ⁇ x ⁇ 2).
  • the anode active material includes a silicon-based composite and a carbon-based material, and the silicon-based composite and the carbon-based material are 1:99 to 50:50, preferably 1:99 to 40:60, preferably 3:97 to 20:80, most preferably 3:97 to 10:90.
  • the negative electrode active material includes a silicon-based composite and a carbon-based material in the above range, the lifespan characteristics of the battery may be improved when it is applied to the battery.
  • the carbonaceous material may include at least one selected from the group consisting of natural graphite, artificial graphite, digraphitizable carbon, nongraphitizable carbon, carbon black, and graphite oxide.
  • the carbon-based material may include graphite, in which case it may improve life characteristics and high temperature storage performance when applied to the battery.
  • Figure 1 is a schematic diagram showing a silicon-based composite according to the present invention.
  • the silicon-based composite may include SiO x (0 ⁇ x ⁇ 2) including pores, a polymer disposed in the pores, and a surface of the SiO x (0 ⁇ x ⁇ 2) or the SiO x (0 Metal compounds disposed on and within the surface of? X? 2).
  • the silicon-based composite may include SiO x (0 ⁇ x ⁇ 2), and in this case, the discharge capacity of the secondary battery may increase.
  • the silicon-based composite material is by including a metallic compound placed on the surface and inside of the surface or the SiO x (0 ⁇ x ⁇ 2) of SiO x (0 ⁇ x ⁇ 2), it is possible to increase the initial efficiency, excellent Lifetime characteristics and swelling characteristics.
  • the metal compound may be included in an amount of 1% by weight to 30% by weight, preferably 3% by weight to 20% by weight, more preferably 5% by weight to 10% by weight, based on the total weight of the silicone-based composite. have.
  • the metal compound includes a metal silicate
  • the metal silicate is Li 2 Si 2 O 5 , Li 2 SiO 3 , Li 4 SiO 4 , Mg 2 SiO 4 , CaSiO 3 , 3Al 2 O 3 ⁇ 2SiO 2 and It may include at least one selected from the group consisting of MgSiO 3 .
  • the initial efficiency of the battery may be improved.
  • the SiO x (0 ⁇ x ⁇ 2) may be one having pores having a size of 50 nm to 1,000 nm, preferably having a plurality of pores having a size of 70 nm to 500 nm, more preferably 100 nm to 300 nm. It may be.
  • the pore size of the SiO x (0 ⁇ x ⁇ 2) satisfies the above range, even when the volume of the silicon-based composite expands during charging and discharging of the battery, the pore may perform a buffering function. Accordingly, the thickness deformation of the electrode due to the volume expansion of SiO x (0 ⁇ x ⁇ 2) can be suppressed.
  • the pore size may be measured by a calculation formula according to the Barrett-Joyer-Halenda (BJH) method or a cross-sectional SEM photographing through N 2 sorption.
  • BJH Barrett-Joyer-Halenda
  • the polymer may include at least one or more of polyacrylate and polyacrylic acid, more preferably polyacrylate and polya It may include all of the chloric acid.
  • SiO x (0 ⁇ x ⁇ 2) are included as the pore increasing the BET specific surface area of the silicon-based composite material the reaction area of the electrolyte increases by Even if the polymer acts as a barrier layer for suppressing side reactions with the electrolyte solution, the side reactions with the electrolyte solution can be suppressed and the lifespan characteristics can be improved.
  • the silicon-based composite may further include a carbon coating layer disposed on the silicon-based composite.
  • the carbon coating layer may be formed to a thickness of 100 nm to 1000 nm, preferably 200 nm to 400 nm on the surface of the silicon-based composite. Since the silicon-based composite further includes a carbon coating layer, electrical contact between the particles of SiO x (0 ⁇ x ⁇ 2) may be improved, and excellent electrical conductivity may be given even after the electrode is expanded as charging and discharging proceeds. The performance of the secondary battery can be further improved.
  • the carbon coating layer may also be disposed in the inner pores of the SiO x may be disposed on a surface of (0 ⁇ x ⁇ 2), or the SiO x (0 ⁇ x ⁇ 2).
  • the BET specific surface area of the silicon-based composite may be 0.5m 2 / g to 2.5m 2 / g, preferably 0.8m 2 / g to 2.0m 2 / g.
  • the silicone-based composite according to the present invention may have a BET specific surface area in the above range by disposing a polymer in the pores as described above, in which case, pores capable of performing a buffering action at the time of volume expansion are sufficiently formed, and thus lifespan characteristics. This can be improved.
  • the specific surface area of the silicone-based composite in the present invention can be measured by the Brunauer-Emmett-Teller (BET) method. For example, it can be measured by BET 6-point method by nitrogen gas adsorption distribution method using a porosimetry analyzer (Bell Japan Inc, Belsorp-II mini).
  • the silicon-based composite may be one having an average particle diameter (D 50 ) of 1 ⁇ m to 20 ⁇ m, preferably may have an average particle diameter (D 50 ) of 5 ⁇ m to 10 ⁇ m.
  • the average particle diameter (D 50 ) may be defined as a particle size corresponding to 50% of the cumulative volume in the particle size distribution curve of the particles.
  • the average particle diameter D 50 may be measured using, for example, a laser diffraction method. In general, the laser diffraction method can measure the particle diameter of several mm from the submicron region, and high reproducibility and high resolution can be obtained.
  • the negative electrode active material according to the present invention SiO x (0 ⁇ x ⁇ 2) is mixed with at least one or more elements selected from the group consisting of Li, Mg, Ca and Al and the first heat treatment to the SiO x (0 ⁇ disposing a metal compound on the surface of or within the surface of x ⁇ 2) or on the surface of SiO x (0 ⁇ x ⁇ 2); Immersing the first heat treated SiO x (0 ⁇ x ⁇ 2) in an etching solution to form pores in SiO x (0 ⁇ x ⁇ 2); Mixing the SiO x (0 ⁇ x ⁇ 2) having pores with a polymer and performing a second heat treatment to place the polymer in the pores to form a silicon-based composite; And mixing the silicon-based composite and the carbon-based material to prepare a negative electrode active material.
  • SiO x (0 ⁇ x ⁇ 2) is mixed with at least one element selected from the group consisting of Li, Mg, Ca and Al and is 1 to 5 hours at 400 ° C. to 1,200 ° C., preferably 600 ° C. to 1,000 ° C.
  • the first heat treatment is carried out for 2 to 3 hours.
  • a metal compound may be formed on and / or inside the silicon-based particles.
  • the metal compound may preferably comprise a metal silicate, more preferably Li 2 Si 2 O 5 , Li 2 SiO 3 , Li 4 SiO 4 , Mg 2 SiO 4 , CaSiO 3 , 3Al 2 O 3 ⁇ 2SiO At least one selected from the group consisting of 2 and MgSiO 3 .
  • the first heat-treated SiO x (0 ⁇ x ⁇ 2) is immersed in the etching solution to form pores in the SiO x (0 ⁇ x ⁇ 2).
  • the etching solution may be at least one of sodium hydroxide (NaOH) and potassium hydroxide (KOH).
  • the degree of pore formation in the SiO x (0 ⁇ x ⁇ 2) by the etching solution may be controlled by controlling the etching time and the concentration of the etching solution.
  • silicon-based particles are immersed in an etching solution of 0.5M to 5M, preferably 1M to 2M. After that, it may be performed for 1 hour to 5 hours, preferably 2 to 3 hours.
  • an etching solution of 0.5M to 5M preferably 1M to 2M.
  • the concentration of the etching solution is less than 0.5 M or the etching time is less than 1 hour, pores may not be sufficiently formed, when the concentration of the etching solution is more than 5M or the etching time is more than 5 hours, The pore size is formed to be 1,000 nm or more, thereby increasing the BET specific surface area, which may increase the side reaction with the electrolyte.
  • the first heat treatment before and after the first heat treatment, or after the formation of the pores in the SiO x (0 ⁇ x ⁇ 2), the SiO x (0 ⁇ x ⁇ It may further comprise forming a carbon coating layer on 2).
  • the formation of the carbon coating layer on the surface of the SiO x (0 ⁇ x ⁇ 2) may be a SiO x (0 ⁇ x ⁇ 2) is carried out by heat treatment after mixing with a carbon precursor.
  • the carbon precursor can be used without particular limitation as long as it generates carbon by heat treatment, and is preferably a gas, amorphous or low crystalline carbon containing carbon.
  • Sugars such as glucose, fructose, galactose, maltose, lactose, or sucrose
  • Resins such as phenolic resin, naphthalene resin, polyvinyl alcohol resin, urethane resin, polyimide resin, furan resin, cellulose resin, epoxy resin, polystyrene resin, resorcinol resin or phloroglucinol resin
  • it may include at least one selected from the group consisting of coal-based pitch, petroleum-based pitch, tar (tar) or low molecular weight heavy oil.
  • the carbon coating layer may be, for example, a method of carbonizing using the amorphous carbon precursor.
  • the coating method can be used for both dry or wet mixing.
  • a deposition method such as a chemical vapor deposition (CVD) method using a gas containing carbon such as methane, ethane, propane, ethylene, acetylene, or the like may also be formed.
  • CVD chemical vapor deposition
  • the heat treatment temperature for forming the carbon coating layer on the SiO x (0 ⁇ x ⁇ 2) is 700 °C to 1,500 °C, preferably 800 °C to 1,200 °C, and the heat treatment time may be about 1 hour to 5 hours, preferably 2 hours to 3 hours.
  • the heat treatment is performed for the above time in the temperature range, it is possible to easily form a carbon coating layer having an appropriate crystal structure on the surface of the negative electrode active material.
  • the heat treatment is preferably performed in an inert atmosphere in which nitrogen gas, argon gas, helium gas, krypton gas, or xenon gas is present.
  • the SiO x (0 ⁇ x ⁇ 2) having the pores is mixed with a polymer and subjected to a second heat treatment to place the polymer in the pores to form a silicon-based composite.
  • the polymer may include at least one or more of polyacrylate and polyacrylic acid, and may preferably include both polyacrylate and polyacrylic acid.
  • the second heat treatment may be performed at 200 ° C. to 500 ° C. for 1 hour to 5 hours, more preferably at 300 ° C. to 400 ° C. for 2 hours to 3 hours.
  • the placement of the polymer in the pores can be facilitated without fear of cracking due to uncured and / or overcured polymer.
  • the second heat treatment is performed at a temperature exceeding 500 ° C., the polymer is thermally decomposed so that the residual of the polymer in the pores of the SiO x is not easy, thereby increasing the BET specific surface area of the silicon-based composite.
  • the lifespan characteristics may be inferior as the reaction area with the electrolyte increases.
  • the polymer may be formed not only in the pores but also on the surface of the SiO x (0 ⁇ x ⁇ 2). If the polymer is to be further formed on a surface of the SiO x (0 ⁇ x ⁇ 2), because they prevent the side reaction between the SiO x (0 ⁇ x ⁇ 2) and electrolyte effect of improving the life characteristics, and also volume expansion Due to the ductility of the polymer, damage of the silicon-based composite particles may also be prevented.
  • the silicon-based composite and the carbon-based material may be used without limitation as long as it is a method capable of uniformly mixing the silicon-based composite and the carbon-based material.
  • the silicon-based composite and the carbon-based material may be mixed by dry mixing. It may be mixing.
  • the negative electrode is formed on the negative electrode current collector and the negative electrode current collector, and includes a negative electrode active material layer containing a negative electrode active material according to the present invention.
  • the negative electrode current collector is not particularly limited as long as it has high conductivity without causing chemical change in the battery.
  • the negative electrode current collector may be formed on a surface of copper, stainless steel, aluminum, nickel, titanium, calcined carbon, copper, or stainless steel. Surface-treated with carbon, nickel, titanium, silver, and the like, aluminum-cadmium alloy and the like can be used.
  • the negative electrode current collector may have a thickness of 3 ⁇ m to 500 ⁇ m, and similarly to the positive electrode current collector, fine concavities and convexities may be formed on the surface of the current collector to enhance the bonding force of the negative electrode active material.
  • it can be used in various forms, such as a film, a sheet, a foil, a net, a porous body, a foam, a nonwoven body.
  • the negative electrode active material layer may further include a conductive material, a binder, and a dispersant, as necessary, together with the negative electrode active material.
  • the negative electrode active material may be included in an amount of 80 to 100% by weight, more specifically 85 to 99% by weight based on the total weight of the negative electrode active material layer.
  • the conductive material is a component for further improving the conductivity of the negative electrode active material, and may be added in an amount of 10 wt% or less, preferably 5 wt% or less, based on the total weight of the negative electrode active material layer.
  • a conductive material is not particularly limited as long as it has conductivity without causing chemical change in the battery, and examples thereof include graphite such as natural graphite and artificial graphite; Carbon blacks such as acetylene black, Ketjen black, channel black, furnace black, lamp black and thermal black; Conductive fibers such as carbon fibers and metal fibers; Metal powders such as carbon fluoride powder, aluminum powder and nickel powder; Conductive whiskeys such as zinc oxide and potassium titanate; Conductive metal oxides such as titanium oxide; Conductive materials such as polyphenylene derivatives and the like can be used.
  • the binder is a component that assists the bonding between the conductive material, the active material and the current collector, and is typically added in an amount of 0.1 wt% to 10 wt% based on the total weight of the negative electrode active material layer.
  • binders include polyvinylidene fluoride (PVDF), polyvinyl alcohol, carboxymethyl cellulose (CMC), starch, hydroxypropyl cellulose, regenerated cellulose, polyvinylpyrrolidone, tetrafluoroethylene, polyethylene, poly Propylene, ethylene-propylene-diene polymer (EPDM), sulfonated-EPDM, styrene-butadiene rubber, nitrile-butadiene rubber, fluorine rubber, various copolymers thereof, and the like.
  • PVDF polyvinylidene fluoride
  • CMC carboxymethyl cellulose
  • EPDM ethylene-propylene-diene polymer
  • sulfonated-EPDM s
  • the thickener may appropriately control the viscosity of the composition forming the negative electrode active material layer, and may include a cellulose compound.
  • the cellulose-based compound the cellulose-based compound is carboxymethyl cellulose, hydroxymethyl cellulose, alcohol solubilized butylate of cellulose, cellulose acetate, cellulose acetate butylate, cellulose butyrate, cyanoethyl cellulose, methyl cellulose , Ethyl cellulose, hydroxy ethyl cellulose, ethyl hydroxy ethyl cellulose, nitrocellulose, carboxymethyl cellulose sodium, carboxymethyl cellulose ammonium, hydroxy ethyl cellulose, hydroxypropyl cellulose, and hydroxypropyl methyl cellulose It may include at least one.
  • the thickener may be included in 1 to 10% by weight based on the total weight of the negative electrode active material.
  • the negative electrode may be manufactured according to a conventional negative electrode manufacturing method, except for using the negative electrode active material according to the present invention.
  • it can manufacture by apply
  • the solvent may be a solvent generally used in the art, dimethyl sulfoxide (DMSO), isopropyl alcohol (isopropyl alcohol), N-methylpyrrolidone (NMP), dimethylformamide (dimethyl formamide, DMF), acetone (acetone) or water, and the like, one of these may be used alone or a mixture of two or more thereof.
  • the amount of the solvent is used to dissolve or disperse the positive electrode active material powder, the conductive material, the binder, and the dispersant in consideration of the coating thickness and the production yield of the slurry, and to have a viscosity that can exhibit excellent thickness uniformity during application for the positive electrode production. Is enough.
  • the negative electrode may be manufactured by casting the composition for forming the negative electrode active material layer on a separate support, and then laminating the film obtained by peeling from the support onto the negative electrode current collector.
  • the present invention can manufacture an electrochemical device comprising the cathode.
  • the electrochemical device may be specifically a battery, a capacitor, or the like, and more specifically, a lithium secondary battery.
  • the lithium secondary battery may specifically include a negative electrode, a positive electrode positioned to face the negative electrode, and a separator and an electrolyte interposed between the negative electrode and the positive electrode. Since the cathode is the same as described above, a detailed description thereof will be omitted, and only the remaining components will be described in detail below.
  • the lithium secondary battery may further include a battery container for accommodating the electrode assembly of the negative electrode, the positive electrode, and the separator, and a sealing member for sealing the battery container.
  • the positive electrode includes a positive electrode current collector and a positive electrode active material layer positioned on the positive electrode current collector.
  • the positive electrode current collector is not particularly limited as long as it has conductivity without causing chemical change in the battery.
  • carbon, nickel, titanium on the surface of stainless steel, aluminum, nickel, titanium, calcined carbon, or aluminum or stainless steel Surface treated with silver, silver or the like can be used.
  • the positive electrode current collector may have a thickness of about 3 to 500 ⁇ m, and may form fine irregularities on the surface of the current collector to increase the adhesion of the positive electrode active material.
  • it can be used in various forms, such as a film, a sheet, a foil, a net, a porous body, a foam, a nonwoven body.
  • the cathode active material layer may further include a binder and a conductive material together with the cathode active material.
  • the cathode active material may be applied without particular limitation as long as it is commonly used as a cathode active material.
  • the cathode active material may be substituted with a layered compound such as lithium cobalt oxide (LiCoO 2 ), lithium nickel oxide (LiNiO 2 ), or one or more transition metals.
  • LiMnO 3 the lithium manganese oxide such as LiMn 2 O 3, LiMnO 2; Lithium copper oxide (Li 2 CuO 2 ); Vanadium oxides such as LiV 3 O 8 , LiFe 3 O 4 , V 2 O 5 , Cu 2 V 2 O 7 and the like; Ni represented by the formula LiNi 1-y2 M y2 O 2 , wherein M is at least one selected from the group consisting of Co, Mn, Al, Cu, Fe, Mg, B, and Ga, wherein 0.01 ⁇ y2 ⁇ 0.3 Site-type lithium nickel oxide; Formula LiMn 2 - y3 M y3 O 2 ( where, M is Co, Ni, Fe, Cr, and at least one or more selected from the group consisting of Zn and Ta, 0.01 ⁇ y3 ⁇ 0.1 Im) or Li 2 Mn 3 MO 8 ( Here, M is at least one or more selected from the group consist
  • the conductive material included in the positive electrode active material layer is used to impart conductivity to the electrode.
  • the conductive material may be used without particular limitation as long as it has electronic conductivity without causing chemical change. Specific examples thereof include graphite such as natural graphite and artificial graphite; Carbon-based materials such as carbon black, acetylene black, ketjen black, channel black, furnace black, lamp black, summer black and carbon fiber; Metal powder or metal fibers such as copper, nickel, aluminum, and silver; Conductive whiskeys such as zinc oxide and potassium titanate; Conductive metal oxides such as titanium oxide; Or conductive polymers such as polyphenylene derivatives, and the like, or a mixture of two or more kinds thereof may be used.
  • the binder included in the cathode active material layer serves to improve adhesion between the cathode active material particles and adhesion between the cathode active material and the cathode current collector.
  • specific examples include polyvinylidene fluoride (PVDF), vinylidene fluoride-hexafluoropropylene copolymer (PVDF-co-HFP), polyvinyl alcohol, polyacrylonitrile, carboxymethyl cellulose (CMC), Starch, hydroxypropylcellulose, regenerated cellulose, polyvinylpyrrolidone, tetrafluoroethylene, polyethylene, polypropylene, ethylene-propylene-diene polymer (EPDM), sulfonated-EPDM, styrene butadiene rubber (SBR), fluororubber Or various copolymers thereof, and the like may be used alone or in a mixture of two or more thereof.
  • PVDF polyvinylidene fluoride
  • the positive electrode active material layer is, for example, coated with a positive electrode active material, and optionally a composition for forming a positive electrode active material layer prepared by dissolving or dispersing a binder and a conductive material in a solvent and drying, or for forming the positive electrode active material layer
  • the composition may be produced by casting the composition on a separate support, and then laminating the film obtained by peeling from the support onto a positive electrode current collector.
  • the separator is to separate the negative electrode and the positive electrode and to provide a passage for the movement of lithium ions, if it is usually used as a separator in a lithium secondary battery can be used without particular limitation, in particular in the ion transfer of the electrolyte It is desirable to have a low resistance against the electrolyte and excellent electrolytic solution-moisture capability.
  • a porous polymer film for example, a porous polymer film made of a polyolefin-based polymer such as ethylene homopolymer, propylene homopolymer, ethylene / butene copolymer, ethylene / hexene copolymer and ethylene / methacrylate copolymer or the like Laminate structures of two or more layers may be used.
  • a porous nonwoven fabrics such as nonwoven fabrics made of high melting point glass fibers, polyethylene terephthalate fibers and the like may be used.
  • a coated separator including a ceramic component or a polymer material may be used to secure heat resistance or mechanical strength, and may be optionally used as a single layer or a multilayer structure.
  • examples of the electrolyte used in the present invention include an organic liquid electrolyte, an inorganic liquid electrolyte, a solid polymer electrolyte, a gel polymer electrolyte, a solid inorganic electrolyte, a molten inorganic electrolyte, and the like, which can be used in manufacturing a lithium secondary battery. It doesn't happen.
  • the electrolyte may include an organic solvent and a lithium salt.
  • the organic solvent may be used without particular limitation as long as it can serve as a medium through which ions involved in the electrochemical reaction of the battery can move.
  • the organic solvent may be an ester solvent such as methyl acetate, ethyl acetate, ⁇ -butyrolactone or ⁇ -caprolactone; Ether solvents such as dibutyl ether or tetrahydrofuran; Ketone solvents such as cyclohexanone; Aromatic hydrocarbon solvents such as benzene and fluorobenzene; Dimethylcarbonate (DMC), diethylcarbonate (DEC), methylethylcarbonate (MEC), ethylmethylcarbonate (EMC), ethylene carbonate (EC), propylene carbonate, Carbonate solvents such as PC); Alcohol solvents such as ethyl alcohol and isopropyl alcohol; Nitriles, such as R-CN (R is a C2-C20 linear, branched or cyclic hydrocarbon group, which may include a
  • carbonate-based solvents are preferable, and cyclic carbonates having high ionic conductivity and high dielectric constant (for example, ethylene carbonate or propylene carbonate) that can improve the charge and discharge performance of a battery, and low viscosity linear carbonate compounds (for example, a mixture of ethyl methyl carbonate, dimethyl carbonate or diethyl carbonate and the like is more preferable.
  • the cyclic carbonate and the chain carbonate may be mixed and used in a volume ratio of about 1: 1 to about 1: 9, so that the performance of the electrolyte may be excellent.
  • the lithium salt may be used without particular limitation as long as it is a compound capable of providing lithium ions used in a lithium secondary battery.
  • the lithium salt is LiPF 6 , LiClO 4 , LiAsF 6 , LiBF 4 , LiSbF 6 , LiAl0 4 , LiAlCl 4 , LiCF 3 SO 3 , LiC 4 F 9 SO 3 , LiN (C 2 F 5 SO 3 ) 2 , LiN (C 2 F 5 SO 2 ) 2 , LiN (CF 3 SO 2 ) 2 .
  • LiCl, LiI, or LiB (C 2 O 4 ) 2 and the like can be used.
  • the concentration of the lithium salt is preferably used within the range of 0.1 to 2.0M. When the concentration of the lithium salt is included in the above range, since the electrolyte has an appropriate conductivity and viscosity, it can exhibit excellent electrolyte performance, and lithium ions can move effectively.
  • the electrolyte includes, for example, haloalkylene carbonate-based compounds such as difluoro ethylene carbonate, pyridine, tri, etc. for the purpose of improving battery life characteristics, reducing battery capacity, and improving discharge capacity of the battery.
  • haloalkylene carbonate-based compounds such as difluoro ethylene carbonate, pyridine, tri, etc.
  • Ethyl phosphite triethanolamine, cyclic ether, ethylene diamine, n-glyme, hexaphosphate triamide, nitrobenzene derivative, sulfur, quinone imine dye, N-substituted oxazolidinone, N, N-substituted imida
  • One or more additives such as zolidine, ethylene glycol dialkyl ether, ammonium salt, pyrrole, 2-methoxy ethanol or aluminum trichloride may be included. In this case, the additive may be included in 0.1 to 5% by weight based on the total weight of the electrolyte.
  • the lithium secondary battery including the secondary battery negative electrode according to the present invention exhibits excellent life characteristics due to a decrease in thickness expansion of the electrode even when the charge / discharge cycle proceeds, and thus is a portable device such as a mobile phone, a notebook computer, or a digital camera.
  • electric vehicle fields such as hybrid electric vehicles (HEVs).
  • a battery module including the lithium secondary battery as a unit cell and a battery pack including the same are provided.
  • the battery module or the battery pack is a power tool (Power Tool); Electric vehicles including electric vehicles (EVs), hybrid electric vehicles, and plug-in hybrid electric vehicles (PHEVs); Or it can be used as a power source for any one or more of the system for power storage.
  • Power Tool Electric vehicles including electric vehicles (EVs), hybrid electric vehicles, and plug-in hybrid electric vehicles (PHEVs); Or it can be used as a power source for any one or more of the system for power storage.
  • the external shape of the lithium secondary battery of the present invention is not particularly limited, but may be cylindrical, square, pouch type, or coin type using a can.
  • the lithium secondary battery according to the present invention may not only be used in a battery cell used as a power source for a small device, but also preferably used as a unit battery in a medium-large battery module including a plurality of battery cells.
  • SiO particles having an average particle diameter (D 50 ) of 6 ⁇ m were mixed with Mg powder at a ratio of 10: 1, and heat-treated at 950 ° C. for 2 hours to obtain SiO particles including a metal compound represented by MgSiO 3 and Mg 2 SiO 4 .
  • the metal compound was included in 8% by weight based on the total weight of the SiO particles.
  • SiO particles including MgSiO 3 and Mg 2 SiO 4 were immersed in a 1 molar NaOH solution for 3 hours to form pores in the SiO particles including MgSiO 3 and Mg 2 SiO 4 .
  • the particles are cut using a focused ion beam (FIB), and the scanning electron microscope is used to cut the particles. Pores were formed, and cross-sectional images of SiO particles including MgSiO 3 and Mg 2 SiO 4 were taken, and as shown in FIG. 2, it was confirmed that they had an average pore size of 300 nm.
  • FIB focused ion beam
  • a mixed material obtained by mixing polyacrylate and polyacrylic acid in a ratio of 1: 1 is prepared. Subsequently, the mixed material and N-methylpyrrolidone (NMP) solvent were mixed at a ratio of 1: 9 to prepare a solution in which the mixture was dissolved. For the entire NMP solution in which the mixed material was dissolved, the pores prepared above were formed, and SiO particles including MgSiO 3 and Mg 2 SiO 4 were added in a ratio of 85:15 (v / v%) at 300 ° C.
  • NMP N-methylpyrrolidone
  • CMC carboxymethyl cellulose
  • the negative electrode slurry was applied to a copper metal thin film having a thickness of 20 ⁇ m and dried. At this time, the temperature of the air circulated was 60 °C. Subsequently, a roll press was performed, dried in a vacuum oven at 130 ° C. for 12 hours, and punched into a circle of 1.4875 cm 2 to prepare a negative electrode.
  • Pores having an average pore size of 300 nm prepared in Example 1 were formed, by mixing SiO particles including MgSiO 3 and Mg 2 SiO 4 at a pitch of 85:15 and heat treatment at 950 ° C. for 2 hours. The pores were formed, and a carbon coating layer was formed on the surface of the SiO particles including MgSiO 3 and Mg 2 SiO 4 . Subsequently, in the same manner as in Example 1, the above prepared pores are formed, and a mixture of polyacrylate and polyacrylic acid is included in the pores of SiO particles including MgSiO 3 and Mg 2 SiO 4 and the carbon coating layer is formed on the surface thereof.
  • a silicon-based composite was prepared, except for using the same, a negative electrode active material and a negative electrode were prepared in the same manner as in Example 1.
  • the pores prepared in Example 1 are formed, and the pores are formed by mixing SiO particles including MgSiO 3 and Mg 2 SiO 4 with polyacrylate and heat-treating at 300 ° C. for 2 hours, and MgSiO 3 and Mg 2 SiO A silicone-based composite in which polyacrylate was disposed in pores of SiO particles including 4 was prepared. Except for using this, a negative electrode was prepared in the same manner as in Example 1.
  • Example 1 The pores prepared in Example 1 were formed, and the SiO 2 particles including MgSiO 3 and Mg 2 SiO 4 were mixed at a ratio of 85:15 with pitch and heat-treated at 950 ° C. for 2 hours to form a carbon coating layer on the surface of the SiO particles. Formed. Subsequently, in the same manner as in Example 3, pores prepared above were formed, and silicon-based composites including MgSiO 3 and Mg 2 SiO 4 , and polyacrylates disposed in pores of SiO particles having a carbon coating layer formed thereon. A negative electrode active material and a negative electrode were prepared in the same manner as in Example 3 except for using the same.
  • Example 1 The pores prepared in Example 1 were formed, and SiO particles including MgSiO 3 and Mg 2 SiO 4 were mixed with polyacrylate and heat treated at 600 ° C. for 2 hours to prepare a silicone-based composite. Except for using this, a negative electrode was prepared in the same manner as in Example 1.
  • a negative electrode was manufactured in the same manner as in Example 1 except that a mixture of SiO particles and graphite in a ratio of 1: 9 was used as the negative electrode active material.
  • SiO particles containing a metal compound represented by MgSiO 3 and Mg 2 SiO 4 were prepared by mixing SiO having an average particle diameter (D 50 ) of 6 ⁇ m with Mg powder at a ratio of 10: 1 and heat treatment at 950 ° C. for 2 hours. Prepared. In this case, the metal compound was included in 8% by weight based on the total weight of the SiO particles.
  • a negative electrode was manufactured in the same manner as in Example 1, except that a mixture of SiO particles including MgSiO 3 and Mg 2 SiO 4 and graphite in a ratio of 1: 9 was used as the negative electrode active material.
  • a negative electrode was manufactured in the same manner as in Example 1 except that a mixture of SiO particles and graphite having a carbon coating layer in a ratio of 1: 9 was used as the negative electrode active material.
  • a negative electrode was manufactured in the same manner as in Example 1, except that a mixture of SiO particles and graphite having a polymer coating layer in a ratio of 1: 9 was used as the negative electrode active material.
  • SiO particles were immersed in a 1 mole percent NaOH solution for 3 hours to produce SiO particles having an average pore size of 300 nm.
  • a negative electrode was manufactured in the same manner as in Example 1, except that a mixture of SiO particles having porosity and graphite in a ratio of 1: 9 was used as the negative electrode active material.
  • the pore size of the SiO particles can be measured by cross-sectional analysis of the particles using a focused ion beam (FIB). Specifically, when manufacturing the silicon-based composite particles in Examples 1 to 5 and Comparative Example 5, SiO particles were etched to extract SiO particles having pores. This was cut using a focused ion beam, the cross-sectional image was acquired by SEM, and the pore size of the SiO particles was measured using the same, which is shown in Table 1 below.
  • FIB focused ion beam
  • the silicon-based composite was introduced into a laser diffraction particle size measuring device (e.g., Microtrac MT 3000) and irradiated with an ultrasonic wave of about 28 kHz at an output of 60 W, and then the average particle diameter at 50% of the particle size distribution in the measuring device (D 50 ) was calculated and shown in Table 1 below.
  • a laser diffraction particle size measuring device e.g., Microtrac MT 3000
  • the specific surface area of the silicone-based composite was measured by the BET method. Specifically, the specific surface area of the silicone-based composite was calculated from the nitrogen gas adsorption amount under liquid nitrogen temperature (77 K) using BELSORP-mini II manufactured by BEL Japan, and is shown in Table 1 below.
  • Example 1 300 One 6
  • Example 2 300 0.8 6
  • Example 3 300 0.9 6
  • Example 4 300 0.8 6
  • Example 5 300 3 6 Comparative Example 1 - 4 6 Comparative Example 2 - 5 6 Comparative Example 3 - 3 6 Comparative Example 4 - One 6 Comparative Example 5 300 7 6
  • the SiO particles prepared in Examples 1 to 4 contain pores having an average size of 300 nm, and the BET specific surface area is 0.8 m 2 / g to by disposing the polymer in the pores of the SiO particles. It was confirmed that 1 m 2 / g was shown. However, since the SiO 2 particles prepared in Example 5 had a relatively high second heat treatment temperature, and the polymer was not thermally decomposed to easily remain in the pores of the SiO particles, the BET specific surface area of the SiO particles was determined in Examples 1 to 4 above. It was confirmed that the higher.
  • a half cell was manufactured using the negative electrodes prepared in Examples 1 to 5 and Comparative Examples 1 to 5, respectively, and the initial efficiency of the battery was measured using the negative cells.
  • the half cell may be manufactured by using a cathode prepared in Examples 1 to 5 and Comparative Examples 1 to 5, and a lithium metal thin film cut in a circular shape of 1.7671 cm 2 as an anode, and having a porosity between the anode and the cathode.
  • a polyethylene separation membrane 0.5% by weight of vinylene carbonate was dissolved in a mixed solution of ethyl methyl carbonate (EMC) and ethylene carbonate in a mixed volume ratio of 7: 3, and an electrolyte solution containing LiPF 6 at a concentration of 1M was injected thereinto, Coin-type half cells were prepared.
  • EMC ethyl methyl carbonate
  • the coin-type half cell prepared above was charged with 0.05C cut off to 4.25V at 0.5C constant current. Thereafter, discharge was performed until the voltage reaches 2.5V at a constant current of 0.5C, and the initial efficiency (%) was derived through the results of one time charge and discharge.
  • the initial efficiency (%) was derived by the following calculation.
  • the full cell may be prepared by laminating the negative electrode prepared in Examples 1 to 5 and Comparative Examples 1 to 5, and the positive electrode prepared below, together with a polyethylene separator, to prepare an electrode assembly, and then, to the battery case. And an electrolyte solution in which 1 M LiPF 6 was dissolved in an organic solvent in which ethylene carbonate (EC): ethyl methyl carbonate (EMC) was mixed at a ratio of 3: 7 was injected to prepare a lithium secondary battery.
  • EC ethylene carbonate
  • EMC ethyl methyl carbonate
  • the positive electrode is a positive electrode active material particles of lithium cobalt oxide (LiCoO 2 ) , carbon black conductive material, and polyvinylidene fluoride (PVDF) binder in a weight ratio of 90: 5: 5 solvent N-methyl-2-pi
  • a cathode active material slurry was prepared by adding 100: 40 weight ratio to rollidone (NMP).
  • NMP rollidone
  • the positive electrode active material slurry was applied to an aluminum thin film having a thickness of 100 ⁇ m, and dried, followed by roll press.
  • the secondary battery including the negative electrodes prepared in Examples 1 to 5 is superior to the secondary batteries prepared in Comparative Examples 1 to 5 in both initial efficiency and capacity retention after 100 cycles.
  • the secondary battery including the negative electrode of Comparative Example 4 is not easy to suppress the volume expansion of the SiO particles due to charge and discharge by coating the polymer on the surface of the SiO particles, Damage such as cracking occurred, and it was confirmed that both initial efficiency and capacity retention ratio were inferior to those of Examples 1 to 5.
  • the BET specific surface area of the negative electrode active material was increased to increase the reaction area with the electrolyte, and thus the capacity retention rate was lowered as compared with Examples 1 to 5. .

Abstract

La présente invention concerne un matériau actif d'anode, son procédé de préparation, une anode comprenant le matériau actif d'anode, et une batterie secondaire au lithium, le matériau actif d'anode comprenant un composite à base de silicium et un matériau à base de carbone, le composite à base de silicium comprenant : SiOx (0 ≤ x ≤ 2) comprenant des pores ; un polymère disposé dans les pores ; et un composé métallique disposé sur la surface de SiOx (0 ≤ x ≤ 2) ou sur la surface de SiOx (0 ≤ x ≤ 2), et disposé à l'intérieur, le composé métallique étant un composé comprenant au moins un élément choisi dans le groupe constitué par Li, Mg, Ca, et Al.
PCT/KR2019/002385 2018-03-02 2019-02-27 Matériau actif d'anode, son procédé de préparation, et batterie secondaire au lithium et d'anode, qui comprennent un matériau actif d'anode WO2019168352A1 (fr)

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US16/771,350 US11764354B2 (en) 2018-03-02 2019-02-27 Negative electrode active material, method of preparing the same, and negative electrode and lithium secondary battery which include the negative electrode active material
EP19761325.0A EP3709406A4 (fr) 2018-03-02 2019-02-27 Matériau actif d'anode, son procédé de préparation, et batterie secondaire au lithium et d'anode, qui comprennent un matériau actif d'anode
CN201980006246.0A CN111466044B (zh) 2018-03-02 2019-02-27 负极活性材料、其制备方法以及包含该负极活性材料的负极和锂二次电池

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