WO2019144415A1 - 一种耐腐蚀的改性纳米复合材料 - Google Patents

一种耐腐蚀的改性纳米复合材料 Download PDF

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WO2019144415A1
WO2019144415A1 PCT/CN2018/074487 CN2018074487W WO2019144415A1 WO 2019144415 A1 WO2019144415 A1 WO 2019144415A1 CN 2018074487 W CN2018074487 W CN 2018074487W WO 2019144415 A1 WO2019144415 A1 WO 2019144415A1
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parts
corrosion
carbon black
nano
modified
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PCT/CN2018/074487
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English (en)
French (fr)
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黄菲
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江苏科力斯通新材料有限公司
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Priority to PCT/CN2018/074487 priority Critical patent/WO2019144415A1/zh
Publication of WO2019144415A1 publication Critical patent/WO2019144415A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints

Definitions

  • the invention relates to nano composite materials, in particular to a corrosion resistant modified nano composite material.
  • a corrosion-resistant modified nanocomposite which comprises a corrosion-resistant resin, an oil-modified polyester resin, a UV-curable resin, an epoxy resin, and a modified composition of the corrosion-resistant modified nanocomposite.
  • the formulation of the modified nanocomposite resistant to corrosion by weight includes 30-50 parts of anticorrosive resin, 15-25 parts of oil modified polyester resin, 10-15 parts of UV curing resin, and epoxy resin 15- 20 parts, 30-40 parts of epoxy iron red antirust paint, 10-20 parts of varnish, 8-12 parts of diluent, 20-28 parts of polyethylene, 15-22 parts of nano barium titanate, nano silica 15- 24 parts, silane coupling agent KH-5504-8 parts, modified nano carbon black 15-24 parts, environmentally friendly plasticizer 4-8 parts, deionized water 30-40 parts.
  • the formulation of the modified nanocomposite resistant to corrosion by weight includes: 35-45 parts of anticorrosive resin, 18-22 parts of oil-modified polyester resin, 12-14 parts of UV-curable resin, epoxy resin 16- 18 parts, 34-37 parts of epoxy iron red antirust paint, 15-17 parts of varnish, 10-11 parts of diluent, 22-25 parts of polyethylene, 17-20 parts of nano-barium titanate, nano-silica 18- 21 parts, silane coupling agent KH-5505-7 parts, modified nano carbon black 17-20 parts, environmentally friendly plasticizer 5-7 parts, deionized water 34-36 parts.
  • the diluent comprises kaolin and talc, and the weight ratio of kaolin to talc in the diluent is from 2 to 7: 7-14.
  • the environmentally friendly plasticizer comprises a synthetic vegetable ester and a Dinch plasticizer, wherein the weight ratio of the synthetic vegetable ester to the Dinch plasticizer in the environmentally friendly plasticizer is from 3 to 9:2 to 5.
  • the preparation process of the modified nano carbon black comprises the following steps:
  • step a the carbon black is laid flat on the bottom of the rectangular parallelepiped container with the heating layer embedded therein, the height of the carbon black is 3-5 cm, and then deionized water and hydrogen peroxide are sprayed on the carbon black to make deionized water in the carbon black.
  • the content reaches 80-90%, and the content of hydrogen peroxide in the carbon black reaches 40-50%;
  • Step b using a heating layer to preheat the carbon black on the bottom of the rectangular container, so that the temperature of the carbon black surface layer reaches 80-90 ° C;
  • Step c at the same time as step b, the polyvinyl alcohol and deionized water are added to the heatable container, so that the temperature of the mixed solution of polyvinyl alcohol and deionized water reaches 90-95 ° C;
  • Step d adding the mixed solution in the step c to the carbon black of the step b, keeping the temperature in the rectangular parallelepiped container at 80-90 ° C, stirring while adding the mixed solution until the mixing solution is added, and stirring is continued. 3-5 min to obtain a mixture a;
  • Step e the heating layer stops heating, the temperature of the mixture a is lowered to room temperature, and the pH of the mixture a is adjusted to 9-10 by adding a sodium hydroxide solution, and the ultrasonic dispersing device on the rectangular parallelepiped container is opened to perform the substance in the rectangular parallelepiped container. Disperse and disperse for 10-15 min to obtain a mixture b;
  • Step d the heating layer restarts heating, so that the temperature in the rectangular parallelepiped container reaches 75 ° C - 80 ° C, the hydrochloric acid solution is added to adjust the pH to 3-4, and then the acetaldehyde solution is added for standing for 1-1.5 h, and then suction filtration is performed. Washing and drying to constant weight to obtain modified nano carbon black.
  • a wavy water supply pipe is disposed in the heating layer, and one end of the water pipe is provided with a water inlet, and the other end of the water pipe is provided with a water outlet, and the outer wall of the rectangular container is provided with ultrasonic dispersion
  • the apparatus, the ultrasonic dispersing device includes a transducer and an ultrasonic generating device, the transducer being connected to an outer wall of the rectangular parallelepiped container, the transducer being coupled to the ultrasonic generating device.
  • the weight ratio of the polyvinyl alcohol to the deionized water in the step c is 1-2:2-3, and the weight ratio of the mixed solution, the carbon black, and the acetaldehyde solution in the step d is 3-5:2-3:4- 6.
  • the concentration of the acetaldehyde solution in step d is 50% to 60%.
  • a method for preparing a corrosion-resistant modified nanocomposite comprises the following steps:
  • Step 1 Deionized water, anticorrosive resin, oil-modified polyester resin, UV curable resin, and epoxy resin are sequentially added to the reaction vessel to be stirred and mixed, and the temperature of the reaction vessel is raised to 70 ° C while stirring, and then Continue stirring to reduce the temperature in the reaction vessel to 30 ° C -40 ° C, add the diluent, continue to stir for 5 min, the stirring speed is 600r / min;
  • Step 2 the stirring speed is increased to 800r / min, while stirring, adding epoxy iron red anti-rust paint, varnish, polyethylene to the reaction tank, after the completion of the addition, stirring for 8-10min;
  • Step 3 reduce the stirring speed to 600r/min, and sequentially add nano-barium titanate, nano-silica, silane coupling agent KH-550, modified nano-carbon black and environmental plasticizer to the reaction kettle, and then continue After stirring for 15-20 min, the temperature in the reaction vessel was lowered to room temperature while stirring to obtain a corrosion-resistant modified nanocomposite.
  • the adhesive of the invention has reasonable formula, good corrosion resistance and long service life after application.
  • a corrosion-resistant modified nanocomposite includes: anti-corrosion resin, oil-modified polyester resin, UV-curing resin, epoxy resin, epoxy iron red anti-rust paint, Varnish, thinner, polyethylene, nano-barium titanate, nano-silica, silane coupling agent KH-550, modified nano-carbon black, environmental plasticizer and deionized water.
  • the formulation of the modified nanocomposite resistant to corrosion by weight includes 30-50 parts of anticorrosive resin, 15-25 parts of oil modified polyester resin, 10-15 parts of UV curing resin, and epoxy resin 15- 20 parts, 30-40 parts of epoxy iron red antirust paint, 10-20 parts of varnish, 8-12 parts of diluent, 20-28 parts of polyethylene, 15-22 parts of nano barium titanate, nano silica 15- 24 parts, silane coupling agent KH-5504-8 parts, modified nano carbon black 15-24 parts, environmentally friendly plasticizer 4-8 parts, deionized water 30-40 parts.
  • the formulation of the modified nanocomposite resistant to corrosion by weight includes 35-45 parts of anticorrosive resin, 18-22 parts of oil-modified polyester resin, 12-14 parts of UV-curable resin, 16-18 parts of epoxy resin, 34-37 parts of epoxy iron red antirust paint, 15-17 parts of varnish, 10-11 parts of diluent, 22-25 parts of polyethylene, 17-20 parts of nano-barium titanate, nano 18-21 parts of silica, silane coupling agent KH-5505-7 parts, modified nano carbon black 17-20 parts, environmentally friendly plasticizer 5-7 parts, and deionized water 34-36 parts.
  • the preparation of the corrosion-resistant modified nanocomposite according to the above formula, the preparation method comprises the following steps:
  • Step 1 Deionized water, anticorrosive resin, oil-modified polyester resin, UV curable resin, and epoxy resin are sequentially added to the reaction vessel to be stirred and mixed, and the temperature of the reaction vessel is raised to 70 ° C while stirring, and then Continue stirring to reduce the temperature in the reaction vessel to 30 ° C -40 ° C, add the diluent, continue to stir for 5 min, the stirring speed is 600r / min;
  • Step 2 the stirring speed is increased to 800r / min, while stirring, adding epoxy iron red anti-rust paint, varnish, polyethylene to the reaction tank, after the completion of the addition, stirring for 8-10min;
  • Step 3 reduce the stirring speed to 600r/min, and sequentially add nano-barium titanate, nano-silica, silane coupling agent KH-550, modified nano-carbon black and environmental plasticizer to the reaction kettle, and then continue After stirring for 15-20 min, the temperature in the reaction vessel was lowered to room temperature while stirring to obtain a corrosion-resistant modified nanocomposite.
  • the diluent comprises kaolin and talc, and the weight ratio of kaolin to talc in the diluent is from 2 to 7: 7-14.
  • the environmentally friendly plasticizer comprises a synthetic vegetable ester and a Dinch plasticizer, and the weight ratio of the synthetic vegetable ester to the Dinch plasticizer in the environmentally friendly plasticizer is from 3 to 9:2 to 5.
  • the preparation process of the modified nano carbon black comprises the following steps:
  • step a the carbon black is laid flat on the bottom of the rectangular parallelepiped container with the heating layer embedded therein, the height of the carbon black is 3-5 cm, and then deionized water and hydrogen peroxide are sprayed on the carbon black to make deionized water in the carbon black.
  • the content reaches 80-90%, and the content of hydrogen peroxide in the carbon black reaches 40-50%;
  • Step b using a heating layer to preheat the carbon black on the bottom of the rectangular container, so that the temperature of the carbon black surface layer reaches 80-90 ° C;
  • Step c at the same time as step b, adding polyvinyl alcohol and deionized water to the heatable container, so that the temperature of the mixed solution of polyvinyl alcohol and deionized water reaches 90-95 ° C, the weight of vinyl alcohol and deionized water
  • the ratio is 1-2:2-3;
  • Step d adding the mixed solution in the step c to the carbon black of the step b, keeping the temperature in the rectangular parallelepiped container at 80-90 ° C, stirring while adding the mixed solution until the mixing solution is added, and stirring is continued. 3-5 min to obtain a mixture a;
  • Step e the heating layer stops heating, the temperature of the mixture a is lowered to room temperature, and the pH of the mixture a is adjusted to 9-10 by adding a sodium hydroxide solution, and the ultrasonic dispersing device on the rectangular parallelepiped container is opened to perform the substance in the rectangular parallelepiped container. Disperse and disperse for 10-15 min to obtain a mixture b;
  • step d the heating layer is restarted to heat, so that the temperature in the rectangular parallelepiped container reaches 75° C.-80° C., the hydrochloric acid solution is added to adjust the pH to 3-4, and then the acetaldehyde solution having a concentration of 50%-60% is added for standing 1- After 1.5 h, it was subjected to suction filtration, washing and drying to constant weight to obtain a modified nano carbon black.
  • a wavy water pipe is disposed in the heating layer, and one end of the water pipe is provided with a water inlet, and the other end of the water pipe is provided with a water outlet, and an outer wall surrounding the rectangular container
  • An ultrasonic dispersing device is provided, the ultrasonic dispersing device comprising a transducer and an ultrasonic generating device, the transducer being connected to an outer wall of the rectangular parallelepiped container, the transducer being coupled to the ultrasonic generating device.
  • the weight ratio of the mixed solution, carbon black, and acetaldehyde solution is 3-5:2-3:4-6.
  • a corrosion-resistant modified nanocomposite comprises: 35-45 parts of anti-corrosion resin, 18-22 parts of oil-modified polyester resin, 12-14 parts of UV-curable resin, 16-18 parts of epoxy resin, 34-37 parts of epoxy iron red antirust paint, 15-17 parts of varnish, 10-11 parts of diluent, 22-25 parts of polyethylene, 17-20 parts of nano-barium titanate, nano 18-21 parts of silica, silane coupling agent KH-5505-7 parts, modified nano carbon black 17-20 parts, environmentally friendly plasticizer 5-7 parts, and deionized water 34-36 parts.
  • a corrosion-resistant modified nanocomposite comprises: 35 parts of anti-corrosion resin, 18 parts of oil-modified polyester resin, 14 parts of UV-curable resin, 18 parts of epoxy resin, 37 parts of epoxy iron red antirust paint, 15 parts of varnish, 11 parts of thinner, 22 parts of polyethylene, 17 parts of nano-barium titanate, 21 parts of nano-silica, silane coupling agent KH-5507 parts, modified nanometer 20 parts of carbon black, 5 parts of environmentally friendly plasticizer, and 34 parts of deionized water.
  • a corrosion-resistant modified nanocomposite the corrosion-resistant modified nanocomposite formulation comprises: 45 parts of anti-corrosion resin, 22 parts of oil-modified polyester resin, 12 parts of UV-curable resin, 16 parts of epoxy resin, 34 parts of epoxy iron red antirust paint, 17 parts of varnish, 10 parts of thinner, 25 parts of polyethylene, 20 parts of nano-barium titanate, 18 parts of nano-silica, silane coupling agent KH-5505 parts, modified nano 17 parts of carbon black, 7 parts of environmentally friendly plasticizer, and 36 parts of deionized water.
  • a corrosion-resistant modified nanocomposite comprises 40 parts of anti-corrosion resin, 20 parts of oil-modified polyester resin, 13 parts of UV-curable resin, 17 parts of epoxy resin, 35 parts of epoxy iron red antirust paint, 16 parts of varnish, 10.5 parts of diluent, 24 parts of polyethylene, 19 parts of nano-barium titanate, 20 parts of nano-silica, silane coupling agent KH-5506 parts, modified nano 18 parts of carbon black, 6 parts of environmentally friendly plasticizer, and 35 parts of deionized water.
  • the corrosion-resistant modified nanocomposites were prepared according to the formulations described in Example 1, Example 2, and Example 3, respectively, and applied to three iron plates. After drying, the three iron plates were placed in a corrosive solution. Change, after 15 days, the formulation on the iron plate of Example 1 was applied to obtain a corrosion-resistant modified nanocomposite which was corroded. After 18 days, the formulation on the iron plate of Example 2 was applied to obtain corrosion-resistant modification. The nanocomposite was corroded, and the modified nanocomposite prepared by the method of the iron plate of Example 3 after 24 days was corroded.
  • the formulation and preparation method of the adhesive of the invention are reasonable, the corrosion resistance is good, and the effective service life after application is long.

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Abstract

一种耐腐蚀的改性纳米复合材料，按重量份数，包括：防腐树脂30-50份、油改性聚酯树脂15-25份、UV固化树脂10-15份、环氧树脂15-20份、环氧铁红防锈漆30-40份、清漆10-20份、稀释剂8-12份、聚乙烯20-28份、纳米钛酸钡15-22份、纳米二氧化硅15-24份、硅烷偶联剂KH-550 4-8份、改性纳米炭黑15-24份、环保增塑剂4-8份、去离子水30-40份。该耐腐蚀的改性纳米复合材料配方合理，耐腐蚀效果好，使用寿命长。

Description

一种耐腐蚀的改性纳米复合材料 技术领域
本发明涉及纳米复合材料，尤其涉及一种耐腐蚀的改性纳米复合材料。
背景技术
随着科技的不断发展，基本上家家户户都有汽车，但是汽车的价格相对较高，使用者对汽车表面的漆性能和漆的使用寿命要求越来越高，特别是对于居住在适度相对较大的地区的，如果车漆的性能和车漆的使用寿命不好会导致整个车的使用寿命下降。
发明内容
本发明的目的提供一种耐腐蚀的改性纳米复合材料，解决上述现有技术问题中的一个或者多个。
根据本发明提供一种耐腐蚀的改性纳米复合材料，按重量份数耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂、油改性聚酯树脂、UV固化树脂、环氧树脂、环氧铁红防锈漆、清漆、稀释剂、聚乙烯、纳米钛酸钡、纳米二氧化硅、硅烷偶联剂KH-550、改性纳米炭黑、环保增塑剂、去离子水。
其中，按重量份数耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂30-50份、油改性聚酯树脂15-25份、UV固化树脂10-15份、环氧树脂15-20份、环氧铁红防锈漆30-40份、清漆10-20份、稀释剂8-12份、聚乙烯20-28份、纳米钛酸钡15-22份、纳米二氧化硅15-24份、硅烷偶联剂KH-5504-8份、改性纳米炭黑15-24份、环保增塑剂4-8份、去离子水30-40份。
进一步，按重量份数耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂35-45份、油改性聚酯树脂18-22份、UV固化树脂12-14份、环氧树脂16-18份、环氧铁红防锈漆34-37份、清漆15-17份、稀释剂10-11份、聚乙烯22-25份、纳米钛酸钡17-20份、纳米二氧化硅18-21份、硅烷偶联剂KH-5505-7份、改性纳米炭黑17-20份、环保增塑剂5-7份、去离子水34-36份。
更进一步，所述稀释剂包括高岭土和滑石粉，所述稀释剂中高岭土和滑石粉的重量比为2-7：7-14。
更进一步，所述环保增塑剂包括合成植物酯和Dinch增塑剂，所述环保增塑剂中合成植物酯和Dinch增塑剂的重量比为3-9：2-5。
其中，所述改性纳米炭黑的制备工艺包括如下步骤：
步骤a，将炭黑平铺到底部嵌有加热层的长方体容器的底部，炭黑的高度在3-5cm，然后在炭黑上喷洒去离子水和双氧水，使得炭黑中的去离子水的含量达到80-90％，炭黑中的双氧水的含量达到40-50％；
步骤b，利用加热层对长方体容器的底部上的炭黑进行预热，使得炭黑表层的温度达到80-90℃；
步骤c，在步骤b进行的同时，将聚乙烯醇和去离子水加入到可加热的容器中，使得聚乙烯醇和去离子水的混合溶液的温度达到90-95℃；
步骤d，将步骤c中的混合溶液加入到步骤b的炭黑中，保持长方体容器中的温度在80-90℃，一边加入混合溶液一边不停的进行搅拌，直至混合溶液加入完成后继续搅拌3-5min得到混合物a；
步骤e，加热层停止加热，混合物a的温度降至室温，加入氢氧化钠溶液对混合物a进行酸碱度的PH值调节至9-10，开启长方体容器上的超声波分散装置对长方体容器中的物质进行分散，分散10-15min，得到混合物b；
步骤d，加热层重新开始加热，使得长方体容器内的温度达到75℃-80℃，加入盐酸溶液调节pH至3-4，然后加入乙醛溶液进行静置1-1.5h，然后进行抽滤、洗涤、干燥至恒重，得到改性纳米炭黑。
进一步，所述加热层内铺设有波浪形的输水管，所述输水管的一端设有进水口，所述输水管的另一端设有出水口，所述长方体容器四周的外壁上设有超声波分散装置，所述超声波分散装置包括换能器和超声波发生装置，所述换能器于长方体容器四周的外壁连接，所述换能器与超声波发生装置连接。
进一步，步骤c中聚乙烯醇和去离子水的重量比为1-2：2-3，步骤d中的混合溶液、炭黑、乙醛溶液的重量比为3-5：2-3：4-6，其中步骤d中的乙醛溶液的浓度为50％-60％。
一种耐腐蚀的改性纳米复合材料的制备方法，所述耐腐蚀的改性纳米复合材料的制备方法包括如下步骤：
步骤1，将去离子水、防腐树脂、油改性聚酯树脂、UV固化树脂、环氧树脂依次加入到反应釜中进行搅拌混合，一边搅拌一边将反应釜的温度升至70℃，然后在继续搅拌将反应釜中的温度降至30℃-40℃，加入稀释剂，继续搅拌5min，搅拌的速度为600r/min；
步骤2，将搅拌的速度升至800r/min，一边搅拌一边向反应釜中依次加入环氧铁红防锈漆、清漆、聚乙烯，加入完成后搅拌8-10min；
步骤3，将搅拌的速度降至600r/min，依次向反应釜中加入纳米钛酸钡、纳米二氧化硅、硅烷偶联剂KH-550、改性纳米炭黑以及环保增塑剂，然后继续搅拌15-20min，一边搅拌一边将反应釜中的温度降至室温即可得到耐腐蚀的改性纳米复合材料。
本发明的胶黏剂的配方合理，耐腐蚀性能好，涂抹后的有效使用寿命长。
具体实施方式
一种耐腐蚀的改性纳米复合材料，耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂、油改性聚酯树脂、UV固化树脂、环氧树脂、环氧铁红防锈漆、清漆、稀释剂、聚乙烯、纳米钛酸钡、纳米二氧化硅、硅烷偶联剂KH-550、改性纳米炭黑、环保增塑剂以及去离子水。其中，按重量份数耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂30-50份、油改性聚酯树脂15-25份、UV固化树脂10-15份、环氧树脂15-20份、环氧铁红防锈漆30-40份、清漆10-20份、稀释剂8-12份、聚乙烯20-28份、纳米钛酸钡15-22份、纳米二氧化硅15-24份、硅烷偶联剂KH-5504-8份、改性纳米炭黑15-24份、环保增塑剂4-8份、去离子水30-40份。
作为本实施例的优选，按重量份数耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂35-45份、油改性聚酯树脂18-22份、UV固化树脂12-14份、环氧树脂16-18份、环氧铁红防锈漆34-37份、清漆15-17份、稀释剂10-11份、聚乙烯22-25份、纳米钛酸钡17-20份、纳米二氧化硅18-21份、硅烷偶联剂KH-5505-7份、改性纳米炭黑17-20份、环保增塑剂5-7份、去离子水34-36份。
按照上述配方进行耐腐蚀的改性纳米复合材料的制取，其制备方法包括如下步骤：
步骤1，将去离子水、防腐树脂、油改性聚酯树脂、UV固化树脂、环氧树脂依次加入到反应釜中进行搅拌混合，一边搅拌一边将反应釜的温度升至70℃，然后在继续搅拌将反应釜中的温度降至30℃-40℃，加入稀释剂，继续搅拌5min，搅拌的速度为600r/min；
步骤2，将搅拌的速度升至800r/min，一边搅拌一边向反应釜中依次加入环氧铁红防锈漆、清漆、聚乙烯，加入完成后搅拌8-10min；
步骤3，将搅拌的速度降至600r/min，依次向反应釜中加入纳米钛酸钡、纳米二氧化硅、硅烷偶联剂KH-550、改性纳米炭黑以及环保增塑剂，然后继续搅拌15-20min，一边搅拌一边将反应釜中的温度降至室温即可得到耐腐蚀的改性纳米复合材料。
作为本实施例的优选，所述稀释剂包括高岭土和滑石粉，所述稀释剂中高岭土和滑石粉的重量比为2-7：7-14。
作为本实施例的优选，所述环保增塑剂包括合成植物酯和Dinch增塑剂，所述环保增塑剂中合成植物酯和Dinch增塑剂的重量比为3-9：2-5。
作为本实施例的优选，所述改性纳米炭黑的制备工艺包括如下步骤：
步骤a，将炭黑平铺到底部嵌有加热层的长方体容器的底部，炭黑的高度在3-5cm，然后在炭黑上喷洒去离子水和双氧水，使得炭黑中的去离子水的含量达到80-90％，炭黑中的双氧水的含量达到40-50％；
步骤b，利用加热层对长方体容器的底部上的炭黑进行预热，使得炭黑表层的温度达到80-90℃；
步骤c，在步骤b进行的同时，将聚乙烯醇和去离子水加入到可加热的容器中，使得聚乙烯醇和去离子水的混合溶液的温度达到90-95℃，乙烯醇和去离子水的重量比为1-2：2-3；
步骤d，将步骤c中的混合溶液加入到步骤b的炭黑中，保持长方体容器中的温度在80-90℃，一边加入混合溶液一边不停的进行搅拌，直至混合溶液加入完成后继续搅拌3-5min得到混合物a；
步骤e，加热层停止加热，混合物a的温度降至室温，加入氢氧化钠溶液对混合物a进行酸碱度的PH值调节至9-10，开启长方体容器上的超 声波分散装置对长方体容器中的物质进行分散，分散10-15min，得到混合物b；
步骤d，加热层重新开始加热，使得长方体容器内的温度达到75℃-80℃，加入盐酸溶液调节pH至3-4，然后加入浓度为50％-60％的乙醛溶液进行静置1-1.5h，然后进行抽滤、洗涤、干燥至恒重，得到改性纳米炭黑。
作为本实施例的优选，所述加热层内铺设有波浪形的输水管，所述输水管的一端设有进水口，所述输水管的另一端设有出水口，所述长方体容器四周的外壁上设有超声波分散装置，所述超声波分散装置包括换能器和超声波发生装置，所述换能器于长方体容器四周的外壁连接，所述换能器与超声波发生装置连接。
作为本实施例的优选，所述混合溶液、炭黑、乙醛溶液的重量比为3-5：2-3：4-6。
实施例1
一种耐腐蚀的改性纳米复合材料，耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂35-45份、油改性聚酯树脂18-22份、UV固化树脂12-14份、环氧树脂16-18份、环氧铁红防锈漆34-37份、清漆15-17份、稀释剂10-11份、聚乙烯22-25份、纳米钛酸钡17-20份、纳米二氧化硅18-21份、硅烷偶联剂KH-5505-7份、改性纳米炭黑17-20份、环保增塑剂5-7份、去离子水34-36份。
实施例1
一种耐腐蚀的改性纳米复合材料，耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂35份、油改性聚酯树脂18份、UV固化树脂14份、环氧树脂18份、环氧铁红防锈漆37份、清漆15份、稀释剂11份、聚乙烯22份、纳米钛酸钡17份、纳米二氧化硅21份、硅烷偶联剂KH-5507份、改性纳米炭黑20份、环保增塑剂5份、去离子水34份。
实施例2
一种耐腐蚀的改性纳米复合材料，耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂45份、油改性聚酯树脂22份、UV固化树脂12份、环氧树脂16份、环氧铁红防锈漆34份、清漆17份、稀释剂10份、聚乙烯25份、纳米钛酸钡20份、纳米二氧化硅18份、硅烷偶联剂KH-5505份、改性纳米炭黑17份、环保增塑剂7份、去离子水36份。
实施例3
一种耐腐蚀的改性纳米复合材料，耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂40份、油改性聚酯树脂20份、UV固化树脂13份、环氧树脂17份、环氧铁红防锈漆35份、清漆16份、稀释剂10.5份、聚乙烯24份、纳米钛酸钡19份、纳米二氧化硅20份、硅烷偶联剂KH-5506份、改性纳米炭黑18份、环保增塑剂6份、去离子水35份。
按照实施例1、实施例2、实施例3所述的配方制取耐腐蚀的改性纳米复合材料分别涂抹到三块铁板上，待其干燥，将三块铁板放置到腐蚀性溶液观察变化，15天后涂抹有实施例1的铁板上的配方制取耐腐蚀的改性纳米复合材料有被腐蚀的现象，18天后涂抹有实施例2的铁板上的配方制取耐腐蚀的改性纳米复合材料有被腐蚀的现象，24天后涂抹有实施例3的铁板上的配方制取耐腐蚀的改性纳米复合材料有被腐蚀的现象。
综上所述，本发明的胶黏剂的配方和制备方法合理,耐腐蚀效果好，涂抹后的有效使用寿命长。
以上所述仅是本发明的一种实施方式，应当指出，对于本领域普通技术人员来说，在不脱离本发明创造构思的前提下，还可以做出若干相似的变形和改进，这些也应视为本发明的保护范围之内。

Claims (8)

  1. 一种耐腐蚀的改性纳米复合材料，其特征在于，耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂、油改性聚酯树脂、UV固化树脂、环氧树脂、环氧铁红防锈漆、清漆、稀释剂、聚乙烯、纳米钛酸钡、纳米二氧化硅、硅烷偶联剂KH-550、改性纳米炭黑、环保增塑剂、去离子水。
  2. 根据权利要求1所述的一种耐腐蚀的改性纳米复合材料，其特征在于，按重量份数耐腐蚀的改性纳米复合材料的配方中包括：防腐树脂30-50份、油改性聚酯树脂15-25份、UV固化树脂10-15份、环氧树脂15-20份、环氧铁红防锈漆30-40份、清漆10-20份、稀释剂8-12份、聚乙烯20-28份、纳米钛酸钡15-22份、纳米二氧化硅15-24份、硅烷偶联剂KH-550 4-8份、改性纳米炭黑15-24份、环保增塑剂4-8份、去离子水30-40份。
  3. 根据权利要求1或2所述的一种耐腐蚀的改性纳米复合材料，其特征在于，所述稀释剂包括高岭土和滑石粉，所述稀释剂中高岭土和滑石粉的重量比为2-7：7-14。
  4. 根据权利要求1或2所述的一种耐腐蚀的改性纳米复合材料，其特征在于，所述环保增塑剂包括合成植物酯和Dinch增塑剂，所述环保增塑剂中合成植物酯和Dinch增塑剂的重量比为3-9：2-5。
  5. 根据权利要求1所述的一种耐腐蚀的改性纳米复合材料，其特征在于，所述改性纳米炭黑的制备工艺包括如下步骤：
    步骤a，将炭黑平铺到底部嵌有加热层的长方体容器的底部，炭黑的高度在3-5cm，然后在炭黑上喷洒去离子水和双氧水，使得炭黑中的去离子水的含量达到80-90％，炭黑中的双氧水的含量达到40-50％；
    步骤b，利用加热层对长方体容器的底部上的炭黑进行预热，使得炭黑表层的温度达到80-90℃；
    步骤c，在步骤b进行的同时，将聚乙烯醇和去离子水加入到可加热的容器中，使得聚乙烯醇和去离子水的混合溶液的温度达到90-95℃；
    步骤d，将步骤c中的混合溶液加入到步骤b的炭黑中，保持长方体容器中的温度在80-90℃，一边加入混合溶液一边不停的进行搅拌，直至混合溶液加入完成后继续搅拌3-5min得到混合物a；
    步骤e，加热层停止加热，混合物a的温度降至室温，加入氢氧化钠溶液对混合物a进行酸碱度的PH值调节至9-10，开启长方体容器上的超声波分散装置对长方体容器中的物质进行分散，分散10-15min，得到混合物b；
    步骤d，加热层重新开始加热，使得长方体容器内的温度达到75℃-80℃，加入盐酸溶液调节pH至3-4，然后加入乙醛溶液进行静置1-1.5h，然后进行抽滤、洗涤、干燥至恒重，得到改性纳米炭黑。
  6. 根据权利要求5所述的一种耐腐蚀的改性纳米复合材料，其特征在于，所述加热层内铺设有波浪形的输水管，所述输水管的一端设有进水口，所述输水管的另一端设有出水口，所述长方体容器四周的外壁上设有超声波分散装置，所述超声波分散装置包括换能器和超声波发生装置，所述换能器于长方体容器四周的外壁连接，所述换能器与超声波发生装置连接。
  7. 根据权利要求5所述的一种耐腐蚀的改性纳米复合材料，其特征在于，步骤c中聚乙烯醇和去离子水的重量比为1-2：2-3，步骤d中的混合溶液、炭黑、乙醛溶液的重量比为3-5：2-3：4-6，其中步骤d中的乙醛溶液的浓度为50％-60％。
  8. 权利要求1所述的一种耐腐蚀的改性纳米复合材料的制备方法，其特征在于，所述耐腐蚀的改性纳米复合材料的制备方法包括如下步骤：
    步骤1，将去离子水、防腐树脂、油改性聚酯树脂、UV固化树脂、环氧树脂依次加入到反应釜中进行搅拌混合，一边搅拌一边将反应釜的温度升至70℃，然后在继续搅拌将反应釜中的温度降至30℃-40℃，加入稀释剂，继续搅拌5min，搅拌的速度为600r/min；
    步骤2，将搅拌的速度升至800r/min，一边搅拌一边向反应釜中依次加入环氧铁红防锈漆、清漆、聚乙烯，加入完成后搅拌8-10min；
    步骤3，将搅拌的速度降至600r/min，依次向反应釜中加入纳米钛酸钡、纳米二氧化硅、硅烷偶联剂KH-550、改性纳米炭黑以及环保增塑剂，然后继续搅拌15-20min，一边搅拌一边将反应釜中的温度降至室温即可得到耐腐蚀的改性纳米复合材料。
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