WO2019144334A1 - 一种太阳能电池及其制备方法 - Google Patents
一种太阳能电池及其制备方法 Download PDFInfo
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- WO2019144334A1 WO2019144334A1 PCT/CN2018/074081 CN2018074081W WO2019144334A1 WO 2019144334 A1 WO2019144334 A1 WO 2019144334A1 CN 2018074081 W CN2018074081 W CN 2018074081W WO 2019144334 A1 WO2019144334 A1 WO 2019144334A1
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- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 108
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 108
- 239000010703 silicon Substances 0.000 claims abstract description 108
- 239000000758 substrate Substances 0.000 claims abstract description 81
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 69
- 239000002070 nanowire Substances 0.000 claims abstract description 43
- 239000011259 mixed solution Substances 0.000 claims abstract description 37
- INPLXZPZQSLHBR-UHFFFAOYSA-N cobalt(2+);sulfide Chemical compound [S-2].[Co+2] INPLXZPZQSLHBR-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229920000301 poly(3-hexylthiophene-2,5-diyl) polymer Polymers 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 25
- 238000004528 spin coating Methods 0.000 claims abstract description 23
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229920000144 PEDOT:PSS Polymers 0.000 claims abstract description 21
- 238000000137 annealing Methods 0.000 claims abstract description 19
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052709 silver Inorganic materials 0.000 claims abstract description 17
- 239000004332 silver Substances 0.000 claims abstract description 17
- 238000004140 cleaning Methods 0.000 claims abstract description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 36
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 22
- 239000000243 solution Substances 0.000 claims description 21
- 239000008367 deionised water Substances 0.000 claims description 20
- 229910021641 deionized water Inorganic materials 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000002207 thermal evaporation Methods 0.000 claims description 10
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- 238000005530 etching Methods 0.000 claims description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 7
- 230000007547 defect Effects 0.000 abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 229910052814 silicon oxide Inorganic materials 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 238000002161 passivation Methods 0.000 description 3
- 229910021417 amorphous silicon Inorganic materials 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000011987 methylation Effects 0.000 description 2
- 238000007069 methylation reaction Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- MARUHZGHZWCEQU-UHFFFAOYSA-N 5-phenyl-2h-tetrazole Chemical compound C1=CC=CC=C1C1=NNN=N1 MARUHZGHZWCEQU-UHFFFAOYSA-N 0.000 description 1
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 1
- KTSFMFGEAAANTF-UHFFFAOYSA-N [Cu].[Se].[Se].[In] Chemical compound [Cu].[Se].[Se].[In] KTSFMFGEAAANTF-UHFFFAOYSA-N 0.000 description 1
- IDJROVMRGKXECW-UHFFFAOYSA-N [Si+4].CCC[O-].CCC[O-].CCC[O-].CCC[O-] Chemical compound [Si+4].CCC[O-].CCC[O-].CCC[O-].CCC[O-] IDJROVMRGKXECW-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/30—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains
- H10K30/35—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains comprising inorganic nanostructures, e.g. CdSe nanoparticles
- H10K30/352—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains comprising inorganic nanostructures, e.g. CdSe nanoparticles the inorganic nanostructures being nanotubes or nanowires, e.g. CdTe nanotubes in P3HT polymer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0216—Coatings
- H01L31/02161—Coatings for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/02167—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0236—Special surface textures
- H01L31/02363—Special surface textures of the semiconductor body itself, e.g. textured active layers
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/50—Photovoltaic [PV] devices
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
- H10K85/1135—Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Definitions
- the invention relates to the field of photoelectric conversion technology, in particular to a solar cell and a preparation method thereof.
- solar cells can be divided into three major categories: the first generation of solar cells specifically include monocrystalline silicon solar energy. Silicon solar cells such as batteries, polycrystalline silicon solar cells, and amorphous silicon solar cells; second-generation solar cells include amorphous silicon thin film solar cells, gallium arsenide solar solar cells, cadmium telluride solar cells, and copper indium gallium selenide solar cells. Thin film solar cells; third generation solar cells specifically include dye-sensitized solar cells, nanocrystalline solar cells. New solar cells such as organic solar cells, organic-inorganic hybrid solar cells, and perovskite solar cells.
- the defect state on the surface of the silicon substrate causes electron-hole recombination, thereby greatly reducing the photoelectric conversion efficiency of the organic-inorganic solar cell.
- Methylation is used to form Si-CH3 bonds on the surface of the silicon wafer to passivate the silicon surface.
- the methylated silicon wafer still has a large number of defect states, and on the other hand, the methylation process is more complicated and The basic processing time is long and it is impossible to perform large-scale applications. Therefore, in view of the above technical problems, it is necessary to improve the passivation mode of the surface of the silicon wafer to improve the photoelectric conversion efficiency of the organic-inorganic solar cell.
- An object of the present invention is to overcome the above deficiencies of the prior art and to provide a solar cell and a method of fabricating the same.
- a method for preparing a solar cell comprises the following steps: (1) cleaning of an n-type silicon substrate: cutting an n-type silicon wafer into an n-type silicon substrate having a size of 3 cm ⁇ 3 cm, and then The n-type silicon substrate is ultrasonically washed in acetone, ethanol and deionized water for 10-15 minutes, then placed in a concentrated H 2 SO 4 /H 2 O 2 mixed solution and heated to 100-110 ° C to maintain 50- 70 minutes, then the n-type silicon substrate was rinsed with deionized water and blown dry with nitrogen for use; (2) a silicon nanowire array was prepared on the upper surface of the n-type silicon substrate: the n obtained in step 1 The silicon substrate is placed in a mixed solution of silver nitrate/hydrofluoric acid, wherein the molar concentration of hydrofluoric acid in the silver nitrate/hydrofluoric acid mixed solution is 4.8 mol/l, and the molar
- step 2 is obtained n
- the silicon substrate is immersed in a hydrofluoric acid solution for 5-10 minutes, and then a mixed solution containing sodium hydroxide and silicon tetrapropoxide is dropped on the upper surface of the n-type silicon substrate and allowed to stand for 3-6 minutes, followed by 2000.
- Cobalt sulfide nanowire/P3HT layer Cobalt sulfide nanowire/P3HT layer; (5) PEDOT: PSS layer preparation: spin-coated PEDOT:PSS solution on the surface of the cobalt sulfide nanowire/P3HT layer; 4000-5000 rpm and time 1-4 minutes, then annealing in a nitrogen atmosphere at a temperature of 110-130 ° C for 20-30 minutes to form the PEDOT:PSS layer; (6) front silver grid Preparation of the electrode; (7) Preparation of the back aluminum electrode.
- the volume ratio of H 2 SO 4 to H 2 O 2 in the concentrated H 2 SO 4 /H 2 O 2 mixed solution is 3:1.
- the concentration of sodium hydroxide in the mixed solution containing sodium hydroxide and silicon tetrapropoxide is 0.3-0.6 mg/ml, and the concentration of silicon tetrapropoxide is 1-2 mg/ml. .
- the concentration of the cobalt sulfide nanowires in the P3HT solution containing the cobalt sulfide nanowires is 0.5-1 mg/ml, and the concentration of the P3HT is 2-5 mg/ml.
- the PEDOT:PSS layer has a thickness of 10-20 nm.
- the front silver gate electrode is formed by a thermal evaporation method, and the front silver gate electrode has a thickness of 100 to 200 nm.
- the back surface aluminum electrode is formed by a thermal evaporation method, and the back surface aluminum electrode has a thickness of 200 to 300 nm.
- the present invention also provides a solar cell which is a solar cell prepared by the above method.
- the present invention can effectively reduce the defect state of the silicon surface by spin-coating silicon tetrapropoxide on the surface of the silicon and annealing the silicon tetrapropoxide to silicon oxide, and simultaneously adding sodium hydroxide and tetra
- the mixed solution of silicon propoxide is allowed to stand for 3-6 minutes, and the surface of the silicon substrate can be micro-etched with sodium hydroxide, so that the silicon tetrapropoxide is sufficiently contacted with the silicon substrate, and the specific process parameters are optimized. Therefore, in the annealing process, a dense and uniform silicon oxide film is formed on the surface of the silicon, the method is simple and easy, and the defect state of the surface of the silicon substrate can be effectively reduced, and the time cost is effectively saved.
- the invention adopts a silicon nanowire array as a light absorbing layer to reduce light reflection, and the presence of a silicon nanowire array increases the contact between silicon and the cobalt sulfide nanowire/P3HT layer, which is beneficial to the separation of electron hole pairs. And transmission efficiency, while the cobalt sulfide nanowires form an interconnection network in the P3HT layer, providing a conduction path for the transport of holes, effectively improving the hole transmission efficiency, by optimizing the structure of the solar cell and the specific content of each component. , effectively improving the photoelectric conversion efficiency of solar cells.
- FIG. 1 is a schematic view showing the structure of a solar cell of the present invention.
- n-type silicon substrate an n-type silicon wafer is cut into an n-type silicon substrate having a size of 3 cm ⁇ 3 cm, and then the n-type silicon substrate is sequentially ultrasonically cleaned in acetone, ethanol, deionized water, 10-15 Minutes, then placed in a concentrated H 2 SO 4 /H 2 O 2 mixed solution and heated to 100-110 ° C for 50-70 minutes, the concentrated H 2 SO 4 /H 2 O 2 mixed solution H 2 SO a volume ratio of 4 to H 2 O 2 of 3:1, followed by rinsing the n-type silicon substrate with deionized water and drying with nitrogen for use;
- the n-type silicon substrate obtained in the step 1 is placed in a silver nitrate/hydrofluoric acid mixed solution, wherein the silver nitrate/hydrogen fluoride
- the molar concentration of hydrofluoric acid in the acid mixed solution is 4.8 mol/l
- the molar concentration of silver nitrate is 0.02 mol/l
- the etching is performed at room temperature for 10-30 minutes to remove the etched n-type silicon substrate.
- rinse with deionized water then immerse in concentrated nitric acid for 50-60 minutes, then rinse the wafer with deionized water and blow dry with nitrogen for later use;
- (6) preparation of a front side silver gate electrode forming the front side silver gate electrode by thermal evaporation, the front side silver gate electrode having a thickness of 100-200 nm;
- the back surface aluminum electrode was formed by a thermal evaporation method, and the back surface aluminum electrode had a thickness of 200 to 300 nm.
- the solar cell prepared by the above method according to the present invention includes a back aluminum electrode 1, a silicon oxide passivation film 2, an n-type silicon substrate 3, a silicon nanowire array 4, and a silicon oxide from bottom to top.
- Passivation film 5 cobalt sulfide nanowire/P3HT layer 6, PEDOT:PSS layer 7, and front silver gate electrode 8.
- a method for preparing a solar cell comprising the steps of:
- the n-type silicon wafer was cut into an n-type silicon substrate having a size of 3 cm ⁇ 3 cm, and then the n-type silicon substrate was sequentially ultrasonically washed in acetone, ethanol, deionized water for 12 minutes, Then, it was placed in a concentrated H 2 SO 4 /H 2 O 2 mixed solution and heated to 105 ° C for 70 minutes, and the concentrated H 2 SO 4 /H 2 O 2 mixed solution was H 2 SO 4 and H 2 O 2 . a volume ratio of 3:1, followed by rinsing the n-type silicon substrate with deionized water and drying with nitrogen for later use;
- the n-type silicon substrate obtained in the step 1 is placed in a silver nitrate/hydrofluoric acid mixed solution, wherein the silver nitrate/hydrogen fluoride
- the molar concentration of hydrofluoric acid in the acid mixed solution is 4.8 mol/l
- the molar concentration of silver nitrate is 0.02 mol/l
- etching at room temperature for 20 minutes after the etched n-type silicon substrate is taken out, Rinse with deionized water, then immerse in concentrated nitric acid for 60 minutes, then rinse the wafer with deionized water and blow dry with nitrogen for later use;
- PEDOT:PSS layer spin-coating PEDOT:PSS solution on the surface of the cobalt sulfide nanowire/P3HT layer; spin coating speed of 4000 rpm/min and time of 3 minutes, then in a nitrogen atmosphere, and Annealing at a temperature of 120 ° C for 25 minutes to form the PEDOT: PSS layer, the thickness of the PEDOT: PSS layer is 15 nm;
- the front side silver gate electrode is formed by thermal evaporation, the thickness of the front side silver gate electrode is 150 nm;
- the back surface aluminum electrode was formed by a thermal evaporation method, and the thickness of the back surface aluminum electrode was 220 nm.
- the solar cell had an open circuit voltage of 0.63 V, a short-circuit current of 31.5 mA/cm 2 , a fill factor of 0.75, and a photoelectric conversion efficiency of 14.9%.
- a method for preparing a solar cell comprising the steps of:
- the n-type silicon wafer was cut into an n-type silicon substrate having a size of 3 cm ⁇ 3 cm, and then the n-type silicon substrate was sequentially ultrasonically cleaned in acetone, ethanol, deionized water for 15 minutes, Then, it was placed in a concentrated H 2 SO 4 /H 2 O 2 mixed solution and heated to 110 ° C for 50 minutes, and the concentrated H 2 SO 4 /H 2 O 2 mixed solution was H 2 SO 4 and H 2 O 2 . a volume ratio of 3:1, followed by rinsing the n-type silicon substrate with deionized water and drying with nitrogen for later use;
- the n-type silicon substrate obtained in the step 1 is placed in a silver nitrate/hydrofluoric acid mixed solution, wherein the silver nitrate/hydrogen fluoride
- the molar concentration of hydrofluoric acid in the acid mixed solution is 4.8 mol/l
- the molar concentration of silver nitrate is 0.02 mol/l
- etching at room temperature for 30 minutes after the etched n-type silicon substrate is taken out, Rinse with deionized water, then immerse in concentrated nitric acid for 60 minutes, then rinse the wafer with deionized water and blow dry with nitrogen for later use;
- PEDOT:PSS layer spin-coating PEDOT:PSS solution on the surface of the cobalt sulfide nanowire/P3HT layer; spin coating speed of 5000 rpm and time of 4 minutes, then in a nitrogen atmosphere, and Annealing at a temperature of 130 ° C for 30 minutes to form the PEDOT:PSS layer, the thickness of the PEDOT:PSS layer is 12 nm;
- the front side silver gate electrode is formed by thermal evaporation, the front side silver gate electrode has a thickness of 200 nm;
- the back surface aluminum electrode was formed by a thermal evaporation method, and the thickness of the back surface aluminum electrode was 300 nm.
- the solar cell had an open circuit voltage of 0.61 V, a short-circuit current of 32.5 mA/cm 2 , a fill factor of 0.71, and a photoelectric conversion efficiency of 14.1%.
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Abstract
Description
Claims (8)
- 一种太阳能电池的制备方法,其特征在于:包括以下步骤:(1)n型硅基底的清洗:将n型硅片切割成尺寸为3cm×3cm的n型硅基底,接着将所述n型硅基底依次在丙酮、乙醇、去离子水中超声清洗10-15分钟,然后置入浓H 2SO 4/H 2O 2混合溶液中并加温至100-110℃保持50-70分钟,接着用去离子水冲洗所述n型硅基底,并用氮气吹干以备用;(2)在所述n型硅基底的上表面制备硅纳米线阵列:将步骤1得到的所述n型硅基底置于硝酸银/氢氟酸混合溶液中,其中所述硝酸银/氢氟酸混合溶液中氢氟酸的摩尔浓度为4.8mol/l,硝酸银的摩尔浓度为0.02mol/l,并在室温下刻蚀10-30分钟,将刻蚀过的所述n型硅基底取出后,用去离子水冲洗,然后浸入浓硝酸中保持50-60分钟,接着用去离子水清洗硅片,并用氮气吹干以备用;(3)对所述n型硅基底进行钝化处理:将步骤2得到n型硅基底在氢氟酸溶液中浸泡5-10分钟,接着在所述n型硅基底的上表面滴加含有氢氧化钠和四丙醇硅的混合溶液并静置3-6分钟,接着在2000-2500转/分钟的条件下旋涂2-5分钟,并在200-400℃的温度下退火30-60分钟,以钝化所述n型硅基底的上表面,然后在所述n型硅基底的下表面滴加含有氢氧化钠和四丙醇硅的混合溶液并静置3-6分钟,接着在2000-2500转/分钟的条件下旋涂2-5分钟,并在200-400℃的温度下退火30-60分钟,以钝化所述n型硅基底的下表面;(4)硫化钴纳米线/P3HT层的制备:在步骤3得到的n型硅基底的上表面旋涂含有硫化钴纳米线的P3HT溶液,旋涂的转速为2000-3000转/分钟以及时间为1-3分钟,然后在氮气环境中,并在120-140℃的温度下退火20-30分钟,形成所述硫化钴纳米线/P3HT层;(5)PEDOT:PSS层的制备:在所述硫化钴纳米线/P3HT层表面旋涂PEDOT:PSS溶液;旋涂的转速为4000-5000转/分钟以及时间为1-4分钟,然后在氮气环境中,并在110-130℃的温度下退火20-30分钟,以形成所述PEDOT:PSS层;(6)正面银栅电极的制备;(7)背面铝电极的制备。
- 根据权利要求1所述的太阳能电池的制备方法,其特征在于:在所述步骤1中,所述浓H 2SO 4/H 2O 2混合溶液中H 2SO 4与H 2O 2体积比为3:1
- 根据权利要求1所述的太阳能电池的制备方法,其特征在于:在所述步骤3中,所述含有氢氧化钠和四丙醇硅的混合溶液中氢氧化钠的浓度为0.3-0.6mg/ml,四丙醇硅的浓度为1-2mg/ml。
- 根据权利要求1所述的太阳能电池,其特征在于:在所述步骤4中,所述含有硫化钴纳米线的P3HT溶液中硫化钴纳米线的浓度为0.5-1mg/ml,P3HT的浓度为2-5mg/ml。
- 根据权利要求1所述的太阳能电池的制备方法,其特征在于:所述PEDOT:PSS层的厚度为10-20nm。
- 根据权利要求1所述的太阳能电池的制备方法,其特征在于:在所述步骤6中通过热蒸镀法形成所述正面银栅电极,所述正面银栅电极的厚度为100-200nm。
- 根据权利要求1所述的太阳能电池的制备方法,其特征在于:在所述步骤7中通过热蒸镀法形成所述背 面铝电极,所述背面铝电极的厚度为200-300nm。
- 一种太阳能电池,其特征在于,采用权利要求1-6任一项所述的方法制备形成的。
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