WO2019132141A1 - 연료전지용 막가습기 - Google Patents

연료전지용 막가습기 Download PDF

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Publication number
WO2019132141A1
WO2019132141A1 PCT/KR2018/007416 KR2018007416W WO2019132141A1 WO 2019132141 A1 WO2019132141 A1 WO 2019132141A1 KR 2018007416 W KR2018007416 W KR 2018007416W WO 2019132141 A1 WO2019132141 A1 WO 2019132141A1
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WO
WIPO (PCT)
Prior art keywords
case
sealing
potting
middle case
cap
Prior art date
Application number
PCT/KR2018/007416
Other languages
English (en)
French (fr)
Korean (ko)
Inventor
김도우
김경주
김인호
안나현
이진형
Original Assignee
코오롱인더스트리 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020170184480A external-priority patent/KR102240511B1/ko
Priority claimed from KR1020180065091A external-priority patent/KR102263284B1/ko
Application filed by 코오롱인더스트리 주식회사 filed Critical 코오롱인더스트리 주식회사
Priority to JP2020535046A priority Critical patent/JP6990312B2/ja
Priority to CN201880084788.5A priority patent/CN111566861B/zh
Priority to EP18896418.3A priority patent/EP3734731A4/en
Priority to US16/958,373 priority patent/US11539060B2/en
Publication of WO2019132141A1 publication Critical patent/WO2019132141A1/ko
Priority to JP2021194717A priority patent/JP7311575B2/ja

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02—Hollow fibre modules
    • B01D63/024—Hollow fibre modules with a single potted end
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02—Hollow fibre modules
    • B01D63/021—Manufacturing thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02—Hollow fibre modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02—Hollow fibre modules
    • B01D63/031—Two or more types of hollow fibres within one bundle or within one potting or tube-sheet
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04126—Humidifying
    • H01M8/04149—Humidifying by diffusion, e.g. making use of membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2313/00—Details relating to membrane modules or apparatus
    • B01D2313/04—Specific sealing means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2313/00—Details relating to membrane modules or apparatus
    • B01D2313/21—Specific headers, end caps
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04828—Humidity; Water content
    • H01M8/0485—Humidity; Water content of the electrolyte
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the present invention relates to a membrane humidifier for a fuel cell, and more particularly, to a membrane humidifier for a fuel cell capable of performing an airtight function in a high temperature / high pressure / high humidity environment by a mechanical assembling structure.
  • Fuel cells are power generation cells that produce electricity by combining hydrogen and oxygen. Unlike conventional chemical batteries, such as batteries and accumulators, fuel cells can produce electricity continuously as long as hydrogen and oxygen are supplied, and they are twice as efficient as internal combustion engines because they have no heat loss.
  • the fuel cell is advantageous not only to be environmentally friendly but also to reduce the concern about resource exhaustion due to an increase in energy consumption.
  • Such a fuel cell can be classified into a polymer electrolyte membrane fuel cell (PEMFC), a phosphoric acid fuel cell (PAFC), a molten carbonate fuel cell (Molten Carbonate Fuel Cell) (MCFC), a solid oxide fuel cell (SOFC), and an alkaline fuel cell (AFC).
  • PEMFC polymer electrolyte membrane fuel cell
  • PAFC phosphoric acid fuel cell
  • MCFC molten carbonate fuel cell
  • SOFC solid oxide fuel cell
  • AFC alkaline fuel cell
  • Each of these fuel cells operates basically on the same principle, but the type of fuel used, the operating temperature, the catalyst, and the electrolyte are different from each other.
  • PEMFCs are known to be most promising not only in small size stationary power generation equipment but also in transportation system because they operate at a lower temperature than other fuel cells and can be miniaturized due to their high output density.
  • PEMFCs polymer electrolyte membrane
  • MEA membrane electrode assemblies
  • the method of humidifying the polymer electrolyte membrane is as follows: 1) a bubbler humidification method in which a pressure vessel is filled with water, a subject gas is passed through a diffuser to supply water, and 2) A direct injection method in which water is directly supplied to the gas flow pipe through calculation using a solenoid valve, and 3) a humidifying membrane method in which water is supplied to a fluidized bed of gas using a polymer separator.
  • the humidifying membrane type which humidifies the polymer electrolyte membrane by providing water vapor to the gas supplied to the polymer electrolyte membrane using a membrane selectively permeable to only the water vapor contained in the exhaust gas is advantageous in that the humidifier can be made lighter and smaller.
  • the selective permeable membrane used in the humidifying membrane method is preferably a hollow fiber membrane having a large permeation area per unit volume when a module is formed. That is, when the membrane humidifier is manufactured using the hollow fiber membrane, the hollow fiber membrane having a large contact surface area can be highly integrated, so that the humidification of the fuel cell can be sufficiently performed even at a small capacity, Moisture and heat contained in the discharged unreacted gas can be recovered and reused through the humidifier.
  • the hollow fiber membrane is housed in the housing part, and the hollow fiber membrane is bonded to the inner wall of the housing part by the potting part.
  • the hollow fiber membrane is housed within the housing portion and adhered and secured to the housing portion by the potting portion, depending on the desired output value of the stack.
  • high temperature air introduced from the blower and high temperature and high humidity air introduced from the stack are introduced.
  • the thermal expansion and the heat shrinkage ratio of the potting portion are large, so that a gap is formed between the housing portion and the potting portion, and air leaks through it. To prevent this, a sealant is applied between the housing part and the potting part.
  • the air introduced from the blower leaks from the membrane humidifier for the fuel cell to reduce the amount of air introduced into the stack. Therefore, the blower must additionally supply an amount larger than the desired inflow amount in the actual stack. Power consumption increases, which leads to system power loss. Therefore, it is advantageous from the viewpoint of overall power efficiency that there is no leakage as much as possible.
  • An object of the present invention is to provide a membrane humidifier for a fuel cell capable of performing an airtight function in a high temperature / high pressure / high humidity environment by a mechanical assembling structure.
  • a membrane humidifier for a fuel cell comprising: a middle case housing a plurality of hollow fiber membranes; A cap case coupled to the middle case; A potting portion formed on the plurality of hollow fiber membrane ends; And an assembling member that is disposed between the cap case and the end of the middle case, and that airtightly couples between the cap case and the middle case, and between the cap case and the potting portion at the same time.
  • the assembling member includes a first sealing portion which is in contact with an inner wall of the cap case and is mounted to an end of the middle case, and a second sealing portion which is formed inside the first sealing portion and is formed to surround the potting portion .
  • the first sealing part may include a first sealing body formed in a C shape and mounted on an end of the middle case in contact with the inner wall of the cap case and a second sealing body extending downward from one end of the first sealing body, And a first sealing leg formed to contact the portion.
  • the first sealing portion may further include an extension leg extending inward from an end of the first sealing leg and extending upward at an end thereof to surround the second sealing portion.
  • the first sealing part may further include a second sealing leg extending downward from the other end of the first sealing body and contacting an inner wall of the cap case and an end of the middle case.
  • the first sealing part may further include a second sealing leg extending downward from the other end of the first sealing body and contacting an inner wall of the cap case and an end of the middle case.
  • the second sealing portion may include a second sealing body formed to surround the potting portion, and a sealing arm inserted into the first sealing body.
  • the first sealing part may be made of a soft material, and the second sealing part may be made of a hard material.
  • a membrane humidifier for a fuel cell comprising: a middle case housing a plurality of hollow fiber membranes; A cap case coupled to the middle case; A potting portion formed on the plurality of hollow fiber membrane ends; And an assembling member that is disposed between the cap case and the end of the middle case, and that airtightly couples between the cap case and the middle case, and between the cap case and the potting unit at the same time.
  • the cap case may include a large diameter portion coupled to the middle case and having an inner diameter larger than the outer diameter of the potting portion, and a small diameter portion protruding from one surface of the large diameter portion and having an inner diameter smaller than the outer diameter of the potting portion.
  • the assembling member includes a body portion disposed between the cap case, the middle case, and the potting portion, and a cap member coupled between the cap case and the middle case to hermetically couple the cap case and the middle case And a second engaging portion contacting the one end of the potting portion and hermetically coupling the capping case with the potting portion.
  • the first engagement portion may include a first extension extending outwardly from the body portion.
  • the first coupling portion may further include a second extension portion extending from an end of the first extension portion to contact the outer surface of the middle case.
  • a stepped portion for receiving the second extended portion of the first engaging portion may be provided on the outer surface of the end portion of the middle case.
  • the cap case may include a protrusion protruding from a surface of the cap case opposite to the end of the middle case.
  • the second engaging portion of the assembling member may include an inclined portion formed on an inner surface of the second engaging portion, and the potting portion may include an inclined portion formed at an end edge of the engaging portion and closely contacting the inclined portion of the second engaging portion.
  • the hardness of the assembling member may be smaller than the potting portion.
  • the plurality of hollow fiber membranes are accommodated in a cartridge, and the cartridge may include an extension rib extending at one end in an outward direction to support one surface of the assembly member.
  • the assembling member may further include a rib portion extending inward to widen the surface area contacting the potting portion.
  • the hardness of the assembling member may be larger than the potting portion, and may be smaller than the middle case and the cap case.
  • the airtight function can be performed in a high temperature / high pressure / high humidity environment by a mechanical assembling structure.
  • FIG 1 and 2 are views showing a membrane humidifier for a fuel cell according to an embodiment of the present invention.
  • FIG 3 is a partial cross-sectional view illustrating a membrane humidifier for a fuel cell according to an embodiment of the present invention.
  • FIG. 4 is a sectional view showing a first embodiment of the assembling member according to the present invention.
  • FIG. 5 is a sectional view showing a second embodiment of the assembling member according to the present invention.
  • FIG. 6 is a sectional view showing a third embodiment of the assembling member according to the present invention.
  • FIG. 7 is a perspective view showing a third embodiment of the assembling member according to the present invention.
  • FIG. 8 is an exploded perspective view showing a third embodiment of the assembling member according to the present invention.
  • FIG. 9 is a partially enlarged view showing a state in which the assembling member of Fig. 4 seals the membrane humidifier for a fuel cell.
  • FIG. 10 is a partially enlarged view showing a state in which the assembling member of Fig. 5 seals the membrane humidifier for a fuel cell.
  • FIG. 11 is a partially enlarged view showing a state in which the assembling member of Fig. 6 seals the membrane humidifier for a fuel cell.
  • Fig. 12 is a view showing the process of assembling the assembling member of Fig. 5 into the potting part.
  • Fig. 13 is a view showing a state in which the assembling member of Fig. 5 is fitted in the potting part.
  • FIG. 14 is a view showing a process of assembling the assembling member of FIG. 6 into the potting portion.
  • Fig. 15 is a view showing a state in which the assembling member of Fig. 6 is fitted in the potting portion.
  • 16 and 17 are exploded perspective views showing a membrane humidifier for a fuel cell according to an embodiment of the present invention.
  • FIG. 18 is a sectional view showing a membrane humidifier according to a fourth embodiment of the present invention.
  • FIG. 19 is a perspective view illustrating a hollow fiber membrane cartridge according to an embodiment of the present invention.
  • 20 is a perspective view showing an assembling member according to an embodiment of the present invention.
  • 21 is a sectional view showing a membrane humidifier according to a fifth embodiment of the present invention.
  • FIG. 22 is a sectional view showing a membrane humidifier according to a sixth embodiment of the present invention.
  • FIG. 23 is a sectional view showing a membrane humidifier according to a seventh embodiment of the present invention.
  • FIG. 24 is a sectional view showing a membrane humidifier according to an eighth embodiment of the present invention.
  • 25 is a sectional view showing a membrane humidifier according to a ninth embodiment of the present invention.
  • a membrane humidifier for a fuel cell according to an embodiment of the present invention includes a middle case 110, a cap case 120, a potting portion 130, and an assembly member 200 .
  • the middle case 110 combines with the cap case 120 to form the outer shape of the membrane humidifier.
  • the middle case 110 and the cap case 120 may be made of hard plastic such as polycarbonate or metal.
  • the middle case 110 and the cap case 120 may have a circular cross-sectional shape in the width direction as shown in Fig. 1, or a polygonal cross-sectional shape as shown in Fig.
  • the polygon may be a square, a square, a trapezoid, a parallelogram, a pentagon, a hexagon, or the like, and the polygon may be rounded.
  • the circular shape may be an elliptical shape.
  • the middle case 110 has a second fluid inlet 112 through which a second fluid is supplied and a second fluid outlet 113 through which a second fluid is discharged.
  • a second fluid inlet 112 through which a second fluid is supplied
  • a second fluid outlet 113 through which a second fluid is discharged.
  • 113 may be the second fluid inlet
  • 112 may be the second fluid outlet.
  • the hollow fiber membrane module may include a plurality of hollow fiber membrane cartridges (C) in which a plurality of hollow fiber membranes are integrated or a hollow fiber membrane bundle in which hollow fiber membranes are accommodated.
  • the hollow fiber membrane module includes the hollow fiber membrane cartridge (C), and does not exclude the case where the hollow fiber membrane module includes the hollow fiber membrane bundle.
  • the cap case 120 is coupled to both ends of the middle case 110.
  • Each cap case 120 is formed with a fluid outlet 121, one of which is the first fluid inlet and the other of which is the first fluid outlet.
  • the first fluid introduced into the fluid inlet 121 of the one side cap case 120 passes through the inner pipe of the hollow fiber membrane accommodated in the hollow fiber membrane cartridge C and then flows into the fluid inlet 121 of the other side cap case 120, .
  • the hollow fiber membrane may be made of, for example, a Nafion material, a polyetherimide material, a polyimide material, a polyphenylsulfone material, a polysulfone material, a polyether sulfone (PES) It can be a hollow fiber membrane made of a material.
  • the hollow fiber membrane module includes a plurality of hollow fiber membrane cartridges C
  • a second fluid introduced into the membrane humidifier through the second fluid inlet 112 is introduced into one side of the hollow fiber membrane cartridges C
  • a second mesh for allowing the second fluid, which has undergone water exchange in the hollow fiber membrane cartridge C, to flow out to the outside of the hollow fiber membrane cartridge C, (Not shown) may be formed.
  • a potting part (130) for binding the hollow fiber membranes and filling the gap between the hollow fiber membranes is formed.
  • both ends of the hollow fiber membrane module are blocked by the potting part 130, and a flow path through which the second fluid passes is formed therein.
  • the material of the potting part 130 is well known in the art and will not be described in detail here.
  • the assembly member 200 includes a first sealing portion 210 and a second sealing portion 220.
  • the assembling member 200 is disposed between the potting portion 130 and the end portion 111 of the middle case 110 to seal the inside of the middle case 110 and the middle case 110 and the cap case 120 simultaneously do.
  • the first sealing part 210 is made of a soft material having a small hardness such as silicon or soft rubber and the second sealing part 220 is made of a hard material having high hardness such as plastic, metal, hard rubber or the like.
  • the criterion of the degree of hardness is based on ASTM D2240 (Shore A) of 70 degrees. That is, if it is 70 degrees or more, it is a hard material, and if it is less than 70 degrees, it is a soft material.
  • the assembly member 200 is formed to have a soft first sealing portion 210 to surround the hard second sealing portion 220 and to perform a sealing function in a high temperature / high pressure / high humidity environment by a unique mechanical assembly structure can do.
  • the first sealing portion 210 is in contact with the inner wall 122 of the cap case and mounted on the end portion 111 of the middle case.
  • the second sealing part 220 is formed on the inner side of the first sealing part 210 and is formed to surround the potting part 130.
  • the soft first sealing portion 210 is compressed by the hard second sealing portion 220 during the assembly process and presses the inner wall 122 of the cap case to be formed by the cartridge C and the cap case 120 Thereby hermetically sealing the space and the space inside the middle case 110.
  • the inner and outer spaces of the cap case 120 and the middle case 110 are hermetically sealed.
  • the hard second sealing portion 220 presses the potting portion 130 so that the space formed by the cartridge C and the cap case 120 and the space inside the middle case 110 Lt; / RTI >
  • the coupling protrusions 123 may be formed on the inner wall of the cap case 120 to improve the fixing force between the cap case 120 and the assembly member 200 when assembling the membrane humidifier, .
  • the assembly member 200 may be embodied in various embodiments depending on the material of the potting part 130. 3, an assembling member according to a third embodiment to be described later is shown.
  • FIG. 4 is a sectional view showing a first embodiment of an assembling member according to an embodiment of the present invention
  • FIG. 5 is a sectional view showing a second embodiment of the assembling member according to an embodiment of the present invention
  • the assembling member of the first embodiment includes a first sealing part 210 including a first sealing body 211 and a first sealing leg 212, a second sealing part 210 including a second sealing body 221, And a second sealing part 220 including a sealing arm 222.
  • the first sealing leg 211 is formed in a " C "shape while contacting the inner wall of the cap case 120, and the first sealing leg 212 extends downward from one end of the first sealing body 211 And is in contact with the second sealing portion 220. (See Fig. 9)
  • the first sealing body 211 presses the inner wall 122 of the cap case while being compressed by the second sealing part 220 and the first sealing leg 212 presses the second sealing part 220 And presses the end portion 111 of the middle case 110 to hermetically seal the space formed by the cartridge C and the cap case 120 and the space inside the middle case 110.
  • the second sealing body 221 and the sealing arm 222 are made of a hard material.
  • the sealing arm 222 presses the first sealing body 211 and the second sealing body 221 presses the first sealing leg 212.
  • the assembling member of the first embodiment is useful when the potting portion 130 is made of a soft material.
  • the assembly member of the first embodiment is fitted while compressing the potting part 130 inwardly when the second sealing body 221 is fitted into the soft potting part 130 in the process of assembling the membrane humidifier.
  • the second sealing body 221 and the potting part 130 are hermetically sealed by the restoring force to restore the potting part 130 of the soft material to the original position.
  • the second sealing body 221 presses the first sealing leg 212, and the first sealing leg 212 is compressed by the second sealing body 221 so that the end 111 of the middle case 110
  • the angle O between the bottom surface and the side surface of the second sealing body 221 is 90 degrees (see FIG. 12 and FIG. 13), for easy assembly of the assembling member and the potting portion 130, .
  • the assembly member of the second embodiment includes a first sealing part 210 including a first sealing body 211, a first sealing leg 212 and a second sealing leg 213, And a second sealing part 220 including a second sealing body 221 and a sealing arm 222.
  • first sealing body 211, the first sealing leg 212, the second sealing body 221, and the sealing arm 222 are the same as those of the first embodiment, repetitive description will be omitted.
  • the first sealing leg 212 extends downward at one end of the first sealing body 211 and the second sealing leg 213 extends downward at the other end of the first sealing body 211.
  • An end 111 of the middle case 110 is fitted between the first sealing leg 212 and the second sealing leg 213. At this time, the end portion 111 of the middle case 110 is formed with a step to which the second sealing leg 213 can be inserted. (See Fig. 10)
  • the assembly member of the third embodiment includes a first sealing body 211, a first sealing leg 212, a second sealing leg 213, and an extension leg 214, A sealing part 210 and a second sealing part 220 including a second sealing body 221 and a sealing arm 222. Since the first sealing body 211, the first sealing leg 212, the second sealing leg 213, the second sealing body 221 and the sealing arm 222 are the same as those of the second embodiment described above, The description is omitted.
  • the extension leg 214 is made of a soft material and extends inwardly from the end of the first sealing leg 212 and extends upwardly at the end thereof to form a second sealing portion 220 (specifically, Body 221). (See Fig. 11)
  • the assembling member of the third embodiment is useful when the potting portion 130 is made of a hard material.
  • the soft expanding leg 214 is compressed and fitted by the potting part 130.
  • the assembly member and the potting portion are hermetically sealed by the resilient force that the flexible extension leg 214 restores to the original position.
  • the second sealing body 221 presses the first sealing leg 212, and the first sealing leg 212 is compressed by the second sealing body 221 so that the end 111 of the middle case 110 Thereby sealing the space formed by the cartridge C and the cap case 120 and the space inside the middle case 110 hermetically. 14 and 15)
  • the angle O between the bottom surface and the side surface of the second sealing body 221 is set to 90 degrees (see FIG. 14 and FIG. 15) for easy assembly of the assembling member and the potting portion 130, .
  • the assembling members of the first and second embodiments described above are useful when the potting portion 130 is a soft material and the assembling member of the third embodiment is useful when the potting portion 130 is a hard material useful.
  • the assembling members of the first to third embodiments are formed in a circular or elliptical ring shape as shown in Figs. 7 and 8, and are disposed between the potting portion 130 and the end portion 111 of the middle case .
  • Figs. 7 and 8 illustrate the assembling member of the third embodiment, and the assembling members of the first and second embodiments can be easily derived therefrom, so that the illustration is omitted.
  • 16 and 17 are exploded perspective views showing a membrane humidifier for a fuel cell according to an embodiment of the present invention.
  • the membrane humidifier 100 for a fuel cell according to an embodiment of the present invention includes a middle case 110, a cap case 120, a potting part 130, 300).
  • the middle case 110 combines with the cap case 120 to form the outer shape of the membrane humidifier.
  • the middle case 110 and the cap case 120 may be made of hard plastic such as polycarbonate or metal.
  • the middle case 110 and the cap case 120 may have a circular cross-sectional shape in the width direction as shown in Fig. 16, or a polygonal cross-sectional shape as shown in Fig. 17.
  • the polygon may be a square, a square, a trapezoid, a parallelogram, a pentagon, a hexagon, or the like, and the polygon may be rounded.
  • the circular shape may be an elliptical shape.
  • the middle case 110 has a second fluid inlet 112 through which a second fluid is supplied and a second fluid outlet 113 through which a second fluid is discharged.
  • a second fluid inlet 112 through which a second fluid is supplied
  • a second fluid outlet 113 through which a second fluid is discharged.
  • 113 may be the second fluid inlet
  • 112 may be the second fluid outlet.
  • the hollow fiber membrane module may include a plurality of hollow fiber membrane cartridges 140 (see FIG. 18) in which a plurality of hollow fiber membranes are integrated or a hollow fiber membrane bundle in which hollow fiber membranes are accommodated.
  • the hollow fiber membrane module includes the hollow fiber membrane cartridge 140 and does not exclude the case where the hollow fiber membrane module includes the hollow fiber membrane bundle.
  • the cap case 120 is coupled to both ends of the middle case 110.
  • Each cap case 120 is formed with a fluid outlet 121, one of which is the first fluid inlet and the other of which is the first fluid outlet.
  • the first fluid introduced into the fluid inlet 121 of the one side cap case 120 passes through the inner pipe of the hollow fiber membrane accommodated in the hollow fiber membrane cartridge 140 and then flows into the fluid inlet 121 of the other side cap case 120, .
  • the hollow fiber membrane may be made of, for example, a Nafion material, a polyetherimide material, a polyimide material, a polyphenylsulfone material, a polysulfone material, a polyether sulfone (PES) It can be a hollow fiber membrane made of a material.
  • the hollow fiber membrane module includes a plurality of hollow fiber membrane cartridges 140
  • a second fluid introduced into the membrane humidifier through the second fluid inlet 112 is introduced into one side of the hollow fiber membrane cartridge 140
  • a second mesh 160 for allowing the second fluid having undergone water exchange inside the hollow fiber membrane cartridge 140 to flow out of the hollow fiber membrane cartridge 140 is formed on the other side of the first mesh part 142, (Not shown) may be formed.
  • a potting portion 130 is formed that binds the hollow fiber membranes and fills the voids between the hollow fiber membranes.
  • both end portions of the hollow fiber membrane module are plugged in the potting portion 130, and a flow passage through which the second fluid passes is formed in the potting portion 130.
  • the material of the potting part 130 is well known in the art and will not be described in detail here.
  • FIG. 18 is a cross-sectional view illustrating a membrane humidifier according to a fourth embodiment of the present invention
  • FIG. 9 is a perspective view illustrating a hollow fiber membrane cartridge according to an embodiment of the present invention
  • the hollow fiber membrane module includes the hollow fiber membrane cartridge 140 .
  • the hollow fiber membrane cartridge 140 is shown in the drawing, it is not excluded that a plurality of hollow fiber membrane cartridges 140 are included in the membrane humidifier.
  • the hollow fiber membrane cartridge 140 of FIG. 19 shows one of the plurality of cartridges disposed inside the case of the film humidifier.
  • FIG. 20 shows an assembling member in which one cartridge and a potting portion are provided.
  • a pair of rectilinear portions and a pair of semicircular portions are integrally connected to each other.
  • 20 (a) is a perspective view seen from the side in contact with the cap case 120
  • FIG. 20 (b) is a perspective view viewed from the opposite side.
  • the assembly member 300 is disposed between the end portion 111 of the middle case 110 and the cap case 120. At the same time, the assembly member 300 is also disposed between the cap case 120 and the potting part 130.
  • the inner surface of the cap case 120 is assembled to be spaced apart from the end 111 of the middle case 110. Also, the inner surface of the cap case 120 is assembled so as to be separated from the potting part 130.
  • the assembling member 300 is assembled so as to airtightly couple between the cap case 120 and the middle case 110 and between the cap case 120 and the potting part 130 at the same time.
  • the middle case 110 and the cap case 120 are assembled by various fastening methods (not shown) such as a plurality of bolts, press fitting, welding, and clamping. At this time, the assembling member 300 is inserted do.
  • the sectional views of FIG. 18 and subsequent drawings are cross-sectional views taken on a plane that does not pass through the fastening portion such as a bolt, and therefore, no fastening portion such as a bolt is shown.
  • the middle case 110 and the cap case 120 may have a polygonal or circular cross-section.
  • the cross-sectional views of FIG. 18 and subsequent drawings show a case where the middle case 110 and the cap case 120 have a rectangular cross- .
  • the cap case 120 has a large diameter portion 125 which is coupled with the middle case 110 and has an inner diameter L1 larger than the outer diameter L3 of the potting portion 130.
  • the large diameter portion 125 protrudes from one surface of the large diameter portion 125, Diameter portion 127 having an inner diameter L2 smaller than the outer diameter L3 of the portion 130.
  • outer diameter and inner diameter, and the large diameter portion and the small diameter portion are terms related to the diameter of the circular pipe in general, but include all cases in which the membrane humidifier housing is circular, elliptical, or polygonal.
  • the distance L2 between the facing inner surfaces of the small diameter portion 127 formed with the fluid outlet 121 of the cap case 120 is larger than the distance L2 between the facing outer surfaces of the potting portion 130 And is smaller than the distance L3.
  • the assembling member 300 can be squeezed between the cap case 120 and the potting part 130 during assembly.
  • the shape of the cap case 120 can be applied not only to the fourth embodiment but also to all the following embodiments.
  • the distance L3 between the facing outer surfaces of the potting part 130 is smaller than the distance between the inner surfaces of the middle case 110.
  • the porting part 130 is spaced apart from the inside of the middle case 110 Respectively.
  • the assembly member 300 may be disposed between the middle case 110 and the potting part 130 to fix the potting part 130 so as not to move with respect to the middle case 110.
  • the assembling member 300 is configured to simultaneously and concurrently connect between the middle case 110 and the cap case 120, between the cap case 120 and the potting part 130, and between the middle case 110 and the potting part 130 .
  • the assembly member 300 includes a main body 310 disposed between the cap case 120, the middle case 110 and the potting part 130, and a pressing part 300 disposed between the cap case 120 and the middle case 110, A first coupling part 320 which hermetically couples the cap case 120 and the middle case 110 to each other and a second coupling part 320 which is in contact with one end of the potting part 130, And a second coupling portion 330 that air-tightly couples the first coupling portion 330 and the second coupling portion 330.
  • the pair of assembling members 300 are shown as being arranged symmetrically in the cross-sectional view of FIG. 18, it will be understood that the assembling member 300 formed integrally as one body is in the form of a rectangular ring as a whole.
  • the main body 310 is disposed in close contact with the inner surface of the cap case 120, the inner surface of the middle case 110, and the upper surface of the potting part 130.
  • the first engaging portion 320 is inserted between the cap case 120 and the end of the middle case 110 and is compressed.
  • the first engagement portion 320 includes a first extension portion 322 extending outwardly from the body portion 310 and a second extension portion 322 extending from the end portion of the extension portion to contact the outer surface of the middle case 110. [ (324). ≪ / RTI > A groove may be formed between the outer surface of the body 310 and the inner surface of the second extension 324 to receive the end of the middle case 110.
  • the outer surface of the second extension portion 324 may contact the inner surface of the cap case 120, but may not be in contact as shown in the drawing.
  • a stepped portion 115 may be formed on the outer surface of the end portion 111 of the middle case 110 to receive the second extension portion 324 of the first coupling portion 320. Accordingly, the outer surface of the middle case 110 and the outer surface of the second extending portion 324 can form substantially the same plane.
  • the second engaging part 330 is a part where the inner edge of the assembling member 300 is pressed onto the corner of the potting part 130.
  • the relative hardness of the assembling member 300 and the potting part 130 may be varied.
  • the second engaging portion 330 of the assembling member 300 may be compressed and shrunk by the potting portion 130 during assembly.
  • Fig. 18 shows this case.
  • the edge of the potting portion 130 can be compressed and contracted by the second engaging portion 330 of the assembling member 300 at the time of assembling .
  • a portion indicated by a dotted line in the second coupling portion 330 shows an external shape before being pressed by the potting portion 130.
  • the pressing parts of the assembling member 300 and the potting part 130 may be simultaneously contracted during assembly.
  • the cap case 120 preferably includes a protrusion 123 protruding from a surface of the middle case 110 opposite to the end 111 thereof.
  • the protrusions 123 may be formed in the form of ribs having a semicircular or cross-sectional shape. The protrusion 123 not only enhances airtightness by further pressing the first engaging portion 320 of the assembling member 300 but also serves to fix the first engaging portion 320 so as not to move during the pressing process do.
  • the protrusion 123 of the cap case 120 may be formed at a position opposite to the end of the middle case 110 but at a position opposite to the edge of the potting part 130. Also, a projection may be formed between the two projections.
  • a rib-shaped protrusion 116 having a semicircular cross section may be formed on the end portion 111 of the middle case 110 as well.
  • the protrusions 116 of the middle case 110 may not be opposed to the protrusions 123 of the cap case 120 but may be staggered. When the two projections are arranged alternately, airtightness can be further improved when the assembling member 300 is compressed.
  • FIG. 21 is a sectional view showing a membrane humidifier according to a fifth embodiment of the present invention.
  • the membrane humidifier of the fifth embodiment is different from the fourth embodiment in that the cartridge 140 includes an extension rib 145 that supports one side of the assembly member 300.
  • Figs. 18 to 25 show that a plurality of hollow fiber membranes are accommodated in the cartridge 140, and one or a plurality of the cartridges are disposed inside the middle case 110.
  • the extending ribs 145 extend outward from the upper end of the cartridge 140 and are formed to support the lower surface of the assembling member 300. As shown in FIG. The extension ribs 145 may be formed to press and support a part or the entire lower surface of the main body 310 of the assembling member 300.
  • the extended rib 145 may be formed in the shape of a rectangular ring having a predetermined width.
  • the extended rib 145 may be in the form of a circular ring having a predetermined width.
  • the first engaging portion 320 is pressed by the end portion 111 of the middle case 110 when the assembling member 300 is assembled and the second engaging portion 330 is compressed by the potting portion 130, do.
  • the main body 310 of the assembling member 300 is also pressed against the cap casing 120 by the extended ribs 145 so that the assembling member 300 is uniformly pressed uniformly to improve airtightness.
  • FIG. 22 is a sectional view showing a membrane humidifier according to a sixth embodiment of the present invention.
  • the membrane humidifier of the sixth embodiment is different from the fourth embodiment in that there is no second extension portion in the first engagement portion 320.
  • the first engaging portion 320 of the assembling member 300 has the first extending portion 322 extending outwardly from the main body portion 310. However, And does not have a second extending portion extending to be in contact with the side surface.
  • the stepped portion is not formed at the end portion 111 of the middle case 110, but the end portion 111 is formed to have a constant thickness and is assembled to press the first extended portion 322.
  • the protrusion 123 formed on the inner surface of the cap case 120 presses the first extended portion 322 so that the first extended portion 322 is pressed against the end portion 111 of the cap case 120 and the middle case 110 Can be securely and tightly coupled.
  • FIG. 23 is a sectional view showing a membrane humidifier according to a seventh embodiment of the present invention.
  • the membrane humidifier of the seventh embodiment is different from the fourth embodiment in that the second engaging portion 330 of the assembling member 300 and the corner portion of the potting portion 130 are formed with inclined surfaces and contact with each other.
  • An inclined portion 332 is formed on the second engaging portion 330 and an inclined portion 132 is formed on both edges of the upper end of the potting portion 130. 23, since the hardness of the assembling member 300 is larger than the potting part 130, when the inclined part 332 of the second engaging part 330 is assembled to the potting part 130 And the slant portion 132 of the slider 132 is compressed.
  • the inclined part 132 of the potting part 130 presses the inclined part 332 of the second engaging part 330 Will be.
  • the airtight performance can be further improved than in the other embodiments.
  • the inclined portion 332 of the second coupling portion 330 and the inclined portion 132 of the potting portion 130 may be formed simultaneously, but may be formed at only one of them.
  • an inclined portion may be formed on one side of the assembly member 300 and the potting portion 130 having a larger hardness, and the other side having a smaller hardness may be pressed on the inclined portion to form an inclined surface.
  • FIG. 24 is a sectional view showing a membrane humidifier according to an eighth embodiment of the present invention.
  • the membrane humidifier of the eighth embodiment is different from the fourth embodiment in that the assembling member 300 further includes a rib portion 335 extending toward the potting portion 130.
  • the second engaging portion 330 of the assembling member 300 is formed with a rib portion 335 extending inward to be in close contact with one side surface of the potting portion 130.
  • the cross-sectional shape of the rib portion 335 may be a triangular shape having a gradually decreasing thickness toward its end portion.
  • the space defined by the cap case 120, the assembling member 300, and the potting part 130 may have a pressure difference depending on conditions of use of the fuel cell system, This pressure makes the rib portion 335 close to one side of the potting portion 130 so that the space therebetween can be more tightly sealed.
  • the assembly member 300 of the eighth embodiment can have a relatively larger hardness than the assembly member 300 of the fourth embodiment. In other words, the assembly member 300 of the eighth embodiment can further enhance airtightness with the potting portion 130 even if the deformation due to the pressing is small during the assembly due to the rib portion 335.
  • the lower surface of the rib 335 may be formed parallel to the contact surface of the potting part 130. However, the lower surface of the rib part 335 may be inclined at a predetermined angle to the contact surface of the potting part 130 It is possible. When the rib portion 335 is formed to be inclined, the rib portion 335 may be deformed by the potting portion 130 at the time of assembling and may be more closely attached to the potting portion 130.
  • FIG. 25 is a sectional view showing a membrane humidifier according to a ninth embodiment of the present invention.
  • the membrane humidifier of the ninth embodiment is different from the eighth embodiment in that there is no second extending portion in the first fitting portion 320.
  • the assembling member 300 further includes a rib portion 335 extending parallel to one side of the potting portion 130.
  • the assembly member 300 includes the rib portion 335, and the hardness difference between the assembly member 300 and the potting portion 130 can be made smaller than that in the eighth embodiment.
  • the assembly member 300 of the ninth embodiment can further enhance the airtightness with the potting part 130 even if the deformation due to the pressing is small during assembly due to the rib part 335.
  • the first engaging portion 320 of the assembling member 300 has the first extending portion 322 extending outwardly from the main body portion 310. However, And does not have a second extending portion extending to be in contact with the side surface.
  • the stepped portion is not formed at the end portion 111 of the middle case 110, but the end portion 111 is formed to have a constant thickness and is assembled to press the first extended portion 322.
  • the protrusion 123 formed on the inner surface of the cap case 120 presses the first extension 322 to allow the first extension 322 to move between the cap case 120 and the end 111 of the middle case 110 Can be securely and tightly coupled.
  • a membrane humidifier for a fuel cell including an assembling member according to various embodiments of the present invention can perform a hermetic function in a high temperature / high pressure / high humidity environment by a mechanical assembling structure.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
PCT/KR2018/007416 2017-12-29 2018-06-29 연료전지용 막가습기 WO2019132141A1 (ko)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2020535046A JP6990312B2 (ja) 2017-12-29 2018-06-29 燃料電池用膜加湿器
CN201880084788.5A CN111566861B (zh) 2017-12-29 2018-06-29 用于燃料电池的膜加湿器
EP18896418.3A EP3734731A4 (en) 2017-12-29 2018-06-29 MEMBRANE HUMIDIFIER FOR FUEL CELL
US16/958,373 US11539060B2 (en) 2017-12-29 2018-06-29 Membrane humidifier for fuel cell
JP2021194717A JP7311575B2 (ja) 2017-12-29 2021-11-30 燃料電池用膜加湿器

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2017-0184480 2017-12-29
KR1020170184480A KR102240511B1 (ko) 2017-12-29 2017-12-29 연료전지 막가습기
KR1020180065091A KR102263284B1 (ko) 2018-06-05 2018-06-05 연료전지용 막가습기
KR10-2018-0065091 2018-06-05

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EP (1) EP3734731A4 (ja)
JP (2) JP6990312B2 (ja)
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KR102546259B1 (ko) 2020-05-22 2023-06-21 코오롱인더스트리 주식회사 가스켓 조립체 및 이를 포함하는 연료전지 가습기
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JP2022037013A (ja) 2022-03-08
EP3734731A1 (en) 2020-11-04
US20210057767A1 (en) 2021-02-25
JP2021508917A (ja) 2021-03-11
JP7311575B2 (ja) 2023-07-19
EP3734731A4 (en) 2021-08-04
CN111566861B (zh) 2023-07-18
US11539060B2 (en) 2022-12-27
CN111566861A (zh) 2020-08-21
JP6990312B2 (ja) 2022-02-03

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