WO2019081796A3 - Trampa molecular para la captura selectiva de disulfuro de carbono y de otros compuestos tóxicos relacionados - Google Patents

Trampa molecular para la captura selectiva de disulfuro de carbono y de otros compuestos tóxicos relacionados Download PDF

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Publication number
WO2019081796A3
WO2019081796A3 PCT/ES2018/070693 ES2018070693W WO2019081796A3 WO 2019081796 A3 WO2019081796 A3 WO 2019081796A3 ES 2018070693 W ES2018070693 W ES 2018070693W WO 2019081796 A3 WO2019081796 A3 WO 2019081796A3
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WO
WIPO (PCT)
Prior art keywords
carbon disulfide
toxic compounds
selective capture
molecular trap
related toxic
Prior art date
Application number
PCT/ES2018/070693
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English (en)
French (fr)
Other versions
WO2019081796A2 (es
Inventor
Juan CÁMPORA PÉREZ
Pilar PALMA RAMÍREZ
Elena ÁVILA SEGURA
Mercedes LUQUE GARRIDO
Original Assignee
Consejo Superior De Investigaciones Científicas (Csic)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior De Investigaciones Científicas (Csic) filed Critical Consejo Superior De Investigaciones Científicas (Csic)
Publication of WO2019081796A2 publication Critical patent/WO2019081796A2/es
Publication of WO2019081796A3 publication Critical patent/WO2019081796A3/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/70—Compounds containing carbon and sulfur, e.g. thiophosgene
    • C01B32/72—Carbon disulfide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/70—Compounds containing carbon and sulfur, e.g. thiophosgene
    • C01B32/77—Carbon oxysulfide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006—Palladium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Molecular Biology (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biophysics (AREA)

Abstract

Trampa molecular para la captura selectiva de disulfuro de carbono y de otros compuestos tóxicos relacionados que consiste en un complejos de metales pertenecientes a los últimos grupos de los elementos de transición capaces de formar complejos plano-cuadrados, estabilizados por un ligando quelatante que ocupa tres de las posiciones de coordinación del metal, mientras que la cuarta posición de coordinación es ocupada por un ligando pirazolato, o similares que contengan nitrógeno libres y potencialmente donadores.
PCT/ES2018/070693 2017-10-24 2018-10-24 Trampa molecular para la captura selectiva de disulfuro de carbono y de otros compuestos tóxicos relacionados WO2019081796A2 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES201731251A ES2710793B2 (es) 2017-10-24 2017-10-24 Trampa molecular para la captura selectiva de disulfuro de carbono y de otros compuestos toxicos relacionados
ESP201731251 2017-10-24

Publications (2)

Publication Number Publication Date
WO2019081796A2 WO2019081796A2 (es) 2019-05-02
WO2019081796A3 true WO2019081796A3 (es) 2019-06-20

Family

ID=66212833

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/ES2018/070693 WO2019081796A2 (es) 2017-10-24 2018-10-24 Trampa molecular para la captura selectiva de disulfuro de carbono y de otros compuestos tóxicos relacionados

Country Status (2)

Country Link
ES (1) ES2710793B2 (es)
WO (1) WO2019081796A2 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110950340A (zh) * 2019-12-19 2020-04-03 成志福 海绵焦作为新型炭原料用于生产二硫化碳的方法

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
AN, K. & ZHU , J. ET AL.: "Why Does Activation of the Weaker C=S Bond in CS 2 by P/N-Based Frustrated Lewis Pairs Require More Energy Than That of the C=O Bond in CO2? A DFT Study", ORGANOMETALLICS 2014, vol. 33, no. 24, 9 December 2014 (2014-12-09), pages 7141 - 7146, XP055617943, ISSN: 0276-7333 *
ARIKAWA, Y. ET AL.: "Reactivity of a Methoxido-Ruthenium Complex Bearing a Pincer-Type Bis(carbene) Ligand toward Thiocyanate, Carbon Disulfide, and Isothiocyanate", EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 2017, no. 5, 9 December 2016 (2016-12-09), pages 881 - 884, XP055617940, ISSN: 1434-1948, Retrieved from the Internet <URL:http://naosite.lb.nagasaki-u.ac.jp/dspace/handle/10069/37622> [retrieved on 20180907], DOI: 10.1002/ejic.201601324 *
COHEN, R. ET AL.: "Metallacarbenes from Diazoalkanes: An Experimental and Computational Study of the Reaction Mechanism", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 125, no. 21, 1 May 2003 (2003-05-01), pages 6532 - 6546, XP055617946, ISSN: 0002-7863, DOI: 10.1021/ja028923c *
KWAN, M.-L. ET AL.: "2,6-Bis[(2,6-diisopropyl-phosphan-yl)-oxy]-4- fluoro-phenyl-kappa(3)P,C( 1) ,P'} (1 H-pyrazole-KN(2))nickel(II) hexa-fluoro- phosphate", ACTA CRYSTALLOGRAPHICA SECTION E, STRUCTURE REPORTS, 19 September 2012 (2012-09-19), XP055617935, ISSN: 1600-5368, Retrieved from the Internet <URL:https://www.ncbi.nlm.nih.gov/pubmed/23125603> DOI: 10.1107/S1600536812039207 *
SCHMEIER, T.J. ET AL.: "Synthesis of PCP-Supported Nickel Complexes and their Reactivity with Carbon Dioxide", CHEMISTRY: A EUROPEAN JOURNAL, vol. 18, no. 22, 23 April 2012 (2012-04-23), pages 6915 - 6927, XP055617930, ISSN: 1521-3765, DOI: 10.1002/chem.201103992 *
SUIJKERBUIJK, B.M.J.M. ET AL.: "Click'' 1,2,3-triazoles as tunable ligands for late transition metal complexes", DALTON TRANSACTIONS 2007, 22 February 2007 (2007-02-22), pages 1273 - 1276, XP055617926, ISSN: 1477-9234, Retrieved from the Internet <URL:https://pubs.rsc.org/en/results?artrefjournalname=dalton%20trans.&artrefstartpage=1273&artrefvolumeyear=2007&fcategory=journal> [retrieved on 20070222], DOI: 10.1039/B701978P *

Also Published As

Publication number Publication date
ES2710793A1 (es) 2019-04-26
ES2710793B2 (es) 2020-03-19
WO2019081796A2 (es) 2019-05-02

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