SA518390803B1 - تركيبة حفزية جديدة تشمل نيكل ومركب ترابطي من معقد فوسفين من نوع نيكل، واستخدامها في طريقة أوليجومرية أولفين - Google Patents

تركيبة حفزية جديدة تشمل نيكل ومركب ترابطي من معقد فوسفين من نوع نيكل، واستخدامها في طريقة أوليجومرية أولفين

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Publication number
SA518390803B1
SA518390803B1 SA518390803A SA518390803A SA518390803B1 SA 518390803 B1 SA518390803 B1 SA 518390803B1 SA 518390803 A SA518390803 A SA 518390803A SA 518390803 A SA518390803 A SA 518390803A SA 518390803 B1 SA518390803 B1 SA 518390803B1
Authority
SA
Saudi Arabia
Prior art keywords
nickel
catalytic composition
ligand
novel catalytic
complexed
Prior art date
Application number
SA518390803A
Other languages
English (en)
Inventor
بيير-ألاين برويل
اوليفيا شوميه-مارتين
Original Assignee
آي إف بي إنرجيز نوفييل
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by آي إف بي إنرجيز نوفييل filed Critical آي إف بي إنرجيز نوفييل
Publication of SA518390803B1 publication Critical patent/SA518390803B1/ar

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

يتعلق الاختراع بتركيبة حفزية تشمل: مصدر أولي لنيكل واحد على الأقل مع رقم أكسدة oxidation (+II) يحتوي على مركب ترابطي phosphine معقد مع نيكل، قاعدة Lewis واحدة على الأقل، وعامل تنشيط واحد على الأقل ينتقى من المجموعة المتشكلة بمركبات hydrocarbylaluminium برومينية وhydrocarbylaluminium مُكلورة، تُستخدم بمفردها أو كخليط، بطريقة حيث تكون النسبة الجزيئية الجرامية لمجموع قاعدة Lewis والمركب الترابطي phosphine المُعقد مع نيكل من التركيبة إلى النيكل في النطاق 5 إلى 30. يتعلق الاختراع أيضا باستخدام التركيبة الحفزية المذكورة.
SA518390803A 2015-07-29 2018-01-25 تركيبة حفزية جديدة تشمل نيكل ومركب ترابطي من معقد فوسفين من نوع نيكل، واستخدامها في طريقة أوليجومرية أولفين SA518390803B1 (ar)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1557248A FR3039431B1 (fr) 2015-07-29 2015-07-29 Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines
PCT/EP2016/058807 WO2017016688A1 (fr) 2015-07-29 2016-04-20 Nouvelle composition catalytique à base de nickel et d'un ligand de type phosphine complexé au nickel et son utilisation dans un procédé d'oligomérisation des oléfines

Publications (1)

Publication Number Publication Date
SA518390803B1 true SA518390803B1 (ar) 2022-03-06

Family

ID=54186176

Family Applications (1)

Application Number Title Priority Date Filing Date
SA518390803A SA518390803B1 (ar) 2015-07-29 2018-01-25 تركيبة حفزية جديدة تشمل نيكل ومركب ترابطي من معقد فوسفين من نوع نيكل، واستخدامها في طريقة أوليجومرية أولفين

Country Status (6)

Country Link
US (1) US10300473B2 (ar)
CN (1) CN108136382B (ar)
FR (1) FR3039431B1 (ar)
SA (1) SA518390803B1 (ar)
TW (1) TWI727962B (ar)
WO (1) WO2017016688A1 (ar)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3045414B1 (fr) * 2015-12-18 2019-12-27 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines
FR3074065B1 (fr) * 2017-11-30 2019-12-13 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel, d’un phosphonium et son utilisation pour l’oligomerisation des olefines
FR3082759A1 (fr) * 2018-06-22 2019-12-27 IFP Energies Nouvelles Composition catalytique a base de nickel et d'un reducteur organique

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU51826A1 (ar) * 1965-09-06 1966-10-26
FR1588162A (ar) 1966-04-14 1970-04-10
DE1568729A1 (de) * 1966-12-09 1970-03-26 Gelsenberg Benzin Ag Katalysator fuer die Oligomerisation von Olefinen und Polymerisation von 1,3-Diolefinen
US3485881A (en) * 1967-10-09 1969-12-23 Phillips Petroleum Co Dimerization of olefins
US3485892A (en) * 1967-11-22 1969-12-23 Sun Oil Co Catalyst system and process for polymerization of olefins
US4176086A (en) 1977-08-25 1979-11-27 Phillips Petroleum Company Catalyst preparation
US4242531A (en) 1978-08-14 1980-12-30 Phillips Petroleum Company Olefin dimerization
US5237118A (en) 1992-08-21 1993-08-17 Phillips Petroleum Company Ethylene oligomerization
EP0646413B1 (fr) * 1993-09-22 2000-03-01 Institut Français du Pétrole Nouvelle composition contenant du nickel pour la catalyse et procédé de dimérisation et d'oligomérisation des oléfines
DE10303931B4 (de) 2002-02-04 2013-04-18 Institut Français du Pétrole Katalytische Zusammensetzung zur Dimerisierung, Co-Dimerisierung, Oligomerisierung und Polymerisation der Olefine
CN1204155C (zh) * 2002-09-03 2005-06-01 中国石油化工股份有限公司 用于烯烃聚合催化剂的配体及其过渡金属配合物
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
FR2895406B1 (fr) 2005-12-22 2010-08-13 Inst Francais Du Petrole Procede pour la fabrication de 2,3-dimethylbut-1-ene
KR101860969B1 (ko) * 2010-12-31 2018-05-24 가부시키가이샤 브리지스톤 니켈-기재 촉매시스템을 이용한 공액 디엔의 벌크중합

Also Published As

Publication number Publication date
FR3039431B1 (fr) 2019-05-31
US10300473B2 (en) 2019-05-28
CN108136382A (zh) 2018-06-08
WO2017016688A1 (fr) 2017-02-02
US20180221861A1 (en) 2018-08-09
FR3039431A1 (fr) 2017-02-03
TW201709982A (zh) 2017-03-16
TWI727962B (zh) 2021-05-21
CN108136382B (zh) 2021-06-15

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