WO2019015353A1 - Film layer patterning method, and array substrate and fabrication method therefor - Google Patents

Film layer patterning method, and array substrate and fabrication method therefor Download PDF

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Publication number
WO2019015353A1
WO2019015353A1 PCT/CN2018/080465 CN2018080465W WO2019015353A1 WO 2019015353 A1 WO2019015353 A1 WO 2019015353A1 CN 2018080465 W CN2018080465 W CN 2018080465W WO 2019015353 A1 WO2019015353 A1 WO 2019015353A1
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WIPO (PCT)
Prior art keywords
film layer
photoresist
region
post
patterning method
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PCT/CN2018/080465
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French (fr)
Chinese (zh)
Inventor
汪军
袁广才
王东方
方冲
李广耀
Original Assignee
京东方科技集团股份有限公司
合肥鑫晟光电科技有限公司
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Priority to US16/094,421 priority Critical patent/US11307498B2/en
Publication of WO2019015353A1 publication Critical patent/WO2019015353A1/en

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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/039Macromolecular compounds which are photodegradable, e.g. positive electron resists
    • G03F7/0392Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/40Treatment after imagewise removal, e.g. baking
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/0271Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
    • H01L21/0273Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers characterised by the treatment of photoresist layers
    • H01L21/0274Photolithographic processes
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/022Quinonediazides
    • G03F7/023Macromolecular quinonediazides; Macromolecular additives, e.g. binders
    • G03F7/0233Macromolecular quinonediazides; Macromolecular additives, e.g. binders characterised by the polymeric binders or the macromolecular additives other than the macromolecular quinonediazides
    • G03F7/0236Condensation products of carbonyl compounds and phenolic compounds, e.g. novolak resins
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/039Macromolecular compounds which are photodegradable, e.g. positive electron resists
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body
    • H01L27/1214Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body
    • H01L27/1214Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
    • H01L27/1259Multistep manufacturing methods
    • H01L27/1288Multistep manufacturing methods employing particular masking sequences or specially adapted masks, e.g. half-tone mask

Definitions

  • At least one embodiment of the present disclosure is directed to a film layer patterning method, an array substrate, and a method of fabricating the same.
  • the process of patterning the film layer generally uses the photoresist as a mask to pattern the patterned film layer. Therefore, the precision of the photoresist mask to be formed is to be formed on the film layer. Small size patterns have a big impact.
  • At least one embodiment of the present disclosure provides a film layer patterning method, an array substrate, and a method of fabricating the same.
  • At least one embodiment of the present disclosure provides a film layer patterning method, comprising: coating a photoresist on a film layer to be patterned; exposing and developing the photoresist, and the photoresist is exposed and developed; The corresponding region of the completely removed portion is the first region; after the photoresist is post-baked, the photoresist is melted at a high temperature to change the corresponding region of the completely removed portion to the second region, and the post-baked photoresist Forming a mask pattern; patterning the film layer with the mask pattern as a mask.
  • a minimum dimension of the first region in a direction parallel to a plane of the film layer is a first dimension
  • a minimum dimension of the second region in a direction parallel to a plane of the film layer is a second dimension
  • a second The size is smaller than the first size
  • the photoresist is a positive photoresist.
  • the planar shape of the second region includes at least one or a combination of a circle and a line.
  • the post-baking temperature is from 150 ° C to 300 ° C to cause the photoresist to collapse at a high temperature.
  • the post-baking time is 10 s-500 s during post-baking.
  • the post-bake time is 10 s to 50 s during post-baking.
  • the second dimension is between 1 ⁇ m and 2.9 ⁇ m.
  • the first size is no less than 3 [mu]m.
  • the photoresist has a thickness in a direction perpendicular to the film layer of from 0.5 ⁇ m to 10 ⁇ m.
  • the thickness of the photoresist in a direction perpendicular to the film layer is from 1.5 ⁇ m to 2.2 ⁇ m.
  • the illumination intensity employed during exposure is 10 J/cm 3 -500 J/cm 3 .
  • At least one embodiment of the present disclosure provides a method of fabricating an array substrate, comprising: providing a substrate; forming a film layer to be patterned on the substrate; and using the film layer provided by any of the above embodiments The patterning method is patterned.
  • At least one embodiment of the present disclosure provides an array substrate fabricated by the above-described method of fabricating an array substrate.
  • the array substrate includes a film layer having a film layer pattern having the same planar shape as the second region.
  • FIG. 1 is a schematic flowchart of a film layer patterning method according to an embodiment of the present disclosure
  • FIG. 2A-2D are schematic diagrams showing a manufacturing process of the film layer patterning method illustrated in FIG. 1;
  • 3A is a partial plan view of a film layer provided by an example of an embodiment of the present disclosure.
  • 3B is a partial plan view of a film layer provided by another example of an embodiment of the present disclosure.
  • FIG. 4 is a schematic flow chart of a method for fabricating an array substrate according to an embodiment of the present disclosure.
  • the inventors of the present application found that the critical dimension (DICD) required to develop the openings in the photoresist mask is very high in the fabrication process of the array substrate.
  • Exposure equipment used to make small-sized aperture patterns in photoresist masks generally has a limit accuracy. If it is necessary to prepare apertures below the limit accuracy, the normal mask method cannot meet the requirements, and a higher precision exposure can be purchased. Equipment and the preparation of high-precision masks can greatly increase production costs.
  • Embodiments of the present disclosure provide a film layer patterning method, an array substrate, and a method of fabricating the same.
  • the film layering method comprises: coating a photoresist on the film layer to be patterned; exposing and developing the photoresist; the corresponding portion of the portion where the photoresist is completely removed after exposure and development is the first a region; after the photoresist is post-baked, the photoresist is melted at a high temperature to change a corresponding portion of the completely removed portion to a second region, and a post-baking photoresist is used to form a mask pattern; The mask patterns the film layer.
  • the film layering method utilizes the characteristics of high-temperature collapse of the hot-melt photoresist after development and post-baking, and provides a possibility to form a small-sized pattern below the exposure machine precision of the film layer to be patterned, and the method is simple in process. ,low cost.
  • FIG. 1 is a schematic flowchart of a film layer patterning method according to an embodiment of the present disclosure
  • FIGS. 2A-2D are a film layer patterning method illustrated in FIG. Schematic diagram of the production process.
  • the steps and manufacturing process of the film layer patterning method provided by an embodiment of the present disclosure include:
  • the film layer 110 to be patterned may be formed on the base substrate 100 by deposition or magnetron sputtering or the like.
  • Fig. 2A is a schematic view, for example, a film layer may not be disposed on a base substrate.
  • the base substrate 100 may be made of glass, polyimide, polycarbonate, polyacrylate, polyetherimide, polyethersulfone, polyethylene terephthalate, and polyethylene naphthalate. Made of one or more materials in the ester, this embodiment includes but is not limited thereto.
  • the film layer 110 may be an insulating layer.
  • the film layer 110 may be a gate insulating layer, an interlayer insulating layer, a passivation layer, or an etch barrier layer, and the like, which is not limited in this embodiment.
  • the film layer 110 may include an inorganic material such as an oxide, a sulfide, or a nitride, which is not limited in this embodiment.
  • the oxide may include calcium oxide, zinc oxide, copper oxide, titanium dioxide, tin dioxide, etc.
  • the sulfide may include iron sulfide, copper sulfide, zinc sulfide, tin disulfide, sulfur dioxide, etc.
  • the nitride may include silicon nitride, Aluminum nitride, etc., this embodiment includes but is not limited thereto.
  • the film layer 110 may also be an organic material, and may include, for example, one or a combination of polyimide, polyamide, polycarbonate, epoxy resin, etc., and the embodiment is not limited thereto.
  • the film layer 110 may also be a metal layer.
  • the material of the film layer 110 may be one or more selected from the group consisting of aluminum, silver, molybdenum, titanium, platinum, gold, chromium, etc., which is not limited in this embodiment.
  • the film layer 110 may also be another film layer.
  • applying a photoresist on the film layer 110 to be patterned includes: applying a thin, uniform, and defect-free photoresist layer on the film layer 110 by spin coating. 120, the embodiment is not limited thereto, and other coating methods may also be employed.
  • the coating temperature of the photoresist is generally the same as the room temperature to minimize the temperature fluctuation of the photoresist, thereby reducing process fluctuations.
  • S102 exposing and developing the photoresist, and the corresponding region of the portion where the photoresist is completely removed after exposure and development is the first region.
  • a mask (not shown) is overlaid on the photoresist layer 120, and the photoresist layer 120 covered with the mask is exposed.
  • the photoresist layer 120 may be irradiated with an electron beam, an ion beam, an X-ray, an ultraviolet ray, or the like.
  • the embodiment is not limited thereto.
  • the ultraviolet ray may be an ordinary ultraviolet ray having a wavelength range of 200 nm to 400 nm, or may have a wavelength.
  • the extreme ultraviolet rays in the range of 10 nm to 14 nm are not limited in this embodiment.
  • the photoresist layer 120 is exposed by ultraviolet light to expose the photoresist layer 120 as an example.
  • the photoresist layer 120 uses an illumination intensity of 10 J/cm 3 during exposure. -500J/cm 3 .
  • 120 employed in the light intensity during exposure of the photoresist layer may be 50J / cm 3 -80J / cm 3 to cause sufficient exposure of the photoresist layer 120, the present embodiment is not limited thereto.
  • 120 employed in the light intensity during exposure of the photoresist layer may also be 80J / cm 3 -200J / cm 3 , 250J / cm 3 -500J / cm 3 or 10J / cm 3 -40J / cm 3 and the like,
  • the intensity of the light in the actual process may depend on the thickness of the photoresist layer 120.
  • the photoresist is composed of a resin, a sensitizer, a solvent, and an additive.
  • the photoresist layer 120 is pre-baked, and the solvent in the photoresist layer 120 is sufficiently evaporated to dry the photoresist layer 120.
  • the pre-baking temperature can be set to about 90 ° C - 120 ° C, and the embodiment is not limited thereto, but the pre-baking temperature cannot be too high to prevent the high-temperature collapse of the photoresist layer 120. Therefore, in the embodiment, The pre-bake temperature does not exceed 140 °C.
  • the pre-baked photoresist layer 120 can be more strongly bonded to the film layer 110.
  • a positive photoresist can be pre-baked in air, while a negative photoresist needs to be pre-baked in a nitrogen atmosphere.
  • the photoresist layer 120 provided in this embodiment includes a photoresist which is a positive photoresist, and the positive photoresist includes, for example, a novolac resin.
  • the novolac resin dissolves in the photoresist.
  • the sensitizer in the positive photoresist includes a photoactive compound (PAC).
  • the photosensitive compound may include diazonaphthoquinone (DNQ) or the like, which is not limited in this embodiment. Prior to exposure, diazonaphthoquinone is a strong dissolution inhibitor that reduces the rate of dissolution of the resin.
  • a photosensitive compound such as diazonaphthoquinone is chemically decomposed by a photochemical reaction in a positive photoresist to cut off the relationship between the main chain of the resin polymer and the chain, thereby weakening the polymer.
  • the purpose is to become a solubility enhancer.
  • the diazonaphthoquinone produces carboxylic acid in this exposure reaction, and its solubility in the developer is high, so the solubility of the exposed photoresist after the subsequent development treatment is increased, and the positive photoresist after exposure is exposed.
  • the dissolution rate is almost 10 times that of the unexposed photoresist.
  • the positive photoresist layer 120 on the exposed region is completely removed to form a blank region (first region 121), and the photoresist on the unexposed region Layer 120 remains on film layer 110 as a subsequent protective film layer, and the pattern replicated onto the surface of film layer 110 is the same as the pattern on the mask layer on photoresist layer 120.
  • the time for developing the photoresist layer 120 in this embodiment may be 10s-500s, and the embodiment includes but is not limited thereto.
  • the developer provided in this embodiment may be a medium-sized alkali solution.
  • the developer may include potassium hydroxide, tetramethylammonium hydroxide, ketone or acetazolamide, and the like, which is not limited in this embodiment.
  • a portion corresponding to a portion of the photoresist layer 120 that is completely removed after exposure and development is a first region 121, which is a positive photoresist on the exposed region.
  • the layer 120 is removed by the developer to remove the blank area left behind.
  • the minimum dimension of the first region 121 in a direction parallel to the plane of the film layer 110 is the first dimension L1.
  • the minimum dimension L1 of the planar pattern of the first region 121 is taken as an example of the minimum dimension L1 of the first region 121 and the contact surface of the film layer 110.
  • the first size L1 is not less than 3 ⁇ m. It should be noted that the size of the first size L1 is also not too large, generally on the order of micrometers. For example, the first size L1 may be 6-10 ⁇ m, and the embodiment includes but is not limited thereto.
  • the shape of the orthographic projection of the plane of the first region 121 having the first dimension L1 on the film layer 110 may include at least one or a combination of a circle and a line, etc., that is, the plane pattern of the first region 121 may include a circle. At least one or a combination of the lines and the like, the embodiment includes but is not limited thereto.
  • the photoresist coated on the patterned film layer is a hot-melt photoresist
  • the heat-resistant composition of the hot-melt photoresist is lower than that of the conventional photoresist, so that the post-baking is performed. High temperature collapse occurs, but does not affect the performance of the photoresist.
  • the photoresist layer 120 having the first region 121 is post-baked, and the post-baking process is performed at a temperature of 150 ° C to 300 ° C to cause the photoresist layer 120 to collapse at a high temperature. That is, the photoresist layer 120 located around the first region 121 is collapsed during post-baking to cause one side of the contact film layer 110 of the photoresist layer 120 to be gathered toward the first region 121, and the photoresist layer 120 is away from the photoresist layer 120. One side of the film layer 110 collapses and collapses. Therefore, the photoresist around the first region 121 flows into the first region 121 after being melted at a high temperature to change the region corresponding to the completely removed photoresist portion. Two areas 122.
  • the photoresist layer 120 having the first region 121 is post-baked, and the temperature used in the post-baking process may be 150 ° C - 200 ° C, or 250 ° C - 300 ° C, etc., which is not limited in this embodiment.
  • the minimum dimension of the second region 122 in a direction parallel to the plane of the film layer 110 is the second dimension L2, that is, the smallest dimension of the side where the second region 122 is in contact with the film layer 110 is
  • the second size L2 is smaller than the first size L1.
  • the second region 122 has a second dimension L2 of 1 ⁇ m to 2.9 ⁇ m which is smaller than the first dimension L1 of the first region 121 shown in FIG. 2B.
  • the second size 122 of the second region 122 may be 1 ⁇ m to 2.5 ⁇ m, or may be 1.5 ⁇ m to 2 ⁇ m, which is not limited in this embodiment.
  • the shape of the plane of the second region 122 having the second dimension L2 may include at least one or a combination of a circle and a line, etc., that is, the planar shape of the second region 122 may include at least one or a combination of a circle and a line. Wait.
  • the circular shape here is approximately circular, and for example, the shape of the plane of the second region 122 having the second dimension L2 may also be an ellipse or the like.
  • the photoresist layer 120 has a thickness in the direction perpendicular to the film layer 110, that is, in the X direction of 0.5 ⁇ m to 10 ⁇ m.
  • the thickness of the photoresist layer 120 in a direction perpendicular to the film layer 110 may be 1.5 ⁇ m - 2.2 ⁇ m to cause the photoresist layer 120 to collapse around the first region 121 of the first region 121.
  • a second region 122 having a desired second dimension L2 is then formed.
  • the thickness of the photoresist layer 120 in the X direction may be 3 ⁇ m to 5 ⁇ m, or the thickness of the photoresist layer 120 in the X direction may be 7 ⁇ m to 10 ⁇ m, which is not limited in this embodiment.
  • the time for post-baking the photoresist layer 120 in this embodiment is 10 s to 500 s.
  • the photoresist layer 120 is post-baked for 10 s to 50 s to cause the photoresist layer 120 around the first region 121 to collapse and collapse to form a second region 122 having a desired second dimension L2.
  • the time for the post-baking of the photoresist layer 120 in this embodiment may be 100s-200s or 300s-500s, which is not limited in this embodiment.
  • an example of the present embodiment is described by taking an example of patterning the film layer 110 to form an opening pattern, which is used for exposure before the pattern having a hole diameter of 1 ⁇ m to 2.9 ⁇ m is formed on the film layer 110 in this embodiment.
  • the limit accuracy of the exposure machine of the photoresist layer 120 is generally 3 ⁇ m
  • the partial step of forming the photoresist layer 120 having the second region 122 includes using a mask having a pore size of 5 ⁇ m as a thickness of 0.5 ⁇ m to 10 ⁇ m (for example, a mask of the photoresist layer 120 having a thickness of 1.5 ⁇ m to 2.2 ⁇ m, and exposing the photoresist layer 120, and the light intensity during the exposure may be 10 J/cm 3 to 500 J/cm 3 , for example, exposure.
  • the light intensity during the process can be selected from 50 J/cm 3 to 80 J/cm 3 .
  • the photoresist layer 120 is developed, and the time during the development may be selected from 10 s to 500 s.
  • the developed photoresist layer 120 is post-baked, and the temperature during the post-baking process may be 150 ° C - 300 ° C, and the post-baking time may be 10 s - 500 s.
  • the post-baking time is 10 s - 50 s.
  • a second region 122 having a second dimension L2 of 1 ⁇ m to 2.9 ⁇ m is formed on the photoresist layer 120.
  • the film layer patterning method utilizes the characteristics of high temperature collapse of the hot melt photoresist after development and post-baking, and provides a possibility to form a small-sized pattern below the exposure machine precision of the film layer to be patterned, and the method The process is simple and the cost is low.
  • the film layer 110 is patterned using the photoresist layer 120 having the second region 122 as a mask to form a small-sized pattern 111/112.
  • patterning the film layer 110 may form the opening 111 having the second dimension L2, that is, the opening 111 has a diameter of 1 ⁇ m to 2.9 ⁇ m.
  • This embodiment includes but is not limited thereto.
  • patterning the film layer 110 may also form a line shape 112 having a minimum size of the second dimension L2, that is, a short side dimension of the line shape 112 (a side length extending in the Y direction) is 1 ⁇ m - 2.9 ⁇ m, and this embodiment includes Not limited to this.
  • FIGS. 2A-2D schematically illustrate the formation of a small-sized pattern 111/112. The embodiment is not limited thereto, and may also be a plurality of small-sized patterns 111/112.
  • FIG. 3A is a partial plan view of a film layer provided by an example of an embodiment of the present disclosure
  • FIG. 3B is a partial plan view of a film layer provided by another example of an embodiment of the present disclosure.
  • the pattern formed on the film layer 110 using the mask pattern having the second region 122 as a mask is an opening 111.
  • planar shape of the opening 111 in the YZ plane may be a standard circular shape or an approximately circular shape, and the embodiment includes but is not limited thereto.
  • the planar shape of the opening 111 in the YZ plane may also be an irregular shape or the like.
  • FIG. 3A schematically shows an opening 111.
  • the embodiment is not limited thereto, and may also be a plurality of openings 111.
  • the source and the drain for connecting the thin film transistor can be formed by using the photoresist layer 120 having the second region 122, that is, the mask pattern as a mask.
  • the contact hole of the pole and the active layer ie, the opening 111).
  • the thin film transistor here is of a top gate type.
  • a contact hole for connecting the source and the drain of the thin film transistor to the active layer may be formed by using the photoresist layer 120 having the second region 122 as a mask (ie, opening) Hole 111).
  • a via hole ie, an opening 111 is formed by using the photoresist layer 120 having the second region 122 as a mask to expose the drain and common electrode lines of the thin film transistor, and the exposed drain
  • the pole electrode may be electrically connected to the subsequently formed pixel electrode through the via hole
  • the exposed common electrode line may be electrically connected to the subsequently formed common electrode through the via hole, and the embodiment includes but is not limited thereto.
  • the film layer 110 may also be other insulating layers or metal layers, etc., which is not limited in this embodiment.
  • the planar pattern formed on the film layer 110 by using the photoresist layer 120 having the second region 122 as a mask may also be a line shape 112, that is, a trench or the like may be formed on the film layer 110.
  • FIG. 3B schematically shows a line shape 112. The embodiment is not limited thereto, and may also be a plurality of line shapes 112.
  • FIG. 4 is a schematic flow chart of a method for fabricating an array substrate according to an embodiment of the present disclosure. As shown in FIG.
  • the base substrate may be made of glass, polyimide, polycarbonate, polyacrylate, polyetherimide, polyethersulfone, polyethylene terephthalate, and polyethylene naphthalate.
  • One or more materials are made, and the embodiment includes but is not limited thereto.
  • a film layer to be patterned may be formed on a base substrate by deposition or magnetron sputtering or the like.
  • the film layer may be an insulating layer.
  • the film layer may be a gate insulating layer, an interlayer insulating layer, a passivation layer or an etch barrier layer, and the like, which is not limited in this embodiment.
  • the film layer may include an inorganic material such as a metal oxide, a metal sulfide, or a metal nitride, which is not limited in this embodiment.
  • the film layer may also be an organic material, and may include, for example, one or a combination of polyimide, polyamide, polycarbonate, epoxy resin, etc., and the embodiment is not limited thereto.
  • the film layer may also be a metal layer.
  • the material of the film layer may be one or more of materials such as aluminum, silver, molybdenum, titanium, platinum, gold, chromium, etc., which is not limited in this embodiment, for example.
  • the film layer may also be other film layers.
  • the film layer is patterned by any of the film layer patterning methods provided in the above embodiments, and the specific patterning step and the shape and size of the obtained small-sized pattern after patterning the film layer are not Let me repeat.
  • the method for fabricating the array substrate utilizes the characteristics of high-temperature collapse of the hot-melt photoresist after development and post-baking, and provides a possibility to form a small-sized pattern below the exposure machine precision of the film layer to be patterned, and the method is simple. ,low cost.
  • An embodiment of the present disclosure provides an array substrate fabricated by the method for fabricating the array substrate provided in the above embodiments.
  • the array substrate includes a film layer having a film layer pattern substantially the same as a planar shape of the second region of the photoresist layer, and the film layer pattern has a minimum dimension in a direction parallel to the plane of the film layer.
  • the second dimension that is, the smallest dimension of the second region in a direction parallel to the plane of the film layer.
  • the minimum dimension of the film pattern in a direction parallel to the plane of the film layer is from 1 ⁇ m to 2.9 ⁇ m.
  • the minimum dimension of the film pattern in a direction parallel to the plane of the film layer may be from 1 ⁇ m to 2.5 ⁇ m, or may also be from 1.5 ⁇ m to 2 ⁇ m, which is not limited in this embodiment.
  • the array substrate can be applied to display devices such as liquid crystal display devices, organic light-emitting diode (OLED) display devices, and televisions, digital cameras, mobile phones, watches, tablets, and notebook computers including the display devices.
  • display devices such as liquid crystal display devices, organic light-emitting diode (OLED) display devices, and televisions, digital cameras, mobile phones, watches, tablets, and notebook computers including the display devices.
  • OLED organic light-emitting diode
  • the present embodiment is not limited to any product or component having a display function such as a navigator.

Abstract

A film layer patterning method, and an array substrate and a fabrication method therefor. The film layer patterning method comprises: applying a photoresist (120) on a film layer (110) to be patterned; exposing and developing the photoresist (120), a region corresponding to a portion of the photoresist (120) that is completely removed after the exposure and development being a first region (121); post-baking the photoresist (120), the photoresist (120) being melted and collapsed at a high temperature to transform the region corresponding to the completely removed portion into a second region (122), and a mask pattern being formed on the post-baked photoresist (120); and patterning the film layer (110) by using the mask pattern as a mask.

Description

膜层图案化方法、阵列基板及其制作方法Film layer patterning method, array substrate and manufacturing method thereof
相关申请的交叉引用Cross-reference to related applications
本申请要求于2017年7月18日递交的中国专利申请第201710585224.7号的优先权,在此全文引用上述中国专利申请公开的内容以作为本申请的一部分。The present application claims priority to Chinese Patent Application No. JP-A No. No. No. No. No. No. No. No. No. No.
技术领域Technical field
本公开至少一个实施例涉及一种膜层图案化方法、阵列基板及其制作方法。At least one embodiment of the present disclosure is directed to a film layer patterning method, an array substrate, and a method of fabricating the same.
背景技术Background technique
在阵列基板的制作工艺中,图案化膜层的过程一般采用光刻胶作为掩模对待图案化的膜层进行图案化,因此,制作的光刻胶掩模的精度对于膜层上待形成的小尺寸图案具有很大影响。In the fabrication process of the array substrate, the process of patterning the film layer generally uses the photoresist as a mask to pattern the patterned film layer. Therefore, the precision of the photoresist mask to be formed is to be formed on the film layer. Small size patterns have a big impact.
发明内容Summary of the invention
本公开的至少一实施例提供一种膜层图案化方法、阵列基板及其制作方法。At least one embodiment of the present disclosure provides a film layer patterning method, an array substrate, and a method of fabricating the same.
本公开的至少一实施例提供一种膜层图案化方法,包括:在待图案化的膜层上涂敷光刻胶;对光刻胶进行曝光以及显影,光刻胶经过曝光以及显影后被完全去除的部分对应的区域为第一区域;对光刻胶进行后烘,光刻胶发生高温融塌以使被完全去除的部分对应的区域变化为第二区域,经过后烘的光刻胶形成掩膜图案;以掩膜图案为掩模对膜层进行图案化。At least one embodiment of the present disclosure provides a film layer patterning method, comprising: coating a photoresist on a film layer to be patterned; exposing and developing the photoresist, and the photoresist is exposed and developed; The corresponding region of the completely removed portion is the first region; after the photoresist is post-baked, the photoresist is melted at a high temperature to change the corresponding region of the completely removed portion to the second region, and the post-baked photoresist Forming a mask pattern; patterning the film layer with the mask pattern as a mask.
例如,在一些示例中,第一区域沿平行于膜层所在平面的方向的最小尺寸为第一尺寸,第二区域沿平行于膜层所在平面的方向的最小尺寸为第二尺寸,且第二尺寸小于第一尺寸。For example, in some examples, a minimum dimension of the first region in a direction parallel to a plane of the film layer is a first dimension, a minimum dimension of the second region in a direction parallel to a plane of the film layer is a second dimension, and a second The size is smaller than the first size.
例如,在一些示例中,光刻胶为正性光刻胶。For example, in some examples, the photoresist is a positive photoresist.
例如,在一些示例中,第二区域的平面形状包括圆形和线形的至少之一或组合。For example, in some examples, the planar shape of the second region includes at least one or a combination of a circle and a line.
例如,在一些示例中,在后烘的过程中,后烘温度为150℃-300℃以使 光刻胶发生高温融塌。For example, in some examples, during the post-baking process, the post-baking temperature is from 150 ° C to 300 ° C to cause the photoresist to collapse at a high temperature.
例如,在一些示例中,在后烘的过程中,后烘时间为10s-500s。For example, in some examples, the post-baking time is 10 s-500 s during post-baking.
例如,在一些示例中,在后烘的过程中,后烘时间为10s-50s。For example, in some examples, the post-bake time is 10 s to 50 s during post-baking.
例如,在一些示例中,第二尺寸为1μm-2.9μm。For example, in some examples, the second dimension is between 1 μm and 2.9 μm.
例如,在一些示例中,第一尺寸不小于3μm。For example, in some examples, the first size is no less than 3 [mu]m.
例如,在一些示例中,光刻胶沿垂直于膜层方向的厚度为0.5μm-10μm。For example, in some examples, the photoresist has a thickness in a direction perpendicular to the film layer of from 0.5 μm to 10 μm.
例如,在一些示例中,光刻胶沿垂直于膜层方向的厚度为1.5μm-2.2μm。For example, in some examples, the thickness of the photoresist in a direction perpendicular to the film layer is from 1.5 μm to 2.2 μm.
例如,在一些示例中,在曝光的过程中采用的光照强度为10J/cm 3-500J/cm 3For example, in some examples, the illumination intensity employed during exposure is 10 J/cm 3 -500 J/cm 3 .
本公开的至少一实施例提供一种阵列基板的制作方法,包括:提供衬底基板;在衬底基板上形成待图案化的膜层;对膜层利用上述任一项实施例提供的膜层图案化方法进行图案化。At least one embodiment of the present disclosure provides a method of fabricating an array substrate, comprising: providing a substrate; forming a film layer to be patterned on the substrate; and using the film layer provided by any of the above embodiments The patterning method is patterned.
本公开的至少一实施例提供一种阵列基板,利用上述的阵列基板的制作方法制作而成。At least one embodiment of the present disclosure provides an array substrate fabricated by the above-described method of fabricating an array substrate.
例如,在一些示例中,阵列基板包括的膜层的表面上具有与第二区域的平面形状相同的膜层图案。For example, in some examples, the array substrate includes a film layer having a film layer pattern having the same planar shape as the second region.
附图说明DRAWINGS
为了更清楚地说明本公开实施例的技术方案,下面将对实施例的附图作简单地介绍,显而易见地,下面描述中的附图仅仅涉及本公开的一些实施例,而非对本公开的限制。In order to more clearly illustrate the technical solutions of the embodiments of the present disclosure, the drawings of the embodiments will be briefly described below. It is obvious that the drawings in the following description relate only to some embodiments of the present disclosure, and are not to limit the disclosure. .
图1为本公开一实施例提供的膜层图案化方法的示意性流程图;FIG. 1 is a schematic flowchart of a film layer patterning method according to an embodiment of the present disclosure;
图2A-2D为图1示出的膜层图案化方法的制作工艺过程示意图;2A-2D are schematic diagrams showing a manufacturing process of the film layer patterning method illustrated in FIG. 1;
图3A为本公开一实施例的一示例提供的膜层的局部平面示意图;3A is a partial plan view of a film layer provided by an example of an embodiment of the present disclosure;
图3B为本公开一实施例的另一示例提供的膜层的局部平面示意图;3B is a partial plan view of a film layer provided by another example of an embodiment of the present disclosure;
图4为本公开一实施例提供的阵列基板的制作方法的流程示意图。FIG. 4 is a schematic flow chart of a method for fabricating an array substrate according to an embodiment of the present disclosure.
具体实施方式Detailed ways
为使本公开实施例的目的、技术方案和优点更加清楚,下面将结合本公开实施例的附图,对本公开实施例的技术方案进行清楚、完整地描述。显然,所描述的实施例是本公开的一部分实施例,而不是全部的实施例。基于所描述的 本公开的实施例,本领域普通技术人员在无需创造性劳动的前提下所获得的所有其他实施例,都属于本公开保护的范围。The technical solutions of the embodiments of the present disclosure will be clearly and completely described below in conjunction with the drawings of the embodiments of the present disclosure. It is apparent that the described embodiments are part of the embodiments of the present disclosure, and not all of the embodiments. All other embodiments obtained by a person of ordinary skill in the art based on the described embodiments of the present disclosure without departing from the scope of the invention are intended to be within the scope of the disclosure.
除非另外定义,本公开使用的技术术语或者科学术语应当为本公开所属领域内具有一般技能的人士所理解的通常意义。本公开中使用的“第一”、“第二”以及类似的词语并不表示任何顺序、数量或者重要性,而只是用来区分不同的组成部分。“包括”或者“包含”等类似的词语意指出现该词前面的元件或者物件涵盖出现在该词后面列举的元件或者物件及其等同,而不排除其他元件或者物件。“上”、“下”、“左”、“右”等仅用于表示相对位置关系,当被描述对象的绝对位置改变后,则该相对位置关系也可能相应地改变。Unless otherwise defined, technical terms or scientific terms used in the present disclosure are intended to be understood in the ordinary meaning of the ordinary skill of the art. The words "first," "second," and similar terms used in the present disclosure do not denote any order, quantity, or importance, but are used to distinguish different components. The word "comprising" or "comprises" or the like means that the element or item preceding the word is intended to be in the "Upper", "lower", "left", "right", etc. are only used to indicate the relative positional relationship, and when the absolute position of the object to be described is changed, the relative positional relationship may also change accordingly.
在研究中,本申请的发明人发现:在阵列基板的制作工艺中,对光刻胶掩模中的开孔进行显影的关键尺寸(DICD)要求非常高。用于制作光刻胶掩模中的小尺寸开孔图案的曝光设备一般都有一个极限精度,若需要制备极限精度以下的开孔,正常掩模方式无法满足要求,而购置更高精度的曝光设备,并制备高精度的掩模会大大增加生产成本。In the study, the inventors of the present application found that the critical dimension (DICD) required to develop the openings in the photoresist mask is very high in the fabrication process of the array substrate. Exposure equipment used to make small-sized aperture patterns in photoresist masks generally has a limit accuracy. If it is necessary to prepare apertures below the limit accuracy, the normal mask method cannot meet the requirements, and a higher precision exposure can be purchased. Equipment and the preparation of high-precision masks can greatly increase production costs.
本公开的实施例提供一种膜层图案化方法、阵列基板及其制作方法。该膜层图案化方法包括:在待图案化的膜层上涂敷光刻胶;对光刻胶进行曝光以及显影,光刻胶经过曝光以及显影后被完全去除的部分对应的区域为第一区域;对光刻胶进行后烘,光刻胶发生高温融塌以使被完全去除的部分对应的区域变化为第二区域,经过后烘的光刻胶形成掩膜图案;以掩膜图案为掩模对膜层进行图案化。该膜层图案化方法利用热融性光刻胶在显影和后烘后发生高温融塌的特点,为待图案化的膜层形成曝光机精度以下的小尺寸图案提供可能,并且该方法工艺简单、成本低。Embodiments of the present disclosure provide a film layer patterning method, an array substrate, and a method of fabricating the same. The film layering method comprises: coating a photoresist on the film layer to be patterned; exposing and developing the photoresist; the corresponding portion of the portion where the photoresist is completely removed after exposure and development is the first a region; after the photoresist is post-baked, the photoresist is melted at a high temperature to change a corresponding portion of the completely removed portion to a second region, and a post-baking photoresist is used to form a mask pattern; The mask patterns the film layer. The film layering method utilizes the characteristics of high-temperature collapse of the hot-melt photoresist after development and post-baking, and provides a possibility to form a small-sized pattern below the exposure machine precision of the film layer to be patterned, and the method is simple in process. ,low cost.
下面结合附图对本公开实施例提供的膜层图案化方法、阵列基板及其制作方法进行描述。The film layer patterning method, the array substrate and the manufacturing method thereof provided by the embodiments of the present disclosure are described below with reference to the accompanying drawings.
本公开一实施例提供一种膜层图案化方法,图1为本公开一实施例提供的膜层图案化方法的示意性流程图,图2A-2D为图1示出的膜层图案化方法的制作工艺过程示意图。如图1和图2A-2D所示,本公开一实施例提供的膜层图案化方法的步骤及制作工艺过程包括:An embodiment of the present disclosure provides a film layer patterning method, FIG. 1 is a schematic flowchart of a film layer patterning method according to an embodiment of the present disclosure, and FIGS. 2A-2D are a film layer patterning method illustrated in FIG. Schematic diagram of the production process. As shown in FIG. 1 and FIG. 2A-2D, the steps and manufacturing process of the film layer patterning method provided by an embodiment of the present disclosure include:
S101:在待图案化的膜层上涂敷光刻胶。S101: Applying a photoresist on the film layer to be patterned.
例如,如图2A所示,在衬底基板100上可以通过沉积或者磁控溅射等方法形成待图案化的膜层110。图2A为示意性视图,例如,膜层也可以不设置 在衬底基板上。For example, as shown in FIG. 2A, the film layer 110 to be patterned may be formed on the base substrate 100 by deposition or magnetron sputtering or the like. Fig. 2A is a schematic view, for example, a film layer may not be disposed on a base substrate.
例如,衬底基板100可以由玻璃、聚酰亚胺、聚碳酸酯、聚丙烯酸酯、聚醚酰亚胺、聚醚砜、聚对苯二甲酸乙二醇酯和聚萘二甲酸乙二醇酯中的一种或多种材料制成,本实施例包括但不限于此。For example, the base substrate 100 may be made of glass, polyimide, polycarbonate, polyacrylate, polyetherimide, polyethersulfone, polyethylene terephthalate, and polyethylene naphthalate. Made of one or more materials in the ester, this embodiment includes but is not limited thereto.
例如,膜层110可以为绝缘层,例如,膜层110可以为栅绝缘层、层间绝缘层、钝化层或者刻蚀阻挡层等,本实施例对此不作限制。For example, the film layer 110 may be an insulating layer. For example, the film layer 110 may be a gate insulating layer, an interlayer insulating layer, a passivation layer, or an etch barrier layer, and the like, which is not limited in this embodiment.
例如,膜层110可以包括氧化物、硫化物或氮化物等无机材料,本实施对此不作限制。For example, the film layer 110 may include an inorganic material such as an oxide, a sulfide, or a nitride, which is not limited in this embodiment.
例如,氧化物可以包括氧化钙、氧化锌、氧化铜、二氧化钛、二氧化锡等;硫化物可以包括硫化铁、硫化铜、硫化锌、二硫化锡、二氧化硫等;氮化物可以包括氮化硅、氮化铝等,本实施例包括但不限于此。For example, the oxide may include calcium oxide, zinc oxide, copper oxide, titanium dioxide, tin dioxide, etc.; the sulfide may include iron sulfide, copper sulfide, zinc sulfide, tin disulfide, sulfur dioxide, etc.; the nitride may include silicon nitride, Aluminum nitride, etc., this embodiment includes but is not limited thereto.
例如,膜层110也可以选用有机材料,例如可以包括聚酰亚胺、聚酰胺、聚碳酸酯、环氧树脂等中的一种或几种的组合等,本实施例不限于此。For example, the film layer 110 may also be an organic material, and may include, for example, one or a combination of polyimide, polyamide, polycarbonate, epoxy resin, etc., and the embodiment is not limited thereto.
例如,膜层110还可以为金属层,例如,膜层110的材料可以选用铝、银、钼、钛、铂、金、铬等材料中的一种或几种,本实施例对此不作限制,膜层110也可以是其他膜层。For example, the film layer 110 may also be a metal layer. For example, the material of the film layer 110 may be one or more selected from the group consisting of aluminum, silver, molybdenum, titanium, platinum, gold, chromium, etc., which is not limited in this embodiment. The film layer 110 may also be another film layer.
例如,如图2A所示,在待图案化的膜层110上涂敷光刻胶包括:采用旋转涂胶法在膜层110上涂敷一层薄而均匀,并且没有缺陷的光刻胶层120,本实施例不限于此,还可以采用其他涂敷方法。For example, as shown in FIG. 2A, applying a photoresist on the film layer 110 to be patterned includes: applying a thin, uniform, and defect-free photoresist layer on the film layer 110 by spin coating. 120, the embodiment is not limited thereto, and other coating methods may also be employed.
例如,光刻胶的涂布温度一般和室温相同,以最大限度的减少光刻胶的温度波动,从而减少工艺波动。For example, the coating temperature of the photoresist is generally the same as the room temperature to minimize the temperature fluctuation of the photoresist, thereby reducing process fluctuations.
S102:对光刻胶进行曝光以及显影,光刻胶经过曝光以及显影后被完全去除的部分对应的区域为第一区域。S102: exposing and developing the photoresist, and the corresponding region of the portion where the photoresist is completely removed after exposure and development is the first region.
例如,在光刻胶层120上覆盖掩模板(图中未示出),对覆盖有掩模板的光刻胶层120进行曝光。For example, a mask (not shown) is overlaid on the photoresist layer 120, and the photoresist layer 120 covered with the mask is exposed.
例如,可以采用电子束、离子束、X射线和紫外线等照射光刻胶层120,本实施例不限于此,例如,紫外线可以为具有波长范围为200nm-400nm的普通紫外线,也可以为具有波长范围为10nm-14nm的极紫外线,本实施例对此不作限制。For example, the photoresist layer 120 may be irradiated with an electron beam, an ion beam, an X-ray, an ultraviolet ray, or the like. The embodiment is not limited thereto. For example, the ultraviolet ray may be an ordinary ultraviolet ray having a wavelength range of 200 nm to 400 nm, or may have a wavelength. The extreme ultraviolet rays in the range of 10 nm to 14 nm are not limited in this embodiment.
本实施例以采用紫外光照射光刻胶层120的方式对光刻胶层120进行曝光为例进行描述,例如,光刻胶层120在曝光的过程中采用的光照强度为10 J/cm 3-500J/cm 3In this embodiment, the photoresist layer 120 is exposed by ultraviolet light to expose the photoresist layer 120 as an example. For example, the photoresist layer 120 uses an illumination intensity of 10 J/cm 3 during exposure. -500J/cm 3 .
例如,光刻胶层120在曝光的过程中采用的光照强度可以为50J/cm 3-80J/cm 3以使光刻胶层120充分曝光,本实施例不限于此。 For example, 120 employed in the light intensity during exposure of the photoresist layer may be 50J / cm 3 -80J / cm 3 to cause sufficient exposure of the photoresist layer 120, the present embodiment is not limited thereto.
例如,光刻胶层120在曝光的过程中采用的光照强度还可以为80J/cm 3-200J/cm 3,250J/cm 3-500J/cm 3或者10J/cm 3-40J/cm 3等,实际工艺中的光照强度可根据光刻胶层120的厚度而定。 For example, 120 employed in the light intensity during exposure of the photoresist layer may also be 80J / cm 3 -200J / cm 3 , 250J / cm 3 -500J / cm 3 or 10J / cm 3 -40J / cm 3 and the like, The intensity of the light in the actual process may depend on the thickness of the photoresist layer 120.
例如,光刻胶由树脂、感光剂、溶剂以及添加剂组成,在曝光之前需对光刻胶层120进行前烘,使光刻胶层120中的溶剂充分蒸发,以使光刻胶层120干燥以增强其与膜层110表面的粘附性等,并且提高曝光后线条分辨率。一般前烘的温度可以设定约为90℃-120℃,本实施例不限于此,但是前烘的温度不能过高以防止光刻胶层120发生高温融塌,因此,本实施例中的前烘温度不超过140℃。经过前烘后的光刻胶层120可以与膜层110粘结的更加牢固。For example, the photoresist is composed of a resin, a sensitizer, a solvent, and an additive. Before the exposure, the photoresist layer 120 is pre-baked, and the solvent in the photoresist layer 120 is sufficiently evaporated to dry the photoresist layer 120. To enhance its adhesion to the surface of the film layer 110, etc., and to improve the line resolution after exposure. Generally, the pre-baking temperature can be set to about 90 ° C - 120 ° C, and the embodiment is not limited thereto, but the pre-baking temperature cannot be too high to prevent the high-temperature collapse of the photoresist layer 120. Therefore, in the embodiment, The pre-bake temperature does not exceed 140 °C. The pre-baked photoresist layer 120 can be more strongly bonded to the film layer 110.
例如,正性光刻胶可以在空气中进行前烘,而负性光刻胶需在氮气环境中进行前烘。For example, a positive photoresist can be pre-baked in air, while a negative photoresist needs to be pre-baked in a nitrogen atmosphere.
例如,本实施例提供的光刻胶层120包括的光刻胶为正性光刻胶,正性光刻胶中例如包括线性酚醛树脂,当没有溶解抑制剂存在时,线性酚醛树脂会溶解在显影液中;正性光刻胶中的感光剂包括光敏化合物(PAC,Photo Active Compound),例如光敏化合物可以包括重氮萘醌(DNQ)等,本实施例对此不作限制。在曝光前,重氮萘醌是一种强烈的溶解抑制剂,可以降低树脂的溶解速度。For example, the photoresist layer 120 provided in this embodiment includes a photoresist which is a positive photoresist, and the positive photoresist includes, for example, a novolac resin. When no dissolution inhibitor is present, the novolac resin dissolves in the photoresist. In the developer, the sensitizer in the positive photoresist includes a photoactive compound (PAC). For example, the photosensitive compound may include diazonaphthoquinone (DNQ) or the like, which is not limited in this embodiment. Prior to exposure, diazonaphthoquinone is a strong dissolution inhibitor that reduces the rate of dissolution of the resin.
例如,在紫外曝光过程中,光敏化合物,例如重氮萘醌在正性光刻胶中通过感光化学反应发生化学分解,切断树脂聚合体主链和从链之间的联系,达到削弱聚合体的目的,从而成为溶解度增强剂。重氮萘醌在这种曝光反应中会产生羧酸,它在显影液中溶解度很高,所以曝光后的光刻胶在随后显影处理过程中溶解度升高,并且曝光后的正性光刻胶的溶解速度几乎是未曝光的光刻胶溶解速度的10倍。因此,正性光刻胶层120在曝光后,被曝光的区域上的正性光刻胶层120被完全去除以形成空白区(第一区域121),未被曝光的区域上的光刻胶层120保留在膜层110上作为后续保护膜层,这种方法复制到膜层110表面上的图形与光刻胶层120上的掩模板上的图形相同。For example, in an ultraviolet exposure process, a photosensitive compound such as diazonaphthoquinone is chemically decomposed by a photochemical reaction in a positive photoresist to cut off the relationship between the main chain of the resin polymer and the chain, thereby weakening the polymer. The purpose is to become a solubility enhancer. The diazonaphthoquinone produces carboxylic acid in this exposure reaction, and its solubility in the developer is high, so the solubility of the exposed photoresist after the subsequent development treatment is increased, and the positive photoresist after exposure is exposed. The dissolution rate is almost 10 times that of the unexposed photoresist. Therefore, after the positive photoresist layer 120 is exposed, the positive photoresist layer 120 on the exposed region is completely removed to form a blank region (first region 121), and the photoresist on the unexposed region Layer 120 remains on film layer 110 as a subsequent protective film layer, and the pattern replicated onto the surface of film layer 110 is the same as the pattern on the mask layer on photoresist layer 120.
例如,由于显影时间不足会导致被曝光的区域上的光刻胶层120不能在显影时完全溶解;显影时间过长会使显影时未被曝光的区域上的光刻胶层120也 会被从边缘钻溶以使图案的边缘变差等,因此本实施例对光刻胶层120进行显影的时间可选为10s-500s,本实施例包括但不限于此。For example, insufficient development time may cause the photoresist layer 120 on the exposed region to be completely dissolved during development; if the development time is too long, the photoresist layer 120 on the unexposed region during development may also be removed from the photoresist layer 120. The edge is drilled to make the edge of the pattern deteriorate, and the like. Therefore, the time for developing the photoresist layer 120 in this embodiment may be 10s-500s, and the embodiment includes but is not limited thereto.
例如,本实施例提供的显影液可以为中型碱溶液,例如,显影液可以包括氢氧化钾、四甲基氢氧化铵、酮或者乙酰唑胺等,本实施例对此不作限制。For example, the developer provided in this embodiment may be a medium-sized alkali solution. For example, the developer may include potassium hydroxide, tetramethylammonium hydroxide, ketone or acetazolamide, and the like, which is not limited in this embodiment.
例如,如图2B所示,光刻胶层120经过曝光以及显影后被完全去除的部分对应的区域为第一区域121,该第一区域121即为被曝光的区域上的正性光刻胶层120被显影液溶解去除后留下的空白区域。For example, as shown in FIG. 2B, a portion corresponding to a portion of the photoresist layer 120 that is completely removed after exposure and development is a first region 121, which is a positive photoresist on the exposed region. The layer 120 is removed by the developer to remove the blank area left behind.
例如,如图2B所示,第一区域121沿平行于膜层110所在平面的方向的最小尺寸为第一尺寸L1。需要说明的是,本实施例以第一区域121的平面图形的最小尺寸L1为第一区域121与膜层110接触面上的最小尺寸L1为例进行说明。For example, as shown in FIG. 2B, the minimum dimension of the first region 121 in a direction parallel to the plane of the film layer 110 is the first dimension L1. It should be noted that, in the present embodiment, the minimum dimension L1 of the planar pattern of the first region 121 is taken as an example of the minimum dimension L1 of the first region 121 and the contact surface of the film layer 110.
例如,第一尺寸L1不小于3μm。需要说明的是,第一尺寸L1的尺寸也不能太大,一般在微米量级,例如,第一尺寸L1可以为6-10μm,本实施例包括但不限于此。For example, the first size L1 is not less than 3 μm. It should be noted that the size of the first size L1 is also not too large, generally on the order of micrometers. For example, the first size L1 may be 6-10 μm, and the embodiment includes but is not limited thereto.
例如,第一区域121具有第一尺寸L1的平面在膜层110上的正投影的形状可以包括圆形和线形的至少之一或组合等,即,第一区域121的平面图形可以包括圆形和线形的至少之一或组合等,本实施例包括但不限于此。For example, the shape of the orthographic projection of the plane of the first region 121 having the first dimension L1 on the film layer 110 may include at least one or a combination of a circle and a line, etc., that is, the plane pattern of the first region 121 may include a circle. At least one or a combination of the lines and the like, the embodiment includes but is not limited thereto.
S103:对光刻胶进行后烘,光刻胶发生高温融塌以使被完全去除的部分对应的区域变化为第二区域,经过后烘的光刻胶形成掩膜图案。S103: post-baking the photoresist, the photoresist is melted at a high temperature to change a corresponding region of the completely removed portion to a second region, and the post-baking photoresist forms a mask pattern.
本实施例在图案化的膜层上涂敷的光刻胶为热融性光刻胶,热融性光刻胶的耐热性组分相比于普通光刻胶要低,因此在后烘时会发生高温融塌,但不会影响光刻胶的性能。In this embodiment, the photoresist coated on the patterned film layer is a hot-melt photoresist, and the heat-resistant composition of the hot-melt photoresist is lower than that of the conventional photoresist, so that the post-baking is performed. High temperature collapse occurs, but does not affect the performance of the photoresist.
例如,如图2B和2C所示,对具有第一区域121的光刻胶层120进行后烘,后烘过程采用的温度为150℃-300℃以使光刻胶层120发生高温融塌,即位于第一区域121四周的光刻胶层120在后烘时下发生融塌以使光刻胶层120的接触膜层110的一侧向第一区域121聚拢,而光刻胶层120的远离膜层110的一侧发生融塌塌陷,因此,第一区域121周围的光刻胶经过高温融塌后向第一区域121内流动以使被完全去除的光刻胶部分对应的区域变成第二区域122。For example, as shown in FIGS. 2B and 2C, the photoresist layer 120 having the first region 121 is post-baked, and the post-baking process is performed at a temperature of 150 ° C to 300 ° C to cause the photoresist layer 120 to collapse at a high temperature. That is, the photoresist layer 120 located around the first region 121 is collapsed during post-baking to cause one side of the contact film layer 110 of the photoresist layer 120 to be gathered toward the first region 121, and the photoresist layer 120 is away from the photoresist layer 120. One side of the film layer 110 collapses and collapses. Therefore, the photoresist around the first region 121 flows into the first region 121 after being melted at a high temperature to change the region corresponding to the completely removed photoresist portion. Two areas 122.
例如,对具有第一区域121的光刻胶层120进行后烘,后烘过程采用的温度可以为150℃-200℃,也可以为250℃-300℃等,本实施例对此不作限制。For example, the photoresist layer 120 having the first region 121 is post-baked, and the temperature used in the post-baking process may be 150 ° C - 200 ° C, or 250 ° C - 300 ° C, etc., which is not limited in this embodiment.
例如,如图2C所示,第二区域122沿平行于膜层110所在平面的方向的最小尺寸为第二尺寸L2,即第二区域122与膜层110接触的一侧具有的最小尺寸为第二尺寸L2,且第二尺寸L2小于第一尺寸L1。For example, as shown in FIG. 2C, the minimum dimension of the second region 122 in a direction parallel to the plane of the film layer 110 is the second dimension L2, that is, the smallest dimension of the side where the second region 122 is in contact with the film layer 110 is The second size L2 is smaller than the first size L1.
例如,如图2C所示,第二区域122具有的第二尺寸L2为1μm-2.9μm,该尺寸小于图2B所示的第一区域121的第一尺寸L1。For example, as shown in FIG. 2C, the second region 122 has a second dimension L2 of 1 μm to 2.9 μm which is smaller than the first dimension L1 of the first region 121 shown in FIG. 2B.
例如,第二区域122具有的第二尺寸L2可以为1μm-2.5μm,或者也可以为1.5μm-2μm,本实施例对此不作限制。For example, the second size 122 of the second region 122 may be 1 μm to 2.5 μm, or may be 1.5 μm to 2 μm, which is not limited in this embodiment.
例如,第二区域122的具有第二尺寸L2的平面的形状可以包括圆形和线形的至少之一或组合等,即第二区域122的平面形状可以包括圆形和线形的至少之一或组合等。需要说明的是,这里的圆形指近似圆形,例如,第二区域122的具有第二尺寸L2的平面的形状也可以为椭圆形等。For example, the shape of the plane of the second region 122 having the second dimension L2 may include at least one or a combination of a circle and a line, etc., that is, the planar shape of the second region 122 may include at least one or a combination of a circle and a line. Wait. It should be noted that the circular shape here is approximately circular, and for example, the shape of the plane of the second region 122 having the second dimension L2 may also be an ellipse or the like.
例如,如图2C所示,光刻胶层120沿垂直于膜层110方向,即沿X方向的厚度为0.5μm-10μm。For example, as shown in FIG. 2C, the photoresist layer 120 has a thickness in the direction perpendicular to the film layer 110, that is, in the X direction of 0.5 μm to 10 μm.
例如,光刻胶层120沿垂直于膜层110方向的厚度可以为1.5μm-2.2μm以使光刻胶层120围绕第一区域121的部分光刻胶向第一区域121内融塌流动结束后形成具有所需第二尺寸L2的第二区域122。For example, the thickness of the photoresist layer 120 in a direction perpendicular to the film layer 110 may be 1.5 μm - 2.2 μm to cause the photoresist layer 120 to collapse around the first region 121 of the first region 121. A second region 122 having a desired second dimension L2 is then formed.
例如,光刻胶层120沿X方向的厚度可以为3μm-5μm,或者光刻胶层120沿X方向的厚度也可以为7μm-10μm,本实施例对此不作限制。For example, the thickness of the photoresist layer 120 in the X direction may be 3 μm to 5 μm, or the thickness of the photoresist layer 120 in the X direction may be 7 μm to 10 μm, which is not limited in this embodiment.
例如,本实施例对光刻胶层120进行后烘的时间为10s-500s。For example, the time for post-baking the photoresist layer 120 in this embodiment is 10 s to 500 s.
例如,对光刻胶层120进行后烘的时间为10s-50s以使第一区域121周围的光刻胶层120发生融塌塌陷后形成具有所需第二尺寸L2的第二区域122。For example, the photoresist layer 120 is post-baked for 10 s to 50 s to cause the photoresist layer 120 around the first region 121 to collapse and collapse to form a second region 122 having a desired second dimension L2.
例如,本实施例对光刻胶层120进行后烘的时间还可以为100s-200s或者300s-500s,本实施例对此不作限制。For example, the time for the post-baking of the photoresist layer 120 in this embodiment may be 100s-200s or 300s-500s, which is not limited in this embodiment.
例如,本实施例的一示例以对膜层110进行图案化以形成开孔图案为例进行描述,本实施例中在膜层110上制作具有1μm-2.9μm孔径的图案之前采用的用于曝光光刻胶层120的曝光机的极限精度一般为3μm,形成具有第二区域122的光刻胶层120的部分步骤包括:使用具有孔径尺寸为5μm的掩模板作为厚度为0.5μm-10μm(例如,厚度为1.5μm-2.2μm)的光刻胶层120的掩模,对光刻胶层120进行曝光,曝光过程中的光照强度可选为10J/cm 3-500J/cm 3,例如,曝光过程中的光照强度可选为50J/cm 3-80J/cm 3。曝光后,对光刻胶层120进行显影,显影过程中的时间可选为10s-500s。对显影后的光刻胶层120 进行后烘,后烘过程中的温度可选为150℃-300℃,后烘时间可选为10s-500s,例如,后烘的时间为10s-50s。在经过上述曝光、显影以及后烘后,在光刻胶层120上形成了具有第二尺寸L2为1μm-2.9μm的第二区域122。因此,该膜层图案化方法利用热融性光刻胶在显影和后烘后发生高温融塌的特点,为待图案化的膜层形成曝光机精度以下的小尺寸图案提供可能,并且该方法工艺简单、成本低。 For example, an example of the present embodiment is described by taking an example of patterning the film layer 110 to form an opening pattern, which is used for exposure before the pattern having a hole diameter of 1 μm to 2.9 μm is formed on the film layer 110 in this embodiment. The limit accuracy of the exposure machine of the photoresist layer 120 is generally 3 μm, and the partial step of forming the photoresist layer 120 having the second region 122 includes using a mask having a pore size of 5 μm as a thickness of 0.5 μm to 10 μm (for example, a mask of the photoresist layer 120 having a thickness of 1.5 μm to 2.2 μm, and exposing the photoresist layer 120, and the light intensity during the exposure may be 10 J/cm 3 to 500 J/cm 3 , for example, exposure. The light intensity during the process can be selected from 50 J/cm 3 to 80 J/cm 3 . After the exposure, the photoresist layer 120 is developed, and the time during the development may be selected from 10 s to 500 s. The developed photoresist layer 120 is post-baked, and the temperature during the post-baking process may be 150 ° C - 300 ° C, and the post-baking time may be 10 s - 500 s. For example, the post-baking time is 10 s - 50 s. After the above exposure, development, and post-baking, a second region 122 having a second dimension L2 of 1 μm to 2.9 μm is formed on the photoresist layer 120. Therefore, the film layer patterning method utilizes the characteristics of high temperature collapse of the hot melt photoresist after development and post-baking, and provides a possibility to form a small-sized pattern below the exposure machine precision of the film layer to be patterned, and the method The process is simple and the cost is low.
S104:以掩膜图案为掩模对膜层进行图案化。S104: pattern the film layer with the mask pattern as a mask.
例如,如图2D所示,以具有第二区域122的光刻胶层120为掩模对膜层110进行图案化后形成了小尺寸的图案111/112。For example, as shown in FIG. 2D, the film layer 110 is patterned using the photoresist layer 120 having the second region 122 as a mask to form a small-sized pattern 111/112.
例如,对膜层110进行图案化可以形成孔径为第二尺寸L2的开孔111,即开孔111的孔径为1μm-2.9μm,本实施例包括但不限于此。For example, patterning the film layer 110 may form the opening 111 having the second dimension L2, that is, the opening 111 has a diameter of 1 μm to 2.9 μm. This embodiment includes but is not limited thereto.
例如,对膜层110进行图案化还可以形成最小尺寸为第二尺寸L2的线形112,即线形112的短边尺寸(沿Y方向延伸的边长)为1μm-2.9μm,本实施例包括但不限于此。需要说明的是,图2A-2D示意性的示出形成一个小尺寸的图案111/112,本实施例不限于此,还可以是多个小尺寸的图案111/112。For example, patterning the film layer 110 may also form a line shape 112 having a minimum size of the second dimension L2, that is, a short side dimension of the line shape 112 (a side length extending in the Y direction) is 1 μm - 2.9 μm, and this embodiment includes Not limited to this. It should be noted that FIGS. 2A-2D schematically illustrate the formation of a small-sized pattern 111/112. The embodiment is not limited thereto, and may also be a plurality of small-sized patterns 111/112.
例如,图3A为本公开一实施例的一示例提供的膜层的局部平面示意图,图3B为本公开一实施例的另一示例提供的膜层的局部平面示意图。如图3A所示,利用具有第二区域122的掩模图案为掩模在膜层110上形成的图案为开孔111。For example, FIG. 3A is a partial plan view of a film layer provided by an example of an embodiment of the present disclosure, and FIG. 3B is a partial plan view of a film layer provided by another example of an embodiment of the present disclosure. As shown in FIG. 3A, the pattern formed on the film layer 110 using the mask pattern having the second region 122 as a mask is an opening 111.
例如,该开孔111在YZ面的平面形状可以为标准圆形,也可以为近似圆形,本实施例包括但不限于此。For example, the planar shape of the opening 111 in the YZ plane may be a standard circular shape or an approximately circular shape, and the embodiment includes but is not limited thereto.
例如,开孔111在YZ面的平面形状还可以为非规则形状等。需要说明的是,图3A示意性的示出一个开孔111,本实施例不限于此,还可以是多个开孔111。For example, the planar shape of the opening 111 in the YZ plane may also be an irregular shape or the like. It should be noted that FIG. 3A schematically shows an opening 111. The embodiment is not limited thereto, and may also be a plurality of openings 111.
例如,膜层110为栅绝缘层和/或层间绝缘层时,利用具有第二区域122的光刻胶层120,即掩模图案为掩模可以形成用于连接薄膜晶体管的源极和漏极与有源层的接触孔(即开孔111)。这里的薄膜晶体管为顶栅型。For example, when the film layer 110 is a gate insulating layer and/or an interlayer insulating layer, the source and the drain for connecting the thin film transistor can be formed by using the photoresist layer 120 having the second region 122, that is, the mask pattern as a mask. The contact hole of the pole and the active layer (ie, the opening 111). The thin film transistor here is of a top gate type.
例如,膜层110为刻蚀阻挡层时,利用具有第二区域122的光刻胶层120为掩模可以形成用于连接薄膜晶体管的源极和漏极与有源层的接触孔(即开孔111)。For example, when the film layer 110 is an etch barrier layer, a contact hole for connecting the source and the drain of the thin film transistor to the active layer may be formed by using the photoresist layer 120 having the second region 122 as a mask (ie, opening) Hole 111).
例如,膜层110为钝化层时,利用具有第二区域122的光刻胶层120为掩 模形成过孔(即开孔111)以露出薄膜晶体管的漏极和公共电极线,露出的漏极可以通过过孔与后续形成的像素电极电连接,露出的公共电极线可以通过过孔与后续形成的公共电极电连接,本实施例包括但不限于此。For example, when the film layer 110 is a passivation layer, a via hole (ie, an opening 111) is formed by using the photoresist layer 120 having the second region 122 as a mask to expose the drain and common electrode lines of the thin film transistor, and the exposed drain The pole electrode may be electrically connected to the subsequently formed pixel electrode through the via hole, and the exposed common electrode line may be electrically connected to the subsequently formed common electrode through the via hole, and the embodiment includes but is not limited thereto.
例如,膜层110还可以为其他绝缘层或者金属层等,本实施例对此不作限制。For example, the film layer 110 may also be other insulating layers or metal layers, etc., which is not limited in this embodiment.
例如,如图3B所示,利用具有第二区域122的光刻胶层120为掩模在膜层110上形成的平面图案还可以为线形112,即在膜层110上可以形成沟槽等。需要说明的是,图3B示意性的示出一个线形112,本实施例不限于此,还可以是多个线形112。For example, as shown in FIG. 3B, the planar pattern formed on the film layer 110 by using the photoresist layer 120 having the second region 122 as a mask may also be a line shape 112, that is, a trench or the like may be formed on the film layer 110. It should be noted that FIG. 3B schematically shows a line shape 112. The embodiment is not limited thereto, and may also be a plurality of line shapes 112.
本公开一实施例提供一种阵列基板的制作方法,图4为本公开一实施例提供的阵列基板的制作方法的流程示意图,如图4所示,制作方法包括:An embodiment of the present disclosure provides a method for fabricating an array substrate. FIG. 4 is a schematic flow chart of a method for fabricating an array substrate according to an embodiment of the present disclosure. As shown in FIG.
S201:提供衬底基板。S201: providing a substrate.
例如,衬底基板可以由玻璃、聚酰亚胺、聚碳酸酯、聚丙烯酸酯、聚醚酰亚胺、聚醚砜、聚对苯二甲酸乙二醇酯和聚萘二甲酸乙二醇酯中的一种或多种材料制成,本实施例包括但不限于此。For example, the base substrate may be made of glass, polyimide, polycarbonate, polyacrylate, polyetherimide, polyethersulfone, polyethylene terephthalate, and polyethylene naphthalate. One or more materials are made, and the embodiment includes but is not limited thereto.
S202:在衬底基板上形成待图案化的膜层。S202: forming a film layer to be patterned on the base substrate.
例如,在衬底基板上可以通过沉积或者磁控溅射等方法形成待图案化的膜层。For example, a film layer to be patterned may be formed on a base substrate by deposition or magnetron sputtering or the like.
例如,膜层可以为绝缘层,例如,膜层可以为栅绝缘层、层间绝缘层、钝化层或者刻蚀阻挡层等,本实施例对此不作限制。For example, the film layer may be an insulating layer. For example, the film layer may be a gate insulating layer, an interlayer insulating layer, a passivation layer or an etch barrier layer, and the like, which is not limited in this embodiment.
例如,膜层可以包括金属氧化物、金属硫化物或金属氮化物等无机材料,本实施对此不作限制。For example, the film layer may include an inorganic material such as a metal oxide, a metal sulfide, or a metal nitride, which is not limited in this embodiment.
例如,膜层也可以选用有机材料,例如可以包括聚酰亚胺、聚酰胺、聚碳酸酯、环氧树脂等中的一种或几种的组合等,本实施例不限于此。For example, the film layer may also be an organic material, and may include, for example, one or a combination of polyimide, polyamide, polycarbonate, epoxy resin, etc., and the embodiment is not limited thereto.
例如,膜层也可以为金属层,例如,膜层的材料可以选用铝、银、钼、钛、铂、金、铬等材料中的一种或几种,本实施例对此不作限制,例如,膜层也可以是其他膜层。For example, the film layer may also be a metal layer. For example, the material of the film layer may be one or more of materials such as aluminum, silver, molybdenum, titanium, platinum, gold, chromium, etc., which is not limited in this embodiment, for example. The film layer may also be other film layers.
S203:对膜层利用膜层图案化方法进行图案化。S203: Patterning the film layer by a film layer patterning method.
本实施例对膜层利用上述实施例提供的任一膜层图案化方法进行图案化,且具体的图案化步骤以及对膜层图案化后的得到的小尺寸图案的形状及尺寸等参数这里不再赘述。In this embodiment, the film layer is patterned by any of the film layer patterning methods provided in the above embodiments, and the specific patterning step and the shape and size of the obtained small-sized pattern after patterning the film layer are not Let me repeat.
该阵列基板的制作方法利用热融性光刻胶在显影和后烘后发生高温融塌的特点,为待图案化的膜层形成曝光机精度以下的小尺寸图案提供可能,并且该方法工艺简单、成本低。The method for fabricating the array substrate utilizes the characteristics of high-temperature collapse of the hot-melt photoresist after development and post-baking, and provides a possibility to form a small-sized pattern below the exposure machine precision of the film layer to be patterned, and the method is simple. ,low cost.
本公开一实施例提供一种阵列基板,该阵列基板由上述实施例提供的阵列基板的制作方法制作而成。An embodiment of the present disclosure provides an array substrate fabricated by the method for fabricating the array substrate provided in the above embodiments.
例如,阵列基板包括的膜层的表面上具有与光刻胶层的第二区域的平面形状大致相同的膜层图案,并且该膜层图案沿平行于膜层所在平面的方向的最小尺寸为第二尺寸,即第二区域沿平行于膜层所在平面的方向的最小尺寸。For example, the array substrate includes a film layer having a film layer pattern substantially the same as a planar shape of the second region of the photoresist layer, and the film layer pattern has a minimum dimension in a direction parallel to the plane of the film layer. The second dimension, that is, the smallest dimension of the second region in a direction parallel to the plane of the film layer.
例如,膜层图案沿平行于膜层所在平面的方向的最小尺寸为1μm-2.9μm。For example, the minimum dimension of the film pattern in a direction parallel to the plane of the film layer is from 1 μm to 2.9 μm.
例如,膜层图案沿平行于膜层所在平面的方向的最小尺寸可以为1μm-2.5μm,或者也可以为1.5μm-2μm,本实施例对此不作限制。For example, the minimum dimension of the film pattern in a direction parallel to the plane of the film layer may be from 1 μm to 2.5 μm, or may also be from 1.5 μm to 2 μm, which is not limited in this embodiment.
例如,该阵列基板可以应用于液晶显示装置、有机发光二极管(Organic Light-Emitting Diode,OLED)显示装置等显示器件以及包括该显示装置的电视、数码相机、手机、手表、平板电脑、笔记本电脑、导航仪等任何具有显示功能的产品或者部件,本实施例不限于此。For example, the array substrate can be applied to display devices such as liquid crystal display devices, organic light-emitting diode (OLED) display devices, and televisions, digital cameras, mobile phones, watches, tablets, and notebook computers including the display devices. The present embodiment is not limited to any product or component having a display function such as a navigator.
有以下几点需要说明:There are a few points to note:
(1)除非另作定义,本公开实施例以及附图中,同一标号代表同一含义。(1) Unless otherwise defined, the same reference numerals are used to refer to the same meaning
(2)本公开实施例附图中,只涉及到与本公开实施例涉及到的结构,其他结构可参考通常设计。(2) In the drawings of the embodiments of the present disclosure, only the structures related to the embodiments of the present disclosure are referred to, and other structures may be referred to the general design.
(3)为了清晰起见,在用于描述本公开的实施例的附图中,层或区域被放大。可以理解,当诸如层、膜、区域或基板之类的元件被称作位于另一元件“上”或“下”时,该元件可以“直接”位于另一元件“上”或“下”,或者可以存在中间元件。(3) For the sake of clarity, layers or regions are enlarged in the drawings for describing embodiments of the present disclosure. It will be understood that when an element such as a layer, a film, a region or a substrate is referred to as being "on" or "lower" Or there may be intermediate elements.
以上所述,仅为本公开的具体实施方式,但本公开的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本公开揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本公开的保护范围之内。因此,本公开的保护范围应以所述权利要求的保护范围为准。The above is only the specific embodiment of the present disclosure, but the scope of the present disclosure is not limited thereto, and any person skilled in the art can easily think of changes or substitutions within the technical scope of the disclosure. It should be covered within the scope of protection of the present disclosure. Therefore, the scope of protection of the present disclosure should be determined by the scope of the claims.

Claims (15)

  1. 一种膜层图案化方法,包括:A film layering method comprising:
    在待图案化的膜层上涂敷光刻胶;Applying a photoresist on the film layer to be patterned;
    对所述光刻胶进行曝光以及显影,所述光刻胶经过曝光以及显影后被完全去除的部分对应的区域为第一区域;Exposing and developing the photoresist, the corresponding region of the portion of the photoresist that is completely removed after exposure and development is a first region;
    对所述光刻胶进行后烘,所述光刻胶发生高温融塌以使被完全去除的部分对应的区域变化为第二区域,经过后烘的所述光刻胶形成掩膜图案;以及After the photoresist is post-baked, the photoresist is melted at a high temperature to change a corresponding portion of the completely removed portion to a second region, and the photoresist is post-baked to form a mask pattern;
    以所述掩膜图案为掩模对所述膜层进行图案化。The film layer is patterned using the mask pattern as a mask.
  2. 根据权利要求1所述的膜层图案化方法,其中,所述第一区域沿平行于所述膜层所在平面的方向的最小尺寸为第一尺寸,所述第二区域沿平行于所述膜层所在平面的方向的最小尺寸为第二尺寸,且所述第二尺寸小于所述第一尺寸。The film layer patterning method according to claim 1, wherein a minimum size of the first region in a direction parallel to a plane of the film layer is a first size, and the second region is parallel to the film The smallest dimension of the direction in which the layer is in the plane is the second dimension, and the second dimension is smaller than the first dimension.
  3. 根据权利要求1或2所述的膜层图案化方法,其中,所述光刻胶为正性光刻胶。The film layer patterning method according to claim 1 or 2, wherein the photoresist is a positive photoresist.
  4. 根据权利要求1-3任一项所述的膜层图案化方法,其中,所述第二区域的平面形状包括圆形和线形的至少之一或组合。The film layer patterning method according to any one of claims 1 to 3, wherein the planar shape of the second region comprises at least one or a combination of a circle and a line.
  5. 根据权利要求1-4任一项所述的膜层图案化方法,其中,在所述后烘的过程中,后烘温度为150℃-300℃以使所述光刻胶发生高温融塌。The film layer patterning method according to any one of claims 1 to 4, wherein, in the post-baking process, the post-baking temperature is from 150 ° C to 300 ° C to cause the photoresist to collapse at a high temperature.
  6. 根据权利要求5所述的膜层图案化方法,其中,在所述后烘的过程中,后烘时间为10s-500s。The film layer patterning method according to claim 5, wherein during the post-baking, the post-baking time is from 10 s to 500 s.
  7. 根据权利要求6所述的膜层图案化方法,其中,在所述后烘的过程中,所述后烘时间为10s-50s。The film layer patterning method according to claim 6, wherein the post-baking time is 10 s to 50 s during the post-baking.
  8. 根据权利要求1-7任一项所述的膜层图案化方法,其中,所述第二尺寸为1μm-2.9μm。The film layer patterning method according to any one of claims 1 to 7, wherein the second size is from 1 μm to 2.9 μm.
  9. 根据权利要求8所述的膜层图案化方法,其中,所述第一尺寸不小于3μm。The film layer patterning method according to claim 8, wherein the first size is not less than 3 μm.
  10. 根据权利要求1-9任一项所述的膜层图案化方法,其中,所述光刻胶沿垂直于所述膜层方向的厚度为0.5μm-10μm。The film layer patterning method according to any one of claims 1 to 9, wherein the photoresist has a thickness in a direction perpendicular to the film layer of from 0.5 μm to 10 μm.
  11. 根据权利要求10所述的膜层图案化方法,其中,所述光刻胶沿垂直于所述膜层方向的所述厚度为1.5μm-2.2μm。The film layer patterning method according to claim 10, wherein the thickness of the photoresist in a direction perpendicular to the film layer is from 1.5 μm to 2.2 μm.
  12. 根据权利要求1-11任一项所述的膜层图案化方法,其中,在所述曝光的过程中采用的光照强度为10J/cm 3-500J/cm 3The film layer patterning method according to any one of claims 1 to 11, wherein the light intensity used in the exposure is 10 J/cm 3 to 500 J/cm 3 .
  13. 一种阵列基板的制作方法,包括:A method for fabricating an array substrate, comprising:
    提供衬底基板;Providing a substrate;
    在所述衬底基板上形成待图案化的膜层;Forming a film layer to be patterned on the base substrate;
    对所述膜层利用权利要求1-12任一项所述的膜层图案化方法进行图案化。The film layer is patterned by the film layer patterning method according to any one of claims 1 to 12.
  14. 一种阵列基板,利用权利要求13所述的阵列基板的制作方法制作而成。An array substrate produced by the method for fabricating the array substrate according to claim 13.
  15. 根据权利要求14所述的阵列基板,其中,所述阵列基板包括的所述膜层的表面上具有与所述第二区域的平面形状相同的膜层图案。The array substrate according to claim 14, wherein the film layer included in the array substrate has a film layer pattern having the same planar shape as that of the second region.
PCT/CN2018/080465 2017-07-18 2018-03-26 Film layer patterning method, and array substrate and fabrication method therefor WO2019015353A1 (en)

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CN107275195B (en) * 2017-07-18 2019-12-31 京东方科技集团股份有限公司 Film patterning method, array substrate and manufacturing method thereof
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101435992A (en) * 2007-11-15 2009-05-20 北京京东方光电科技有限公司 Photoresist masking method
US20100038649A1 (en) * 2008-08-14 2010-02-18 Samsung Electronics Co., Ltd. Mold, manufacturing method of mold, method for forming patterns using mold, and display substrate and display device manufactured by using method for forming patterns
CN102455593A (en) * 2010-10-25 2012-05-16 京东方科技集团股份有限公司 Method for forming photoresist pattern and manufacturing method of array substrate
CN104716092A (en) * 2015-04-02 2015-06-17 京东方科技集团股份有限公司 Manufacturing method of array substrate and manufacturing device
CN107275195A (en) * 2017-07-18 2017-10-20 京东方科技集团股份有限公司 Film pattern method, array base palte and preparation method thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006243499A (en) * 2005-03-04 2006-09-14 Oki Electric Ind Co Ltd Method for forming photoresist pattern and method for manufacturing semiconductor device
US20060257785A1 (en) * 2005-05-13 2006-11-16 Johnson Donald W Method of forming a photoresist element
TWI463659B (en) * 2009-07-06 2014-12-01 Au Optronics Corp Thin film transistor array and manufacturing method thereof
CN104330196B (en) * 2014-11-28 2017-02-22 杭州士兰集成电路有限公司 Cavity film piezoresistive pressure sensor and manufacturing method thereof
CN105527801B (en) * 2016-03-04 2017-08-11 京东方科技集团股份有限公司 A kind of patterning method of film layer, substrate and preparation method thereof, display device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101435992A (en) * 2007-11-15 2009-05-20 北京京东方光电科技有限公司 Photoresist masking method
US20100038649A1 (en) * 2008-08-14 2010-02-18 Samsung Electronics Co., Ltd. Mold, manufacturing method of mold, method for forming patterns using mold, and display substrate and display device manufactured by using method for forming patterns
CN102455593A (en) * 2010-10-25 2012-05-16 京东方科技集团股份有限公司 Method for forming photoresist pattern and manufacturing method of array substrate
CN104716092A (en) * 2015-04-02 2015-06-17 京东方科技集团股份有限公司 Manufacturing method of array substrate and manufacturing device
CN107275195A (en) * 2017-07-18 2017-10-20 京东方科技集团股份有限公司 Film pattern method, array base palte and preparation method thereof

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