WO2018232823A1 - Anti-corrosion coating for mechanical equipment - Google Patents
Anti-corrosion coating for mechanical equipment Download PDFInfo
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- WO2018232823A1 WO2018232823A1 PCT/CN2017/094184 CN2017094184W WO2018232823A1 WO 2018232823 A1 WO2018232823 A1 WO 2018232823A1 CN 2017094184 W CN2017094184 W CN 2017094184W WO 2018232823 A1 WO2018232823 A1 WO 2018232823A1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
Definitions
- the invention relates to the technical field of gardening tool manufacturing, in particular to a mixed powder for gardening tools and a preparation method thereof.
- a coating is a material that can be applied to the surface of an object using different application techniques to form a solid film that is firmly adhered, has a strength, and is continuous.
- the film thus formed is generally referred to as a coating film, also known as a paint film or coating. It belongs to organic chemical polymer materials, and the formed coating film belongs to the type of polymer compound. According to the classification of modern chemical products, coatings are fine chemical products. Modern coatings are gradually becoming a class of versatile engineering materials and an important industry in the chemical industry. At present, the coating function on the market is relatively simple and cannot meet the needs of people.
- the present invention provides an anti-corrosion coating for mechanical equipment with low cost, simple manufacturing process, and can effectively prevent acid-base corrosion, and is suitable for various types of mechanical equipment.
- An anti-corrosion coating for mechanical equipment comprises the following components by mass: 8 to 12 parts of epoxy-acrylic acid, 2 to 4 parts of iron oxide, 2 to 4 parts of talc, and chromium 4-8 parts of acid bismuth, 6-9 parts of tributyl phosphate, 2-8 parts of ethylene glycol monobutyl ether, 8-16 parts of sodium carboxymethyl cellulose, and 4-8 parts of dibutyl phthalate.
- the components include the following parts by mass: 10 to 12 parts of epoxy-acrylic acid, 3 to 4 parts of iron oxide, 3 to 4 parts of talc, 6 to 8 parts of strontium chromate, and 7 to 9 parts of tributyl phosphate.
- the components include the following parts by mass: 11 parts of epoxy-acrylic acid, 3.5 parts of iron oxide, 3.5 parts of talc, 7 parts of strontium chromate, 8 parts of tributyl phosphate, and 6 parts of ethylene glycol monobutyl ether. , 14 parts of sodium carboxymethyl cellulose, 7 parts of dibutyl phthalate, 5 parts of ethylene glycol, 11 parts of ammonium phosphate, 10 parts of sodium nitrate, 3.5 parts of methanol, 17 parts of ammonium acrylate, isopropyl acrylate 5 Parts: 14 parts of butyl acetate, 9 parts of ammonium persulfate, and 4 parts of dry triol.
- the anti-corrosion coating provided by the invention has low cost, simple manufacturing process, can effectively prevent acid-base corrosion, and is suitable for various mechanical equipments.
- An anticorrosive coating for mechanical equipment comprising the following components by mass: 8 parts of epoxy-acrylic acid, 2 parts of iron oxide, 2 parts of talc, 4 parts of strontium chromate, 6 parts of tributyl phosphate, and 2 2 parts of alcohol monobutyl ether, 8 parts of sodium carboxymethyl cellulose, 4 parts of dibutyl phthalate, 2 parts of ethylene glycol, 8 parts of ammonium phosphate, 4 parts of sodium nitrate, 2 parts of methanol, 10 parts of ammonium acrylate 3 parts of isopropyl acrylate, 12 parts of butyl acetate, 5 parts of ammonium persulfate, and 2 parts of dry triol.
- An anticorrosive coating for mechanical equipment comprising the following parts by mass: 12 parts of epoxy-acrylic acid, 4 parts of iron oxide, 4 parts of talc, 8 parts of strontium chromate, 9 parts of tributyl phosphate, and 2 8 parts of alcohol monobutyl ether, 16 parts of sodium carboxymethyl cellulose, 8 parts of dibutyl phthalate, 6 parts of ethylene glycol, 12 parts of phosphoric acid, 12 parts of sodium nitrate, 4 parts of methanol, 20 parts of ammonium acrylate, 6 parts of isopropyl acrylate, 15 parts of butyl acetate, 10 parts of ammonium persulfate, and 5 parts of dry triol.
- An anticorrosive coating for mechanical equipment comprising the following parts by mass: 11 parts of epoxy-acrylic acid, 3.5 parts of iron oxide, 3.5 parts of talc, 7 parts of strontium chromate, 8 parts of tributyl phosphate, and 2 6 parts of alcohol monobutyl ether, 14 parts of sodium carboxymethyl cellulose, 7 parts of dibutyl phthalate, 5 parts of ethylene glycol, 11 parts of ammonium phosphate, 10 parts of sodium nitrate, 3.5 parts of methanol, 17 parts of ammonium acrylate 5 parts of isopropyl acrylate, 14 parts of butyl acetate, 9 parts of ammonium persulfate, and 4 parts of dry triol.
- the anti-corrosion coating provided by the invention has low cost, simple manufacturing process, can effectively prevent acid-base corrosion, and is suitable for various mechanical equipments.
Abstract
An anti-corrosion coating for mechanical equipment, comprising the following components in parts by mass: 8-12 parts of epoxy-acrylic acid, 2-4 parts of iron oxide, 2-4 parts of talcum powder, 4-8 parts of strontium chromate, 6-9 parts of tributyl phosphate, 2-8 parts of ethylene glycol monobutyl ether, 8-16 parts of carboxymethyl cellulose sodium, 4-8 parts of dibutyl phthalate, 2-6 parts of ethylene glycol, 8-12 parts of ammonium phosphate, 4-12 parts of sodium nitrate, 2-4 parts of methanol, 10-20 parts of ammonium acrylate, 3-6 parts of isopropyl acrylate, 12-15 parts of butyl acetate, 5-10 parts of ammonium persulphate, and 2-5 parts of dry triol.
Description
本发明涉及园艺工具制造技术领域，具体涉及一种园艺工具用混合粉及其制备方法。The invention relates to the technical field of gardening tool manufacturing, in particular to a mixed powder for gardening tools and a preparation method thereof.
涂料是一种材料，这种材料可以用不同的施工工艺涂覆在物件表面，形成粘附牢固、具有一定强度、连续的固态薄膜。这样形成的膜通称涂膜，又称漆膜或涂层。属于有机化工高分子材料，所形成的涂膜属于高分子化合物类型。按照现代通行的化工产品的分类，涂料属于精细化工产品。现代的涂料正在逐步成为一类多功能性的工程材料，是化学工业中的一个重要行业。目前市面上的涂料功能比较单一，不能满足人们的需求。A coating is a material that can be applied to the surface of an object using different application techniques to form a solid film that is firmly adhered, has a strength, and is continuous. The film thus formed is generally referred to as a coating film, also known as a paint film or coating. It belongs to organic chemical polymer materials, and the formed coating film belongs to the type of polymer compound. According to the classification of modern chemical products, coatings are fine chemical products. Modern coatings are gradually becoming a class of versatile engineering materials and an important industry in the chemical industry. At present, the coating function on the market is relatively simple and cannot meet the needs of people.
发明内容Summary of the invention
发明目的：本发明针对不足，提出一种机械设备用防腐蚀涂料，成本低，制作工艺简单，可以对有效防止酸碱腐蚀，适用于各类机械设备。OBJECT OF THE INVENTION: The present invention provides an anti-corrosion coating for mechanical equipment with low cost, simple manufacturing process, and can effectively prevent acid-base corrosion, and is suitable for various types of mechanical equipment.
技术方案：本发明所述的一种机械设备用防腐蚀涂料，包括如下质量份数的组分：环氧‐丙烯酸8～12份，氧化铁2～4份，滑石粉2～4份，铬酸锶4～8份，磷酸三丁酯6～9份，乙二醇一丁醚2～8份，羟甲基纤维素钠8～16份，邻苯二甲酸二丁酯4～8份，乙二醇2～6份，磷酸铵8～12份，硝酸钠4～12份，甲醇2～4份，丙烯酸铵10～20份，丙烯酸异丙酯3～6份，乙酸丁酯12～15份，过硫酸铵5～10份，干三醇2～5份。Technical Solution: An anti-corrosion coating for mechanical equipment according to the present invention comprises the following components by mass: 8 to 12 parts of epoxy-acrylic acid, 2 to 4 parts of iron oxide, 2 to 4 parts of talc, and chromium 4-8 parts of acid bismuth, 6-9 parts of tributyl phosphate, 2-8 parts of ethylene glycol monobutyl ether, 8-16 parts of sodium carboxymethyl cellulose, and 4-8 parts of dibutyl phthalate. 2 to 6 parts of ethylene glycol, 8 to 12 parts of ammonium phosphate, 4 to 12 parts of sodium nitrate, 2 to 4 parts of methanol, 10 to 20 parts of ammonium acrylate, 3 to 6 parts of isopropyl acrylate, and butyl acetate 12 to 15 Parts, 5 to 10 parts of ammonium persulfate and 2 to 5 parts of dry triol.
进一步的，包括如下质量份数的组分：环氧‐丙烯酸10～12份，氧化铁3～4份，滑石粉3～4份，铬酸锶6～8份，磷酸三丁酯7～9份，乙二醇一丁醚4～8份，羟甲基纤维素钠10～16份，邻苯二甲酸二丁酯6～8份，乙二醇4～6份，磷酸铵10～12份，硝酸钠8～12份，甲醇3～4份，丙烯酸铵15～20份，丙烯酸异丙酯4～6份，乙酸丁酯13～15份，过硫酸铵7～10份，干三醇3～5份。Further, the components include the following parts by mass: 10 to 12 parts of epoxy-acrylic acid, 3 to 4 parts of iron oxide, 3 to 4 parts of talc, 6 to 8 parts of strontium chromate, and 7 to 9 parts of tributyl phosphate. Parts, 4-8 parts of ethylene glycol monobutyl ether, 10-16 parts of sodium carboxymethyl cellulose, 6-8 parts of dibutyl phthalate, 4-6 parts of ethylene glycol, 10-12 parts of ammonium phosphate , sodium nitrate 8 to 12 parts, methanol 3 to 4 parts, ammonium acrylate 15 to 20 parts, isopropyl acrylate 4 to 6 parts, butyl acetate 13 to 15 parts, ammonium persulfate 7 to 10 parts, dry triol 3 ~5 copies.
进一步的，包括如下质量份数的组分：环氧‐丙烯酸11份，氧化铁3.5份，滑石粉3.5份，铬酸锶7份，磷酸三丁酯8份，乙二醇一丁醚6份，羟甲基纤维素钠14份，邻苯二甲酸二丁酯7份，乙二醇5份，磷酸铵11份，硝酸钠10份，甲醇3.5份，丙烯酸铵17份，丙烯酸异丙酯5份，乙酸丁酯14份，过硫酸铵9份，干三醇4份。Further, the components include the following parts by mass: 11 parts of epoxy-acrylic acid, 3.5 parts of iron oxide, 3.5 parts of talc, 7 parts of strontium chromate, 8 parts of tributyl phosphate, and 6 parts of ethylene glycol monobutyl ether. , 14 parts of sodium carboxymethyl cellulose, 7 parts of dibutyl phthalate, 5 parts of ethylene glycol, 11 parts of ammonium phosphate, 10 parts of sodium nitrate, 3.5 parts of methanol, 17 parts of ammonium acrylate, isopropyl acrylate 5 Parts: 14 parts of butyl acetate, 9 parts of ammonium persulfate, and 4 parts of dry triol.
有益效果：本发明提供的防腐蚀涂料，成本低，制作工艺简单，可以对有效防止酸碱腐蚀，适用于各类机械设备。Advantageous Effects: The anti-corrosion coating provided by the invention has low cost, simple manufacturing process, can effectively prevent acid-base corrosion, and is suitable for various mechanical equipments.
下面结合具体实施例对本发明作进一步说明：The present invention will be further described below in conjunction with specific embodiments:
实施例1
Example 1
一种机械设备用防腐蚀涂料，包括如下质量份数的组分：环氧‐丙烯酸8份，氧化铁2份，滑石粉2份，铬酸锶4份，磷酸三丁酯6份，乙二醇一丁醚2份，羟甲基纤维素钠8份，邻苯二甲酸二丁酯4份，乙二醇2份，磷酸铵8份，硝酸钠4份，甲醇2份，丙烯酸铵10份，丙烯酸异丙酯3份，乙酸丁酯12份，过硫酸铵5份，干三醇2份。An anticorrosive coating for mechanical equipment, comprising the following components by mass: 8 parts of epoxy-acrylic acid, 2 parts of iron oxide, 2 parts of talc, 4 parts of strontium chromate, 6 parts of tributyl phosphate, and 2 2 parts of alcohol monobutyl ether, 8 parts of sodium carboxymethyl cellulose, 4 parts of dibutyl phthalate, 2 parts of ethylene glycol, 8 parts of ammonium phosphate, 4 parts of sodium nitrate, 2 parts of methanol, 10 parts of ammonium acrylate 3 parts of isopropyl acrylate, 12 parts of butyl acetate, 5 parts of ammonium persulfate, and 2 parts of dry triol.
实施例2Example 2
一种机械设备用防腐蚀涂料，包括如下质量份数的组分：环氧‐丙烯酸12份，氧化铁4份，滑石粉4份，铬酸锶8份，磷酸三丁酯9份，乙二醇一丁醚8份，羟甲基纤维素钠16份，邻苯二甲酸二丁酯8份，乙二醇6份，磷酸12份，硝酸钠12份，甲醇4份，丙烯酸铵20份，丙烯酸异丙酯6份，乙酸丁酯15份，过硫酸铵10份，干三醇5份。An anticorrosive coating for mechanical equipment, comprising the following parts by mass: 12 parts of epoxy-acrylic acid, 4 parts of iron oxide, 4 parts of talc, 8 parts of strontium chromate, 9 parts of tributyl phosphate, and 2 8 parts of alcohol monobutyl ether, 16 parts of sodium carboxymethyl cellulose, 8 parts of dibutyl phthalate, 6 parts of ethylene glycol, 12 parts of phosphoric acid, 12 parts of sodium nitrate, 4 parts of methanol, 20 parts of ammonium acrylate, 6 parts of isopropyl acrylate, 15 parts of butyl acetate, 10 parts of ammonium persulfate, and 5 parts of dry triol.
实施例3Example 3
一种机械设备用防腐蚀涂料，包括如下质量份数的组分：环氧‐丙烯酸11份，氧化铁3.5份，滑石粉3.5份，铬酸锶7份，磷酸三丁酯8份，乙二醇一丁醚6份，羟甲基纤维素钠14份，邻苯二甲酸二丁酯7份，乙二醇5份，磷酸铵11份，硝酸钠10份，甲醇3.5份，丙烯酸铵17份，丙烯酸异丙酯5份，乙酸丁酯14份，过硫酸铵9份，干三醇4份。An anticorrosive coating for mechanical equipment, comprising the following parts by mass: 11 parts of epoxy-acrylic acid, 3.5 parts of iron oxide, 3.5 parts of talc, 7 parts of strontium chromate, 8 parts of tributyl phosphate, and 2 6 parts of alcohol monobutyl ether, 14 parts of sodium carboxymethyl cellulose, 7 parts of dibutyl phthalate, 5 parts of ethylene glycol, 11 parts of ammonium phosphate, 10 parts of sodium nitrate, 3.5 parts of methanol, 17 parts of ammonium acrylate 5 parts of isopropyl acrylate, 14 parts of butyl acetate, 9 parts of ammonium persulfate, and 4 parts of dry triol.
本发明提供的防腐蚀涂料，成本低，制作工艺简单，可以对有效防止酸碱腐蚀，适用于各类机械设备。The anti-corrosion coating provided by the invention has low cost, simple manufacturing process, can effectively prevent acid-base corrosion, and is suitable for various mechanical equipments.
以上所述，仅是本发明的较佳实施例而已，并非对本发明作任何形式上的限制，虽然本发明已以较佳实施例揭露如上，然而并非用以限定本发明，任何熟悉本专业的技术人员，在不脱离本发明技术方案范围内，当可利用上述揭示的技术内容作出些许更动或修饰为等同变化的等效实施例，但凡是未脱离本发明技术方案的内容，依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与修饰，均仍属于本发明技术方案的范围内。
The above is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention. Although the present invention has been disclosed in the above preferred embodiments, it is not intended to limit the present invention. The skilled person can make some modifications or modifications to the equivalent embodiments by using the above-disclosed technical contents without departing from the technical scope of the present invention, but the present invention does not deviate from the technical solution of the present invention. Technical Substantials Any simple modifications, equivalent changes and modifications made to the above embodiments are still within the scope of the technical solutions of the present invention.
Claims (3)
- 一种机械设备用防腐蚀涂料，其特征在于：包括如下质量份数的组分：环氧‐丙烯酸8～12份，氧化铁2～4份，滑石粉2～4份，铬酸锶4～8份，磷酸三丁酯6～9份，乙二醇一丁醚2～8份，羟甲基纤维素钠8～16份，邻苯二甲酸二丁酯4～8份，乙二醇2～6份，磷酸铵8～12份，硝酸钠4～12份，甲醇2～4份，丙烯酸铵10～20份，丙烯酸异丙酯3～6份，乙酸丁酯12～15份，过硫酸铵5～10份，干三醇2～5份。The invention relates to an anticorrosive coating for mechanical equipment, which comprises the following components: 5 to 12 parts of epoxy-acrylic acid, 2 to 4 parts of iron oxide, 2 to 4 parts of talc, and 4 to 4 of strontium chromate. 8 parts, 6-9 parts of tributyl phosphate, 2-8 parts of ethylene glycol monobutyl ether, 8-16 parts of sodium carboxymethyl cellulose, 4-8 parts of dibutyl phthalate, ethylene glycol 2 ~6 parts, 8 to 12 parts of ammonium phosphate, 4 to 12 parts of sodium nitrate, 2 to 4 parts of methanol, 10 to 20 parts of ammonium acrylate, 3 to 6 parts of isopropyl acrylate, 12 to 15 parts of butyl acetate, persulfuric acid 5 to 10 parts of ammonium and 2 to 5 parts of dry triol.
- 根据权利要求1所述的一种机械设备用防腐蚀涂料，其特征在于：包括如下质量份数的组分：环氧‐丙烯酸10～12份，氧化铁3～4份，滑石粉3～4份，铬酸锶6～8份，磷酸三丁酯7～9份，乙二醇一丁醚4～8份，羟甲基纤维素钠10～16份，邻苯二甲酸二丁酯6～8份，乙二醇4～6份，磷酸铵10～12份，硝酸钠8～12份，甲醇3～4份，丙烯酸铵15～20份，丙烯酸异丙酯4～6份，乙酸丁酯13～15份，过硫酸铵7～10份，干三醇3～5份。The anticorrosive paint for mechanical equipment according to claim 1, characterized by comprising the following components by mass: 10 to 12 parts of epoxy-acrylic acid, 3 to 4 parts of iron oxide, and talc powder 3 to 4 Servings, 6-8 parts of strontium chromate, 7-9 parts of tributyl phosphate, 4-8 parts of ethylene glycol monobutyl ether, 10-16 parts of sodium carboxymethyl cellulose, and 6-butyl phthalate 8 parts, 4 to 6 parts of ethylene glycol, 10 to 12 parts of ammonium phosphate, 8 to 12 parts of sodium nitrate, 3 to 4 parts of methanol, 15 to 20 parts of ammonium acrylate, 4 to 6 parts of isopropyl acrylate, butyl acetate 13 to 15 parts, 7 to 10 parts of ammonium persulfate, and 3 to 5 parts of dry triol.
- 根据权利要求1所述的一种机械设备用防腐蚀涂料，其特征在于：包括如下质量份数的组分：环氧‐丙烯酸11份，氧化铁3.5份，滑石粉3.5份，铬酸锶7份，磷酸三丁酯8份，乙二醇一丁醚6份，羟甲基纤维素钠14份，邻苯二甲酸二丁酯7份，乙二醇5份，磷酸铵11份，硝酸钠10份，甲醇3.5份，丙烯酸铵17份，丙烯酸异丙酯5份，乙酸丁酯14份，过硫酸铵9份，干三醇4份。 The anticorrosive paint for mechanical equipment according to claim 1, comprising the following components by mass: 11 parts of epoxy-acrylic acid, 3.5 parts of iron oxide, 3.5 parts of talc, and strontium chromate 7 Parts, 8 parts of tributyl phosphate, 6 parts of ethylene glycol monobutyl ether, 14 parts of sodium carboxymethyl cellulose, 7 parts of dibutyl phthalate, 5 parts of ethylene glycol, 11 parts of ammonium phosphate, sodium nitrate 10 parts, 3.5 parts of methanol, 17 parts of ammonium acrylate, 5 parts of isopropyl acrylate, 14 parts of butyl acetate, 9 parts of ammonium persulfate, and 4 parts of dry triol.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710472715.0 | 2017-06-21 | ||
| CN201710472715.0A CN107245259A (en) | 2017-06-21 | 2017-06-21 | A kind of plant equipment anticorrosive coating |
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| WO2018232823A1 true WO2018232823A1 (en) | 2018-12-27 |
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| PCT/CN2017/094184 WO2018232823A1 (en) | 2017-06-21 | 2017-07-24 | Anti-corrosion coating for mechanical equipment |
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|---|---|---|---|---|
| CN1821331A (en) * | 2006-03-20 | 2006-08-23 | 王新成 | Anti-corrosion paint capable of coating with rust |
| CN1927968A (en) * | 2006-09-05 | 2007-03-14 | 英志祥 | Water industrial paint based on organosilicon acrylic acid epoxy ester water dispersion and preparation method thereof |
| CN104087070A (en) * | 2014-07-15 | 2014-10-08 | 杨美 | Anti-corrosion coating |
| CN106243808A (en) * | 2016-08-17 | 2016-12-21 | 张娟 | Anticorrosion gluing |
-
2017
- 2017-06-21 CN CN201710472715.0A patent/CN107245259A/en active Pending
- 2017-07-24 WO PCT/CN2017/094184 patent/WO2018232823A1/en active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1821331A (en) * | 2006-03-20 | 2006-08-23 | 王新成 | Anti-corrosion paint capable of coating with rust |
| CN1927968A (en) * | 2006-09-05 | 2007-03-14 | 英志祥 | Water industrial paint based on organosilicon acrylic acid epoxy ester water dispersion and preparation method thereof |
| CN104087070A (en) * | 2014-07-15 | 2014-10-08 | 杨美 | Anti-corrosion coating |
| CN106243808A (en) * | 2016-08-17 | 2016-12-21 | 张娟 | Anticorrosion gluing |
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| CN107245259A (en) | 2017-10-13 |
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