CN105907208A - Water-based metal anticorrosion thermal insulation compound paint and preparation method thereof - Google Patents
Water-based metal anticorrosion thermal insulation compound paint and preparation method thereof Download PDFInfo
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- CN105907208A CN105907208A CN201610462692.0A CN201610462692A CN105907208A CN 105907208 A CN105907208 A CN 105907208A CN 201610462692 A CN201610462692 A CN 201610462692A CN 105907208 A CN105907208 A CN 105907208A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses water-based metal anticorrosion thermal insulation compound paint. The water-based metal anticorrosion thermal insulation compound paint is prepared from, by weight, 60-90 parts of water-based acrylic resin, 3-10 parts of Carbomer resin, 20-35 parts of composite heat insulation agent, 3-8 parts of modified polyurea, 10-20 parts of inorganic filler, 3-6 parts of wetting dispersant, 8-15 parts of gaseous phase aluminum oxide, 2-10 parts of zinc oxide, 1-5 parts of low molecular polyethylene wax, 1-2 parts of 1.5% phytic acid solution, 2-8 parts of propylene glycol, 0.5-1 part of benzotriazole, 3-20 parts of other additives and 20-30 parts of water. Meanwhile, the invention discloses a preparation method of the water-based metal anticorrosion thermal insulation compound paint. The compound paint prepared through the raw material formula and the preparation method has good metal anticorrosion performance, environment friendliness and heat insulation performance at the same time.
Description
Technical field
The present invention relates to a kind of composite paint, be specifically related to a kind of water-based metal anticorrosive heat insulating composite paint.
Background technology
Corrosion of metal is the phenomenon that metal is occurred by electrochemistry or the chemical action of surrounding medium to destroy.Metal erosion, throughout the every field of national economy, brings massive losses to national economy.In the country that industry is flourishing, the direct economic loss that metal erosion causes accounts for the 1%~4% of total value of production in national economy, accounts for the 20% of total output due to the iron and steel of rust corrosion every year, and the equipment that there are about 30% is scrapped because of metal erosion.And in China, the economic loss caused due to metal erosion every year accounts for the 4% of gross national product.Just because of this, rust-preventing characteristic and resistant to chemical media corrosive metal anti-corrosion paint goods with excellence are able to fast development, are widely used in all trades and professions.But existing anti-corrosion of metal composite paint many employings organic solvent is as base solvent, the feature of environmental protection is poor, use the most on a large scale and easily surrounding is affected greatly, and the heat-proof quality of existing metal anti-corrosion paint goods is poor, for the metallic article that especially uses under the conditions of Exposure to Sunlight under the conditions of outdoor application usually because high temperature brings potential safety hazard, conventional water drenches or air-conditioning temperature-reducing can cause a large amount of wastes of the energy.
Summary of the invention
Not enough for prior art, the invention provides a kind of metal heat insulating and corrosion composite paint with good environmental-protecting performance and preparation method thereof.
The present invention solves the technical scheme of above-mentioned technical problem employing: a kind of water-based metal anticorrosive heat insulating composite paint, including the raw material of following parts by weight: water-borne acrylic resin 60 ~ 90 parts, carbomer 3 ~ 10 parts, compound heat-insulation agent 20 ~ 35 parts, modified polyurea 3 ~ 8 parts, inorganic filler 10 ~ 20 parts, wetting dispersing agent 3 ~ 6 parts, 8 ~ 15 parts of gaseous oxidation aluminum, zinc oxide 2 ~ 10 parts, low-molecular polyethylene wax 1 ~ 5 part, the plant acid solution 1 ~ 2 part of 1.5% concentration, propylene glycol 2 ~ 8 parts, benzotriazole 0.5 ~ 1 part, other auxiliary agents 3 ~ 20 parts and 20 ~ 30 parts of water;
Described compound heat-insulation agent is hollow glass micropearl and the complex of nano ceramics heat-insulating powder, and its mass parts is than for 1:2 ~ 4;
The particle diameter of described hollow glass micropearl is 1000 ~ 1500 mesh.
Further, described wetting dispersing agent is wetting dispersing agent h-9040 or wetting dispersing agent h-9060.
Further, described inorganic filler is nanometer hydroxyapatite powder and nano mica powder, and its mass parts ratio is 1 ~ 3:1.
Further, other described auxiliary agents are one or more in defoamer, auxiliary rheological agents, film former, anti-sudden strain of a muscle rust agent.
The preparation method of described a kind of water-based metal anticorrosive heat insulating composite paint, comprises the following steps:
After being on the waiting list raw material according to described parts by weight, after wetting dispersing agent, the plant acid solution of 1.5% concentration and propylene glycol and water mixing and stirring, add compound heat-insulation agent vibrating dispersion to uniform state, then water-borne acrylic resin, carbomer, modified polyurea, low-molecular polyethylene wax, gaseous oxidation aluminum, inorganic filler, benzotriazole, zinc oxide and other auxiliary agents it are sequentially added into, ensure that added raw material, in the state of stirring, obtains the composite paint of the present invention after filtering when adding raw material every time.
Compared with prior art, the beneficial effect that the present invention possesses:
1) present invention is proved by rational raw material choice and many experiments, and the composite paint prepared by composition of raw materials and the preparation method of the present invention has good anticorrosive metal;
2) there is the good feature of environmental protection, by selecting the raw material that the feature of environmental protection is excellent, and using water as solvent, it is ensured that the anticorrosion composite paint of the present invention possesses the good feature of environmental protection;
3) there is good heat-proof quality, the present invention with the addition of compound heat-insulation agent, by adding that heat conductivity is low, physicochemical property is stable, thermal and insulating performance is good, do not fire, the hollow glass micropearl of asepsis environment-protecting and nano ceramics heat-insulating powder, coordinate other auxiliary agents, make the composite paint of the present invention possess excellent heat-proof quality.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1: a kind of water-based metal anticorrosive heat insulating composite paint, including the raw material of following parts by weight: water-borne acrylic resin 75 parts, carbomer 6 parts, compound heat-insulation agent 28 parts, modified polyurea 6 parts, inorganic filler 15 parts, wetting dispersing agent 5 parts, 12 parts of gaseous oxidation aluminum, zinc oxide 6 parts, low-molecular polyethylene wax 3 parts, the plant acid solution 1.5 parts of 1.5% concentration, propylene glycol 5 parts, benzotriazole 0.5 part, other auxiliary agents 12 parts and 25 parts of water;
Described compound heat-insulation agent is hollow glass micropearl and the complex of nano ceramics heat-insulating powder, and its mass parts is than for 1:3;The particle diameter of described hollow glass micropearl is 1000 ~ 1500 mesh.
Further, described wetting dispersing agent is wetting dispersing agent h-9040.
Further, described inorganic filler is nanometer hydroxyapatite powder and nano mica powder, and its mass parts is than for 2:1.
Further, other described auxiliary agents are defoamer, film former and anti-sudden strain of a muscle rust agent.
The preparation method of described a kind of water-based metal anticorrosive heat insulating composite paint, comprises the following steps:
After being on the waiting list raw material according to described parts by weight, after wetting dispersing agent, the plant acid solution of 1.5% concentration and propylene glycol and water mixing and stirring, add compound heat-insulation agent vibrating dispersion to uniform state, then water-borne acrylic resin, carbomer, modified polyurea, low-molecular polyethylene wax, gaseous oxidation aluminum, inorganic filler, benzotriazole, zinc oxide and other auxiliary agents it are sequentially added into, ensure that added raw material, in the state of stirring, obtains the composite paint of the present invention after filtering when adding raw material every time.
Embodiment 2: a kind of water-based metal anticorrosive heat insulating composite paint, including the raw material of following parts by weight: water-borne acrylic resin 60 parts, carbomer 3 parts, compound heat-insulation agent 20 parts, modified polyurea 3 parts, inorganic filler 10 parts, wetting dispersing agent 3 parts, 8 parts of gaseous oxidation aluminum, zinc oxide 2 parts, low-molecular polyethylene wax 1 part, the plant acid solution 1 part of 1.5% concentration, propylene glycol 2 parts, benzotriazole 0.5 part, other auxiliary agents 3 parts and 20 parts of water;
Described compound heat-insulation agent is hollow glass micropearl and the complex of nano ceramics heat-insulating powder, and its mass parts is than for 1:4;The particle diameter of described hollow glass micropearl is 1000 ~ 1500 mesh.
Further, described wetting dispersing agent is wetting dispersing agent h-9060;Described inorganic filler is nanometer hydroxyapatite powder and nano mica powder, and its mass parts is than for 1:1;Other described auxiliary agents are auxiliary rheological agents and film former.
The preparation method of described a kind of water-based metal anticorrosive heat insulating composite paint, its concrete steps are with embodiment 1.
Embodiment 3: a kind of water-based metal anticorrosive heat insulating composite paint, including the raw material of following parts by weight: water-borne acrylic resin 90 parts, carbomer 10 parts, compound heat-insulation agent 35 parts, modified polyurea 8 parts, inorganic filler 20 parts, wetting dispersing agent 6 parts, 15 parts of gaseous oxidation aluminum, zinc oxide 10 parts, low-molecular polyethylene wax 5 parts, the plant acid solution 2 parts of 1.5% concentration, propylene glycol 8 parts, benzotriazole 1 part, other auxiliary agents 20 parts and 30 parts of water;
Described compound heat-insulation agent is hollow glass micropearl and the complex of nano ceramics heat-insulating powder, and its mass parts is than for 1:2;The particle diameter of described hollow glass micropearl is 1000 ~ 1500 mesh.
Further, described wetting dispersing agent is wetting dispersing agent h-9040;Described inorganic filler is nanometer hydroxyapatite powder and nano mica powder, and its mass parts is than for 3:1;Other described auxiliary agents are defoamer and auxiliary rheological agents.
The preparation method of described a kind of water-based metal anticorrosive heat insulating composite paint, its concrete steps are with embodiment 1.
Embodiment 4: a kind of water-based metal anticorrosive heat insulating composite paint, including the raw material of following parts by weight: water-borne acrylic resin 90 parts, carbomer 3 parts, compound heat-insulation agent 35 parts, modified polyurea 3 parts, inorganic filler 20 parts, wetting dispersing agent 3 parts, 15 parts of gaseous oxidation aluminum, zinc oxide 2 parts, low-molecular polyethylene wax 5 parts, the plant acid solution 1 part of 1.5% concentration, propylene glycol 8 parts, benzotriazole 0.5 part, other auxiliary agents 20 parts and 20 parts of water;
Described compound heat-insulation agent is hollow glass micropearl and the complex of nano ceramics heat-insulating powder, and its mass parts is than for 2:5;The particle diameter of described hollow glass micropearl is 1000 ~ 1500 mesh.
Further, described wetting dispersing agent is wetting dispersing agent h-9040;Described inorganic filler is nanometer hydroxyapatite powder and nano mica powder, and its mass parts is than for 3:2;Other described auxiliary agents are auxiliary rheological agents, film former and anti-sudden strain of a muscle rust agent.
The preparation method of described a kind of water-based metal anticorrosive heat insulating composite paint, its concrete steps are with embodiment 1.
Embodiment 5: a kind of water-based metal anticorrosive heat insulating composite paint, including the raw material of following parts by weight: water-borne acrylic resin 70 parts, carbomer 5 parts, compound heat-insulation agent 25 parts, modified polyurea 5 parts, inorganic filler 12 parts, wetting dispersing agent 5 parts, 10 parts of gaseous oxidation aluminum, zinc oxide 5 parts, low-molecular polyethylene wax 2 parts, the plant acid solution 1 part of 1.5% concentration, propylene glycol 5 parts, benzotriazole 1 part, other auxiliary agents 10 parts and 28 parts of water;
Described compound heat-insulation agent is hollow glass micropearl and the complex of nano ceramics heat-insulating powder, and its mass parts is than for 2:7;The particle diameter of described hollow glass micropearl is 1000 ~ 1500 mesh.
Further, described wetting dispersing agent is wetting dispersing agent h-9040;Described inorganic filler is nanometer hydroxyapatite powder and nano mica powder, and its mass parts is than for 5:2;Other described auxiliary agents are defoamer, auxiliary rheological agents, film former and anti-sudden strain of a muscle rust agent.
The preparation method of described a kind of water-based metal anticorrosive heat insulating composite paint, its concrete steps are with embodiment 1.
Comparative example: a kind of water-based metal anticorrosive heat insulating composite paint, including the raw material of following parts by weight: water-borne acrylic resin 75 parts, carbomer 6 parts, modified polyurea 6 parts, inorganic filler 15 parts, wetting dispersing agent 5 parts, 12 parts of gaseous oxidation aluminum, zinc oxide 6 parts, low-molecular polyethylene wax 3 parts, the plant acid solution 1.5 parts of 1.5% concentration, propylene glycol 5 parts, benzotriazole 0.5 part, other auxiliary agents 12 parts and 25 parts of water.
Further, described wetting dispersing agent is wetting dispersing agent h-9040.
Further, described inorganic filler is nanometer hydroxyapatite powder and nano mica powder, and its mass parts is than for 2:1.
Further, other described auxiliary agents are defoamer, film former and anti-sudden strain of a muscle rust agent.
The preparation method of described a kind of water-based metal anticorrosive heat insulating composite paint, comprises the following steps:
After being on the waiting list raw material according to described parts by weight, after wetting dispersing agent, the plant acid solution of 1.5% concentration and propylene glycol and water mixing and stirring, it is sequentially added into water-borne acrylic resin, carbomer, modified polyurea, low-molecular polyethylene wax, gaseous oxidation aluminum, inorganic filler, benzotriazole, zinc oxide and other auxiliary agents, ensure that added raw material, in the state of stirring, obtains the composite paint of the present invention after filtering when adding raw material every time.
The composite paint of embodiments of the invention 1-5 and comparative example gained being coated on the steel plate cleared up, after natural drying, carry out performance test according to corresponding country's mark testing standard, concrete outcome is as shown in the table:
Performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example |
Adhesive force/level | 1 | 1-2 | 1 | 1 | 1 | 1-2 |
Acid resistance/5%H2SO4·5d | Normally | Normally | Normally | Normally | Normally | Play microvesicle |
Alkali resistance/5%NaHO 96h | Normally | Normally | Normally | Normally | Normally | Play microvesicle |
Salt water resistance/3%NaCl 16d | Normally | Normally | Normally | Normally | Normally | Play microvesicle |
According to the standard of JG/T234-2008, the composite paint of embodiment 1-5 and comparative example gained is thermally shielded the test of performance, test result is, contrast with the blank steel plate of standard testing, the heat insulation temperature difference after the balance that embodiment 1-5 obtains is 8 ~ 10 DEG C, and the heat insulation temperature difference after the balance that comparative example obtains is 2.8 DEG C, the effect of heat insulation of the composite paint of embodiment 1-5 is substantially better than the composite paint of comparative example.
Claims (5)
1. a water-based metal anticorrosive heat insulating composite paint, it is characterized in that, including the raw material of following parts by weight: water-borne acrylic resin 60 ~ 90 parts, carbomer 3 ~ 10 parts, compound heat-insulation agent 20 ~ 35 parts, modified polyurea 3 ~ 8 parts, inorganic filler 10 ~ 20 parts, wetting dispersing agent 3 ~ 6 parts, 8 ~ 15 parts of gaseous oxidation aluminum, zinc oxide 2 ~ 10 parts, low-molecular polyethylene wax 1 ~ 5 part, the plant acid solution 1 ~ 2 part of 1.5% concentration, propylene glycol 2 ~ 8 parts, benzotriazole 0.5 ~ 1 part, other auxiliary agents 3 ~ 20 parts and 20 ~ 30 parts of water;
Described compound heat-insulation agent is hollow glass micropearl and the complex of nano ceramics heat-insulating powder, and its mass parts is than for 1:2 ~ 4;
The particle diameter of described hollow glass micropearl is 1000 ~ 1500 mesh.
A kind of water-based metal anticorrosive heat insulating composite paint the most according to claim 1, it is characterised in that: described wetting dispersing agent is wetting dispersing agent h-9040 or wetting dispersing agent h-9060.
A kind of water-based metal anticorrosive heat insulating composite paint the most according to claim 1, it is characterised in that: described inorganic filler is nanometer hydroxyapatite powder and nano mica powder, and its mass parts ratio is 1 ~ 3:1.
A kind of water-based metal anticorrosive heat insulating composite paint the most according to claim 1, it is characterised in that: other described auxiliary agents are one or more in defoamer, auxiliary rheological agents, film former, anti-sudden strain of a muscle rust agent.
5. the preparation method of a kind of water-based metal anticorrosive heat insulating composite paint described in any one of claim 1-4, it is characterised in that comprise the following steps:
After being on the waiting list raw material according to described parts by weight, after wetting dispersing agent, the plant acid solution of 1.5% concentration and propylene glycol and water mixing and stirring, add compound heat-insulation agent vibrating dispersion to uniform state, then water-borne acrylic resin, carbomer, modified polyurea, low-molecular polyethylene wax, gaseous oxidation aluminum, inorganic filler, benzotriazole, zinc oxide and other auxiliary agents it are sequentially added into, ensure that added raw material, in the state of stirring, obtains the composite paint of the present invention after filtering when adding raw material every time.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106854423A (en) * | 2016-12-05 | 2017-06-16 | 钦州市钦南区生产力促进中心 | A kind of metal coating and preparation method thereof |
CN107163791A (en) * | 2017-05-25 | 2017-09-15 | 周淑华 | A kind of composite paint |
CN107778934A (en) * | 2017-09-25 | 2018-03-09 | 安徽瑞田机械有限公司 | A kind of cutting machine metal protection paint and preparation method thereof |
CN107793879A (en) * | 2017-09-25 | 2018-03-13 | 安徽瑞田机械有限公司 | A kind of electric welding machine anti-corrosion protection paint and preparation method thereof |
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CN101665645A (en) * | 2009-10-19 | 2010-03-10 | 华南理工大学 | Nanometer compound water-based heat insulation anticorrosion paint used for metal and preparation method thereof |
CN103819989A (en) * | 2014-02-24 | 2014-05-28 | 浙江大学 | Aqueous anticorrosive heat-insulation paint and preparation method |
JP2015168729A (en) * | 2014-03-05 | 2015-09-28 | 日本化学塗料株式会社 | Aqueous antirust paint and metallic product coated with aqueous antirust paint |
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Patent Citations (3)
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CN101665645A (en) * | 2009-10-19 | 2010-03-10 | 华南理工大学 | Nanometer compound water-based heat insulation anticorrosion paint used for metal and preparation method thereof |
CN103819989A (en) * | 2014-02-24 | 2014-05-28 | 浙江大学 | Aqueous anticorrosive heat-insulation paint and preparation method |
JP2015168729A (en) * | 2014-03-05 | 2015-09-28 | 日本化学塗料株式会社 | Aqueous antirust paint and metallic product coated with aqueous antirust paint |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106854423A (en) * | 2016-12-05 | 2017-06-16 | 钦州市钦南区生产力促进中心 | A kind of metal coating and preparation method thereof |
CN107163791A (en) * | 2017-05-25 | 2017-09-15 | 周淑华 | A kind of composite paint |
CN107778934A (en) * | 2017-09-25 | 2018-03-09 | 安徽瑞田机械有限公司 | A kind of cutting machine metal protection paint and preparation method thereof |
CN107793879A (en) * | 2017-09-25 | 2018-03-13 | 安徽瑞田机械有限公司 | A kind of electric welding machine anti-corrosion protection paint and preparation method thereof |
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