WO2018190642A3 - 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 산화적 탈수소화용 반응기 및 산화적 탈수소화 방법 - Google Patents

산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 산화적 탈수소화용 반응기 및 산화적 탈수소화 방법 Download PDF

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Publication number
WO2018190642A3
WO2018190642A3 PCT/KR2018/004273 KR2018004273W WO2018190642A3 WO 2018190642 A3 WO2018190642 A3 WO 2018190642A3 KR 2018004273 W KR2018004273 W KR 2018004273W WO 2018190642 A3 WO2018190642 A3 WO 2018190642A3
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Prior art keywords
oxidative dehydrogenation
reactor
reaction
catalyst system
catalyst
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PCT/KR2018/004273
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English (en)
French (fr)
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WO2018190642A9 (ko
WO2018190642A2 (ko
Inventor
서명지
고동현
강전한
남현석
한상진
김성민
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(주) 엘지화학
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Priority claimed from KR1020180042151A external-priority patent/KR102224278B1/ko
Application filed by (주) 엘지화학 filed Critical (주) 엘지화학
Priority to EP18784966.6A priority Critical patent/EP3488921A4/en
Priority to US16/327,151 priority patent/US10946364B2/en
Priority to CN201880003266.8A priority patent/CN109641187A/zh
Priority to JP2019510770A priority patent/JP6733099B2/ja
Publication of WO2018190642A2 publication Critical patent/WO2018190642A2/ko
Publication of WO2018190642A3 publication Critical patent/WO2018190642A3/ko
Publication of WO2018190642A9 publication Critical patent/WO2018190642A9/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/12—Alkadienes
    • C07C11/16—Alkadienes with four carbon atoms
    • C07C11/167—1, 3-Butadiene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 산화적 탈수소화용 반응기 및 산화적 탈수소화 방법에 관한 것으로, 보다 상세하게는 산화적 탈수소화 반응용 촉매를 고정층 반응기에 n개(n은 2 이상의 정수)의 단으로 충진하되, 각각의 단이 수학식 1 및 2를 만족하도록 충진하여 반응 시 반응기 내부의 발열이 효과적으로 제어되어 전환율, 선택도, 수율 등이 크게 개선되는 효과를 제공할 수 있으며, 촉매의 열화 현상 저감으로 촉매의 장기 안정성이 향상되는 효과를 제공하는 촉매 시스템 등에 관한 것이다.
PCT/KR2018/004273 2017-04-12 2018-04-12 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 산화적 탈수소화용 반응기 및 산화적 탈수소화 방법 WO2018190642A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP18784966.6A EP3488921A4 (en) 2017-04-12 2018-04-12 CATALYST SYSTEM FOR OXIDATIVE DEHYDRATION REACTION, REACTOR FOR OXIDATIVE DEHYDRATION AND METHOD FOR OXIDATIVE DEHYDRATION
US16/327,151 US10946364B2 (en) 2017-04-12 2018-04-12 Catalyst system for oxidative dehydrogenation, reactor for oxidative dehydrogenation including catalyst system, and method of performing oxidative dehydrogenation using reactor
CN201880003266.8A CN109641187A (zh) 2017-04-12 2018-04-12 用于氧化脱氢反应的催化剂体系、包括其的用于氧化脱氢的反应器、以及氧化脱氢方法
JP2019510770A JP6733099B2 (ja) 2017-04-12 2018-04-12 酸化的脱水素化反応用触媒システム、それを含む酸化的脱水素化用反応器及び酸化的脱水素化方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2017-0047504 2017-04-12
KR20170047504 2017-04-12
KR1020180042151A KR102224278B1 (ko) 2017-04-12 2018-04-11 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 산화적 탈수소화용 반응기 및 산화적 탈수소화 방법
KR10-2018-0042151 2018-04-11

Publications (3)

Publication Number Publication Date
WO2018190642A2 WO2018190642A2 (ko) 2018-10-18
WO2018190642A3 true WO2018190642A3 (ko) 2018-12-20
WO2018190642A9 WO2018190642A9 (ko) 2019-01-31

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PCT/KR2018/004273 WO2018190642A2 (ko) 2017-04-12 2018-04-12 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 산화적 탈수소화용 반응기 및 산화적 탈수소화 방법

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102262896B1 (ko) * 2017-11-30 2021-06-09 주식회사 엘지화학 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 부타디엔 제조용 반응기 및 1,3-부타디엔의 제조방법
KR102353146B1 (ko) 2018-03-13 2022-01-18 주식회사 엘지화학 페라이트계 코팅 촉매의 제조방법 및 이를 이용한 부타디엔의 제조방법

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100847206B1 (ko) * 2007-05-10 2008-07-17 에스케이에너지 주식회사 아연 페라이트 촉매, 이의 제조방법 및 이를 이용한1,3-부타디엔의 제조방법
US20110004041A1 (en) * 2008-03-28 2011-01-06 Sk Energy Co., Ltd. Method of producing 1,3-butadiene from n-butene using continuous-flow dual-bed reactor
KR20120009687A (ko) * 2010-07-20 2012-02-02 에스케이이노베이션 주식회사 혼성 망간 페라이트가 코팅된 촉매, 이의 제조방법 및 이를 이용한 1,3-부타디엔의 제조방법
KR20130046458A (ko) * 2011-10-28 2013-05-08 주식회사 엘지화학 연속 반응기를 이용한 1,3-부타디엔의 제조방법
KR20140082869A (ko) * 2012-12-18 2014-07-03 에스케이이노베이션 주식회사 혼성 망간 페라이트 허니컴형 촉매, 이의 제조방법 및 이를 이용한 1,3-부타디엔의 제조방법

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100847206B1 (ko) * 2007-05-10 2008-07-17 에스케이에너지 주식회사 아연 페라이트 촉매, 이의 제조방법 및 이를 이용한1,3-부타디엔의 제조방법
US20110004041A1 (en) * 2008-03-28 2011-01-06 Sk Energy Co., Ltd. Method of producing 1,3-butadiene from n-butene using continuous-flow dual-bed reactor
KR20120009687A (ko) * 2010-07-20 2012-02-02 에스케이이노베이션 주식회사 혼성 망간 페라이트가 코팅된 촉매, 이의 제조방법 및 이를 이용한 1,3-부타디엔의 제조방법
KR20130046458A (ko) * 2011-10-28 2013-05-08 주식회사 엘지화학 연속 반응기를 이용한 1,3-부타디엔의 제조방법
KR20140082869A (ko) * 2012-12-18 2014-07-03 에스케이이노베이션 주식회사 혼성 망간 페라이트 허니컴형 촉매, 이의 제조방법 및 이를 이용한 1,3-부타디엔의 제조방법

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WO2018190642A2 (ko) 2018-10-18

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