WO2018159976A3 - 광학 재료용 실록산 티올 올리고머 및 실록산 (메트)아크릴레이트 올리고머 - Google Patents

광학 재료용 실록산 티올 올리고머 및 실록산 (메트)아크릴레이트 올리고머 Download PDF

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Publication number
WO2018159976A3
WO2018159976A3 PCT/KR2018/002373 KR2018002373W WO2018159976A3 WO 2018159976 A3 WO2018159976 A3 WO 2018159976A3 KR 2018002373 W KR2018002373 W KR 2018002373W WO 2018159976 A3 WO2018159976 A3 WO 2018159976A3
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WO
WIPO (PCT)
Prior art keywords
siloxane
thiol
meth
oligomers
lenses
Prior art date
Application number
PCT/KR2018/002373
Other languages
English (en)
French (fr)
Other versions
WO2018159976A2 (ko
Inventor
홍승모
김상묵
서현명
심종민
신정환
Original Assignee
에스케이씨 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020170026231A external-priority patent/KR101928535B1/ko
Priority claimed from KR1020170026149A external-priority patent/KR101890332B1/ko
Priority claimed from KR1020170026261A external-priority patent/KR101813258B1/ko
Priority claimed from KR1020170026175A external-priority patent/KR20180099137A/ko
Application filed by 에스케이씨 주식회사 filed Critical 에스케이씨 주식회사
Publication of WO2018159976A2 publication Critical patent/WO2018159976A2/ko
Publication of WO2018159976A3 publication Critical patent/WO2018159976A3/ko

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00—Producing optical elements, e.g. lenses or prisms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • G—PHYSICS
    • G02—OPTICS
    • G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00—Optical parts
    • G02C7/02—Lenses; Lens systems ; Methods of designing lenses

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ophthalmology & Optometry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

실시예는 광학 재료용 실록산 티올 올리고머 및 실록산 (메트)아크릴레이트 올리고머에 관한 것으로, 실시예에 따른 실록산 티올 올리고머 및 실록산 (메트)아크릴레이트 올리고머는 유리의 기본 화학구조인 Si-O- 결합을 티올 구조 및 아크릴 구조 내에 함유함으로써, 플라스틱 렌즈의 장점을 유지하면서 유리렌즈의 장점인 높은 투명도 및 아베수, 내열성 등의 특성을 제공할 수 있다. 또한, 상기 실록산 티올 올리고머 및 실록산 (메트)아크릴레이트 올리고머는 금속 성분이 공중합되어 포함될 수 있으므로, 우수한 굴절률을 가질 뿐만 아니라, UV 영역이 자동으로 차단되어 자외선 흡수제를 사용하지 않아도 내광성을 확보할 수 있으므로, 안경렌즈, 카메라 렌즈 등 각종 플라스틱 렌즈의 제조에 유용하게 사용될 수 있다.
PCT/KR2018/002373 2017-02-28 2018-02-27 광학 재료용 실록산 티올 올리고머 및 실록산 (메트)아크릴레이트 올리고머 WO2018159976A2 (ko)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
KR10-2017-0026149 2017-02-28
KR10-2017-0026175 2017-02-28
KR10-2017-0026261 2017-02-28
KR1020170026231A KR101928535B1 (ko) 2017-02-28 2017-02-28 광학 재료용 실록산 (메트)아크릴레이트 올리고머
KR1020170026149A KR101890332B1 (ko) 2017-02-28 2017-02-28 광학 재료용 실록산 티올 올리고머
KR10-2017-0026231 2017-02-28
KR1020170026261A KR101813258B1 (ko) 2017-02-28 2017-02-28 광학 재료용 실록산 티올 올리고머
KR1020170026175A KR20180099137A (ko) 2017-02-28 2017-02-28 광학 재료용 실록산 (메트)아크릴레이트 올리고머

Publications (2)

Publication Number Publication Date
WO2018159976A2 WO2018159976A2 (ko) 2018-09-07
WO2018159976A3 true WO2018159976A3 (ko) 2018-10-25

Family

ID=63370473

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2018/002373 WO2018159976A2 (ko) 2017-02-28 2018-02-27 광학 재료용 실록산 티올 올리고머 및 실록산 (메트)아크릴레이트 올리고머

Country Status (1)

Country Link
WO (1) WO2018159976A2 (ko)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070064442A (ko) * 2004-11-16 2007-06-20 미쓰이 가가쿠 가부시키가이샤 금속 함유 화합물 및 그 용도
KR20130017057A (ko) * 2011-08-09 2013-02-19 한국과학기술원 광학용 투명 하이브리드 재료
CN105860083A (zh) * 2016-04-14 2016-08-17 顺德职业技术学院 改性乙烯基硅树脂及含改性乙烯基硅树脂的有机硅封胶的制备方法
KR101813258B1 (ko) * 2017-02-28 2017-12-29 에스케이씨 주식회사 광학 재료용 실록산 티올 올리고머

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070064442A (ko) * 2004-11-16 2007-06-20 미쓰이 가가쿠 가부시키가이샤 금속 함유 화합물 및 그 용도
KR20130017057A (ko) * 2011-08-09 2013-02-19 한국과학기술원 광학용 투명 하이브리드 재료
CN105860083A (zh) * 2016-04-14 2016-08-17 顺德职业技术学院 改性乙烯基硅树脂及含改性乙烯基硅树脂的有机硅封胶的制备方法
KR101813258B1 (ko) * 2017-02-28 2017-12-29 에스케이씨 주식회사 광학 재료용 실록산 티올 올리고머

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
KIM, J.-S.: "Photo-curable siloxane hybrid material fabricated by a thiol-ene reaction of sol-gel synthesized oligosiloxanes", CHEMICAL COMMUNICATIONS, 2011, pages 6051 - 6053, XP055189642, DOI: 10.1039/c1cc11297j *
SHELKOVNIKOV, V. V. ET AL.: "Synthesis and thermomechanical properties of hybrid photopolymer films based on the thiol-siloxane and acrylate oligomers", JOURNAL OF MATERIALS SCIENCE, vol. 50, no. 233, 2015, pages 7544 - 7556, XP035547972, DOI: doi:10.1007/s10853-015-9265-9 *

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