WO2018151506A1 - Refiner for pyrolyzer - Google Patents

Refiner for pyrolyzer Download PDF

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Publication number
WO2018151506A1
WO2018151506A1 PCT/KR2018/001890 KR2018001890W WO2018151506A1 WO 2018151506 A1 WO2018151506 A1 WO 2018151506A1 KR 2018001890 W KR2018001890 W KR 2018001890W WO 2018151506 A1 WO2018151506 A1 WO 2018151506A1
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exhaust gas
purifier
oil
refiner
water tank
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PCT/KR2018/001890
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French (fr)
Korean (ko)
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이달은
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이달은
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes

Definitions

  • the present invention relates to a pyrolysis device configured to pyrolyze waste to obtain regenerated fuel, and more particularly, to recover foreign substances and oils including dust at a difference in specific gravity in exhaust gas discharged from pyrolysis of waste, and to clean the exhaust gas. It relates to a purifier for a pyrolysis device configured to discharge to the atmosphere.
  • an indirect heating pyrolysis apparatus for pyrolysis waste in a high temperature and vacuum environment includes a pyrolysis furnace including a pyrolysis furnace for pyrolyzing waste installed at an inside of a heating furnace, which is a heating means, at a high temperature and a vacuum state. And a refiner (oil collecting device) for collecting oil in the exhaust gas of the discharged waste.
  • FIG. 1 shows a schematic diagram of a conventional pyrolysis apparatus, and includes a pyrolyzer 1 and a refiner 2 for separating oil in exhaust gas discharged from the pyrolyzer 1.
  • the ordinary purifier 2 comprises a purifier tank 2a in which water is stored for cooling, and an exhaust gas guide tube 2b installed in the tank in a zigzag manner to guide the exhaust gas.
  • a 'U' shaped connector (2c) for cleaning is installed in the bending section of the exhaust gas guide pipe (2b) installed in a zigzag shape, and the inside of the pipe is periodically cleaned.
  • the efficiency is reduced due to the shutdown of the pyrolysis due to the cleaning.
  • the oil (Oil) contained in the exhaust gas is mixed with the foreign matter loaded in the tube has a disadvantage in that the recovery rate of the oil falls.
  • the present invention improves the recovery capacity of oil contained in the exhaust gas emitted from the pyrolysis device for pyrolyzing waste, and collects foreign substances such as dust contained in the exhaust gas to collect the exhaust gas discharged into the atmosphere.
  • An object of the present invention is to provide a purifier for a pyrolysis device, which is configured to reduce the amount of oil and foreign substances.
  • the present invention to achieve this object is, in the refiner for recovering oil from the exhaust gas discharged from the pyrolysis pyrolysis waste, a supply port to which the exhaust gas provided on one side is supplied, and is provided on the other side opposite to the supply port It includes a discharge port through which exhaust gas is discharged, an oil discharge port for discharging oil recovered on one side, and a foreign substance discharge port for discharging foreign substances deposited on the lower side, and the water is stored inside and divided into a water tank part and an exhaust gas passage part.
  • a hermetically sealed purifier body It is installed in the vertical direction in the upper side of the purifier body, and includes a plurality of moving passage diaphragm to form a zigzag-type exhaust gas movement path in the exhaust gas passage, while the lower end of the supply port for supplying the exhaust gas and
  • the lower end of the moving passage diaphragm may be located below the water surface of the water tank, so that the exhaust gas cannot be moved toward the lower end of the moving diaphragm.
  • One or more tank diaphragms are installed in the lower side of the refiner body to separate the tank into a plurality of unit tanks, and the upper end of the tank diaphragm is located at a position higher than the lower end of the movable diaphragm.
  • the pyrolytic purifier may further include a cooling water tank for cooling the purifier body using the cooling water.
  • a plurality of separation grooves in the vertical direction may be formed in the movable diaphragm.
  • the purifier for a pyrolyzer has a zigzag-type exhaust gas movement path formed in the exhaust gas passage part by a plurality of movement path diaphragms, so that the movement path of the exhaust gas becomes long, so that foreign substances in the exhaust gas are lowered.
  • the foreign matter falls to the provided water tank unit, and the foreign matter dropped into the water tank unit is not mixed back into the exhaust gas, thereby reducing the amount of foreign matter contained in the exhaust gas discharged to the atmosphere.
  • the exhaust gas is cooled by the cooling water tank to increase the efficiency of separating the oil and foreign matter and water contained in the exhaust gas.
  • FIG. 1 is a schematic diagram of a purifier for a pyrolysis machine in conventional use.
  • Figure 2 is a perspective schematic view of a purifier for an embodiment of the present invention pyrolysis.
  • Figure 3 is a schematic cross-sectional view of a purifier for a pyrolysis machine according to an embodiment of the present invention.
  • Figure 4 is a front sectional schematic view of a purifier for a pyrolysis machine according to one embodiment of the present invention.
  • Figure 5 is a side cross-sectional schematic view of a purifier for an pyrolysis machine according to one embodiment of the present invention.
  • Figure 6 is a detailed cross-sectional schematic view of the main part of the purifier for a pyrolysis machine which is one embodiment of the present invention.
  • Figure 7 is a perspective schematic view of the diaphragm for the movement of the purifier for a pyrolysis machine according to an embodiment of the present invention.
  • Figure 8 is a side cross-sectional schematic view of a purifier for a pyrolysis machine comprising a cooling bath which is another embodiment of the present invention.
  • Figure 9 is a perspective schematic view of a purifier for a pyrolysis machine comprising a cooling bath according to another embodiment of the present invention.
  • FIG. 10 is a side sectional schematic view of a purifier for a pyrolysis machine including a cooling bath according to another embodiment of the present invention shown in FIG. 9;
  • the present invention relates to a pyrolytic purifier for use in a pyrolysis device for pyrolyzing waste in a vacuum, high temperature state.
  • the present invention relates to a pyrolytic purifier configured to recover foreign substances and oil including dust at a difference in specific gravity in waste gas discharged from pyrolysis and discharge exhaust gas in a clean state to the atmosphere.
  • Such a refiner for a pyrolyzer includes a supply port through which exhaust gas is provided on one side, an exhaust port through which exhaust gas installed on the other side opposite to the supply port is discharged, an oil outlet through which oil recovered on one side is discharged, and
  • a hermetically sealed purifier body including a foreign substance discharge port for discharging the foreign substances precipitated on the side surface and having water stored therein and partitioned into a water tank part and an exhaust gas passage part; It is installed in the vertical direction in the upper side of the refiner body, and includes a plurality of moving passage diaphragm to form a zigzag-type exhaust gas passage in the exhaust gas passage portion,
  • the lower end of the supply port for supplying the exhaust gas and the lower end of the moving passage diaphragm are located below the water surface of the water tank so that the exhaust gas cannot move toward the lower end of the traveling diaphragm.
  • the configuration of the refiner 100 for the pyrolyzer according to the present invention includes a hermetically sealed purifier body 110 which is divided into a water tank unit 10 and an exhaust gas passage unit 20 by storing water therein; A plurality of moving plate plates 120 installed vertically on the upper side of the refiner body 110 to form a zigzag-type exhaust gas moving path in the exhaust gas passage part 20; It includes a configuration of one or more tank diaphragm 130 to separate the tank unit 10 formed in the lower side of the refiner body 110 into a plurality of unit tanks (11, 12, 13).
  • the purifier body 110 is connected to an exhaust gas guide tube for guiding the exhaust gas discharged from the pyrolyzer 1 and is provided with an exhaust gas supply port 111 formed at one side such that the exhaust gas is introduced therein, and the supply port ( 111 is installed on the other side opposite to the exhaust gas outlet 112 for discharging the exhaust gas from which oil and foreign substances have been removed, the oil outlet 113 for discharging the recovered oil on one side, and discharge the precipitated foreign matter It includes a foreign matter outlet 114.
  • the lower end 111a of the exhaust gas supply port 111 is positioned below the water surface of the water tank 10 so that the exhaust gas is discharged in the water tank. This can increase the cooling rate of the exhaust gas discharged to increase the collection efficiency of oil (Oil) and foreign matter.
  • the exhaust gas outlet 112 is connected to an exhaust gas guide tube that guides the exhaust gas to the flue so that the exhaust gas is discharged to the atmosphere through the flue.
  • the oil outlet 113 is configured to discharge the oil (Oil) collected on the water surface of the water tank unit 10 to the outside, located on the water surface of the water tank unit 10, as shown in Figure 4, is provided with a valve for opening and closing do.
  • the foreign matter discharge port 114 is configured to discharge the foreign matter precipitated in the water tank unit 10 to the outside, each foreign matter discharge port (114a, 114b, 114c) is installed in a plurality of unit tank (11, 12, 13) Each foreign matter discharge port (114a, 114b, 114c) is provided with an opening and closing valve.
  • the moving plate diaphragm 120 is configured to form a zigzag-type exhaust gas moving path in the exhaust gas passage part 20 as shown in FIG. 3, and the moving plate diaphragm 120 as shown in FIGS. 4 and 6.
  • the lower end 120a of the water tank 10 is positioned below the water surface so that the exhaust gas does not move through the lower end 120a of the moving plate diaphragm 120. That is, the exhaust gas is moved through the zigzag-shaped exhaust gas moving path.
  • the moving plate diaphragm 120 is installed in a vertical direction and is collected in a lower water tank unit 10 at the time of attachment of oil and foreign substances contained in the moving exhaust gas.
  • the moving plate diaphragm 120 may have a plurality of separation grooves 120b in the vertical direction to increase the collection efficiency of oil and foreign substances.
  • the plurality of separation grooves 120b interfere with the flow of the moving exhaust gas, so that oil and foreign substances are attached to the moving plate diaphragm 120 or fall downward. This phenomenon can increase the collection efficiency of oil and foreign matter.
  • the water tank diaphragm 130 is configured to separate the water tank unit 10 into a plurality of unit water tanks 11, 12, and 13, and the upper end 130a of the water tank diaphragm 130 is a movable diaphragm ( It is located at a position higher than the bottom (120a) of 120.
  • the water tank diaphragm 130 may be formed of one or more water tank diaphragms 131 and 132, and the unit water tanks 11, 12 and 13 formed by the plurality of water tank diaphragms 131 and 132 may be provided.
  • the water level is different.
  • the water level of the first water tank 11 positioned at the exhaust gas supply port 111 is set to be the highest, and the oil discharge port 113 is formed at the exhaust gas discharge port 112.
  • the oil collected in the second tank 13 is lower than the first tank diaphragm 131 so that the level of the second tank 13 is lower than that of the first tank diaphragm 131 so that the oil recovered as shown in FIG. 11 to the second tank 12, the third tank 13 to be moved.
  • the oil of the upper oil layer is discharged through the oil outlet 113, and the foreign matter of the lower sediment layer is discharged to the foreign material outlet 114 and recycled.
  • the cooling water tank 200 is configured such that the cooling water surrounds the entire purifier body 110. That is, the refiner body 110 is positioned in the cooling water tank 200 in which the cooling water is stored.
  • the cooling water tank 210 in which the coolant is stored is installed on the upper side of the refiner body 110, and the plurality of air-cooled cooling fins are provided on the side of the refiner body 110 and the cooling water tank 210. 220 is installed.
  • the air-cooled cooling fin 220 allows the refiner body 110 to be cooled by air-cooling, while cooling is performed by using the cooling water of the cooling water tank 210.
  • the pyrolytic purifier according to the present invention recovers foreign substances and oil containing dust at the difference in specific gravity in the exhaust gas discharged from pyrolysis, and discharges the clean exhaust gas to the atmosphere. Is expected.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Separating Particles In Gases By Inertia (AREA)

Abstract

The present invention relates to a pyrolizer configured to pyrolyze a waste and to acquire regenerated fuel and, more particularly, to a refiner for a pyrolyzer configured to recover dust-containing alien substances and oil, on the basis of a difference in specific gravity, inside exhaust gas discharged during pyrolysis of the waste, and to discharge exhaust gas in a clean condition to the atmosphere. A refiner for a pyrolyzer for recovering oil from exhaust gas discharged from a pyrolyzer for pyrolyzing a waste according to the present invention comprises: a sealed refiner body comprising a supply opening installed on one side thereof so as to supply exhaust gas, a discharge opening installed on the other side lying opposite the supply opening so as to discharge exhaust gas, an oil discharge opening for discharging oil recovered on a side surface, and an alien substance discharge opening for discharging alien substances accumulated on a lower surface, the refiner body storing water therein such that the same is delimited into a water reservoir portion and an exhaust gas passage portion; and multiple movement channel barriers installed vertically on the upper side inside the refiner body such that an exhaust gas movement channel is formed in a zigzag type in the exhaust gas passage portion. The lower end of the supply opening for supplying exhaust gas and the lower ends of the movement channel barriers are positioned below the water surface in the water reservoir portion such that the exhaust gas does not move toward the lower ends of the movement channel barriers.

Description

열분해기용 정제기Pyrolytic Purifier
본 발명은 폐기물을 열분해하여 재생연료를 획득하도록 이루어진 열분해기에 관한 것으로, 상세하게는 폐기물을 열분해시 배출되는 배기가스 내에서 비중의 차이로 분진을 포함하는 이물질과 오일을 회수하고 청정한 상태의 배기가스를 대기에 배출하도록 이루어진 열분해기용 정제기에 관한 것이다.The present invention relates to a pyrolysis device configured to pyrolyze waste to obtain regenerated fuel, and more particularly, to recover foreign substances and oils including dust at a difference in specific gravity in exhaust gas discharged from pyrolysis of waste, and to clean the exhaust gas. It relates to a purifier for a pyrolysis device configured to discharge to the atmosphere.
사회가 본격적인 산업화 양상을 나타내면서 '대량생산과 대량소비'에 따른 폐기물이 급증하는 가운데 폐기물 처리에 수반되는 환경오염 문제가 심각하게 대두됨에 따라 효율적인 폐기물 처리방안이 시급히 요구되고 있는 실정이다.As society shows full-scale industrialization, as the waste caused by 'mass production and mass consumption' is rapidly increasing, the environmental pollution accompanying the waste disposal is seriously required. Therefore, efficient waste disposal plans are urgently required.
일반적으로 폐기물 처리방안에는 '감량', '재활용', '재생', '매립' 및 '소각' 등이 있으며, 최근에는 고온 및 진공환경에서 폐기물을 열분해(pyrolysis)하는 다양한 방법이 소개되었으며, 특허문헌들과 같이 다양한 열분해 장치 및 방법이 제시 및 개발되어 사용되고 있으며, 더욱더 향상된 기술을 제공하고자 지속적으로 기술을 개발하고 있다(참고 특허문헌 (KR) 등록특허공보 제10-0266852호, (KR) 등록특허공보 제10-0513932호, (KR) 등록특허공보 제10-0748624호).Generally, there are 'reduction', 'recycling', 'recycling', 'landing' and 'incineration' in the waste treatment method. Recently, various methods of pyrolysis of waste in high temperature and vacuum environment have been introduced, and patents have been introduced. Various pyrolysis apparatuses and methods are presented, developed and used as in the literature, and technologies are continuously being developed to provide more and more advanced technologies (reference patent document (KR) No. 10-0266852, (KR) registration Patent Publication No. 10-0513932, (KR) Patent Publication No. 10-0748624).
일반적으로 고온 및 진공환경에서 폐기물을 열분해(pyrolysis) 하는 간접가열방식의 열분해장치는 크게 가열수단인 가열로의 내측에 설치된 폐기물을 고온 및 진공상태에서 열분해 시키는 열분해로을 포함하는 열분해기와, 상기 열분해기에 배출되는 폐기물 중 배기가스 내에서 오일을 포집하도록 하는 정제기(오일 포집장치)를 포함한다.In general, an indirect heating pyrolysis apparatus for pyrolysis waste in a high temperature and vacuum environment includes a pyrolysis furnace including a pyrolysis furnace for pyrolyzing waste installed at an inside of a heating furnace, which is a heating means, at a high temperature and a vacuum state. And a refiner (oil collecting device) for collecting oil in the exhaust gas of the discharged waste.
도 1은 통상의 열분해장치에 관한 개략도를 나타낸 것으로, 열분해기(1)와 상기 열분해기(1)에서 배출되는 배기가스 내에서 오일을 분리하는 정제기(2)를 포함한다.1 shows a schematic diagram of a conventional pyrolysis apparatus, and includes a pyrolyzer 1 and a refiner 2 for separating oil in exhaust gas discharged from the pyrolyzer 1.
통상의 상기 정제기(2)는 냉각을 위하여 물이 저장된 정제기용 수조(2a)와, 상기 수조 내에 지그재그 형태로 설치되어 배기가스를 안내하는 배기가스 안내관(2b)으로 이루어진다.The ordinary purifier 2 comprises a purifier tank 2a in which water is stored for cooling, and an exhaust gas guide tube 2b installed in the tank in a zigzag manner to guide the exhaust gas.
상기 배기가스 안내관(2b) 내에는 시간이 경과 함에 따라 배기가스 내의 이물질이 적재되어 관의 내부가 막힘 현상이 발생한다. 이러한 막힘 현상을 해결하고자 지그재그 형태로 설치된 배기가스 안내관(2b)의 꺾임 구간에 청소를 위한 'U'자 형태의 연결구(2c)를 설치하고, 이를 이용하여 주기적으로 관 내부를 청소한다.In the exhaust gas guide pipe 2b, as the time passes, foreign matters in the exhaust gas are loaded, and the inside of the pipe is clogged. In order to solve such a clogging phenomenon, a 'U' shaped connector (2c) for cleaning is installed in the bending section of the exhaust gas guide pipe (2b) installed in a zigzag shape, and the inside of the pipe is periodically cleaned.
이와 같이 배기가스 안내관(2b) 상에 설치된 연결구(2c)를 분리하여 청소를 하는 경우 다양한 문제점을 가진다.As described above, when the connector 2c installed on the exhaust gas guide pipe 2b is separated and cleaned, there are various problems.
첫째, 청소에 따른 열분해기의 가동 중지로 인하여 효율이 저하되는 단점을 가진다.First, the efficiency is reduced due to the shutdown of the pyrolysis due to the cleaning.
둘째, 배기가스 안내관(2b) 상에 설치된 연결구(2c) 분리시 악취가 발생하게 되고, 악취로 인한 작업자의 작업회피 및 민원이 야기되는 단점을 가진다.Secondly, when the connector 2c installed on the exhaust gas guide pipe 2b is separated, odors are generated, and the worker's work avoidance and complaints are caused by the odors.
셋째, 배기가스 내에 포함되어 있는 오일(Oil)은 관내에 적재된 이물질에 섞이게 됨으로써 오일의 회수률이 떨어지는 단점을 가진다. Third, the oil (Oil) contained in the exhaust gas is mixed with the foreign matter loaded in the tube has a disadvantage in that the recovery rate of the oil falls.
이러한 목적을 달성하고자 본 출원인은 특허문헌을 통하여 물이 저장된 수조를 이용한 다양한 정제기에 관련된 오일포집장치 및 열분해 시스템에 대한 기술을 제공하였다(참고 특허문헌 (KR) 등록특허공보 제10-1202810호, (KR) 등록특허공보 제10-1379225호).In order to achieve this object, the present applicant has provided a technology for an oil collecting device and a pyrolysis system related to various refiners using a water tank in which water is stored (Patent Document (KR) No. 10-1202810, (KR) Patent Publication No. 10-1379225).
본 발명은 폐기물을 열분해시키는 열분해기에서 배출되는 배기가스 내에 포함되어 있는 오일(Oil)의 회수능력을 높이고, 배기가스 내에서 포함되어 있는 분진과 같은 이물질을 포집함으로써 대기로 배출되는 배기가스의 내의 오일과 이물질의 양을 줄일 수 있도록 이루어진 열분해기용 정제기를 제공하고자 한다.The present invention improves the recovery capacity of oil contained in the exhaust gas emitted from the pyrolysis device for pyrolyzing waste, and collects foreign substances such as dust contained in the exhaust gas to collect the exhaust gas discharged into the atmosphere. An object of the present invention is to provide a purifier for a pyrolysis device, which is configured to reduce the amount of oil and foreign substances.
또한, 이물질에 의한 막힘 현상 등이 발생하지 않도록 함으로써 이로부터 발생하는 문제점을 해결할 수 있도록 이루어진 열분해기용 정제기를 제공하고자 한다.In addition, to prevent the clogging phenomenon caused by foreign matters to provide a purifier for a pyrolysis device made to solve the problems resulting therefrom.
이러한 목적을 달성하고자 하는 본 발명은, 폐기물을 열분해하는 열분해기에서 배출되는 배기가스로부터 오일을 회수하는 정제기에 있어서, 일측에 설치된 배기가스가 공급되는 공급구와, 상기 공급구와 반대측인 타측에 설치되는 배기가스가 배출되는 배출구와, 일측면에 회수된 오일을 배출하는 오일배출구와, 하측면에 침전된 이물질을 배출하는 이물질 배출구를 포함하며, 내부에 물이 저장되어 수조부와 배기가스 통로부로 구획되는 밀폐형의 정제기 몸체; 상기 정제기 몸체 내 상측에 수직방향으로 설치되고, 배기가스 통로부에 지그재그 형태의 배기가스용 이동로가 형성되도록 하는 다수개의 이동로용 격판을 포함하는 한편, 배기가스를 공급하는 상기 공급구의 하단과, 상기 이동로용 격판의 하단은 수조부의 수면보다 하측에 위치하도록 하여 배기가스가 이동로용 격판의 하단 쪽으로 이동하지 못하도록 이루어지는 열분해기용 정제기로 해결될 수 있다.The present invention to achieve this object is, in the refiner for recovering oil from the exhaust gas discharged from the pyrolysis pyrolysis waste, a supply port to which the exhaust gas provided on one side is supplied, and is provided on the other side opposite to the supply port It includes a discharge port through which exhaust gas is discharged, an oil discharge port for discharging oil recovered on one side, and a foreign substance discharge port for discharging foreign substances deposited on the lower side, and the water is stored inside and divided into a water tank part and an exhaust gas passage part. A hermetically sealed purifier body; It is installed in the vertical direction in the upper side of the purifier body, and includes a plurality of moving passage diaphragm to form a zigzag-type exhaust gas movement path in the exhaust gas passage, while the lower end of the supply port for supplying the exhaust gas and The lower end of the moving passage diaphragm may be located below the water surface of the water tank, so that the exhaust gas cannot be moved toward the lower end of the moving diaphragm.
상기 정제기 몸체 내 하측에는 수조부를 다수의 단위 수조로 분리되도록 하나 이상의 수조용 격판이 설치되며, 상기 수조용 격판의 상단은 이동로용 격판의 하단 보다 높은 위치에 있도록 한다.One or more tank diaphragms are installed in the lower side of the refiner body to separate the tank into a plurality of unit tanks, and the upper end of the tank diaphragm is located at a position higher than the lower end of the movable diaphragm.
상기 열분해기용 정제기는 냉각수를 이용하여 정제기 몸체를 냉각시키는 냉각수조를 더 포함할 수 있다.The pyrolytic purifier may further include a cooling water tank for cooling the purifier body using the cooling water.
상기 이동로용 격판에는 세로방향의 다수의 분리용 홈이 형성될 수도 있다.A plurality of separation grooves in the vertical direction may be formed in the movable diaphragm.
이와 같이 이루어진 본 발명인 열분해기용 정제기는 다수개의 이동로용 격판에 의하여 배기가스 통로부에 지그재그 형태의 배기가스용 이동로가 형성됨에 따라 배기가스의 이동로가 길어지게 되어 배기가스 내의 이물질이 하측에 구비된 수조부로 떨어지게 되고, 상기 수조부에 떨어진 이물질은 다시 배기가스 내로 섞이지 않음으로써 대기로 배출되는 배기가스 내에 포함되는 이물질의 양은 감소되게 된다.As described above, the purifier for a pyrolyzer according to the present invention has a zigzag-type exhaust gas movement path formed in the exhaust gas passage part by a plurality of movement path diaphragms, so that the movement path of the exhaust gas becomes long, so that foreign substances in the exhaust gas are lowered. The foreign matter falls to the provided water tank unit, and the foreign matter dropped into the water tank unit is not mixed back into the exhaust gas, thereby reducing the amount of foreign matter contained in the exhaust gas discharged to the atmosphere.
또한, 냉각수조에 의하여 배기가스가 냉각되어 배기가스 내에 포함되어 있는 수분 및 오일 및 이물질이 분리되는 효율이 높아질 수 있는 효과가 있다.In addition, the exhaust gas is cooled by the cooling water tank to increase the efficiency of separating the oil and foreign matter and water contained in the exhaust gas.
또한, 이동로용 격판에 세로방향의 다수의 분리용 홈이 형성됨에 따라 오일 및 이물질의 포집효율이 높아지는 효과가 있다.In addition, since a plurality of separation grooves in the vertical direction are formed in the moving plate diaphragm, the collection efficiency of oil and foreign matters is increased.
도 1은 종래 사용중에 있는 열분해기용 정제기의 개략도.1 is a schematic diagram of a purifier for a pyrolysis machine in conventional use.
도 2는 본 발명의 일 실시 예인 열분해기용 정제기의 사시 개략도.Figure 2 is a perspective schematic view of a purifier for an embodiment of the present invention pyrolysis.
도 3은 본 발명의 일 실시 예인 열분해기용 정제기의 평단면 개략도.Figure 3 is a schematic cross-sectional view of a purifier for a pyrolysis machine according to an embodiment of the present invention.
도 4는 본 발명의 일 실시 예인 열분해기용 정제기의 정단면 개략도.Figure 4 is a front sectional schematic view of a purifier for a pyrolysis machine according to one embodiment of the present invention.
도 5는 본 발명의 일 실시 예인 열분해기용 정제기의 측단면 개략도.Figure 5 is a side cross-sectional schematic view of a purifier for an pyrolysis machine according to one embodiment of the present invention.
도 6은 본 발명의 일 실시 예인 열분해기용 정제기의 주요부분에 대한 상세 단면 개략도.Figure 6 is a detailed cross-sectional schematic view of the main part of the purifier for a pyrolysis machine which is one embodiment of the present invention.
도 7은 본 발명의 일 실시 예인 열분해기용 정제기의 이동로용 격판에 대한 사시 개략도.Figure 7 is a perspective schematic view of the diaphragm for the movement of the purifier for a pyrolysis machine according to an embodiment of the present invention.
도 8은 본 발명의 다른 실시 예인 냉각용 수조를 포함하는 열분해기용 정제기의 측단면 개략도.Figure 8 is a side cross-sectional schematic view of a purifier for a pyrolysis machine comprising a cooling bath which is another embodiment of the present invention.
도 9는 본 발명의 또 다른 실시 예인 냉각용 수조를 포함하는 열분해기용 정제기의 사시 개략도.Figure 9 is a perspective schematic view of a purifier for a pyrolysis machine comprising a cooling bath according to another embodiment of the present invention.
도 10은 도 9에 도시된 본 발명의 또 다른 실시 예인 냉각용 수조를 포함하는 열분해기용 정제기의 측단개략도.FIG. 10 is a side sectional schematic view of a purifier for a pyrolysis machine including a cooling bath according to another embodiment of the present invention shown in FIG. 9;
본 발명은 진공, 고온의 상태에서 폐기물을 열분해하는 열분해기에 사용되는 열분해기용 정제기에 관한 것이다.The present invention relates to a pyrolytic purifier for use in a pyrolysis device for pyrolyzing waste in a vacuum, high temperature state.
즉, 폐기물을 열분해시 배출되는 배기가스 내에서 비중의 차이로 분진을 포함하는 이물질과 오일을 회수하고 청정한 상태의 배기가스를 대기에 배출하도록 이루어진 열분해기용 정제기에 관한 것이다.That is, the present invention relates to a pyrolytic purifier configured to recover foreign substances and oil including dust at a difference in specific gravity in waste gas discharged from pyrolysis and discharge exhaust gas in a clean state to the atmosphere.
이러한 본 발명인 열분해기용 정제기는, 일측에 설치된 배기가스가 공급되는 공급구와, 상기 공급구와 반대측인 타측에 설치되는 배기가스가 배출되는 배출구와, 일측면에 회수된 오일을 배출하는 오일배출구와, 하측면에 침전된 이물질을 배출하는 이물질 배출구를 포함하며, 내부에 물이 저장되어 수조부와 배기가스 통로부로 구획되는 밀폐형의 정제기 몸체와; 상기 정제기 몸체 내 상측에 수직방향으로 설치되고, 배기가스 통로부에 지그재그 형태의 배기가스용 이동로가 형성되도록 하는 다수개의 이동로용 격판을 포함하는 한편,Such a refiner for a pyrolyzer according to the present invention includes a supply port through which exhaust gas is provided on one side, an exhaust port through which exhaust gas installed on the other side opposite to the supply port is discharged, an oil outlet through which oil recovered on one side is discharged, and A hermetically sealed purifier body including a foreign substance discharge port for discharging the foreign substances precipitated on the side surface and having water stored therein and partitioned into a water tank part and an exhaust gas passage part; It is installed in the vertical direction in the upper side of the refiner body, and includes a plurality of moving passage diaphragm to form a zigzag-type exhaust gas passage in the exhaust gas passage portion,
배기가스를 공급하는 상기 공급구의 하단과, 상기 이동로용 격판의 하단은 수조부의 수면보다 하측에 위치하도록 하여 배기가스가 이동로용 격판의 하단 쪽으로 이동하지 못하도록 이루어진다.The lower end of the supply port for supplying the exhaust gas and the lower end of the moving passage diaphragm are located below the water surface of the water tank so that the exhaust gas cannot move toward the lower end of the traveling diaphragm.
본 발명인 열분해기용 정제기에 대하여 첨부된 실시 예 도면을 참조하여 상세하게 설명하도록 한다.The present invention will be described in detail with reference to the accompanying drawings.
도 2 내지 도 5를 참조하면,2 to 5,
본 발명인 열분해기용 정제기(100)의 구성은 크게, 내부에 물이 저장되어 수조부(10)와 배기가스 통로부(20)로 구획되는 밀폐형의 정제기 몸체(110)와; 상기 정제기 몸체(110) 내 상측에 수직방향으로 설치되어, 배기가스 통로부(20)에 지그재그 형태의 배기가스용 이동로가 형성되도록 하는 다수개의 이동로용 격판(120)과; 상기 정제기 몸체(110) 내 하측에 형성되는 수조부(10)를 다수의 단위 수조(11, 12, 13)로 분리되도록 하는 하나 이상의 수조용 격판(130)의 구성을 포함한다.The configuration of the refiner 100 for the pyrolyzer according to the present invention includes a hermetically sealed purifier body 110 which is divided into a water tank unit 10 and an exhaust gas passage unit 20 by storing water therein; A plurality of moving plate plates 120 installed vertically on the upper side of the refiner body 110 to form a zigzag-type exhaust gas moving path in the exhaust gas passage part 20; It includes a configuration of one or more tank diaphragm 130 to separate the tank unit 10 formed in the lower side of the refiner body 110 into a plurality of unit tanks (11, 12, 13).
상기 정제기 몸체(110)에는 열분해기(1)에서 배출되는 배기가스을 안내하는 배기가스 안내관과 연결되어 내측으로 배기가스가 유입되도록 일측에 형성된 배기가스용 공급구(111)와, 상기 공급구(111)와 반대측인 타측에 설치되어 오일 및 이물질이 제거된 배기가스를 배출하는 배기가스용 배출구(112)와, 일측면에 회수된 오일을 배출하는 오일배출구(113)와, 침전된 이물질을 배출하는 이물질 배출구(114)를 포함한다.The purifier body 110 is connected to an exhaust gas guide tube for guiding the exhaust gas discharged from the pyrolyzer 1 and is provided with an exhaust gas supply port 111 formed at one side such that the exhaust gas is introduced therein, and the supply port ( 111 is installed on the other side opposite to the exhaust gas outlet 112 for discharging the exhaust gas from which oil and foreign substances have been removed, the oil outlet 113 for discharging the recovered oil on one side, and discharge the precipitated foreign matter It includes a foreign matter outlet 114.
상기 배기가스용 공급구(111)의 하단(111a)은 수조부(10)의 수면보다 하측에 위치하도록 하여 배출되는 배기가스가 수조 내에서 배출되도록 한다. 이는 배출되는 배기가스의 냉각속도를 높일 수 있어 오일(Oil)과 이물질의 포집효율을 높일 수 있다. The lower end 111a of the exhaust gas supply port 111 is positioned below the water surface of the water tank 10 so that the exhaust gas is discharged in the water tank. This can increase the cooling rate of the exhaust gas discharged to increase the collection efficiency of oil (Oil) and foreign matter.
상기 배기가스용 배출구(112)는 연도를 통하여 배기가스가 대기로 배출될 수 있도록 연도에 배기가스를 안내하는 배기가스 안내관과 연결된다.The exhaust gas outlet 112 is connected to an exhaust gas guide tube that guides the exhaust gas to the flue so that the exhaust gas is discharged to the atmosphere through the flue.
상기 오일배출구(113)는 수조부(10)의 수면에 포집된 오일(Oil)을 외부로 배출하는 구성으로, 도 4와 같이 수조부(10)의 수면부위에 위치하며, 개폐용 밸브가 구비된다.The oil outlet 113 is configured to discharge the oil (Oil) collected on the water surface of the water tank unit 10 to the outside, located on the water surface of the water tank unit 10, as shown in Figure 4, is provided with a valve for opening and closing do.
상기 이물질 배출구(114)는 수조부(10)에 침전된 이물질을 외부에 배출하도록 하는 구성으로, 다수의 단위 수조(11, 12, 13)에 각각의 이물질 배출구(114a, 114b, 114c)가 설치되며, 각각의 이물질 배출구(114a, 114b, 114c)에는 개폐용 밸브가 구비된다.The foreign matter discharge port 114 is configured to discharge the foreign matter precipitated in the water tank unit 10 to the outside, each foreign matter discharge port (114a, 114b, 114c) is installed in a plurality of unit tank (11, 12, 13) Each foreign matter discharge port (114a, 114b, 114c) is provided with an opening and closing valve.
이는 단위 수조(11, 12, 13)에 침전되는 이물질의 양이 상이하게 되고, 이로 인하여 이물질의 배출하는 주기를 각각 상이하게 배출할 수 있도록 할 수 있다.This is because the amount of the foreign matter precipitated in the unit tank (11, 12, 13) is different, thereby allowing the discharge cycle of the foreign matter can be discharged differently.
상기 이동로용 격판(120)은 도 3과 같이 배기가스 통로부(20)에 지그재그 형태의 배기가스용 이동로가 형성되도록 하는 구성으로, 도 4와 도 6과 같이 이동로용 격판(120)의 하단(120a)은 수조부(10)의 수면보다 하측에 위치하도록 하여 배기가스가 이동로용 격판(120)의 하단(120a)을 통하여 이동하지 않도록 한다. 즉, 배기가스가 지그재그 형태의 배기가스용 이동로를 통하여 이동하도록 한다.The moving plate diaphragm 120 is configured to form a zigzag-type exhaust gas moving path in the exhaust gas passage part 20 as shown in FIG. 3, and the moving plate diaphragm 120 as shown in FIGS. 4 and 6. The lower end 120a of the water tank 10 is positioned below the water surface so that the exhaust gas does not move through the lower end 120a of the moving plate diaphragm 120. That is, the exhaust gas is moved through the zigzag-shaped exhaust gas moving path.
상기 이동로용 격판(120)는 수직방향으로 설치됨으로써 이동하는 배기가스 내의 포함되어 있는 오일 및 이물질의 부착시에는 하측의 수조부(10)에 떨어져 포집된다.The moving plate diaphragm 120 is installed in a vertical direction and is collected in a lower water tank unit 10 at the time of attachment of oil and foreign substances contained in the moving exhaust gas.
또한, 도 7과 같이 이동로용 격판(120)에는 오일 및 이물질의 포집효율을 높이고자 세로방향으로 다수의 분리용 홈(120b)을 가질 수 있을 것이다. In addition, as shown in FIG. 7, the moving plate diaphragm 120 may have a plurality of separation grooves 120b in the vertical direction to increase the collection efficiency of oil and foreign substances.
즉, 상기 다수의 분리용 홈(120b)은 이동하는 배기가스의 흐름을 간섭하게 되어, 오일 및 이물질이 이동로용 격판(120)에 부착되거나 하측으로 떨어지게 된다. 이러한 현상에 의하여 오일 및 이물질의 포집효율을 높일 수 있다.That is, the plurality of separation grooves 120b interfere with the flow of the moving exhaust gas, so that oil and foreign substances are attached to the moving plate diaphragm 120 or fall downward. This phenomenon can increase the collection efficiency of oil and foreign matter.
상기 수조용 격판(130)은 수조부(10)를 다수의 단위 수조(11, 12, 13)로 분리하도록 하는 구성이며, 상기 수조용 격판(130)의 상단(130a)은 이동로용 격판(120)의 하단(120a) 보다 높은 위치에 있도록 한다.The water tank diaphragm 130 is configured to separate the water tank unit 10 into a plurality of unit water tanks 11, 12, and 13, and the upper end 130a of the water tank diaphragm 130 is a movable diaphragm ( It is located at a position higher than the bottom (120a) of 120.
상기 수조용 격판(130)은 하나 이상의 다수의 수조용 격판(131, 132)으로 이루어질 수 있으며, 상기 다수의 수조용 격판(131, 132)에 의하여 형성되는 단위 수조(11, 12, 13)의 수위는 상이하도록 한다.The water tank diaphragm 130 may be formed of one or more water tank diaphragms 131 and 132, and the unit water tanks 11, 12 and 13 formed by the plurality of water tank diaphragms 131 and 132 may be provided. The water level is different.
즉, 도 4와 같이 배기가스용 공급구(111) 측에 위치하는 제1 수조(11)의 수위가 가장 높도록 하고, 배기가스용 배출구(112) 측에 위치하여 오일배출구(113)가 형성되는 제3 수조(13)의 수위가 가장 낮도록 제1 수조용 격판(131) 보다 제2 수조용 격판(132)의 높이를 낮게 하여 도 6과 같이 회수되는 오일(Oil)이 제1 수조(11)에서 제2 수조(12), 제3 수조(13)로 이동할 수 있도록 한다.That is, as shown in FIG. 4, the water level of the first water tank 11 positioned at the exhaust gas supply port 111 is set to be the highest, and the oil discharge port 113 is formed at the exhaust gas discharge port 112. The oil collected in the second tank 13 is lower than the first tank diaphragm 131 so that the level of the second tank 13 is lower than that of the first tank diaphragm 131 so that the oil recovered as shown in FIG. 11 to the second tank 12, the third tank 13 to be moved.
이러한 제1 수조(11), 제2 수조(12), 제3 수조(13)로 이루어지는 수조부(10)에는 비중에 차이에 의하여 상측부분에는 오일(Oil) 층이 형성되고, 하측에는 이물질이 침전되어 침전물 층(S)을 형성하게 된다.In the water tank unit 10 including the first water tank 11, the second water tank 12, and the third water tank 13, an oil layer is formed on the upper portion due to a difference in specific gravity. It is precipitated to form the precipitate layer (S).
상기 상층부 오일(Oil) 층의 오일(Oil)은 오일배출구(113)를 통하여 배출되고, 하측의 침전물 층의 이물질은 이물질 배출구(114)로 배출되어 각각 재활용이 된다.The oil of the upper oil layer is discharged through the oil outlet 113, and the foreign matter of the lower sediment layer is discharged to the foreign material outlet 114 and recycled.
도 8 내지 도 10은 냉각수조(200, 210)에 저장된 냉각수를 이용하여 정제기 몸체(110)를 냉각시켜 오일 및 이물질의 포집효율을 높이도록 한 것으로,8 to 10 is to increase the collection efficiency of oil and foreign matter by cooling the refiner body 110 by using the cooling water stored in the cooling water tank (200, 210),
도 8의 실시 예는, 냉각수조(200)는 냉각수가 정제기 몸체(110) 전체를 감싸도록 이루어진 형태이다. 즉, 냉각수가 저장되는 냉각수조(200) 내에 정제기 몸체(110)가 위치하도록 한 것이다.In the embodiment of FIG. 8, the cooling water tank 200 is configured such that the cooling water surrounds the entire purifier body 110. That is, the refiner body 110 is positioned in the cooling water tank 200 in which the cooling water is stored.
도 9 내지 도 10의 실시 예는, 정제기 몸체(110)의 상측에 냉각수가 저장되는 냉각수조(210)를 설치하고, 상기 정제기 몸체(110)와 냉각수조(210) 측면에는 다수의 공냉식 냉각핀(220)이 설치된다.9 to 10, the cooling water tank 210 in which the coolant is stored is installed on the upper side of the refiner body 110, and the plurality of air-cooled cooling fins are provided on the side of the refiner body 110 and the cooling water tank 210. 220 is installed.
상기 공냉식 냉각핀(220)은 정제기 몸체(110)를 공냉식으로 냉각을 시키는 한편, 냉각수조(210)의 냉각수를 이용하여 냉각이 이루어질 수 있도록 한다.The air-cooled cooling fin 220 allows the refiner body 110 to be cooled by air-cooling, while cooling is performed by using the cooling water of the cooling water tank 210.
이와 같이 이루어지는 본 발명인 열분해기용 정제기는 폐기물을 열분해시 배출되는 배기가스 내에서 비중의 차이로 분진을 포함하는 이물질과 오일을 회수하여 청정 상태의 배기가스를 대기에 배출함으로써 산업상 이용 가능성이 아주 높을 것으로 예측된다.In the present invention, the pyrolytic purifier according to the present invention recovers foreign substances and oil containing dust at the difference in specific gravity in the exhaust gas discharged from pyrolysis, and discharges the clean exhaust gas to the atmosphere. Is expected.

Claims (6)

  1. 폐기물을 열분해하는 열분해기에서 배출되는 배기가스로부터 오일을 회수하는 정제기에 있어서,In the refiner for recovering oil from the exhaust gas from the pyrolysis pyrolysis waste,
    일측에 설치된 배기가스가 공급되는 공급구(111)와, 상기 공급구와 반대측인 타측에 설치되는 배기가스가 배출되는 배출구(112)와, 일측면에 회수된 오일을 배출하는 오일배출구(113)와, 하측면에 침전된 이물질을 배출하는 이물질 배출구(114)를 포함하며, 내부에 물이 저장되어 수조부(10)와 배기가스 통로부(20)로 구획되는 밀폐형의 정제기 몸체(110);A supply port 111 to which the exhaust gas is installed at one side, a discharge port 112 at which the exhaust gas is installed at the other side opposite to the supply port, and an oil discharge port 113 at which the oil recovered on one side is discharged; And, the lower side includes a foreign matter discharge port 114 for discharging the foreign matter deposited on the inside, the water is stored therein the water purifier body 10 and the exhaust gas passage section 20 of the hermetic refiner body 110;
    상기 정제기 몸체(110) 내 상측에 수직방향으로 설치되고, 배기가스 통로부(20)에 지그재그 형태의 배기가스용 이동로가 형성되도록 하는 다수개의 이동로용 격판(120)을 포함하는 한편,It is installed in the vertical direction in the upper side of the purifier body 110, and includes a plurality of moving passage plates 120 to form a zigzag-type exhaust gas movement path in the exhaust gas passage portion 20,
    배기가스를 공급하는 상기 공급구(111)의 하단(111a)과, 상기 이동로용 격판(120)의 하단(120a)은 수조부(10)의 수면보다 하측에 위치하도록 하여 배기가스가 이동로용 격판(120)의 하단(120a) 쪽으로 이동하지 못하도록 함을 특징으로 하는 열분해기용 정제기.The lower end 111a of the supply port 111 for supplying the exhaust gas and the lower end 120a of the moving plate diaphragm 120 are located below the water surface of the water tank unit 10 so that the exhaust gas moves through the movement path. Purifier for pyrolysis characterized in that it does not move toward the bottom (120a) of the diaphragm (120).
  2. 제1항에 있어서,The method of claim 1,
    상기 정제기 몸체(110) 내 하측에는 수조부(10)를 다수의 단위 수조(11, 12, 13)로 분리되도록 하나 이상의 수조용 격판(130)이 설치되며,At least one tank diaphragm 130 is installed at the lower side of the refiner body 110 to separate the tank unit 10 into a plurality of unit tanks 11, 12, and 13.
    상기 수조용 격판(130)의 상단(130a)은 이동로용 격판(120)의 하단(120a) 보다 높은 위치에 있도록 함을 특징으로 하는 열분해기용 정제기.The upper end (130a) of the water tank diaphragm 130 is a purifier for the pyrolyzer, characterized in that the position higher than the lower end (120a) of the moving plate (120).
  3. 제1항 또는 제2항에 있어서,The method according to claim 1 or 2,
    상기 열분해기용 정제기는 냉각수를 이용하여 정제기 몸체(110)를 냉각하는 냉각수조(200, 210)를 더 포함함을 특징으로 하는 열분해기용 정제기.The pyrolytic purifier further comprises a cooling water tank (200, 210) for cooling the purifier body (110) using cooling water.
  4. 제3항에 있어서,The method of claim 3,
    상기 냉각수조(200)는, 냉각수가 정제기 몸체(110) 전체를 감싸도록 이루어짐을 특징으로 하는 열분해기용 정제기.The cooling water tank 200, the pyrolysis purifier, characterized in that the cooling water is made to surround the entire purifier body (110).
  5. 제3항에 있어서,The method of claim 3,
    상기 냉각수조(210)는 정제기 몸체(110)의 상측에 형성되고, 냉각수조(210)와 정제기 몸체(110)에는 다수개의 공냉식 냉각핀(220)으로 연결됨을 특징으로 하는 열분해기용 정제기.The cooling water tank 210 is formed on the upper side of the purifier body 110, the cooling water tank 210 and the purifier body 110, characterized in that connected to the plurality of air-cooled cooling fins 220, the purifier.
  6. 제1항 또는 제2항에 있어서,The method according to claim 1 or 2,
    상기 이동로용 격판(120)에는 세로방향의 다수의 분리용 홈(120b)이 형성되어 배기가스 통로부(20)를 이동하는 배기가스 내에서 오일과 이물질이 분리되는 효율을 높일 수 있도록 함을 특징으로 하는 열분해기용 정제기.A plurality of separation grooves 120b in the vertical direction are formed in the moving plate diaphragm 120 to increase the efficiency of separating oil and foreign substances in the exhaust gas moving through the exhaust gas passage part 20. Purifier for pyrolysis characterized in that.
PCT/KR2018/001890 2017-02-14 2018-02-13 Refiner for pyrolyzer WO2018151506A1 (en)

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