WO2018139498A1 - Oil composition and cosmetic product including same - Google Patents

Oil composition and cosmetic product including same Download PDF

Info

Publication number
WO2018139498A1
WO2018139498A1 PCT/JP2018/002163 JP2018002163W WO2018139498A1 WO 2018139498 A1 WO2018139498 A1 WO 2018139498A1 JP 2018002163 W JP2018002163 W JP 2018002163W WO 2018139498 A1 WO2018139498 A1 WO 2018139498A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil composition
oil
hydrogen
cosmetic product
composition according
Prior art date
Application number
PCT/JP2018/002163
Other languages
French (fr)
Japanese (ja)
Inventor
桂子 東野
Original Assignee
株式会社Ｙｏｕｒ Ｓｕｎｒｉｓｅ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2017126986A external-priority patent/JP2018118954A/en
Application filed by 株式会社Ｙｏｕｒ Ｓｕｎｒｉｓｅ filed Critical 株式会社Ｙｏｕｒ Ｓｕｎｒｉｓｅ
Publication of WO2018139498A1 publication Critical patent/WO2018139498A1/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/68—Sphingolipids, e.g. ceramides, cerebrosides, gangliosides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9789—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Definitions

  • the present invention relates to an oil composition and a cosmetic product including the same, and more particularly to a cosmetic oil composition applied to human skin and a cosmetic product including the same.
  • cosmetic oils for moisturizing human skin are known.
  • cosmetic oils are added with materials for providing an additional effect.
  • materials for providing an additional effect For example, collagen and hyaluronic acid are known as components for further improving the moisturizing effect.
  • Patent Documents 1 and 2 disclose techniques for using hydrogen in cosmetics.
  • Patent Document 1 describes that hydrogen is added to a skin care product that directly contacts the skin in order to impart an effect of suppressing or preventing skin aging. However, as in Patent Document 1, even if hydrogen is added to a skin care product, for example, hydrogen is released over time, so that it is not suitable for long-term storage.
  • Patent Document 2 discloses a beauty pack material containing such a hydrogen generating material.
  • microclustered silica is used as a hydrogen-generating material, and the material has a property of generating hydrogen by contact with water.
  • JP 2000-119161 A Japanese Patent Laying-Open No. 2015-89880
  • the cosmetic composition changes its effect and feeling of use depending on the combination of the components contained therein. Therefore, when producing a cosmetic oil containing microclustered silica as described in Patent Document 2, the optimal composition of the cosmetic product is described. It is necessary to find out.
  • the present invention has been made in view of the above-mentioned problems, and an object of the present invention is to generate hydrogen by containing hydrogen-generating silica particles, and to provide an oil composition that has an excellent effect as a beauty oil and an oil composition thereof It is to obtain a cosmetic product containing.
  • At least one of elastin and ceramide NP (ceramide 3) and placenta are contained in the oil.
  • the oil composition according to the present invention includes a vegetable oil made from a plant, hydrogen-producing silica particles capable of generating hydrogen by contact with water, at least one of elastin and ceramide NP, and placenta. And no surfactant.
  • the oil composition of the present invention since it contains hydrogen-generating silica particles capable of generating hydrogen by contact with water, hydrogen is generated by contact with water during use. Demonstrates an anti-aging effect by exerting an oxidizing action. In addition, since it contains at least one of elastin and ceramide NP, an excellent moisturizing effect can be obtained. Further, since it contains a placenta, the skin is textured and tensioned, and a face lift-up effect and a whitening effect are also obtained. That is, since these components provide an excellent moisturizing effect and metabolic effect, an excellent skin beautifying effect is achieved. Furthermore, since the oil composition according to the present invention does not contain a surfactant, the skin to which the oil composition is applied can be prevented from receiving unwanted damage.
  • the vegetable oil is preferably olive oil.
  • the hydrogen generating silica particles may contain at least one of potassium carbonate, potassium citrate, magnesium sulfate, and sodium hydrogen carbonate.
  • a cosmetic product according to the present invention is a cosmetic product in which the above oil composition is filled in a discharge container, and the vegetable oil constituting the oil composition is in a sterile state and has not been oxidized.
  • the discharge container includes a flexible inner container that is deformed in a squeezing manner as the filled oil composition is reduced, and an outer container that accommodates the inner container so that the outside air can be accommodated between the inner container and the discharge container. It is configured so that the outside air does not flow into the inner container after the oil composition is discharged, and the vegetable oil can be maintained in a sterile and non-oxidized state until all the oil composition is discharged. To do.
  • the oil composition is filled in the discharge container that has the above-described configuration and prevents the oil composition from coming into contact with the outside air. Mixing can be prevented. Thereby, it is possible to maintain the same quality from the start of use of the cosmetic product to when all of the contained oil composition is used up.
  • an oil composition having an antioxidant effect and an excellent skin beautifying effect as a beauty oil and a cosmetic product including the same.
  • the oil composition according to the present embodiment includes oil as a main component and includes hydrogen-generating silica particles, at least one of elastin and ceramide NP, and placenta. However, the oil composition according to the present embodiment does not contain a surfactant.
  • the oil as the main component of the oil composition according to this embodiment vegetable oil is preferably used, and olive oil is particularly preferable. Olive oil has an excellent moisturizing effect among vegetable oils, and is preferably applied to the oil composition according to the present embodiment.
  • the oil used as the main component of an oil composition is not restricted to vegetable oil, and may contain other oils, such as mineral oil. However, even in this case, vegetable oil is included in the oil composition.
  • the hydrogen-generating silica particles contained in the oil composition according to the present embodiment have a property of generating hydrogen by bringing silicon dioxide as a main component and mixing other components as necessary to come into contact with water. It is a thing. Examples of other components include potassium carbonate, potassium citrate, magnesium sulfate, and sodium hydrogen carbonate.
  • the hydrogen-generating silica particles for example, a microcluster or a unicluster manufactured by Unilife Japan Co., Ltd. can be used.
  • the hydrogen generating silica particles may not have an amount of hydrogen that can be expected to have a sufficient antioxidant effect if the content concentration is too small, and conversely, if the content concentration is too large, there is a risk of undesirable side effects. is there. Therefore, the content concentration of the hydrogen generating silica particles in the oil composition according to this embodiment is preferably about 0.001 wt% to 5 wt%.
  • the well-known elastin or ceramide NP widely used in the cosmetics field can be used as the elastin or ceramide NP contained in the oil composition according to the present embodiment.
  • Elastin and ceramide NP are components that are particularly expected to have a moisturizing effect.
  • the oil composition according to the present embodiment includes one or both of elastin and ceramide NP.
  • the total concentration of these components is preferably 0.00001% by weight or more, for example.
  • placenta contained in the oil composition according to the present embodiment a well-known placenta widely used in the cosmetic field can be used.
  • Placenta is a component that can provide a texture and tension to the skin in addition to a moisturizing effect, can be expected to have a face lift-up effect, and can also be expected to have a whitening effect.
  • the concentration of placenta is preferably 0.00001% by weight or more, for example.
  • the oil composition contains the above components, but may be loaded with further components.
  • further components for example, petrolatum, glycerin, higher alcohol, or the like can be added.
  • higher alcohol for example, octyldodecanol can be used.
  • the oil composition according to this embodiment does not contain a surfactant. For this reason, the damage to the skin by surfactant can be prevented. Further, as described above, since the hydrogen-generating silica particles generate hydrogen by contact with water, the oil composition does not contain water in order to prevent generation of hydrogen before use of the oil composition. It is preferable.
  • the oil composition according to the present embodiment contains oil as a main component.
  • the oil composition is preferably in a sterile state.
  • the cosmetic product including the oil composition according to the present embodiment uses a discharge container having a structure in which outside air containing oxygen or the like is not mixed into the container that stores the oil composition even after repeated use. .
  • the oil composition according to the present embodiment is contained in a discharge container, and the discharge container is squeezed as the filled oil composition decreases.
  • the vegetable oil can be maintained in a sterile and unoxidized state until the entire oil composition is discharged.
  • an antioxidant container used in the food industry can be used.
  • the discharge containers disclosed in Japanese Patent Application Laid-Open Nos. 2004-231280 and 2012-192975 are disclosed. Can be used.
  • oil composition according to the present embodiment and the cosmetic product including the oil composition include the components described above, an excellent skin beautifying effect can be obtained by applying to the skin.
  • Example 1 and Example 2 which are oil compositions according to the present invention, and a comparative example, which is a conventional oil composition not including the structure of the present invention, are applied to human skin. The effect was evaluated and compared.
  • Example 1 The oil composition of Example 1 was obtained by adding olive oil as a main component and adding hydrogen-generating silica particles, elastin and placenta.
  • hydrogen-generating silica particles Unicluster manufactured by Unilife Japan Co., which contains potassium carbonate, potassium citrate, magnesium sulfate and sodium hydrogen carbonate in addition to silica was used at a concentration of 0.5% by weight.
  • the oil composition of Example 2 was prepared by using ceramide NP instead of elastin in the composition of Example 1 above.
  • the oil composition of Comparative Example was composed of olive oil as the main component and containing only 0.5% by weight of the above unicluster.
  • Test Example 1 First, Test Example 1 in which Example 1 is compared with a comparative example will be described.
  • Test Example 1 six people were tested, and the oil composition of Example 1 or Comparative Example was applied to each person's face twice a day in the morning and at night for 5 days to evaluate the effect.
  • the evaluation items were moisturizing, moisturizing persistence, pore tightness, lift-up, lift-up persistence, skin texture, and visual impression (rigidity) in 5 stages (5 is the highest, 1 is the lowest) .
  • the age and sex of the six test subjects are as follows. A: a man in his 50s, B: a woman in his 40s, C: a woman in his 20s, D: a man in his 50s, E: a woman in his 70s, F: a man in his 40s.
  • Test Example 1 The results of Test Example 1 are shown in Table 1 below.
  • Table 1 in each column of A to F, the left column shows the evaluation of Example 1, and the right column shows the evaluation of the comparative example.
  • the oil composition of Example 1 showed an effect superior to that of the comparative example regardless of gender and age.
  • the oil composition of Example 1 showed excellent results in the evaluation items regarding lift-up and its sustainability.
  • Test Example 2 Next, Test Example 2 in which Example 2 is compared with Comparative Example will be described.
  • Test Example 2 seven people were used as test subjects, and the oil composition of Example 2 or Comparative Example was applied to each person's face twice a day in the morning and at night for two days to evaluate the effect. Evaluation items were moisturizing, moisturizing persistence, pore tightness, lift-up, lift-up persistence, skin texture, appearance impression (brightness), and whitening (5 is the best, 1 is Minimum).
  • a to C are the same as A to C in Test Example 1, and the age and sex of the other four are as follows.
  • G Women in their 20s
  • H Women in their 30s
  • I Women in their 40s
  • J Women in their 50s.
  • Test Example 2 The results of Test Example 2 are shown in Table 2 below.
  • Table 2 In Table 2, in each column of A to C and G to J, the left column shows the evaluation of Example 2, and the right column shows the evaluation of the comparative example.
  • the whitening evaluation items were evaluated only by 4 persons from G to H.
  • the oil composition of Example 2 showed an effect superior to that of the comparative example regardless of gender and age. Similar to the oil composition of Example 1, the oil composition of Example 2 showed excellent results in the evaluation items regarding lift-up and its sustainability.
  • Test Example 3 three people were tested, and the oil compositions of Examples 3 to 8 were applied to each person's face twice a day in the morning and at night for 3 days to evaluate the effects.
  • the evaluation items were moisturization, pore tightness, lift-up, skin texture, and visual impression (wrinkle), which were evaluated in five levels (5 is the highest, 1 is the lowest).
  • the results of Test Example 3 are shown in Table 4 below. Table 4 shows the average of the evaluation of three people.
  • Example 4 As shown in Table 4, any of the effects was recognized in any of the examples. Considering Example 3 as a reference, Example 4 with increased amounts of olive oil and placenta gave better results for moisture retention, pore tightness and skin texture. This result is attributed to the characteristics of olive oil and placenta. Further, in Example 5 in which the amount of hydrogen generating silica was increased compared to Example 4 and the amount of olive oil was reduced, the same effect as Example 4 was shown and the visual impression (brightness) was A better effect than in Example 4 was observed. Further, in Example 6 in which the amount of hydrogen-generating silica was increased as compared with Example 3, a better result than Example 3 was obtained as in Examples 4 and 5.
  • oil composition according to the present invention can be expected to have various skin beautifying effects.
  • the oil composition according to the present invention provides an excellent skin effect when applied to the skin, and is useful as a cosmetic material such as beauty oil.

Abstract

This oil composition includes a plant-based vegetable oil, hydrogen-generating silica particles capable of generating hydrogen upon contact with water, at least one from among elastin and ceramide NP, and placenta, and does not include a surfactant.

Description

オイル組成物及びそれを含む化粧料製品Oil composition and cosmetic product containing the same
　本発明は、オイル組成物及びそれを含む化粧料製品に関し、特に、人の肌に適用する美容用のオイル組成物及びそれを含む化粧料製品に関する。 The present invention relates to an oil composition and a cosmetic product including the same, and more particularly to a cosmetic oil composition applied to human skin and a cosmetic product including the same.
　従来から人の肌の保湿等のための美容オイルが知られている。美容オイルには、主成分となるオイルの他に、付加的効果をもたらすための材料が加えられている。例えば、保湿効果をより向上するための成分としてコラーゲンやヒアルロン酸等が知られている。 Conventionally, beauty oils for moisturizing human skin are known. In addition to the oil as the main component, cosmetic oils are added with materials for providing an additional effect. For example, collagen and hyaluronic acid are known as components for further improving the moisturizing effect.
　また、近年、化粧品業界において水素を含む化粧品の開発及び販売が進められている。水素は、抗酸化作用を有し、皮膚老化や酸化ストレスの原因となる活性酸素を低減する効果を奏する。化粧品に水素を利用する技術について、例えば特許文献１、２に開示がある。 In recent years, cosmetics containing hydrogen have been developed and sold in the cosmetics industry. Hydrogen has an antioxidant effect and has an effect of reducing active oxygen which causes skin aging and oxidative stress. For example, Patent Documents 1 and 2 disclose techniques for using hydrogen in cosmetics.
　特許文献１には、肌に直接接触するスキンケア用品に皮膚の老化を抑制又は予防する効果を付与するために、水素を加えることが記載されている。しかしながら、特許文献１のように、例えばスキンケア用品に水素を加えても、時間の経過と共に水素が抜けていくため、長期保存には適しない。 Patent Document 1 describes that hydrogen is added to a skin care product that directly contacts the skin in order to impart an effect of suppressing or preventing skin aging. However, as in Patent Document 1, even if hydrogen is added to a skin care product, for example, hydrogen is released over time, so that it is not suitable for long-term storage.
　このため、直接に水素を添加するのではなく、水素発生性材料を化粧品中に含有させて、使用時に水素が発生するような構成にすることが考えられている。特許文献２には、このような水素発生性材料を含む美容パック材が開示されている。特許文献２では、特に、マイクロクラスター化したシリカを水素発生性材料としており、当該材料は水と接触することにより水素を発生する性質を有する。 For this reason, instead of directly adding hydrogen, it is considered that a hydrogen generating material is included in cosmetics so that hydrogen is generated during use. Patent Document 2 discloses a beauty pack material containing such a hydrogen generating material. In Patent Document 2, in particular, microclustered silica is used as a hydrogen-generating material, and the material has a property of generating hydrogen by contact with water.
特開２０００－１１９１６１号公報JP 2000-119161 A 特開２０１５－８９８８０号公報Japanese Patent Laying-Open No. 2015-89880
　化粧品は、含まれる成分の組合せにより、その効果や使用感が変化するため、オイルに特許文献２に記載されるようなマイクロクラスター化シリカを含有させた美容オイルを製造する場合、その最適な組成を見出す必要がある。 The cosmetic composition changes its effect and feeling of use depending on the combination of the components contained therein. Therefore, when producing a cosmetic oil containing microclustered silica as described in Patent Document 2, the optimal composition of the cosmetic product is described. It is necessary to find out.
　本発明は、前記の問題に鑑みてなされたものであり、その目的は、水素発生性シリカ粒子を含むことで水素を発生できると共に、美容オイルとしての効果が優れているオイル組成物及びそれを含む化粧料製品を得ることにある。 The present invention has been made in view of the above-mentioned problems, and an object of the present invention is to generate hydrogen by containing hydrogen-generating silica particles, and to provide an oil composition that has an excellent effect as a beauty oil and an oil composition thereof It is to obtain a cosmetic product containing.
　前記の目的を達成するために、本発明では、オイルに水素発生性シリカ粒子の他に、エラスチン及びセラミドＮＰ（セラミド３）の少なくとも一方と、プラセンタとを含有させた。 In order to achieve the above object, in the present invention, in addition to hydrogen-generating silica particles, at least one of elastin and ceramide NP (ceramide 3) and placenta are contained in the oil.
　具体的に、本発明に係るオイル組成物は、植物を原料とする植物性オイルと、水と接触することにより水素を発生できる水素発生性シリカ粒子と、エラスチン及びセラミドＮＰの少なくとも一方と、プラセンタとを含み、界面活性剤を含まないことを特徴とする。 Specifically, the oil composition according to the present invention includes a vegetable oil made from a plant, hydrogen-producing silica particles capable of generating hydrogen by contact with water, at least one of elastin and ceramide NP, and placenta. And no surfactant.
　本発明に係るオイル組成物によると、水と接触することにより水素を発生できる水素発生性シリカ粒子を含むため、使用時に水と接触することで水素が発生するので、皮膚に適用することにより抗酸化作用を発揮してアンチエイジング効果を奏する。また、エラスチン及びセラミドＮＰの少なくとも一方を含むため、優れた保湿効果が得られ、さらにプラセンタを含むため、肌にキメや張りを与え、顔のリフトアップ効果や美白効果も得られる。すなわち、これらの成分により、優れた保湿効果及び代謝効果が得られるため、優れた美肌効果を奏する。さらに、本発明に係るオイル組成物では、界面活性剤を含まないため、当該オイル組成物を適用された肌が望まれないダメージを受けることを防止できる。 According to the oil composition of the present invention, since it contains hydrogen-generating silica particles capable of generating hydrogen by contact with water, hydrogen is generated by contact with water during use. Demonstrates an anti-aging effect by exerting an oxidizing action. In addition, since it contains at least one of elastin and ceramide NP, an excellent moisturizing effect can be obtained. Further, since it contains a placenta, the skin is textured and tensioned, and a face lift-up effect and a whitening effect are also obtained. That is, since these components provide an excellent moisturizing effect and metabolic effect, an excellent skin beautifying effect is achieved. Furthermore, since the oil composition according to the present invention does not contain a surfactant, the skin to which the oil composition is applied can be prevented from receiving unwanted damage.
　本発明に係るオイル組成物において、植物性オイルは、オリーブオイルであることが好ましい。 In the oil composition according to the present invention, the vegetable oil is preferably olive oil.
　植物性オイルとしてオリーブオイルを用いることにより、皮膚に対して良好な保湿効果等の美肌効果を与えることができる。 By using olive oil as a vegetable oil, it is possible to impart skin beautifying effects such as a good moisturizing effect to the skin.
　本発明に係るオイル組成物において、水素発生性シリカ粒子には、炭酸カリウム、クエン酸カリウム、硫酸マグネシウム及び炭酸水素ナトリウムの少なくとも一種が含まれていてもよい。 In the oil composition according to the present invention, the hydrogen generating silica particles may contain at least one of potassium carbonate, potassium citrate, magnesium sulfate, and sodium hydrogen carbonate.
　本発明に係る化粧料製品は、上記のオイル組成物が吐出容器に充填されてなる化粧料製品であって、オイル組成物を構成する植物性オイルは、無菌状態で且つ酸化を受けておらず、吐出容器は、充填された前記オイル組成物の減少に伴いしぼみ変形する可撓性の内容器と、内容器との間に外気を収容できるように該内容器を収容する外容器とを備え、オイル組成物の吐出後に外気が内容器に流入しないように構成されており、オイル組成物を全て吐出するまで、植物性オイルを無菌状態で且つ酸化を受けていない状態に維持できることを特徴とする。 A cosmetic product according to the present invention is a cosmetic product in which the above oil composition is filled in a discharge container, and the vegetable oil constituting the oil composition is in a sterile state and has not been oxidized. The discharge container includes a flexible inner container that is deformed in a squeezing manner as the filled oil composition is reduced, and an outer container that accommodates the inner container so that the outside air can be accommodated between the inner container and the discharge container. It is configured so that the outside air does not flow into the inner container after the oil composition is discharged, and the vegetable oil can be maintained in a sterile and non-oxidized state until all the oil composition is discharged. To do.
　本発明に係る化粧料製品によると、上記構成を有し、オイル組成物が外気と接触することを防ぐ吐出容器にオイル組成物が充填されているため、オイル組成物が酸化したり、細菌が混入したりすることを防止できる。これにより、当該化粧料製品の使用開始時から、収容されたオイル組成物を全て使い切るまでの間、同等の品質を保持することが可能となる。 According to the cosmetic product of the present invention, the oil composition is filled in the discharge container that has the above-described configuration and prevents the oil composition from coming into contact with the outside air. Mixing can be prevented. Thereby, it is possible to maintain the same quality from the start of use of the cosmetic product to when all of the contained oil composition is used up.
　本発明によると、抗酸化効果があり、美容オイルとしての美肌効果が優れているオイル組成物及びそれを含む化粧料製品を得ることができる。 According to the present invention, it is possible to obtain an oil composition having an antioxidant effect and an excellent skin beautifying effect as a beauty oil, and a cosmetic product including the same.
　以下、本発明を実施するための形態を説明する。以下の好ましい実施形態の説明は、本質的に例示に過ぎず、本発明、その適用方法或いはその用途を制限することを意図するものではない。 Hereinafter, modes for carrying out the present invention will be described. The following description of the preferred embodiments is merely exemplary in nature and is not intended to limit the invention, its method of application, or its application.
　本実施形態に係るオイル組成物は、オイルを主成分とし、水素発生性シリカ粒子と、エラスチン及びセラミドＮＰの少なくとも一方と、プラセンタとを含むものである。但し、本実施形態に係るオイル組成物は、界面活性剤を含まない。 The oil composition according to the present embodiment includes oil as a main component and includes hydrogen-generating silica particles, at least one of elastin and ceramide NP, and placenta. However, the oil composition according to the present embodiment does not contain a surfactant.
　本実施形態に係るオイル組成物の主成分となるオイルとしては、植物性オイルが用いられることが好ましく、特にオリーブオイルであることが好ましい。オリーブオイルは、植物性オイルの中でも保湿効果に優れており、本実施形態に係るオイル組成物に適用することが好ましい。また、オイル組成物の主成分となるオイルは、植物性オイルに限らず、ミネラルオイル等の他のオイルが含まれていてもよい。但し、この場合であっても植物性オイルはオイル組成物に含まれる。 As the oil as the main component of the oil composition according to this embodiment, vegetable oil is preferably used, and olive oil is particularly preferable. Olive oil has an excellent moisturizing effect among vegetable oils, and is preferably applied to the oil composition according to the present embodiment. Moreover, the oil used as the main component of an oil composition is not restricted to vegetable oil, and may contain other oils, such as mineral oil. However, even in this case, vegetable oil is included in the oil composition.
　本実施形態に係るオイル組成物に含まれる水素発生性シリカ粒子とは、二酸化珪素を主成分とし、必要に応じてその他の成分を配合して水と接触することで水素を発生する性質を付与したものである。他の成分としては、例えば炭酸カリウム、クエン酸カリウム、硫酸マグネシウム及び炭酸水素ナトリウムが挙げられる。また、水素発生性シリカ粒子は、例えばユニライフジャパン株式会社製のマイクロクラスター又はユニクラスター等を用いることができる。なお、本実施形態において、水素発生性シリカ粒子は、含有濃度が小さ過ぎると抗酸化作用を十分に期待できる水素量が得られず、逆に含有濃度が大きすぎると望まれない副作用のおそれがある。従って、本実施形態に係るオイル組成物において水素発生性シリカ粒子の含有濃度は０．００１重量％～５重量％程度であることが好ましい。 The hydrogen-generating silica particles contained in the oil composition according to the present embodiment have a property of generating hydrogen by bringing silicon dioxide as a main component and mixing other components as necessary to come into contact with water. It is a thing. Examples of other components include potassium carbonate, potassium citrate, magnesium sulfate, and sodium hydrogen carbonate. In addition, as the hydrogen-generating silica particles, for example, a microcluster or a unicluster manufactured by Unilife Japan Co., Ltd. can be used. In the present embodiment, the hydrogen generating silica particles may not have an amount of hydrogen that can be expected to have a sufficient antioxidant effect if the content concentration is too small, and conversely, if the content concentration is too large, there is a risk of undesirable side effects. is there. Therefore, the content concentration of the hydrogen generating silica particles in the oil composition according to this embodiment is preferably about 0.001 wt% to 5 wt%.
　本実施形態に係るオイル組成物に含まれるエラスチン又はセラミドＮＰは、化粧品分野において広く用いられている周知のエラスチン又はセラミドＮＰを用いることができる。エラスチン及びセラミドＮＰは、特に保湿効果が期待される成分である。本実施形態に係るオイル組成物は、エラスチンとセラミドＮＰとのいずれか一方又はその両方を含む。これらの成分の総含有濃度としては、例えば０．００００１重量％以上であることが好ましい。 The well-known elastin or ceramide NP widely used in the cosmetics field can be used as the elastin or ceramide NP contained in the oil composition according to the present embodiment. Elastin and ceramide NP are components that are particularly expected to have a moisturizing effect. The oil composition according to the present embodiment includes one or both of elastin and ceramide NP. The total concentration of these components is preferably 0.00001% by weight or more, for example.
　本実施形態に係るオイル組成物に含まれるプラセンタは、化粧品分野において広く用いられている周知のプラセンタを用いることができる。プラセンタは、保湿効果に加え、肌にキメや張りを与え、顔のリフトアップ効果が期待でき、他に美白効果等も期待できる成分である。本実施形態に係るオイル組成物において、プラセンタの含有濃度は、例えば０．００００１重量％以上であることが好ましい。 As the placenta contained in the oil composition according to the present embodiment, a well-known placenta widely used in the cosmetic field can be used. Placenta is a component that can provide a texture and tension to the skin in addition to a moisturizing effect, can be expected to have a face lift-up effect, and can also be expected to have a whitening effect. In the oil composition according to the present embodiment, the concentration of placenta is preferably 0.00001% by weight or more, for example.
　本実施形態において、オイル組成物は上記の成分を含有するが、更なる成分を負荷しても構わない。例えば保湿効果を向上させるために、例えばワセリンやグリセリン、高級アルコール等を加えることができる。高級アルコールとしては、例えばオクチルドデカノールを用いることができる。 In this embodiment, the oil composition contains the above components, but may be loaded with further components. For example, in order to improve the moisturizing effect, for example, petrolatum, glycerin, higher alcohol, or the like can be added. As the higher alcohol, for example, octyldodecanol can be used.
　一方、本実施形態に係るオイル組成物は界面活性剤も含まない。このため、界面活性剤による肌へのダメージを防止できる。また、上述の通り、水素発生性シリカ粒子は、水と接触することにより水素を発生するので、当該オイル組成物の使用前における水素の発生を防止するために、オイル組成物は水を含まないことが好ましい。 On the other hand, the oil composition according to this embodiment does not contain a surfactant. For this reason, the damage to the skin by surfactant can be prevented. Further, as described above, since the hydrogen-generating silica particles generate hydrogen by contact with water, the oil composition does not contain water in order to prevent generation of hydrogen before use of the oil composition. It is preferable.
　本実施形態に係るオイル組成物は、上述の通り、オイルを主成分といるが、オイルは酸化するとその特性が変化し、美肌効果も低減するため、酸化していないオイルを用いることが好ましい。また、当然に当該オイル組成物は無菌状態であることが好ましい。これらの理由から、本実施形態に係るオイル組成物を含む化粧料製品には、繰り返しの使用によってもオイル組成物を収容する容器内に酸素等を含む外気を混入させない構造の吐出容器が用いられる。 As described above, the oil composition according to the present embodiment contains oil as a main component. However, when the oil is oxidized, its characteristics change and the skin beautifying effect is reduced. Therefore, it is preferable to use an oil that has not been oxidized. Of course, the oil composition is preferably in a sterile state. For these reasons, the cosmetic product including the oil composition according to the present embodiment uses a discharge container having a structure in which outside air containing oxygen or the like is not mixed into the container that stores the oil composition even after repeated use. .
　具体的に、本実施形態に係る化粧料製品は、上記本実施形態に係るオイル組成物が吐出容器に収容されたものであり、該吐出容器は、充填されたオイル組成物の減少に伴いしぼみ変形する可撓性の内容器と、該内容器との間に外気を収容できるように該内容器を収容する外容器とを備え、オイル組成物の吐出後に外気が内容器に流入しないように構成されている。このような構造により、オイル組成物を全て吐出するまで、植物性オイルを無菌状態で且つ酸化を受けていない状態に維持できる。このような吐出容器としては、食品業界で用いられているような酸化防止容器を用いることができ、例えば特開２００４－２３１２８０号公報や特開２０１２－１９２９７５号公報等に開示されている吐出容器を用いることができる。 Specifically, in the cosmetic product according to the present embodiment, the oil composition according to the present embodiment is contained in a discharge container, and the discharge container is squeezed as the filled oil composition decreases. A flexible inner container that deforms, and an outer container that accommodates the inner container so that the outer air can be accommodated between the inner container, so that the outer air does not flow into the inner container after the oil composition is discharged. It is configured. With such a structure, the vegetable oil can be maintained in a sterile and unoxidized state until the entire oil composition is discharged. As such a discharge container, an antioxidant container used in the food industry can be used. For example, the discharge containers disclosed in Japanese Patent Application Laid-Open Nos. 2004-231280 and 2012-192975 are disclosed. Can be used.
　以上に説明したように、本実施形態に係るオイル組成物及びそれを含む化粧料製品は、上述した成分を含むため、肌に適用することにより、優れた美肌効果が得られる。 As described above, since the oil composition according to the present embodiment and the cosmetic product including the oil composition include the components described above, an excellent skin beautifying effect can be obtained by applying to the skin.
　以下に、本発明に係るオイル組成物を詳細に説明するための実施例を示す。 Examples for explaining the oil composition according to the present invention in detail are shown below.
　本実施例では、本発明に係るオイル組成物である実施例１及び実施例２と、本発明の構成を含まない従来のオイル組成物である比較例とを人の肌に適用し、それぞれの効果について評価し、比較した。 In this example, Example 1 and Example 2, which are oil compositions according to the present invention, and a comparative example, which is a conventional oil composition not including the structure of the present invention, are applied to human skin. The effect was evaluated and compared.
　オリーブオイルを主成分とし、これに水素発生性シリカ粒子、エラスチン及びプラセンタを加えたものを実施例１のオイル組成物とした。なお、水素発生性シリカ粒子としては、シリカの他に、炭酸カリウム、クエン酸カリウム、硫酸マグネシウム及び炭酸水素ナトリウムを含むユニライフジャパン株式会社製のユニクラスターを０．５重量％の濃度で用いた。 The oil composition of Example 1 was obtained by adding olive oil as a main component and adding hydrogen-generating silica particles, elastin and placenta. In addition, as the hydrogen-generating silica particles, Unicluster manufactured by Unilife Japan Co., which contains potassium carbonate, potassium citrate, magnesium sulfate and sodium hydrogen carbonate in addition to silica was used at a concentration of 0.5% by weight.
　また、上記実施例１の組成においてエラスチンの代わりにセラミドＮＰを用いたものを実施例２のオイル組成物とした。また、オリーブオイルを主成分とし、０．５重量％の上記ユニクラスターのみを含むものを比較例のオイル組成物とした。 The oil composition of Example 2 was prepared by using ceramide NP instead of elastin in the composition of Example 1 above. The oil composition of Comparative Example was composed of olive oil as the main component and containing only 0.5% by weight of the above unicluster.
　（試験例１）
　まず、実施例１と比較例とを比較した試験例１について説明する。試験例１では、６名の人を試験対象とし、各人の顔に実施例１又は比較例のオイル組成物を朝と夜の１日２回で５日間適用し、その効果を評価した。評価項目は保湿、保湿の持続性、毛穴のしまり、リフトアップ、リフトアップの持続性、肌のキメ、及び見た目の印象（溌剌さ）を５段階で評価した（５が最高、１が最低）。なお、試験対象の６名の年齢と性別は以下の通りである。Ａ：５０代の男性、Ｂ：４０代の女性、Ｃ：２０代の女性、Ｄ：５０代の男性、Ｅ：７０代の女性、Ｆ：４０代の男性。 (Test Example 1)
First, Test Example 1 in which Example 1 is compared with a comparative example will be described. In Test Example 1, six people were tested, and the oil composition of Example 1 or Comparative Example was applied to each person's face twice a day in the morning and at night for 5 days to evaluate the effect. The evaluation items were moisturizing, moisturizing persistence, pore tightness, lift-up, lift-up persistence, skin texture, and visual impression (rigidity) in 5 stages (5 is the highest, 1 is the lowest) . The age and sex of the six test subjects are as follows. A: a man in his 50s, B: a woman in his 40s, C: a woman in his 20s, D: a man in his 50s, E: a woman in his 70s, F: a man in his 40s.
　試験例１の結果を以下の表１に示す。なお、表１においてＡ～Ｆの各人の欄において、左欄は実施例１、右欄は比較例の評価を示す。 The results of Test Example 1 are shown in Table 1 below. In Table 1, in each column of A to F, the left column shows the evaluation of Example 1, and the right column shows the evaluation of the comparative example.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
　表１に示すように全ての評価項目において、性別及び年代を問わず、実施例１のオイル組成物は比較例のオイル組成物よりも優れた効果を示した。特に、実施例１のオイル組成物では、リフトアップ及びその持続性に関する評価項目において優れた結果を示した。 As shown in Table 1, in all evaluation items, the oil composition of Example 1 showed an effect superior to that of the comparative example regardless of gender and age. In particular, the oil composition of Example 1 showed excellent results in the evaluation items regarding lift-up and its sustainability.
　（試験例２）
　次に、実施例２と比較例とを比較した試験例２について説明する。試験例２では、７名の人を試験対象とし、各人の顔に実施例２又は比較例のオイル組成物を朝と夜の１日２回で２日間適用し、その効果を評価した。評価項目は保湿、保湿の持続性、毛穴のしまり、リフトアップ、リフトアップの持続性、肌のキメ、見た目の印象（溌剌さ）、及び美白を５段階で評価した（５が最高、１が最低）。なお、試験対象の７名のうちＡ～Ｃは試験例１のＡ～Ｃと同一人であり、他の４名の年齢と性別は以下の通りである。Ｇ：２０代の女性、Ｈ：３０代の女性、Ｉ：４０代の女性、Ｊ：５０代の女性。 (Test Example 2)
Next, Test Example 2 in which Example 2 is compared with Comparative Example will be described. In Test Example 2, seven people were used as test subjects, and the oil composition of Example 2 or Comparative Example was applied to each person's face twice a day in the morning and at night for two days to evaluate the effect. Evaluation items were moisturizing, moisturizing persistence, pore tightness, lift-up, lift-up persistence, skin texture, appearance impression (brightness), and whitening (5 is the best, 1 is Minimum). Of the seven test subjects, A to C are the same as A to C in Test Example 1, and the age and sex of the other four are as follows. G: Women in their 20s, H: Women in their 30s, I: Women in their 40s, J: Women in their 50s.
　試験例２の結果を以下の表２に示す。なお、表２においてＡ～Ｃ及びＧ～Ｊの各人の欄において、左欄は実施例２、右欄は比較例の評価を示す。なお、美白の評価項目はＧ～Ｈの４名のみが評価した。 The results of Test Example 2 are shown in Table 2 below. In Table 2, in each column of A to C and G to J, the left column shows the evaluation of Example 2, and the right column shows the evaluation of the comparative example. The whitening evaluation items were evaluated only by 4 persons from G to H.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
　表２に示すように全ての評価項目において、性別及び年代を問わず、実施例２のオイル組成物は比較例のオイル組成物よりも優れた効果を示した。実施例２のオイル組成物も実施例１のオイル組成物と同様に、リフトアップ及びその持続性に関する評価項目において優れた結果を示した。 As shown in Table 2, in all the evaluation items, the oil composition of Example 2 showed an effect superior to that of the comparative example regardless of gender and age. Similar to the oil composition of Example 1, the oil composition of Example 2 showed excellent results in the evaluation items regarding lift-up and its sustainability.
　（試験例３）
　次に、オイル組成物の各成分の含有比率を変えて、各比率におけるオイル組成物の効果を比較した。具体的に、以下に示す実施例３～８の６種類のオイル組成物を調製し、それらを比較した。なお、表３の各成分の数値の単位は重量％である。 (Test Example 3)
Next, the content ratio of each component of the oil composition was changed, and the effects of the oil composition at each ratio were compared. Specifically, six types of oil compositions of Examples 3 to 8 shown below were prepared and compared. In addition, the unit of the numerical value of each component of Table 3 is weight%.
Figure JPOXMLDOC01-appb-T000003
  
Figure JPOXMLDOC01-appb-T000003
  
　試験例３では、３名の人を試験対象とし、各人の顔に実施例３～８のオイル組成物を朝と夜の１日２回で３日間適用し、その効果を評価した。評価項目は保湿、毛穴のしまり、リフトアップ、肌のキメ、及び見た目の印象（溌剌さ）を５段階で評価した（５が最高、１が最低）。試験例３の結果を以下の表４に示す。なお、表４は３名の評価の平均を示す。 In Test Example 3, three people were tested, and the oil compositions of Examples 3 to 8 were applied to each person's face twice a day in the morning and at night for 3 days to evaluate the effects. The evaluation items were moisturization, pore tightness, lift-up, skin texture, and visual impression (wrinkle), which were evaluated in five levels (5 is the highest, 1 is the lowest). The results of Test Example 3 are shown in Table 4 below. Table 4 shows the average of the evaluation of three people.
Figure JPOXMLDOC01-appb-T000004
  
Figure JPOXMLDOC01-appb-T000004
  
　表４に示すように、いずれの実施例においてもいずれかの効果は認められた。実施例３を基準として考えた場合、オリーブオイル及びプラセンタの量を増やした実施例４は、保湿、毛穴のしまり及び肌のキメについてより良好な結果が得られた。この結果は、オリーブオイルやプラセンタのそれぞれが持つ特性に起因するものと考えられる。また、実施例４よりも水素発生性シリカの量を増大させ、オリーブオイルの量を低減させた実施例５では、実施例４と同等の効果を示し且つ見た目の印象（溌剌さ）については、実施例４よりも良好な効果が認められた。また、実施例３と比較して水素発生性シリカの量を増大させた実施例６においても、実施例４や５と同じく実施例３よりも良好な結果が得られた。これらの結果から、水素発生性シリカの量をある程度増やすことにより、良好な効果が得られると考えられる。但し、実施例７のように、水素発生性シリカ等の成分を過剰に増やしても効果の増大は認められなかった。反対に、実施例８のように、水素発生性シリカ等の成分を低減すると、上記各効果も低減することとなる。上記結果から、特に実施例３～６の成分比率又はそれらに近い成分比率でオイル組成物を調製することが好ましいといえる。 As shown in Table 4, any of the effects was recognized in any of the examples. Considering Example 3 as a reference, Example 4 with increased amounts of olive oil and placenta gave better results for moisture retention, pore tightness and skin texture. This result is attributed to the characteristics of olive oil and placenta. Further, in Example 5 in which the amount of hydrogen generating silica was increased compared to Example 4 and the amount of olive oil was reduced, the same effect as Example 4 was shown and the visual impression (brightness) was A better effect than in Example 4 was observed. Further, in Example 6 in which the amount of hydrogen-generating silica was increased as compared with Example 3, a better result than Example 3 was obtained as in Examples 4 and 5. From these results, it is considered that a good effect can be obtained by increasing the amount of the hydrogen generating silica to some extent. However, as in Example 7, an increase in the effect was not recognized even if the components such as hydrogen-generating silica were excessively increased. On the other hand, if the components such as hydrogen generating silica are reduced as in Example 8, the above-mentioned effects are also reduced. From the above results, it can be said that it is particularly preferable to prepare the oil composition at the component ratio of Examples 3 to 6 or a component ratio close thereto.
　以上の各試験例から、本発明に係るオイル組成物は、各種の美肌効果が期待できることが示唆された。 From the above test examples, it was suggested that the oil composition according to the present invention can be expected to have various skin beautifying effects.
　本発明に係るオイル組成物は、肌に適用することにより優れた美肌効果が得られ、美容オイル等の化粧料として有用である。 The oil composition according to the present invention provides an excellent skin effect when applied to the skin, and is useful as a cosmetic material such as beauty oil.

Claims (4)

  1. 　植物を原料とする植物性オイルと、
    　水と接触することにより水素を発生できる水素発生性シリカ粒子と、
    　エラスチン及びセラミドＮＰの少なくとも一方と、
    　プラセンタと、を含み、
    　界面活性剤を含まないことを特徴とするオイル組成物。     Vegetable oil made from plants,
    Hydrogen-generating silica particles capable of generating hydrogen by contact with water;
    At least one of elastin and ceramide NP;
    A placenta, and
    An oil composition characterized by not containing a surfactant.
  2. 　前記植物性オイルは、オリーブオイルであることを特徴とする請求項１に記載のオイル組成物。 The oil composition according to claim 1, wherein the vegetable oil is olive oil.
  3. 　前記水素発生性シリカ粒子には、炭酸カリウム、クエン酸カリウム、硫酸マグネシウム及び炭酸水素ナトリウムの少なくとも一種が含まれていることを特徴とする請求項１又は２に記載のオイル組成物。 The oil composition according to claim 1 or 2, wherein the hydrogen-generating silica particles contain at least one of potassium carbonate, potassium citrate, magnesium sulfate and sodium hydrogen carbonate.
  4. 　請求項１～３のいずれか１項に記載のオイル組成物が吐出容器に充填されてなる化粧料製品であって、
    　前記オイル組成物を構成する前記植物性オイルは、無菌状態で且つ酸化を受けておらず、
    　前記吐出容器は、
    　　充填された前記オイル組成物の減少に伴いしぼみ変形する可撓性の内容器と、
    　　前記内容器との間に外気を収容できるように該内容器を収容する外容器とを備え、
    　　前記オイル組成物の吐出後に外気が前記内容器に流入しないように構成されており、
    　前記オイル組成物を全て吐出するまで、前記植物性オイルを無菌状態で且つ酸化を受けていない状態に維持できることを特徴とする化粧料製品。     A cosmetic product in which the oil composition according to any one of claims 1 to 3 is filled in a discharge container,
    The vegetable oil constituting the oil composition is sterile and not oxidized,
    The discharge container is
    A flexible inner container that deforms by sag as the filled oil composition decreases,
    An outer container that houses the inner container so that outside air can be accommodated between the inner container,
    It is configured so that outside air does not flow into the inner container after discharging the oil composition,
    A cosmetic product characterized in that the vegetable oil can be maintained in a sterile and non-oxidized state until all of the oil composition is discharged.
PCT/JP2018/002163 2017-01-24 2018-01-24 Oil composition and cosmetic product including same WO2018139498A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2017010391 2017-01-24
JP2017-010391 2017-01-24
JP2017126986A JP2018118954A (en) 2017-01-24 2017-06-29 Oil composition and cosmetic product including the same
JP2017-126986 2017-06-29

Publications (1)

Publication Number Publication Date
WO2018139498A1 true WO2018139498A1 (en) 2018-08-02

Family

ID=62979074

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2018/002163 WO2018139498A1 (en) 2017-01-24 2018-01-24 Oil composition and cosmetic product including same

Country Status (1)

Country Link
WO (1) WO2018139498A1 (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004231280A (en) * 2003-01-31 2004-08-19 Yoshino Kogyosho Co Ltd Synthetic resin container
JP2010505886A (en) * 2006-10-13 2010-02-25 エヴォニク ゴールドシュミット ゲーエムベーハー Skin treatment composition
JP2012192975A (en) * 2011-02-28 2012-10-11 Yoshino Kogyosho Co Ltd Discharging container
JP2014019689A (en) * 2012-07-23 2014-02-03 Kracie Home Products Ltd Powder for hydrogen generation
JP2014028714A (en) * 2012-07-31 2014-02-13 Kracie Home Products Ltd Composition for generating hydrogen
JP2014205635A (en) * 2013-04-12 2014-10-30 クラシエホームプロダクツ株式会社 Hydrogen generating composition and bath composition
JP2015157774A (en) * 2014-02-24 2015-09-03 オリザ油化株式会社 Lipoperoxide inhibitor of keratinocyte and fibroblast, and skin aging inhibitor using the same

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004231280A (en) * 2003-01-31 2004-08-19 Yoshino Kogyosho Co Ltd Synthetic resin container
JP2010505886A (en) * 2006-10-13 2010-02-25 エヴォニク ゴールドシュミット ゲーエムベーハー Skin treatment composition
JP2012192975A (en) * 2011-02-28 2012-10-11 Yoshino Kogyosho Co Ltd Discharging container
JP2014019689A (en) * 2012-07-23 2014-02-03 Kracie Home Products Ltd Powder for hydrogen generation
JP2014028714A (en) * 2012-07-31 2014-02-13 Kracie Home Products Ltd Composition for generating hydrogen
JP2014205635A (en) * 2013-04-12 2014-10-30 クラシエホームプロダクツ株式会社 Hydrogen generating composition and bath composition
JP2015157774A (en) * 2014-02-24 2015-09-03 オリザ油化株式会社 Lipoperoxide inhibitor of keratinocyte and fibroblast, and skin aging inhibitor using the same

Similar Documents

Publication Publication Date Title
CN107997996B (en) Double-layer facial cleanser and preparation method thereof
KR101270308B1 (en) The porous puff for make-up and cosmetic composition impreganted in the same
US7981403B2 (en) Artificial hair color removal compositions and methods
TW201701866A (en) Composition
CA2417702A1 (en) Moist cleansing, skin care or cosmetic article
Alaghehmand et al. Effect of fluoride-free and fluoridated carbamide peroxide gels on the hardness and surface roughness of aesthetic restorative materials
KR101964666B1 (en) Water-soluble solid foam cleanser
CN103784343B (en) Foundation cream breast is repaired in the moisturizing of a kind of water profit
CN113908071A (en) Composition for tightening pores, relieving sensitivity and improving skin glossiness and preparation method and application thereof
WO2018139498A1 (en) Oil composition and cosmetic product including same
JP2018118954A (en) Oil composition and cosmetic product including the same
CN110063902A (en) It is a kind of with polyglycereol class be remove ornaments and formal dress ingredient the net face makeup remover of Shu Run and preparation method
KR102172199B1 (en) Cosmetic composition for skin antiaging containing sodium dna and astazanthine
JPH0314284B2 (en)
KR20070098074A (en) Clear cosmetic compositions for high moisturization without emollient
JP2009167146A (en) Cleansing cosmetic composition
JPS6081117A (en) Liquid cosmetic composition of multi-layer type
RU2689156C1 (en) Active additive to perfume and cosmetic products
KR20130109064A (en) Layered cosmetic product comprising fluorine oil
CN102764209A (en) Cosmetic composition and preparation method thereof
JP7408379B2 (en) cleaning composition
KR20200140005A (en) Gommage Type Cosmetic Composition for Exfoliating skin
JP2018203683A (en) Antiperspirant composition
KR20130074137A (en) Water dispersion cosmetic composition comprising polyquaternum-51 and adipic acid/neopentyl glycol crosspolymer suspension solution
JPS6366114A (en) Toothpaste composition

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18744648

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 18744648

Country of ref document: EP

Kind code of ref document: A1