WO2018128315A3 - 중합개시제 조성물, 이의 제조방법 및 이를 이용한 중합체의 제조방법 - Google Patents

중합개시제 조성물, 이의 제조방법 및 이를 이용한 중합체의 제조방법 Download PDF

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Publication number
WO2018128315A3
WO2018128315A3 PCT/KR2017/015531 KR2017015531W WO2018128315A3 WO 2018128315 A3 WO2018128315 A3 WO 2018128315A3 KR 2017015531 W KR2017015531 W KR 2017015531W WO 2018128315 A3 WO2018128315 A3 WO 2018128315A3
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WIPO (PCT)
Prior art keywords
polymerization initiator
preparation
same
initiator composition
preparing polymer
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PCT/KR2017/015531
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English (en)
French (fr)
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WO2018128315A2 (ko
Inventor
최재훈
최종영
최동철
김현주
김현희
이정용
김찬중
이명한
한혜진
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주식회사 엘지화학
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Priority to CN201780076878.5A priority Critical patent/CN110114398B/zh
Priority to JP2019535244A priority patent/JP6888094B2/ja
Priority to EP17889595.9A priority patent/EP3533824A4/en
Priority to US16/468,998 priority patent/US11214665B2/en
Publication of WO2018128315A2 publication Critical patent/WO2018128315A2/ko
Publication of WO2018128315A3 publication Critical patent/WO2018128315A3/ko

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/56Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • C08K5/18Amines; Quaternary ammonium compounds with aromatically bound amino groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/70Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/53Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having the nitrogen atom of at least one of the amino groups further bound to a hydrocarbon radical substituted by amino groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds

Abstract

본 발명은 중합개시제 조성물, 이의 제조방법 및 이를 이용한 중합체 제조방법에 관한 것으로, 본 발명의 중합개시제 조성물은 중합개시제의 이성질체를 포함함으로써, 중합개시제의 불안정과 불활성 및 SSBR의 물성 저하를 방지할 수 있고, 부산물 및 미반응물을 최소화할 수 있으며, 전환율을 획기적으로 개선할 수 있다. 또한, 중합개시제 제조시에 이미 극성첨가제가 첨가되어 중합체 중합시에 별도로 극성 첨가제를 첨가하지 않아도 되며, 소수성인 SSBR과 친수성인 실리카를 효과적으로 분산시키는 장점이 있다.
PCT/KR2017/015531 2017-01-04 2017-12-27 중합개시제 조성물, 이의 제조방법 및 이를 이용한 중합체의 제조방법 WO2018128315A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201780076878.5A CN110114398B (zh) 2017-01-04 2017-12-27 聚合引发剂组合物,其制备方法以及使用该聚合引发剂组合物制备聚合物的方法
JP2019535244A JP6888094B2 (ja) 2017-01-04 2017-12-27 重合開始剤組成物、その製造方法およびそれを用いた重合体の製造方法
EP17889595.9A EP3533824A4 (en) 2017-01-04 2017-12-27 POLYMERIZATION INITIATOR COMPOSITION, PROCESS FOR PREPARING THE SAME, AND PROCESS FOR PREPARING POLYMER USING THE SAME
US16/468,998 US11214665B2 (en) 2017-01-04 2017-12-27 Polymerization initiator composition, preparation method therefor, and method for preparing polymer using same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2017-0001272 2017-01-04
KR20170001272 2017-01-04

Publications (2)

Publication Number Publication Date
WO2018128315A2 WO2018128315A2 (ko) 2018-07-12
WO2018128315A3 true WO2018128315A3 (ko) 2018-11-22

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PCT/KR2017/015531 WO2018128315A2 (ko) 2017-01-04 2017-12-27 중합개시제 조성물, 이의 제조방법 및 이를 이용한 중합체의 제조방법

Country Status (6)

Country Link
US (1) US11214665B2 (ko)
EP (1) EP3533824A4 (ko)
JP (1) JP6888094B2 (ko)
KR (1) KR102034454B1 (ko)
CN (1) CN110114398B (ko)
WO (1) WO2018128315A2 (ko)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2022553037A (ja) * 2020-02-28 2022-12-21 エルジー・ケム・リミテッド 変性共役ジエン系重合体、その製造方法、およびそれを含むゴム組成物
CN113754828B (zh) * 2021-08-23 2022-08-30 南京工业大学 一种微通道前端聚合制备图案化凝胶材料的方法

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Also Published As

Publication number Publication date
WO2018128315A2 (ko) 2018-07-12
JP2020503413A (ja) 2020-01-30
KR102034454B1 (ko) 2019-10-21
EP3533824A4 (en) 2019-12-04
US11214665B2 (en) 2022-01-04
KR20180080687A (ko) 2018-07-12
JP6888094B2 (ja) 2021-06-16
CN110114398B (zh) 2021-07-27
EP3533824A2 (en) 2019-09-04
US20190330447A1 (en) 2019-10-31
CN110114398A (zh) 2019-08-09

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