WO2018113328A1 - Light-emitting diode and manufacturing method therefor - Google Patents

Light-emitting diode and manufacturing method therefor Download PDF

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Publication number
WO2018113328A1
WO2018113328A1 PCT/CN2017/097841 CN2017097841W WO2018113328A1 WO 2018113328 A1 WO2018113328 A1 WO 2018113328A1 CN 2017097841 W CN2017097841 W CN 2017097841W WO 2018113328 A1 WO2018113328 A1 WO 2018113328A1
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Prior art keywords
layer
metal mask
mask layer
type semiconductor
electrode region
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PCT/CN2017/097841
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French (fr)
Chinese (zh)
Inventor
卢怡安
吴俊毅
王笃祥
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厦门三安光电有限公司
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Publication of WO2018113328A1 publication Critical patent/WO2018113328A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes

Definitions

  • the present invention relates to the field of semiconductor manufacturing, and more particularly to a light emitting diode and a method of fabricating the same.
  • Light-emitting diodes are widely used in lighting, home appliances, display screens, and indicator lights because of their low energy consumption, long life, good stability, small size, fast response, and stable luminous length.
  • the light-increasing process of the existing light-emitting diodes generally produces a roughened surface on the light-emitting surface of the device to improve the light-emitting efficiency.
  • the area of the pad electrode and the extension electrode is usually avoided in the roughened etching region to prevent the roughened surface from affecting the flat surface of the electrode and the extension strip.
  • a common process uses a photoresist as a mask, and the photoresist is covered in a place to be covered, usually at the position of the electrode and the extension bar, and is larger than or equal to the area of the electrode and the extension strip, and then the roughening process is performed. .
  • the yellow light alignment before and after the bonding often has a misalignment problem, so that the extended electrodes are not well received.
  • the coverage causes the roughening solution to etch below the electrode extension, creating a risk of fragile or shedding of the metal contact.
  • the present invention provides a light-emitting diode and a manufacturing method for reducing rough side etching.
  • the technical solution of the present invention is: a method for fabricating a light emitting diode, comprising the steps of: (1) providing an epitaxial structure, which in turn comprises a growth substrate, a first type semiconductor layer, an active layer and a second type semiconductor layer;
  • the thickness of the metal mask layer formed in the step (2) is 10 to 200 nm, more preferably 50 to 100 nm.
  • the edge of the metal mask layer formed in the step (2) is at least 2 micrometers, preferably 2 to 10 micrometers, beyond the edge of the extension electrode.
  • a metal mask layer is formed in the pad electrode region and the extended electrode region.
  • the manufacturing method of the light emitting diode further comprises the step (7): forming a pad electrode in a pad electrode region of the second type semiconductor layer.
  • the metal mask layer formed in the step (2) forms an ohmic contact with the second type semiconductor layer.
  • the material of the metal mask layer formed in the step (2) is Au, Cr, Ni, Ti or Pd.
  • Au is used.
  • a metal mask layer and an electrode material layer are formed in the pad electrode region, and the metal mask layer is overlapped with the pad electrode region, and the electrode material is The material of the layer is the same as the material of the extension electrode.
  • Another technical solution of the present invention is: a method for fabricating a light emitting diode, comprising the steps of: (1) providing an epitaxial structure, comprising a growth substrate, a first type semiconductor layer, an active layer, and a second type semiconductor layer in this order; (2) defining a pad electrode region and an extension electrode region on a surface of the second type semiconductor layer, and sequentially forming an extension electrode and a metal mask layer on the extension electrode region, the metal mask layer The area completely covers the extended electrode region and extends outward, the area of the metal mask layer > the area of the extended electrode; (3) providing a temporary substrate, bonding it to the epitaxial structure, and removing the growth Substrate, exposing a surface of the first type of semiconductor layer; (4) providing a conductive substrate, bonding the epitaxial structure, removing the germanium substrate, exposing a portion of the surface and metal of the second type semiconductor layer a mask layer; (5) chemically etching the exposed surface of the second type of semiconductor layer to form a rough
  • the thickness of the metal mask layer formed in the step (2) is 10 to 200 nm, and more preferably 50. ⁇ 100nm.
  • the edge of the metal mask layer formed in the step (2) is at least 2 micrometers, preferably 2 to 10 micrometers, beyond the edge of the extension electrode.
  • a metal mask layer is formed on the pad electrode region and the extended electrode region.
  • the method for fabricating the light emitting diode further comprises the step (7): forming a pad electrode in a pad electrode region of the second type semiconductor layer.
  • the metal mask layer formed in the step (2) forms an ohmic contact with the second type semiconductor layer.
  • the material of the metal mask layer formed in the step (2) is selected from Au, Cr, Ni, Ti or Pd, and Cr is preferably used.
  • the electrode region is first expanded to form an extension electrode, and then a metal mask layer is formed on the surface of the second type semiconductor layer of the pad electrode region and the extension electrode.
  • a metal mask layer is formed only in the extended electrode region, and the pad electrode region does not form a metal mask layer, and the step (5) is first The pad electrode region forms a photoresist layer mask and is etched, and the step (6) further includes removing the photoresist mask layer.
  • the manufacturing method of the light-emitting diode of the present invention firstly forms a metal mask before the bonding process, extends the metal region, directly uses the metal as a rough mask layer, reduces misalignment and roughening side etching problems, and improves the light-emitting diode Quality and yield.
  • a light emitting diode structure fabricated using the method according to the invention is provided.
  • Embodiment 1 is a flow chart showing the fabrication of a light emitting diode according to Embodiment 1 of the present invention.
  • FIGS. 2 to 13 are schematic views showing the process of a light emitting diode according to Embodiment 1 of the present invention.
  • FIG. 14 is a flow chart showing the fabrication of a light emitting diode according to Embodiment 2 of the present invention.
  • 15 to 24 are views showing a manufacturing process of a light emitting diode according to Embodiment 2 of the present invention.
  • 25 to 28 are partial schematic views showing a manufacturing process of a light emitting diode according to Embodiment 3 of the present invention.
  • FIG. 1 is a flow chart of manufacturing a light emitting diode according to a first preferred embodiment of the present invention, which mainly includes steps S110 to S160, and quaternary light emitting diodes are taken as an example below with reference to FIGS. 2-13. Detailed description
  • Step S110 Providing a growth substrate 100 on which the light-emitting epitaxial structure 120 is formed.
  • the growth substrate 100 is preferably made of a III-V compound semiconductor material, such as gallium arsenide, indium phosphide (InP), gallium phosphide or sapphire.
  • the luminescent epitaxial structure may be a conventional epitaxial structure, and may generally include n.
  • the growth substrate 100 is provided, and the etch stop layer 110 is grown directly on the surface of the growth substrate 100 by, for example, deposition.
  • an n-type ohmic contact layer 121 is formed on the etch stop layer 101, wherein the material of the n-type ohmic contact layer 121 may be, for example, gallium arsenide, gallium arsenide or aluminum gallium phosphide.
  • the light-emitting epitaxial structure 120 is grown on the n-type ohmic contact layer 121.
  • the light-emitting epitaxial structure 120 may include an n-type confinement layer 122 and an active layer 123 stacked on the surface of the n-type ohmic contact layer 121 in sequence.
  • the p-type confinement layer 124 and the window layer 125 are as shown in FIG.
  • the material of the N-type confinement layer 122 may be, for example, aluminum gallium arsenide Al x Ga x As, x>0.4 or aluminum gallium indium phosphide (Al x Ga , _ x ) y In , _ y P, x>0.4;
  • the material of the p-type confinement layer 124 may be, for example, aluminum gallium arsenide (Al x G ai — x As, x>0.4) or phosphating.
  • the material of the active layer 123 may be, for example, aluminum gallium indium phosphide ((Al x Ga lx ) y In ly P, x ⁇ 0.5)
  • the material of the window layer 125 can be, for example, gallium phosphide, gallium arsenide, aluminum gallium arsenide or aluminum gallium phosphide.
  • Step S120 defining an electrode region 140 on the surface 120a of the light-emitting epitaxial structure, including a pad electrode region 140a and an extended electrode region 140b, as shown in FIG.
  • a metal mask layer 130 and an electrode material layer 141 are sequentially formed on the electrode region 140, wherein the metal mask layer 130a and the electrode material layer 141a deposited on the pad electrode region 140a substantially coincide with the pad electrode region 130a, and expand.
  • the metal mask layer 130b deposited on the electrode region 140b completely covers the extended electrode region 140b and extends outward.
  • the electrode material layer 141b on the metal mask layer 130b serves as an extension electrode and overlaps the extended electrode region 140b, that is, the metal mask layer 130b.
  • the area is larger than the area of the extension electrode 141b, as shown in Figs. 4 and 5, wherein Fig. 4 is a side cross-sectional view, and Fig. 5 is a plan view.
  • the material of the electrode material layer 140 may be a metal ruthenium alloy, a gold zinc alloy or a chrome gold alloy.
  • the metal mask layer 130 needs to consider the following factors: (1) The spread electrode 141b can be protected as a mask layer in the subsequent roughening process, and the underside of the extended electrode 141b is prevented from being undercut, so that the edge of the metal mask layer 130b is required to extend beyond the extended electrode Preferably, the edge 141 has an excess distance d of at least 2 micrometers, preferably 2 to 5 micrometers.
  • the width dl of the extension electrode 141b is 6 micrometers, and the width of the metal mask layer 130b is 10 micrometers.
  • the distance d between the edge of the film layer 130b and the edge of the extension electrode 141 is 2 ⁇ m; (2) the metal mask layer of the non-electrode region is removed after the rough process is completed, so the thickness of the metal mask layer is not too thick, and The material which is relatively easy to remove, for example, Au or the like, may be used, and the thickness may be 10 to 200 nm, preferably 50 to 100 nm.
  • the metal mask layer 130 is located between the epitaxial layer 125 and the electrode material layer 141, it is necessary to ensure metal.
  • the mask layer 130 forms an ohmic contact with the epitaxial structure 120, so a material that can form an ohmic contact with the epitaxial material layer is used.
  • the metal mask layer 130 is made of Au, which can form a good ohmic contact with the epitaxial layer and is easily removed by a chemical etching solution.
  • Step S130 providing a pass-through substrate 200, bonding the Linyi substrate 200 to the light-emitting epitaxial structure 120 by using the bonding layer 210, and then removing the growth substrate 100 on the light-emitting epitaxial structure 120 to expose the surface of the n-type semiconductor layer.
  • the bonding layer 210 may be first coated on the exposed portion of the surface 120a of the luminescent epitaxial structure 120, the exposed portion of the metal mask layer 130, and the electrode material layer 141, and then the lining substrate 200 is pasted on the bonding layer 210. Above, as shown in FIG.
  • the bonding layer 210 may be first coated on the surface of the lining substrate 200, and then the bonding layer 210 is attached to the surface 120a of the luminescent epitaxial structure 120, metal. Cover The film layer 130 and the electrode material layer 141 complete the bonding of the lining substrate 200 and the luminescent epitaxial structure 120.
  • the growth substrate 100 is removed by, for example, chemical etching or grinding, the etch stop layer 110 is exposed, and the etch stop layer 152 is removed by chemical etching or grinding to expose the n-type ohmic contact layer 121, such as Figure 7 shows.
  • the bonding temperature of the bonding substrate 200 is controlled to be between 150 and 500 ° C (preferably below 30 ° C), and the material of the substrate 200 may be glass, silicon, gallium arsenide, etc.
  • the material of layer 210 may be lead-tin alloy, gold-bismuth alloy, gold-bismuth alloy, gold-tin alloy, tin, indium, palladium-indium alloy, benzocyclobutene, epoxy resin, silicon, polyimide or spin-coated glass.
  • a patterned ohmic contact and mirror structure is formed on the exposed surface of the light-emitting epitaxial structure.
  • the n-type ohmic contact layer 121 is patterned, and the surface of the n-type confinement layer 122 is exposed, and an n-type ohmic contact metal layer 150 is formed on the n-type ohmic contact layer 121 to improve the electrical quality of the device.
  • the material of the n-type ohmic contact metal layer 150 may be, for example, a ruthenium alloy/gold composite material, a gold/gold iridium alloy/gold composite material or a gold ruthenium alloy/nickel/gold composite material.
  • a transparent material layer 161 is formed on the exposed portion of the surface of the n-type confinement layer 122, the surface of which is flush with the surface of the n-type ohmic contact metal layer 150.
  • a reflective metal layer 162 is formed on the transparent material layer 161 and the n-type ohmic contact metal layer 150, as shown in FIG. Among them, the transparent material layer 161 and the reflective metal layer 162 constitute an omnidirectional reflection structure.
  • Step S140 providing a conductive substrate 180, bonding the conductive substrate 200 to the metal reflective structure by using the bonding layer 170.
  • the material bonding layer 122 of the bonding layer 170 is preferably a tin-lead alloy or a metal tantalum. Alloy, niobium alloy, gold tin alloy, tin, indium, palladium indium alloy or silicon.
  • the Liner substrate 200 and the bonding layer 210 may then be removed by etching to expose the surface 120a of the light emitting epitaxial structure 120, the metal mask layer 130, and the electrode material layer 141, as shown in FIG.
  • Step S150 chemically etching the exposed surface of the window layer 125 to form a roughened surface, as shown in FIG. Specifically, at least 10 g of I2 iodine powder is added to 1600 ml of CH3COOH, and then stirred, and then uniformly heated to 40 to 45 ° C; then, after the solution is kept stable, a mixture of HF, HN03 and C H3COOH is added. The volume ratio of each substance is 3: 2: 4, and the temperature is controlled to 35 to 40 ° C. Next, the above-mentioned light-emitting epitaxial structure is placed in a solvent which is disposed, and roughened for 1 to 2 minutes.
  • Step S160 After the roughening is completed, the exposed metal mask layer 130 is removed by etching, as shown in FIG. Preferably, the surface of the light-emitting epitaxial structure and the surface of the extension electrode 141b are covered with an insulating protective layer 190. Next, the pad electrode 142 is formed on the electrode material layer 141a above the pad electrode region 140a, and the fabrication of the light emitting diode is completed, as shown in FIG.
  • the mask layer is first fabricated before the substrate bonding process to reduce the influence of yellow light on the dislocation layer; secondly, the metal is used as a mask layer, and is not etched during the roughening process, The ohmic contact can be considered to solve the problem that the extended electrode is etched, and the risk of the metal contact being weak or falling off is avoided.
  • FIG. 14 is a flow chart showing the fabrication of a light emitting diode according to a second preferred embodiment of the present invention, which mainly includes steps S210 to S260.
  • the extension electrode 141 is formed in the extended electrode region 141b of the light-emitting epitaxial structure in step S220, and then the metal mask layer 130a is covered on the surface of the extension electrode 141. The details will be described below with reference to Figs. 15-24.
  • a growth substrate 100 is provided on which a light-emitting epitaxial structure 120 is formed, and then a pad electrode region 140a and an extended electrode region 140b are defined on a surface 120a of the light-emitting epitaxial structure 120, which is referred to the first implementation. Just fine.
  • the extension electrode 141 is first formed on the extension electrode region 140b of the light-emitting epitaxial structure surface 120a, and then the metal mask layer 130 is formed on the pad electrode region 140a and the extension electrode 141 of the light-emitting epitaxial structure surface 120a, wherein The metal mask layer 130a deposited on the pad electrode region 140a substantially coincides with the pad electrode region 130a, and the metal mask layer 130b deposited on the extension electrode 141 completely covers the extension electrode 141 and extends outward.
  • the metal mask layer 130b The area is larger than the area of the extension electrode 141b, as shown in Figs. 15 and 16, wherein Fig. 15 is a side cross-sectional view, and Fig. 16 is a plan view.
  • the material of the extension electrode 141 may be gold iridium alloy, gold zinc alloy or chrome gold alloy.
  • the metal mask layer 130 has a thickness of 50 to 100 nm, and the material thereof is selected from Cr.
  • the edge of the metal mask layer 130b on the extension electrode 141 is beyond the edge of the extension electrode 141, and the distance d exceeds at least 2 micrometers. The value is preferably 2 to 5 ⁇ m.
  • the width dl of the extension electrode 141b is 6 ⁇ m
  • the width of the metal mask layer 130b is 10 ⁇ m
  • the distance d of the edge of the metal mask layer 130b beyond the edge of the extension electrode 141 is 2 ⁇ m.
  • a pass-through substrate 200 is provided, and the pass-through substrate 200 is bonded to the light-emitting epitaxial structure 120 by the bonding layer 210. Then, as shown in FIG. 17, the growth substrate 100 on the light-emitting epitaxial structure 120 is removed, and exposed. The surface of the n-type ohmic contact layer 121 is formed as shown in FIG. Next, a patterned ohmic contact and mirror structure is formed on the exposed surface of the n-type ohmic contact layer 121, as shown in FIG. Next, a conductive substrate 180 is provided, and the conductive substrate 200 is bonded to the metal reflective structure by the bonding layer 170, as shown in FIG. Show.
  • the lining substrate 200 and the bonding layer 210 are removed by etching to expose the surface 120a of the luminescent epitaxial structure 120 and the metal mask layer 130, as shown in FIG.
  • the surface of the exposed window layer 125 is chemically etched to form a roughened surface as shown in FIG.
  • the metal mask layer 130 is removed by etching to expose the surface of the extension electrode 141 and the surface of the window layer of the pad electrode region 140a as shown in FIG.
  • an insulating protective layer 190 is overlaid on the surface of the light-emitting epitaxial structure and the surface of the extension electrode 141, and then a high-resistance current blocking layer 143 and a pad electrode 143 are sequentially formed over the pad electrode region 140a to complete the light-emitting diode.
  • the production as shown in Figure 24.
  • the pad electrode 142 is connected to the extension electrode 141, and when the current ⁇ is injected into the pad electrode 142, it flows to the window layer 125 through the extension electrode 141.
  • Cr is used as a mask layer for roughening.
  • Cr is not corroded by the rough etching solution, thereby ensuring that the underlying region is not edge-etched;
  • Cr is an inert metal, and will not Diffusion occurs and does not cause damage to other structures such as the extension electrode; it is also easy to remove by chemical etching.
  • 25 to 28 are partial process diagrams showing a method of fabricating an LED according to a third preferred embodiment of the present invention.
  • the metal mask layer 130 is formed only on the extended electrode region 140b in step S220, as shown in FIGS. 25 and 26; after the step S240 is completed, the epitaxial structure 120 is first performed.
  • a photoresist layer 220 is formed on the pad electrode region 140a of the surface 120a as a mask layer, as shown in FIGS. 27 and 28, and then subjected to a roughening process in step S250; in step S260, a different solution is used to remove the photoresist.
  • the layer 220 and the metal mask layer 130 are used to form pad electrodes in the pad electrode regions.
  • the top pad electrode and the pad electrode are designed as a loop, as shown in FIG. 3, so the pad electrode region in the first and second preferred embodiments.
  • the metal mask layer of the extended electrode region forms a series of closed loops, causing the charged particles in the roughening liquid to perform the movement of cutting the magnetic induction line during the roughening process, so that the charged particles of different electrical properties in the roughening liquid are in their respective The magnetic field is offset in a certain direction, thereby affecting the roughening effect.
  • the extended electrode and the metal mask layer are formed in the extended electrode region, and the photoresist layer is used as a mask layer in the pad electrode region, thereby avoiding the formation of a closed loop in the pad electrode region and the extended electrode region. Therefore, the charged particles in the roughening liquid are not directionalally moved by the action of the magnetic field, but are randomly and freely moved, thereby increasing the roughening ratio of the outgoing light to increase the LED light extraction rate.

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Abstract

A manufacturing method for a light-emitting diode, comprising the steps of: providing an epitaxial structure (120) sequentially comprising a growth substrate (100), a first type semiconductor layer (121 and 122), an active layer (123), and a second type semiconductor layer (124 and 125); defining a solder pad electrode area (140a) and an extended electrode area (140b) on the surface of the second type semiconductor layer, sequentially forming a metal mask layer (130b) and an extended electrode (141b) on the extended electrode area, the area of the metal mask layer completely covering the extended electrode area and extending outwards, and the area of the metal mask layer > the area of the extended electrode; providing a temporary substrate (200), joining same with the epitaxial structure, removing the growth substrate, and exposing the surface of the first type semiconductor layer; providing an electrically-conductive substrate (180), joining same with the epitaxial structure, removing the temporary substrate, and exposing a part of the surface of the second type semiconductor layer, a part of the metal mask layer, and the extended electrode; chemically etching the exposed surface of the second type semiconductor layer to form a roughened surface; and removing the exposed metal mask layer.

Description

发光二极管及其制作方法 技术领域  Light-emitting diode and manufacturing method thereof
[0001] 本发明涉及半导体制造领域, 具体的说是一种发光二极管及其制作方法。  [0001] The present invention relates to the field of semiconductor manufacturing, and more particularly to a light emitting diode and a method of fabricating the same.
背景技术  Background technique
[0002] 发光二极管具有低能耗, 高寿命, 稳定性好, 体积小, 响应速度快以及发光波 长稳定等良好光电特性, 被广泛应用于照明、 家电、 显示屏及指示灯等领域。 技术问题  [0002] Light-emitting diodes are widely used in lighting, home appliances, display screens, and indicator lights because of their low energy consumption, long life, good stability, small size, fast response, and stable luminous length. technical problem
[0003] 现有发光二极管之增光工艺, 常见地于器件出光表面制作粗化面以增进出光效 率。 在粗化蚀刻区域通常会避幵焊盘电极与扩展电极等区域, 以避免粗化面影 响电极与扩展条的平坦面。 一般常用工艺会使用光刻胶作为掩膜, 将光刻胶覆 盖在欲遮盖的地方, 通常位在电极与扩展条的位置, 并大于等于电极与扩展条 的区域面积, 接着再进行粗化工艺。 但在采用基板转移技术制作高亮度发光二 极管中, 由于经过键合工艺的晶圆片会有不同的曲翘模式, 键合前后的黄光对 位常有错位的问题, 使得扩展电极未受到良好的覆盖, 导致粗化液蚀刻到电极 扩展的下方, 形成金属接触脆弱或脱落的风险。  [0003] The light-increasing process of the existing light-emitting diodes generally produces a roughened surface on the light-emitting surface of the device to improve the light-emitting efficiency. The area of the pad electrode and the extension electrode is usually avoided in the roughened etching region to prevent the roughened surface from affecting the flat surface of the electrode and the extension strip. Generally, a common process uses a photoresist as a mask, and the photoresist is covered in a place to be covered, usually at the position of the electrode and the extension bar, and is larger than or equal to the area of the electrode and the extension strip, and then the roughening process is performed. . However, in the high-brightness light-emitting diodes fabricated by the substrate transfer technology, since the wafers subjected to the bonding process have different warp patterns, the yellow light alignment before and after the bonding often has a misalignment problem, so that the extended electrodes are not well received. The coverage causes the roughening solution to etch below the electrode extension, creating a risk of fragile or shedding of the metal contact.
问题的解决方案  Problem solution
技术解决方案  Technical solution
[0004] 针对上述问题, 本发明提供了一种降低粗化侧蚀之发光二级管与制作方法。  In view of the above problems, the present invention provides a light-emitting diode and a manufacturing method for reducing rough side etching.
[0005] 本发明的技术方案为: 发光二极管的制作方法, 包括步骤: (1) 提供一外延 结构, 依次包含生长衬底、 第一类型半导体层、 有源层和第二类型半导体层;[0005] The technical solution of the present invention is: a method for fabricating a light emitting diode, comprising the steps of: (1) providing an epitaxial structure, which in turn comprises a growth substrate, a first type semiconductor layer, an active layer and a second type semiconductor layer;
(2) 在所述第二类型半导体层的表面上定义焊盘电极区和扩展电极区, 并在所 述扩展电极区上依次形成金属掩膜层和扩展电极, 所述金属掩膜层的面积完全 覆盖所述扩展电极区并向外延伸, 所述金属掩膜层的面积〉扩展电极的面积;(2) defining a pad electrode region and an extension electrode region on a surface of the second type semiconductor layer, and sequentially forming a metal mask layer and an extension electrode on the extension electrode region, an area of the metal mask layer Fully covering the extended electrode region and extending outward, the area of the metal mask layer > the area of the extended electrode;
(3) 提供一临吋基板, 将其与所述外延结构接合, 并去除所述生长衬底, 裸露 出第一类型半导体层的表面; (4) 提供一导电基板, 将其与所述外延结构接合 (3) providing a temporary substrate, bonding the epitaxial structure, and removing the growth substrate to expose a surface of the first type semiconductor layer; ( 4) providing a conductive substrate, and the epitaxial Structural bonding
, 移除所述临吋基板, 裸露出部分第二类型半导体层的表面、 部分金属掩膜层 和扩展电极; (5) 采用化学蚀刻裸露出来的第二类型半导体层的表面, 形成粗 化表面; (6) 去除裸露出的金属掩膜层。 Removing the lining substrate to expose a portion of the surface of the second type semiconductor layer and a portion of the metal mask layer And an extension electrode; (5) using a chemically etched exposed surface of the second type of semiconductor layer to form a roughened surface; (6) removing the exposed metal mask layer.
[0006] 优选地, 所述步骤 (2) 中形成的金属掩膜层的厚度为 10~200nm, 更佳的为 50 ~100nm。 [0006] Preferably, the thickness of the metal mask layer formed in the step (2) is 10 to 200 nm, more preferably 50 to 100 nm.
[0007] 优选地, 所述步骤 (2) 中形成的金属掩膜层的边缘超出所述扩展电极的边缘 至少 2微米, 较佳的为 2~10微米。  [0007] Preferably, the edge of the metal mask layer formed in the step (2) is at least 2 micrometers, preferably 2 to 10 micrometers, beyond the edge of the extension electrode.
[0008] 优选地, 所述步骤 (2) 中同吋在所述焊盘电极区和扩展电极区形成金属掩膜 层。 [0008] Preferably, in the step (2), a metal mask layer is formed in the pad electrode region and the extended electrode region.
[0009] 优选地, 所述发光二极管的制作方法还包括步骤 (7) : 在所述第二类型半导 体层的焊盘电极区形成焊盘电极。  [0009] Preferably, the manufacturing method of the light emitting diode further comprises the step (7): forming a pad electrode in a pad electrode region of the second type semiconductor layer.
[0010] 优选地, 所述步骤 (2 中形成的金属掩膜层与所述第二类型半导体层形成欧 姆接触。  [0010] Preferably, the metal mask layer formed in the step (2) forms an ohmic contact with the second type semiconductor layer.
[0011] 优选地, 所述步骤 (2 中形成的金属掩膜层的材料选用 Au、 Cr、 Ni、 Ti或 Pd [0011] Preferably, the material of the metal mask layer formed in the step (2) is Au, Cr, Ni, Ti or Pd.
, 较佳选用 Au。 Preferably, Au is used.
[0012] 优选地, 所述步骤 (2 中同吋在所述焊盘电极区形成金属掩膜层和电极材料 层, 所述金属掩膜层与所述焊盘电极区重合, 所述电极材料层的材料与所述扩 展电极的材料一样。 [0012] Preferably, in the step (2), a metal mask layer and an electrode material layer are formed in the pad electrode region, and the metal mask layer is overlapped with the pad electrode region, and the electrode material is The material of the layer is the same as the material of the extension electrode.
[0013] 本发明的另一技术方案为: 发光二极管的制作方法, 包括步骤: (1) 提供一 外延结构, 依次包含生长衬底、 第一类型半导体层、 有源层和第二类型半导体 层; (2) 在所述第二类型半导体层的表面上定义焊盘电极区和扩展电极区, 并 在所述扩展电极区上依次形成扩展电极和金属掩膜层, 所述金属掩膜层的面积 完全覆盖所述扩展电极区并向外延伸, 所述金属掩膜层的面积〉扩展电极的面 积; (3) 提供一临吋基板, 将其与所述外延结构接合, 并去除所述生长衬底, 裸露出第一类型半导体层的表面; (4) 提供一导电基板, 将其与所述外延结构 接合, 移除所述临吋基板, 裸露出部分第二类型半导体层的表面和金属掩膜层 ; (5) 采用化学蚀刻裸露出来的第二类型半导体层的表面, 形成粗化表面; ( 6) 去除金属掩膜层。  [0013] Another technical solution of the present invention is: a method for fabricating a light emitting diode, comprising the steps of: (1) providing an epitaxial structure, comprising a growth substrate, a first type semiconductor layer, an active layer, and a second type semiconductor layer in this order; (2) defining a pad electrode region and an extension electrode region on a surface of the second type semiconductor layer, and sequentially forming an extension electrode and a metal mask layer on the extension electrode region, the metal mask layer The area completely covers the extended electrode region and extends outward, the area of the metal mask layer > the area of the extended electrode; (3) providing a temporary substrate, bonding it to the epitaxial structure, and removing the growth Substrate, exposing a surface of the first type of semiconductor layer; (4) providing a conductive substrate, bonding the epitaxial structure, removing the germanium substrate, exposing a portion of the surface and metal of the second type semiconductor layer a mask layer; (5) chemically etching the exposed surface of the second type of semiconductor layer to form a roughened surface; (6) removing the metal mask layer.
[0014] 优选地, 所述步骤 (2) 中形成的金属掩膜层的厚度为 10~200nm, 更佳的为 50 ~100nm。 [0014] Preferably, the thickness of the metal mask layer formed in the step (2) is 10 to 200 nm, and more preferably 50. ~100nm.
[0015] 优选地, 所述步骤 (2) 中形成的金属掩膜层的边缘超出所述扩展电极的边缘 至少 2微米, 较佳的为 2~10微米。  [0015] Preferably, the edge of the metal mask layer formed in the step (2) is at least 2 micrometers, preferably 2 to 10 micrometers, beyond the edge of the extension electrode.
[0016] 优选地, 所述步骤 (2) 中同吋在所述焊盘电极区和扩展电极区形成金属掩膜 层。 [0016] Preferably, in the step (2), a metal mask layer is formed on the pad electrode region and the extended electrode region.
[0017] 优选地, 所述发光二极管的制作方法还包括步骤 (7) : 在所述第二类型半导 体层的焊盘电极区形成焊盘电极。  [0017] Preferably, the method for fabricating the light emitting diode further comprises the step (7): forming a pad electrode in a pad electrode region of the second type semiconductor layer.
[0018] 优选地, 所述步骤 (2) 中形成的金属掩膜层与所述第二类型半导体层形成欧 姆接触。 [0018] Preferably, the metal mask layer formed in the step (2) forms an ohmic contact with the second type semiconductor layer.
[0019] 优选地, 所述步骤 (2) 中形成的金属掩膜层的材料选用 Au、 Cr、 Ni、 Ti或 Pd , 较佳选用 Cr。  [0019] Preferably, the material of the metal mask layer formed in the step (2) is selected from Au, Cr, Ni, Ti or Pd, and Cr is preferably used.
[0020] 在一些实施例中, 所述步骤 (2) 中先扩展电极区形成扩展电极, 然后在焊盘 电极区的第二类型半导体层表面上和所述扩展电极上形成金属掩膜层。  In some embodiments, in the step (2), the electrode region is first expanded to form an extension electrode, and then a metal mask layer is formed on the surface of the second type semiconductor layer of the pad electrode region and the extension electrode.
[0021] 在另一些实施例中, 所述步骤 (2) 中仅在扩展电极区形成金属掩膜层, 所述 焊盘电极区不形成金属掩膜层, 所述步骤 (5) 中先在所述焊盘电极区形成一光 阻层掩膜层, 再进行蚀刻, 所述步骤 (6) 中还包括去除光阻掩膜层。  [0021] In other embodiments, in the step (2), a metal mask layer is formed only in the extended electrode region, and the pad electrode region does not form a metal mask layer, and the step (5) is first The pad electrode region forms a photoresist layer mask and is etched, and the step (6) further includes removing the photoresist mask layer.
发明的有益效果  Advantageous effects of the invention
有益效果  Beneficial effect
[0022] 本发明所述发光二极管的制作方法, 在键合工艺前先制作金属掩膜, 延伸金属 区域, 将金属直接作为粗化掩膜层, 减少错位及粗化侧蚀问题, 提升发光二极 管的质量及良率。  [0022] The manufacturing method of the light-emitting diode of the present invention firstly forms a metal mask before the bonding process, extends the metal region, directly uses the metal as a rough mask layer, reduces misalignment and roughening side etching problems, and improves the light-emitting diode Quality and yield.
[0023] 根据本发明的另一个实施例, 提供了一种使用根据本发明的方法制造的发光二 极管结构。  [0023] According to another embodiment of the invention, a light emitting diode structure fabricated using the method according to the invention is provided.
[0024] 本发明的其它特征和优点将在随后的说明书中阐述, 并且, 部分地从说明书中 变得显而易见, 或者通过实施本发明而了解。 本发明的目的和其他优点可通过 在说明书、 权利要求书以及附图中所特别指出的结构来实现和获得。  [0024] Other features and advantages of the invention will be set forth in the description in the description which follows. The objectives and other advantages of the invention will be realized and attained by the <RTI
对附图的简要说明  Brief description of the drawing
附图说明 [0025] 附图用来提供对本发明的进一步理解, 并且构成说明书的一部分, 与本发明的 实施例一起用于解释本发明, 并不构成对本发明的限制。 此外, 附图数据是描 述概要, 不是按比例绘制。 DRAWINGS The drawings are intended to provide a further understanding of the invention, and are intended to be a part of the description of the invention. In addition, the drawing figures are a summary of the description and are not drawn to scale.
[0026] 图 1显示本发明实施例 1的一种发光二极管的制作流程图。 1 is a flow chart showing the fabrication of a light emitting diode according to Embodiment 1 of the present invention.
[0027] 图 2~13显示了本发明实施例 1的一种发光二极管的过程示意图。 2 to 13 are schematic views showing the process of a light emitting diode according to Embodiment 1 of the present invention.
[0028] 图 14显示本发明实施例 2的一种发光二极管的制作流程图。 14 is a flow chart showing the fabrication of a light emitting diode according to Embodiment 2 of the present invention.
[0029] 图 15~24显示本发明实施例 2的一种发光二极管的制作过程示意图。 15 to 24 are views showing a manufacturing process of a light emitting diode according to Embodiment 2 of the present invention.
[0030] 图 25~28显示本发明实施例 3的一种发光二极管的制作过程部分示意图。 25 to 28 are partial schematic views showing a manufacturing process of a light emitting diode according to Embodiment 3 of the present invention.
本发明的实施方式 Embodiments of the invention
[0031] 以下将结合附图及实施例来详细说明本发明的实施方式, 借此对本发明如何应 用技术手段来解决技术问题, 并达成技术效果的实现过程能充分理解并据以实 施。 需要说明的是, 只要不构成冲突, 本发明中的各个实施例以及各实施例中 的各个特征可以相互结合, 所形成的技术方案均在本发明的保护范围之内。  The embodiments of the present invention will be described in detail below with reference to the accompanying drawings and embodiments, in which the technical solutions of the present invention can be used to solve the technical problems, and the implementation of the technical effects can be fully understood and implemented. It should be noted that the various embodiments of the present invention and the various features of the various embodiments may be combined with each other as long as they do not constitute a conflict, and the technical solutions formed are all within the protection scope of the present invention.
[0032] 图 1显示了本发明第一个较佳实施例之一种发光二极管的制作流程图, 其主要 包括步骤 S110~S160, 下面以四元系发光二极管为例结合附图 2~13进行详细说明  1 is a flow chart of manufacturing a light emitting diode according to a first preferred embodiment of the present invention, which mainly includes steps S110 to S160, and quaternary light emitting diodes are taken as an example below with reference to FIGS. 2-13. Detailed description
[0033] 步骤 S110: 提供生长衬底 100, 在其上形成发光外延结构 120。 其中生长衬底 10 0较佳可采用 III- V族化合物半导体材料, 例如砷化镓、 磷化铟 (InP)、 磷化镓或蓝 宝石, 发光外延结构为常规外延结构即可, 一般可包含 n型半导体层、 有源层和 p型半导体层。 具体的, 首先提供成长基板 100, 再利用例如沉积方式直接在生 长基板 100的表面上成长蚀刻终止层 110。 接下来, 形成 n型欧姆接触层 121于蚀 刻终止层 101上, 其中 n型欧姆接触层 121的材料例如可为砷化镓、 磷化镓砷或 磷化铝镓铟。 接着, 在 n型欧姆接触层 121上生长发光外延结构 120, 较佳的, 发 光外延结构 120可以包括依序堆栈在 n型欧姆接触层 121的表面上的 n型限制层 122 、 有源层 123、 p型限制层 124以及窗口层 125, 如图 2所示。 其中, N型限制层 122 的材料例如可为砷化铝镓 Al xGa xAs, x>0.4或磷化铝镓铟(Al xGa ,_x) yIn ,_y P, x>0.4; p型限制层 124的材料例如可为砷化铝镓 (Al xGa ixAs, x>0.4)或磷化 铝镓铟(Al xGa i_J yIn i_yP, x>0.4, 有源层 123的材料例如可为磷化铝镓铟 ((Al x Ga l x) yIn l yP, x<0.5) , 窗口层 125的材料例如可为磷化镓、 磷化镓砷、 砷化铝 镓或磷化铝镓铟。 [0033] Step S110: Providing a growth substrate 100 on which the light-emitting epitaxial structure 120 is formed. The growth substrate 100 is preferably made of a III-V compound semiconductor material, such as gallium arsenide, indium phosphide (InP), gallium phosphide or sapphire. The luminescent epitaxial structure may be a conventional epitaxial structure, and may generally include n. A semiconductor layer, an active layer, and a p-type semiconductor layer. Specifically, first, the growth substrate 100 is provided, and the etch stop layer 110 is grown directly on the surface of the growth substrate 100 by, for example, deposition. Next, an n-type ohmic contact layer 121 is formed on the etch stop layer 101, wherein the material of the n-type ohmic contact layer 121 may be, for example, gallium arsenide, gallium arsenide or aluminum gallium phosphide. Next, the light-emitting epitaxial structure 120 is grown on the n-type ohmic contact layer 121. Preferably, the light-emitting epitaxial structure 120 may include an n-type confinement layer 122 and an active layer 123 stacked on the surface of the n-type ohmic contact layer 121 in sequence. The p-type confinement layer 124 and the window layer 125 are as shown in FIG. The material of the N-type confinement layer 122 may be, for example, aluminum gallium arsenide Al x Ga x As, x>0.4 or aluminum gallium indium phosphide (Al x Ga , _ x ) y In , _ y P, x>0.4; The material of the p-type confinement layer 124 may be, for example, aluminum gallium arsenide (Al x G aix As, x>0.4) or phosphating. Aluminum gallium indium (Al x G ai _J y I ni _ y P, x>0.4, the material of the active layer 123 may be, for example, aluminum gallium indium phosphide ((Al x Ga lx ) y In ly P, x < 0.5) The material of the window layer 125 can be, for example, gallium phosphide, gallium arsenide, aluminum gallium arsenide or aluminum gallium phosphide.
[0034] 步骤 S120: 在发光外延结构的表面 120a上定义电极区 140, 包括焊盘电极区 140 a和扩展电极区 140b, 如图 3所示。 接着, 在电极区 140上依次形成金属掩膜层 130 和电极材料层 141, 其中焊盘电极区 140a上沉积的金属掩膜层 130a、 电极材料层 1 41a基本与焊盘电极区 130a重合, 扩展电极区 140b上沉积的金属掩膜层 130b完全 覆盖扩展电极区 140b并向外延伸, 金属掩膜层 130b上的电极材料层 141b作为扩 展电极, 与扩展电极区 140b重合, 即金属掩膜层 130b的面积大于扩展电极 141b 的面积, 如图 4和 5所示, 其中图 4为侧面剖视图, 图 5为俯视图。 其中, 电极材 料层 140可选用的材料可为金铍合金、 金锌合金或铬金合金。 金属掩膜层 130需 考虑以下因素: (1) 能够在后续粗化流程中作为掩膜层保护扩电极 141b, 避免 扩展电极 141b下方被侧蚀, 因此要求金属掩膜层 130b的边缘超出扩展电极 141的 边缘, 其超出的距离 d至少达到 2微米以上为宜, 较佳值为 2~5微米, 例如扩展电 极 141b的宽度 dl为 6微米, 金属掩膜层 130b的宽度为 10微米, 金属掩膜层 130b的 边缘超出扩展电极 141的边缘的距离 d为 2微米; (2) 在完成粗制程后需将非电 极区的金属掩膜层去除, 因此金属掩膜层的厚度不宜太厚, 并选用较易去除的 材料, 例如可选用 Au等, 厚度可取 10~200nm, 较佳为 50~100nm; (3) 由于金 属掩膜层 130位于外延层 125与电极材料层 141之间, 需确保金属掩膜层 130与发 光外延结构 120形成欧姆接触, 因此需选用能与外延材料层形成欧姆接触的材料 。 在本实施例中金属掩膜层 130选用 Au, 其既可与外延层形成良好的欧姆接触, 又容易采用化学蚀刻液去除。  [0034] Step S120: defining an electrode region 140 on the surface 120a of the light-emitting epitaxial structure, including a pad electrode region 140a and an extended electrode region 140b, as shown in FIG. Next, a metal mask layer 130 and an electrode material layer 141 are sequentially formed on the electrode region 140, wherein the metal mask layer 130a and the electrode material layer 141a deposited on the pad electrode region 140a substantially coincide with the pad electrode region 130a, and expand. The metal mask layer 130b deposited on the electrode region 140b completely covers the extended electrode region 140b and extends outward. The electrode material layer 141b on the metal mask layer 130b serves as an extension electrode and overlaps the extended electrode region 140b, that is, the metal mask layer 130b. The area is larger than the area of the extension electrode 141b, as shown in Figs. 4 and 5, wherein Fig. 4 is a side cross-sectional view, and Fig. 5 is a plan view. The material of the electrode material layer 140 may be a metal ruthenium alloy, a gold zinc alloy or a chrome gold alloy. The metal mask layer 130 needs to consider the following factors: (1) The spread electrode 141b can be protected as a mask layer in the subsequent roughening process, and the underside of the extended electrode 141b is prevented from being undercut, so that the edge of the metal mask layer 130b is required to extend beyond the extended electrode Preferably, the edge 141 has an excess distance d of at least 2 micrometers, preferably 2 to 5 micrometers. For example, the width dl of the extension electrode 141b is 6 micrometers, and the width of the metal mask layer 130b is 10 micrometers. The distance d between the edge of the film layer 130b and the edge of the extension electrode 141 is 2 μm; (2) the metal mask layer of the non-electrode region is removed after the rough process is completed, so the thickness of the metal mask layer is not too thick, and The material which is relatively easy to remove, for example, Au or the like, may be used, and the thickness may be 10 to 200 nm, preferably 50 to 100 nm. (3) Since the metal mask layer 130 is located between the epitaxial layer 125 and the electrode material layer 141, it is necessary to ensure metal. The mask layer 130 forms an ohmic contact with the epitaxial structure 120, so a material that can form an ohmic contact with the epitaxial material layer is used. In the present embodiment, the metal mask layer 130 is made of Au, which can form a good ohmic contact with the epitaxial layer and is easily removed by a chemical etching solution.
[0035] 步骤 S130: 提供一临吋基板 200, 利用接合层 210将临吋基板 200与发光外延结 构 120接合, 接着去除发光外延结构 120上的生长衬底 100, 露出发 n型半导体层 的表面。 具体的, 可先将接合层 210涂布在发光外延结构 120的表面 120a的暴露 部分、 金属掩膜层 130的暴露部分和电极材料层 141上, 再将临吋基板 200贴设在 接合层 210上, 如图 6所示; 在另一个实施例中, 也可先将接合层 210涂布在临吋 基板 200的表面上, 再将接合层 210贴合在发光外延结构 120的表面 120a、 金属掩 膜层 130和电极材料层 141, 完成临吋基板 200与发光外延结构 120的接合。 接着 , 利用例如化学蚀刻法或研磨法移除生长衬底 100, 暴露出蚀刻终止层 110, 再 利用化学蚀刻法或研磨法移除蚀刻终止层 152, 以暴露出 n型欧姆接触层 121, 如 图 7所示。 其中, 贴合临吋基板 200的贴合温度控制在 150~500°C之间 (较佳为 30 0°C以下) , 临吋基板 200的材料可为玻璃、 硅、 砷化镓等, 接合层 210的材料可 为铅锡合金、 金锗合金、 金铍合金、 金锡合金、 锡、 铟、 钯铟合金、 苯并环丁 烯、 环氧树脂、 硅、 聚亚酰胺或旋转涂布玻璃高分子, 其中较佳采用苯并环丁 烯或环氧树脂。 [0035] Step S130: providing a pass-through substrate 200, bonding the Linyi substrate 200 to the light-emitting epitaxial structure 120 by using the bonding layer 210, and then removing the growth substrate 100 on the light-emitting epitaxial structure 120 to expose the surface of the n-type semiconductor layer. . Specifically, the bonding layer 210 may be first coated on the exposed portion of the surface 120a of the luminescent epitaxial structure 120, the exposed portion of the metal mask layer 130, and the electrode material layer 141, and then the lining substrate 200 is pasted on the bonding layer 210. Above, as shown in FIG. 6; in another embodiment, the bonding layer 210 may be first coated on the surface of the lining substrate 200, and then the bonding layer 210 is attached to the surface 120a of the luminescent epitaxial structure 120, metal. Cover The film layer 130 and the electrode material layer 141 complete the bonding of the lining substrate 200 and the luminescent epitaxial structure 120. Next, the growth substrate 100 is removed by, for example, chemical etching or grinding, the etch stop layer 110 is exposed, and the etch stop layer 152 is removed by chemical etching or grinding to expose the n-type ohmic contact layer 121, such as Figure 7 shows. Wherein, the bonding temperature of the bonding substrate 200 is controlled to be between 150 and 500 ° C (preferably below 30 ° C), and the material of the substrate 200 may be glass, silicon, gallium arsenide, etc. The material of layer 210 may be lead-tin alloy, gold-bismuth alloy, gold-bismuth alloy, gold-tin alloy, tin, indium, palladium-indium alloy, benzocyclobutene, epoxy resin, silicon, polyimide or spin-coated glass. A polymer, preferably a benzocyclobutene or an epoxy resin.
[0036] 较佳的, 在裸露出上的发光外延结构的表面上制作图案化的欧姆接触及反射镜 结构。 具体的, 图案化 n型欧姆接触层 121, 并暴露 n型限制层 122的表面, 再形 成 n型欧姆接触金属层 150在 n型欧姆接触层 121上, 以改善组件的电性质量。 其 中, n型欧姆接触金属层 150的材料例如可为金锗合金 /金复合材料、 金 /金锗合 金 /金复合材料或金锗合金 /镍 /金复合材料。 接着, 在 n型限制层 122的表面的暴 露部分上形成透明材料层 161, 其表面与 n型欧姆接触金属层 150的表面齐平。 接 下来, 在透明材料层 161和 n型欧姆接触金属层 150上形成反射金属层 162, 如图 8 所示。 其中, 透明材料层 161和反射金属层 162构成全方位反射结构。  [0036] Preferably, a patterned ohmic contact and mirror structure is formed on the exposed surface of the light-emitting epitaxial structure. Specifically, the n-type ohmic contact layer 121 is patterned, and the surface of the n-type confinement layer 122 is exposed, and an n-type ohmic contact metal layer 150 is formed on the n-type ohmic contact layer 121 to improve the electrical quality of the device. The material of the n-type ohmic contact metal layer 150 may be, for example, a ruthenium alloy/gold composite material, a gold/gold iridium alloy/gold composite material or a gold ruthenium alloy/nickel/gold composite material. Next, a transparent material layer 161 is formed on the exposed portion of the surface of the n-type confinement layer 122, the surface of which is flush with the surface of the n-type ohmic contact metal layer 150. Next, a reflective metal layer 162 is formed on the transparent material layer 161 and the n-type ohmic contact metal layer 150, as shown in FIG. Among them, the transparent material layer 161 and the reflective metal layer 162 constitute an omnidirectional reflection structure.
[0037] 步骤 S140: 提供一个导电基板 180, 利用接合层 170将导电基板 200与金属反射 结构接合, 如图 9所示, 接合层 170的材料接合层 122较佳可为铅锡合金、 金锗合 金、 金铍合金、 金锡合金、 锡、 铟、 钯铟合金或硅。 接着可利用蚀刻方式移除 临吋基板 200与接合层 210, 而暴露出发光外延结构 120的表面 120a、 金属掩膜层 1 30和电极材料层 141, 如图 10所示。  [0037] Step S140: providing a conductive substrate 180, bonding the conductive substrate 200 to the metal reflective structure by using the bonding layer 170. As shown in FIG. 9, the material bonding layer 122 of the bonding layer 170 is preferably a tin-lead alloy or a metal tantalum. Alloy, niobium alloy, gold tin alloy, tin, indium, palladium indium alloy or silicon. The Liner substrate 200 and the bonding layer 210 may then be removed by etching to expose the surface 120a of the light emitting epitaxial structure 120, the metal mask layer 130, and the electrode material layer 141, as shown in FIG.
[0038] 步骤 S150: 采用化学蚀刻裸露出来的窗口层 125的表面, 形成粗化表面, 如图 1 1所示。 具体为: 将至少 10g I2碘粉加入到 1600ml CH3COOH中, 然后进行搅拌 , 待均匀后加热至 40〜45°C; 接着待前述溶液持温稳定后, 加入 HF、 HN03和 C H3COOH的混合液, 其中各物质的体积比 3: 2: 4, 控温至 35〜40°C; 接下来将 前述发光外延结构放入配置完成的溶剂中, 粗化吋间 l〜2min。  [0038] Step S150: chemically etching the exposed surface of the window layer 125 to form a roughened surface, as shown in FIG. Specifically, at least 10 g of I2 iodine powder is added to 1600 ml of CH3COOH, and then stirred, and then uniformly heated to 40 to 45 ° C; then, after the solution is kept stable, a mixture of HF, HN03 and C H3COOH is added. The volume ratio of each substance is 3: 2: 4, and the temperature is controlled to 35 to 40 ° C. Next, the above-mentioned light-emitting epitaxial structure is placed in a solvent which is disposed, and roughened for 1 to 2 minutes.
[0039] 步骤 S160: 粗化完成后, 采用蚀刻去除裸露出的金属掩膜层 130, 如图 12所示 。 较佳地, 在发光外延结构的表面及扩展电极 141b的表面上覆盖绝缘保护层 190 , 接着在焊盘电极区 140a上方的电极材料层 141a上形成焊盘电极 142, 完成发光 二极管的制作, 如图 13所示。 [0039] Step S160: After the roughening is completed, the exposed metal mask layer 130 is removed by etching, as shown in FIG. Preferably, the surface of the light-emitting epitaxial structure and the surface of the extension electrode 141b are covered with an insulating protective layer 190. Next, the pad electrode 142 is formed on the electrode material layer 141a above the pad electrode region 140a, and the fabrication of the light emitting diode is completed, as shown in FIG.
[0040] 在本实施例中, 首先将掩膜层制作提前至基板接合工艺前, 减少黄光对位错位 影响; 其次采用金属作为掩膜层, 在粗化过程中不会被蚀刻, 同吋可兼顾欧姆 接触, 解决扩展电极被蚀的问题, 避免了金属接触脆弱或脱落的风险。  [0040] In this embodiment, the mask layer is first fabricated before the substrate bonding process to reduce the influence of yellow light on the dislocation layer; secondly, the metal is used as a mask layer, and is not etched during the roughening process, The ohmic contact can be considered to solve the problem that the extended electrode is etched, and the risk of the metal contact being weak or falling off is avoided.
[0041] 图 14显示了本发明第二个较佳实施例之一种发光二极管的制作流程图, 其主要 包括步骤 S210~S260。 区别于第一个较佳实施例, 在本实施例中, 在步骤 S220中 在发光外延结构的扩展电极区 141b先形成扩展电极 141, 接着在扩展电极 141的 表面上覆盖金属掩膜层 130a, 下面结合附图 15-24进行详细说明。  14 is a flow chart showing the fabrication of a light emitting diode according to a second preferred embodiment of the present invention, which mainly includes steps S210 to S260. Different from the first preferred embodiment, in the embodiment, the extension electrode 141 is formed in the extended electrode region 141b of the light-emitting epitaxial structure in step S220, and then the metal mask layer 130a is covered on the surface of the extension electrode 141. The details will be described below with reference to Figs. 15-24.
[0042] 首先, 提供生长衬底 100, 在其上形成发光外延结构 120, 接着, 在发光外延结 构 120的表面 120a上定义焊盘电极区 140a和扩展电极区 140b, 此部分参照第一个 实施例即可。  [0042] First, a growth substrate 100 is provided on which a light-emitting epitaxial structure 120 is formed, and then a pad electrode region 140a and an extended electrode region 140b are defined on a surface 120a of the light-emitting epitaxial structure 120, which is referred to the first implementation. Just fine.
[0043] 接下来, 先在发光外延结构表面 120a的扩展电极区 140b上形成扩展电极 141, 然后在发光外延结构表面 120a的焊盘电极区 140a和扩展电极 141上形成金属掩膜 层 130, 其中焊盘电极区 140a上沉积的金属掩膜层 130a、 基本与焊盘电极区 130a 重合, 扩展电极 141上沉积的金属掩膜层 130b完全包覆扩展电极 141并向外延伸 , 金属掩膜层 130b的面积大于扩展电极 141b的面积, 如图 15和 16所示, 其中图 1 5为侧面剖视图, 图 16为俯视图。 其中, 扩展电极 141可选用的材料可为金铍合 金、 金锌合金或铬金合金。 金属掩膜层 130的厚度为 50~100nm, 其材料选用 Cr, 扩展电极 141上的金属掩膜层 130b的边缘超出扩展电极 141的边缘, 其超出的距 离 d至少达到 2微米以上为宜, 较佳值为 2~5微米, 例如扩展电极 141b的宽度 dl为 6微米, 金属掩膜层 130b的宽度为 10微米, 金属掩膜层 130b的边缘超出扩展电极 141的边缘的距离 d为 2微米。  [0043] Next, the extension electrode 141 is first formed on the extension electrode region 140b of the light-emitting epitaxial structure surface 120a, and then the metal mask layer 130 is formed on the pad electrode region 140a and the extension electrode 141 of the light-emitting epitaxial structure surface 120a, wherein The metal mask layer 130a deposited on the pad electrode region 140a substantially coincides with the pad electrode region 130a, and the metal mask layer 130b deposited on the extension electrode 141 completely covers the extension electrode 141 and extends outward. The metal mask layer 130b The area is larger than the area of the extension electrode 141b, as shown in Figs. 15 and 16, wherein Fig. 15 is a side cross-sectional view, and Fig. 16 is a plan view. The material of the extension electrode 141 may be gold iridium alloy, gold zinc alloy or chrome gold alloy. The metal mask layer 130 has a thickness of 50 to 100 nm, and the material thereof is selected from Cr. The edge of the metal mask layer 130b on the extension electrode 141 is beyond the edge of the extension electrode 141, and the distance d exceeds at least 2 micrometers. The value is preferably 2 to 5 μm. For example, the width dl of the extension electrode 141b is 6 μm, the width of the metal mask layer 130b is 10 μm, and the distance d of the edge of the metal mask layer 130b beyond the edge of the extension electrode 141 is 2 μm.
[0044] 接下来, 提供一临吋基板 200, 利用接合层 210将临吋基板 200与发光外延结构 1 20接合, 如图 17所示, 接着去除发光外延结构 120上的生长衬底 100, 露出发 n型 欧姆接触层 121的表面, 如图 18所示。 接下来, 在裸露出上的 n型欧姆接触层 121 的表面上制作图案化的欧姆接触及反射镜结构, 如图 19所示。 接下来, 提供一 个导电基板 180, 利用接合层 170将导电基板 200与金属反射结构接合, 如图 20所 示。 接下来, 利用蚀刻方式移除临吋基板 200与接合层 210, 暴露出发光外延结 构 120的表面 120a、 金属掩膜层 130, 如图 21所示。 接下来, 采用化学蚀刻裸露出 来的窗口层 125的表面, 形成粗化表面, 如图 22所示。 接下来, 采用蚀刻去除金 属掩膜层 130, 裸露出扩展电极 141的表面及焊盘电极区 140a的窗口层的表面, 如 图 23所示。 接下来, 在发光外延结构的表面及扩展电极 141的表面上覆盖绝缘保 护层 190, 接着在焊盘电极区 140a上方的依次形成高阻值的电流阻挡层 143和焊盘 电极 143, 完成发光二极管的制作, 如图 24所示。 其中焊盘电极 142与扩展电极 1 41连接, 当向焊盘电极 142注放电流吋, 通过扩展电极 141流向窗口层 125。 [0044] Next, a pass-through substrate 200 is provided, and the pass-through substrate 200 is bonded to the light-emitting epitaxial structure 120 by the bonding layer 210. Then, as shown in FIG. 17, the growth substrate 100 on the light-emitting epitaxial structure 120 is removed, and exposed. The surface of the n-type ohmic contact layer 121 is formed as shown in FIG. Next, a patterned ohmic contact and mirror structure is formed on the exposed surface of the n-type ohmic contact layer 121, as shown in FIG. Next, a conductive substrate 180 is provided, and the conductive substrate 200 is bonded to the metal reflective structure by the bonding layer 170, as shown in FIG. Show. Next, the lining substrate 200 and the bonding layer 210 are removed by etching to expose the surface 120a of the luminescent epitaxial structure 120 and the metal mask layer 130, as shown in FIG. Next, the surface of the exposed window layer 125 is chemically etched to form a roughened surface as shown in FIG. Next, the metal mask layer 130 is removed by etching to expose the surface of the extension electrode 141 and the surface of the window layer of the pad electrode region 140a as shown in FIG. Next, an insulating protective layer 190 is overlaid on the surface of the light-emitting epitaxial structure and the surface of the extension electrode 141, and then a high-resistance current blocking layer 143 and a pad electrode 143 are sequentially formed over the pad electrode region 140a to complete the light-emitting diode. The production, as shown in Figure 24. The pad electrode 142 is connected to the extension electrode 141, and when the current 注 is injected into the pad electrode 142, it flows to the window layer 125 through the extension electrode 141.
[0045] 在本实施例中, 采用 Cr作为粗化的掩膜层, 首先 Cr不会被粗化蚀刻液腐蚀, 保 证了其下方的区域不会被侧蚀; 其次 Cr为惰性金属, 不会发生扩散, 且不会对 扩展电极等其他结构产生破坏; 再者容易采用化学蚀刻去除。  [0045] In this embodiment, Cr is used as a mask layer for roughening. First, Cr is not corroded by the rough etching solution, thereby ensuring that the underlying region is not edge-etched; secondly, Cr is an inert metal, and will not Diffusion occurs and does not cause damage to other structures such as the extension electrode; it is also easy to remove by chemical etching.
[0046] 图 25~28显示了本发明第三个较佳实施例之一种发光二极管制作方法的部分过 程示意图。 作为第二个较佳实施例的一个变形, 在步骤 S220中仅在扩展电极区 1 40b上形成金属掩膜层 130, 如图 25和 26所示; 在完成 S240步骤后, 先在外延结 构 120的表面 120a的焊盘电极区 140a上形成一光阻层 220作为掩膜层, 如图 27和 28 所示, 再进行 S250步骤作粗化处理; 在 S260步骤中分别采用不同的溶液去除光 阻层 220和金属掩膜层 130, 再在焊盘电极区制作焊盘电极。  25 to 28 are partial process diagrams showing a method of fabricating an LED according to a third preferred embodiment of the present invention. As a modification of the second preferred embodiment, the metal mask layer 130 is formed only on the extended electrode region 140b in step S220, as shown in FIGS. 25 and 26; after the step S240 is completed, the epitaxial structure 120 is first performed. A photoresist layer 220 is formed on the pad electrode region 140a of the surface 120a as a mask layer, as shown in FIGS. 27 and 28, and then subjected to a roughening process in step S250; in step S260, a different solution is used to remove the photoresist. The layer 220 and the metal mask layer 130 are used to form pad electrodes in the pad electrode regions.
[0047] 通常较大功率垂直发光二极管芯片中, 一般顶面的焊盘电极与焊盘电极会设计 成回路, 如图 3所示, 因此第一、 第二较佳实施例中焊盘电极区和扩展电极区的 金属掩膜层会形成一系列闭合回路, 造成粗化过程中粗化液中的带电粒子做切 割磁感线的运动, 使得粗化液中不同电性的带电粒子在各自的磁场内按一定方 向发生偏移, 从而影响粗化效果。 为避免前述问题, 本实施例中仅在扩展电极 区形成扩展电极和金属掩膜层, 焊盘电极区采用光阻做了掩膜层, 从而避免了 焊盘电极区和扩展电极区形成闭合回路, 使得粗化液中的带电粒子不会因为磁 场作用做定向运动, 而是随机自由运动, 从而提高出面光的粗化比以提升 LED光 取出率。  [0047] Generally, in a large power vertical LED chip, generally the top pad electrode and the pad electrode are designed as a loop, as shown in FIG. 3, so the pad electrode region in the first and second preferred embodiments. And the metal mask layer of the extended electrode region forms a series of closed loops, causing the charged particles in the roughening liquid to perform the movement of cutting the magnetic induction line during the roughening process, so that the charged particles of different electrical properties in the roughening liquid are in their respective The magnetic field is offset in a certain direction, thereby affecting the roughening effect. In order to avoid the foregoing problem, in the embodiment, only the extended electrode and the metal mask layer are formed in the extended electrode region, and the photoresist layer is used as a mask layer in the pad electrode region, thereby avoiding the formation of a closed loop in the pad electrode region and the extended electrode region. Therefore, the charged particles in the roughening liquid are not directionalally moved by the action of the magnetic field, but are randomly and freely moved, thereby increasing the roughening ratio of the outgoing light to increase the LED light extraction rate.
[0048] 很明显地, 本发明的说明不应理解为仅仅限制在上述实施例, 而是包括利用本 发明构思的所有可能的实施方式。  [0048] It is to be understood that the description of the present invention should not be construed as being limited to the above-described embodiments, but rather, including all possible embodiments of the inventive concept.

Claims

权利要求书 [权利要求 1] 发光二极管的制作方法, 包括步骤: (1) 提供一外延结构, 依次包含生长衬底、 第一类型半导体层、 有 源层和第二类型半导体层; (2) 在所述第二类型半导体层的表面上定义焊盘电极区和扩展电极 区, 并在所述扩展电极区上依次形成金属掩膜层和扩展电极, 所述金 属掩膜层的面积完全覆盖所述扩展电极区并向外延伸, 所述金属掩膜 层的面积〉扩展电极的面积; (3) 提供一临吋基板, 将其与所述外延结构接合, 并去除所述生长 衬底, 裸露出第一类型半导体层的表面; (4) 提供一导电基板, 将其与所述外延结构接合, 移除所述临吋基 板, 裸露出部分第二类型半导体层的表面、 部分金属掩膜层和扩展电 极; (5) 采用化学蚀刻裸露出来的第二类型半导体层的表面, 形成粗化 表面; (6) 去除裸露出的金属掩膜层。 [权利要求 2] 发光二极管的制作方法, 包括步骤: The invention provides a method for fabricating a light emitting diode, comprising the steps of: (1) providing an epitaxial structure comprising a growth substrate, a first type semiconductor layer, an active layer and a second type semiconductor layer in sequence; (2) Determining a pad electrode region and an extension electrode region on a surface of the second type semiconductor layer, and sequentially forming a metal mask layer and an extension electrode on the extension electrode region, the area of the metal mask layer completely covering the area Extending the electrode region and extending outward, the area of the metal mask layer > the area of the extension electrode; (3) providing a temporary substrate, bonding the epitaxial structure, and removing the growth substrate, exposed Forming a surface of the first type of semiconductor layer; (4) providing a conductive substrate, bonding the epitaxial structure, removing the lining substrate, exposing a portion of the surface of the second type semiconductor layer, and partially depositing a metal mask layer And an extension electrode; (5) using a chemically etched exposed surface of the second type of semiconductor layer to form a roughened surface; (6) removing the exposed metal mask layer. [Claim 2] A method for fabricating a light emitting diode, comprising the steps of:
(1) 提供一外延结构, 依次包含生长衬底、 第一类型半导体层、 有 源层和第二类型半导体层;  (1) providing an epitaxial structure comprising, in order, a growth substrate, a first type semiconductor layer, an active layer, and a second type semiconductor layer;
(2) 在所述第二类型半导体层的表面上定义焊盘电极区和扩展电极 区, 并在所述扩展电极区上依次形成扩展电极和金属掩膜层, 所述金 属掩膜层的面积完全覆盖所述扩展电极区并向外延伸, 所述金属掩膜 层的面积〉扩展电极的面积;  (2) defining a pad electrode region and an extension electrode region on a surface of the second type semiconductor layer, and sequentially forming an extension electrode and a metal mask layer on the extension electrode region, an area of the metal mask layer Fully covering the extended electrode region and extending outward, the area of the metal mask layer > the area of the extended electrode;
(3) 提供一临吋基板, 将其与所述外延结构接合, 并去除所述生长 衬底, 裸露出第一类型半导体层的表面;  (3) providing a temporary substrate, bonding the epitaxial structure, and removing the growth substrate to expose a surface of the first type semiconductor layer;
(4) 提供一导电基板, 将其与所述外延结构接合, 移除所述临吋基 板, 裸露出部分第二类型半导体层的表面和金属掩膜层;  (4) providing a conductive substrate, bonding the epitaxial structure, removing the lining substrate, exposing a portion of the surface of the second type semiconductor layer and the metal mask layer;
(5) 采用化学蚀刻裸露出来的第二类型半导体层的表面, 形成粗化 表面; (5) Forming the surface of the second type semiconductor layer exposed by chemical etching to form a roughening Surface
(6) 去除金属掩膜层。  (6) Remove the metal mask layer.
[权利要求 3] 根据权利要求 1或 2所述的发光二极管的制作方法, 其特征在于: 所述 步骤 (2) 中形成的金属掩膜层的厚度为 10~200nm。  [Claim 3] The method for fabricating a light emitting diode according to claim 1 or 2, wherein the metal mask layer formed in the step (2) has a thickness of 10 to 200 nm.
[权利要求 4] 根据权利要求 1或 2所述的发光二极管的制作方法, 其特征在于: 所述 步骤 (2) 中, 形成的金属掩膜层的边缘超出所述扩展电极的边缘至 少 2微米。  [Claim 4] The method for fabricating a light emitting diode according to claim 1 or 2, wherein in the step (2), the edge of the formed metal mask layer is at least 2 micrometers beyond the edge of the extension electrode. .
[权利要求 5] 根据权利要求 1或 2所述的发光二极管的制作方法, 其特征在于: 还包 括步骤 (7) : 在所述第二类型半导体层的焊盘电极区形成焊盘电极  [Claim 5] The method of fabricating a light emitting diode according to claim 1 or 2, further comprising the step (7): forming a pad electrode in a pad electrode region of the second type semiconductor layer
[权利要求 6] 根据权利要求 1或 2所述的发光二极管的制作方法, 其特征在于: 所述 步骤 (2) 中形成的金属掩膜层的材料选用 Au、 Cr、 Ni、 Ti或 Pd。 [Claim 6] The method for fabricating a light emitting diode according to claim 1 or 2, wherein the material of the metal mask layer formed in the step (2) is Au, Cr, Ni, Ti or Pd.
[权利要求 7] 根据权利要求 1所述的发光二极管的制作方法, 其特征在于: 所述步 骤 (2) 中同吋在所述焊盘电极区形成金属掩膜层和电极材料层, 所 述金属掩膜层与所述焊盘电极区重合, 所述电极材料层的材料与所述 扩展电极的材料一样。  [Claim 7] The method for fabricating a light emitting diode according to claim 1, wherein: in the step (2), a metal mask layer and an electrode material layer are formed in the pad electrode region, A metal mask layer is overlapped with the pad electrode region, and the material of the electrode material layer is the same as the material of the extension electrode.
[权利要求 8] 根据权利要求 2所述的发光二极管的制作方法, 其特征在于: 所述步 骤 (2) 中先扩展电极区形成扩展电极, 然后在焊盘电极区的第二类 型半导体层表面上和所述扩展电极上形成金属掩膜层。  [Claim 8] The manufacturing method of the light emitting diode according to claim 2, wherein: in the step (2), the electrode region is first extended to form an extension electrode, and then the surface of the second type semiconductor layer in the pad electrode region is formed. A metal mask layer is formed on the upper and the extension electrodes.
[权利要求 9] 根据权利要求 2所述的发光二极管的制作方法, 其特征在于: 所述步 骤 (2) 中仅在扩展电极区形成金属掩膜层, 所述焊盘电极区不形成 金属掩膜层, 所述步骤 (5) 中先在所述焊盘电极区形成一光阻层掩 膜层, 再进行蚀刻, 所述步骤 (6) 中还包括去除光阻掩膜层。  [Claim 9] The method for fabricating a light emitting diode according to claim 2, wherein: in the step (2), a metal mask layer is formed only in the extended electrode region, and the pad electrode region does not form a metal mask. In the film layer, in the step (5), a photoresist layer is formed on the pad electrode region, and then etching is performed. The step (6) further includes removing the photoresist mask layer.
[权利要求 10] —种发光二极管, 采用前述权利要求 1-9中的任一项制作方法制得。  [Claim 10] A light emitting diode produced by the method of any one of the preceding claims 1-9.
PCT/CN2017/097841 2016-12-22 2017-08-17 Light-emitting diode and manufacturing method therefor WO2018113328A1 (en)

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