WO2018103139A1 - Procédé de fabrication d'une feuille anti-reflet résistante à l'eau - Google Patents

Procédé de fabrication d'une feuille anti-reflet résistante à l'eau Download PDF

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Publication number
WO2018103139A1
WO2018103139A1 PCT/CN2016/111222 CN2016111222W WO2018103139A1 WO 2018103139 A1 WO2018103139 A1 WO 2018103139A1 CN 2016111222 W CN2016111222 W CN 2016111222W WO 2018103139 A1 WO2018103139 A1 WO 2018103139A1
Authority
WO
WIPO (PCT)
Prior art keywords
transparent
substrate
waterproof
sheet
layer
Prior art date
Application number
PCT/CN2016/111222
Other languages
English (en)
Chinese (zh)
Inventor
许东勇
Original Assignee
许东勇
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 许东勇 filed Critical 许东勇
Publication of WO2018103139A1 publication Critical patent/WO2018103139A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • B05D7/534—Base coat plus clear coat type the first layer being let to dry at least partially before applying the second layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2502/00—Acrylic polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2503/00—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2518/00—Other type of polymers

Definitions

  • the invention relates to the technical field of production technology of waterproof glare sheets, in particular to a production process of a breathable waterproof glare sheet for making articles such as garments, shoes and hats.
  • articles such as clothing, shoes and hats are generally made of cloth or leather, especially shoes, which have high requirements on air permeability and waterproof performance, and the layers of such materials generally have a single color and the surface is covered with small holes.
  • the cloth or leather can not be electroplated or optically plated. If the glare effect is to be achieved, the glare sheet is generally pasted or sewn on the surface of the material layer, so it is necessary to improve .
  • the object of the present invention is to provide a production process of a waterproof glare sheet.
  • the invention has simple process and is easy to implement, and the production process is environmentally friendly and non-polluting, and the waterproof glare sheet has excellent brilliance. Light effect.
  • another object of the present invention is to provide a production process of a breathable waterproof glare shoe material, which is breathable and waterproof, has excellent air permeability and waterproof performance, and has excellent glare effect.
  • a production process of waterproof glare sheet comprising the following steps,
  • the substrate is selected, and a single-layer fabric, a PU sheet, a TPU sheet, a KPU sheet, an animal leather sheet or an artificial leather sheet is used as a substrate, or at least two sheets are selected as the substrate.
  • the composite sheet of the composite layer is a substrate;
  • the substrate is processed to have a pattern printed on a partial or full area of the surface of the substrate and/or a decorative sheet is fixed;
  • the transparent top coat is blended, and 3 to 10% of the polyurethane and 45 to 60% of the butyl ester and 35 to 50% of the acrylic resin are uniformly mixed according to the weight percentage of the effective substance to obtain a transparent top coat;
  • Optical coating after the transparent topcoat is dried, a transparent transparent film layer is plated on the surface of the substrate by an optical coating process;
  • the substrate in the step of selecting a substrate, is selected from a sheet having a gas permeable mesh or a gas permeable cavity, and a partial or full area of the substrate is covered with a gas permeable mesh or a permeable backing;
  • the material layer of the composite sheet comprises at least two of a cloth layer, a PU layer, a TPU layer, a KPU layer, an animal leather layer or an artificial leather layer.
  • the substrate is cut into a shape of the upper of the shoe or the upper of the upper.
  • the production process comprises the steps of formulating a transparent primer, and preparing a transparent primer step, mixing 40-60% of the isocyanate polymer and 40-60% of the butyl ester according to the weight percentage of the effective substance.
  • a clear primer is obtained; the transparent primer step is first applied, and the transparent primer is evenly sprayed on the surface of the substrate subjected to degreasing and dusting, and after the transparent primer is dried, a transparent topcoating step is performed.
  • 5% of the polyurethane and 55% of the butyl ester and 45% of the acrylic resin are uniformly mixed according to the weight percentage of the effective substance to obtain a transparent Topcoat; in the step of formulating the transparent primer, 55% of the isocyanate polymer and 45% of the butyl ester are uniformly mixed according to the weight percentage of the effective substance to obtain a transparent primer.
  • the transparent primer in the step of spraying the transparent primer, has a thickness of 1 to 50 ⁇ m, and the transparent primer does not block the gas permeable mesh or the gas permeable cavity of the substrate; in the step of spraying the transparent topcoat, The transparent topcoat has a thickness of 1 to 50 ⁇ m, and the transparent topcoat does not block the gas permeable mesh or the gas permeable cavity of the substrate.
  • the organic coating method and the metal plating material are simultaneously used for the optical coating process, and the coating film formed on the surface of the substrate is a mixed type transparent transparent waterproof film layer, and the transparent transparent film layer Does not block the permeable mesh or venting of the substrate.
  • a surface treatment step is added between the step of spraying the transparent topcoat and the optical coating, and the nano-sized zirconia powder is uniformly sprayed on the surface of the transparent topcoat by a flame spraying process, in a flame spraying process.
  • the flame temperature is controlled at 80-90 ° C.
  • the zirconia powder is combined with the transparent topcoat to form a transparent nano-zirconia composite layer on the surface of the transparent topcoat.
  • the thickness of the nano-zirconia composite layer is 1-2 ⁇ m.
  • the invention has the advantages that the process of the invention is simple, easy to implement, environmentally friendly and pollution-free in the production process, and the waterproof glare sheet produced has excellent waterproof performance, and the breathable waterproof glare shoe material It has excellent air permeability and waterproof performance, and has excellent glare effect. In different angles, different distance observations and dynamic observation, different areas have different color and color changes, showing more The color changes and the color is more translucent.
  • a production process of waterproof glare sheet comprising the following steps,
  • the layer includes at least two of a cloth layer, a PU layer, a TPU layer, a KPU layer, an animal leather layer, or an artificial leather layer.
  • the substrate is processed, and a pattern is printed on a partial area or a whole area of the surface of the substrate.
  • Some decorative sheets may be fixed on the surface of the substrate by a pasting process or a sewing process, and the substrate is cut into a sheet of a desired shape.
  • the substrate is cleaned by ultrasonication and then dried.
  • the transparent top coat is blended, and 3 to 10% of the polyurethane and 45 to 60% of the butyl ester and 35 to 50% of the acrylic resin are uniformly mixed according to the weight percentage of the effective substance to obtain a transparent top coat; wherein, the transparent top coat is more
  • the ratio is preferably such that 5% of the polyurethane and 55% of the butyl ester and 45% of the acrylic resin are uniformly mixed to obtain a transparent top coat.
  • a transparent topcoat is sprayed, and the transparent topcoat is uniformly sprayed on the surface of the substrate subjected to degreasing and dust removal; the thickness of the transparent topcoat is 1 to 50 ⁇ m.
  • the transparent topcoat acts as a dielectric layer and has excellent adhesion to the substrate, so that the optical coating process can be coated with a light waterproof film layer on the surface thereof, and the top coat and the light transmissive waterproof film layer are also excellent. Adhesion, but also has the effect of increasing the glare effect.
  • the surface of the substrate is plated with a transparent waterproof film layer by an optical coating process; specifically, an organic mixed drug and a metal plated material are simultaneously used for optical coating process to form a surface of the substrate.
  • the coating is a hybrid light-transmitting waterproof film layer, and the thickness of the light-transmitting waterproof film layer is 1 to 10 ⁇ m.
  • the process of the invention is simple, easy to implement, environmentally friendly and pollution-free in the production process, and the waterproof glare sheet produced by the product has waterproof performance; the waterproof glare sheet is observed at different angles and different distances, and the different regions of the waterproof glare sheet are respectively Presenting different colors in the dynamic observation of breathable waterproof glare sheets In the process, or in the process of moving or shaking the waterproof glare sheet, different areas of the waterproof glare sheet respectively exhibit different color and color changes, and the color is more translucent, and has excellent glare effect.
  • a production process of a breathable waterproof glare shoe material comprising the following steps,
  • the substrate is selected, and the substrate is made of a sheet having a gas permeable mesh or a gas permeable cavity, and a partial or full area of the substrate is covered with a gas permeable mesh or a gas permeable cavity; specifically, the substrate is a single layer.
  • the structure of the cloth, the PU sheet, the TPU sheet, the KPU sheet, the animal leather sheet or the artificial leather sheet is used as the substrate.
  • the substrate of the single layer structure is preferably a cloth filled with a breathable mesh.
  • a composite sheet having at least two composite layer structures is selected as the substrate, and the material layer of the composite sheet includes at least two of a cloth layer, a PU layer, a TPU layer, a KPU layer, an animal leather layer or an artificial leather layer.
  • the top and bottom layers of the composite sheet are both meshed with a mesh
  • the intermediate layer is a PU layer, a TPU layer or a KPU with a gas permeable mesh or a gas permeable cavity in a partial or full area.
  • the substrate is processed, and a pattern is printed on a partial area or a whole area of the surface of the substrate, and some decorative pieces can be fixed on the surface of the substrate by a pasting process or a sewing process, and the substrate is cut into a shoe upper or a flat shape of the upper. .
  • the substrate is cleaned by ultrasonication and then dried.
  • the transparent primer step is prepared, and 40 to 60% of the isocyanate polymer and 40 to 60% of the butyl ester are uniformly mixed according to the weight percentage of the effective substance to obtain a transparent primer; wherein, the transparent topcoat is preferably provided. In the ratio, 55% of the isocyanate polymer and 45% of the butyl ester were uniformly mixed in a weight percentage of the effective substance to obtain a transparent primer.
  • the transparent top coat is blended, and 3 to 10% of the polyurethane and 45 to 60% of the butyl ester and 35 to 50% of the acrylic resin are uniformly mixed according to the weight percentage of the effective substance to obtain a transparent top coat; wherein, the transparent top coat is more
  • the ratio is preferably such that 5% of the polyurethane and 55% of the butyl ester and 45% of the acrylic resin are uniformly mixed to obtain a transparent top coat.
  • the transparent primer is sprayed, and the transparent primer is evenly sprayed on the surface of the substrate subjected to degreasing and dusting.
  • the transparent primer has a thickness of 1 to 10 ⁇ m, and the transparent primer does not block the gas permeable mesh or the gas permeable cavity of the substrate.
  • the surface of the substrate is plated with a transparent waterproof film layer by an optical coating process; specifically, an organic mixed drug and a metal plated material are simultaneously used for optical coating process to form a surface of the substrate.
  • the coating is a mixed light-transmissive waterproof film layer, the thickness of the transparent waterproof film layer is 1 to 10 ⁇ m, and the transparent waterproof film layer does not block the gas permeable mesh or the gas permeable cavity of the substrate, the primer, the topcoat and the light transmission.
  • the waterproof film layer forms a gas permeable, water impermeable composite layer.
  • the finished product is made of breathable waterproof glare shoes for making shoes.
  • the process of the invention is simple, easy to implement, environmentally friendly and pollution-free in the production process, and the breathable waterproof glare shoe material obtained has excellent breathability and waterproof performance; and the breathable waterproof glare shoe material is observed at different angles and different distances.
  • the different areas of the breathable waterproof glare shoe material respectively have different colors.
  • the breathable waterproof glare shoe Different areas of the material show different color and color changes, and the color is more translucent, with excellent glare effect.
  • the production process of the breathable waterproof glare shoe material the main steps of the embodiment are the same as those of the second embodiment, including the steps of selecting the substrate, the substrate processing step, the degreasing and dust removing step, the step of preparing the transparent primer, and the transparent surface.
  • the lacquering step, the spraying of the transparent primer step, the spraying of the transparent topcoat step, the optical coating step and the finished step, the same steps are not repeated here, except that a step is added between the step of spraying the transparent topcoat and the step of the optical coating.
  • the surface treatment step specifically, after the transparent topcoat is dried, the nano-sized zirconia powder is uniformly sprayed on the surface of the transparent topcoat by a flame spraying process, and the flame temperature in the flame spraying process is controlled at 80-90 ° C, and oxidized.
  • the zirconium powder is combined with the transparent topcoat to form a transparent nano-zirconia composite layer on the surface of the transparent topcoat, and the thickness of the nano-zirconia composite layer is 1-2 ⁇ m.
  • the optical coating is made easier to implement, and the adhesion of the light-transmitting waterproof film layer formed by the optical plating process is further improved.
  • the breathable and waterproof glare shoes respectively show more color and color changes, and the static observation and the dynamic observation respectively have different glare effects, and the colors are more translucent and glare. The effect is even more cool.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Laminated Bodies (AREA)

Abstract

L'invention concerne un procédé de fabrication d'une feuille anti-reflet résistante à l'eau comprenant une étape de sélection de substrat, une étape d'élimination d'huile et d'élimination de poussière, une étape de mélange de peinture de surface transparente, une étape de pulvérisation de peinture de surface transparente et une étape de revêtement optique, ce qui permet de produire une feuille anti-reflet aérée et résistante à l'eau. Le présent procédé de fabrication est simple et facile à mettre en œuvre et présente un processus de production écologique et exempt de pollution. La feuille anti-reflet étanche à l'eau fabriquée présente une performance d'étanchéité à l'eau extrêmement élevée. Le matériau de chaussure anti-reflet aérée et étanche à l'eau présente des performances d'aération et d'étanchéité à l'eau extrêmement élevées et, en même temps, présente des effets anti-reflet importants au niveau des extrémités; lorsqu'il est observé à partir de différents angles et à différentes distances et pendant une observation dynamique, différentes zones présentent respectivement des couleurs et des variations de couleur différentes, ce qui permet de présenter un nombre accru de variations de couleur et d'augmenter la transparence et la luminosité des couleurs.
PCT/CN2016/111222 2016-12-11 2016-12-21 Procédé de fabrication d'une feuille anti-reflet résistante à l'eau WO2018103139A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201611134796.5A CN106670080B (zh) 2016-12-11 2016-12-11 一种防水炫光片材的生产工艺
CN201611134796.5 2016-12-11

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Publication Number Publication Date
WO2018103139A1 true WO2018103139A1 (fr) 2018-06-14

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CN (1) CN106670080B (fr)
WO (1) WO2018103139A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109043735B (zh) * 2018-08-08 2021-05-04 福建省万物智联科技有限公司 一种无底一体鞋的制作工艺
CN110481107B (zh) * 2019-09-05 2024-05-28 深圳市摩码克来沃化学科技有限公司 一种可动态变色薄膜及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1049124A (zh) * 1990-07-11 1991-02-13 中国黄石金利新型包装材料有限公司 一种高分子复合布及其生产方法和应用
EP1468619A1 (fr) * 2003-04-17 2004-10-20 Industria Bergamasca Rifrangenti S.r.l. Méthode de production de produits imprimés rétroréfléchissants de visibilité élevée
EP1584738A1 (fr) * 2004-04-01 2005-10-12 Industria Bergamasca Rifrangenti S.r.l. Procédé de production de produits imprimés à haute visibilité
CN102497981A (zh) * 2009-07-16 2012-06-13 陶氏环球技术有限责任公司 基于聚烯烃的人造皮革
CN102808333A (zh) * 2011-06-01 2012-12-05 现代自动车株式会社 具有透气性的合成革的制造方法
CN103225204A (zh) * 2013-03-22 2013-07-31 电子科技大学 可穿戴的柔性传感器及制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85202629U (zh) * 1985-07-02 1986-05-28 张秀英 反光的遮阳帽
US8058188B2 (en) * 2005-04-13 2011-11-15 Albany International Corp Thermally sprayed protective coating for industrial and engineered fabrics
JP4638379B2 (ja) * 2006-05-22 2011-02-23 克史 段 煙火保護シート
CN102615880B (zh) * 2012-03-22 2015-08-26 东莞劲胜精密组件股份有限公司 一种光学膜及其制备方法
CN103537418A (zh) * 2013-10-31 2014-01-29 陈来运 一种硬质箱包表面的喷涂工艺
CN204605055U (zh) * 2015-04-08 2015-09-02 福建柒牌集团有限公司 一种新型炫光面料
CN205562855U (zh) * 2016-04-18 2016-09-07 安徽恒安交通科技有限公司 一种可转移炫彩植珠膜

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1049124A (zh) * 1990-07-11 1991-02-13 中国黄石金利新型包装材料有限公司 一种高分子复合布及其生产方法和应用
EP1468619A1 (fr) * 2003-04-17 2004-10-20 Industria Bergamasca Rifrangenti S.r.l. Méthode de production de produits imprimés rétroréfléchissants de visibilité élevée
EP1584738A1 (fr) * 2004-04-01 2005-10-12 Industria Bergamasca Rifrangenti S.r.l. Procédé de production de produits imprimés à haute visibilité
CN102497981A (zh) * 2009-07-16 2012-06-13 陶氏环球技术有限责任公司 基于聚烯烃的人造皮革
CN102808333A (zh) * 2011-06-01 2012-12-05 现代自动车株式会社 具有透气性的合成革的制造方法
CN103225204A (zh) * 2013-03-22 2013-07-31 电子科技大学 可穿戴的柔性传感器及制备方法

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