WO2018040274A1 - 一种宽体电梯平衡补偿链及其生产工艺 - Google Patents

一种宽体电梯平衡补偿链及其生产工艺 Download PDF

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WO2018040274A1
WO2018040274A1 PCT/CN2016/104433 CN2016104433W WO2018040274A1 WO 2018040274 A1 WO2018040274 A1 WO 2018040274A1 CN 2016104433 W CN2016104433 W CN 2016104433W WO 2018040274 A1 WO2018040274 A1 WO 2018040274A1
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wide
chain
flame retardant
compensation chain
anchor chain
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PCT/CN2016/104433
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English (en)
French (fr)
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魏伟
吴夕虎
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江苏兴华胶带股份有限公司
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16GBELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G13/00Chains
    • F16G13/12Hauling- or hoisting-chains so called ornamental chains
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/02Making granules by dividing preformed material
    • B29B9/06Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/20Carboxylic acid amides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16GBELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G13/00Chains
    • F16G13/02Driving-chains
    • F16G13/10Driving-chains with universal joints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/22Halogen free composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

Definitions

  • the invention relates to the technical field of elevator equipment, in particular to a wide-body elevator balance compensation chain with a large unit length ratio and high strength and a production process thereof.
  • the traction elevators include a car, a traction wire rope, a counterweight and an accompanying cable.
  • the length of the wire rope on the car side and the counterweight side is constantly changing, which causes the change of the weight of the wire rope on both sides of the traction sheave. For this reason, when the lifting height of the elevator exceeds a certain height, it must be set to have A certain weight of components to balance the weight change due to height changes, this is the elevator balance compensation chain.
  • the elevator balance compensation chain is defined as: a component for balancing the weight of the car and the counterweight, balancing the traction rope and the accompanying cable, and balancing the operation of the elevator. It is required to have a large load carrying capacity, low operating noise, and weight per unit length.
  • the rope wearing compensation chain is the most primitive type of compensation chain and can only be used for elevators with a speed of 1.75m/s or less.
  • the structure is such that the hemp rope is inserted into the iron chain.
  • friction and collision occur between the chain and the chain, the noise is relatively large, and it is easy to rust, and the hemp rope is easy to shrink after being wet, and the time is long. Rotting, affecting the safety of elevator operation.
  • plastic coated compensation chain in order to reduce the noise during the running process of the rope compensation chain, and at the same time slow down the corrosion of the iron chain, so on the basis of the rope compensation chain wrapped a layer of plastic sleeve, forming a plastic compensation chain.
  • the plastic-plastic compensation chain can slow down the impact of the chain when running, which greatly reduces the noise.
  • the plastic sleeve of the compensation chain is easy to crack and fall off, so it still needs to be improved in terms of flexibility and durability. .
  • CN104044981A discloses a new type of elevator full plastic balance chain, and the outer part of the electric welding anchor chain is sequentially provided.
  • CN2646475Y discloses an elevator balance compensation chain, which comprises an iron chain and a rubber cylinder. In the above two publications, the fiber layer is prevented from cracking by increasing the fiber layer, but the compensation chain is inflexible during operation, and the bending outer circumference is stretched to a large extent.
  • the present invention provides a balance compensation chain for elevators with reduced noise and high strength during elevator operation and production thereof. Process.
  • the invention provides a wide-body elevator balance compensation chain, comprising: an anchor chain and an outer wrap layer wrapped around the anchor chain, the outer wrap layer comprises a raw material: an elastomer resin, a flame retardant and a processing aid, and an elastomer resin Including: styrenic block copolymer and polyolefin thermoplastic elastomer, flame retardant includes: flame retardant silicon masterbatch, intumescent flame retardant and flame retardant synergist; anchor chain is structural steel, structural steel includes elements: Fe, C, Si, Mn, Cr, Mo, Ni, Al, and residual elements: Cu, P, S, N; the outer wrap and the anchor chain are solid monoliths cast together.
  • the mass percentage of each of the raw materials in the outer wrap is:
  • the styrenic block copolymer is a styrene-ethylene-propylene-styrene block copolymer having a styrene content of from 10% to 55%.
  • the concentration of the silicon polymer in the flame retardant silicon masterbatch is from 15% to 65%, and the silicon polymer is a polysiloxane.
  • the intumescent flame retardant is melamine phosphate borate.
  • the flame retardant synergist is one or more of silica, titania, magnesia, montmorillonite.
  • the weight percentage of each element of the anchor chain is: C: 0.1% - 0.28%, Si: 0.15% - 0.4%, Mn: 0.2% - 1.7%, Cr: 0.5% - 1.2%, Mo : 0.2% - 0.5%, Ni: 0.8% - 1.00%, Nb: 0.02% - 0.08%, Al: 0.01% - 0.04%, Cu ⁇ 0.20%, P ⁇ 0.02%, S ⁇ 0.005%, N: 0.004% -0.009%, the remaining content is Fe.
  • the substrate for anchor chain is produced, and the obtained substrate is subjected to ring butt welding to form an anchor chain, and the obtained anchor chain is placed in a continuous quenching furnace for quenching and tempering, and the quenching is performed.
  • the tempering step is: in the continuous quenching furnace, the anchor chain is quenched and heated to 900-1100 ° C, and kept warm for 2-3 h, water cooled to room temperature, tempered at 580-650 ° C, and kept warm for 2-3 h, again water cooled To room temperature.
  • the anchor chain obtained above was placed in a mold of an extruder, and the above-mentioned sheet-like rubber was fed into an extruder.
  • the extrusion temperature is controlled at 130 ° C to 150 ° C, and the extrusion speed of the extrusion is 5 to 15 m / sec.
  • the extruder extrudes the above-mentioned rubber material, extrudes it into the above mold, and wraps it on the anchor chain.
  • the anchor chain is placed in the wrapping layer to produce a balance compensation chain for the elevator.
  • one or two anchor chains are included.
  • the invention provides a wide-body elevator balance compensation chain. Compared with the prior art, the invention has the beneficial effects of: forming a solid integral piece by pouring the outer wrap layer and the anchor chain together, and using the running stability during operation. Good, reduce the noise during operation; use double anchor chain if necessary, can increase the specific gravity per unit length; the outer layer of the raw material formula makes the outer layer meet the soft, environmental stress cracking, hardness, and significant Good heat resistance, bending radius greater than 800mm, flame retardant, low smoke density, anti-aging, the material hardness reaches 80-90 Shore hardness; the elemental formula of the anchor chain improves the strength and toughness of the anchor chain, making the balance
  • the compensation chain has a large load carrying capacity and effectively improves the safety performance of the elevator; the anchor chain adopts structural steel, which has the characteristics of high strength, high toughness and good tensile performance.
  • FIG. 1 is an axial cross-sectional view of a wide-body elevator balance compensation chain according to a first embodiment of the present invention
  • Figure 2 is a radial cross-sectional view of the wide-body elevator balance compensation chain shown in Figure 1;
  • FIG. 3 is an axial cross-sectional view of a wide-body elevator balance compensation chain according to a second embodiment of the present invention.
  • FIG. 4 is a radial cross-sectional view of the wide body elevator balance compensation chain shown in FIG. 3.
  • the present invention discloses an outer wrap layer for a balance compensation chain for an elevator by the three embodiments of the embodiments 1-3, which comprises a raw material: an elastomer resin, a flame retardant and a processing aid, wherein the elastomer resin Including: styrenic block copolymer, polyolefin thermoplastic elastomer, flame retardant including: flame retardant silicon masterbatch, intumescent flame retardant and flame retardant synergist.
  • the raw materials in the outer wrap 2 are:
  • each of the raw materials is obtained according to the above components and percentage thereof, wherein the styrenic block copolymer is copolymerized with styrene-ethylene-propylene-styrene block having a styrene content of 10%; and the silicon polymer in the flame retardant silicon masterbatch
  • the concentration is 15%, the silicon polymer is polysiloxane; the intumescent flame retardant is melamine phosphate borate; the flame retardant synergist is silica and montmorillonite;
  • the processing aid includes: antioxidant, Lubricants, fillers, colorants, wherein the antioxidants are auxiliary antioxidants, the lubricants are erucamides, silicone masterbatches, and the fillers are montmorillonite carbon black.
  • the raw materials are mixed in a kneader to bring the temperature to 85 ° C, and the mixed raw materials are sent to a cooling stirrer to be cooled to 40 ° C, and then poured into a feeder, which is fed.
  • the feeder is fed into a twin-screw extruder, extruded and granulated, and the material extruded in the twin-screw extruder is drawn, cooled and sliced to obtain a sheet-like rubber.
  • the raw materials in the outer wrap 2 are:
  • each of the raw materials is obtained according to the above components and percentage thereof, wherein the styrenic block copolymer is copolymerized with styrene-ethylene-propylene-styrene block having a styrene content of 20%; and the silicon polymer in the flame retardant silicon masterbatch
  • the concentration is 40%, the silicon polymer is polysiloxane; the intumescent flame retardant is melamine phosphate borate; the flame retardant synergist is titanium dioxide;
  • the processing aid includes antioxidant, lubricant, filler, wherein The antioxidant is an aromatic amine antioxidant, the lubricant is stearic acid and oleic acid amide, and the filler is made of clay, talcum powder and mica powder.
  • the raw materials are mixed in a kneader to bring the temperature to 95 ° C, and the mixed raw materials are sent to a cooling stirrer to be cooled to 50 ° C, and then poured into a feeder, which is fed.
  • the feeder is fed into a twin-screw extruder, extruded and granulated, and the material extruded in the twin-screw extruder is drawn, cooled and sliced to obtain a sheet-like rubber.
  • the raw materials in the outer wrap 2 are:
  • each of the raw materials is obtained according to the above components and percentage thereof, wherein the styrenic block copolymer is copolymerized with styrene-ethylene-propylene-styrene block having a styrene content of 55%; and the silicon polymer in the flame retardant silicon masterbatch
  • the concentration is 65%, the silicon polymer is polysiloxane; the intumescent flame retardant is melamine phosphate borate; the flame retardant synergist is magnesium oxide and montmorillonite; the processing aid includes antioxidant and lubricant.
  • the raw materials are mixed in a kneader to bring the temperature to 90 ° C, and the mixed raw materials are sent to a cooling stirrer and cooled to 45 ° C, and then poured into a feeder, which is fed.
  • the feeder is fed into a twin-screw extruder, extruded and granulated, and the material extruded in the twin-screw extruder is drawn, cooled and sliced to obtain a sheet-like rubber.
  • flame-retardant silicon masterbatch is used, and the flame-retardant silicon masterbatch is used for the outer layer of the styrene-based block copolymer and the polyolefin thermoplastic elastomer due to the flame retardant silicon masterbatch during combustion.
  • the silicone polymer can form a carbon layer with the styrenic block copolymer and the polyolefin thermoplastic elastomer, which can improve the oxygen index and reduce the flame propagation speed, and has a good flame retarding effect.
  • the silicone polymerization The material can improve impact strength, mechanical properties, heat resistance and the like.
  • the use of a plurality of flame retardant synergists and an intumescent flame retardant in the outer wrap material further improves the flame retardant efficiency of the flame retardant system, and at the same time, the amount of smoke generated by the material is greatly reduced, and the elevator is improved.
  • the safety performance, and the flame retardant has low smoke, low toxicity, no halogen, and good stability.
  • the surface can form a uniform layer of carbon foam. It has excellent flame retardancy by the functions of heat insulation, oxygen barrier and smoke suppression, and prevents the occurrence of droplets.
  • the elastomer material prepared according to the above formula ratio is a halogen-free flame-retardant elastomer material, which has the characteristics of high strength, good flame retardancy and strong flexibility.
  • the invention discloses an anchor chain for a balance compensation chain for an elevator by the three embodiments of the embodiment 4-6, wherein the anchor chain includes main elements: Fe, C, Si, Mn, Cr, Mo, Ni, Nb, Al, and residual elements: Cu, P, S, N; the content (% by weight) of each main component is:
  • the carbon equivalent is greater than 1.40
  • C carbon can increase the strength of the steel, and at the same time increase the hardenability of the steel, less than 0.1%, the mechanical properties of the weld can not meet the strength requirements of the four-stage mooring chain, Above 0.28%, in the quenching process, the base material is prone to quench cracks, and the residual carbon in the flash butt weld portion increases, which will reduce the impact toughness at the weld. Therefore, the carbon content is determined to be: 0.1%-0.28%; Si: silicon can increase the strength and hardenability of the steel, and the minimum content is 0.15%, in order to achieve the effect, but the silicon content is too high, especially when it is combined with manganese and chromium.
  • the manganese content range is determined to be 0.2-1.7%; Cr: chromium is improved
  • the upper limit of chromium is determined to be 1.20%;
  • Mo molybdenum can be improved Hardenability of steel, prevent temper brittleness, improve quenching characteristics at steel welds, reduce quenching cracks, and improve impact toughness at welds. When molybdenum content exceeds 0.5%, the effect on performance improvement will not increase;
  • Ni Nickel can be improved The strength, lowering the low temperature brittle transition temperature of the steel, improving the fatigue resistance of the steel and reducing the sensitivity to the notch, significantly improving the low temperature impact toughness at the weld, and the nickel element is also one of the elements to improve the corrosion resistance of the steel.
  • the content is too high, not only increases the cost, but also because the metal matrix under the oxide scale becomes nickel-rich and is not easily oxidized, thereby causing the scale to adhere and form an oxide scale which is not easy to fall off, so the content range is determined to be 0.8-1.0%;
  • Nb As a refined grain element and precipitation strengthening element, cerium is effective in reducing the gas content in steel and improving the low temperature impact toughness of steel. When its content exceeds 0.08%, its improvement effect is no longer increased;
  • Al aluminum and strontium The effect is similar, mainly to refine the grain and reduce the oxygen and nitrogen content of the gas in the steel to improve the comprehensive mechanical properties.
  • the aluminum exceeds 0.040%, the aluminum oxide inclusion increases, which will deteriorate the impact toughness of the steel.
  • an anchor chain for a balance compensation chain for elevators controls residual elements at: Cu ⁇ 0.20%, P ⁇ 0.02%, S ⁇ 0.005%, N: 0.004% - 0.009%, to be reduced to The effect of anchor chain strength.
  • the base material for the anchor chain is produced according to the above formula ratio, and the obtained substrate is subjected to ring butt welding to prepare
  • the anchor chain and the obtained anchor chain are placed in a continuous quenching and tempering furnace for quenching and tempering.
  • the quenching and tempering steps are as follows: in the continuous quenching and tempering furnace, the anchor chain is quenched and heated to 1000 ° C, and the heat is insulated. 2.5h, water cooled to room temperature, tempered at 600 ° C, and kept for 2.5h, and then water cooled to room temperature.
  • the anchor chain obtained according to the above method has the characteristics of high strength, high toughness and low yield ratio, so that the load of the balance compensation chain is large, and the safety performance of the elevator is effectively improved.
  • FIG. 1 through 4 schematically illustrate a wide body elevator balance compensation chain made using the outer wrap 2 and the anchor chain 1 provided in accordance with two embodiments of the present invention.
  • a wide-body elevator balance compensation chain disclosed by the present invention comprises an anchor chain 1 and an outer wrap layer 2 wrapped around the anchor chain 1.
  • the outer wrap 2 utilizes the above elastic system.
  • the outer wrap 2 and the anchor chain 1 are solid monoliths that are cast together.
  • the surface of the anchor chain 1 is provided with a protective layer.
  • the protective layer is a painted layer.
  • the wide-body elevator balance compensation chain disclosed by the present invention comprises two anchor chains 1 and an outer wrap layer 2 wrapped around the anchor chain 1.
  • the outer wrap 2 utilizes the above elastic system.
  • the outer wrap 2 and the anchor chain 1 and the cable 3 are solid monoliths that are cast together.
  • the surface of the anchor chain 1 is provided with a protective layer.
  • the protective layer is a galvanized layer.
  • a solid integral piece is formed by pouring the outer wrap layer and the anchor chain together, which is stable during use, reduces noise during operation, and uses a double anchor chain if necessary. Increase the proportion of unit length.
  • a cable can be cast in the outer wrap as needed to connect the electrical components on the opposite side of the elevator and the car side to realize signal transmission on the car side and the counterweight side, and the number of accompanying cables has been reduced. Simplify layout and reduce costs.

Abstract

一种宽体电梯平衡补偿链及其生产工艺,包括:锚链(1)及包覆于锚链(1)外的外裹层(2),外裹层(2)包括原料:苯乙烯系嵌段共聚物、聚烯烃热塑性弹性体、阻燃硅母粒、膨胀型阻燃剂、阻燃协效剂及加工助剂,外裹层(2)与锚链(1)为浇注在一起的实心整体件。该平衡补偿链的外裹层(2)具有柔软、耐环境应力开裂、硬度大、比重大、耐热性能好、弯曲半径大于800mm、阻燃、低烟密度、耐老化的优点,该锚链(1)强度大且韧性大,使得平衡补偿链承载负荷大,有效提高了电梯的安全性能。

Description

一种宽体电梯平衡补偿链及其生产工艺 技术领域
本发明涉及电梯设备技术领域,尤其涉及一种单位长度比重大、具有高强度的一种宽体电梯平衡补偿链及其生产工艺。
背景技术
目前,市场上运用的升降电梯大多曳引电梯,曳引电梯包括轿厢、曳引钢丝绳、对重及随行缆线。电梯在运行过程中,轿厢侧和对重侧的钢丝绳的长度在不断变化,从而引起曳引轮两侧钢丝绳重量的变化,为此,当电梯的提升高度超过一定高度时,必须要设置具有一定重量的部件来平衡因高度变化带来的重量变化,这就是电梯平衡补偿链。简而言之,电梯平衡补偿链定义为:用于连接电梯的轿厢与对重,平衡曳引绳及随行缆线的重量,对电梯的运行起平衡作用的部件。要求其具有承载负荷大,运行噪声小,单位长度重量等特点。
目前市面上的电梯补偿链有以下几种:
1、穿绳补偿链,是最原始的一种补偿链,只能用于梯速1.75m/s以下的电梯。结构为在铁链中穿入麻绳,这种补偿链在使用过程中由于链与链之间发生摩擦和碰撞,噪音比较大,且容易生锈,麻绳受潮后易收缩,时间长了容易腐烂,影响电梯运行的安全性。
2、包塑补偿链,为了减小穿绳补偿链在运行过程中的噪音,同时减缓环境对铁链的腐蚀,于是在穿绳补偿链的基础上包裹一层塑料套,形成了包塑补偿链。相比于穿绳补偿链,包塑补偿链运行时能减缓链环撞击,使噪音大大减小,但是这种补偿链塑料套容易开裂、脱落,因此,在柔韧性及耐用性方面仍需改善。
3、全塑补偿链,可用至6m/s的高速电梯,外表为缆状PVC结构,使用时电梯运行能达到平稳静音的效果。但是由于补偿链的单位长度重量需与曳引绳单位长度重量相匹配,从而须增大外裹层的直径,CN104044981A公开了一种新型电梯全塑平衡链,其电焊锚链外部依次设有第一PVC橡塑复合层、纤维层和第二PVC橡塑复合层。CN2646475Y公开了一种电梯平衡补偿链,包括铁链,橡胶柱体。上述两份公开文件中通过增加纤维层来防止开裂,但是这种补偿链在运转过程中弯曲不灵活,其弯曲外圆周拉伸幅度大。
发明内容
为克服现有技术中存在的噪声大、容易开裂及弯曲不灵活的问题,本发明提供了一种减小电梯运行过程中的减小噪声、具有高强度的升降电梯用平衡补偿链及其生产工艺。
本发明提供的一种宽体电梯平衡补偿链,包括:锚链及包覆于锚链外的外裹层,外裹层包括原料:弹性体树脂、阻燃剂及加工助剂,弹性体树脂包括:苯乙烯系嵌段共聚物及聚烯烃热塑性弹性体,阻燃剂包括:阻燃硅母粒、膨胀型阻燃剂和阻燃协效剂;锚链为结构钢,结构钢包括元素:Fe、C、Si、Mn、Cr、Mo、Ni、Al,及残余元素:Cu、P、S、N;外裹层与锚链为浇注在一起的实心整体件。
在一些实施方式中,外裹层中各原料的质量百分比为:
Figure PCTCN2016104433-appb-000001
在一些实施方式中,苯乙烯系嵌段共聚物为苯乙烯-乙烯-丙烯-苯乙烯嵌段共聚,其苯乙烯含量为10%-55%。
在一些实施方式中,阻燃硅母粒中的硅聚合物的浓度为15%-65%,硅聚合物为聚硅氧烷。
在一些实施方式中,膨胀型阻燃剂为磷酸三聚氰胺硼酸盐。
在一些实施方式中,阻燃协效剂为二氧化硅、二氧化钛、氧化镁、蒙脱土中的一种或多种。
取上述各原料,将上述原料在捏合机中混合使温度达到85℃-95℃,将混合好的原料送入冷却搅拌器中冷却至40℃-50℃后倒入喂料机中,由喂料机喂入到双螺杆挤出机中,挤出造粒,将双螺杆挤出机中挤出的料进行拉条、冷却、切片,制成片状胶料。
在一些实施方式中,锚链各元素所占的重量百分比为:C:0.1%-0.28%、Si:0.15%-0.4%、Mn:0.2%-1.7%、Cr:0.5%-1.2%、Mo:0.2%-0.5%、Ni:0.8%-1.00%、Nb:0.02%-0.08%、Al:0.01%-0.04%、Cu≤0.20%、P≤0.02%、S≤0.005%、N:0.004%-0.009%,其余含量为Fe。
按照上述配方生产出锚链用基材,再对得到的基材进行编环对焊,制成锚链,制得的锚链置于连续式调质炉中进行淬火、回火处理,其淬火、回火步骤为:在连续式调质炉中,将锚链淬火加热到900-1100℃,并保温2-3h,水冷至室温,580-650℃回火,并保温2-3h,再次水冷至室温。
将上述制得的锚链置入挤出机的模具内,再将上述片状胶料,送入挤出机。挤出的温度控制在为130℃~150℃,挤出的牵引速度为5~15米/秒,挤出机将上述胶料挤出,挤压到上述模具内,包裹于锚链上,使上述锚链置于包裹层内,制得平升降电梯用衡补偿链。
在一些实施方式中,包括一根或两根锚链。
本发明提供的一种宽体电梯平衡补偿链与现有技术相比,本发明的有益效果是:通过将外裹层与锚链浇注在一起,形成一实心整体件,在使用运行时平稳性好,降低运行时的噪声;在需要的情况下采用双锚链,可增加了单位长度的比重;外裹层的原料配方使外裹层满足了柔软、耐环境应力开裂、硬度大、比重大、耐热性能好、弯曲半径大于800mm,阻燃、低烟密度、耐老化的优点,其材料硬度达到80-90邵氏硬度;锚链的元素配方提高了锚链的强度和韧性,使得平衡补偿链承载负荷大,有效提高了电梯的安全性能;锚链采用结构钢,其具有强度大、韧性大、抗拉性能好的特性。
附图说明
图1为本发明提供的第一种实施方式的一种宽体电梯平衡补偿链的轴向剖视图;
图2为图1所示的一种宽体电梯平衡补偿链的径向剖视图;
图3为为本发明提供的第二种实施方式的一种宽体电梯平衡补偿链的轴向剖视图;
图4为图3所示的一种宽体电梯平衡补偿链的径向剖视图。
具体实施方式
以下结合附图和实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本发明,并不用于限定本发明。
本发明通过实施例1-3三个实施例披露了一种用于升降电梯用平衡补偿链的外裹层,其包括原料:弹性体树脂、阻燃剂及加工助剂,其中,弹性体树脂包括:苯乙烯系嵌段共聚物、聚烯烃热塑性弹性体、阻燃剂包括:阻燃硅母粒、膨胀型阻燃剂及阻燃协效剂。
实施例1:
外裹层2中的原料:苯乙烯系嵌段共聚物、聚烯烃热塑性弹性体、阻燃硅母粒、膨胀型阻燃剂、阻燃协效剂及加工助剂的质量百分比为:
Figure PCTCN2016104433-appb-000002
按照上述成分及其百分比取各原料,其中,苯乙烯系嵌段共聚物采用苯乙烯含量为10%的苯乙烯-乙烯-丙烯-苯乙烯嵌段共聚;阻燃硅母粒中的硅聚合物的浓度为15%,硅聚合物采用聚硅氧烷;膨胀型阻燃剂采用磷酸三聚氰胺硼酸盐;阻燃协效剂采用二氧化硅和蒙脱土;加工助剂包括:抗氧剂、润滑剂、填料、着色剂,其中,抗氧剂采用辅助抗氧剂,润滑剂采用芥酸酰胺类、硅酮母粒,填料采用蒙脱土炭黑。按照上述成分及其百分比取各原料,将上述原料在捏合机中混合,使温度达到85℃,将混合好的原料送入冷却搅拌器中冷却至40℃后倒入喂料机中,由喂料机喂入到双螺杆挤出机中,挤出造粒,将双螺杆挤出机中挤出的料进行拉条、冷却、切片,制成片状胶料。
实施例2:
外裹层2中的原料:苯乙烯系嵌段共聚物、聚烯烃热塑性弹性体、阻燃硅母粒、膨胀型阻燃剂、阻燃协效剂及加工助剂的质量百分比为:
Figure PCTCN2016104433-appb-000003
按照上述成分及其百分比取各原料,其中,苯乙烯系嵌段共聚物采用苯乙烯含量为20%的苯乙烯-乙烯-丙烯-苯乙烯嵌段共聚;阻燃硅母粒中的硅聚合物的浓度为40%,硅聚合物采用聚硅氧烷;膨胀型阻燃剂采用磷酸三聚氰胺硼酸盐;阻燃协效剂采用二氧化钛;加工助剂包括抗氧剂、润滑剂、填料,其中,抗氧剂采用芳香胺类抗氧剂,润滑剂采用硬脂酸和油酸酰胺类,填料采用陶土、滑石粉、云母粉。按照上述成分及其百分比取各原料,将上述原料在捏合机中混合,使温度达到95℃,将混合好的原料送入冷却搅拌器中冷却至50℃后倒入喂料机中,由喂料机喂入到双螺杆挤出机中,挤出造粒,将双螺杆挤出机中挤出的料进行拉条、冷却、切片,制成片状胶料。
实施例3:
外裹层2中的原料:苯乙烯系嵌段共聚物、聚烯烃热塑性弹性体、阻燃硅母粒、膨胀型阻燃剂、阻燃协效剂及加工助剂的质量百分比为:
Figure PCTCN2016104433-appb-000004
按照上述成分及其百分比取各原料,其中,苯乙烯系嵌段共聚物采用苯乙烯含量为55%的苯乙烯-乙烯-丙烯-苯乙烯嵌段共聚;阻燃硅母粒中的硅聚合物的浓度为65%,硅聚合物采用聚硅氧烷;膨胀型阻燃剂采用磷酸三聚氰胺硼酸盐;阻燃协效剂采用氧化镁、蒙脱土;加工助剂包括抗氧剂、润滑剂、填料、着色剂,其中,抗氧剂采用受阻酚类抗氧剂,润滑剂采用油酸酰胺类和芥酸酰胺类,填料 采用石棉粉、碳酸钙、蒙脱土炭黑。按照上述成分及其百分比取各原料,将上述原料在捏合机中混合,使温度达到90℃,将混合好的原料送入冷却搅拌器中冷却至45℃后倒入喂料机中,由喂料机喂入到双螺杆挤出机中,挤出造粒,将双螺杆挤出机中挤出的料进行拉条、冷却、切片,制成片状胶料。
上述3个实施例中,均采用阻燃硅母粒,阻燃硅母粒对于含有苯乙烯系嵌段共聚物及聚烯烃热塑性弹性体的外裹层,由于燃烧时阻燃硅母粒中的硅酮聚合物能与苯乙烯系嵌段共聚物及聚烯烃热塑性弹性体形成炭层,既能提高其氧指数,又能降低火焰传播速度,起到良好的阻燃作用,此外,硅酮聚合物能改善抗冲击强度、机械性能、耐热性能等。外裹层原料中采用多种阻燃协效剂与膨胀型阻燃剂进行复配使用,进一步提升了阻燃体系的阻燃效率,同时也使得材料燃烧的发烟量大大降低,提高了电梯的安全性能,并且,阻燃剂具有低烟、低毒、无卤、稳定性好,将其加入到聚合物用时,在聚合物受热时,表面能够生成一层均匀的碳质泡沫层,起到隔热、隔氧、抑烟的作用,并防止产生熔滴现象,因此具有极好的阻燃性。按照上述配方配比制得的弹性体材料为无卤阻燃弹性体材料,其具有强度高,阻燃性好,柔性强的特点。
本发明通过实施例4-6三个实施例披露了一种用于升降电梯用平衡补偿链的锚链,该锚链中包括主要元素:Fe、C、Si、Mn、Cr、Mo、Ni、Nb、Al,及残余元素:Cu、P、S、N;各主要成分的含量(重量%)为:
实施例4:
C:0.1%、Si:0.15%、Mn:0.2%、Cr:0.5%、Mo:0.2%、Ni:0.8%、Nb:0.02%、Al:0.01%、Cu:0.12%、P:0.013%、S:0.004:%、N:0.004%,其余为Fe。
实施例5:
C:0.2%、Si:0.28%、Mn:1.63%、Cr:1.0%、Mo:0.4%、Ni:0.9%、Nb:0.035%、Al:0.032%、Cu:0.12%、P:0.014%、S:0.002%、N:0.0056%,其余为Fe。
实施例6:
C:0.28%、Si:0.4%、Mn:1.7%、Cr:1.2%、Mo:0.5%、Ni;1.00%、Nb:0.08%、Al:0.04%,Cu:0.20%、P:0.02%、S:0.005%、N:0.009%,其余为Fe。
其中,碳的当量大于1.40,C:碳可提高钢的强度,同时又可提高钢的淬透性,低于0.1%,焊缝处的力学性能达不到四级系泊链的强度要求,高于0.28%,在淬火工艺中,母材易产生淬火裂纹,且闪光对焊部分残留的碳增多,将降低焊缝处的冲击韧性。因此碳含量确定为:0.1%-0.28%;Si:硅可提高钢的强度及淬透性,其最低含量为0.15%,才能达到其效果,但硅含量过高特别是当其与锰、铬元素共存时,增加钢的过热敏感性一钢的回火脆性。同时由于硅易被氧化,钢中硅酸盐夹杂的存在,将降低钢的冲击韧性,因此Si含量上限为0.30%;Mn:锰可提高强度、韧性及淬透性,但锰含量过高易产生钢晶粒粗化的倾向,且增加了钢的回火脆性的敏感性,当锰含量超过1.7%时,易产生淬火裂纹,因此锰含量范围确定为0.2-1.7%;Cr:铬是提高抗腐蚀能力的主要元素,同时铬可以抑制和降低碳的扩散速度,减少钢在焊接时碳的烧损,提高焊缝处的力学性能,铬还有提高钢的淬透性及回火稳定性的作用,因此铬应不低于0.50%,而较高的铬含量所形成的氧化物夹杂滞留于焊缝处,将降低钢的冲击韧性,铬的上限确定为1.20%;Mo:钼可提高钢的淬透性,防止回火脆性,改善钢材焊缝处的淬火特性,减少淬火裂纹,提高焊缝处的冲击韧性,当钼含量超过0.5%时,对性能改善的效果将不再增加;Ni:镍可提高钢的强度,降低钢的低温脆性转变温度,提高钢的抗疲劳性能和减少对缺口的敏感性,明显提高焊缝处的低温冲击韧性,同时镍元素也是作为提高钢的耐腐蚀性能的元素之一,但含量过高,不仅增加成本,而且由于氧化皮下的金属基体成为富镍而不易氧化,从而导致氧化皮粘附,形成不易脱落的氧化皮,因此含量范围确定为0.8-1.0%;Nb:铌作为细化晶粒元素和沉淀强化元素而加入,对降低钢中气体含量及改善钢的低温冲击韧性作用明显,当其含量超过0.08%时,其改善效果不再增加;Al:铝与铌的作用相类似,主要是细化晶粒及降低钢中气体氧、氮含量,以改善综合力学性能,铝超过0.040%时,铝的氧化物夹杂增加,将恶化钢材的冲击韧性。
残余元素:Cu、P、S、N超过一定含量时,将降低锚链的低温冲击韧性,提高锚链的脆性转变温度,恶化锚链的综合力学性能。因此,披露了一种用于升降电梯用平衡补偿链的锚链将残余元素控制在:Cu≤0.20%、P≤0.02%、S≤0.005%、N:0.004%-0.009%,以减小为锚链强度的影响。
按照上述配方配比生产出锚链用基材,再对得到的基材进行编环对焊,制成 锚链,制得的锚链置于连续式调质炉中进行淬火、回火处理,其淬火、回火步骤为:在连续式调质炉中,将锚链淬火加热到1000℃,并保温2.5h,水冷至室温,600℃回火,并保温2.5h,再次水冷至室温。
按照上述方法制得的锚链,具有高强度、高韧性、较低的屈强比的特性,使的平衡补偿链承载负荷大,有效提高了电梯的安全性能。
为了制成本发明披露的一种宽体电梯平衡补偿链,需要将上述制得的锚链置入挤出机的模具内,再将上述片状胶料,送入挤出机。挤出的温度控制在为140℃,挤出的牵引速度为8米/秒,挤出机将上述胶料挤出,挤压到上述模具内,包裹于锚链上,使上述锚链置于包裹层内。
图1至图4示意性地显示了根据本发明两种实施方式提供的利用上述外裹层2和锚链1制得的一种宽体电梯平衡补偿链。
实施例7:
如图1和图2所示,本发明披露的一种宽体电梯平衡补偿链,包括一根锚链1及包覆于锚链1外的外裹层2,外裹层2利用上述弹性体制成,外裹层2与锚链1为浇注在一起的实心整体件。锚链1表面设有防护层,作为优选的,防护层为喷漆层。
实施例9:
如图3和图4所示,本发明披露的一种宽体电梯平衡补偿链,包括两根锚链1及包覆于锚链1外的外裹层2,外裹层2利用上述弹性体制成,外裹层2与锚链1及缆线3为浇注在一起的实心整体件。锚链1表面设有防护层,作为优选的,防护层为镀锌层。
上述两个实施例中,通过将外裹层与锚链浇注在一起,形成一实心整体件,在使用运行时平稳性好,降低运行时的噪声,并且,在需要的情况下采用双锚链,增加了单位长度的比重。另外,可根据需要,在外裹层内还浇注有缆线,用于连接电梯对重侧和轿厢侧的电气部件,实现轿厢侧与对重侧的信号传输,已减少随行电缆的增加,简化布局,降低成本。
上述说明示出并描述了本发明的优选实施例,如前所述,应当理解本发明并非局限于本文所披露的形式,不应看作是对其他实施例的排除,而可用于各种其他组合、修改和环境,并能够在本文所述发明构想范围内,通过上述教导或相关 领域的技术或知识进行改动。而本领域人员所进行的改动和变化不脱离本发明的精神和范围,则都应在本发明所附权利要求的保护范围内。

Claims (10)

  1. 一种宽体电梯平衡补偿链,包括锚链(1)及包覆于所述锚链(1)外的外裹层(2),其特征在于:所述外裹层(2)与所述锚链(1)为浇注在一起的实心整体件;所述外裹层(2)包括原料:弹性体树脂、阻燃剂及加工助剂,其中,所述弹性体树脂包括:苯乙烯系嵌段共聚物及聚烯烃热塑性弹性体,所述阻燃剂包括:阻燃硅母粒、膨胀型阻燃剂和阻燃协效剂;
    所述锚链(1)为结构钢,结构钢包括:主要元素:Fe、C、Si、Mn、Cr、Mo、Ni、Al,及残余元素:Cu、P、S、N。
  2. 根据权利要求1所述的一种宽体电梯平衡补偿链,其特征在于,所述外裹层(2)中各原料的质量百分比为:
    Figure PCTCN2016104433-appb-100001
  3. 根据权利要求2所述的一种宽体电梯平衡补偿链,其特征在于,所述苯乙烯系嵌段共聚物为苯乙烯-乙烯-丙烯-苯乙烯嵌段共聚,其苯乙烯含量为10%-55%。
  4. 根据权利要求2所述的一种宽体电梯平衡补偿链,其特征在于,所述阻燃硅母粒中的硅聚合物的浓度为15%-65%,所述硅聚合物为聚硅氧烷。
  5. 根据权利要求2所述的一种宽体电梯平衡补偿链,其特征在于,所述膨胀型阻燃剂为磷酸三聚氰胺硼酸盐。
  6. 根据权利要求2所述的一种宽体电梯平衡补偿链,其特征在于,所述阻燃协效剂为二氧化硅、二氧化钛、氧化镁、蒙脱土中的一种或多种。
  7. 根据权利要求1所述的一种宽体电梯平衡补偿链,其特征在于,所述锚链各元素所占的重量百分比为:C:0.1%-0.28%、Si:0.15%-0.4%、Mn:0.2%-1.7%、Cr:0.5%-1.2%、Mo:0.2%-0.5%、Ni:0.8%-1.00%、Nb:0.02%-0.08%、Al:0.01%-0.04%、Cu≤0.20%、P≤0.02%、S≤0.005%、N:0.004%-0.009%,其余含量为Fe。
  8. 根据权利要求1所述的一种宽体电梯平衡补偿链,其特征在于,包括一根或两根所述锚链(1)。
  9. 一种宽体电梯平衡补偿链的生产工艺,其特征在于,取制作外裹层(2)的原料在捏合机中混合,使温度达到85℃-95℃,将混合好的原料送入冷却搅拌器中冷却至40℃-50℃后喂入双螺杆挤出机挤出造粒,将双螺杆挤出机中挤出的胶料进行拉条、冷却、切片,制成片状胶料备用;将锚链置入挤出机的模具内,将所述片状胶料,送入挤出机,挤出机将上述片状胶料挤出,挤压至模具内,包裹于锚链外。
  10. 根据权利要求9所述的一种宽体电梯平衡补偿链的生产工艺,其特征在于,所述片状胶料挤出的温度控制在为130℃-150℃,挤出的牵引速度为5~15米/秒。
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