WO2018031373A1 - Polyol acrylé et acylé ou acétalisé en tant que substitut d'origine biologique pour matériaux durs, rigides, thermoplastiques et thermodurcissables - Google Patents
Polyol acrylé et acylé ou acétalisé en tant que substitut d'origine biologique pour matériaux durs, rigides, thermoplastiques et thermodurcissables Download PDFInfo
- Publication number
- WO2018031373A1 WO2018031373A1 PCT/US2017/045340 US2017045340W WO2018031373A1 WO 2018031373 A1 WO2018031373 A1 WO 2018031373A1 US 2017045340 W US2017045340 W US 2017045340W WO 2018031373 A1 WO2018031373 A1 WO 2018031373A1
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- WO
- WIPO (PCT)
- Prior art keywords
- polyol
- copolymer
- monomer
- acrylated
- average degree
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/26—Bituminous materials, e.g. tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F20/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/02—Alcohols; Phenols; Ethers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2641—Polyacrylates; Polymethacrylates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/282—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing two or more oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/283—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/01—High molecular weight, e.g. >800,000 Da.
Definitions
- the glycerol molecule was successfully modified such that when it was polymerized soft thermoplastic elastomers were created. These soft thermoplastic elastomers can be used in a wide range of applications, i.e. pressure sensitive adhesives, viscosity modifiers, etc.
- Another aspect of the present invention relates to a method for preparing a fracking liquid.
- the method comprises mixing the thermoplastic homopolymer, the
- the copolymer is a thermosetting copolymer.
- the acrylated and acylated or acetalized polyol monomeric units have different degrees of acrylation and acylation or acetalization of hydroxyl groups.
- the acrylated and acylated or acetalized polyol monomeric units have different degrees of acrylation and acylation or acetalization of hydroxyl groups.
- the average degree of acylation in acrylated and acylated sorbitol can range from 0.001 to 5.9.
- the average degree of acrylation in acrylated and acylated isosorbide can range from 0.001 to 2.
- the average degree of acylation in acrylated and acylated isosorbide can range from 0.001 to 2.
- the average degree of acrylation in acrylated and acylated dextrose can range from 0.001 to 4.9.
- the average degree of acylation in acrylated and acylated dextrose can range from 0.001 to 4.9.
- One or more acrylated and acylated or acetalized polyol monomeric units of the PA block can contain one or more alkoxy groups.
- Exemplary methacrylamides include N-(2- aminoethyl)methacrylamide (hydrochloride) (AEMAm) and N-(3-aminopropyl)methacrylamide (hydrochloride) (APMAm), N-(2-(dimethylamino)ethyl)acrylamide (DEAPMAm), N-(3- (dimethylamino)propyl)methacrylamide (hydrochloride) (DMAPMAm), etc.
- the stoichiometric ratio of the acrylic reagent to the polyol can range from 1 to the maximum number of the hydroxyl functionalities in the polyol molecule.
- the stoichiometric ratio of the acrylic reagent to glycerol typically ranges from 1 to 3.
- the method comprises providing an acrylated and acetalized polyol composition comprising plural polyol monomeric units.
- the polyol monomelic units being acrylated and acetalized.
- initiation is typically based on the reversible formation of growing radicals in a redox reaction between various transition metal compounds and an initiator.
- GTR ground tire rubber
- cryogenic GTR is produced by shredding the tire into relatively large pieces and then subjecting the rubber to grinding under cryogenic conditions; ambient or warm-ground GTR is produced under warm or ambient grinding procedure.
- the shredding and pulling apart of the tire rubber at ambient temperatures produces irregular particles having a high surface area which desirably increases the number of reactive sites available for bonding or cross-linking with the acrylated polyol-based
- thermoplastic copolymer a thermoplastic block copolymer, or a thermoplastic statistical copolymer as an asphalt additive, modifier, and/or filler, with a weight percentage in the range of 0.01 % to 1.05 %, into an asphalt composition to form a homogeneous asphalt composition.
- the asphalt composition comprises i) an asphalt component, and ii) a crumb rubber having a weight percentage in the range of 1 % to 15 %. Any of the thermoplastic homopolymer, copolymer, block copolymer, or statistical copolymer discussed in the above embodiments can be used herein.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
La présente invention concerne un homopolymère, un copolymère, un copolymère séquencé et un copolymère statistique comprenant plusieurs motifs monomères de polyol. Les motifs monomères de polyol sont acrylés et acylés ou acétalisés. Les motifs monomères de polyol acrylés et acylés ou acétalisés présentent un degré moyen d'acrylation égal ou supérieur à 1, mais inférieur au nombre de groupes hydroxyle du polyol et ayant un degré moyen d'acylation ou d'acétalisation qui est égal ou supérieur à 1, mais inférieur au nombre des groupes hydroxyle du polyol. La présente invention concerne également un procédé de fabrication des homopolymères, copolymères, copolymères séquencés et copolymères statistiques, et leur utilisation dans diverses applications, comme les modificateurs de bitume-caoutchouc, les adhésifs, ou un additif dans un fluide de fracturation hydraulique destiné à la fracturation hydraulique pour le forage de puits de pétrole.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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US16/272,261 US11248076B2 (en) | 2016-08-12 | 2019-02-11 | Acrylated and acylated or acetalized polyol as a biobased substitute for hard, rigid thermoplastic and thermoset materials |
US17/554,544 US11813892B2 (en) | 2016-08-12 | 2021-12-17 | Acrylated and acylated or acetalized polyol as a biobased substitute for hard, rigid thermoplastic and thermoset materials |
US18/468,464 US20240001711A1 (en) | 2016-08-12 | 2023-09-15 | Acrylated and acylated or acetalized polyol as a biobased substitute for hard, rigid thermoplastic and thermoset materials |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US201662374414P | 2016-08-12 | 2016-08-12 | |
US62/374,414 | 2016-08-12 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US16/272,261 Continuation-In-Part US11248076B2 (en) | 2016-08-12 | 2019-02-11 | Acrylated and acylated or acetalized polyol as a biobased substitute for hard, rigid thermoplastic and thermoset materials |
Publications (2)
Publication Number | Publication Date |
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WO2018031373A1 true WO2018031373A1 (fr) | 2018-02-15 |
WO2018031373A8 WO2018031373A8 (fr) | 2018-04-19 |
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PCT/US2017/045340 WO2018031373A1 (fr) | 2016-08-12 | 2017-08-03 | Polyol acrylé et acylé ou acétalisé en tant que substitut d'origine biologique pour matériaux durs, rigides, thermoplastiques et thermodurcissables |
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US (3) | US11248076B2 (fr) |
WO (1) | WO2018031373A1 (fr) |
Cited By (10)
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CN108707443A (zh) * | 2018-05-18 | 2018-10-26 | 杭州海维特化工科技有限公司 | 一种柔强可控的芳香型黏合剂胶乳膜及其制备方法 |
CN108892755A (zh) * | 2018-05-31 | 2018-11-27 | 广东基业长青节能环保实业有限公司 | 一种缓释型聚羧酸减水剂及其制备方法和用途 |
CN109628063A (zh) * | 2018-12-19 | 2019-04-16 | 大连理工大学 | 一种聚合物改性沥青粘结剂及其制备方法 |
CN110272408A (zh) * | 2018-03-16 | 2019-09-24 | 杭州盛弗泰新材料科技有限公司 | 一种光固化剂二甲基二恶戊烷醇甲基丙烯酸酯的制备方法 |
WO2019202038A3 (fr) * | 2018-04-19 | 2019-12-12 | University Of Tartu | Synthèse et polymérisation de monométhacrylates à base d'isosorbide |
KR20200052480A (ko) * | 2018-11-06 | 2020-05-15 | 주식회사 제일화성 | 흡수성 수지용 아크릴계 가교제의 제조방법, 이로 제조된 흡수성 수지용 아크릴계 가교제 및 이를 포함하는 생분해성 고흡수성 수지 |
WO2020254460A1 (fr) | 2019-06-21 | 2020-12-24 | Evonik Operations Gmbh | Procédé de production de mono(méth)acrylate de glycérol |
CN112300306A (zh) * | 2020-11-09 | 2021-02-02 | 广东石油化工学院 | 一种生物降解性可辐射固化的(甲基)丙烯酸酯及其制备方法 |
CN112566892A (zh) * | 2018-08-16 | 2021-03-26 | 赢创运营有限公司 | (甲基)丙烯酸酯的制备 |
US11414373B2 (en) | 2017-01-20 | 2022-08-16 | Evonik Operations Gmbh | Glycerol (meth)acrylate carboxylic ester having a long shelf life |
Families Citing this family (3)
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WO2018031373A1 (fr) * | 2016-08-12 | 2018-02-15 | Iowa State University Research Foundation, Inc. | Polyol acrylé et acylé ou acétalisé en tant que substitut d'origine biologique pour matériaux durs, rigides, thermoplastiques et thermodurcissables |
WO2024105089A1 (fr) * | 2022-11-15 | 2024-05-23 | Sabic Global Technologies B.V. | Composition d'asphalte à durée de vie améliorée |
CN117327044A (zh) * | 2023-05-31 | 2024-01-02 | 江苏集萃光敏电子材料研究所有限公司 | 一种超低体积收缩的丙烯酸酯类单体和应用 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3993663A (en) * | 1974-12-27 | 1976-11-23 | Showa High Polymer Co., Ltd. | Curable resinous composition |
US5763548A (en) | 1995-03-31 | 1998-06-09 | Carnegie-Mellon University | (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
US6538091B1 (en) | 1995-11-15 | 2003-03-25 | Carnegie Mellon University | Atom or group transfer radical polymerization |
WO2012057748A1 (fr) * | 2010-10-27 | 2012-05-03 | Empire Technology Development Llc | Produits acrylates polymérisables biocompatibles et procédés correspondants |
US20130184383A1 (en) | 2012-01-18 | 2013-07-18 | Iowa State University Research Foundation, Inc. | Thermoplastic elastomers via atom transfer radical polymerization of plant oil |
US20140343192A1 (en) | 2013-05-20 | 2014-11-20 | Iowa State University Research Foundation, Inc. | Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides |
WO2015179553A2 (fr) * | 2014-05-21 | 2015-11-26 | Iowa State University Research Foundation, Inc. | Poly (polyol acrylé) et procédé de fabrication et d'utilisation associé comme modificateur d'asphalte-caoutchouc, adhésif, additif de fracturation ou fluide de fracturation |
US20160229863A1 (en) * | 2015-02-09 | 2016-08-11 | Marc A. Hillmyer | Isosorbide-based polymethacrylates |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL123667C (fr) | 1961-03-23 | |||
DE1816380A1 (de) * | 1968-12-21 | 1970-12-17 | Merck Anlagen Gmbh | Mittel zur Gelchromatographie und Verfahren zu ihrer Herstellung |
US5936015A (en) | 1998-10-16 | 1999-08-10 | Creanova Inc. | Rubber-modified asphalt paving binder |
US7011932B2 (en) | 2001-05-01 | 2006-03-14 | E. I. Du Pont De Nemours And Company | Polymer waveguide fabrication process |
US20050065310A1 (en) | 2003-09-23 | 2005-03-24 | Wang Zhikai Jeffrey | Urethane (meth)acrylate resin with acrylic backbone and ink compositions containing the same |
CN101321837B (zh) | 2005-10-18 | 2012-04-11 | 佩什托普特殊化学股份公司 | 双固化组合物 |
US8420710B2 (en) | 2008-04-30 | 2013-04-16 | Armstrong World Industries, Inc. | UV/EB curable biobased coating for flooring application |
JP5947028B2 (ja) * | 2010-12-02 | 2016-07-06 | ローム アンド ハース エレクトロニック マテリアルズ エルエルシーRohm and Haas Electronic Materials LLC | ポリマー、フォトレジスト組成物、およびフォトリソグラフィパターンを形成する方法 |
CN103619889B (zh) | 2011-05-30 | 2015-10-07 | 三菱丽阳株式会社 | 聚合物及其制造方法 |
ES2532028T3 (es) | 2011-10-14 | 2015-03-23 | Allnex Ip S.À.R.L. | Procedimiento para la preparación de (met)acrilatos de uretano de baja viscosidad, diluibles en agua |
EP2644634A1 (fr) | 2012-03-30 | 2013-10-02 | Cytec Surface Specialties, S.A. | Composés (méth)acrylés durcissables par rayonnement |
BR112015028040A2 (pt) * | 2013-05-06 | 2018-04-24 | The Regents Of The Univ Of Minnesota | polímero contendo cadeia principal derivada de acrilato, métodos para preparar polímeros, formulações farmacêuticas e métodos para aumentar a solubilidade de um fármaco |
WO2018031373A1 (fr) * | 2016-08-12 | 2018-02-15 | Iowa State University Research Foundation, Inc. | Polyol acrylé et acylé ou acétalisé en tant que substitut d'origine biologique pour matériaux durs, rigides, thermoplastiques et thermodurcissables |
-
2017
- 2017-08-03 WO PCT/US2017/045340 patent/WO2018031373A1/fr active Application Filing
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2019
- 2019-02-11 US US16/272,261 patent/US11248076B2/en active Active
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2021
- 2021-12-17 US US17/554,544 patent/US11813892B2/en active Active
-
2023
- 2023-09-15 US US18/468,464 patent/US20240001711A1/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3993663A (en) * | 1974-12-27 | 1976-11-23 | Showa High Polymer Co., Ltd. | Curable resinous composition |
US5763548A (en) | 1995-03-31 | 1998-06-09 | Carnegie-Mellon University | (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
US6538091B1 (en) | 1995-11-15 | 2003-03-25 | Carnegie Mellon University | Atom or group transfer radical polymerization |
WO2012057748A1 (fr) * | 2010-10-27 | 2012-05-03 | Empire Technology Development Llc | Produits acrylates polymérisables biocompatibles et procédés correspondants |
US20130184383A1 (en) | 2012-01-18 | 2013-07-18 | Iowa State University Research Foundation, Inc. | Thermoplastic elastomers via atom transfer radical polymerization of plant oil |
US20140343192A1 (en) | 2013-05-20 | 2014-11-20 | Iowa State University Research Foundation, Inc. | Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides |
WO2015179553A2 (fr) * | 2014-05-21 | 2015-11-26 | Iowa State University Research Foundation, Inc. | Poly (polyol acrylé) et procédé de fabrication et d'utilisation associé comme modificateur d'asphalte-caoutchouc, adhésif, additif de fracturation ou fluide de fracturation |
US20160229863A1 (en) * | 2015-02-09 | 2016-08-11 | Marc A. Hillmyer | Isosorbide-based polymethacrylates |
Non-Patent Citations (8)
Title |
---|
DAVIS ET AL.: "Atom Transfer Radical Polymerization of tert-Butyl Acrylate and Preparation of Block Copolymers", MACROMOLECULES, vol. 33, 2000, pages 4039 - 4047, XP000927903, DOI: doi:10.1021/ma991826s |
MATYJASZEWSKI ET AL.: "Atom Transfer Radical Polymerization", CHEMICAL REVIEWS, vol. 101, 2001, pages 2921 - 2990 |
MOAD ET AL.: "Living Radical Polymerization by the Raft Process- a First Update", AUSTRALIAN JOURNAL OF CHEMISTRY, vol. 59, 2006, pages 669 - 92 |
MOAD ET AL.: "Living Radical Polymerization by the Raft Process- a Second Update", AUSTRALIAN JOURNAL OF CHEMISTRY, vol. 62, no. 11, 2009, pages 1402 - 72 |
MOAD ET AL.: "Living Radical Polymerization by the Raft Process- a Third Update", AUSTRALIAN JOURNAL OF CHEMISTRY, vol. 65, 2012, pages 985 - 1076 |
MOAD ET AL.: "The Chemistry of Radical Polymerization - Second Fully Revised Edition", 2006, ELSEVIER SCIENCE LTD. |
PAGLIARO ET AL.: "The Future of Glycerol 2nd Edition,", 2010, THE ROYAL SOCIETY OF CHEMISTRY |
SKEY ET AL.: "Facile one pot synthesis of a range of reversible addition-fragmentation chain transfer (RAFT) agents", CHEMICAL COMMUNICATIONS, vol. 35, 2008, pages 4183 - 85 |
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WO2018031373A8 (fr) | 2018-04-19 |
US20220105753A1 (en) | 2022-04-07 |
US20190177454A1 (en) | 2019-06-13 |
US20240001711A1 (en) | 2024-01-04 |
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