WO2018021218A1 - 農作物における有害生物の防除方法 - Google Patents
農作物における有害生物の防除方法 Download PDFInfo
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- WO2018021218A1 WO2018021218A1 PCT/JP2017/026634 JP2017026634W WO2018021218A1 WO 2018021218 A1 WO2018021218 A1 WO 2018021218A1 JP 2017026634 W JP2017026634 W JP 2017026634W WO 2018021218 A1 WO2018021218 A1 WO 2018021218A1
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- 238000000034 method Methods 0.000 title claims abstract description 89
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- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical class COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 claims abstract description 11
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- 108090000623 proteins and genes Proteins 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 24
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 17
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- 230000000855 fungicidal effect Effects 0.000 claims description 13
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims description 12
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- 239000000417 fungicide Chemical class 0.000 claims description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 12
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- FZXISNSWEXTPMF-UHFFFAOYSA-N terbutylazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C)=N1 FZXISNSWEXTPMF-UHFFFAOYSA-N 0.000 description 1
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- KNDVJPKNBVIKML-UHFFFAOYSA-N tetraniliprole Chemical compound CNC(=O)C1=CC(C#N)=CC(C)=C1NC(=O)C1=CC(CN2N=C(N=N2)C(F)(F)F)=NN1C1=NC=CC=C1Cl KNDVJPKNBVIKML-UHFFFAOYSA-N 0.000 description 1
- LOQQVLXUKHKNIA-UHFFFAOYSA-N thifensulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C2=C(SC=C2)C(O)=O)=N1 LOQQVLXUKHKNIA-UHFFFAOYSA-N 0.000 description 1
- WOSNCVAPUOFXEH-UHFFFAOYSA-N thifluzamide Chemical compound S1C(C)=NC(C(F)(F)F)=C1C(=O)NC1=C(Br)C=C(OC(F)(F)F)C=C1Br WOSNCVAPUOFXEH-UHFFFAOYSA-N 0.000 description 1
- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical group COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 description 1
- DQFPEYARZIQXRM-LTGZKZEYSA-N tralkoxydim Chemical compound C1C(=O)C(C(/CC)=N/OCC)=C(O)CC1C1=C(C)C=C(C)C=C1C DQFPEYARZIQXRM-LTGZKZEYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- XOPFESVZMSQIKC-UHFFFAOYSA-N triasulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)OCCCl)=N1 XOPFESVZMSQIKC-UHFFFAOYSA-N 0.000 description 1
- BQZXUHDXIARLEO-UHFFFAOYSA-N tribenuron Chemical compound COC1=NC(C)=NC(N(C)C(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 BQZXUHDXIARLEO-UHFFFAOYSA-N 0.000 description 1
- REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 description 1
- AZHZOGYUMMIAOF-UHFFFAOYSA-N trifludimoxazin Chemical compound O=C1N(C)C(=S)N(C)C(=O)N1C(C(=C1)F)=CC2=C1OC(F)(F)C(=O)N2CC#C AZHZOGYUMMIAOF-UHFFFAOYSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- AKTQJCBOGPBERP-UHFFFAOYSA-N triflusulfuron Chemical compound FC(F)(F)COC1=NC(N(C)C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2C)C(O)=O)=N1 AKTQJCBOGPBERP-UHFFFAOYSA-N 0.000 description 1
- DFFWZNDCNBOKDI-UHFFFAOYSA-N trinexapac Chemical compound O=C1CC(C(=O)O)CC(=O)C1=C(O)C1CC1 DFFWZNDCNBOKDI-UHFFFAOYSA-N 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 239000002753 trypsin inhibitor Substances 0.000 description 1
- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
Definitions
- the present invention relates to a method for controlling pests in crops, that is, harmful arthropods, nematodes, phytopathogenic fungi and / or weeds, and a herbicide composition.
- This invention makes it a subject to provide the method of exhibiting the outstanding effect in the pest control of the cultivation place of agricultural products.
- the present invention relates to ethyl [3- [2-chloro-4-fluoro-5- (1-methyl-6-trifluoromethyl-2,4-) before, simultaneously with and / or after sowing of crops.
- a method for controlling pests in a crop cultivation area (1) A step of treating crop seeds with one or more compounds selected from compound group A, (2) Before sowing, simultaneously with and / or after sowing the crop seed obtained in the above step, ethyl [3- [2-chloro-4-fluoro-5- (1-methyl-6-tri A process of treating fluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl) phenoxy] -2-pyridyloxy] acetate in the crop cultivation area, and (3) growth of the crop A method for controlling pests, comprising a step of treating a crop with one or more compounds selected from the compound group B in the season.
- Compound group A Neonicotinoid compounds, diamide compounds, carbamate compounds, organophosphorus compounds, biological nematicide compounds, other insecticide compounds and nematicide compounds, azole compounds, strobilurin compounds A group consisting of compounds, metalaxyl compounds, SDHI compounds, other fungicide compounds and plant growth regulators.
- Compound group B A group consisting of strobilurin compound, azole compound, SDHI compound, other fungicide compound, pyrethroid compound, benzoylphenylurea compound, organophosphorus insecticide compound, neonicotinoid compound and diamide compound.
- Strobilurin compounds pyraclostrobin, azoxystrobin, mandestrobin, trifloxystrobin and picoxystrobinazole compounds: prothioconazole, epoxiconazole, tebuconazole, cyproconazole, propiconazole, metconazole, Bromuconazole, tetraconazole, triticonazole, ipfentrifluconazole and mefentrifluconazole SDHI compounds: benzovindiflupyr, bixafen, fluxapiloxad, N- (7-fluoro-1,1,3-trimethyl Indan-4-yl) -1-methyl-3-difluoromethylpyrazole-4-carboxylic acid amide (racemic or enantiomer, mixture of R-enantiomer and S-enantiomer in any proportion) ) And N- (1,1,3-trimethylindan-4-yl) -1-methyl-3-difluoromethylpyrazole-4-car
- the pest control method of the present invention can be used to control pests in crop cultivation areas.
- the method for controlling weeds according to the present invention comprises ethyl [3- [2-chloro-4-fluoro-5- (1-methyl-6-trifluoro] before sowing, simultaneously with sowing and / or after sowing.
- a step of treating a crop cultivation area with methyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl) phenoxy] -2-pyridyloxy] acetate hereinafter referred to as Compound X) Including.
- the pest control method of the present invention (hereinafter referred to as the present pest control method) (1) A step of treating crop seeds with one or more compounds selected from the compound group A (hereinafter sometimes referred to as step (1)), (2) A step of treating compound X in the crop cultivation area (hereinafter, referred to as step (2)) before, at the same time as and / or after sowing the crop seed obtained in the above step. ), And (3) a step of treating the crop with one or more compounds selected from the compound group B during the growing season of the crop (hereinafter, sometimes referred to as step (3)). including.
- Compound X is a known compound and is represented by the following formula (I).
- Compound X can be produced by a known method such as the method described in US Pat. No. 6,537,948.
- examples of agricultural crops include corn, cotton, rapeseed, rice, wheat, barley, sugar cane, sugar beet, sorghum, and sunflower, but are not limited as long as they are cultivated as crops in general.
- Such varieties of plants include PPO inhibitors such as flumioxazin, 4-hydroxyphenylpyruvate dioxygenase inhibitors such as isoxaflutole, acetolactate synthase such as imazetapyr and thifensulfuron methyl (hereinafter abbreviated as ALS).
- EPSP 5-enolpyruvylshikimate-3-phosphate synthase
- EPSP 5-enolpyruvylshikimate-3-phosphate synthase
- EPSP 5-enolpyruvylshikimate-3-phosphate synthase
- glyphosate glutamine synthetase inhibitors
- glutamine synthetase inhibitors such as glufosinate
- auxin-type herbicides such as acetyl CoA carboxylases
- cetoxydim also included are plants to which resistance to PSII inhibitors such as inhibitors and bromoxynil (hereinafter abbreviated as ACCase) has been imparted by classical breeding methods, genome editing, or gene recombination techniques.
- Examples of plants to which tolerance has been imparted by a classic breeding method include STS soybeans that are resistant to sulfonylurea ALS-inhibiting herbicides such as thifensulfuron methyl.
- examples of plants imparted with resistance by classical breeding methods include rice, wheat, corn, rapeseed, sunflower resistant to imidazolinone ALS inhibitors, Clearfield (registered trademark), Express (registered trademark), etc. Is already sold under the brand name.
- examples of plants imparted with resistance by a classic breeding method include corn and rice resistant to ACCase inhibitors, and trade names such as Poost Protected (registered trademark) and Provisia (registered trademark).
- an example of a plant to which tolerance has been imparted by classical breeding methods is PSII inhibitor-resistant Triazine Tolerant rapeseed.
- plants that have been rendered resistant by genetic recombination technology include glyphosate-resistant soybean, corn, cotton, and rapeseed, which are already sold under trade names such as RoundupReady (registered trademark) and Gly-Tol (registered trademark).
- RoundupReady registered trademark
- Gly-Tol registered trademark
- glufosinate-tolerant soybean which is already sold under a trade name such as LibertyLink (registered trademark).
- Optimum GAT® which is resistant to both glyphosate and ALS inhibitors.
- the above plants also include plants that can synthesize, for example, selective toxins known in the genus Bacillus, using genetic recombination techniques.
- toxins expressed in such genetically modified plants insecticidal proteins derived from Bacillus cereus and Bacillus popilliae; Cry1Ab, Cry1Ac and Cry1Ac derived from Bacillus thuringiensis ⁇ -endotoxins such as Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, insecticidal proteins such as VIP1, VIP2, VIP3 or VIP3A; nematicidal insecticidal proteins; scorpion toxins, spider toxins, bee toxins or insect-specific neurotoxins Toxins produced by animals; filamentous fungal toxins; plant lectins; agglutinins; trypsin inhibitors, serine protease inhibitors, patatin, Protease inhibitors such as statins and papain inhibitors; ribosome in
- toxins expressed in such a genetically modified crop include Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1, Cry9C, Cry34Ab or Cry35Ab and other ⁇ -endotoxin proteins, VIP1, VIP2, VIP3 and the like
- Insecticidal protein hybrid toxins, partially defective toxins, and modified toxins are also included.
- Hybrid toxins are produced by new combinations of different domains of these proteins using recombinant techniques.
- Cry1Ab lacking a part Cry1Ab lacking a part of the amino acid sequence is known.
- the modified toxin has one or more of the amino acids of the natural toxin replaced.
- Examples of these toxins and recombinant plants capable of synthesizing these toxins are described in EP-A-0374753, WO93 / 07278, WO95 / 34656, EP-A-0427529, EP-A-451878, WO03 / 052073, etc. Has been.
- the toxins contained in these recombinant plants particularly confer resistance to Coleoptera pests, Diptera pests, and Lepidoptera pests.
- genetically modified plants that contain one or more insecticidal pest resistance genes and express one or more toxins are already known and some are commercially available. Examples of these genetically modified plants include Intatta (registered trademark) and the like.
- Examples of the plant used in the present invention also include plants imparted with resistance against aphids such as soybeans into which a Rag1 (Resistivity Aphid Gene 1) gene has been introduced.
- the plant used in the present invention includes those to which resistance to nematodes has been imparted using a classical breeding method or a gene recombination technique.
- RNAi is an example of a gene recombination technique that provides nematode resistance.
- the above-mentioned plants include those imparted with the ability to produce an anti-pathogenic substance having a selective action using genetic recombination technology.
- anti-pathogenic substances PR proteins and the like are known (PRPs, EP-A-0392225).
- PRPs PR proteins and the like are known (PRPs, EP-A-0392225).
- anti-pathogenic substances and genetically modified plants that produce them are described in EP-A-0392225, WO95 / 33818, EP-A-0353191, and the like.
- anti-pathogenic substances expressed in such genetically modified plants include, for example, sodium channel inhibitors, calcium channel inhibitors (KP1, KP4, KP6 toxins produced by viruses, etc.).
- Ion channel inhibitor Ion channel inhibitor
- stilbene synthase bibenzyl synthase
- chitinase glucanase
- PR protein peptide antibiotics, antibiotics having heterocycles, protein factors involved in plant disease resistance (referred to as plant disease resistance gene, WO03 / 000906)) and other anti-pathogenic substances produced by microorganisms.
- the above plants also include plants imparted with useful traits such as oil component modification and amino acid content enhancing traits using genetic recombination techniques. Examples include VISTIVE (registered trademark) (low linolenic soybean with reduced linolenic content) and the like. Moreover, the plant which gave the environmental stress tolerance using the gene recombination technique is also included.
- Examples include DraughtGard (registered trademark).
- DraughtGard registered trademark
- the above-mentioned classic herbicide traits or herbicide resistance genes, insecticidal pest resistance genes, anti-pathogenic substance production genes, useful traits such as oil component modification and amino acid content enhancement traits Combined stack varieties are also included. This includes those using genome editing technology instead of genetic recombination.
- the compound group A includes neonicotinoid compounds, diamide compounds, carbamate compounds, organophosphorus compounds, biological nematicide compounds, other insecticide compounds and nematicide compounds. , As well as azole compounds, strobilurin compounds, metalaxyl compounds, SDHI compounds, other fungicide compounds and plant growth regulators.
- examples of neonicotinoid compounds to be treated on crop seeds include the following. Clothianidin (clothianidin), imidacloprid (imidacloprid), nitenpyram (nitenpyram), acetamiprid (acetamiprid), thiamethoxam (thiamethoxam), Furupirajifuron (flupyradifurone), sulfo hexa Flor (sulfoxaflor), triflupromazine meso pyridinium beam (triflumezopyrim), dichloro meso thia's (Dicloromezotiaz ), Thiacloprid and dinotefuran.
- examples of the diamide compound to be treated on the crop seed include the following. Flubenamide, chlorantaniprole, cyantraniprole, cyclaniliprole, brofuranilide, and rolanidirol.
- examples of the carbamate compounds to be treated on the crop seeds include the following. Aldicarb, oxamyl, thiodicarb, carbofuran, carbosulfan and dimethoate.
- examples of the organic phosphorus compounds to be treated on the crop seeds include the following. Fenamiphos, imicyafos, fensulfothion, terbufos, phosthiazate, phosphocarb, phosphicarb, dicofentimide, diclofenthion Cadusafos, chlorpyrifos, heterofos, mecarphone, folate, thionazine, triazophos, diamifos (d) amidafos), fosthietan (fosthietan) and phosphamidon (phosphamidon).
- examples of the biological nematicide compound to be treated on the crop seed include the following. Harpin Protein, Pasteuria nishizawae, Pasteuria penetrans, Pasteuria usage, Myrothecium verrucaria, Burholderia cepacia, Bacillus chitonosporus, Paecilomyces lilacinus, Bacillus amyloliquefaciens, Bacillus firmus, Bacillus subtilis, Bacillus pumulus, Trichoderma harzianum, Hirsutella rhossiliensis, Hirsutella minnesotensis, Verticillium chlamydosporum and Art robotics dactyloides.
- Examples of other insecticide compounds and nematicide compounds to be treated on crop seeds in this pest control method include the following. Fipronil, etiprole, beta-cyfluthrin, tefluthrin, chlorpyrifos, abamectin, spirotetrazene, spirotetrazene, spirotetrazene (Fluazaindolizine), flusulfone, and fluxamethamide.
- examples of the azole compound to be treated on the crop seed include the following. Azaconazole, bittertanol, bromuconazole, cyproconazole, difenoconazole, dinicoconazole, dinicoconazole, dinicoconazole Fluquinconazole, flusilazole, flutria fol, hexaconazole, imibenconazole, ipconazole, metconazole etconazole), microbutanil, penconazole, propiconazole, prothioconeole, ciconazole, tebuconazole, teconazole.
- Triticonazole Triticonazole, fenarimol, nuarimol, pirifenox, imazaril, oxipoconazole fumarate, oxpoconazole fumarate Zoeto (pefurazoate), prochloraz (Prochloraz), triflumizole (triflumizole), type phen triflupromazine Kona tetrazole (ipfentrifluconazole) and main phen triflupromazine Kona tetrazole (mefentrifluconazole).
- examples of the strobilurin-based compound to be treated on crop seeds include the following. Cresoxime-methyl, azoxystrobin, trifloxystrobin, floxastrobin, picoxystrobin, pyracrostrobin, pyrostrostrobin Strobin, pyribencarb, metminostrobin, oryastrobine and mandestrobin.
- examples of the metalaxyl compounds to be treated on crop seeds include the following. Metalaxyl and metalaxyl-M (metalaxyl-M or mefenoxam).
- examples of the SDHI compound to be treated on the crop seed include the following. Sedaxane, penflufen, carboxin, boscalid, furametopyr, flutolanil, fluxapiroxalu, isopyrazamlu (Isofetamid), pyraziflumid, pydiflumethofen, N- (7-fluoro-1,1,3-trimethylindan-4-yl) -1-methyl-3-difluoromethylpyrazole-4- Carboxylic acid amides (racemic or enantiomers, R enantiomers and S enantiomers) R-rich compound having an R-isomer / S-isomer and an R-enriched compound having an R-isomer / S-isomer of 80/20 or more is hereinafter referred to as F9990), N- (1,1 , 3-Trimethylindan-4-yl) -1-methyl-3-difluoromethylpyrazole-4-carboxy
- examples of the plant growth control agent to be treated on the crop seeds include the following. Ethephon, chlormequat-chloride, mepiquat-chloride, 4-oxo-4- (2-phenylethyl) aminobutyric acid (hereinafter sometimes referred to as compound 2).
- examples of other fungicide compounds to be treated on the crop seeds include the following. Tolclophos-methyl, tiram, captan, carbendazim, thiophanate-methyl, mancozeb, thiobendizyl (thiabendizil) , Picarbutrazox, and oxathiapiprolin.
- the compounds constituting the above compound group A are all known compounds, can be synthesized based on known technical literature, and can be purchased and used on the market.
- compound group B includes strobilurin compounds, azole compounds, SDHI compounds, other fungicide compounds, pyrethroid compounds, benzoylphenylurea compounds, organophosphorus insecticide compounds, neonicotinoid compounds And a group consisting of diamide compounds.
- examples of the strobilurin-based compound for foliar treatment of crops include the following. Pyraclostrobin, azoxystrobin, mandestrobin, trifloxystrobin and picoxystrobin.
- examples of the azole compound for foliar treatment of agricultural crops include the following. Prothioconazole, epoxiconazole, tebuconazole, cyproconazole, propiconazole, metconazole, bromconazole, tetraconazole, triticonazole, ipfentrifluconazole and mefentrifluconazole.
- examples of the SDHI compound to be used for the foliage treatment of crops include the following. Benzovindiflupyr, bixafen, fluxapyroxad, F9990 and compound 1.
- examples of other fungicide compounds for foliar treatment of agricultural products include the following. Toluclophos methyl and ethaboxam.
- examples of pyrethroid compounds to be used for the foliage treatment of agricultural crops include the following. Bifenthrin, lambda cyhalothrin, gamma cyhalothrin, cypermethrin, phenpropatoline, etofenprox, silafluophene and esfenvalerate.
- examples of the benzoylphenylurea compound for foliar treatment of agricultural products include the following. Teflubenzuron and triflumuron.
- examples of the organophosphorus insecticide compound for foliar treatment of crops include the following. Acephate and mesomil.
- examples of neonicotinoid compounds for foliar treatment of crops include the following. Imidacloprid, clothianidin, thiamethoxam, suloxafurol, flupiradifurone, triflumezopyrum and dichloromesothiaz.
- examples of the diamide compound to be used for the foliage treatment of agricultural crops include the following. Flubendiamide, chlorantraniliprole, cyantraniliprolol, brofuranilide, tetranyriprole and cyhalodiamide.
- the compounds constituting the above compound group B are all known compounds, can be synthesized based on known patent documents, and can also be purchased and used on the market.
- compound A In the step of treating one or more compounds selected from the above compound group A (hereinafter referred to as “compound A”) on the crop seed of this pest control method, compound A is usually a solid carrier, liquid carrier, etc. It is mixed with a carrier and, if necessary, a formulation adjuvant such as a surfactant is added and formulated to be used.
- a preferred dosage form is an aqueous liquid suspension formulation.
- Compound A may be a single component or a combination of two or more, or a combination of two or more components.
- the treatment amount of Compound A is usually in the range of 0.2 to 5000 g, preferably 0.5 to 1000 g per 100 kg of crop seeds.
- a method of treating compound A with crop seeds for example, a method of dressing a formulation containing compound A in crop seeds, a method of immersing crop seeds in a formulation containing compound A, and a formulation containing compound A as a crop Examples thereof include a method of spraying seeds and a method of coating crop seeds with a mixture of Compound A and a carrier.
- compound X is treated in the crop cultivation area before sowing, simultaneously with and / or after sowing the crop seed.
- the crop cultivation place in the present invention is not particularly limited as long as it is a place where crops are cultivated, and examples thereof include a field, a farm field, a non-farm land, a park, a bank, a seedling tray, a seedling box, and a nursery.
- compound X is usually mixed with a carrier such as a solid carrier or a liquid carrier, and a formulation adjuvant such as a surfactant is added as necessary.
- a carrier such as a solid carrier or a liquid carrier
- a formulation adjuvant such as a surfactant
- Preferred dosage forms are aqueous liquid suspension preparations, wettable powders, granular wettable powders, granules and emulsions, more preferably emulsions.
- a preparation containing Compound X as a single component may be used alone, or may be used in combination with a preparation containing another herbicide as an active ingredient.
- a preparation containing Compound X and another herbicide as an active ingredient may be used, and a preparation containing Compound X and another herbicide as an active ingredient and a preparation containing another herbicide as an active ingredient may be used in combination. May be used.
- Examples of the method for treating Compound X in the crop cultivation area include a method in which Compound X is sprayed on the soil in the crop cultivation area and a method in which Compound X is sprayed on the weeds after weeds are generated.
- the amount of compound X to be treated is usually in the range of 1 to 1000 g, preferably 2 to 500 g, more preferably 5 to 200, and still more preferably 10 to 100 g per 10,000 m 2 of the crop cultivation area.
- compound X may be treated by mixing an adjuvant.
- the type of adjuvant is not particularly limited, but is oil-based such as Agri-Dex and MSO, nonionic (such as ester or ether of polyoxyethylene) such as Induce, anionic (such as substituted sulfonate) such as Gramein S, Genamine T Examples thereof include cationic systems such as 200BM (polyoxyethyleneamine) and organic silicon systems such as Silwett L77.
- the pH and hardness of the spray liquid when treating compound X in the crop cultivation area are not particularly limited, but are usually in the range of pH 5-9, and the hardness is usually in the range of 0 to 500.
- the time zone for treating Compound X in the crop cultivation area is not particularly limited, but is usually in the range of 5 am to 9 pm, and the photon flux density is usually 10 to 2500 ⁇ mol / sq.m / sec.
- crop seeds are sown in a cultivation area by a normal method.
- Compound X may be treated in the crop cultivation area before sowing of the crop seed, and may be treated simultaneously with and / or after sowing of the crop seed. That is, the number of treatments with compound X is one before before sowing, simultaneously with sowing, or after sowing of crop seeds, twice before sowing, twice excluding simultaneous sowing, or after sowing. Either twice or three times at any timing.
- compound X is treated before sowing seeds of crops, 50 days before sowing to immediately before sowing, preferably 30 days before sowing to immediately before sowing, more preferably 20 days before sowing to immediately before sowing, more preferably 10 days before sowing.
- Compound X is treated just before sowing.
- compound X When compound X is treated after sowing of crop seeds, compound X is usually treated immediately after sowing to before flowering. More preferably, it is between immediately after sowing and before emergence, and between the 1st and 6th leaf stages of the main crop.
- compound B When compound X is treated with foliage at the 1st to 6th leaves of the main leaves of the crop, it is mixed with one or more compounds selected from the above compound group B (hereinafter referred to as compound B) to obtain the step (3 ) May be performed simultaneously or sequentially.
- the order is not particularly limited.
- the case where the compound X is treated simultaneously with the sowing of the crop seed is a case where the seeder and the spreader are integrated.
- step (3) of this pest control method compound B is usually mixed with a carrier such as a solid carrier or a liquid carrier, and further formulated with a supplement such as a surfactant as necessary.
- a carrier such as a solid carrier or a liquid carrier
- a supplement such as a surfactant as necessary.
- Preferred formulations are emulsions, aqueous suspensions, and aqueous liquids.
- the time for carrying out the step (3) is preferably 10 days to 120 days after sowing, more preferably 21 days to 90 days after sowing.
- a plurality of preparations each containing a single active ingredient may be used. In this case, they are mixed or sequentially processed. Moreover, you may use the mixed formulation in which the several compound became an active ingredient.
- the treatment amount of Compound B is usually in the range of 5 to 5000 g, preferably 20 to 2000 g, more preferably 50 to 1500 g per 10000 m 2 of the crop cultivation area.
- an adjuvant may be mixed and processed.
- weeds can be controlled.
- harmful arthropods, harmful nematodes and / or phytopathogenic fungi, and pests such as weeds can be controlled.
- Such harmful arthropods include the following. Hemiptera: small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), Sejirounka (Sogatella furcifera) planthoppers such as, green rice leafhopper (Nephotettix cincticeps), Taiwan green rice leafhopper (Nephotettix virescens) leafhoppers such as, cotton aphid (Aphis gossypii) , Peaches aphids (Myzus persicae), radish aphids (Brevicoryne brassicae), tulip beetle aphids (Macrosiphum euphorbiae), potato beetle aphids (Aulacorthum solani), wheat Aphids such as aphids (Rhopalosiphum padi), citrus aphids (Toxoptera citricidus),
- Lepidoptera rice stem borer (Chilo suppressalis), Sankameiga (Tryporyza incertulas), leaf roller (Cnaphalocrocis medinalis), Watanomeiga (Notarcha derogata), Indian meal moth (Plodia interpunctella), the European corn borer (Ostrinia furnacalis), European corn borer (Ostrinia nubilaris), Japanese medlars such as Hydara noidai (Hellula undalis), Shibata toga (Pediasia teterrellus), Spodoptera litura, Spodoptera exigua, Pseudoletia separata, Mamestra brassicae, Agrotis ipsilon, Pseianipisvelina, Trichopussia spp.
- Spp. Spp.
- Etc. Suga such as Plutella xylostella, cotton moth (Pectinophora gossypiella), potato moth (Phthorimaea perculella), etc .
- Hirokosukoga such as Koiga (Tineola bisselliella);
- Thysanoptera western flower thrips (Frankliniella occidentalis), Minami thrips (Thrips peri), yellow tea thrips (Scirtothrips dorsalis), green onion thrips (Thrips tabaci), Hirazuhanaazamiuma (Frankliniella intonsa), tobacco thrips (Frankliniella fusca) thrips, etc. Etc .;
- Diptera Housefly (Musca domestica), Culex (Culex popiens pallens), gadfly (Tabanus trigonus), onion maggot (Hylemya antiqua), seedcorn maggot (Hylemya platura), Anopheles sinensis (Anopheles sinensis), rice leafminer (Agromyza oryzae), rice Hydrelia grisela, Chlorops oryzae, Liriomyza trifolii, etc., Dust cubita citrus Coleoptera: beetle, Epilachna vigintioctopunctata (Epilachna vigintioctopunctata), cucurbit leaf beetle (Aulacophora femoralis), Kisujinomihamushi (Phyllotreta striolata), Inedorooimushi (Oulema oryzae), rice weevil (Echinocnemus squameus), rice
- Pterodactyl pests Locusta migratoria, Kelly (Gryllotalpa africana), Oxya yezoensis, Oxya japonica, etc .; Hymenopteran pests: Athalia rosae, Achillymex spp., Fire ant (Solenopsis spp.), Etc .;
- Cockroach eyes pests German cockroaches (Blatella germanica), black cockroaches (Periplaneta fuliginosa), cockroaches (Periplaneta americana), Japanese cockroaches (Peripraneta brunat)
- spider mites such as spider mites (Aculops pelekassi), tick spider mites such as spider mites (Telonychus urticae), citrus spider mites (Panoychus cipri), Oligonycus spp.
- Acarids such as mosquitoes, spider mites, tyrophagus putrescentiae, Dermatophagoides farinae, Dermatophagoides tick , Stag Tsumedani (Cheyletus malaccensis), Minami Tsumedani (Cheyletus moorei) Tsumedani such as such.
- plant pathogens include the following. Cercospora gossypina, Cercospora zekui, Cercospora zeae-maydis, Cercospora sojina, Phakopsora gossypii, Rhizotonia solani, Col. , Penicillium spp. Fusarium spp. , Tricoderma spp. Thielaviopsis spp. Rhizopus spp. Mucor spp. Corticium spp. , Puma spp. Diplodia spp. , Verticillium spp. , Puccinia spp. , Mycosphaerella spp. , Phytophthora spp.
- Phythophthora sojae Phytophthora nicotianae var. Nicotianae, Phytophthora infestans, Phytophthora erythropeptica, etc.
- Phythium spp. Pythium debaryanum, Pythium sylvaticum, Pythium gramicola, Pythium irregulare, Pythium ultimum, etc.
- Microsphaera diffusa Diaporthephalum. sojae, Septoria glycines, Phakopsora pachyrhizi, Sclerotinia sclerotiorum, Elsinoe glyphinees, Ustilago Mayoris, Cochliobolus heterostros. .
- weeds examples include the following. Nettle weeds: Ultica urens Polygonaceae weeds: wild buckwheat (Polygonum convolvulus), Sanaetade (Polygonum lapathifolium), the United States smartweed (Polygonum pensylvanicum), Harutade (Polygonum persicaria), knotweed (Polygonum longisetum), Polygonum aviculare (Polygonum aviculare), Haimichiyanagi (Polygonum arenastrum), Japanese knotweed ( Polygonum cuspidatum), Rumex japonicus, Rumex crispus, Rumex obtusifolius, Rumex acetosa Physalis Weed: Physalis (Portulaca oleracea) Weeping weeds: Stellaria media, Cerastium holosteoides, Cerastium glomeratum, Spergula arvensis, Silene gallic Pomegranate family weed
- Leguminous weeds Aeschynomene indica, zigzag joint vetch (Aeschyomene rudis), American horned um (Sesbania exaltata), Ebisu (Cesia obtusifolia), tuna White clover (Trifolium repens), Kudu (Pueraria lobata), Caladium pea (Vicia angustifolia), Raccoon dog (Indigofera hirsuta), Indigofera tolxylene (Indigofera tolxylene) nsis), wild cowpea (Vigna sinensis) Oxalis family: Oxalis cornicula, Oxalis tricica, Oxalis oxyptera Auricularia Weeds: American Fluor (Geranium carolinense), Dutch Fluor (Erodium ciculatum) Euphorbiaceae weeds: spurge (Euphorbia helioscopia), Euphorbia nutans
- Convolvulaceae weeds morning glory (Ipomoea nil), American morning glory (Ipomoea hederacea), Ipomoea purpurea (Ipomoea purpurea), tall American morning glory (. Ipomoea hederacea var integriuscula), beans morning glory (Ipomoea lacunosa), Hoshiasagao (Ipomoea triloba), Noasagao ( Ipomoea acuminata), Ipomoea hedefifolia, Ibarumou (Ipomoea coccinea), Ipomoea quamoclit, Ipomoea olmoia (Ipomoea aporia) a aristolochiafolia), Maple bus morning glory (Ipomoea cairica), field bindweed (Convolvulus arvensis), Kohirugao (Calystegia hederacea), morning glory (Calystegia
- Solanum weeds Datura stramonium, Solanum nigrum, Solanum americanum, Solanum pylori (Solanum ptycanthum), Solanum ptycanum Solanum aculeatissimum), wild tomato (Solanum sisymbriifolium), walnut bean (Solanum carolinense), Physalis angulata, Physalis sublabra sen, smooth ground cherry (Physalis sublabra sen) Li (Nicandra physaloides) Weeping weeds: Verasica hederaefolia, Veronica persica, Veronica arvensis Plantain family: Plantago asiatica
- Asteraceae weeds cocklebur (Xanthium pensylvanicum), Ooonamomi (Xanthium occidentale), wild sunflower (Helianthus annuus), chamomile (Matricaria chamomilla), Inukamitsure (Matricaria perforata), corn marigold (Chrysanthemum segetum), Oroshagiku (Matricaria matricarioides), mugwort (Artemisia princeps), Artemisia vulgaris, Chinese mugwort (Artemisia verlotorum), Solidago altissima , Dandelion (Taraxacum officinale), galinsoga quadriradiata (Galinsoga ciliata), Kogomegiku (Galinsoga parviflora), Senecio vulgaris (Senecio vulgaris), senecioic brasiliensis down cis (Senecio brasiliensis), sen
- Gramineae weeds Echinochloa crus-galli, Enocologia (Setaria viridis), Aquinoaria glaudia (Setaria giraci), American Enocitaliagrass (Setaria giracia) , Jamaican crabgrass (Digitalia horizontalis), Japanese horsetail (Digitaria insularis), Hoshishiba (Eleusine indica), Suzumeka Kataura (Poa annua), Suzumenotepukurusu (Alospecures) s), blackgrass (Alopecurus myosuroides), oats (Avena fatua), sorghum sorghum (Sorghum vulgare), Sorghum violet (Srophum vulgare) , Boumgi (Lolium rigidum), Karasunochahiki (Bromus secalinus), Umanochahiki (Bromus tectorum), Hordeum jubatum, Aegilops cylindrisica, cedaryo, cedaryo
- Cyperus weeds Cyperus microria, Cyperus iria, Cyperus odorundus, Cyperus, Cyperus, Cyperus, Cyperus Cloveraceae weeds: Equisetum arvense, Equisetum palustre, and the like.
- Examples of such harmful nematodes include the following. Meloidogyne incognita, Meloidogyne javanica, Meloidogyne hapla, Meloidogyne arenari, Meloidogyne acronea, Ditylelenchus destructor, Ditylenchus dipsaci, Pratylenchus penetrans, Pratylenchus cffeae, Pratylenchus loosi, Pratylenchus vulnus, Globodera rostochiensis, Globodera pallida, Heterodera glycines, Heterodera shachtoii, Aphelenchoides besseyi, Ap elenchoides ritzemabosi, Aphelenchoides fragarieae, Aphelenchus avenae, Radopholus similis, Tylenchulus semipenetrans, Rotylenchulus reniformis, Burs
- the variation within the species is not particularly limited. That is, those having reduced sensitivity to specific insecticides, fungicides, and herbicides are also included.
- the decrease in sensitivity may be a mutation at the target site (action point mutation), or the sensitivity may be decreased by a factor that is not an action point mutation (non-action point mutation).
- Factors that decrease sensitivity due to non-acting point mutations include increased metabolism, malabsorption, migration failure, and out-of-system excretion.
- Factors that enhance metabolism include those in which the activity of metabolic enzymes such as cytochrome P450 monooxygenase, allyl acylamidase, esterase, and glutathione S-transferase is increased.
- the out-of-system discharge includes transport to the vacuole by ABC transporter.
- Examples of reduced susceptibility of weeds due to action point mutation include, for example, those having any of the following or multiple amino acid substitutions in the ALS gene. Ala122Thr, Ala122Val, Ala122Tyr, Pro197Ser, Pro197His, Pro197Thr, Pro197Arg, Pro197Leu, Pro197Gln, Pro197Ala, Pro197Ile, Ala205Val, Ala205Phe, Asp376Glu, Arg377His, Trp574Leu, Trp574Gly, Trp574Met, Ser653Thr, Ser653Thr, Ser653Asn, Ser635Ile, Gly654Glu, Gly645Asp.
- examples of reduced weed susceptibility due to site-of-action mutations include those with one or more of the following amino acid substitutions in the ACCase gene. Ile1781Leu, Ile1781Val, Ile1781Thr, Trp1999Cys, Trp1999Leu, Ala2004Val, Trp2027Cys, Ile2041Asn, Ile2041Val, Asp2078Gly, Cys2088Arg, Gly2096AlaS, Gly2096AlaS, Gly2096AlaS.
- examples of the reduction in the sensitivity of weeds due to the action point mutation include the ⁇ Gly210 in the PPX2L gene and the Arg98Leu mutation in the PPX1 gene.
- Hydrangea having the [Delta] Gly210 mutation in the PPX2L gene, Aspergillus niger, and Ragweed having Arg98Leu in PPX1 are effectively controlled.
- examples of the reduction in the sensitivity of weeds due to the action point mutation include amino acid substitution such as Thr102Ile, Pro106Ser, Pro106Ala, Pro106Leu, etc. in the EPSP gene.
- glyphosate-resistant canopy, mud wheat, scallop, squirrel cypress, cybridae, coriander, etc. having one or both of these are effectively controlled.
- examples of reduced weed susceptibility due to action points include those in which the EPSP gene copy number has increased.
- glyphosate-resistant giant blue-headed hawks, cypresses, and brooms with such mutations are effectively controlled.
- the Glyphosate-resistant wormwood wormwood, giant pelargonium and retinophyllum that are involved in ABC transporter are also effectively controlled.
- compound X can be treated with one or more other herbicides, plant growth regulators and safeners.
- the combined use includes mixed use, mixing, and sequential processing, and the order in particular is not particularly limited. Examples of the herbicide, plant growth regulator and safener include the following.
- Herbicides glyphosate and its salts (isopropylammonium salt, ammonium salt, potassium salt, guanidine salt, dimethylamine salt, monoethanolamine salt), MCPA and its salt or ester (dimethylammonium salt, 2-ethylhexyl ester, Isooctyl ester (isooctyl ester), sodium salt), MCPB, mecoprop and salts or esters thereof (dimethylammonium salt, diolamine salt, etazyl ester (1,2-ethanediyl ester), 2-ethylhexyl ester , Isooctyl ester (isooctyl ester), methyl ester, potassium salt, sodium salt, trolamine salt), mecoprop-P and its Or ester (dimethylammonium salt, 2-ethylhexyl ester, isobutyl salt, potassium salt), dicloprop and its salt or ester (
- Plant growth regulators hymexazole, paclobutrazol, uniconazole, uniconazole-P, inabenfide, prohexadione-cium Propene (1-methylcyclopropene) and trinexapac.
- Safeners Benoxacor, cloquintoset, cloquintocet-mexyl, cyometrinil, cyprosulfamide (dipromide), dichlormid (di) Dietholate, fenchlorazole, fenchlorazole-ethyl, fenchlorim, flurazole, floxofenim, flilazole adifen), isoxadifen-ethyl (isoxadifen-ethyl), mefenpyr (mefenpyr), mefenpyr-diethyl (mefenpyr-diethyl), Mefeneto (mephenate), naphthalate Rick polyanhydride (naphthalic anhydride) and oxabetrinil (oxabetrinil).
- herbicides that can be used in combination with compound X include glyphosate potassium salt, glyphosate guanidine salt, glyphosate dimethylamine salt, glyphosate monoethanolamine salt, glufosinate ammonium salt, glyphosate isopropylammonium salt, flumioxazin, Full-microlac pentyl, cretodim, lactofen, S-metolachlor, metribudine, fluphenacet, nicosulfuron, rimsulfuron, acetochlor, mesotrione, isoxaflutol, chlorimuron ethyl, thifensulfuron methyl, chloranthram methyl, Imazetapyr ammonium salt and metribuzin are preferred.
- a safener that can be used in combination with Compound X, cyprosulfamide, benoxacol, dichlormide, and flirazole are particularly preferable.
- the ratio to compound X is usually in the range of 0.01 to 1000 times by weight, preferably 0.1 to 100 times, more preferably 1 to 10 times. is there.
- examples of the compound B that is used for the foliage treatment of crops are listed below, but are not limited thereto.
- plant nutritional management in general crop cultivation can be performed.
- the fertilization system may be based on Precision Agricultural or uniform practices.
- nitrogen-fixing bacteria and mycorrhizal fungi can be inoculated in combination with the seed treatment of compound group A.
- the evaluation of the phytopathogenic fungi control efficacy is that the symptom caused by the phytopathogenic fungus at the time of the survey is not different from that of the untreated or is almost the same as “0”, and the symptom caused by the phytopathogenic fungus is completely or A value that is hardly seen is classified as “100” and is divided into 0 to 100.
- herbicidal efficacy The herbicidal efficacy was evaluated as “0” when the weeding or growing state of the test weeds at the time of the survey was almost the same as that of the untreated ones. A sample in which budding or growth is completely suppressed is defined as “100” and classified into 0 to 100.
- Drug damage to crops Evaluation of phytotoxicity to crops is ⁇ no harm '' when almost no phytotoxicity is observed, ⁇ small '' when mild phytotoxicity is observed, ⁇ medium '' when moderate phytotoxicity is observed, and severe phytotoxicity The case is indicated by “large”.
- NipsIt (clothianidin 600 g / L, Valent) is treated with soybean (variety RoundupReady2Yield soybean) seeds so that the treatment amount of NipsIt is 206 mL / kg seeds (1.28 liquid ounces / 100 pound seeds).
- Example 2 As in Example 1, NipsIt is treated to soybean seeds.
- the treatment amount of Compound X is 5, 20 or 80 g / ha
- Roundup WeatherMax glyphosate potassium salt 660 g / L, manufactured by Monsanto
- Formulation X is treated with Formulation X and Roundup WeatherMax
- Roundup WeatherMax glyphosate potassium salt 660 g / L, manufactured by Monsanto
- Roundup WeatherMax is treated at the third leaf stage of the main soybean so that the treatment amount is 2.338 L / ha (32 fluid ounces / acre).
- Example 3 As in Example 1, NipsIt is treated with soybean seeds and sown in a field. On the day after sowing, Formulation X is treated so that the treatment amount of Compound X is 5, 20 or 80 g / ha. Roundup WeatherMax (glyphosate potassium salt 660 g / L, manufactured by Monsanto) is treated at the third leaf stage of the main soybean so that the treatment amount is 2.338 L / ha (32 fluid ounces / acre).
- Roundup WeatherMax glyphosate potassium salt 660 g / L, manufactured by Monsanto
- Example 4 As in Example 1, NipsIt is treated with soybean seeds and sown in a field. On the day after sowing, the treatment amount of Compound X is 5, 20 or 80 g / ha, and the roundup WeatherMax (glyphosate potassium salt 660 g / L, manufactured by Monsanto) is 2.338 L / ha (32 fluid ounces / acre). Treat formulation X and Roundup WeatherMax as follows. Roundup WeatherMax (glyphosate potassium salt 660 g / L, manufactured by Monsanto) is treated at the third leaf stage of the main soybean so that the treatment amount is 2.338 L / ha (32 fluid ounces / acre).
- Examples 5-8 In each of Examples 1 to 4, instead of treating Formulation X, the throughput of Compound X was 5, 20 or 80 g / ha, and the throughput of ValorSX (flumioxazine 51%, manufactured by Valent) was 210 g / ha.
- Formulation X and ValorSX are treated as follows.
- Examples 13-24 In each of Examples 1 to 12, instead of NipponIt, INOVATE (clothianidin 160 g / L + metalaxyl 13 g / L + ipconazole 8 g / L, manufactured by Valent) was used, and the throughput of INOVATE was 309 mL / 100 kg seed (4.74 solution Amount ounce / 100 pound seed).
- Examples 25-36 In each of Examples 1 to 12, instead of NipsIt, CruiserMAX Vibrance (thiamethoxam 240 g / L + metalaxyl M36 g / L + fludioxonil 12 g / L + sedaxane 12 g / L, manufactured by Syngenta Co.) was used. Treat to seed (3.22 fl oz / 100 lb seed).
- Examples 37-48 In each of Examples 1-12, instead of treating NipsIt with soybean seeds, the Acceleron system (DX-612 (fluxapiroxad 326 g / L, Monsanto) 31 ml / 100 kg seeds + DX-309 (metalaxyl 313 g / L) Monsanto) 242 ml / 100 kg seed (1.5 fl oz / 100 lb seed) + DX-109 (pyraclostrobin 200 g / L, Monsanto) 242 ml / 100 kg seed (1.5 fl oz / 100 lb) Seed) + IX-104 (Imidacloprid 600 g / L, Monsanto) 515 ml / 100 kg seed (3.2 fl oz / 100 lb seed)).
- DX-612 fluxapiroxad 326 g / L, Monsanto
- DX-309 metalaxyl 313 g
- Examples 49-96 In each of Examples 1 to 48, the foliage treatment is performed so that Compound 1 is treated at 30 g / ha during the soybean flowering period.
- Examples 97-144 In each of Examples 1 to 48, compound 1 and tebuconazole are treated with foliage at the soybean flowering stage so that the respective treatment amounts are 30 g / ha and 150 / ha.
- Examples 145-288 In each of Examples 1 to 144, instead of treating Roundup WeatherMax (glyphosate potassium salt 660 g / L, manufactured by Monsanto) at the third leaf stage of soybean main leaves, the treatment amount of Compound X was 5, 20 or 80 g / ha, Roundup WeatherMax The formulation X and RoundweatherMax are processed so that the throughput of is 2.338 L / ha (32 fluid ounces / acre).
- Roundup WeatherMax glyphosate potassium salt 660 g / L, manufactured by Monsanto
- Examples 289-576 In each of Examples 1 to 288, instead of the soybean main leaf three leaf stage, the soybean main leaf six leaf stage is treated.
- Examples 577 to 1152 In each of Examples 1 to 576, corn seed or cotton seed is used instead of soybean seed.
- the pest control method of the present invention can efficiently control pests in the crop cultivation area.
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Abstract
Description
本発明は、以下のものを含む。
[2] 農作物の栽培地における有害生物の防除方法であって、
(1)農作物種子に、化合物群Aより選択される1種以上の化合物を処理する工程、
(2)前記工程で得られた農作物種子を播種する前、播種すると同時、および/または播種した後に、エチル[3-[2-クロロ-4-フルオロ-5-(1-メチル-6-トリフルオロメチル-2,4-ジオキソ-1,2,3,4-テトラヒドロピリミジン-3-イル)フェノキシ]-2-ピリジルオキシ]アセテートを農作物の栽培地に処理する工程、ならびに
(3)農作物の生育期に、化合物群Bより選択される1種以上の化合物を農作物に茎葉処理する工程
を含む、有害生物の防除方法。
化合物群A:ネオニコチノイド系化合物、ジアミド系化合物、カーバメート系化合物、有機リン系化合物、生物系殺線虫剤化合物、その他の殺虫剤化合物および殺線虫剤化合物、ならびにアゾール系化合物、ストロビルリン系化合物、メタラキシル系化合物、SDHI化合物、その他の殺菌剤化合物および植物生長制御剤から成る群。
化合物群B:ストロビルリン系化合物、アゾール系化合物、SDHI化合物、その他の殺菌剤化合物、ピレスロイド系化合物、ベンゾイルフェニルウレア化合物、有機リン系殺虫剤化合物、ネオニコチノイド系化合物およびジアミド系化合物から成る群。
[3] 化合物群Aより選択される1種以上の化合物が、以下の化合物から成る群より選択される化合物である[2]記載の防除方法。
ネオニコチノイド系化合物:クロチアニジン、チアメトキサム、イミダクロプリド、ジノテフラン、ニテンピラム、トリフルメゾピリム、ジクロロメゾチアズ、スルホキサフロール、フルピラジフロン、アセタミプリドおよびチアクロプリド
ジアミド系化合物:フルベンジアミド、クロラントラニリプロール、シアントラニリプロール、シクラニリプロール、ブロフラニリド、シハロジアミドおよびテトラニリプロール
カーバメート系化合物:アルジカルブ、オキサミル、チオジカルブ、カルボフラン、カルボスルファンおよびジメトエート
有機リン系化合物:フェナミホス、イミシアフォス、フェンスルホチオン、テルブホス、ホスチアゼート、ホスホカルブ、ジクロフェンチオン、イサミドホス、イサゾホス、エトプロホス、カズサホス、クロルピリホス、ヘテロホス、メカルホン、ホレート、チオナジン、トリアゾホス、ジアミダホス、ホスチエタンおよびホスファミドン
生物系殺線虫剤化合物:Harpin Protein、Pasteuria nishizawae、Pasteuria penetrans、Pasteuria usage、Myrothecium verrucaria、Burkholderia cepacia、Bacillus、chitonosporus、Paecilomyces lilacinus、Bacillus amyloliquefaciens、Bacillus firmus、Bacillus subtilis、Bacillus pumulus、Trichoderma harzianum、Hirsutella rhossiliensis、Hirsutella minnesotensis、Verticillium chlamydosporumおよびArthrobotrys dactyloides
その他の殺虫剤化合物および殺線虫剤化合物:フィプロニル、エチプロール、ベータシフルトリン、テフルトリン、クロルピリホス、アバメクチン、スピロテトラマト、チオキサザフェン、フルアザインドリジン、フルエンスルホンおよびフルキサメタミド
アゾール系化合物:アザコナゾール、ビテルタノール、ブロムコナゾール、シプロコナゾール、ジフェノコナゾール、ジニコナゾール、エポキシコナゾール、フェンブコナゾール、フルキンコナゾール、フルシラゾール、フルトリアホール、ヘキサコナゾール、イミベンコナゾール、イプコナゾール、メトコナゾール、ミクロブタニル、ペンコナゾール、プロピコナゾール、プロチオコナゾール、シメコナゾール、テブコナゾール、テトラコナゾール、トリアジメノール、トリチコナゾール、フェナリモール、ヌアリモール、ピリフェノックス、イマザリル、オキシポコナゾール-フマレート、ペフラゾエート、プロクロラズ、トリフルミゾール、イプフェントリフルコナゾールおよびメフェントリフルコナゾール
ストロビルリン系化合物:クレソキシム-メチル、アゾキシストロビン、トリフロキシストロビン、フルオキサストロビン、ピコキシストロビン、ピラクロストロビン、ジモキシストロビン、ピリベンカルブ、メトミノストロビン、オリサストロビンおよびマンデストロビン
メタラキシル系化合物:メタラキシルおよびメタラキシル-M
SDHI化合物:セダキサン、ペンフルフェン、カルボキシン、ボスカリド、フラメトピル、フルトラニル、フルキサピロキサド、イソピラザム、フルオピラム、チフルザミド、イソフェタミド、ピラジフルミド、ピジフルメトフェン、N-(7-フルオロ-1,1,3-トリメチルインダン-4-イル)-1-メチル-3-ジフルオロメチルピラゾール-4-カルボン酸アミド(ラセミ体またはエナンチオマー、R体のエナンチオマーとS体のエナンチオマーの任意の割合での混合物を含む)、N-(1,1,3-トリメチルインダン-4-イル)-1-メチル-3-ジフルオロメチルピラゾール-4-カルボン酸アミド(ラセミ体またはエナンチオマー、R体のエナンチオマーとS体のエナンチオマーの任意の割合での混合物を含む)
その他の殺菌剤化合物:トルクロホスメチル、チラム、キャプタン、カルベンダジム、チオファネートメチル、マンコゼブ、チアベンダゾール、イソチアニル、エタボキサム、ピカルブトラゾクス、オキサチアピプロリンおよびトリアゾキシド
植物生長制御剤:エテホン、クロルメコート、メピコートおよび4-オキソ-4-(2-フェニルエチル)アミノ酪酸
[4] 化合物群Bより選択される1種以上の化合物が、以下の化合物から成る群より選択される化合物である[2]または[3]記載の防除方法。
ストロビルリン系化合物:ピラクロストロビン、アゾキシストロビン、マンデストロビン、トリフロキシストロビンおよびピコキシストロビン
アゾール系化合物:プロチオコナゾール、エポキシコナゾール、テブコナゾール、シプロコナゾール、プロピコナゾール、メトコナゾール、ブロムコナゾール、テトラコナゾール、トリチコナゾール、イプフェントリフルコナゾールおよびメフェントリフルコナゾール
SDHI化合物:ベンゾビンジフルピル、ビキサフェン、フルキサピロキサド、N-(7-フルオロ-1,1,3-トリメチルインダン-4-イル)-1-メチル-3-ジフルオロメチルピラゾール-4-カルボン酸アミド(ラセミ体またはエナンチオマー、R体のエナンチオマーとS体のエナンチオマーの任意の割合での混合物を含む)およびN-(1,1,3-トリメチルインダン-4-イル)-1-メチル-3-ジフルオロメチルピラゾール-4-カルボン酸アミド(ラセミ体またはエナンチオマー、R体のエナンチオマーとS体のエナンチオマーの任意の割合での混合物を含む)
その他の殺菌剤化合物:トルクロホスメチルおよびエタボキサム
ピレスロイド系化合物:ビフェントリン、ラムダシハロトリン、ガンマシハロトリン、シペルメトリン、フェンプロパトリン、エトフェンプロックス、シラフルオフェンおよびエスフェンバレレート
ベンゾイルフェニルウレア化合物:テフルベンズロンおよびトリフルムロン
有機リン系殺虫剤化合物:アセフェートおよびメソミル
ネオニコチノイド系化合物:イミダクロプリド、クロチアニジン、チアメトキサム、スルホキサフロール、フルピラジフロン、トリフルメゾピルムおよびジクロロメゾチアズ
ジアミド系化合物:フルベンジアミド、クロラントラニリプロール、シアントラニリプロール、ブロフラニリド、テトラニリプロールおよびシハロジアミド
[5] 農作物種子を播種する前に、エチル[3-[2-クロロ-4-フルオロ-5-(1-メチル-6-トリフルオロメチル-2,4-ジオキソ-1,2,3,4-テトラヒドロピリミジン-3-イル)フェノキシ]-2-ピリジルオキシ]アセテートを農作物の栽培地に処理する、[1]または[2]記載の防除方法。
[6] 農作物種子を播種すると同時に、エチル[3-[2-クロロ-4-フルオロ-5-(1-メチル-6-トリフルオロメチル-2,4-ジオキソ-1,2,3,4-テトラヒドロピリミジン-3-イル)フェノキシ]-2-ピリジルオキシ]アセテートを農作物の栽培地に処理する、[1]または[2]記載の防除方法。
[7] 農作物種子を播種した後に、エチル[3-[2-クロロ-4-フルオロ-5-(1-メチル-6-トリフルオロメチル-2,4-ジオキソ-1,2,3,4-テトラヒドロピリミジン-3-イル)フェノキシ]-2-ピリジルオキシ]アセテートを農作物の栽培地に処理する、[1]または[2]記載の防除方法。
[8] 有害生物が、雑草および/または節足動物および/または植物病原菌である[2]~[7]のいずれかに記載の防除方法。
[9] 有害生物が、雑草である[2]~[7]のいずれかに記載の防除方法。
[10] 農作物が、ダイズ、トウモロコシ、ワタ、ナタネ、イネ、コムギ、オオムギ、サトウキビ、サトウダイコン、ソルガムおよびヒマワリから成る群より選択される農作物である[2]~[9]のいずれかに記載の防除方法。
(1)農作物種子に、前記化合物群Aより選択される1種以上の化合物を処理する工程(以下、工程(1)と記すことがある)、
(2)前記工程で得られた農作物種子を播種する前、播種すると同時、および/または播種した後に、化合物Xを農作物の栽培地に処理する工程(以下、工程(2)と記すことがある)、ならびに
(3)農作物の生育期に、前記化合物群Bより選択される1種以上の化合物を農作物に茎葉処理する工程(以下、工程(3)と記すことがある)
を含む。
かかる品種の植物には、フルミオキサジン等のPPO阻害剤、イソキサフルトール等の4-ヒドロキシフェニルピルビン酸ジオキシゲナーゼ阻害剤、イマゼタピル、チフェンスルフロンメチル等のアセト乳酸合成酵素(以後ALSと略する)阻害剤、グリホサート等の5-エノールピルビルシキミ酸-3-リン酸シンターゼ(以後EPSPと略する)阻害剤、グルホシネート等のグルタミン合成酵素阻害剤、オーキシン型除草剤、セトキシジム等のアセチルCoAカルボキシラーゼ(以降ACCaseと略する)阻害剤、ブロモキシニル等のPSII阻害剤に対する耐性が、古典的な育種法、ゲノム編集、または遺伝子組換え技術により付与された植物も含まれる。
また、遺伝子組換え技術により耐性を付与された植物の例として、グリホサート耐性のダイズ、トウモロコシ、ワタ、ナタネがあり、RoundupReady(登録商標)、Gly-Tol(登録商標)等の商品名で既に販売されている。同様に遺伝子組換え技術によるグルホシネート耐性のダイズがあり、LibertyLink(登録商標)等の商品名で既に販売されている。グリホサートおよびALS阻害剤の両方に耐性であるOptimum GAT(登録商標)の商品名のダイズ、トウモロコシ品種がある。同様に遺伝子組換え技術によるイミダゾリノン系ALS阻害剤耐性のダイズがあり、Cultivanceの名前で開発されている。
アリルオキシアルカノエートジオキゲナーゼ(aryloxyalkanoate dioxygenase)をコードする遺伝子を導入し、キザロホップ、ハロキシホップ、フルアジホップ、ジクロホップ、フェノキサプロップ、メタミホップ、シハロホップ、クロジナホップ等のアリールオキシフェノキシ系除草剤に耐性となる作物を作出することができ、Enlist(登録商標)の商品名のダイズ品種がある。
この様な遺伝子組換え植物で発現される毒素として、バチルス・セレウス(Bacillus cereus)やバチルス・ポピリエ(Bacillus popilliae)由来の殺虫性タンパク;バチルス・チューリンゲンシス(Bacillus thuringiensis)由来のCry1Ab、Cry1Ac、Cry1F、Cry1Fa2、Cry2Ab、Cry3A、Cry3Bb1またはCry9Cなどのδ-エンドトキシン、VIP1、VIP2、VIP3またはVIP3Aなどの殺虫タンパク;線虫由来の殺虫タンパク;さそり毒素、クモ毒素、ハチ毒素または昆虫特異的神経毒素等動物によって産生される毒素;糸状菌類毒素;植物レクチン;アグルチニン;トリプシン阻害剤、セリンプロテアーゼ阻害剤、パタチン、シスタチン、パパイン阻害剤等のプロテアーゼ阻害剤;リシン、トウモロコシ-RIP、アブリン、ルフィン、サポリン、ブリオジン等のリボゾーム不活性化タンパク(RIP);3-ヒドロキシステロイドオキシダーゼ、エクジステロイド-UDP-グルコシルトランスフェラーゼ、コレステロールオキシダーゼ等のステロイド代謝酵素;エクダイソン阻害剤;HMG-CoAリダクターゼ;ナトリウムチャネル、カルシウムチャネル阻害剤等のイオンチャネル阻害剤;幼若ホルモンエステラーゼ;利尿ホルモン受容体;スチルベンシンターゼ;ビベンジルシンターゼ;キチナーゼ;グルカナーゼ等が挙げられる。
また、この様な遺伝子組換え作物で発現される毒素として、Cry1Ab、Cry1Ac、Cry1F、Cry1Fa2、Cry2Ab、Cry3A、Cry3Bb1、 Cry9C、Cry34AbまたはCry35Abなどのδ-エンドトキシンタンパク、VIP1、VIP2、VIP3またはVIP3Aなどの殺虫タンパクのハイブリッド毒素、一部を欠損した毒素、修飾された毒素も含まれる。ハイブリッド毒素は、組換え技術を用いて、これらタンパクの異なるドメインの新しい組合せによって作り出される。一部を欠損した毒素としては、アミノ酸配列の一部を欠損したCry1Abが知られている。修飾された毒素は、天然型の毒素のアミノ酸の1つまたは複数が置換されている。これら毒素の例およびこれら毒素を合成する事ができる組換え植物は、EP-A-0374753、WO93/07278、WO95/34656、EP-A-0427529、EP-A-451878、WO03/052073等に記載されている。これらの組換え植物に含まれる毒素は、特に、甲虫目害虫、双翅目害虫、鱗翅目害虫への耐性を植物へ付与する。
また、1つ若しくは複数の殺虫性の害虫抵抗性遺伝子を含み、1つまたは複数の毒素を発現する遺伝子組換え植物は既に知られており、いくつかのものは市販されている。これら遺伝子組換え植物の例として、Intacta(登録商標)等が挙げられる。本発明に用いられる植物としては、例えばRag1(Resistance Aphid Gene 1)遺伝子が導入されたダイズ等のアブラムシに対する耐性が付与された植物も挙げられる。
また、本発明に用いられる植物としては、線虫に対する耐性が、古典的育種法または遺伝子組換え技術を用いて付与されたものも含まれる。線虫耐性を与える遺伝子組換え技術としてはRNAiが挙げられる。
上記の植物は、遺伝子組換え技術を用いて、油糧成分改質やアミノ酸含量増強形質などの有用形質を付与した植物も含む。例として、VISTIVE(登録商標)(リノレン含量を低減させた低リノレンダイズ)等が挙げられる。また、遺伝子組み換え技術を用いて、環境ストレス耐性を付与した植物も含む。例として、DroughtGard(登録商標)等が挙げられる。
さらに、上記の古典的な除草剤形質または除草剤耐性遺伝子、殺虫性害虫抵抗性遺伝子、抗病原性物質産生遺伝子、油糧成分改質やアミノ酸含量増強形質などの有用形質について、これらを複数組み合わせたスタック品種も含まれる。遺伝子組み換えに変えてゲノム編集の技術を用いたものも含まれる。
クロチアニジン(clothianidin)、イミダクロプリド(imidacloprid)、ニテンピラム(nitenpyram)、アセタミプリド(acetamiprid)、チアメトキサム(thiamethoxam)、フルピラジフロン(flupyradifurone)、スルホキサフロール(sulfoxaflor)、トリフルメゾピリム(triflumezopyrim)、ジクロロメゾチアズ(dicloromezotiaz)、チアクロプリド(thiacloprid)およびジノテフラン(dinotefuran)。
フルベンジアミド(flubendiamide)、クロラントラニリプロール(chlorantraniliprole)、シアントラニリプロール(cyantraniliprole)、シクラニリプロール(cyclaniliprole)、ブロフラニリド(broflanilide)、テトラニリプロール(tetraniliprole)およびシハロジアミド(cyhalodiamide)。
アルジカルブ(aldicarb)、オキサミル(oxamyl)、チオジカルブ(thiodicarb)、カルボフラン(carbofuran)、カルボスルファン(carbosulfan)およびジメトエート(dimethoate)。
フェナミホス(fenamiphos)、イミシアフォス(imicyafos)、フェンスルホチオン(fensulfothion)、テルブホス(terbufos)、ホスチアゼート(fosthiazate)、ホスホカルブ(phosphocarb)、ジクロフェンチオン(dichlofenthion)、イサミドホス(isamidofos)、イサゾホス(isazophos)、エトプロホス(ethoprophos)、カズサホス(cadusafos)、クロルピリホス(chlorpyrifos)、ヘテロホス(heterofos)、メカルホン(mecarphon)、ホレート(phorate)、チオナジン(thionazin)、トリアゾホス(triazophos)、ジアミダホス(diamidafos)、ホスチエタン(fosthietan)およびホスファミドン(phosphamidon)。
Harpin Protein、Pasteuria nishizawae、Pasteuria penetrans、Pasteuria usage、Myrothecium verrucaria、Burholderia cepacia、Bacillus chitonosporus、Paecilomyces lilacinus、Bacillus amyloliquefaciens、Bacillus firmus、Bacillus subtilis、Bacillus pumulus、Trichoderma harzianum、Hirsutella rhossiliensis、Hirsutella minnesotensis、Verticillium chlamydosporumおよびArthrobotrys dactyloides。
フィプロニル(fipronil)、エチプロール(ethiprole)、ベータシフルトリン(beta-cyfluthrin)、テフルトリン(tefluthrin)、クロルピリホス(chlorpyrifos)、アバメクチン(abamectin)、スピロテトラマト(spirotetramat)、チオキサザフェン(tioxazafen)、フルアザインドリジン(fluazaindolizine)、フルエンスルホン(fluensulfone)およびフルキサメタミド(fluxametamide)。
アザコナゾール(azaconazole)、ビテルタノール(bitertanol)、ブロムコナゾール(bromuconazole)、シプロコナゾール(cyproconazole)、ジフェノコナゾール(difenoconazole)、ジニコナゾール(diniconazole)、エポキシコナゾール(epoxyconazole)、フェンブコナゾール(fenbuconazole)、フルキンコナゾール(fluquinconazole)、フルシラゾール(flusilazole)、フルトリアホール(flutriafol)、ヘキサコナゾール(hexaconazole)、イミベンコナゾール(imibenconazole)、イプコナゾール(ipconazole)、メトコナゾール(metconazole)、ミクロブタニル(myclobutanil)、ペンコナゾール(penconazole)、プロピコナゾール(propiconazole)、プロチオコナゾール(prothioconazole)、シメコナゾール(simeconazole)、テブコナゾール(tebuconazole)、テトラコナゾール(tetraconazole)、トリアジメノール(triadimenol)、トリチコナゾール(triticonazole)、フェナリモール(fenarimol)、ヌアリモール(nuarimol)、ピリフェノックス(pyrifenox)、イマザリル(imazalil)、オキシポコナゾール-フマレート(oxpoconazole fumarate)、ペフラゾエート(pefurazoate)、プロクロラズ(prochloraz)、トリフルミゾール(triflumizole)、イプフェントリフルコナゾール(ipfentrifluconazole)およびメフェントリフルコナゾール(mefentrifluconazole)。
クレソキシム-メチル(kresoxim-methyl)、アゾキシストロビン(azoxystrobin)、トリフロキシストロビン(trifloxystrobin)、フルオキサストロビン(fluoxastrobin)、ピコキシストロビン(picoxystrobin)、ピラクロストロビン(pyraclostrobin)、ジモキシストロビン(dimoxystrobin)、ピリベンカルブ(pyribencarb)、メトミノストロビン(metominostrobin)、オリサストロビン(orysastrobin)およびマンデストロビン(mandestrobin)。
メタラキシル(metalaxyl)およびメタラキシル-M(metalaxyl-Mまたはmefenoxam)。
セダキサン(sedaxane)、ペンフルフェン(penflufen)、カルボキシン(carboxin)、ボスカリド(boscalid)、フラメトピル(furametpyr)、フルトラニル(flutolanil)、フルキサピロキサド(fluxapyroxad)、イソピラザム(isopyrazam)、フルオピラム(fluopyram)、イソフェタミド(isofetamid)、ピラジフルミド(pyraziflumid)、ピジフルメトフェン(pydiflumetofen)、N-(7-フルオロ-1,1,3-トリメチルインダン-4-イル)-1-メチル-3-ジフルオロメチルピラゾール-4-カルボン酸アミド(ラセミ体またはエナンチオマー、R体のエナンチオマーとS体のエナンチオマーの任意の割合での混合物を含み、化合物のエナンチオマー比が、R体/S体で80/20以上のR体リッチなものを以下、F9990と記すことがある)、N-(1,1,3-トリメチルインダン-4-イル)-1-メチル-3-ジフルオロメチルピラゾール-4-カルボン酸アミド(ラセミ体またはエナンチオマー、R体のエナンチオマーとS体のエナンチオマーの任意の割合での混合物を含み、化合物のエナンチオマー比が、R体/S体で80/20以上のR体リッチなものを以下では化合物1と記すことがある)、およびチフルザミド(thifluzamide)。
エテホン(ethephon)、クロルメコート(chlormequat-chloride)、メピコート(mepiquat-chloride)、4-オキソ-4-(2-フェニルエチル)アミノ酪酸(以下、化合物2と記すことがある)。
トルクロホスメチル(tolclophos-methyl)、チラム(thiram)、キャプタン(captan)、カルベンダジム(carbendazim)、チオファネートメチル(thiophanate-methyl)、マンコゼブ(mancozeb)、チアベンダゾール(thiabendazole)、イソチアニル(isotianil)、トリアゾキシド(triazoxide)、ピカルブトラゾクス(picarbutrazox)、およびオキサチアピプロリン(oxathiapiprolin)。
ピラクロストロビン、アゾキシストロビン、マンデストロビン、トリフロキシストロビンおよびピコキシストロビン。
プロチオコナゾール、エポキシコナゾール、テブコナゾール、シプロコナゾール、プロピコナゾール、メトコナゾール、ブロムコナゾール、テトラコナゾール、トリチコナゾール、イプフェントリフルコナゾールおよびメフェントリフルコナゾール。
ベンゾビンジフルピル、ビキサフェン、フルキサピロキサド、F9990および化合物1。
トルクロホスメチルおよびエタボキサム。
ビフェントリン、ラムダシハロトリン、ガンマシハロトリン、シペルメトリン、フェンプロパトリン、エトフェンプロックス、シラフルオフェンおよびエスフェンバレレート。
テフルベンズロンおよびトリフルムロン。
アセフェートおよびメソミル。
イミダクロプリド、クロチアニジン、チアメトキサム、スルホキサフロール、フルピラジフロン、トリフルメゾピルムおよびジクロロメゾチアズ。
フルベンジアミド、クロラントラニリプロール、シアントラニリプロール、ブロフラニリド、テトラニリプロールおよびシハロジアミド。
農作物の栽培地に化合物Xを処理する方法としては、例えば、化合物Xを農作物の栽培地の土壌に散布する方法および化合物Xを雑草発生後の雑草に散布する方法が挙げられる。
化合物Xの処理量は、農作物の栽培地10000m2あたり通常1~1000g、好ましくは2~500g、より好ましくは5~200、さらに好ましくは10~100gの範囲である。なお、農作物の栽培地に化合物Xを処理する工程において、アジュバントを混合して化合物Xを処理してもよい。アジュバントの種類は、特に限定されないが、Agri-Dex、MSO等のオイル系、Induce等のノニオン系(ポリオキシエチレンのエステルまたはエーテル)、グラミンS等のアニオン系(置換スルホン酸塩)、Genamin T 200BM等のカチオン系(ポリオキシエチレンアミン)、Silwett L77等の有機シリコン系が挙げられる。
農作物の栽培地に化合物Xを処理する際の散布液のpHや硬度は特に限定されないが、通常pH5-9の範囲であり、硬度は通常0~500の範囲である。
農作物の栽培地に化合物Xを処理する時間帯は特に限定されないが、通常午前5時-午後9時の範囲であり、光量子束密度は通常10~2500マイクロモル/平米/秒である。
農作物種子の播種前に化合物Xを処理する場合は、播種前50日前~播種直前、好ましくは播種前30日~播種直前、より好ましくは播種前20日~播種直前、さらに好ましくは播種前10日~播種直前に化合物Xが処理される。
農作物種子の播種後に化合物Xを処理する場合は、通常播種直後~開花前に化合物Xが処理される。より好ましくは、播種直後~出芽前の間と、農作物の本葉1~6葉期の間である。農作物の本葉1~6葉期に化合物Xが茎葉処理される場合は、上記化合物群Bより選択される1種以上の化合物(以下、化合物Bと記す)と混用することにより、工程(3)を同時に実施してもよいし順次実施してもよい。順次実施する場合、順番は特に限定されない。
農作物種子の播種と同時に化合物Xを処理する場合とは、播種機と散布機が一体化している場合である。
半翅目害虫:ヒメトビウンカ(Laodelphax striatellus)、トビイロウンカ(Nilaparvata lugens)、セジロウンカ(Sogatella furcifera)等のウンカ類、ツマグロヨコバイ(Nephotettix cincticeps)、タイワンツマグロヨコバイ(Nephotettix virescens)等のヨコバイ類、ワタアブラムシ(Aphis gossypii)、モモアカアブラムシ(Myzus persicae)、ダイコンアブラムシ(Brevicoryne brassicae)、チューリップヒゲナガアブラムシ(Macrosiphum euphorbiae)、ジャガイモヒゲナガアブラムシ(Aulacorthum solani)、ムギクビレアブラムシ(Rhopalosiphum padi)、ミカンクロアブラムシ(Toxoptera citricidus)等のアブラムシ類、アオクサカメムシ(Nezara antennata)、ホソヘリカメムシ(Riptortus clavetus)、クモヘリカメムシ(Leptocorisa chinensis)、トゲシラホシカメムシ(Eysarcoris parvus)、クサギカメムシ(Halyomorpha mista)、ターニッシュッドプラントバグ(Lygus lineolaris)等のカメムシ類、オンシツコナジラミ(Trialeurodes vaporariorum)、タバココナジラミ(Bemisia tabaci)、シルバーリーフコナジラミ(Bemisia argentifolii)等のコナジラミ類、アカマルカイガラムシ(Aonidiella aurantii)、サンホーゼカイガラムシ(Comstockaspis perniciosa)、シトラススノースケール(Unaspis citri)、ルビーロウムシ(Ceroplastes rubens)、イセリヤカイガラムシ(Icerya purchasi)等のカイガラムシ類、グンバイムシ類、キジラミ類等;
甲虫目害虫:ニジュウヤホシテントウ(Epilachna vigintioctopunctata)、ウリハムシ(Aulacophora femoralis)、キスジノミハムシ(Phyllotreta striolata)、イネドロオイムシ(Oulema oryzae)、イネゾウムシ(Echinocnemus squameus)、イネミズゾウムシ(Lissorhoptrus oryzophilus)、ワタミゾウムシ(Anthonomus grandis)、アズキゾウムシ(Callosobruchus chinensis)、シバオサゾウムシ(Sphenophorus venatus)、マメコガネ(Popillia japonica)、ドウガネブイブイ(Anomala cuprea)、コーンルートワームの仲間(Diabrotica spp.)、コロラドハムシ(Leptinotarsa decemlineata)、コメツキムシの仲間(Agriotes spp.)、タバコシバンムシ(Lasioderma serricorne)、ヒメマルカツオブシムシ(Anthrenus verbasci)、コクヌストモドキ(Tribolium castaneum)、ヒラタキクイムシ(Lyctus brunneus)、ゴマダラカミキリ(Anoplophora malasiaca)、マツノキクイムシ(Tomicus piniperda)等;
膜翅目害虫:カブラハバチ(Athalia rosae)、ハキリアリ(Acromyrmex spp.)、ファイヤーアント(Solenopsis spp.)等;
Cercospora gossypina、Cercospora kikuchii、Cercospora zeae-maydis、Cercospora sojina、Phakopsora gossypii、Rhizoctonia solani、Colletotrichum gossypii、Peronospora gossypina、Aspergillus spp.、Penicillium spp.、Fusarium spp.、Tricoderma spp.、Thielaviopsis spp.、Rhizopus spp.、Mucor spp.、Corticium spp.、Phoma spp.、Diplodia spp.、Verticillium spp.、Puccinia spp.、Mycosphaerella spp.、Phytophtora spp.(Phytophthora sojae、Phytophthora nicotianae var. nicotianae、Phytophthora infestans、Phytophthora erythroseptica等)、Pythium spp.(Pythium debaryanum、Pythium sylvaticum、 Pythium graminicola、 Pythium irregulare、 Pythium ultimum等)、Microsphaera diffusa、Diaporthe phaseolorum var. sojae、Septoria glycines、Phakopsora pachyrhizi、Sclerotinia sclerotiorum、Elsinoe glycines、Ustilago maydis、Cochliobolus heterostrophus、Gloeocercospora sorghi、Alternaria spp.。
イラクサ科雑草:ヒメイラクサ(Urtica urens)
タデ科雑草:ソバカズラ(Polygonum convolvulus)、サナエタデ(Polygonum lapathifolium)、アメリカサナエタデ(Polygonum pensylvanicum)、ハルタデ(Polygonum persicaria)、イヌタデ(Polygonum longisetum)、ミチヤナギ(Polygonum aviculare)、ハイミチヤナギ(Polygonum arenastrum)、イタドリ(Polygonum cuspidatum)、ギシギシ(Rumex japonicus)、ナガバギシギシ(Rumex crispus)、エゾノギシギシ(Rumex obtusifolius)、スイバ(Rumex acetosa)
スベリヒユ科雑草:スベリヒユ(Portulaca oleracea)
ナデシコ科雑草:ハコベ(Stellaria media)、ミミナグサ(Cerastium holosteoides)、オランダミミナグサ(Cerastium glomeratum)、オオツメクサ(Spergula arvensis)、マンテマ(Silene gallica)
ザクロソウ科雑草:クルマバザクロウソウ(Mollugo verticillata)
アカザ科雑草:シロザ(Chenopodium album)、ケアリタソウ(Chenopodium ambrosioides)、ホウキギ(Kochia scoparia)、ノハラヒジキ(Salsola kali)、アトリプレックス属(Atriplex spp.)
ケシ科雑草:ヒナゲシ(Papaver rhoeas)、アザミゲシ(Argemone mexicana)
アブラナ科雑草:セイヨウノダイコン(Raphanus raphanistrum)、ラディッシュ(Raphanus sativus)、ノハラガラシ(Sinapis arvensis)、ナズナ(Capsella bursa-pastoris)、セイヨウカラシナ(Brassica juncea)、セイヨウアブラナ(Brassica campestris)、ヒメクジラグサ(Descurainia pinnata)、スカシタゴボウ(Rorippa islandica)、キレハイヌガラシ(Rorippa sylvestris)、グンバイナズナ(Thlaspi arvense)、ミヤガラシ(Myagrum rugosum)、マメグンバイナズナ(Lepidium virginicum)、カラクサナズナ(Coronopus didymus)
フウチョウソウ科雑草:クレオメ アフィニス(Cleome affinis)
カタバミ科:カタバミ(Oxalis corniculata)、オッタチカタバミ(Oxalis strica)、オキザリス オキシプテラ(Oxalis oxyptera)
フウロソウ科雑草:アメリカフウロ(Geranium carolinense)、オランダフウロ(Erodium cicutarium)
トウダイグサ科雑草:トウダイグサ(Euphorbia helioscopia)、オオニシキソウ(Euphorbia maculata)、コニシキソウ(Euphorbia humistrata)、ハギクソウ(Euphorbia esula)、ショウジョウソウ(Euphorbia heterophylla)、ヒソップリーフサンドマット(Euphorbia brasiliensis)、エノキグサ(Acalypha australis)、トロピッククロトン(Croton glandulosus)、ロブドクロトン(Croton lobatus)、ブラジルコミカンソウ(Phyllanthus corcovadensis)、トウゴマ(Ricinus communis)
アオギリ科雑草:コバンバノキ(Waltheria indica)
スミレ科雑草:マキバスミレ(Viola arvensis)、ワイルドパンジ-(Viola tricolor)
ウリ科雑草:アレチウリ(Sicyos angulatus)、ワイルドキューカンバー(Echinocystis lobata)、野生ニガウリ(Momordica charantia)
ミソハギ科雑草:エゾミソハギ(Lythrum salicaria)
セリ科雑草:チドメグサ(Hydrocotyle sibthorpioides)
ムクロジ科雑草:フウセンカズラ(Cardiospermum halicacabum)
サクラソウ科雑草:アカバナルリハコベ(Anagallis arvensis)
ガガイモ科雑草:オオトウワタ(Asclepias syriaca)、ハニーヴァインミルクウィード(Ampelamus albidus)
アカネ科雑草:キャッチウィードベッドストロー(Galium aparine)、ヤエムグラ(Galium spurium var. echinospermon)、ヒロハフタバムグラ(Spermacoce latifolia)、ブラジルハシカグサモドキ(Richardia brasiliensis)、ウィングドファルスボタンウィード(Borreria alata)
ムラサキ科雑草:ワスレナグサ(Myosotis arvensis)
シソ科雑草:ヒメオドリコソウ(Lamium purpureum)、ホトケノザ(Lamium amplexicaule)、タマザキメハジキ(Leonotis nepetaefolia)、ニオイニガクサ(Hyptis suaveolens)、ヒプティス ロファンタ(Hyptis lophanta)、メハジキ(Leonurus sibiricus)、ヤブチョロギ(Stachys arvensis)
ゴマノハグサ科雑草:フラサバソウ(Veronica hederaefolia)、オオイヌノフグリ(Veronica persica)、タチイヌノフグリ(Veronica arvensis)
オオバコ科:オオバコ(Plantago asiatica)
ツユクサ科雑草:ツユクサ(Commelina communis)、マルバツユクサ(Commelina bengharensis)、エレクトデイフラワー(Commelina erecta)
トクサ科雑草:スギナ(Equisetum arvense)、イヌスギナ(Equisetum palustre)等。
上記除草剤、植物生長調節剤および薬害軽減剤としては、例えば、以下のものが挙げられる。
除草剤:グリホサート(glyphosate)およびその塩(イソプロピルアンモニウム塩、アンモニウム塩、カリウム塩、グアニジン塩、ジメチルアミン塩、モノエタノールアミン塩)、MCPAおよびその塩またはエステル(ジメチルアンモニウム塩、2-エチルヘキシルエステル、イソクチルエステル(イソオクチルエステル)、ナトリウム塩)、MCPB、メコクプロップ(mecoprop)およびその塩またはエステル(ジメチルアンモニウム塩、ジオールアミン塩、エタジルエステル(1,2-エタンジイルエステル)、2-エチルヘキシルエステル、イソクチルエステル(イソオクチルエステル)、メチルエステル、カリウム塩、ナトリウム塩、トロールアミン塩)、メコプロップP(mecoprop-P)およびその塩またはエステル(ジメチルアンモニウム塩、2-エチルヘキシルエステル、イソブチル塩、カリウム塩)、ジクロプロップ(dichlorprop)およびその塩またはエステル(ブトチルエステル(2-ブトキシエチルエステル)、ジメチルアンモニウム塩、2-エチルヘキシルエステル、イソクチルエステル、メチルエステル、カリウム塩、ナトリウム塩)、ジクロプロップP(dichlorprop-P)、ジクロプロップPジメチルアンモニウム塩(dichlorprop-P-dimethylammonium)、キンクロラック(quinclorac)、キンメラック(quinmerac)、ブロモキシニル(bromoxynil)、ブロモキシニルオクタノエート(bromoxynil-octanoate)、ジクロベニル(dichlobenil)、メチオゾリン(methiozolin)、アイオキシニル(ioxynil)、アイオキシニルオクタノエート(ioxynil-octanoate)、ジアレート(di-allate)、ブチレート(butylate)、トリアレート(tri-allate)、フェンメディファム(phenmedipham)、クロロプロファム(chlorpropham)、デスメジファム(desmedipham)、アシュラム(asulam)、フェニソファム(phenisopham)、ベンチオカーブ(benthiocarb)、モリネート(molinate)、エスプロカルブ(esprocarb)、ピリブチカルブ(pyributicarb)、プロスルカルブ(prosulfocarb)、オルベンカルブ(orbencarb)、EPTC、ジメピペレート(dimepiperate)、スウェップ(swep)、プロパクロール(propachlor)、メタザクロール(metazachlor)、アラクロール(alachlor)、アセトクロール(acetochlor)、メトラクロール(metolachlor)、S-メトラクロール(S-metolachlor)、ブタクロール(butachlor)、プレチラクロール(pretilachlor)、テニルクロール(thenylchlor)、アミノシクロピラクロール(aminocyclopyrachlor)、アミノシクロピラクロールメチル(aminocyclopyrachlor-methyl)、アミノシクロピラクロールカリウム(aminocyclopyrachlor-potassium)、トリフルラリン(trifluralin)、ペンディメタリン(pendimethalin)、エタフルラリン(ethalfluralin)、ベンフルラリン(benfluralin)、プロジアミン(prodiamine)、シマジン(simazine)、アトラジン(atrazine)、プロパジン(propazine)、シアナジン(cyanazine)、アメトリン(ametryn)、シメトリン(simetryn)、ジメタメトリン(dimethametryn)、プロメトリン(prometryn)、インダジフラム(indaziflam)、トリアジフラム(triaziflam)、メトリブジン(metribuzin)、ヘキサジノン(hexazinone)、テルブメトン(terbumeton)、テルブチラジン(terbuthylazine)、テルブトリン(terbutryn)、トリエタジン(trietazine)、イソキサベン(isoxaben)、ジフルフェニカン(diflufenican)、ジウロン(diuron)、リニュロン(linuron)、メトブロムロン(metobromuron)、メトキスロン(metoxuron)、モノリニュロン(monolinuron)、シデュロン(siduron)、フルオメツロン(fluometuron)、ジフェノクスロン(difenoxuron)、メチルダイムロン(methyl-daimuron)、イソプロツロン(isoproturon)、イソウロン(isouron)、テブチウロン(tebuthiuron)、ベンズチアズロン(benzthiazuron)、メタベンズチアズウロン(methabenzthiazuron)、プロパニル(propanil)、メフェナセット(mefenacet)、クロメプロップ(clomeprop)、ナプロアニリド(naproanilide)、ブロモブチド(bromobutide)、ダイムロン(daimuron)、クミルロン(cumyluron)、ジフルフェンゾピル(diflufenzopyr)、エトベンザニド(etobenzanid)、ベンタゾン(bentazon)、トリジファン(tridiphane)、インダノファン(indanofan)、アミトロール(amitrole)、フェンクロラゾール(fenchlorazole)、クロマゾン(clomazone)、マレイン酸ヒドラジド(maleic hydrazide)、ピリデート(pyridate)、クロリダゾン(chloridazon)、ノルフルラゾン(norflurazon)、ブロマシル(bromacil)、ターバシル(terbacil)、レナシル(lenacil)、オキサジクロメホン(oxaziclomefone)、シンメチリン(cinmethylin)、べンフレセート(benfuresate)、カフェンストロール(cafenstrole)、フルフェナセット(flufenacet)、ピリチオバック(pyrithiobac)、ピリチオバックナトリウム塩(pyrithiobac-sodium)、ピリミノバック(pyriminobac)、ピリミノバックメチル(pyriminobac-methyl)、ビスピリバック(bispyribac)、ビスピリバックナトリウム塩(bispyribac-sodium)、ピリベンゾキシム(pyribenzoxim)、ピリミスルファン(pyrimisulfan)、ピリフタリド(pyriftalid)、トリアファモン(triafamone)、フェントラザミド(fentrazamide)、ジメテナミド(dimethenamid)、ジメテナミドP(dimethenamid-P)、ACN、ジチオピル(dithiopyr)、トリクロピル(triclopyr)およびその塩またはエステル(ブトチルエステル(2-ブトキシエチルエステル)、トリエチルアンモニウム塩)、フルロキシピル(fluroxypyr)、フルロキシピルメプチル(fluroxypyr-meptyl)、チアゾピル(thiazopyr)、アミノピラリド(aminopyralid)およびその塩(カリウム塩、トリイソパノールアンモニウム塩)、クロピラリド(clopyralid)およびその塩(オラミン塩、カリウム塩、トリエチルアンモニウム塩)、ピクロラム(picloram)およびその塩(カリウム塩、トリイソパノールアンモニウム塩)、ダラポン(dalapon)、クロルチアミド(chlorthiamid)、アミドスルフロン(amidosulfuron)、アジムスルフロン(azimsulfuron)、ベンスルフロン(bensulfuron)、ベンスルフロンメチル(bensulfuron-methyl)、クロリムロン(chlorimuron)、クロリムロンエチル(chlorimuron-ethyl)、シクロスルファムロン(cyclosulfamuron)、エトキシスルフロン(ethoxysulfuron)、フラザスルフロン(flazasulfuron)、フルセトスルフロン(flucetosulfuron)、フルピルスルフロン(flupyrsulfuron)、フルピルスルフロンメチルナトリウム(flupyrsulfuron-methyl-sodium)、ホラムスルフロン(foramsulfuron)、ハロスルフロン(halosulfuron)、ハロスルフロンメチル(halosulfuron-methyl)、イマゾスルフロン(imazosulfuron)、メソスルフロン(mesosulfuron)、メソスルフロンメチル(mesosulfuron-methyl)、メタゾスルフロン(metazosulfuron)、ニコスルフロン(nicosulfuron)、オルトスルファムロン(orthosulfamuron)、オキサスルフロン(oxasulfuron)、プリミスルフロン(primisulfuron)、プリミスルフロンメチル(primisulfuron-methyl)、プロピリスルフロン(propyrisulfuron)、ピラゾスルフロン(pyrazosulfuron)、ピラゾスルフロンエチル(pyrazosulfuron-ethyl)、リムスルフロン(rimsulfuron)、スルホメツロン(sulfometuron)、スルホメツロンメチル(sulfometuron-methyl)、スルホスルフロン(sulfosulfuron)、トリフロキシスルフロンナトリウム塩(trifloxysulfuron-sodium)、トリフロキシスルフロン(trifloxysulfuron)、クロルスルフロン(chlorsulfuron)、シノスルフロン(cinosulfuron)、エタメトスルフロン(ethametsulfuron)、エタメトスルフロンメチル(ethametsulfuron-methyl)、ヨードスルフロン(iodosulfuron)、ヨードスルフロンメチルナトリウム(iodosulfuron-methyl-sodium)、イオフェンスルフロン(iofensulfuron)、イオフェンスルフロンナトリウム(iofensulfuron-sodium)、メトスルフロン(metsulfuron)、メトスルフロンメチル(metsulfuron-methyl)、プロスルフロン(prosulfuron)、チフェンスルフロン(thifensulfuron)、チフェンスルフロンメチル(thifensulfuron-methyl)、トリアスルフロン(triasulfuron)、トリベニュロン(tribenuron)、トリベニュロンメチル(tribenuron-methyl)、トリフルスルフロン(triflusulfuron)、トリフルスルフロンメチル(triflusulfuron-methyl)、トリトスルフロン(tritosulfuron)、ピコリナフェン(picolinafen)、ベフルブタミド(beflubutamid)、ノルフルラゾン(norflurazon)、フルリドン(fluridone)、フルロクロリドン(flurochloridone)、フルルタモン(flurtamone)、ベンゾビシクロン(benzobicyclon)、ビシクロピロン(bicyclopyrone)、メソトリオン(mesotrione)、スルコトリオン(sulcotrione)、テフリルトリオン(tefuryltrione)、テンボトリオン(tembotrione)、イソキサクロルトール(isoxachlortole)、イソキサフルトール(isoxaflutole)、ベンゾフェナップ(benzofenap)、ピラスルホトール(pyrasulfotole)、ピラゾリネート(pyrazolynate)、ピラゾキシフェン(pyrazoxyfen
)、トプラメゾン(topramezone)、トルピラレート(tolpyralate)、ランコトリオンナトリウム塩(lancotrione-sodium)、フルポキサム(flupoxam)、アミカルバゾン(amicarbazone)、ベンカルバゾン(bencarbazone)、 フルカルバゾン(flucarbazone)、フルカルバゾンナトリウム塩(flucarbazone-sodium)、イプフェンカルバゾン(ipfencarbazone)、プロポキシカルバゾン(propoxycarbazone)、プロポキシカルバゾンナトリウム塩(propoxycarbazone-sodium)、チエンカルバゾン(thiencarbazone)、チエンカルバゾンメチル(thiencarbazone-methyl)、クロランスラム(cloransulam)、クロランスラムメチル(cloransulam-methyl)、ジクロスラム(diclosulam)、フロラスラム(florasulam)、フルメトスラム(flumetsulam)、メトスラム(metosulam)、ペノキススラム(penoxsulam)、ピロキシスラム(pyroxsulam)、イマザメタベンズ(imazamethabenz)、イマザメタベンズメチル(imazamethabenz-methyl)、イマザモックス(imazamox)、イマザモックスアンモニウム塩(imazamox-ammonium)、イマザピック(imazapic)、イマザピックアンモニウム塩(imazapic-ammonium)、イマザピル(imazapyr)、イマザピルイソプロピルアンモニウム塩(imazapyr-isopropylammonium)、イマザキン(imazaquin)、イマザキンアンモニウム塩(imazaquin-ammonium)、イマゼタピル(imazethapyr)、イマゼタピルアンモニウム塩(imazethapyr-ammonium)、クロジナホップ(clodinafop)、クロジナホッププロパルギル(clodinafop-propargyl)、シハロホップ(cyhalofop)、 シハロホップブチル(cyhalofop-butyl)、ジクロホップ(diclofop)、ジクロホップメチル(diclofop-methyl)、フェノキサプロップ(fenoxaprop)、フェノキサプロップエチル(fenoxaprop-ethyl)、フェノキサプロップP(fenoxaprop-P)、フェノキサプロップPエチル(fenoxaprop-P-ethyl)、フルアジホップ(fluazifop)、フルアジホップブチル(fluazifop-butyl)、フルアジホップP(fluazifop-P)、フルアジホップPブチル(fluazifop-P-butyl)、ハロキシホップ(haloxyfop)、ハロキシホップメチル(haloxyfop-methyl)、ハロキシホップP(haloxyfop-P)、ハロキシホップPメチル(haloxyfop-P-methyl)、メタミホップ(metamifop)、プロパキザホップ(propaquizafop)、キザロホップ(quizalofop)、キザロホップエチル(quizalofop-ethyl)、キザロホップP(quizalofop-P)、キザロホップPエチル(quizalofop-P-ethyl)、アロキシジム(alloxydim)、クレトジム(clethodim)、セトキシジム(sethoxydim)、テプラロキシジム(tepraloxydim)、トラルコキシジム(tralkoxydim)、ピノキサデン(pinoxaden)、フェノキサスルホン(fenoxasulfone)、グルホシネート(glufosinate)、グルホシネートアンモニウム塩(glufosinate-ammonium)、グルホシネートP(glufosinate-P)、グルホシネートPナトリウム塩(glufosinate-P-sodium)、ビアラホス(bialafos)、アニロホス(anilofos)、ベンスリド(bensulide)、ブタミホス(butamifos)、パラコート(paraquat)、パラコートジクロリド(paraquat-dichloride)、ジクワット(diquat)、ジクワットジブロミド(diquat-dibromide)、ハローキシフェン(halauxifen)、ハローキシフェンメチル(halauxifen-methyl)、フロルピローキシフェン(florpyrauxifen)、フロルピローキシフェンベンジル(florpyrauxifen-benzyl)、フルミオキサジン(flumioxazin)、フルミクロラックペンチル(flumiclorac-pentyl)、ホメサフェンナトリウム塩(fomesafen-sodium)、ラクトフェン(lactofen)、サフルフェナシル(saflufenacil)、チアフェナシル(tiafenacil)、トリフルジモキサジン(trifludimoxazin)、アシフルオルフェンナトリウム塩(acifluorfen-sodium)、アクロニフェン(aclonifen)、ビフェノックス(bifenox)、クロメトキシフェン(chlomethoxyfen)、クロルニトロフェン(chlornitrofen)、エトキシフェンエチル(ethoxyfen-ethyl)、フルオロジフェン(fluorodifen)、フルオログリコフェンエチル(fluoroglycofen-ethyl)、フルオロニトロフェン(fluoronitrofen)、ハロサフェン(halosafen)、ニトロフェン(nitrofen)、ニトロフルオルフェン(nitrofluorfen)、オキシフルオルフェン(oxyfluorfen)、シニドンエチル(cinidon-ethyl)、プロフルアゾル(profluazol)、ピラクロニル(pyraclonil)、オキサジアルギル(oxadiargyl)、オキサジアゾン(oxadiazone)、ペントキサゾン(pentoxazone)、フルアゾレート(fluazolate)、ピラフルフェンエチル(pyraflufen-ethyl)、ベンズフェンジゾン(benzfendizone)、ブタフェナシル(butafenacil)、フルチアセットメチル(fluthiacet-methyl)、チジアジミン(thidiazimin)、アザフェニジン(azafenidin)、カルフェントラゾンエチル(carfentrazone-ethyl)、スルフェントラゾン(sulfentrazone)、フルフェンピルエチル(flufenpyr-ethyl)
薬害軽減剤:ベノキサコール(benoxacor)、クロキントセット(cloquintocet)、クロキントセットメクシル(cloquintocet-mexyl)、シオメトリニル(cyometrinil)、シプロスルファミド(cyprosulfamide)、ジクロルミド(dichlormid)、ジシクロノン(dicyclonon)、ジエトレート(dietholate)、フェンクロラゾール(fenchlorazole)、フェンクロラゾールエチル(fenchlorazole-ethyl)、フェンクロリム(fenclorim)、フルラゾール(flurazole)、フルクソフェニム(fluxofenim)、フリラゾール(furilazole)、イソキサジフェン(isoxadifen)、イソキサジフェンエチル(isoxadifen-ethyl)、メフェンピル(mefenpyr)、メフェンピルジエチル(mefenpyr-diethyl)、メフェネート(mephenate)、ナフタリックアンヒドライド(naphthalic anhydride)およびオキサベトリニル(oxabetrinil)。
化合物Xおよびキンメラックの組合せ
化合物Xおよびブロモキシニルの組合せ
化合物Xおよびブロモキシニルオクタノエートの組合せ
化合物Xおよびジクロベニルの組合せ
化合物Xおよびメチオゾリンの組合せ
化合物Xおよびアイオキシニルの組合せ
化合物Xおよびアイオキシニルオクタノエートの組合せ
化合物Xおよびジアレートの組合せ
化合物Xおよびブチレートの組合せ
化合物Xおよびトリアレートの組合せ
化合物Xおよびフェンメディファムの組合せ
化合物Xおよびクロロプロファムの組合せ
化合物Xおよびデスメジファムの組合せ
化合物Xおよびアシュラムの組合せ
化合物Xおよびフェニソファムの組合せ
化合物Xおよびベンチオカーブの組合せ
化合物Xおよびモリネートの組合せ
化合物Xおよびエスプロカルブの組合せ
化合物Xおよびピリブチカルブの組合せ
化合物Xおよびプロスルホカルブの組合せ
化合物Xおよびオルベンカルブの組合せ
化合物XおよびEPTCの組合せ
化合物Xおよびジメピペレートの組合せ
化合物Xおよびスウェップの組合せ
化合物Xおよびプロパクロールの組合せ
化合物Xおよびメタザクロールの組合せ
化合物Xおよびアラクロールの組合せ
化合物Xおよびアセトクロールの組合せ
化合物Xおよびメトラクロールの組合せ
化合物XおよびSメトラクロールの組合せ
化合物Xおよびブタクロールの組合せ
化合物Xおよびプレチラクロールの組合せ
化合物Xおよびテニルクロールの組合せ
化合物Xおよびアミノシクロピラクロールの組合せ
化合物Xおよびアミノシクロピラクロールメチルの組合せ
化合物Xおよびアミノシクロピラクロールカリウムの組合せ
化合物Xおよびトリフルラリンの組合せ
化合物Xおよびペンディメタリンの組合せ
化合物Xおよびエタルフルラリンの組合せ
化合物Xおよびベンフルラリンの組合せ
化合物Xおよびプロジアミンの組合せ
化合物Xおよびシマジンの組合せ
化合物Xおよびアトラジンの組合せ
化合物Xおよびプロパジンの組合せ
化合物Xおよびシアナジンの組合せ
化合物Xおよびアメトリンの組合せ
化合物Xおよびシメトリンの組合せ
化合物Xおよびジメタメトリンの組合せ
化合物Xおよびインダジフラムの組合せ
化合物Xおよびトリアジフラムの組合せ
化合物Xおよびメトリブジンの組合せ
化合物Xおよびヘキサジノンの組合せ
化合物Xおよびテルブメトンの組合せ
化合物Xおよびテルブチラジンの組合せ
化合物Xおよびテルブトリンの組合せ
化合物Xおよびトリエタジンの組合せ
化合物Xおよびイソキサベンの組合せ
化合物Xおよびジフルフェニカンの組合せ
化合物Xおよびジウロンの組合せ
化合物Xおよびリニュロンの組合せ
化合物Xおよびメトブロムロンの組合せ
化合物Xおよびメトキスロンの組合せ
化合物Xおよびモノリニュロンの組合せ
化合物Xおよびシデュロンの組合せ
化合物Xおよびフルオメツロンの組合せ
化合物Xおよびジフェノクスロンの組合せ
化合物Xおよびメチルダイムロンの組合せ
化合物Xおよびイソプロツロンの組合せ
化合物Xおよびイソウロンの組合せ
化合物Xおよびテブチウロンの組合せ
化合物Xおよびベンズチアズロンの組合せ
化合物Xおよびメタベンズチアズロンの組合せ
化合物Xおよびプロパニルの組合せ
化合物Xおよびメフェナセットの組合せ
化合物Xおよびクロメプロップの組合せ
化合物Xおよびナプロアニリドの組合せ
化合物Xおよびブロモブチドの組合せ
化合物Xおよびダイムロンの組合せ
化合物Xおよびクミルロンの組合せ
化合物Xおよびジフルフェンゾピルの組合せ
化合物Xおよびエトベンザニドの組合せ
化合物Xおよびベンタゾンの組合せ
化合物Xおよびトリジファンの組合せ
化合物Xおよびインダノファンの組合せ
化合物Xおよびアミトロールの組合せ
化合物Xおよびフェンクロラゾールエチルの組合せ
化合物Xおよびメフェンピルジエチルの組合せ
化合物Xおよびベノキサコールの組合せ
化合物Xおよびジクロルミドの組合せ
化合物Xおよびクロキントセットメクシルの組合せ
化合物Xおよびシプロスルファミドの組合せ
化合物Xおよびイソキサジフェンエチルの組合せ
化合物Xおよびクロマゾンの組合せ
化合物Xおよびマレイン酸ヒドラジドの組合せ
化合物Xおよびピリデートの組合せ
化合物Xおよびクロリダゾンの組合せ
化合物Xおよびブロマシルの組合せ
化合物Xおよびターバシルの組合せ
化合物Xおよびレナシルの組合せ
化合物Xおよびオキサジクロメホンの組合せ
化合物Xおよびシンメチリンの組合せ
化合物Xおよびベンフレセートの組合せ
化合物Xおよびカフェンストロールの組合せ
化合物Xおよびフルフェナセットの組合せ
化合物Xおよびピリチオバックの組合せ
化合物Xおよびピリチオバックナトリウム塩の組合せ
化合物Xおよびピリミノバックの組合せ
化合物Xおよびピリミノバックメチルの組合せ
化合物Xおよびビスピリバックの組合せ
化合物Xおよびビスピリバックナトリウム塩の組合せ
化合物Xおよびピリベンゾキシムの組合せ
化合物Xおよびピリミスルファンの組合せ
化合物Xおよびピリフタリドの組合せ
化合物Xおよびトリアファモンの組合せ
化合物Xおよびフェントラザミドの組合せ
化合物Xおよびジメテナミドの組合せ
化合物XおよびジメテナミドPの組合せ
化合物XおよびACNの組合せ
化合物Xおよびジチオピルの組合せ
化合物Xおよびトリクロピルの組合せ
化合物Xおよびトリクロピルブトチルの組合せ
化合物Xおよびトリクロピルアンモニウム塩の組合せ
化合物Xおよびフルロキシピルの組合せ
化合物Xおよびフルロキシピルメプチルの組合せ
化合物Xおよびチアゾピルの組合せ
化合物Xおよびアミノピラリドの組合せ
化合物Xおよびアミノピラリドカリウム塩の組合せ
化合物Xおよびアミノピラリドトリイソパノールアンモニウム塩の組合せ
化合物Xおよびクロピラリドオラミン塩の組合せ
化合物Xおよびクロピラリドカリウム塩の組合せ
化合物Xおよびクロピラリドトリエチルアンモニウム塩の組合せ
化合物Xおよびピクロラムカリウム塩の組合せ
化合物Xおよびピクロラムトリイソパノールアンモニウム塩の組合せ
化合物Xおよびダラポンの組合せ
化合物Xおよびクロルチアミドの組合せ
化合物Xおよびアミドスルフロンの組合せ
化合物Xおよびアジムスルフロンの組合せ
化合物Xおよびベンスルフロンメチルの組合せ
化合物Xおよびクロリムロンエチルの組合せ
化合物Xおよびシクロスルファムロンの組合せ
化合物Xおよびエトキシスルフロンの組合せ
化合物Xおよびフラザスルフロンの組合せ
化合物Xおよびフルセトスルフロンの組合せ
化合物Xおよびフルピルスルフロンメチルナトリウムの組合せ
化合物Xおよびホラムスルフロンの組合せ
化合物Xおよびハロスルフロンメチルの組合せ
化合物Xおよびイマゾスルフロンの組合せ
化合物Xおよびメソスルフロンメチルの組合せ
化合物Xおよびメタゾスルフロンの組合せ
化合物Xおよびニコスルフロンの組合せ
化合物Xおよびオルトスルファムロンの組合せ
化合物Xおよびオキサスルフロンの組合せ
化合物Xおよびプリミスルフロンメチルの組合せ
化合物Xおよびプロピリスルフロンの組合せ
化合物Xおよびピラゾスルフロンエチルの組合せ
化合物Xおよびリムスルフロンの組合せ
化合物Xおよびスルホメツロンメチルの組合せ
化合物Xおよびスルホスルフロンの組合せ
化合物Xおよびトリフロキシスルフロンナトリウム塩の組合せ
化合物Xおよびクロルスルフロンの組合せ
化合物Xおよびシノスルフロンの組合せ
化合物Xおよびエタメトスルフロンメチルの組合せ
化合物Xおよびヨードスルフロンメチルナトリウムの組合せ
化合物Xおよびイオフェンスルフロンナトリウムの組合せ
化合物Xおよびメトスルフロンメチルの組合せ
化合物Xおよびプロスルフロンの組合せ
化合物Xおよびチフェンスルフロンメチルの組合せ
化合物Xおよびトリアスルフロンの組合せ
化合物Xおよびトリベニュロンメチルの組合せ
化合物Xおよびトリフルスルフロンメチルの組合せ
化合物Xおよびトリトスルフロンの組合せ
化合物Xおよびピロコリナフェンの組合せ
化合物Xおよびベフルブタミドの組合せ
化合物Xおよびノルフルラゾンの組合せ
化合物Xおよびフルリドンの組合せ
化合物Xおよびフルロクロリドンの組合せ
化合物Xおよびフルルタモンの組合せ
化合物Xおよびベンゾビシクロンの組合せ
化合物Xおよびビシクロピロンの組合せ
化合物Xおよびメソトリオンの組合せ
化合物Xおよびスルコトリオンの組合せ
化合物Xおよびテフリルトリオンの組合せ
化合物Xおよびテンボトリオンの組合せ
化合物Xおよびイソキサクロルトールの組合せ
化合物Xおよびイソキサフルトールの組合せ
化合物Xおよびベンゾフェナップの組合せ
化合物Xおよびピラスルホトールの組合せ
化合物Xおよびピラゾリネートの組合せ
化合物Xおよびピラゾキシフェンの組合せ
化合物Xおよびトプラメゾンの組合せ
化合物Xおよびトルピラレートの組合せ
化合物Xおよびランコトリオンナトリウム塩の組合せ
化合物Xおよびフルポキサムの組合せ
化合物Xおよびアミカルバゾンの組合せ
化合物Xおよびベンカルバゾンの組合せ
化合物Xおよびフルカルバゾンナトリウム塩の組合せ
化合物Xおよびイプフェンカルバゾンの組合せ
化合物Xおよびプロポキシカルバゾンナトリウム塩
化合物Xおよびチエンカルバゾンメチルの組合せ
化合物Xおよびクロランスラムメチルの組合せ
化合物Xおよびジクロスラムの組合せ
化合物Xおよびフロラスラムの組合せ
化合物Xおよびフルメトスラムの組合せ
化合物Xおよびメトスラムの組合せ
化合物Xおよびペノキススラムの組合せ
化合物Xおよびピロキシスラムの組合せ
化合物Xおよびイマザメタベンズメチルの組合せ
化合物Xおよびイマザモックスアンモニウム塩の組合せ
化合物Xおよびイマザピックアンモニウム塩の組合せ
化合物Xおよびイマザピルイソプロピルアンモニウム塩の組合せ
化合物Xおよびイマザキンアンモニウム塩の組合せ
化合物Xおよびイマゼタピルアンモニウム塩の組合せ
化合物Xおよびクロジナホッププロパルギルの組合せ
化合物Xおよびシハロホップブチルの組合せ
化合物Xおよびジクロホップメチルの組合せ
化合物Xおよびフェノキサプロップエチルの組合せ
化合物XおよびフェノキサプロップPエチルの組合せ
化合物Xおよびフルアジホップブチルの組合せ
化合物XおよびフルアジホップPブチルの組合せ
化合物Xおよびハロキシホップメチルの組合せ
化合物XおよびハロキシホップPメチルの組合せ
化合物Xおよびプロパキザホップの組合せ
化合物Xおよびキザロホップエチルの組合せ
化合物XおよびキザロホップPエチルの組合せ
化合物Xおよびアロキシジムの組合せ
化合物Xおよびクレトジムの組合せ
化合物Xおよびセトキシジムの組合せ
化合物Xおよびテプラロキシジムの組合せ
化合物Xおよびトラルコキシジムの組合せ
化合物Xおよびピノキサデンの組合せ
化合物Xおよびフェノキサスルホンの組合せ
化合物Xおよびグルホシネートの組合せ
化合物Xおよびグルホシネートアンモニウム塩の組合せ
化合物XおよびグルホシネートPの組合せ
化合物XおよびグルホシネートPナトリウム塩の組合せ
化合物Xおよびビアラホスの組合せ
化合物Xおよびアニロホスの組合せ
化合物Xおよびベンスリドの組合せ
化合物Xおよびブタミホスの組合せ
化合物Xおよびパラコートの組合せ
化合物Xおよびパラコートジクロリドの組合せ
化合物Xおよびジクワットの組合せ
化合物Xおよびジクワットジブロミドの組合せ
化合物Xおよびハローキシフェンの組合せ
化合物Xおよびハローキシフェンメチルの組合せ
化合物Xおよびフロルピローキシフェンの組合せ
化合物Xおよびフロルピローキシフェンベンジルの組合せ
化合物Xおよびフルミオキサジンの組合せ
化合物Xおよびフルミクロラックペンチルの組合せ
化合物Xおよびホメサフェンナトリウム塩の組合せ
化合物Xおよびラクトフェンの組合せ
化合物Xおよびサフルフェナシルの組合せ
化合物Xおよびチアフェナシルの組合せ
化合物Xおよびトリフルジモキサジンの組合せ
化合物Xおよびアシフルオルフェンナトリウム塩の組合せ
化合物Xおよびアクロニフェンの組合せ
化合物Xおよびビフェノックスの組合せ
化合物Xおよびクロメトキシフェンの組合せ
化合物Xおよびクロルニトロフェンの組合せ
化合物Xおよびエトキシフェンエチルの組合せ
化合物Xおよびフルオロジフェンの組合せ
化合物Xおよびフルオログリコフェンエチルの組合せ
化合物Xおよびフルオロニトロフェンの組合せ
化合物Xおよびハロサフェンの組合せ
化合物Xおよびニトロフェンの組合せ
化合物Xおよびニトロフルオルフェンの組合せ
化合物Xおよびオキシフルオルフェンの組合せ
化合物Xおよびシニドンエチルの組合せ
化合物Xおよびプロフルアゾルの組合せ
化合物Xおよびピラクロニルの組合せ
化合物Xおよびオキサジアルギルの組合せ
化合物Xおよびオキサジアゾンの組合せ
化合物Xおよびペントキサゾンの組合せ
化合物Xおよびフルアゾレートの組合せ
化合物Xおよびピラフルフェンエチルの組合せ
化合物Xおよびベンズフェンジゾンの組合せ
化合物Xおよびブタフェナシルの組合せ
化合物Xおよびフルチアセットメチルの組合せ
化合物Xおよびチジアジミンの組合せ
化合物Xおよびアザフェニジンの組合せ
化合物Xおよびカルフェントラゾンエチルの組合せ
化合物Xおよびスルフェントラゾンの組合せ
化合物Xおよびフルフェンピルエチルの組合せ
化合物Xおよびグリホサートの組合せ
化合物Xおよびグリホサートイソプロピルアンモニウム塩の組合せ
化合物Xおよびグリホサートアンモニウム塩の組合せ
化合物Xおよびグリホサートカリウム塩の組合せ
化合物Xおよびグリホサートグアニジン塩の組合せ
化合物Xおよびグリホサートジメチルアミン塩の組合せ
化合物Xおよびグリホサートモノエタノールアミン塩の組合せ
化合物XおよびMCPAの組合せ
化合物XおよびMCPAジメチルアンモニウム塩の組合せ
化合物XおよびMCPA2-エチルヘキシルエステルの組合せ
化合物XおよびMCPAイソクチルの組合せ
化合物XおよびMCPAナトリウム塩の組合せ
化合物XおよびMCPBの組合せ
化合物Xおよびメコプロップの組合せ
化合物Xおよびメコプロップジメチルアンモニウム塩の組合せ
化合物Xおよびメコプロップジオールアミン塩の組合せ
化合物Xおよびメコプロップエタジルの組合せ
化合物Xおよびメコプロップ2-エチルヘキシルエステルの組合せ
化合物Xおよびメコプロップイソクチルの組合せ
化合物Xおよびメコプロップメチルエステルの組合せ
化合物Xおよびメコプロップカリウム塩の組合せ
化合物Xおよびメコプロップナトリウム塩の組合せ
化合物Xおよびメコプロップトロールアミン塩の組合せ
化合物XおよびメコプロップPの組合せ
化合物XおよびメコプロップPジメチルアンモニウム塩の組合せ
化合物XおよびメコプロップP2-エチルヘキシルエステルの組合せ
化合物XおよびメコプロップPイソブチルエステルの組合せ
化合物XおよびメコプロップPカリウム塩の組合せ
化合物Xおよびジクロプロップの組合せ
化合物Xおよびジクロプロップブトチルの組合せ
化合物Xおよびジクロプロップジメチルアンモニウム塩の組合せ
化合物Xおよびジクロプロップ2-エチルヘキシルエステルの組合せ
化合物Xおよびジクロプロップイソクチルエステルの組合せ
化合物Xおよびジクロプロップメチルエステルの組合せ
化合物Xおよびジクロプロップカリウム塩の組合せ
化合物Xおよびジクロプロップナトリウム塩の組合せ
化合物XおよびジクロプロップPの組合せ
化合物XおよびジクロプロップPジメチルアンモニウム塩の組合せ
[表3]のつづき
[表3]のつづき
[表3]のつづき
[表3]のつづき
[表3]のつづき
[表3]のつづき
[表3]のつづき
[表3]のつづき
[表3]のつづき
[表3]のつづき
[表3]のつづき
[表3]のつづき
[表3]のつづき
エポキシコナゾール
シプロコナゾール
プロピコナゾール
テトラコナゾール
テブコナゾール
メトコナゾール
ベンゾビンジフルピル
フルキサピロキサド
化合物1
ピラクロストロビン
アゾキシストロビン
トリフロキシストロビン
ピコキシストロビン
アゾキシストロビン+ベンゾビンジフルピル
アゾキシストロビン+プロピコナゾール
アゾキシストロビン+テブコナゾール
アゾキシストロビン+フルトリアホール
アゾキシストロビン+テトラコナゾール
アゾキシストロビン+シプロコナゾール
プロチオコナゾール+トリフロキシストロビン
ピラクロストロビン+フルキサピロキサド
トリフロキシストロビン+テブコナゾール
トリフロキシストロビン+プロチオコナゾール
ピラクロストロビン+メトコナゾール
ピラクロストロビン+エポキシコナゾール
ピコキシストロビン+シプロコナゾール
化合物1
化合物1+テブコナゾール
化合物1+プロチオコナゾール
F9990
F9990+テブコナゾール
F9990+プロチオコナゾール
(a)農作物の栽培地に、化合物Xを単独で処理すること、または先に例示した化合物Xおよび除草剤もしくは薬害軽減剤の組合せで処理すること、
(b)農作物種子に、上記化合物群Aより選択されるいずれか1種の化合物を単独で処理すること、または表1~3に記載の組合せで処理すること、
(c)先に例示した化合物Bを農作物に茎葉処理すること、および
(d)各種農作物
のあらゆる個々の組合せを開示する。
[有害節足動物防除効力]
有害節足動物防除効力の評価は、調査時の虫の生死を判別し、次の式により防除価を求める。
防除価(%)=100×(1-T/C)
なお、式中の文字は以下の意味を表す。
C:無処理区の観察時の虫数
T:処理区の観察時の虫数
植物病原菌防除効力の評価は、調査時の植物病原菌による病徴が、無処理のそれと比較して違いが全くないか、ほとんど違いがないものを「0」とし、植物病原菌による病徴が全く若しくはほとんど見られないものを「100」として、0~100に区分する。
除草効力の評価は、調査時の供試雑草の出芽または生育の状態が無処理のそれと比較して違いが全くないか、ほとんど違いがないものを「0」とし、供試植物が完全枯死または出芽若しくは生育が完全に抑制されているものを「100」として、0~100に区分する。
[作物に対する薬害]
作物に対する薬害の評価は、薬害がほとんど認められない場合は「無害」、軽度の薬害が認められる場合は「小」、中程度の薬害が認められる場合は「中」、強度の薬害が認められる場合は「大」で示される。
NipsIt(クロチアニジン600g/L、Valent社製)をダイズ(品種Genuity RoundupReady2Yieldダイズ)種子にNipsItの処理量が206mL/kg種子(1.28液量オンス/100ポンド種子)となるように処理する。当該ダイズの播種前の圃場に、化合物Xを含有する製剤(化合物X 5重量部、Geronol FF/4-E(Rhodia社製) 2重量部、Geronol FF/6-E(Rhodia社製) 8重量部、Solvesso 200(Exxon Mobile社製) 85重量部をよく混合して得られる乳剤(以下、製剤Xと記す))を水で希釈し、化合物Xの処理量が5、20または80g/haとなるように処理する。化合物Xの処理7日後に当該ダイズを当該圃場に播種し、ダイズ本葉3葉期にRoundupWeatherMax(グリホサートカリウム塩660g/L、Monsanto社製)を、処理量が2.338L/ha(32液量オンス/エーカー)となるように処理する。
実施例1と同様にNipsItをダイズ種子に処理する。当該ダイズの播種前の圃場に、化合物Xの処理量が5、20または80g/ha、RoundupWeatherMax(グリホサートカリウム塩660g/L、Monsanto社製)の処理量が2.338L/ha(32液量オンス/エーカー)となるように製剤XおよびRoundupWeatherMaxを処理し、7日後に当該ダイズを当該圃場に播種する。ダイズ本葉3葉期にRoundupWeatherMax(グリホサートカリウム塩660g/L、Monsanto社製)を、処理量が2.338L/ha(32液量オンス/エーカー)となるように処理する。
実施例1と同様にNipsItをダイズ種子に処理し、圃場に播種する。播種翌日に、製剤Xを化合物Xの処理量が5、20または80g/haとなるように処理する。ダイズ本葉3葉期にRoundupWeatherMax(グリホサートカリウム塩660g/L、Monsanto社製)を、処理量が2.338L/ha(32液量オンス/エーカー)となるように処理する。
実施例1と同様にNipsItをダイズ種子に処理し、圃場に播種する。播種翌日に、化合物Xの処理量が5、20または80g/ha、RoundupWeatherMax(グリホサートカリウム塩660g/L、Monsanto社製)の処理量が2.338L/ha(32液量オンス/エーカー)となるように製剤XおよびRoundupWeatherMaxを処理する。ダイズ本葉3葉期にRoundupWeatherMax(グリホサートカリウム塩660g/L、Monsanto社製)を、処理量が2.338L/ha(32液量オンス/エーカー)となるように処理する。
実施例1~4のそれぞれにおいて、製剤Xを処理する代わりに、化合物Xの処理量が5、20または80g/ha、ValorSX(フルミオキサジン51%、Valent社製)の処理量が210g/haとなるように製剤XおよびValorSXを処理する。
実施例5~8のそれぞれにおいて、ValorSXに代えて、ValorXLT(フルミオキサジン30%+クロリムロンエチル10.3%、Valent社製)を用い、ValorXLTの処理量が315g/haとなるように処理する。
実施例1~12のそれぞれにおいて、NipsItに代えて、INOVATE(クロチアニジン160g/L+メタラキシル13g/L+イプコナゾール8g/L、Valent社製)を用い、INOVATEの処理量が309mL/100kg種子(4.74液量オンス/100ポンド種子)となるように処理する。
実施例1~12のそれぞれにおいて、NipsItに代えて、CruiserMAXX Vibrance(チアメトキサム240g/L+メタラキシルM36g/L+フルジオキソニル12g/L+セダキサン12g/L、Syngenta社製)を用い、CruiserMAXX Vibranceの処理量が235mL/100kg種子(3.22液量オンス/100ポンド種子)となるように処理する。
実施例1~12のそれぞれにおいて、ダイズ種子にNipsItを処理する代わりに、Acceleronシステム(DX-612(フルキサピロキサド326g/L、Monsanto社製)31ml/100kg種子+DX-309(メタラキシル313g/L、Monsanto社製)242ml/100kg種子(1.5液量オンス/100ポンド種子)+DX-109(ピラクロストロビン200g/L、Monsanto社製)242ml/100kg種子(1.5液量オンス/100ポンド種子)+IX-104(イミダクロプリド600g/L、Monsanto社製)515ml/100kg種子(3.2液量オンス/100ポンド種子))で処理する。
実施例1~48のそれぞれにおいて、ダイズ開花期に化合物1を処理量が30g/haとなるように茎葉処理する。
実施例1~48のそれぞれにおいて、ダイズ開花期に化合物1およびテブコナゾールをそれぞれの処理量が30g/haおよび150/haとなるように茎葉処理する。
実施例1~144のそれぞれにおいて、ダイズ本葉3葉期にRoundupWeatherMax(グリホサートカリウム塩660g/L、Monsanto社製)を処理する代わりに、化合物Xの処理量が5、20または80g/ha、RoundupWeatherMaxの処理量が2.338L/ha(32液量オンス/エーカー)となるように製剤XおよびRoundupWeatherMaxを処理する。
実施例1~288のそれぞれにおいて、ダイズ本葉3葉期に代えて、ダイズ本葉6葉期に処理する。
実施例1~576のそれぞれにおいて、ダイズ種子に代えて、トウモロコシ種子またはワタ種子を用いる。
Claims (10)
- 農作物種子を播種する前、播種すると同時、および/または播種した後に、エチル[3-[2-クロロ-4-フルオロ-5-(1-メチル-6-トリフルオロメチル-2,4-ジオキソ-1,2,3,4-テトラヒドロピリミジン-3-イル)フェノキシ]-2-ピリジルオキシ]アセテートを農作物の栽培地に処理する工程を含む雑草の防除方法。
- 農作物の栽培地における有害生物の防除方法であって、
(1)農作物種子に、化合物群Aより選択される1種以上の化合物を処理する工程、
(2)前記工程で得られた農作物種子を播種する前、播種すると同時、および/または播種した後に、エチル[3-[2-クロロ-4-フルオロ-5-(1-メチル-6-トリフルオロメチル-2,4-ジオキソ-1,2,3,4-テトラヒドロピリミジン-3-イル)フェノキシ]-2-ピリジルオキシ]アセテートを農作物の栽培地に処理する工程、ならびに
(3)農作物の生育期に、化合物群Bより選択される1種以上の化合物を農作物に茎葉処理する工程
を含む、有害生物の防除方法。
化合物群A:ネオニコチノイド系化合物、ジアミド系化合物、カーバメート系化合物、有機リン系化合物、生物系殺線虫剤化合物、その他の殺虫剤化合物および殺線虫剤化合物、ならびにアゾール系化合物、ストロビルリン系化合物、メタラキシル系化合物、SDHI化合物、その他の殺菌剤化合物および植物生長制御剤から成る群。
化合物群B:ストロビルリン系化合物、アゾール系化合物、SDHI化合物、その他の殺菌剤化合物、ピレスロイド系化合物、ベンゾイルフェニルウレア化合物、有機リン系殺虫剤化合物、ネオニコチノイド系化合物およびジアミド系化合物から成る群。 - 化合物群Aより選択される1種以上の化合物が、以下の化合物から成る群より選択される化合物である請求項2記載の防除方法。
ネオニコチノイド系化合物:クロチアニジン、チアメトキサム、イミダクロプリド、ジノテフラン、ニテンピラム、トリフルメゾピリム、ジクロロメゾチアズ、スルホキサフロール、フルピラジフロン、アセタミプリドおよびチアクロプリド
ジアミド系化合物:フルベンジアミド、クロラントラニリプロール、シアントラニリプロール、シクラニリプロール、ブロフラニリド、シハロジアミドおよびテトラニリプロール
カーバメート系化合物:アルジカルブ、オキサミル、チオジカルブ、カルボフラン、カルボスルファンおよびジメトエート
有機リン系化合物:フェナミホス、イミシアフォス、フェンスルホチオン、テルブホス、ホスチアゼート、ホスホカルブ、ジクロフェンチオン、イサミドホス、イサゾホス、エトプロホス、カズサホス、クロルピリホス、ヘテロホス、メカルホン、ホレート、チオナジン、トリアゾホス、ジアミダホス、ホスチエタンおよびホスファミドン
生物系殺線虫剤化合物:Harpin Protein、Pasteuria nishizawae、Pasteuria penetrans、Pasteuria usage、Myrothecium verrucaria、Burkholderia cepacia、Bacillus、chitonosporus、Paecilomyces lilacinus、Bacillus amyloliquefaciens、Bacillus firmus、Bacillus subtilis、Bacillus pumulus、Trichoderma harzianum、Hirsutella rhossiliensis、Hirsutella minnesotensis、Verticillium chlamydosporumおよびArthrobotrys dactyloides
その他の殺虫剤化合物および殺線虫剤化合物:フィプロニル、エチプロール、ベータシフルトリン、テフルトリン、クロルピリホス、アバメクチン、スピロテトラマト、チオキサザフェン、フルアザインドリジン、フルエンスルホンおよびフルキサメタミド
アゾール系化合物:アザコナゾール、ビテルタノール、ブロムコナゾール、シプロコナゾール、ジフェノコナゾール、ジニコナゾール、エポキシコナゾール、フェンブコナゾール、フルキンコナゾール、フルシラゾール、フルトリアホール、ヘキサコナゾール、イミベンコナゾール、イプコナゾール、メトコナゾール、ミクロブタニル、ペンコナゾール、プロピコナゾール、プロチオコナゾール、シメコナゾール、テブコナゾール、テトラコナゾール、トリアジメノール、トリチコナゾール、フェナリモール、ヌアリモール、ピリフェノックス、イマザリル、オキシポコナゾール-フマレート、ペフラゾエート、プロクロラズ、トリフルミゾール、イプフェントリフルコナゾールおよびメフェントリフルコナゾール
ストロビルリン系化合物:クレソキシム-メチル、アゾキシストロビン、トリフロキシストロビン、フルオキサストロビン、ピコキシストロビン、ピラクロストロビン、ジモキシストロビン、ピリベンカルブ、メトミノストロビン、オリサストロビンおよびマンデストロビン
メタラキシル系化合物:メタラキシルおよびメタラキシル-M
SDHI化合物:セダキサン、ペンフルフェン、カルボキシン、ボスカリド、フラメトピル、フルトラニル、フルキサピロキサド、イソピラザム、フルオピラム、チフルザミド、イソフェタミド、ピラジフルミド、ピジフルメトフェン、N-(7-フルオロ-1,1,3-トリメチルインダン-4-イル)-1-メチル-3-ジフルオロメチルピラゾール-4-カルボン酸アミド(ラセミ体またはエナンチオマー、R体のエナンチオマーとS体のエナンチオマーの任意の割合での混合物を含む)、N-(1,1,3-トリメチルインダン-4-イル)-1-メチル-3-ジフルオロメチルピラゾール-4-カルボン酸アミド(ラセミ体またはエナンチオマー、R体のエナンチオマーとS体のエナンチオマーの任意の割合での混合物を含む)
その他の殺菌剤化合物:トルクロホスメチル、チラム、キャプタン、カルベンダジム、チオファネートメチル、マンコゼブ、チアベンダゾール、イソチアニル、エタボキサム、ピカルブトラゾクス、オキサチアピプロリンおよびトリアゾキシド
植物生長制御剤:エテホン、クロルメコート、メピコートおよび4-オキソ-4-(2-フェニルエチル)アミノ酪酸 - 化合物群Bより選択される1種以上の化合物が、以下の化合物から成る群より選択される化合物である請求項2または3記載の防除方法。
ストロビルリン系化合物:ピラクロストロビン、アゾキシストロビン、マンデストロビン、トリフロキシストロビンおよびピコキシストロビン
アゾール系化合物:プロチオコナゾール、エポキシコナゾール、テブコナゾール、シプロコナゾール、プロピコナゾール、メトコナゾール、ブロムコナゾール、テトラコナゾール、トリチコナゾール、イプフェントリフルコナゾールおよびメフェントリフルコナゾール
SDHI化合物:ベンゾビンジフルピル、ビキサフェン、フルキサピロキサド、N-(7-フルオロ-1,1,3-トリメチルインダン-4-イル)-1-メチル-3-ジフルオロメチルピラゾール-4-カルボン酸アミド(ラセミ体またはエナンチオマー、R体のエナンチオマーとS体のエナンチオマーの任意の割合での混合物を含む)およびN-(1,1,3-トリメチルインダン-4-イル)-1-メチル-3-ジフルオロメチルピラゾール-4-カルボン酸アミド(ラセミ体またはエナンチオマー、R体のエナンチオマーとS体のエナンチオマーの任意の割合での混合物を含む)
その他の殺菌剤化合物:トルクロホスメチルおよびエタボキサム
ピレスロイド系化合物:ビフェントリン、ラムダシハロトリン、ガンマシハロトリン、シペルメトリン、フェンプロパトリン、エトフェンプロックス、シラフルオフェンおよびエスフェンバレレート
ベンゾイルフェニルウレア化合物:テフルベンズロンおよびトリフルムロン
有機リン系殺虫剤化合物:アセフェートおよびメソミル
ネオニコチノイド系化合物:イミダクロプリド、クロチアニジン、チアメトキサム、スルホキサフロール、フルピラジフロン、トリフルメゾピルムおよびジクロロメゾチアズ
ジアミド系化合物:フルベンジアミド、クロラントラニリプロール、シアントラニリプロール、ブロフラニリド、テトラニリプロールおよびシハロジアミド - 農作物種子を播種する前に、エチル[3-[2-クロロ-4-フルオロ-5-(1-メチル-6-トリフルオロメチル-2,4-ジオキソ-1,2,3,4-テトラヒドロピリミジン-3-イル)フェノキシ]-2-ピリジルオキシ]アセテートを農作物の栽培地に処理する、請求項1または2記載の防除方法。
- 農作物種子を播種すると同時に、エチル[3-[2-クロロ-4-フルオロ-5-(1-メチル-6-トリフルオロメチル-2,4-ジオキソ-1,2,3,4-テトラヒドロピリミジン-3-イル)フェノキシ]-2-ピリジルオキシ]アセテートを農作物の栽培地に処理する、請求項1または2記載の防除方法。
- 農作物種子を播種した後に、エチル[3-[2-クロロ-4-フルオロ-5-(1-メチル-6-トリフルオロメチル-2,4-ジオキソ-1,2,3,4-テトラヒドロピリミジン-3-イル)フェノキシ]-2-ピリジルオキシ]アセテートを農作物の栽培地に処理する、請求項1または2記載の防除方法。
- 有害生物が、雑草および/または節足動物および/または植物病原菌である請求項2~7のいずれかに記載の防除方法。
- 有害生物が、雑草である請求項2~7のいずれかに記載の防除方法。
- 農作物が、ダイズ、トウモロコシ、ワタ、ナタネ、イネ、コムギ、オオムギ、サトウキビ、サトウダイコン、ソルガムおよびヒマワリから成る群より選択される農作物である請求項2~9のいずれかに記載の防除方法。
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MX2019001054A MX2019001054A (es) | 2016-07-29 | 2017-07-24 | Metodo para controlar plagas de cultivos agricolas. |
CA3032267A CA3032267A1 (en) | 2016-07-29 | 2017-07-24 | Herbicidal composition comprising flumioxazin |
BR112019001364-4A BR112019001364B1 (pt) | 2016-07-29 | 2017-07-24 | Método de controle de pragas de culturas agrícolas e composição herbicida |
BR122022001366A BR122022001366B8 (pt) | 2016-07-29 | 2017-07-24 | Método de controle de pragas de culturas agrícolas e composição herbicida |
US16/256,350 US20190150440A1 (en) | 2016-07-29 | 2019-01-24 | Method for controlling pests of farm crops |
US16/814,421 US11369112B2 (en) | 2016-07-29 | 2020-03-10 | Method for controlling pests of farm crops |
AU2022202359A AU2022202359B2 (en) | 2016-07-29 | 2022-04-08 | Method for controlling pests of farm crops |
US17/746,265 US11819024B2 (en) | 2016-07-29 | 2022-05-17 | Method for controlling pests of farm crops |
US18/484,474 US20240090500A1 (en) | 2016-07-29 | 2023-10-11 | Method for controlling pests of farm crops |
AU2024205281A AU2024205281A1 (en) | 2016-07-29 | 2024-07-31 | Method for controlling pests of farm crops |
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US11160279B2 (en) | 2018-02-21 | 2021-11-02 | Sumitomo Chemical Company, Limited | Method of controlling herbicide resistant weeds |
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AU2017319643B2 (en) | 2017-12-20 | 2024-01-25 | Sumitomo Chemical Company, Limited | Method for controlling harmful organisms in crops |
CN109601555A (zh) * | 2018-12-12 | 2019-04-12 | 中山大学 | 核盘菌在防治薇甘菊中的应用及其菌株的诱发方法 |
JP2019137701A (ja) * | 2018-12-26 | 2019-08-22 | 住友化学株式会社 | 雑草の防除方法 |
CN111248207A (zh) * | 2020-03-11 | 2020-06-09 | 安徽辉隆集团银山药业有限责任公司 | 一种含有氯氟醚菌唑和戊唑醇的杀菌组合物 |
JP2021185174A (ja) * | 2021-08-23 | 2021-12-09 | 住友化学株式会社 | 除草剤組成物及び雑草防除方法 |
CN118450798A (zh) | 2021-12-16 | 2024-08-06 | 联合工业公司 | 即用型屏障和击倒杀有害生物剂 |
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US20240090500A1 (en) | 2024-03-21 |
US20200205409A1 (en) | 2020-07-02 |
BR122022001366B1 (pt) | 2022-10-11 |
US11369112B2 (en) | 2022-06-28 |
AU2017301293A1 (en) | 2019-02-07 |
US20220272977A1 (en) | 2022-09-01 |
US11819024B2 (en) | 2023-11-21 |
AR109272A1 (es) | 2018-11-14 |
AU2022202359A1 (en) | 2022-04-28 |
AU2017301293B2 (en) | 2022-01-13 |
AU2024205281A1 (en) | 2024-08-22 |
JP2017019840A (ja) | 2017-01-26 |
BR122022001366B8 (pt) | 2022-12-13 |
BR112019001364A2 (pt) | 2019-04-30 |
CA3032267A1 (en) | 2018-02-01 |
AR125912A2 (es) | 2023-08-23 |
BR112019001364B1 (pt) | 2022-07-12 |
US20190150440A1 (en) | 2019-05-23 |
MX2019001054A (es) | 2019-06-20 |
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