WO2018018399A1 - Feuille de couleur universelle à base d'eau de type dispersion - Google Patents

Feuille de couleur universelle à base d'eau de type dispersion Download PDF

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Publication number
WO2018018399A1
WO2018018399A1 PCT/CN2016/091682 CN2016091682W WO2018018399A1 WO 2018018399 A1 WO2018018399 A1 WO 2018018399A1 CN 2016091682 W CN2016091682 W CN 2016091682W WO 2018018399 A1 WO2018018399 A1 WO 2018018399A1
Authority
WO
WIPO (PCT)
Prior art keywords
parts
dispersion resin
universal color
based universal
color
Prior art date
Application number
PCT/CN2016/091682
Other languages
English (en)
Chinese (zh)
Inventor
简基连
Original Assignee
江门骅弘科技股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 江门骅弘科技股份有限公司 filed Critical 江门骅弘科技股份有限公司
Priority to CN201680027502.0A priority Critical patent/CN107690460A/zh
Priority to PCT/CN2016/091682 priority patent/WO2018018399A1/fr
Publication of WO2018018399A1 publication Critical patent/WO2018018399A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/24—Homopolymers or copolymers of amides or imides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257—(Meth)acrylic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon

Definitions

  • the present invention relates to the field of aqueous coloring, and in particular to a dispersed aqueous universal color film.
  • the water-based universal color paste made of deionized water as a matrix solves the above problems to some extent.
  • the conventional deionized water solvent aqueous general-purpose color paste has a low toner content, and thus the concentration is not high, and the coloring power is also inferior to that of the oily color paste.
  • the technical problem to be solved by the invention is to provide a dispersive water-based universal color film, which has a long shelf life and can be widely used for textiles, synthetic leather materials or interior and exterior walls of buildings, has strong coloring power and does not cause dispersion of environmental pollution.
  • Type water-based universal color film and its manufacturing method are examples of materials that have a long shelf life and can be widely used for textiles, synthetic leather materials or interior and exterior walls of buildings, has strong coloring power and does not cause dispersion of environmental pollution.
  • the technical solution of the present invention is a dispersion type water-based universal color sheet composed of the following components of mass ratio: acrylic resin dispersion resin 20-40%, toner 60 to 80%, wherein the acrylic dispersion resin comprises the following parts by mass:
  • the polymer obtained by the saponification reaction of each component of the acrylic dispersion resin is an acrylic dispersion resin.
  • a method of making a dispersed aqueous universal color film comprising the following steps:
  • the propylene dispersion resin is combined with the color material, the shelf life of the dispersed water-based universal color film is prolonged, and the application range of the color film is broadened, so that it can be generally applied to textiles, synthetic leather materials or inside and outside the building.
  • the wall body has strong coloring power, and since the dispersion type water-based universal color film is produced only by kneading and solidifying the propylene dispersion resin and the color material, it is not necessary to use deionized water as a carrier, the process flow is simple, the production cost is low, and Will not cause environmental pollution.
  • the acrylic dispersion resin formed after the reaction is similar in properties, and thus is formed only by the saponification reaction of each component in the following mass parts.
  • the acrylic dispersion resin is described as the acrylic dispersion resin in the following examples.
  • the toner can be tested in different colors, and different toners will only cause different colors, such as indigo blue powder, indigo green powder, carbon black powder, etc.
  • the color does not affect its properties other than color, and in order to make the different examples and the comparative examples comparable, the toners of the following examples and comparative examples are carbon black powder, preservative and defoaming.
  • Agents are commonly used types, such as defoamers can be commonly used types such as organic defoamers, silicone defoamers and polyether defoamers, while preservatives are commonly used industrial grade preservatives, preservatives and There is no specific restriction on the type of preservative, and only the CTAC preservative is used here.
  • the mass ratio 75% carbon black powder and 25% acrylic acid dispersion resin are added to the kneading pot for preliminary kneading. After the kneading is completed, a colloid is formed, and the colloid is kneaded with the high speed kneader for 2 hours. After high-speed kneading, the colloid is hot-pressed by heating to a 125 ° C cross-back type three-roller, and cooled at room temperature to form a color block, and the color block is pulverized to form a dispersed water-based universal color piece.
  • the colloid After high-speed kneading, the colloid is hot-pressed by heating to a 125 ° C cross-back type three-roller, and cooled at room temperature to form a color block, and the color block is pulverized to form a dispersed water-based universal color piece.
  • 80% of carbon black powder and 20% of acrylic resin dispersion were taken according to the mass ratio, and they were sequentially added to the kneading pot for preliminary kneading. After the kneading was completed, a colloid was formed, and the colloid was kneaded with the high speed kneader for 2 hours. After high-speed kneading, the colloid is hot-pressed by heating to a 125 ° C cross-back type three-roller, and cooled at room temperature to form a color block, and the color block is pulverized to form a dispersed water-based universal color piece.
  • the carbon black powder is used as the coloring material, and 60% of the indigo blue powder and 40% of the acrylic dispersing resin are taken according to the mass ratio, and are sequentially added to the kneading pot for preliminary kneading, and after the kneading is completed, the colloid is formed, and then the colloid and the high speed are formed. Kneading in a kneading machine for 2 hours After high-speed kneading, the colloid is hot-pressed by heating to a 125 ° C cross-back type three-roller, and cooled at room temperature to form a color block, and the color block is pulverized to form a dispersed water-based universal color piece.
  • the conventional color film is made of the following mass parts of raw materials: 1250-5600 parts of carbon black powder; 2100-3700 parts of styrene-acrylic resin; 300 parts of ethanolamine; 5000 parts of water.
  • the raw materials are weighed according to the above parts by mass; then the styrene-acrylic resin, ethanolamine and water are poured into the cylinder of the ball mill, ground for 5-20 minutes, and fully mixed and dissolved to prepare an emulsion.
  • the primary color powder is poured into a material tank, and is dispersed by a ball mill for 2 to 2.5 hours to fully mix the emulsion with the primary color powder to obtain a slurry; finally, the slurry is dried by a dryer to obtain a solid water. Color film.
  • test formula for tinting strength, dispersibility and viscosity was: 60 g of deionized water plus 40 g of color film, and both of them were commercially available laboratory high-speed dispersers (model: KFS-400W). Disperse at speed 4000 RPM for 2 hours.
  • the final test results are as follows:
  • Example 2 Example 3
  • Example 4 Tint strength 100% 120% 123% 130% 115% Dispersibility 1.5g color residue No residue No residue No residue No residue No residue No residue No residue Viscosity ( mPa ⁇ s ) 150 165 173 200 160 Shelf life (days) 350 ⁇ 365 450 ⁇ 540 450 ⁇ 540 450 ⁇ 540 Scope of application Synthetic leather material Textiles, synthetic leather materials, interior and exterior walls of buildings
  • Tinting strength also known as tinting strength, refers to the ability of a pigment to form a color with a reference pigment. The method of determining the tinting strength is usually compared with a standard sample and determined by the difference ratio, expressed as a percentage.
  • the dispersibility is mainly filtered through a 1000 mesh screen, and the degree of dispersibility is compared by judging whether or not there is a residue.
  • the dispersed aqueous universal color sheet of the present invention has a viscosity at least 10% higher than that of the comparative product, and the toner content is higher than that of the comparative color sheet, so that the coloring power is better than the comparative ratio, and in addition, the particles of the present invention Fineness less than 5 ⁇ m
  • the favorable toner is dispersed in the system, and the toner remains in the system for a long time.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Cette invention concerne une feuille de couleur universelle à base d'eau de type dispersion, comprenant les composants suivants en pourcentage en poids : de 20 à 40 % d'une résine de dispersion acide acrylique et de 60 à 80 % de toner. L'invention concerne également un procédé de préparation de ladite feuille de couleur universelle à base d'eau de type dispersion. La feuille de couleur universelle à base d'eau de type dispersion selon l'invention a une longue durée de conservation, une large gamme d'applications, un pouvoir colorant élevé et s'obtient par un procédé technologique simple. Elle n'utilise pas d'eau désionisée comme véhicule, n'engendre par conséquent que de faibles coûts de production, et ne cause pas de pollution de l'environnement.
PCT/CN2016/091682 2016-07-26 2016-07-26 Feuille de couleur universelle à base d'eau de type dispersion WO2018018399A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201680027502.0A CN107690460A (zh) 2016-07-26 2016-07-26 一种分散型水性通用色片
PCT/CN2016/091682 WO2018018399A1 (fr) 2016-07-26 2016-07-26 Feuille de couleur universelle à base d'eau de type dispersion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2016/091682 WO2018018399A1 (fr) 2016-07-26 2016-07-26 Feuille de couleur universelle à base d'eau de type dispersion

Publications (1)

Publication Number Publication Date
WO2018018399A1 true WO2018018399A1 (fr) 2018-02-01

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Country Status (2)

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CN (1) CN107690460A (fr)
WO (1) WO2018018399A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108841251A (zh) * 2018-07-04 2018-11-20 浙江大利实业有限公司 一种用于封箱的水性环保不透明胶带色浆及其制备方法
CN109385138A (zh) * 2018-11-06 2019-02-26 厦门易统水墨有限公司 一种水性固体再溶性油墨及加工工艺方法
CN115073869A (zh) * 2021-08-12 2022-09-20 东莞市集丰塑化材料有限公司 一种亚克力固态颜料的制备方法与亚克力固态颜料

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003087248A1 (fr) * 2002-04-15 2003-10-23 Kuboko Paint Co., Ltd. Revetement en poudre dispersee dans l'eau, procede de production correspondant, et procede d'echantillonnage de la couleur
CN102206360A (zh) * 2011-03-31 2011-10-05 佛山市顺德区天隆颜料有限公司 人造革用水性色片及其制备方法
CN102212277A (zh) * 2011-03-31 2011-10-12 佛山市顺德区天隆颜料有限公司 人造革用水性白色色片及其制备方法
CN102212278A (zh) * 2011-03-31 2011-10-12 佛山市顺德区天隆颜料有限公司 人造革用水性黑色色片及其制备方法
CN103965393A (zh) * 2014-05-06 2014-08-06 江门骅弘颜料有限公司 一种水性丙烯酸树脂
CN103965698A (zh) * 2014-05-06 2014-08-06 江门骅弘颜料有限公司 一种水油两用色浆

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003087248A1 (fr) * 2002-04-15 2003-10-23 Kuboko Paint Co., Ltd. Revetement en poudre dispersee dans l'eau, procede de production correspondant, et procede d'echantillonnage de la couleur
CN102206360A (zh) * 2011-03-31 2011-10-05 佛山市顺德区天隆颜料有限公司 人造革用水性色片及其制备方法
CN102212277A (zh) * 2011-03-31 2011-10-12 佛山市顺德区天隆颜料有限公司 人造革用水性白色色片及其制备方法
CN102212278A (zh) * 2011-03-31 2011-10-12 佛山市顺德区天隆颜料有限公司 人造革用水性黑色色片及其制备方法
CN103965393A (zh) * 2014-05-06 2014-08-06 江门骅弘颜料有限公司 一种水性丙烯酸树脂
CN103965698A (zh) * 2014-05-06 2014-08-06 江门骅弘颜料有限公司 一种水油两用色浆

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