WO2017115820A1

WO2017115820A1 - Second preparation composition for aerosol-type hair dye or hair bleaching agent

Info

Publication number: WO2017115820A1
Application number: PCT/JP2016/088988
Authority: WO
Inventors: 宗男小川
Original assignee: 花王株式会社
Priority date: 2015-12-28
Filing date: 2016-12-27
Publication date: 2017-07-06
Also published as: JP2017119694A; JP2023093737A; JP2021100980A; TWI731014B; JP7274519B2; JP7165486B2; TW201735897A

Abstract

A second preparation composition for aerosol-type hair dying or hair bleaching, which is mixed with a first preparation composition containing an alkaline agent upon use, and which contains the components (A) to (D) mentioned below, wherein the ratio of the total amount of the components (C) and (D) to the amount of the component (B), i.e., [(C)+(D)]/(B), is 1.0 to 3.5 inclusive by mass and the ratio of the amount of the component (D) to the amount of the component (C), i.e., (D)/(C), is 1.2 to 2.2 inclusive by mass: (A) hydrogen peroxide; (B) a nonionic surfactant; (C) a higher alcohol; and (D) a hydrocarbon.

Description

Aerosol-type hair dye or hair bleaching agent second agent composition

The present invention relates to a second agent composition of an aerosol type hair dye or a hair bleaching agent.

Conventionally, it consists of a first agent containing an alkali agent and a second agent containing an oxidant, and the first agent and the second agent are respectively stored in independent aerosol containers, and they are discharged and mixed when used. A two-component aerosol hair dye or hair bleaching agent is known (Patent Documents 1 and 2).

(Patent Document 1) JP 2000-297018 JP (Patent Document 2) JP 2004-091359 JP

The present invention is an aerosol-type hair dyeing or hair bleaching second agent composition used by mixing with an alkali agent-containing first agent composition, which comprises the following components (A) to (D): The total mass ratio [(C) + (D)] / (B) of components (C) and (D) to component (B) is 1.0 or more and 3.5 or less, and component (D) to component (C) The present invention provides a second agent composition for aerosol hair dyeing or hair bleaching, wherein the mass ratio (D) / (C) is 1.2 or more and 2.2 or less.
(A) Hydrogen peroxide (B) Nonionic surfactant (C) Higher alcohol (D) Hydrocarbon

Detailed Description of the Invention

It is generally known that when manufacturing a two-part type aerosol product, a high shear force is applied to the agent when the agent is filled in the aerosol container or when the agent is discharged from the aerosol container. And since this shear force is very strong, it changed the emulsification structure of the agent, and when used, it sometimes became lower than the viscosity of the agent initially set. Such a decrease in the viscosity of the agent causes a change in the discharge amount of the agent from the aerosol container. In particular, in a two-component aerosol hair dye or hair bleaching agent, due to the above viscosity change, the first agent discharged from the first agent container and the second agent container discharged from the second agent container There is a possibility that a stable hair dyeing / decoloring effect cannot be obtained because the discharge amount of the two agents is significantly different.

In addition, in the aerosol hair dye / bleaching agent, if hydrogen peroxide and a cationic surfactant (in many cases counter ions are chloride ions) are used as the second agent, the metal container may corrode. In order to suppress it, it is necessary to select the inner bag and inner surface coat of the metal container, and it takes a lot of labor. If an anionic surfactant is used as the second agent, the hair feel is deteriorated and the pH is low. There is also a problem that it is difficult to use an ionic surfactant.

Therefore, the present invention uses a ionic surfactant as much as possible and keeps the viscosity of the agent from the aerosol container stable by keeping the viscosity from before the agent is filled into the aerosol container to after being discharged from the aerosol container. The present invention relates to a second agent composition capable of realizing discharge and obtaining a stable hair dyeing / bleaching effect.

As a result of intensive studies, the present inventor has found that, in the second agent of the aerosol type hair dye or hair decoloring agent, in order to keep the viscosity of the agent constant without using an ionic surfactant as much as possible, the emulsion particle size should be reduced. In addition, it has been found that, for that purpose, it is effective to blend a nonionic surfactant, a higher alcohol and a hydrocarbon in a specific ratio.

The second agent composition of the present invention is capable of stably discharging from the aerosol container because the viscosity is kept constant by suppressing the viscosity reduction due to filling and discharging into the aerosol container. When used as a hair or depigmenting agent, a stable hair dyeing / bleaching effect can be obtained.

[Second Agent Composition]
The 2nd agent composition of this invention is combined with the 1st agent composition containing an alkaline agent, and is used as an aerosol type hair dye or a hair bleaching agent.

[Component (A): Hydrogen peroxide]
The second agent composition of the present invention contains hydrogen peroxide as component (A). The content of hydrogen peroxide in the second agent composition is preferably 1% by mass or more, more preferably 3% by mass or more from the viewpoint of obtaining sufficient decoloring power, and also suppresses irritation to the scalp. From the viewpoint, it is preferably 9% by mass or less, more preferably 6% by mass or less.

[Component (B): Nonionic surfactant]
The second agent composition of the present invention contains a nonionic surfactant as component (B). Examples of the component (B) include polyoxyalkylene alkyl ethers, alkyl alkanolamides, polyoxyalkylene alkyl amines, alkyl polyglucosides, and alkyl glyceryl ethers. Among these, from the viewpoint of keeping the viscosity of the second agent composition constant, polyoxyalkylene alkyl ether is preferable, and polyoxyethylene alkyl ether is more preferable.

As the polyoxyethylene alkyl ether, those represented by the following general formula (1) can be used.

R ¹ —O— (CH ₂ CH ₂ —O) _m —H (1)
[Wherein, R ¹ represents a linear or branched saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms, and m represents an average value of 1 to 100 inclusive. ]

In the general formula (1), the carbon number of R ¹ is 8 or more, preferably 10 or more, more preferably 12 or more, from the viewpoint of the solubility of the dye contained in the hair dye. It is 22 or less, preferably 20 or less, more preferably 18 or less. A component (B) can be used individually or in combination of 2 or more types.

Component (B) includes those in which m in general formula (1) is (B-1) 1 or more and less than 30 and (B-2) 30 or more and 100 from the viewpoint of the stability of the second agent composition. A combination with the following is preferable, and a combination of (B-1) from 1 to 20 and (B-2) from 35 to 60 is more preferable. A combination of B-1) 1 to 10 and (B-2) 35 to 45 is more preferred. The mass ratio of the component (B-1) to the component (B-2) [(B-1) :( B-2)] is preferably 0.5: 9.5 to from the viewpoint of the stability of the second agent composition. 4: 1, more preferably 1: 9 to 3: 2, more preferably 1.5: 8.5 to 1: 1, still more preferably 1: 4 to 2: 3.

The content of the component (B) in the second agent composition is preferably 0.5% by mass or more, more preferably 1.0% by mass or more, and further preferably 2% by mass from the viewpoint of keeping the viscosity of the second agent composition constant. % Or more, more preferably 3% by weight or more, further preferably 5% by weight or more, further preferably 7% by weight or more, and preferably 15% by weight or less, more preferably 12% by weight or less, and still more preferably 10%. It is not more than mass%, more preferably not more than 9 mass%.

[Component (C): Higher alcohol]
The second agent composition of the present invention contains a higher alcohol as component (C). As the component (C), those represented by the following general formula (2) can be used.

R ² —OH (2)
[Wherein R ² represents a linear or branched hydrocarbon group having 12 to 24 carbon atoms. ]

Component (C) includes lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, carnervir alcohol, oleyl alcohol and the like. Component (C) can be used alone or in combination of two or more.

Component (C) is a compound in which R ² in general formula (2) is (C-1) a linear alkyl group having 12 to 18 carbon atoms from the viewpoint of keeping the viscosity of the second agent composition constant. And (C-2) a straight-chain alkyl group having 20 to 24 carbon atoms, preferably (C-1) a straight-chain alkyl group having 14 to 18 carbon atoms. (C-2) A combination with a linear alkyl group having 20 to 22 carbon atoms is more preferable. The mass ratio of component (C-1) to component (C-2) [(C-1) :( C-2)] is preferably 0.5: from the viewpoint of keeping the viscosity of the second agent composition constant. 9.5 to 9.5: 0.5, more preferably 1: 9 to 9: 1, more preferably 1.5: 8.5 to 8.5: 1.5, still more preferably 1: 4 to 4: 1, more preferably 1: 3 to 3: 1 is there.

The content of the component (C) in the second agent composition is preferably 0.5% by mass or more, more preferably 0.8% by mass or more, and still more preferably 1.0% by mass from the viewpoint of keeping the viscosity of the second agent composition constant. % Or more, more preferably 2% by mass or more, further preferably 3% by mass or more, and preferably 30% by mass or less, more preferably 25% by mass or less, still more preferably 20% by mass or less, and further preferably 15% or less. It is at most 10% by mass, more preferably at most 10% by mass, further preferably at most 8% by mass.

[Component (D): Hydrocarbon]
The second agent composition of the present invention contains a hydrocarbon as component (D). The hydrocarbon of component (D) used in the present invention is preferably a liquid at 25 ° C., for example, liquid paraffin, liquid isoparaffin, light isoparaffin, light liquid isoparaffin, heavy liquid isoparaffin, squalane and the like. It is done. Among these, liquid paraffin is preferable from the viewpoint of keeping the viscosity of the second agent composition constant. A component (D) can be used individually or in combination of 2 or more types.

The content of the component (D) in the second agent composition is preferably 3% by mass or more, more preferably 5% by mass or more, and preferably from the viewpoint of improving the brightness after dyeing or decolorization. Is 30% by mass or less, more preferably 25% by mass or less, still more preferably 20% by mass or less, still more preferably 15% by mass or less, and further preferably 12% by mass or less.

In addition, the total mass ratio [(C) + (D)] / (B) of the components (C) and (D) to the component (B) in the second agent composition is the viscosity of the second agent composition. From the viewpoint of keeping constant, it is 1.0 or more, preferably 1.2 or more, more preferably 1.5 or more, and 3.5 or less, preferably 3.3 or less, more preferably 3.2 or less.

Further, the mass ratio (D) / (C) of the component (D) to the component (C) in the second agent composition is 1.2 or more from the viewpoint of keeping the viscosity of the second agent composition constant, Preferably it is 1.3 or more, and is 2.2 or less, Preferably it is 2.1 or less.

[Component (E): Cationic surfactant]
The 2nd agent composition of this invention can contain a cationic surfactant as a component (E). As the cationic surfactant of component (E), monoalkyltrimethylammonium chloride and monoalkyltrimethylammonium bromide are preferable, and stearyltrimethylammonium chloride (steartrimonium chloride), cetyltrimethylammonium chloride (cetrimonium chloride), Lauryltrimethylammonium chloride (lauryltrimonium chloride) can be used. Component (E) can be used alone or in combination of two or more.

The content of the component (E) in the second agent composition is preferably 0.001% by mass or less, more preferably 0.0005% by mass or less from the viewpoint of preventing corrosion of the metal container, and further the component (E). It is preferable not to contain.

[Component (F): Hydroxyethanediphosphonic acid]
The second agent of the present invention may contain hydroxyethane diphosphonic acid as component (F). The content of component (F) in the second agent composition is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.10% by mass or more, from the viewpoint of stabilization of hydrogen peroxide. Preferably it is 0.3 mass% or more, Preferably it is 2 mass% or less, More preferably, it is 1.5 mass% or less, More preferably, it is 1 mass% or less.

[PH]
The pH (25 ° C.) of the second agent composition of the present invention is preferably 2 or more, more preferably 2.5 or more, and preferably 6 or less, more preferably 4 from the viewpoint of inhibiting decomposition of hydrogen peroxide. It is as follows. Examples of the pH adjuster include inorganic acids such as hydrochloric acid and phosphoric acid; organic acids such as citric acid, glycolic acid and lactic acid; and phosphates such as monopotassium dihydrogen phosphate and disodium monohydrogen phosphate.

〔viscosity〕
The viscosity (hereinafter referred to as “viscosity 1”) before filling the second agent composition of the present invention into an aerosol container is preferably 5,000 mPa · s or more, more preferably 10,000 mPa · s, from the viewpoint of the stability of the formulation. s or more, more preferably 15,000 mPa · s or more, more preferably 20,000 mPa · s or more, more preferably 25,000 mPa · s or more, and preferably 100,000 mPa · s or less, more preferably 90,000 mPa · s or less, More preferably, it is 80,000 mPa · s or less, More preferably, it is 70,000 mPa · s or less, More preferably, it is 50,000 mPa · s or less.

The viscosity immediately after discharging the second agent composition from the second container one month after filling the inner bag with the second agent composition of the present invention (hereinafter referred to as “viscosity 2”) is the stability of the formulation. In view of the above, preferably 5,000 mPa · s or more, more preferably 10,000 mPa · s or more, more preferably 15,000 mPa · s or more, further preferably 20,000 mPa · s or more, more preferably 25,000 mPa · s or more, Further, it is preferably 100,000 mPa · s or less, more preferably 90,000 mPa · s or less, further preferably 80,000 mPa · s or less, further preferably 70,000 mPa · s or less, and further preferably 50,000 mPa · s or less.

The ratio of viscosity 2 to viscosity 1 (viscosity 2 / viscosity 1) is preferably 0.80 or more, more preferably 0.85 or more, still more preferably 0.90 or more, still more preferably 0.93 or more, from the viewpoint of the stability of the formulation. It is preferably 1.25 or less, more preferably 1.20 or less, still more preferably 1.15 or less, and still more preferably 1.13 or less.

The viscosity (25 ° C.) of the second agent composition of the present invention is the value after rotating for 1 minute at 10 rpm using a TC rotor using a B-type viscometer with a helical stand.

[Volume average diameter of emulsified particles in the second agent composition]
From the viewpoint of keeping the viscosity constant, the volume average diameter of the emulsified particles before filling the second agent composition of the present invention into the inner bag is preferably 0.05 μm or more, more preferably 0.10 μm or more, and preferably 23 μm or less. More preferably, it is 20 μm or less, more preferably 15 μm or less, further preferably 12 μm or less, and further preferably 10 μm or less.

By setting to the above range, the viscosity of the second agent composition discharged from the second container can be kept constant in any temperature range.

Here, the volume average diameter of the emulsified particles in the second agent composition was determined using a dynamic light scattering particle size distribution measuring device manufactured by HORIBA, and the sample setting was “Organic sample” (refractive index: 1.600-0.000i) The setting of the dispersion medium is a value obtained by selecting “Water” (refractive index: 1.333) and measuring the volume distribution of the average diameter of the second agent.

[First Agent Composition]
The 2nd agent composition of this invention is combined with the 1st agent composition containing an alkaline agent, and is used as an aerosol type hair dye or a hair bleaching agent.

[Alkaline agent]
The first agent composition contains an alkali agent. Alkaline agents include ammonia and salts thereof (for example, ammonium hydrogen carbonate); alkanolamines such as monoethanolamine, isopropanolamine, 2-amino-2-methylpropanol, and 2-aminobutanol; and salts thereof; 1,3-propanediamine And alkanediamines and salts thereof; carbonates such as guanidine carbonate, sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate and the like. These alkaline agents can be used alone or in combination of two or more.

The content of the alkaline agent in the first agent composition is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 1.0% by mass or more, and further preferably 2 from the viewpoint of sufficient hair dyeing effect. From the viewpoint of reducing hair damage and scalp irritation, it is preferably 15% by mass or less, more preferably 10% by mass or less, and further preferably 7% by mass or less.

〔dye〕
When the 2nd agent composition of this invention is the 2nd agent for hair dyes, an oxidation dye intermediate body or a direct dye may be contained in a 1st agent composition.

(Oxidized dye intermediate)
As the oxidation dye intermediate, known precursors and couplers usually used in hair dyes can be used. Examples of the precursor include paraphenylenediamine, toluene-2,5-diamine, orthochloroparaphenylenediamine, N-phenylparaphenylenediamine, N, N-bis (hydroxyethyl) paraphenylenediamine, and 3-methyl-4-amino. Phenol, 2-hydroxyethylparaphenylenediamine, paraaminophenol, paramethylaminophenol, 4-amino-methcresol, orthoaminophenol, and salts thereof can be mentioned.

Examples of the coupler include resorcin, 2-methylresorcin, 1-naphthol, 1,5-dihydroxynaphthalene, 5-aminoorthocresol, metaphenylenediamine, orthoaminophenol, metaaminophenol, paraaminophenol, 2,4- Examples include diaminophenoxyethanol, 2,6-diaminopyridine, 2-methyl-5-hydroxyethylaminophenol, 2-amino-3-hydroxypyridine, and salts thereof.

Each of the precursor and the coupler can be used alone or in combination of two or more. The content of each of the precursor and the coupler in the first agent composition is preferably 0.01% by mass or more, more preferably 0.1% by mass or more. Moreover, it is preferably 5% by mass or less, more preferably 4% by mass or less.

(Direct dye)
Examples of direct dyes include acid dyes, nitro dyes, disperse dyes, and basic dyes. More specifically, examples of the acid dye include blue No. 1, purple No. 401, black No. 401, orange color No. 205, red No. 227, red No. 106, yellow No. 203, acidic orange 3, etc., and nitro dyes As 2-nitro-p-phenylenediamine, 2-amino-6-chloro-4-nitrophenol, 3-nitro-p-hydroxyethylaminophenol, 4-nitro-o-phenylenediamine, 4-amino-3 -Nitrophenol, 4-hydroxypropylamino-3-nitrophenol, HC blue 2, HC orange 1, HC red 1, HC yellow 2, HC yellow 4, HC yellow 5, HC red 3, N, N-bis (2 -Hydroxyethyl) -2-nitro-p-phenylenediamine and the like, and disperse dyes include disperse purple 1, disperse blue 1, disperse black 9 and the like, and basic dyes include basic blue 99, Basic tea 16, basic tea 17, basic red 76, basic yellow 76, basic orange 31, basic red 51, and the like.

Direct dyes can be used alone or in combination of two or more, and may be used in combination with an oxidation dye intermediate. The content of the direct dye in the first agent is preferably 0.001% by mass or more, more preferably 0.01% by mass or more, and preferably 5% by mass or less, more preferably 3% by mass or less.

[Other ingredients in the first agent]
In the 1st agent, the component which can be normally used in the said field | area can be contained besides the said alkali agent and dye.

[Form of aerosol container]
As an aerosol container that can be used in the present invention, (1) a double aerosol container in which an inner bag containing a first agent and an inner bag containing a second agent are housed in an independent aerosol container (for example, (Container described in JP 2000-297018 A), (2) a double aerosol container in which each of an inner bag containing a first agent and an inner bag containing a second agent is housed in one aerosol container ( For example, there is a container described in JP-A-2013-43659.

As the inner bag, those having elasticity are preferable, high-density or low-density polyethylene, saponified ethylene / vinyl acetate copolymer, polyethylene terephthalate, polypropylene, polyacrylonitrile, etc., laminated layers of these, etc. Are preferred, and those having low propellant gas permeability are preferred. Also, the inner surface of the inner bag can be coated with a chemical resistant resin.

The propellant gas used in the present invention is not particularly limited as long as it is generally used for aerosol products, such as dimethyl ether, liquefied petroleum gas, nitrogen gas, and alternative chlorofluorocarbon. Of these, nitrogen gas is preferable from the viewpoint of preventing alteration.

(Dosage form)
The dosage form when the second agent composition of the present invention is discharged from the aerosol container can be cream, gel, paste, foam or the like.

[Method for producing aerosol hair dye or hair bleach]
By filling an aerosol container with the first agent composition containing the alkaline agent and the second agent composition of the present invention, an aerosol type hair dye or a hair bleaching agent can be produced. At this time, the viscosity of the second agent composition of the present invention is preferably adjusted to the above-described viscosity range, that is, 5,000 mPa · s or more and 100,000 mPa · s or less, and then filled into an aerosol container.

[Hair dyeing tool]
The aerosol type hair dye or decoloring agent of the present invention can be applied to hair using a hair dyeing tool. As the hair dyeing tool, a hair dyeing tool having a brush portion and a comb portion as described in JP 2006-326081 A can be used.

With respect to the embodiments described above, preferred embodiments of the present invention will be further disclosed below.

<1> A second agent composition for aerosol hair dyeing or hair bleaching used by mixing with a first agent composition containing an alkaline agent, comprising the following components (A) to (D): The total mass ratio [(C) + (D)] / (B) of components (C) and (D) to component (B) is 1.0 or more and 3.5 or less, and the mass of component (D) with respect to component (C) A second agent composition for aerosol hair dyeing or hair bleaching, wherein the ratio (D) / (C) is 1.2 or more and 2.2 or less.
(A) Hydrogen peroxide (B) Nonionic surfactant (C) Higher alcohol (D) Hydrocarbon

<2> The content of the component (A) in the second agent composition is preferably 1% by mass or more, more preferably 3% by mass or more, and preferably 9% by mass or less, more preferably 6% by mass. % 2nd agent composition as described in <1>.

<3> The second agent composition according to <1> or <2>, wherein the component (B) is preferably a polyoxyethylene alkyl ether represented by the following general formula (1).
R ¹ —O— (CH ₂ CH ₂ —O) _m —H (1)
[Wherein, R ¹ represents a linear or branched saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms, and m represents an average value of 1 to 100 inclusive. ]

<4> The carbon number of R ^{1 in} the general formula (1) is preferably 10 or more, more preferably 12 or more, and preferably 20 or less, more preferably 18 or less, according to <3>. The second agent composition.

<5> Component (B), preferably (B-1) polyoxyethylene alkyl ether in which m in general formula (1) is 1 or more and less than 30 and (B-2) m in general formula (1) In combination with a polyoxyethylene alkyl ether having a molecular weight of 30 to 100, more preferably (B-1) a polyoxyethylene alkyl ether having a general formula (1) wherein m is 1 to 20 and (B-2) A combination with a polyoxyethylene alkyl ether in which m in the general formula (1) is 35 or more and 60 or less, more preferably (B-1) polyoxyethylene in which m in the general formula (1) is 1 or more and 10 or less The second agent composition according to <3> or <4>, which is a combination of an alkyl ether and a polyoxyethylene alkyl ether (B-2) in which m in the general formula (1) is 35 or more and 45 or less.

<6> The mass ratio of the component (B-1) to the component (B-2) [(B-1) :( B-2)] is preferably 0.5: 9.5 to 4: 1, more preferably 1: The second agent composition according to <5>, which is 9 to 3: 2, more preferably 1.5: 8.5 to 1: 1, and more preferably 1: 4 to 2: 3.

<7> The content of the component (B) in the second agent composition is preferably 0.5% by mass or more, more preferably 1.0% by mass or more, still more preferably 2% by mass or more, and further preferably 3% by mass or more. More preferably 5% by mass or more, further preferably 7% by mass or more, and preferably 15% by mass or less, more preferably 12% by mass or less, still more preferably 10% by mass or less, and further preferably 9% by mass or less. The second agent composition according to any one of <1> to <6>.

<8> The second agent composition according to any one of <1> to <7>, wherein component (C) is a higher alcohol represented by the following general formula (2).
R ² —OH (2)
[Wherein, R ² represents a linear or branched hydrocarbon group having 12 to 24 carbon atoms. ]

<9> Component (C) is preferably (C-1) a higher alcohol in which R ² in general formula (2) is a straight chain hydrocarbon group having 12 to 18 carbon atoms and (C-2) general A combination of higher alcohols in which R ² in the formula (2) is a straight hydrocarbon group having 20 to 24 carbon atoms, more preferably (C-1) R ² in the general formula (2) is a carbon number A higher alcohol which is a linear hydrocarbon group of 14 to 18 or less and (C-2) a higher alcohol where R ² in the general formula (2) is a straight hydrocarbon group of 20 to 22 carbon atoms The second agent composition according to <8>, which is a combination.

<10> Mass ratio of component (C-1) to component (C-2) [(C-1) :( C-2)] is preferably 0.5: 9.5 to 9.5: 0.5, more preferably 1: The second agent according to <9>, which is 9 to 9: 1, more preferably 1.5: 8.5 to 8.5: 1.5, more preferably 1: 4 to 4: 1, more preferably 1: 3 to 3: 1. Composition.

<11> The content of the component (C) in the second agent composition is preferably 0.5% by mass or more, more preferably 0.8% by mass or more, still more preferably 1.0% by mass or more, and further preferably 2% by mass or more. More preferably, it is 3% by mass or more, preferably 30% by mass or less, more preferably 25% by mass or less, still more preferably 20% by mass or less, still more preferably 15% by mass or less, and further preferably 10% by mass or less. The second agent composition according to any one of <1> to <10>, more preferably 8% by mass or less.

<12> The second agent composition according to any one of <1> to <11>, wherein the component (D) is a hydrocarbon that is preferably liquid at 25 ° C.

<13> The component (D) is preferably at least one selected from the group consisting of liquid paraffin, liquid isoparaffin, light isoparaffin, light liquid isoparaffin, heavy liquid isoparaffin, and squalane. Two agent composition.

<14> The content of the component (D) in the second agent composition is preferably 3% by mass or more, more preferably 5% by mass or more, and preferably 30% by mass or less, more preferably 25% by mass. % Or less, more preferably 20% by mass or less, more preferably 15% by mass or less, and still more preferably 12% by mass or less, according to any one of <1> to <13>.

<15> The total mass ratio [(C) + (D)] / (B) of components (C) and (D) to component (B) in the second agent composition is preferably 1.2 or more, more preferably Is the second agent composition according to any one of <1> to <14>, which is 1.5 or more, preferably 3.3 or less, more preferably 3.2 or less.

<16> The mass ratio (D) / (C) of component (D) to component (C) in the second agent composition is preferably 1.3 or more, and preferably 2.1 or less, <1> The second agent composition according to any one of to <15>.

<17> Furthermore, preferably in the range of 0.001% by mass or less in the second agent composition, more preferably in the range of 0.0005% by mass or less, a cationic surfactant can be contained as component (E). The second agent composition according to any one of <1> to <16>, which preferably contains no component (E).

<18> The second agent composition according to any one of <1> to <17>, preferably further containing hydroxyethanediphosphonic acid as component (F).

<19> The content of the component (F) in the second agent composition is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.10% by mass or more, and further preferably 0.3% by mass or more. The second agent composition according to <18>, which is preferably 2% by mass or less, more preferably 1.5% by mass or less, and still more preferably 1% by mass or less.

<20> The pH at 25 ° C. is preferably 2 or more, more preferably 2.5 or more, and preferably 6 or less, more preferably 4 or less, according to any one of <1> to <19> Second agent composition.

<21> The viscosity before filling into an aerosol container is preferably 5,000 mPa · s or more, more preferably 10,000 mPa · s or more, more preferably 15,000 mPa · s or more, further preferably 20,000 mPa · s or more, and further preferably Is 25,000 mPa · s or more, preferably 100,000 mPa · s or less, more preferably 90,000 mPa · s or less, more preferably 80,000 mPa · s or less, still more preferably 70,000 mPa · s or less, and even more preferably 50,000 mPa · s. The second agent composition according to any one of <1> to <20>, which is s or less.

<22> The viscosity immediately after being discharged from the second container after filling the inner bag is preferably 5,000 mPa · s or more, more preferably 10,000 mPa · s or more, more preferably 15,000 mPa · s or more. More preferably, it is 20,000 mPa · s or more, more preferably 25,000 mPa · s or more, preferably 100,000 mPa · s or less, more preferably 90,000 mPa · s or less, more preferably 80,000 mPa · s or less, more preferably The second agent composition according to any one of <1> to <21>, which is 70,000 mPa · s or less, more preferably 50,000 mPa · s or less.

<23> The ratio (viscosity 2 / viscosity 1) of the viscosity (viscosity 2) immediately after being discharged from the second container after filling the inner bag with respect to the viscosity (viscosity 1) before filling the aerosol container, Preferably it is 0.80 or more, more preferably 0.85 or more, more preferably 0.90 or more, further preferably 0.93 or more, preferably 1.25 or less, more preferably 1.20 or less, still more preferably 1.15 or less, still more preferably 1.13 or less. The second agent composition according to any one of <1> to <22>.

<24> The volume average diameter of the emulsified particles of the second agent composition before filling the inner bag is preferably 0.05 μm or more, more preferably 0.10 μm or more, preferably 23 μm or less, more preferably 20 μm or less, The second agent composition according to any one of <1> to <23>, which is preferably 15 μm or less, more preferably 12 μm or less, and further preferably 10 μm or less.

Example 1 and Comparative Example 1
The 2nd agent composition of the mixing | blending prescription shown in Table 1 was prepared. Next, the second agent composition was filled in the inner bag of the second container of the double aerosol, and nitrogen gas was filled between the inner bag and the second agent container. By the method shown below, the viscosity and volume average diameter of the second agent composition were measured.

(Viscosity measurement method)
The viscosity of the second agent composition was measured at two time points before filling into the container and immediately after discharging from the container one month after filling into the container. Viscosity (25 ° C) is measured using a B-type viscometer with a helical stand (manufactured by Toki Sangyo Co., Ltd., model TVB-10R, T-BAR STAGE TS-10) and rotated at 10 rpm for 1 minute using a TC rotor. It is the value after.

(Method for measuring volume average diameter of emulsified particles)
The volume average diameter of the emulsified particles was DYNAMIC LIGHT SCATTERING PARTICLE SIZE ANALYZER LB-500 manufactured by HORIBA, the sample setting was “Organic sample” (refractive index: 1.600-0.000i), and the dispersion medium setting was “Water” This is a value obtained by selecting a refractive index: 1.333) and measuring the volume distribution of the average diameter of the emulsified particles.

Examples 2-7, Comparative Examples 2-5
The 2nd agent composition of the mixing | blending prescription shown in Table 2 and Table 3 was prepared. The volume average diameter of the emulsified particles of the second agent composition was measured by the method described above.

Claims

A second agent composition for aerosol hair dyeing or hair bleaching used by mixing with a first agent composition containing an alkaline agent, comprising the following components (A) to (D), and a component (B ) The total mass ratio [(C) + (D)] / (B) of components (C) and (D) to 1.0 is not more than 3.5 and the mass ratio of component (D) to component (C) (D ) / (C) is a second agent composition for aerosol-type hair dyeing or hair bleaching, having a ratio of 1.2 to 2.2.
(A) Hydrogen peroxide (B) Nonionic surfactant (C) Higher alcohol (D) Hydrocarbon
The second agent composition according to claim 1, wherein the component (B) is a polyoxyethylene alkyl ether represented by the following general formula (1).
R 1 —O— (CH 2 CH 2 —O) m —H (1)
[Wherein, R 1 represents a linear or branched saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms, and m represents an average value of 1 to 100 inclusive. ]
Component (B) is (B-1) polyoxyethylene alkyl ether in which m in general formula (1) is 1 or more and less than 30, and (B-2) m in general formula (1) is 30 or more and 100 or less. The 2nd agent composition of Claim 2 which is a combination with the polyoxyethylene alkyl ether which is.
The mass ratio of the component (B-1) to the component (B-2) [(B-1) :( B-2)] is 0.5: 9.5 to 4: 1. Agent composition.
The second agent composition according to any one of claims 1 to 4, wherein the content of the component (B) in the second agent composition is 0.5 mass% or more and 15 mass% or less.
The second agent composition according to any one of claims 1 to 5, wherein the component (C) is a higher alcohol represented by the following general formula (2).
R 2 —OH (2)
[Wherein, R 2 represents a linear or branched hydrocarbon group having 12 to 24 carbon atoms. ]
Component (C) is a higher alcohol wherein (C-1) R 2 in general formula (2) is a straight chain hydrocarbon group having 12 to 18 carbon atoms and (C-2) in general formula (2) The second agent composition according to claim 6, which is a combination of higher alcohols in which R 2 is a linear hydrocarbon group having 20 to 24 carbon atoms.
The mass ratio [(C-1) :( C-2)] of the component (C-1) and the component (C-2) is 0.5: 9.5 to 9.5: 0.5, Agent composition.
The second agent composition according to any one of claims 1 to 8, wherein the content of the component (C) in the second agent composition is 0.5% by mass or more and 30% by mass or less.
The component (D) is at least one selected from the group consisting of liquid paraffin, liquid isoparaffin, light isoparaffin, light liquid isoparaffin, heavy liquid isoparaffin, and squalane. Two agent composition.
The second agent composition according to any one of claims 1 to 10, wherein the content of the component (D) in the second agent composition is 3% by mass or more and 30% by mass or less.
The second agent composition according to any one of claims 1 to 11, further comprising a cationic surfactant as component (E) in a range of 0.001% by mass or less in the second agent composition.
The second agent composition according to any one of claims 1 to 12, further comprising hydroxyethanediphosphonic acid as component (F).
The second agent composition according to any one of claims 1 to 13, wherein the viscosity before filling the aerosol container is from 5,000 mPa · s to 100,000 mPa · s.
15. An aerosol type hair dye or hair bleaching agent obtained by filling an aerosol container with the second agent composition according to any one of claims 1 to 14 and the first agent composition containing an alkaline agent.
14. Aerosol hair dye or hair decolorization, wherein the viscosity of the second agent composition according to any one of claims 1 to 13 is adjusted to 5,000 mPa · s to 100,000 mPa · s and then filled into an aerosol container. Manufacturing method.
Use of the combination of the second agent composition according to any one of claims 1 to 14 and the first agent composition containing an alkaline agent as an aerosol type hair dye or a hair bleaching agent.