Classifications

• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
  • A01M1/00—Stationary means for catching or killing insects
  • A01M1/20—Poisoning, narcotising, or burning insects
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
  • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
  • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
  • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
  • A01N41/10—Sulfones; Sulfoxides
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
  • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
  • A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
  • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
  • A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
  • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
  • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
  • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
  • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
  • A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
  • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
  • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
  • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
  • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
  • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
  • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
  • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
  • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
  • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
  • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
  • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
  • A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
  • A01N57/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing acyclic or cycloaliphatic radicals

Definitions

• the present invention relates to a pest control composition
• a pest control composition comprising an iminopyridine derivative and at least one other pest control agent.
• Patent Document 1 European Patent Application Publication No. 268915
• Patent Document 2 International Publication No. 2012/029672
• Patent Document 3 Japanese Patent Application Laid-Open No. 5-78323
• Patent Document 3 includes a general formula (1) described later. It has been suggested that a compound having a structure similar to the compound represented by the formula (2) is used in combination with other pest control agents.
• Patent Document 4 includes a composition and a combination in which a compound having a structure similar to the compound represented by the general formula (1) described later and another pesticide are mixed. There is a description about the thing.
• International Publication No. 2015/055555 (Patent Document 5) International Publication No.
• the object of the present invention is to provide a novel pest control composition to solve the problems of existing drugs such as reduced drug sensitivity and sustained effect in the pest control field.
• At least one pest control agent selected from the group (a) consisting of an iminopyridine derivative represented by the following general formula (1) and an acid addition salt thereof, and other than the group (a)
• a composition for controlling pests comprising at least one pest control agent selected from the group (b) consisting of the above pest control agents.
• Ar is a halogen atom, a C1-C4 alkyl group optionally substituted by a halogen atom, an alkyloxy group optionally substituted by a halogen atom, a hydroxyl group, a cyano group, or a nitro group.
• the group (a) is N- [1-((6-chloropyridin-3-yl) methyl) pyridine-2 (1H) -ylidene] -2,2,2-trifluoroacetamide, N- [1-((6-chloro- 5-fluoropyridin-3-yl) methyl) pyridine-2 (1H) -ylidene] -2,2,2-trifluoroacetamide, N- [1-((6-fluoropyridin-3-yl) methyl) Pyridine-2 (1H) -ylidene] -2,2,2-trifluoroacetamide, N- [1-((6-bromopyridin-3-yl) methyl) pyridine-2 (1H) -ylidene] -2 , 2,2-trifluoroacetamide, N- [1- (1- (6-chloropyridin-3-yl) ethyl) pyridine-2 (1H) -ylidene]
• the iminopyridine derivative represented by the general formula (1) is N- [1-((6-chloropyridin-3-yl) methyl) pyridine-2 (1H) -ylidene] -2,2,2
• [8] Applying at least one pest control agent selected from the group (a) and at least one pest control agent selected from the group (b) to a region to be treated simultaneously.
• a useful plant from a pest comprising applying the combination according to [6] to at least one selected from the group consisting of a pest, a useful plant, soil, and a cultivation carrier as an application target. How to protect.
• [14] A method of using the pest control composition as described in any one of [1] to [5] for protecting useful plants from pests.
• the present invention it is possible to provide a pest control composition that exhibits a high control effect against pests that are problematic in the agricultural field.
• the damage to crops caused by pests can be reduced by directly treating the pests with the composition for controlling pests of the present invention, or treating the plant body, soil, or crop cultivation carrier with a drug. it can.
• by treating with the pest control composition of the present invention it is possible to show a higher control effect at a lower dose than when each pest control agent is used as a single agent.
• composition for controlling pests of the present invention comprises, as an active ingredient, at least one pest control agent (first pest control agent) selected from the group (a), and harmful substances other than the group (a). It contains at least one pest control agent (second pest control agent) selected from the group (b) consisting of a biocontrol agent.
• first pest control agent selected from the group (a)
• second pest control agent selected from the group (b) consisting of a biocontrol agent.
• the composition for pest control of the present invention provides the second pest control. When used in combination with an agent, it exhibits a control effect superior to that used with a single agent.
• the pest control composition of the present invention can be used as an agricultural and horticultural pest control agent, sanitary pest control agent, unpleasant pest control agent, stored / stored food pest control agent, house pest control agent, and the like.
• the agricultural and horticultural pest control agent can be used as a paddy rice pest control agent.
• the first pest control agent is a pest control agent selected from the group (a) consisting of an iminopyridine derivative represented by the following general formula (1) and an acid addition salt thereof.
• the first pest control agent may be any one pest control agent selected from the group (a) or a mixture of two or more pest control agents.
• Ar is a halogen atom, a C1-C4 alkyl group optionally substituted by a halogen atom, an alkyloxy group optionally substituted by a halogen atom, a hydroxyl group, a cyano group, or a nitro group.
• R1 represents a hydrogen atom or a C1-C6 alkyl group.
• Y represents a hydrogen atom, a halogen atom, a hydroxyl group, a C1-C6 alkyl group optionally substituted by a halogen atom, a C1-C6 alkyloxy group optionally substituted by a halogen atom, a cyano group, a formyl group, or a nitro group.
• R2 represents a C1-C6 alkyl group substituted with a halogen atom.
• the optionally substituted substituent is a halogen atom or a C1 optionally substituted by a halogen atom.
• a preferred substituent is a halogen atom.
• examples of the “halogen atom” include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom.
• the “C1-C4 alkyl group optionally substituted by a halogen atom” specifically includes a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group.
• examples of the “alkyloxy group optionally substituted by a halogen atom” include a methoxy group, an ethoxy group, a trifluoromethyloxy group, a difluoromethyloxy group, and the like.
• Ar examples include 3-pyridyl group, 6-chloro-3-pyridyl group, 6-chloro-5-fluoro-3-pyridyl group, and 6-bromo-3.
• 6-chloro-3-pyridyl group 6-fluoro-3-pyridyl group, 6-chloro-5-fluoro-3-pyridyl group, 6-bromo-3-pyridyl group, 2-chloro-5 are preferable.
• 6-chloro-3-pyridyl group 6-fluoro-3-pyridyl group, 6-chloro-5-fluoro-3-pyridyl group, 6-bromo-3-pyridyl group, 2-chloro-5 are preferable.
• -Pyrimidyl group and the like 6-chloro-3-pyridyl group, 6-fluoro-3-pyridyl group, 6-chloro-5-fluoro-3-pyridyl group, 6-bromo-3-pyridyl group, 2-chloro-5 are preferable.
• -Pyrimidyl group and the like 6-chloro-3-pyridyl group, 6-fluoro-3-pyridyl group,
• Examples of the “C1 to C6 alkyl group” represented by R1 include a chain, branched, cyclic, or a combination thereof having 1 to 6 carbon atoms. When the branched or cyclic alkyl group is included, the number of carbon atoms is 3 or more. Specific examples include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, and a cyclopropyl group. Among them, preferred are a methyl group, an ethyl group and the like.
• C1-C6 alkyl group optionally substituted with a halogen atom represented by Y
• Y include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an n-pentyl group, Examples include a difluoromethyl group, a trifluoromethyl group, a chloromethyl group, a 2,2,2-trifluoroethyl group, and a 2-chloroethyl group.
• C1-C6 alkyloxy group optionally substituted by a halogen atom represented by Y include a methoxy group, an ethoxy group, a trifluoromethyloxy group, a difluoromethyloxy group, and an isopropyloxy group. Is mentioned.
• the “C1-C6 alkyl group substituted with a halogen atom” represented by R2 is a chain, branched, cyclic, or combination thereof having one or more hydrogen atoms substituted with a halogen atom.
• the upper limit of the number of substituted hydrogen atoms is the number of hydrogen atoms of the alkyl group.
• the number of carbon atoms is 3 or more.
• a trifluoromethyl group preferably a trifluoromethyl group, a trichloromethyl group, a dichloromethyl group, a difluoromethyl group, a difluorochloromethyl group, a chloromethyl group, a pentafluoroethyl group, more preferably a trifluoromethyl group, a difluoromethyl group, A difluorochloromethyl group, a chloromethyl group and a pentafluoroethyl group;
• preferred compounds are N- [1-((6-chloropyridin-3-yl) methyl) pyridine-2 (1H) -ylidene] -2,2, 2-trifluoroacetamide, N- [1-((6-chloro-5-fluoropyridin-3-yl) methyl) pyridine-2 (1H) -ylidene] -2,2,2-trifluoroacetamide, N- [1-((6-Fluoropyridin-3-yl) methyl) pyridine-2 (1H) -ylidene] -2,2,2-trifluoroacetamide, N- [1-((6-bromopyridine -3-yl) methyl) pyridin-2 (1H) -ylidene] -2,2,2-trifluoroacetamide, N- [1- (1- (6-chloropyridin-3-yl) ethyl) pyr
• the second pest control agent is selected from the group (b) consisting of a pest control agent other than the group (a) (a pest control agent other than the pest control agent contained in the group (a)).
• the second pest control agent may be any one pest control agent selected from the group (b) or a mixture of two or more pest control agents.
• Such a group (b) includes acetamiprid, imidacloprid, dinotefuran, thiacloprid, nitenpyram, cartap, thiocyclam, spinetoram, fulvendiamide, flonicamid, pyrifluquinazone, pymetrozine, cyhalothrin, spirotetramat, acephate, buprofezin, fiprolopene, fiprolonide Published in 2006/129714), brofuranilide (described in WO2005 / 073165), tetranyriprole (described in WO2010 / 066952), cyclaniliprol (international) Publication No.
• the group (a) is N- [1-((6-chloropyridin-3-yl) methyl) pyridine-2 (1H) -ylidene. -2,2,2-trifluoroacetamide (compound 1) and acid addition salts thereof, wherein the group (b) is acetamiprid, imidacloprid, dinotefuran, thiacloprid, nitenpyram, cartap, thiocyclam, spinetoram, Flubendiamide, flonicamid, pyrifluquinazone, pymetrozine, aphidopyropene, cyhalothrin, spirotetramat, acephate, buprofezin, fipronil, brofuranilide, tetraniliprol, cyclaniliprol, carbosulfan, isoprothiolane, thiamethoxam, 2- (3- ( Tylsulfony
• the content ratio of the first pest control agent and the second pest control agent is the content of the first pest control agent (a mixture).
• the content of the second pest control agent is preferably in the range of 0.001 to 100 parts by weight with respect to 1 part by weight of the total content (the same applies hereinafter).
• the content of the first pest control agent and the content of the second pest control agent with respect to the total weight depend on the treatment method and the treatment amount, respectively. Can be adjusted accordingly.
• composition for controlling pests of the present invention further comprises a pest control agent other than the group (a) and the group (b), in addition to the first pest control agent and the second pest control agent.
• C It may contain at least one pest control agent selected from the group (hereinafter sometimes referred to as “third pest control agent”).
• the third pest control agent that can be mixed in the pest control composition of the present invention is a pest control agent other than the group (a) and the group (b) (the group (a) or the above. (B) selected from the group (c) consisting of a pest control agent other than the pest control agent included in the group.
• the third pest control agent may be any one pest control agent selected from the group (c) or a mixture of two or more pest control agents.
• Such groups (c) include the pesticide manual (issued by the 13th edition The British Crop Protection Council) and the Shibuya index (SHIBUA INDEX 16th edition, 2012, SHIBUA INDEX RESEARCH GROUP compound insecticide). , Acaricide, nematicide, fungicide) and the like.
• examples of the insecticide, acaricide or nematicide included in the group (c) include dichlorvos, EPN, fenitrothion, fenamifos, prothiofos, profenofos Organophosphate-based compounds such as (profenofos), pyraclofos, chlorpyrifos-methyl, diazinon, fothiazate, imiciafos (i) , Aldicarb, oxamyl, propo Propoxur, carbaryl, fenobucarb, etiofencarb, phenothiocarb, pirimicarb, carbofuran, carbofuran (carbene)
• Nereistoxin derivatives such as: dicofol, organic chlorinated compounds such as tetradiphon; permethrin, tefluthrin, cypermethrin, deltamethrin, fetalmethrin Pyrethroid compounds such as va
• preferable compounds as pest control agents included in the group (c) include clothianidin, spinosad, chlorantaniprolol, cyantraniliprole, and benfuracarb. (Benfuracarb), etofenprox, silafluofen, cyhalothrin, etiprole, sulfoxafloor, flupyraflon mectin benzoate), and insecticides such as Shikurokisapurido (cycloxaprid) and the like.
• Examples of the bactericides included in the group (c) include azoxystrobin, cresoxym-methyl, trifloxystrobin, methinostrobin, and oryastrobine.
• azoxystrobin cresoxym-methyl, trifloxystrobin, methinostrobin, and oryastrobine.
• other anilinopyrimidine compounds such as mepanipyrim, pyrimethanil, cyprodinil; triadimefon, bitoltanol, bittertanol, triflumizol
• Propiconazole penconazole, flusilazole, microbutanil, cyproconazole, proconazole, tebuconazole, tebuconazole, tebuconazole, tebuconazole, tebuconazole
• Azole compounds such as quinomethionate; quinoxaline compounds such as quinomethionate; maneb, zyne
• Thiocarbamate compounds phenylcarbamate compounds such as dietofencarb; organochlorine compounds such as chlorothalonil, quintozene; benomyl, thiophanatemethyl, thiophanate-methylcarbyl
• Benzimidazole compounds such as: metalaxyl, oxadixyl, ofurase, benalaxyl, furalaxyl, chloroanilide such as cyprofuran; sulfenic acid-based compounds such as nid); copper-based compounds such as cupric hydroxide and oxyquinoline copper; isoxazole-based compounds such as hydroxyisoxazole; fosetyl Organophosphorus compounds such as aluminum (fosetyl-aluminium) and tolcrofos-methyl; N-halogenoalkyl compounds such as captan, captafol and folpet; procymidone Of dicarboximide such as (promidone
• preferable compounds as a pest control agent included in the group (c) include azoxystrobin, oryastrostrobin, thifluzamide, furamethpyr, fthalide, Probenazole, acibenzolar-S-methyl, thiazinyl, isothianyl, carpropamide, diclocymet, phencylyl, fenoxanil , Ferimzone (ferimzone), Tebufurokin (tebufloquin), simeconazole (simeconazole), validamycin (validamycin), kasugamycin (Kasugamycin), pencycuron (pencycuron), and disinfectants such as penflufen (penflufen) and the like.
• Examples of the insect species (pests) in which the composition for controlling pests of the present invention exhibits a controlling effect include lepidopterous pests (for example, Spodoptera litura, Scarlet moth, Acacia serrata, Aomushi, Konaga, Shirochimojiyoto, Nikamaiga, Sangophagaga, Sinophyta , Rice mushrooms, yellow-tailed moths, dipterocarp, octopus moths, sand moths, leaf moths, wolfweeds, Agrotis spp, Helicoberpa spp, Heliotis spp Red aphid, cotton aphid, Aphis fabae, corn aphid, pea aphid, potato beetle Aphids, bean aphids, tulip beetle aphids, Macrosiphum avenae, Methopolophium dirhodum, barley aphids, barley
• thrips pests eg, Thrips thrips, Thrips thrips, Thrips thrips
• plant parasitic lines E.g., root-knot nematode, Negu Saleh nematode, rice thin Galle nematode, etc. Bursaphelenchus xylophilus
• the more preferable insect species to which the composition for controlling pests of the present invention is applied are lepidopterous pests (for example, green moth, scallop, Sirphophaga innotata, Chilo polychrysus, rice mushroom, corn borer) Eye pests (Spotted planthoppers, White-tailed planthoppers, Brown leafhoppers, White-winged leafhoppers, Shirahoshi-kamemushi, Minami-okame-mushi, Akahigehosomidorikami-kameka, Akasika-kamushi-kame), Coleoptera pests (e.g. , Diptera pests (for example, rice flies, rice flies). More preferred are brown planthopper, white-spotted plant, red-bellied green turtle, and green moth.
• lepidopterous pests for example, green moth, scallop, Sirphophaga innotata, Chilo polychrysus, rice mushroom, corn borer
• Eye pests spot pests
• a blast fungus (Pyricularia oryzae), a blight fungus (Rhizotonia solani), an idiot fungus (Gibberella fujikuri), Bacterial fungi (Cochliobolus niyabeanus), Sphaerulina oryzina, Magnaportis salvini, Phythumaspirusumusiumusu, and Fusarium sp.
• Rhizopus oryzae Trichoderma viride
• white leaf blight fungus Xanthomonas oryzae
• seedling blight fungus Burkholderia plantarii
• brown streak fungus Acidovorax avenae
• rice bran blight fungus Burkolderia pneumoniae fungus disease
• Erwinia chrysanthemi inner wilt brown fungus
• Erwinia ananas seedling blight fungus
• leaf sheath browning fungus Pseudomonas fuscovaginae
• red mold fungus G red mold fungus G.
• Phytophthora japon ca yellow dwarf fungus (Sclerophthora macrospora), brown sclerotia fungus (Ceratobasidium setariae), brown sclerotia fungus (Watea circinata), brown leaf blight fungus (Monogephella albescens fungus) Brown rot fungus (Nigrospora oryzae), strain blight fungus (Gibberella fujikurooi), eye spot disease fungus (Drechsella gigantean), sclerotia hydrophilum, black rot fungus disease (Endocritio black rot fungus) , Small black sclerotia fungus (Hlm inspodium sigmoidea, Sphaerulina miyakei, cinnamon mold fungus (Peziza ostracodderma), white silk fungus (Sclerotium olofusi), leaf blight fungus (Sphaeul
• Rice blast fungus (Alternaria oryzae), gray sclerotia fungus (Sclerotium fumigatum), gray leaf blight fungus (Hendersonia oryzae), leaf blight fungus (Phaeosphaeria oryzae), leaf blight fungus Poliomas bau ), Pine seed rot fungus (Fusarium avenaceum), leaf sheath rot fungus (Cylindrocladium scoparium), leaf sheath brown rot fungus (Pryrenochaeta sp.), Leaf rot rot fungus (Sarocladium oryzae), phytophytic fungus, and the like.
• the more preferable bacteria to which the composition for controlling pests of the present invention is applied are rice blast fungus (Pyricularia oryzae), blight fungus (Rhizoctonia solani), idiotic seedling fungus (Gibberella fujikuroi), and sesame leaves.
• liquid carrier examples include alcohols such as methanol, n-hexanol, and ethylene glycol; ketones such as acetone, methyl ethyl ketone, and cyclohexanone; aliphatic hydrocarbons such as n-hexane, kerosene, and kerosene; toluene, xylene, Aromatic hydrocarbons such as methylnaphthalene; ethers such as diethyl ether, dioxane and tetrahydrofuran; esters such as ethyl acetate; nitriles such as acetonitrile and isobutyronitrile; acid amides such as dimethylformamide and dimethylacetamide; Vegetable oils such as soybean oil and cottonseed oil; dimethyl sulfoxide; water and the like.
• alcohols such as methanol, n-hexanol, and ethylene glycol
• ketones such as acetone, methyl
• gaseous carrier examples include LPG, air, nitrogen, carbon dioxide gas, dimethyl ether and the like.
• the pest control composition of the present invention can be applied to pests (pest insects, fungi), useful plants, cultivation materials, and areas where it is necessary to prevent the entry of pests. These applications can be made before and after pest infestation.
• pest control composition of the present invention can also be applied to genetically modified crops.
• a first composition comprising the first pest control agent as an active ingredient and a second composition comprising the second pest control agent as an active ingredient.
• a method of protecting useful plants from pests comprising applying the composition of claim 1 to the area to be treated.
• preferable soil application methods include hydroponics for production of vegetables and flowers, and solid medium cultivation such as sand cultivation, NFT (Nutrient Film Technique) and rock wool cultivation.
• solid medium cultivation such as sand cultivation, NFT (Nutrient Film Technique) and rock wool cultivation.
• NFT Nutrient Film Technique
• the use to the nutrient solution in such a nutrient culture system and the application to the seedling box for rice seedling raising (floor soil mixing etc.) are mentioned.
• the pest control composition or combination of the present invention may be directly applied to an artificial soil containing vermiculite and a solid medium containing an artificial mat for raising seedlings.
• Formulation Example 2 [Granular wettable powder] Compound 1 10% by weight Aphidopyropen 20% by weight 60% clay Dextrin 5% by weight Alkyl maleic acid copolymer 4% by weight Sodium lauryl sulfate 1% by weight The above components were uniformly pulverized and mixed, water was added and kneaded well, and then granulated and dried to obtain a granular wettable powder.
• Theoretical value (%) 100 ⁇ (A ⁇ B) / 100 (A: 100- (Death rate when only Compound 1 is treated) B: 100- (Death rate when only each compound described in the left column of the following table is treated)) (Synergistic effect judgment method)
• Test Example 2 Yellow planthopper (Nilaparava lagens) soil irrigation treatment test Potted rice seedlings, compound 1 having a predetermined concentration prepared to become 10% acetone water, compounds described in the left column of the following table, and each of these The chemical solution of the mixed agent was subjected to soil irrigation treatment so that the treatment amount described in the following table was obtained. After being left for 3 days, the 2nd instar larvae of the brown planthopper were released. Thereafter, it was left in a constant temperature room at 25 ° C. (16 hours light period-8 hours dark period). The insects were observed for life and death 3 days after the release, and the death rate was calculated according to the following formula. The test was conducted by a two-run system.
• Test Example 4 Trigonotylus caelestialium (Trigonotylus caelestialium) Control Test 50% aqueous acetone in a predetermined concentration prepared as a (0.05% for Tween20 pressurized) Compound 1, the compounds described in the left column of the table below, And the seedlings of wheat seedlings 4 days after sowing were soaked for 30 seconds in the chemical solutions of these respective mixtures so as to achieve the treatment amounts shown in the following table. After air-drying, this was put in a glass tube, and further, 2 second-instar larvae of red bearded winged midge were released in the same glass tube. After releasing, the tube was covered and left in a constant temperature room at 25 ° C.
• Theoretical value (%) 100 ⁇ (A ⁇ B) / 100 (A: 100- (Death rate when only Compound 1 is treated) B: 100- (Death rate when only each compound described in the left column of the following table is treated)) (Synergistic effect judgment method)
• a synergistic effect was determined when the mortality rate of the mixed agent against the red beetle mosquito exceeds the theoretical value according to the Colby equation. All of the tested admixtures showed a mortality rate that exceeded the theoretical value, demonstrating a synergistic effect.
• Test Example 5 Compound 1 at a predetermined concentration prepared to become 10% acetone water for rice seedlings grown in pot cultivated rice seedlings (Chilo suppressalis) soil , each compound described in the left column of the following table, and these The chemical solution of each mixture was subjected to soil irrigation treatment so that the treatment amount described in the following table was obtained. After standing for 3 days, the second instar larvae of the green moth were released. Thereafter, it was left in a constant temperature room at 25 ° C. (16 hours light period-8 hours dark period). The insects were observed for viability 6 days after release, and the mortality was calculated according to the following formula. The test was conducted by a two-run system.
• Theoretical value (%) 100 ⁇ (A ⁇ B) / 100 (A: 100- (rate of death when only Compound 1 is treated) B: 100- (Death rate when only each compound described in the left column of the following table is treated)) (Synergistic effect judgment method)
• a synergistic effect was determined when the mortality rate of the mixed agent against the green moth exceeded the theoretical value according to the Colby equation. All of the tested admixtures showed a mortality rate that exceeded the theoretical value, demonstrating a synergistic effect.

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