WO2017094255A1 - Method for producing sintered ore - Google Patents
Method for producing sintered ore Download PDFInfo
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- WO2017094255A1 WO2017094255A1 PCT/JP2016/005000 JP2016005000W WO2017094255A1 WO 2017094255 A1 WO2017094255 A1 WO 2017094255A1 JP 2016005000 W JP2016005000 W JP 2016005000W WO 2017094255 A1 WO2017094255 A1 WO 2017094255A1
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- stirring
- raw material
- sintered
- sintering
- speed
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/12—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic in rotating drums
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/28—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic using special binding agents
Definitions
- the present invention relates to a method for producing a sintered ore that is sintered using a Dwight-Lloyd type sintering machine or the like.
- Sinter ore is generally manufactured in the following three steps.
- Sintering raw materials contain moisture, and aggregate together to form pseudo particles during granulation. And when this pseudo-particle-ized sintering raw material is inserted in the pallet of a sintering machine, it helps to ensure good air permeability of the charging layer, and promotes the sintering reaction smoothly.
- powder iron ore for sintering has been lowered in quality due to depletion of high-quality iron ore. That is, in the powdered iron ore for sintering, the proportion of fine iron ore increases as the slag component increases. An increase in the content of alumina, which is one of the slag components in the sintered iron ore, and the ratio of the fine iron ore causes a decrease in the granulation properties of the sintered iron ore.
- a sintered ore used in a blast furnace a low-slag ratio, high reducibility and high-strength sintered ore are required from the viewpoint of reducing hot metal production cost in the blast furnace and reducing CO 2 generation amount. ing.
- HPS method Hybrid Pelletized Sinter method
- the HPS method is a method using a drum mixer and a disk pelletizer in a granulation process of a sintered raw material.
- Patent Documents 1 to 5 describe a sintered blended raw material containing a large amount of fine iron ore with a high iron content as a drum mixer. It is disclosed that a sintered ore having a low slag ratio and a high reducibility is produced by granulation using a slag and a disk pelletizer.
- Patent Literature 6 discloses a method of conditioning and mixing with a high-speed rotary mixer before the granulation step of the sintered raw material powder.
- Patent Literature 7 discloses a fine powder before the granulation step.
- a method of premixing iron ore and ironmaking dust with a stirring mixer is disclosed, and
- Patent Document 8 discloses a method of premixing fine iron ore with an Eirich mixer and then granulating with a drum mixer. Has been.
- Japanese Patent Publication No.2-4658 Japanese Patent Publication No. 6-21297 Japanese Patent Publication No. 6-21298 Japanese Patent Publication No. 6-21299 Japanese Patent Publication No. 6-60358 JP 60-52534 A JP-A-1-312036 JP-A-7-331342
- the particle size becomes uneven, and the granulated particles with weak bond strength are merely aggregates of fine iron ores. It becomes easy to be granulated.
- the charging layer becomes a dense deposit structure and the bulk density increases, and the air permeability in the charging layer increases. Gets worse.
- the particles are easily broken and pulverized by applying a load (compression force) to the particles.
- the gap to be formed is reduced and the porosity is lowered.
- the air permeability in the charging layer is deteriorated.
- the deterioration of the permeability of the charging layer extends the sintering time of the sintered raw material, and thus reduces the productivity of the sintered ore.
- the formation of coarse pseudo-particles in the sintered raw material causes a decrease in the productivity of the sintered ore.
- the present invention has been made in view of the above-described problems of the prior art, and its purpose is to use coarse materials contained in the sintered raw material using a high-speed stirring device when using the sintered raw material containing fine iron ore.
- An object of the present invention is to provide a method for producing a sintered ore, in which simple pseudo particles are pulverized in advance before granulation to improve productivity in a sintering machine.
- a method for producing a sintered ore which is a high-speed stirring device having a rotating cylindrical container and a stirring blade rotating in the cylindrical container, so that the sintering raw material is satisfied so as to satisfy the following formula (1)
- v peripheral speed (m / s) of the bottom plate of the cylindrical container
- u peripheral speed (m / s) at the tip of the stirring blade
- t time (s) during which the sintered raw material is stirred by a high-speed stirring device
- L the length of the circumference drawn by the tip of the stirring blade (m)
- S Area (m 2 ) obtained by removing the area of a circle drawn by the tip of the stirring blade from the projected area of the cylindrical container projected from the rotation axis direction of the stirring blade.
- the sintered raw material contains 10 to 50% by mass of fine iron ore having a particle size of 0.125 mm or less, and the Al 2 O 3 concentration of the sintered ore obtained by sintering the sintered raw material with the sintering machine Is 1.6 mass% or more, The manufacturing method of the sintered ore as described in [1].
- FIG. 1 is a plan view of a high speed stirring device 10. It is a figure explaining L and S in high-speed stirring apparatus 10.
- 6 is a graph showing the relationship between Experimental Examples 1 to 4 and the production rate improvement effect. It is a graph which shows the relationship between a stirring speed and a sintering production rate improvement effect. It is a graph which shows the relationship between the average particle diameter after a stirring process, and a sintering production rate improvement effect. It is a figure which shows the relationship between the water
- the present invention preliminarily crushes coarse pseudo-particles generated by agglomeration of fine iron ore by agitation treatment using a high-speed agitator before granulating the sintered raw material containing fine iron ore. To do. First, the characteristic of the sintering raw material containing the fine iron ore which produces
- FIG. 1 is a graph showing a difference in particle size distribution of pseudo particles with and without pellet feed.
- the black plot shows the particle size distribution of iron ore not containing a pellet feed that is fine iron ore.
- the white plot has shown the particle size distribution of what mix
- the particle size distribution shown in the black plot became the particle size distribution shown in the white plot. That is, by mixing 40% by mass of the pellet feed, not only fine particles (less than 0.5 mm) but also coarse (greater than 10 mm) pseudo particles were generated. If the fine iron ore has the same wettability, the finer particles have a larger specific surface area and therefore absorb more moisture, so that more moisture is retained between the powders. For this reason, the fine iron ore preferentially absorbs moisture with respect to other iron ores that are not fine iron ore.
- the particle size and mass ratio are determined by dividing the raw material into each particle size by sieving using an open sieve according to JIS Z 8801, measuring the mass of each particle size, The mass ratio of each particle size is calculated from the total mass.
- mixing 40% by mass of a pellet feed having a particle size of 0.125 mm or less means that a pellet feed that has passed through a sieve having a nominal aperture of 125 ⁇ m according to JIS Z 8801 has a ratio of 40 to the total mass of iron ore. It means blending so that it becomes mass%.
- FIG. 2 (a) is a graph showing the difference in the particle size distribution of the granulated particles with and without pellet feed.
- FIG. 2B is a graph showing the distribution of pellet feed in the granulated particles.
- FIG.2 (c) is a graph which shows the dispersion
- the amount of pellet feed contained in the coarse particles was as high as about 75% by mass with respect to the total amount of the pellet feed that was input, and most of the pellet feed was unevenly distributed in the coarse particles. From this, it was found that the coarse particles contained in the granulated particles are formed by pseudo particles in which pellet feeds are aggregated.
- the coarse particles contained in the granulated particles contained a lot of moisture.
- the pellet feed preferentially absorbs moisture with respect to other iron ores and forms coarse particles in the granulated particles.
- coarse particles containing a large amount of moisture are not easily bound by a binder or the like, and the bond strength of the coarse particles is weakened.
- the grain size becomes uneven and coarse grains with weak bond strength are granulated.
- granulated particles containing such coarse particles are charged into a pallet of a sintering machine, fine particles enter between the coarse particles to form a dense deposit structure, and a charged layer having a low porosity and a high bulk density is formed. It is formed.
- the coarse particles are easily broken and powdered by applying a load (compression force), and the porosity of the charge layer is further increased. Reduce. As a result, as shown in FIG.
- the air permeability of the charging layer is deteriorated, and as a result, the sintering time of the sintered raw material is extended and the productivity of the sintered ore is lowered.
- the arrows indicate the air passages in the charging layer.
- FIG. 4 is an internal perspective view of the high-speed stirring device 10.
- FIG. 5 is a plan view of the high-speed stirring device 10.
- the high-speed stirring device 10 is a device that stirs the sintered raw material 40.
- the high-speed stirring device 10 includes a cylindrical container 20 in which the sintering raw material 40 is charged, a stirring blade 30, and a weir 36.
- the weir 36 is preferably provided for scraping the sintered raw material, but may not be provided.
- the cylindrical container 20 includes a cylindrical cylinder 22 and a circular bottom plate 24.
- the cylindrical container 20 is provided with openings (not shown) for supplying and discharging the sintering raw material 40.
- the bottom plate 24 is provided integrally with the cylinder 22, and the bottom plate 24 receives the driving force and rotates together with the cylinder 22.
- the cylindrical container 20 may include a top plate that seals the upper side of the cylindrical container 20.
- the sintering raw material 40 includes fine iron ore, limestone, and solid fuel such as powder coke, and further, auxiliary raw material powder such as quartzite and serpentine, dust, scale, return mineral, and the like. Other raw material powders, and a binder may be included.
- the fine iron ore in the sintering raw material 40 is a fine iron ore having a particle size of 0.125 mm or less.
- the stirring blade 30 includes a rotating shaft 32 and a plurality of stirring plates 34.
- the rotating shaft 32 is a position eccentric from the center of the cylindrical container 20, and the stirring blade 30 rotates by receiving a driving force from a driving unit (not shown) provided on the upper side of the cylindrical container 20. Therefore, the stirring blade 30 and the bottom plate 24 can rotate independently of each other.
- the rotation shaft 32 may be provided at the center of the cylindrical container 20.
- the stirring plate 34 is provided to project radially outward from the rotary shaft 32.
- the stirring plate 34 is provided in six directions at 60 ° intervals at two locations in the vertical direction of the rotating shaft 32. Therefore, the stirring blade 30 is provided with a total of 12 stirring plates 34.
- the number of stirring plates 34 is not limited to 12, and may be arbitrarily set according to the shape of the stirring plate 34, the number of rotations of the stirring blade 30, the number of rotations of the bottom plate 24, or the like.
- 8 to 16 stirring plates 34 may be provided at 4 to 8 positions in the vertical direction of the stirring shaft 32.
- the angle and height interval of the stirring plate 34 may be set arbitrarily.
- the bottom plate 24 rotates, for example, clockwise, and the stirring blade 30 rotates counterclockwise.
- the sintering raw material 40 charged in the cylindrical container 20 rotates clockwise along the rotation direction of the bottom plate 24.
- the sintering raw material 40 rotated clockwise is stirred by colliding with the stirring blade 30 rotated counterclockwise.
- the rotation direction of the bottom plate 24 and the stirring blade 30 may be clockwise or counterclockwise. Further, the rotation directions of the bottom plate 24 and the stirring blade 30 may be different from each other or the same.
- FIGS. 4 and 5 show an example in which the high-speed stirring device 10 stirs the sintered raw material 40 in a horizontally installed state, but the high-speed stirring device 10 may be tilted and used. Further, the stirring blade 30 may be supported while being supported in the vertical direction, and only the cylindrical container 20 may be tilted.
- the sintering raw material 40 contains fine iron ore
- the fine iron ore aggregates to generate coarse pseudo particles.
- the sintered raw material 40 is preliminarily stirred to break up coarse pseudo particles, and fine iron ore can be dispersed in the sintered raw material 40.
- the stirring conditions of the high-speed stirring device 10 will be described.
- the sintering raw material 40 is processed and granulated for a predetermined time using a drum mixer.
- coarse pseudo particles contained in the sintering raw material 40 are crushed using the high-speed stirring device 10. This is because coarse particles are granulated in the drum mixer by crushing fine iron ore that is easy to retain moisture and adhere, before granulating with a drum mixer and reducing coarse pseudo particles. It is for suppressing.
- the drum mixer is an example of a granulating apparatus, and a general granulator, particularly a rolling granulator may be used.
- the sintering raw material 40 in the cylindrical container 20 collides with the tip of the stirring plate 34 and the tip of the stirring plate 34 in the stirring blade 30 is drawn. It was found that even if it entered the inside of the circle, it could only enter up to half the length of the blade. From this, it is considered that the sintering raw material 40 is stirred on the circumference drawn by the tip of the stirring plate 34. Therefore, when the circumferential length L drawn by the tip of the stirring plate 34 is increased, the cylindrical container 20 is baked. Since the kneading
- the length L of the circumference drawn by the tip of the stirring plate 34 is referred to as “effective blade length”.
- the area excluding the area of the circle drawn by the tip of the stirring blade 30 from the area of the bottom plate 24 is S (m 2 ).
- the sintering raw material 40 exists in the S region. Since the sintering raw material 40 existing in the region S does not come into contact with the stirring plate 34 unless it reaches the circumference drawn by the tip of the stirring plate 34, the stirring efficiency of the high-speed stirring device 10 decreases as S increases. .
- the area S obtained by subtracting the area of the circle drawn by the tip of the stirring blade 30 from the area of the bottom plate 24 is referred to as “effective area”.
- the stirring shaft 32 is provided to be inclined with respect to the bottom plate 24
- the area calculated by the difference from the area of the circle drawn by the tip of the can be the effective area.
- FIG. 6 is a diagram for explaining the effective blade length L and the effective area S in the high-speed stirring device 10.
- L is the circumference of a circle 50 drawn by the tip of the stirring plate 34 of the stirring blade 30 in FIG.
- S is a region 52 indicated by hatching in FIG. This is an area obtained by subtracting the area occupied by the movement of the stirring blade 30 from the projected area of the container from the rotation axis direction of the stirring blade 30.
- the effective blade length L is the total of the circumferences drawn by the tips of the stirring plates 34 in the plurality of stirring blades 30.
- the effective area S is the sum of circles drawn by the tips of the stirring plates 34 in the plurality of stirring blades 30 from the projected area of the cylindrical container 20 from the direction of the rotation axis 32 of the stirring blade 30. It becomes the area excluding the area.
- the efficiency of stirring by the rotation of the bottom plate 24 is related to the transport speed of the sintering raw material 40 that is transported to the stirring blade 30 by the rotation of the bottom plate 24. Since the sintering raw material 40 moves with the rotation of the bottom plate 24, the transport speed for transporting the sintering raw material 40 to the stirring blade 30 is related to the peripheral speed v (m / s) of the bottom plate 24. Therefore, the peripheral speed v (m / s) of the bottom plate 24 is set as one index indicating the efficiency of stirring in the high-speed stirring device 10.
- the peripheral speed of the bottom plate 24 can be calculated by the product of the circumferential length (m) of the bottom plate 24 and the rotational speed (rpm) of the bottom plate 24.
- the efficiency of stirring by the rotation of the stirring blade 30 is related to the amount of movement of the tip of the stirring plate 34 that moves in the time during which the sintering raw material 40 is stirred in the high-speed stirring device 10. Therefore, the tip of the stirring plate 34 is the product of the time t (s) during which the sintered raw material 40 is stirred by the high-speed stirring device 10 and the peripheral speed u (m / s) that is the speed of the tip of the stirring plate 34.
- the moving distance “u ⁇ t” (m) was set as one of the indexes indicating the efficiency of stirring in the high-speed stirring device 10.
- the following formula (2) which is a product of “L / S”, “v”, and “u ⁇ t”, which is an index indicating the above-described stirring efficiency, shows the stirring efficiency of the high-speed stirring device It was found that it can be evaluated.
- the value calculated by following Numerical formula (2) be stirring speed (m / sec).
- the high-speed stirring device 10 is provided with the weir 36. However, since the movement of the sintering raw material 40 in the cylindrical container 20 does not change greatly with or without the weir 36, the high-speed stirring device with or without the weir 36 is used.
- the following numerical formula (2) for evaluating the efficiency of stirring of 10 does not change.
- the stirring speed is preferably 3000 m / s or less. This is because even if the stirring speed is higher than 3000 m / s, only the electric power is used and there is almost no effect of improving the production rate of the sintered ore. This is considered to be because most of the coarse pseudo particles contained in the sintered raw material 40 were crushed by setting the stirring speed to 3000 m / s.
- the peripheral speed v of the stirring blades 30 is the sum of the peripheral speeds v of the plurality of stirring blades 30.
- a simple average divided by the number may be used.
- the effective area S may be a value obtained by subtracting the sum of the areas occupied by the movement of all the stirring blades 30 from the area of the bottom plate 24.
- the effective stirring blade length L may be the sum of the effective stirring blade lengths L of the respective stirring blades 30, and v, u, t, L, and S are set so that these values are 500 m / s or more. As a result, a high effect of improving the production rate of sintered ore can be obtained.
- Fine iron ore is defined as particles having a particle size of 0.125 mm or less, and a sintered raw material to which fine iron ore made of hematite ore having a particle size of 0.125 mm or less is added, is included in the sintering raw material.
- the sample which changed the content rate of the fine iron ore mentioned above was created.
- the sintering raw material contains 67% by mass of iron ore, 15% by mass of return ore, 5% by mass of carbonaceous material, 11% by mass of limestone as an auxiliary material, and 2% by mass of quick lime.
- the product mass (t) is measured for each sample, the product quality quantity (t) is divided by the sintering time (h) and the cross-sectional area (m 2 ) of the test pan, and the sintering production rate (t / (m 2 ⁇ h)) was calculated.
- content of a fine iron ore is the value which calculated the ratio of the iron ore of 0.125 mm or less in advance, and calculated from the compounding quantity.
- the moisture content of the sample is an inner value relative to the amount of the sintering raw material, and is a value calculated from the dry basis raw material and added moisture.
- FIG. 7 is a graph showing the relationship between the content of fine iron ore having a particle size of 0.125 mm or less and the sintering production rate.
- the sintering production rate is rapidly decreased. From this, it is considered that when the proportion of fine iron ore exceeds 10% by mass, coarse pseudo particles having low bonding strength are formed, and as a result, the sintering production rate is rapidly reduced.
- the ratio of fine iron ore exceeds 50 mass%, granulation with a drum mixer becomes difficult.
- the condition for forming coarse pseudo-particles in the sintered raw material is when the fine iron ore of 0.125 mm or less is contained in the range of 10 to 50% by mass.
- the sintering raw material having a particle size of 0.125 mm or less increased the adhesion force representing the adhesion between particles in the powder to which moisture was added, and exhibited different behavior in the granulation property of the sintering raw material.
- the particle size threshold of iron ore was 0.125 mm.
- the influence of the concentration of Al 2 O 3 in the sintering raw material will be described.
- the Al 2 O 3 concentration of the sintered raw material 40 is high, there is a problem that the viscosity of the melt that becomes a factor for improving the strength of the sintered ore during the production of the sintered ore becomes high.
- ores containing a large amount of Al 2 O 3 are classified as clay-type ores that easily aggregate. Therefore, when a sintering raw material having a high Al 2 O 3 ratio is used, the ore containing a large amount of Al 2 O 3 agglomerates, so that the viscosity of the melt generated during sintering is increased, and the sintered ore is increased.
- the melt is not dispersed in the charging layer, and the strength of the sintered ore is reduced.
- the sintering material 40 has a high Al 2 O 3 concentration
- the increase in the viscosity of the melt due to Al 2 O 3 during the sintering is suppressed, and the melt generated during the production of the sinter can be dispersed in the sintering raw material 40, so that the strength of the sinter is increased. Will improve.
- high-speed advantage of improved strength of the sintered ore by stirring treatment of stirrer 10 the concentration of Al 2 O 3 sintered ore is sintered by a sintering machine to 1.6 mass% In the case of.
- the stirring process when the stirring process is performed using the high-speed stirring device 10, the stirring process may be performed including at least one of the binder, the carbonaceous material, and the limestone contained in the sintering raw material 40.
- the productivity of the sintered ore can be improved as compared with the case where the stirring process is not performed.
- the binder that is originally added before granulation by the drum mixer is added to the sintering raw material 40 before the stirring treatment, and the stirring treatment is performed using the high-speed stirring device 10, so that A binder that easily aggregates can be dispersed in the sintering material 40. Since the drum mixer hardens the binder and granulates the particles, if the binder can be dispersed, it is possible to suppress variations in the bonding strength of the granulated particles. Thereby, it can suppress that the particle
- the granulated particles with weak bond strength are destroyed by impact when supplying the granulated particles to the pallet of the sintering machine, and fine powder is generated by the destruction.
- the fine powder generated by the destruction hinders the air permeability of the charging layer and decreases the productivity of the sintered ore. Since the binder is stirred together with the sintering raw material 40 using the high-speed agitator 10 and the binder is dispersed in the sintering raw material 40, it is possible to suppress granulation of particles having low bonding strength.
- the productivity of the sintered ore can be improved as compared with the case where the stirring device 10 does not perform the stirring treatment.
- the carbonaceous material can be dispersed in the sintered raw material by stirring the carbonaceous material using the high-speed stirring device 10. If the sintered material is sintered in a state where the carbon material cannot be dispersed in the sintered material and is contained non-uniformly, uneven burning occurs. Uneven burning causes insufficient sintering and reduces the strength of the sintered ore. For this reason, since the above-mentioned uneven burning can be suppressed by stirring the carbonaceous material together with the sintering raw material 40 by using the high-speed stirring device 10 to disperse the carbonaceous material, the high-speed stirring device 10 does not perform the stirring treatment. As a result, the productivity of sintered ore can be improved.
- the limestone addition time “before stirring” means that limestone is included in the sintered raw material before stirring with the high-speed stirring device 10.
- the limestone addition time “after stirring” means that the limestone is included in the sintered raw material after stirring using the high-speed stirring device 10.
- the high speed stirring device 10 in which the diameter of the stirring blade 30 is 0.35 m and the diameter of the cylindrical container 20 is 0.75 m, the rotational speed of the stirring blade 30 is 500 rpm, and the rotational speed of the bottom plate 24 is 28 rpm. And stirred.
- the sintering raw material 40 in each sample was adjusted to include 15% by mass of fine iron ore having a particle size of 0.125 mm or less.
- the sintering raw material contains 67% by mass of iron ore, 15% by mass of return ore, 5% by mass of carbonaceous material, 11% by mass of limestone as an auxiliary material, and 2% by mass of quick lime.
- moisture content at the time of stirring by the high-speed stirring apparatus 10 was 5.5 mass%.
- water was added so that the water content was 7.5% by mass, and granulation was performed for 300 seconds.
- the granulated granule was baked using the iron test pot, the sinter cake was manufactured, and the sintering production rate was computed.
- not only stirring treatment was performed, but granulated particles granulated under the same other conditions were also fired using a similar iron test pan to produce a sinter cake, and the sintering production rate was calculated.
- FIG. 8 is a graph showing the relationship between Experimental Examples 1 to 4 and the production rate improvement effect.
- the production rate improvement effect is calculated by taking the difference between the sintering production rate when the stirring process by the high-speed stirring device 10 is performed and the sintering production rate when the stirring process by the high-speed stirring device 10 is not performed. did.
- Experimental Example 3 in which the proportion of Al 2 O 3 is lower than 1.6% by mass
- Experimental Example 1 and Experimental Example 2 in which the proportion of Al 2 O 3 is 1.6% by mass or more are better. It can be seen that the production rate improvement effect is greater. From the above results, it has been clarified that the effect of the present invention is further enhanced when the concentration of Al 2 O 3 is 1.6% by mass or more.
- a sintered iron ore containing 15% by mass of fine iron ore having a particle size of 0.125 mm or less and the concentration of Al 2 O 3 in the sintered ore is 1.6% by mass or more. Even if it was a ligation raw material, it turned out that productivity of a sintered ore can be improved more by granulating with a drum mixer after stirring with the high-speed stirring apparatus 10, and manufacturing a sintered ore.
- quick lime (CaO) is used as a binder, but slaked lime (Ca (OH) 2 ), a thickening organic binder, and an inorganic binder, which are binders that increase the granulation property in a drum mixer, are used. May be. Since quicklime is cheap, sintered ore can be manufactured at low cost by using quicklime as a binder.
- the sintering raw material 40 containing fine iron ore was stirred using the high-speed stirring device 10, and then the productivity improvement effect of the sintered ore was confirmed using the granulated particles granulated using a drum mixer.
- Sintering raw material 40 includes 15% by mass of fine iron ore having a particle size of 0.125 mm or less and an iron ore raw material having an Al 2 O 3 concentration of 1.6% by mass in the sintered ore. Was used.
- the sintering raw material contains 67% by mass of iron ore, 15% by mass of return ore, 5% by mass of carbonaceous material, 11% by mass of limestone as an auxiliary material, and 2% by mass of quick lime.
- moisture content at the time of stirring by the high-speed stirring apparatus 10 was 5.5 mass%. Furthermore, water was added so that the water content was 7.5% by mass, and granulation was performed using a drum mixer for 300 seconds, followed by sintering to produce a sintered ore, and the effect of improving the sintering production rate was calculated. .
- Table 2 stirring conditions of the stirring blade 30 of the high-speed stirring device 10 in Examples 1 to 7 of the present invention and Comparative Examples 1 and 2, rotation conditions of the bottom plate 24, stirring time, effective blade length, effective area, stirring speed and The production rate improvement effect is shown.
- FIG. 9 is a graph showing the relationship between the stirring speed and the effect of improving the sintering production rate.
- FIG. 9 is a graph plotting Invention Examples 1 to 7 and Comparative Examples 1 and 2 in Table 2 when the vertical axis is the production rate improvement effect and the horizontal axis is the stirring speed. From FIG. 9, it was found that the effect of improving the production rate of high sintered ore can be obtained when the stirring speed is higher than 500 m / s. On the other hand, it was found that even if the stirring speed was higher than 3000 m / s, the effect of improving the production rate of sintered ore was not changed. Note that FIG. 9 indicates that the stirring speed is more preferably 700 m / s or more, and more preferably 1300 m / s or more.
- the average particle size is determined by collecting 1 kg of the powder sample after the stirring treatment, drying, and then using a sieve having openings of 0.25, 0.5, 1, 2.8, 4.75, and 8 mm. The powder samples were sieved in order of wide opening, the mass ratio of each particle size was measured, and the particle diameter using the mass ratio was calculated by weighted averaging.
- FIG. 10 is a graph showing the relationship between the average particle diameter after the stirring treatment and the effect of improving the sintering production rate.
- FIG. 10 shows that the effect of improving the production rate of sintered ore is great when the average particle size after stirring with the high-speed stirring device 10 is 3 mm or less. That is, the sintering raw material 40 is agitated with the high-speed agitator 10 to break up coarse pseudo particles in the sintering raw material 40, thereby reducing the average particle diameter of the sintering raw material 40 to 3 mm or less. The effect of improving the production rate of the ore could be enhanced.
- FIG. 10 shows that the average particle diameter after stirring with the high-speed stirring device 10 is more preferably 2.5 mm or less, and further preferably 2 mm or less.
- the amount of water during stirring was measured such that the average particle size after stirring using the high-speed stirring device 10 was 3 mm or less.
- the entire amount of the sintered raw material 40 was charged into the high-speed stirring device 10 and stirred, and the average particle size after stirring was measured.
- the sintered material 40, the ratio is 15 mass% of iron ore fines, percentage 55% by weight of the core particles, the ratio of Al 2 O 3 is used a sintered material 40 of 1.6 wt%.
- the sintering raw material contains 67% by mass of iron ore, 15% by mass of return ore, 5% by mass of carbonaceous material, 11% by mass of limestone as an auxiliary material, and 2% by mass of quick lime.
- the diameter of the cylindrical container 20 in the high-speed stirring device 10 is 0.75 m, and the diameter of the stirring blade 30 is 0.35 m. Moreover, the rotation speed of the bottom plate 24 in the cylindrical container 20 is 28 rpm, and the rotation speed of the stirring blade 30 is 500 rpm. Sintering raw materials 40 having different moisture contents were prepared, and the stirring treatment was performed under the above conditions, and the average particle diameter after the stirring treatment at each moisture content was measured.
- FIG. 11 is a diagram showing the relationship between moisture during the stirring process and average particles after the stirring process. It can be seen from FIG. 11 that by making the water content during stirring 7% by mass or less, the average particle size after the stirring process becomes 3 mm or less, and the effect of improving the production rate of sintered ore by performing the stirring process increases. . In addition, it turns out that it is more preferable to make the moisture content at the time of stirring into 6 mass% or less from FIG. 11, and it is still more preferable to make the moisture content at the time of stirring into 4 mass% or less.
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Abstract
Description
v:前記円筒容器の底板の周速(m/s)、
u:前記撹拌羽根の先端の周速(m/s)、
t:前記焼結原料が高速撹拌装置によって撹拌される時間(s)、
L:前記撹拌羽根の先端が描く円周の長さ(m)、
S:前記撹拌羽根の回転軸方向から投影した円筒容器の投影面積から前記撹拌羽根の先端が描く円の面積を除いた面積(m2)、である。 However, in the above formula (1),
v: peripheral speed (m / s) of the bottom plate of the cylindrical container,
u: peripheral speed (m / s) at the tip of the stirring blade,
t: time (s) during which the sintered raw material is stirred by a high-speed stirring device;
L: the length of the circumference drawn by the tip of the stirring blade (m),
S: Area (m 2 ) obtained by removing the area of a circle drawn by the tip of the stirring blade from the projected area of the cylindrical container projected from the rotation axis direction of the stirring blade.
図1において黒プロットは、微粉鉄鉱石であるペレットフィードが配合されていない鉄鉱石の粒度分布を示している。また、白プロットは、黒プロットで粒度分布が示された鉄鉱石にペレットフィードを40質量%配合したものの粒度分布を示している。 FIG. 1 is a graph showing a difference in particle size distribution of pseudo particles with and without pellet feed.
In FIG. 1, the black plot shows the particle size distribution of iron ore not containing a pellet feed that is fine iron ore. Moreover, the white plot has shown the particle size distribution of what mix | blended 40 mass% of pellet feed with the iron ore which the particle size distribution was shown by the black plot.
20 円筒容器
22 円筒
24 底板
30 撹拌羽根
32 回転軸
34 撹拌板
36 堰
40 焼結原料
50 円
52 領域 DESCRIPTION OF
Claims (6)
- 焼結鉱の製造方法であって、
回転する円筒容器と、前記円筒容器内で回転する撹拌羽根と、を有する高速撹拌装置で、下記数式(1)を満たすように焼結原料を撹拌処理し、
撹拌処理後の焼結原料を造粒装置を用いて造粒し、
造粒後の焼結原料を焼結機を用いて焼結して、焼結鉱を製造する焼結鉱の製造方法。
v:前記円筒容器の底板の周速(m/s)、
u:前記撹拌羽根の先端の周速(m/s)、
t:前記焼結原料が高速撹拌装置によって撹拌される時間(s)、
L:前記撹拌羽根の先端が描く円周の長さ(m)、
S:前記撹拌羽根の回転軸方向から投影した円筒容器の投影面積から前記撹拌羽根の先端が描く円の面積を除いた面積(m2)、
である。 A method for producing sintered ore, comprising:
In a high-speed stirring device having a rotating cylindrical container and a stirring blade rotating in the cylindrical container, the sintering raw material is stirred so as to satisfy the following formula (1),
The sintered raw material after the stirring treatment is granulated using a granulator,
A method for producing sintered ore, in which a sintered raw material after granulation is sintered using a sintering machine to produce sintered ore.
v: peripheral speed (m / s) of the bottom plate of the cylindrical container,
u: peripheral speed (m / s) at the tip of the stirring blade,
t: time (s) during which the sintered raw material is stirred by a high-speed stirring device;
L: the length of the circumference drawn by the tip of the stirring blade (m),
S: Area (m 2 ) obtained by removing the area of the circle drawn by the tip of the stirring blade from the projected area of the cylindrical container projected from the rotation axis direction of the stirring blade.
It is. - 前記焼結原料は、粒径0.125mm以下である微粉鉄鉱石を10~50質量%含み、かつ前記焼結機で焼結原料を焼結した焼結鉱のAl2O3濃度が1.6質量%以上である請求項1に記載の焼結鉱の製造方法。 The sintered raw material contains 10 to 50% by mass of fine iron ore having a particle size of 0.125 mm or less, and the Al 2 O 3 concentration of the sintered ore obtained by sintering the sintered raw material with the sintering machine is 1. It is 6 mass% or more, The manufacturing method of the sintered ore of Claim 1.
- 前記焼結原料は、さらに、バインダーを含む請求項1または請求項2に記載の焼結鉱の製造方法。 The method for producing sintered ore according to claim 1 or 2, wherein the sintering raw material further contains a binder.
- 前記バインダーは、生石灰である請求項3に記載の焼結鉱の製造方法。 The method for producing a sintered ore according to claim 3, wherein the binder is quicklime.
- 前記高速撹拌装置で撹拌処理した後の前記焼結原料の平均粒子径は、3mm以下である請求項1から請求項4のいずれか一項に記載の焼結鉱の製造方法。 The method for producing a sintered ore according to any one of claims 1 to 4, wherein an average particle size of the sintered raw material after being stirred by the high-speed stirring device is 3 mm or less.
- 前記高速撹拌装置で撹拌処理する前の前記焼結原料は、7質量%以下の水分を含む請求項5に記載の焼結鉱の製造方法。 The method for producing a sintered ore according to claim 5, wherein the sintering raw material before stirring with the high-speed stirring device contains 7% by mass or less of moisture.
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