WO2017068686A1 - Refrigeration cycle device - Google Patents

Refrigeration cycle device Download PDF

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Publication number
WO2017068686A1
WO2017068686A1 PCT/JP2015/079850 JP2015079850W WO2017068686A1 WO 2017068686 A1 WO2017068686 A1 WO 2017068686A1 JP 2015079850 W JP2015079850 W JP 2015079850W WO 2017068686 A1 WO2017068686 A1 WO 2017068686A1
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Prior art keywords
refrigerant
detection sensor
leakage
unit
refrigerant leakage
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PCT/JP2015/079850
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French (fr)
Japanese (ja)
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伸哲 上原
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三菱電機株式会社
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Application filed by 三菱電機株式会社 filed Critical 三菱電機株式会社
Priority to JP2017546342A priority Critical patent/JP6381824B2/en
Priority to PCT/JP2015/079850 priority patent/WO2017068686A1/en
Priority to CN201590000691.3U priority patent/CN206420200U/en
Publication of WO2017068686A1 publication Critical patent/WO2017068686A1/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B49/00Arrangement or mounting of control or safety devices
    • F25B49/02Arrangement or mounting of control or safety devices for compression type machines, plants or systems

Definitions

  • the present invention relates to a refrigeration cycle apparatus used in refrigeration equipment, a low temperature apparatus, an air conditioner, and the like, and particularly relates to a protective function for ensuring safety in a refrigeration cycle apparatus using a flammable refrigerant. .
  • the presence or absence of refrigerant leakage is determined based on operating state information such as refrigerant pressure and temperature.
  • refrigerant leakage detection sensor for detection (see, for example, Patent Document 1).
  • the detection sensitivity may decrease due to aging. If the operation of the air conditioner is continued with the detection sensitivity of the refrigerant leakage detection sensor being lowered, there is a problem that the detection is delayed despite the refrigerant leakage, and safety cannot be ensured.
  • the ignition due to the leakage of the combustible refrigerant is largely related to the refrigerant leakage speed.
  • diffusion into the indoor space proceeds and the gas concentration is reduced, so that the refrigerant concentration in the room does not fall within the ignition concentration range.
  • a safety measure in consideration of the refrigerant leakage rate is required.
  • the present invention has been made in view of the above points, and can detect and notify a decrease in the detection sensitivity of the refrigerant leakage detection sensor, thereby reducing the occurrence of a high refrigerant concentration region due to a decrease in the sensitivity of the refrigerant leakage detection sensor.
  • An object is to obtain a refrigeration cycle apparatus.
  • a refrigeration cycle apparatus includes a compressor, a condenser, a decompression device, and an evaporator, a refrigerant circuit in which a flammable refrigerant circulates, a leak rate estimation unit that estimates a rate of refrigerant leak from the refrigerant circuit, A refrigerant leak detection sensor for detecting refrigerant leak from the refrigerant circuit and a refrigerant leak rate estimated by the leak rate estimation unit equal to or higher than a reference value and no refrigerant leak has been detected by the refrigerant leak detection sensor.
  • a deterioration detection unit that determines that the detection sensitivity of the leakage detection sensor has decreased, and a notification unit that notifies that when the deterioration of the detection sensitivity of the refrigerant leakage detection sensor is detected by the deterioration detection unit.
  • the present invention since a decrease in detection sensitivity of the refrigerant leak detection sensor is detected and notified, replacement and repair of the refrigerant leak detection sensor can be promoted. As a result, it is possible to reduce the occurrence of a high refrigerant concentration region due to a decrease in sensitivity of the refrigerant leakage detection sensor and the disadvantage of refrigerant ignition.
  • FIG. 1 shows the refrigerant circuit of the air conditioning apparatus in Embodiment 1 of this invention. It is a control block diagram of the control apparatus of the air conditioning apparatus of FIG. It is a flowchart which shows the flow of the refrigerant
  • FIG. FIG. 1 is a diagram illustrating a refrigerant circuit of the air-conditioning apparatus according to Embodiment 1 of the present invention.
  • the air conditioner in Embodiment 1 includes a compressor 11, a four-way valve 12, an outdoor heat exchanger 13, a decompression device 14 including an expansion valve, a refrigerant container 15, and an indoor heat exchanger 21, and is combustible.
  • a refrigerant circuit in which the refrigerant circulates is provided.
  • the air conditioner further includes an outdoor fan 16 that blows air to the outdoor heat exchanger 13 and an indoor fan 22 that blows air to the indoor heat exchanger 21.
  • the compressor 11, the four-way valve 12, the outdoor heat exchanger 13, the decompression device 14, and the refrigerant container 15 are arranged in the outdoor unit 1, and the indoor heat exchanger 21 and the indoor blower 22 are arranged in the indoor unit 2.
  • the outdoor unit 1 is further provided with a discharge temperature sensor 17 for detecting the temperature discharged from the compressor 11.
  • the indoor unit 2 is further provided with a refrigerant leakage detection sensor 23 that detects refrigerant leakage from the refrigerant circuit.
  • the air conditioner is provided with a plurality of sensors for detecting temperatures and pressures at various locations in the refrigerant circuit, and detection from various sensors in the air conditioner. A signal is input to a control device 31 described later.
  • the specific configuration of the refrigerant leakage detection sensor 23 is not particularly limited, and an existing technology can be adopted.
  • the technique described in Patent Document 1 may be employed. That is, a sensor for detecting the pressure and temperature of the refrigerant in the refrigerant circuit is provided, and the current refrigerant amount in the refrigerant circuit is calculated based on the measured value measured from each sensor during the refrigerant leak detection operation. It is good also as a structure which detects a refrigerant
  • a technique described in JP-A-2002-5548 may be employed.
  • the electric current detection sensor which detects a compressor driving current, and judging that the refrigerant
  • a gas concentration sensor may be used as the refrigerant leakage detection sensor 23.
  • the detection signal is input to the control device 31 described later, and a display indicating that refrigerant leakage has occurred is displayed on the display unit 35 described later. Yes.
  • the air conditioner configured as described above can perform a cooling operation or a heating operation by switching the four-way valve 12.
  • the indoor heat exchanger 21 is an evaporator and the outdoor heat exchanger 13 is a condenser to perform a cooling operation
  • the four-way valve 12 is switched to the dotted line side in FIG.
  • the indoor heat exchanger 21 is a condenser and the outdoor heat exchanger 13 is an evaporator, and the heating operation is performed.
  • the air conditioner includes an outdoor unit control device 31a that controls the entire outdoor unit and an indoor unit control device 31b that controls the entire indoor unit.
  • the indoor unit control device 31b exchanges control signals and the like with the remote controller 34 for individually operating the indoor unit 2, and communicates with the outdoor unit control device 31a via a transmission line (may be wireless). It is possible to exchange control signals and the like.
  • a transmission line may be wireless
  • the control device 31 can be configured by hardware such as a circuit device that realizes the function, or can be configured by an arithmetic device such as a microcomputer or a CPU, and a control program executed thereon. .
  • the remote controller 34 includes a display unit 35 configured with a liquid crystal panel or the like.
  • the display unit 35 displays an operation mode, a message indicating that a refrigerant leak has occurred, a message indicating that the detection sensitivity of the refrigerant leak detection sensor 23 has decreased, and the like.
  • the display unit 35 corresponds to a notification unit of the present invention that notifies a decrease in detection sensitivity of the refrigerant leakage detection sensor 23.
  • a speaker or the like may be used as the notification unit.
  • FIG. 2 is a control block diagram of the control device of the air conditioner of FIG.
  • the control device 31 performs drive frequency control of the compressor 11 and opening degree control of the decompression device 14 based on detection signals from various sensors in the air conditioning apparatus.
  • the control device 31 includes a leakage rate estimation unit 32 that estimates the rate of refrigerant leakage from the refrigerant circuit, and a deterioration detection unit 33 that detects a decrease in detection sensitivity of the refrigerant leakage detection sensor 23.
  • the leak rate estimation unit 32 and the deterioration detection unit 33 are functionally configured by a CPU and a control program.
  • the leakage rate estimation unit 32 estimates the refrigerant leakage rate based on detection signals from various sensors in the air conditioner.
  • the method for estimating the refrigerant leak rate in the leak rate estimating unit 32 is not particularly limited, and an existing technique can be adopted. For example, using the technique disclosed in Japanese Patent No. 4799563, first, an operation of detecting the refrigerant charge amount filled in the refrigerant circuit from the information of the pressure and temperature of the refrigerant is performed a plurality of times, and the refrigerant charge amount for each time Is calculated. Then, the refrigerant leakage rate can be estimated by dividing the difference between the respective refrigerant charging amounts by the detection operation interval time.
  • a method disclosed in Japanese Patent Application Laid-Open No. 2002-5548 may be adopted in which the rate of decrease in compressor operating current during compressor operation is estimated as the refrigerant leakage rate.
  • the leak rate estimation unit 32 estimates the leak rate independently of the detection result of the refrigerant leak detection sensor 23.
  • the deterioration detection unit 33 detects a decrease in detection sensitivity of the refrigerant leak detection sensor 23 based on the detection result of the refrigerant leak detection sensor 23 and the estimation result of the leak rate estimation unit 32. Specifically, the deterioration detection unit 33 has a refrigerant leakage rate detected by the leakage rate estimation unit 32 that is equal to or higher than a reference value for determining a decrease in detection sensitivity, and the refrigerant leakage detection sensor 23 performs refrigerant leakage. Is not detected at all, it is determined that the detection sensitivity of the refrigerant leakage detection sensor 23 is lowered.
  • the actual refrigerant concentration when the refrigerant leak detection sensor 23 detects that there is a refrigerant leak is higher than the refrigerant concentration that should be detected as having a refrigerant leak. Will be higher.
  • the four-way valve 12 is switched to the state indicated by the dotted line in FIG.
  • the refrigerant compressed by the compressor 11 becomes a high-temperature and high-pressure gas refrigerant and is sent to the indoor heat exchanger 21 through the four-way valve 12.
  • the refrigerant flowing into the indoor heat exchanger 21 is liquefied by exchanging heat with the indoor air conveyed by the indoor blower 22 and dissipating heat.
  • the liquefied refrigerant passes through the refrigerant container 15 and is decompressed by the decompression device 14 to be in a gas-liquid two-phase state.
  • the refrigerant in the gas-liquid two-phase state flows into the outdoor heat exchanger 13, exchanges heat with outdoor air conveyed by the outdoor blower 16, gasifies by absorbing heat, and returns to the compressor 11.
  • the heating operation is performed by circulating the refrigerant through the refrigerant circuit.
  • the four-way valve 12 is switched to the state shown by the solid line in FIG.
  • the refrigerant compressed by the compressor 11 becomes a high-temperature and high-pressure gas refrigerant, which is sent to the outdoor heat exchanger 13 through the four-way valve 12.
  • the refrigerant flowing into the outdoor heat exchanger 13 is liquefied by exchanging heat with the outdoor air conveyed by the outdoor blower 16 and dissipating heat.
  • the liquefied refrigerant is decompressed by the decompression device 14 to become a gas-liquid two-phase state, and flows into the indoor heat exchanger 21 through the refrigerant container 15.
  • the refrigerant that has flowed into the indoor heat exchanger 21 exchanges heat with the indoor air conveyed by the indoor blower 22, gasifies by absorbing heat, and is returned to the compressor 11. As described above, the refrigerant circulates through the refrigerant circuit to perform the cooling operation.
  • FIG. 3 is a flowchart showing the flow of the refrigerant leak detection sensor deterioration detection process of the air-conditioning apparatus according to Embodiment 1 of the present invention.
  • the flowchart of FIG. 3 is performed at every deterioration detection timing of the refrigerant leakage detection sensor.
  • the air conditioner checks whether there is a refrigerant leak at the refrigerant leak detection sensor 23 at all times or at an appropriate timing.
  • the leakage speed estimation unit 32 estimates the refrigerant leakage speed (S1).
  • the estimation of the refrigerant leakage rate in the leakage rate estimation unit 32 may be performed using a conventionally known technique as described above.
  • the deterioration detection unit 33 checks whether or not the refrigerant leakage rate estimated by the leakage rate estimation unit 32 is equal to or higher than a reference value and the refrigerant leakage detection sensor 23 has never detected the refrigerant leakage (S2). .
  • the deterioration detection unit 33 has a reduced detection sensitivity of the refrigerant leakage detection sensor 23. to decide.
  • the control device 31 performs predetermined control when the refrigerant leaks (S3). In other words, the control device 31 displays and notifies the display unit 35 of the remote controller 34 that “sensor sensitivity is reduced”.
  • This notification is not limited to the display unit 35 of the remote controller 34 as described above, and may be notified by voice, or the display unit (not shown) of the indoor unit 2 and the display unit (not shown) of the outdoor unit 1. You may make it display and alert
  • control device 31 operates the indoor blower 22 for a certain period of time as a predetermined control when the refrigerant leaks, and stirs the ambient air to prevent the indoor refrigerant concentration from entering the ignition concentration range.
  • coolant leak detection sensor 23 was detected here and not the refrigerant
  • step S2 the refrigerant leak detection sensor deterioration detection process is terminated.
  • a decrease in detection sensitivity of the refrigerant leakage detection sensor 23 is detected and notified. For this reason, it is possible to notify the user or serviceman of a decrease in detection sensitivity of the refrigerant leak detection sensor 23 and to prompt replacement or repair of the refrigerant leak detection sensor 23. As a result, it is possible to reduce the possibility of occurrence of a high refrigerant concentration region and refrigerant ignition due to a decrease in detection sensitivity of the refrigerant leakage detection sensor 23.
  • the refrigerant leakage speed detected by the leakage speed estimation unit 32 is equal to or higher than a reference value for determining a decrease in detection sensitivity, and the refrigerant leakage detection is performed.
  • the detection sensitivity of the refrigerant leakage detection sensor 23 is lowered. For this reason, generation
  • the technique of the first embodiment is very effective because there is no viewpoint of detecting and notifying the detection sensitivity decrease of the refrigerant leakage detection sensor 23 in the past.
  • the deterioration detection timing is always performed or at an appropriate timing, but may be performed in cooperation with refrigerant leakage detection. That is, when the refrigerant leakage detection is performed, for example, at the timing of manual operation or schedule setting, the deterioration detection may be performed following the refrigerant leakage detection timing.
  • the configuration in which the refrigerant leakage detection sensor 23 is provided on the indoor unit side is illustrated.
  • the refrigerant leakage detection sensor 23 is provided on the outdoor unit side to detect refrigerant leakage and estimate the refrigerant leakage speed. It may be.
  • the refrigeration cycle apparatus is described as an air conditioner.
  • the refrigeration cycle apparatus may be a cooling apparatus that cools a refrigerated warehouse or the like.

Abstract

This refrigeration cycle device is equipped with: a refrigerant circuit, which is provided with a compressor, a condenser, a depressurizing device, and an evaporator, and in which a flammable refrigerant is circulated; a leakage speed estimation unit that estimates the speed of refrigerant leakage from the refrigerant circuit; a refrigerant leakage detection sensor that detects the refrigerant leakage from the refrigerant circuit; a deterioration detection unit that determines that the detection sensitivity of the refrigerant leakage detection sensor is deteriorated in the cases where the refrigerant leakage speed estimated by the leakage speed estimation unit is equal to or higher than a reference value, and the refrigerant leakage has not been detected even once by the refrigerant leakage detection sensor; and a notification unit that notifies the deterioration of the refrigerant leakage detection sensor in the cases where the deterioration has been detected by the deterioration detection unit.

Description

冷凍サイクル装置Refrigeration cycle equipment
 本発明は、冷凍機器、低温装置及び空気調和装置等で使用されている冷凍サイクル装置に関するものであり、特に可燃性冷媒を用いた冷凍サイクル装置における安全性確保のための保護機能に関するものである。 The present invention relates to a refrigeration cycle apparatus used in refrigeration equipment, a low temperature apparatus, an air conditioner, and the like, and particularly relates to a protective function for ensuring safety in a refrigeration cycle apparatus using a flammable refrigerant. .
 可燃性冷媒を用いた冷凍サイクル装置として例えば空気調和装置では、冷媒漏洩時の居住空間での冷媒着火を防止するために、冷媒の圧力、温度などの運転状態情報に基づいて冷媒漏洩の有無を検知する冷媒漏洩検知センサーを備えた技術がある(例えば、特許文献1参照)。 For example, in an air conditioner as a refrigeration cycle apparatus using a combustible refrigerant, in order to prevent refrigerant ignition in the living space at the time of refrigerant leakage, the presence or absence of refrigerant leakage is determined based on operating state information such as refrigerant pressure and temperature. There is a technology including a refrigerant leakage detection sensor for detection (see, for example, Patent Document 1).
特開2007-263539号公報JP 2007-263539 A
 冷媒漏洩検知センサーは、種類によっては経年劣化により検知感度が低下するものがある。冷媒漏洩検知センサーの検知感度が低下したままで空気調和装置の運転を継続すると、冷媒漏洩が発生しているにも関わらず検知が遅れ、安全性が確保できないという課題があった。 Depending on the type of refrigerant leak detection sensor, the detection sensitivity may decrease due to aging. If the operation of the air conditioner is continued with the detection sensitivity of the refrigerant leakage detection sensor being lowered, there is a problem that the detection is delayed despite the refrigerant leakage, and safety cannot be ensured.
 また、可燃性冷媒の漏洩による着火は、冷媒漏洩速度が大きく関係することが分かってきた。漏洩速度の小さい緩やかな漏れでは、室内空間への拡散が進むためガス濃度が薄められ、室内の冷媒濃度が着火濃度範囲内に入らない。しかし、短時間内に冷媒が多量に室内に漏洩した場合、高冷媒濃度領域が発生してしまう。このため、冷媒漏洩速度を考慮した安全対策が求められている。 In addition, it has been found that the ignition due to the leakage of the combustible refrigerant is largely related to the refrigerant leakage speed. In a gradual leak with a low leak rate, diffusion into the indoor space proceeds and the gas concentration is reduced, so that the refrigerant concentration in the room does not fall within the ignition concentration range. However, when a large amount of refrigerant leaks into the room within a short time, a high refrigerant concentration region occurs. For this reason, a safety measure in consideration of the refrigerant leakage rate is required.
 本発明はこのような点を鑑みなされたもので、冷媒漏洩検知センサーの検知感度の低下を検知して報知し、冷媒漏洩検知センサーの感度低下による高冷媒濃度領域の発生を減らすことが可能な冷凍サイクル装置を得ることを目的とする。 The present invention has been made in view of the above points, and can detect and notify a decrease in the detection sensitivity of the refrigerant leakage detection sensor, thereby reducing the occurrence of a high refrigerant concentration region due to a decrease in the sensitivity of the refrigerant leakage detection sensor. An object is to obtain a refrigeration cycle apparatus.
 本発明に係る冷凍サイクル装置は、圧縮機、凝縮器、減圧装置及び蒸発器を備え、可燃性冷媒が循環する冷媒回路と、冷媒回路からの冷媒漏洩の速度を推定する漏洩速度推定部と、冷媒回路からの冷媒漏洩を検知する冷媒漏洩検知センサーと、漏洩速度推定部で推定された冷媒漏洩速度が基準値以上、かつ、冷媒漏洩検知センサーで冷媒漏洩が一度も検知されていない場合、冷媒漏洩検知センサーの検知感度が低下したと判断する劣化検知部と、劣化検知部で冷媒漏洩検知センサーの検知感度の低下が検知された場合にその旨を報知する報知部とを備えたものである。 A refrigeration cycle apparatus according to the present invention includes a compressor, a condenser, a decompression device, and an evaporator, a refrigerant circuit in which a flammable refrigerant circulates, a leak rate estimation unit that estimates a rate of refrigerant leak from the refrigerant circuit, A refrigerant leak detection sensor for detecting refrigerant leak from the refrigerant circuit and a refrigerant leak rate estimated by the leak rate estimation unit equal to or higher than a reference value and no refrigerant leak has been detected by the refrigerant leak detection sensor. A deterioration detection unit that determines that the detection sensitivity of the leakage detection sensor has decreased, and a notification unit that notifies that when the deterioration of the detection sensitivity of the refrigerant leakage detection sensor is detected by the deterioration detection unit. .
 本発明によれば、冷媒漏洩検知センサーの検知感度の低下を検知して報知するので、冷媒漏洩検知センサーの交換、修理を促すことが可能になる。その結果、冷媒漏洩検知センサーの感度低下による高冷媒濃度領域の発生、冷媒着火の不都合を減らすことが可能である。 According to the present invention, since a decrease in detection sensitivity of the refrigerant leak detection sensor is detected and notified, replacement and repair of the refrigerant leak detection sensor can be promoted. As a result, it is possible to reduce the occurrence of a high refrigerant concentration region due to a decrease in sensitivity of the refrigerant leakage detection sensor and the disadvantage of refrigerant ignition.
本発明の実施の形態1における空気調和装置の冷媒回路を示す図である。It is a figure which shows the refrigerant circuit of the air conditioning apparatus in Embodiment 1 of this invention. 図1の空気調和装置の制御装置の制御ブロック図である。It is a control block diagram of the control apparatus of the air conditioning apparatus of FIG. 本発明の実施の形態1における空気調和装置の冷媒漏洩検知センサー劣化検知処理の流れを示すフローチャートである。It is a flowchart which shows the flow of the refrigerant | coolant leakage detection sensor deterioration detection process of the air conditioning apparatus in Embodiment 1 of this invention.
 以下、冷凍サイクル装置の一例である空気調和装置の構成を説明する。
実施の形態1.
 図1は、本発明の実施の形態1における空気調和装置の冷媒回路を示す図である。
 本実施の形態1における空気調和装置は、圧縮機11、四方弁12、室外熱交換器13、膨張弁などで構成された減圧装置14、冷媒容器15及び室内熱交換器21を備え、可燃性冷媒が循環する冷媒回路を備えている。空気調和装置は更に、室外熱交換器13に送風する室外送風機16と、室内熱交換器21に送風する室内送風機22とを備えている。
Hereinafter, the structure of the air conditioning apparatus which is an example of a refrigeration cycle apparatus will be described.
Embodiment 1 FIG.
FIG. 1 is a diagram illustrating a refrigerant circuit of the air-conditioning apparatus according to Embodiment 1 of the present invention.
The air conditioner in Embodiment 1 includes a compressor 11, a four-way valve 12, an outdoor heat exchanger 13, a decompression device 14 including an expansion valve, a refrigerant container 15, and an indoor heat exchanger 21, and is combustible. A refrigerant circuit in which the refrigerant circulates is provided. The air conditioner further includes an outdoor fan 16 that blows air to the outdoor heat exchanger 13 and an indoor fan 22 that blows air to the indoor heat exchanger 21.
 そして、室外機1に圧縮機11、四方弁12、室外熱交換器13、減圧装置14及び冷媒容器15が配置され、室内機2に室内熱交換器21及び室内送風機22が配置されている。また、室外機1には更に、圧縮機11から吐出された温度を検知する吐出温度センサー17が配置されている。室内機2には更に、冷媒回路からの冷媒漏洩を検知する冷媒漏洩検知センサー23が配置されている。また、空気調和装置には、吐出温度センサー17及び冷媒漏洩検知センサー23の他、冷媒回路の各所の温度、圧力を検知する複数のセンサー等が配置され、空気調和装置内の各種センサーからの検知信号が後述の制御装置31に入力されるようになっている。 The compressor 11, the four-way valve 12, the outdoor heat exchanger 13, the decompression device 14, and the refrigerant container 15 are arranged in the outdoor unit 1, and the indoor heat exchanger 21 and the indoor blower 22 are arranged in the indoor unit 2. Further, the outdoor unit 1 is further provided with a discharge temperature sensor 17 for detecting the temperature discharged from the compressor 11. The indoor unit 2 is further provided with a refrigerant leakage detection sensor 23 that detects refrigerant leakage from the refrigerant circuit. In addition to the discharge temperature sensor 17 and the refrigerant leakage detection sensor 23, the air conditioner is provided with a plurality of sensors for detecting temperatures and pressures at various locations in the refrigerant circuit, and detection from various sensors in the air conditioner. A signal is input to a control device 31 described later.
 冷媒漏洩検知センサー23の具体的な構成は特に限定するものではなく、既存の技術を採用できる。冷媒漏洩検知センサー23として、例えば特許文献1に記載の技術を採用してもよい。すなわち、冷媒回路内の冷媒の圧力、温度を検知するセンサーを備え、冷媒漏洩検知運転時に各センサーから計測した計測値に基づき冷媒回路内の現在の冷媒量を算出し、算出した冷媒量と初期冷媒量との差から冷媒漏洩を検知する構成としてもよい。冷媒漏洩検知センサー23として他に例えば、特開2002-5548号公報に記載の技術を採用してもよい。すなわち、圧縮機運転電流を検知する電流検知センサーを備え、電流検知センサーで検知した電流が基準値以下となったことで冷媒漏洩と判断する構成としてもよい。冷媒漏洩検知センサー23として他に例えばガス濃度センサーを用いても良い。 The specific configuration of the refrigerant leakage detection sensor 23 is not particularly limited, and an existing technology can be adopted. As the refrigerant leakage detection sensor 23, for example, the technique described in Patent Document 1 may be employed. That is, a sensor for detecting the pressure and temperature of the refrigerant in the refrigerant circuit is provided, and the current refrigerant amount in the refrigerant circuit is calculated based on the measured value measured from each sensor during the refrigerant leak detection operation. It is good also as a structure which detects a refrigerant | coolant leakage from the difference with a refrigerant | coolant amount. In addition to the refrigerant leakage detection sensor 23, for example, a technique described in JP-A-2002-5548 may be employed. That is, it is good also as a structure provided with the electric current detection sensor which detects a compressor driving current, and judging that the refrigerant | coolant leaks when the electric current detected with the electric current detection sensor became below the reference value. In addition, for example, a gas concentration sensor may be used as the refrigerant leakage detection sensor 23.
 そして、冷媒漏洩検知センサー23で冷媒漏洩が検知されると、その検知信号が後述の制御装置31に入力され、冷媒漏洩が発生した旨の表示が後述の表示部35に行われるようになっている。 When refrigerant leakage is detected by the refrigerant leakage detection sensor 23, the detection signal is input to the control device 31 described later, and a display indicating that refrigerant leakage has occurred is displayed on the display unit 35 described later. Yes.
 以上のように構成された空気調和装置は、四方弁12の切り換えにより冷房運転又は暖房運転が可能となっている。四方弁12を図1の実線側に切り換えた場合、室内熱交換器21が蒸発器、室外熱交換器13が凝縮器となり冷房運転が実施され、四方弁12を図1の点線側に切り換えた場合、室内熱交換器21が凝縮器、室外熱交換器13が蒸発器となり暖房運転が実施される。 The air conditioner configured as described above can perform a cooling operation or a heating operation by switching the four-way valve 12. When the four-way valve 12 is switched to the solid line side in FIG. 1, the indoor heat exchanger 21 is an evaporator and the outdoor heat exchanger 13 is a condenser to perform a cooling operation, and the four-way valve 12 is switched to the dotted line side in FIG. In this case, the indoor heat exchanger 21 is a condenser and the outdoor heat exchanger 13 is an evaporator, and the heating operation is performed.
 また、空気調和装置は、室外機全体を制御する室外機制御装置31aと、室内機全体を制御する室内機制御装置31bを備えている。室内機制御装置31bは、室内機2を個別に操作するためのリモコン34との間で制御信号等のやりとりを行ったり、室外機制御装置31aとの間で伝送線(無線でもよい)を介して制御信号等のやりとりを行ったりすることができるようになっている。以下では、室内機制御装置31bと室外機制御装置31aとをまとめるときは制御装置31として説明する。制御装置31は、その機能を実現する回路デバイスのようなハードウェアで構成することもできるし、マイコンやCPUのような演算装置と、その上で実行される制御プログラムとにより構成することもできる。 The air conditioner includes an outdoor unit control device 31a that controls the entire outdoor unit and an indoor unit control device 31b that controls the entire indoor unit. The indoor unit control device 31b exchanges control signals and the like with the remote controller 34 for individually operating the indoor unit 2, and communicates with the outdoor unit control device 31a via a transmission line (may be wireless). It is possible to exchange control signals and the like. Below, when uniting the indoor unit control apparatus 31b and the outdoor unit control apparatus 31a, it demonstrates as the control apparatus 31. FIG. The control device 31 can be configured by hardware such as a circuit device that realizes the function, or can be configured by an arithmetic device such as a microcomputer or a CPU, and a control program executed thereon. .
 リモコン34は、液晶パネルなどで構成された表示部35を備えている。表示部35には、運転モードの表示、冷媒漏洩が発生した旨の表示、冷媒漏洩検知センサー23の検知感度が低下した旨の表示等が行われる。この表示部35は冷媒漏洩検知センサー23の検知感度の低下を報知する、本発明の報知部に相当する。報知部としては、他に例えば、スピーカー等を用いても良い。 The remote controller 34 includes a display unit 35 configured with a liquid crystal panel or the like. The display unit 35 displays an operation mode, a message indicating that a refrigerant leak has occurred, a message indicating that the detection sensitivity of the refrigerant leak detection sensor 23 has decreased, and the like. The display unit 35 corresponds to a notification unit of the present invention that notifies a decrease in detection sensitivity of the refrigerant leakage detection sensor 23. As the notification unit, for example, a speaker or the like may be used.
(冷凍空調装置の制御ブロック構成)
 図2は、図1の空気調和装置の制御装置の制御ブロック図である。
 制御装置31は、空気調和装置内の各種センサーからの検知信号に基づいて圧縮機11の駆動周波数制御、減圧装置14の開度制御等を行う。また、制御装置31は、冷媒回路からの冷媒漏洩の速度を推定する漏洩速度推定部32と、冷媒漏洩検知センサー23の検知感度の低下を検知する劣化検知部33とを備えている。漏洩速度推定部32及び劣化検知部33は、CPUと制御プログラムとにより機能的に構成されている。
(Control block configuration of refrigeration air conditioner)
FIG. 2 is a control block diagram of the control device of the air conditioner of FIG.
The control device 31 performs drive frequency control of the compressor 11 and opening degree control of the decompression device 14 based on detection signals from various sensors in the air conditioning apparatus. In addition, the control device 31 includes a leakage rate estimation unit 32 that estimates the rate of refrigerant leakage from the refrigerant circuit, and a deterioration detection unit 33 that detects a decrease in detection sensitivity of the refrigerant leakage detection sensor 23. The leak rate estimation unit 32 and the deterioration detection unit 33 are functionally configured by a CPU and a control program.
 漏洩速度推定部32は、空気調和装置内の各種センサーからの検知信号に基づいて冷媒漏洩速度を推定する。漏洩速度推定部32における冷媒漏洩速度の推定方法は特に限定するものではなく、既存の技術を採用できる。例えば、特許4799563号公報に開示された技術を用いて、まず冷媒の圧力、温度の情報から、冷媒回路内に充填された冷媒充填量を検知する運転を複数回実施し、各回の冷媒充填量を算出する。そして、各回の冷媒充填量同士の差を検知運転間隔時間で除算することにより、冷媒漏洩速度を推定できる。他に例えば、特開2002-5548号公報に開示された、圧縮機運転中の圧縮機運転電流の低下速度を冷媒漏洩速度として推定する方法を採用してもよい。なお、漏洩速度推定部32は冷媒漏洩検知センサー23の検知結果とは関係無く独立して漏洩速度を推定するものである。 The leakage rate estimation unit 32 estimates the refrigerant leakage rate based on detection signals from various sensors in the air conditioner. The method for estimating the refrigerant leak rate in the leak rate estimating unit 32 is not particularly limited, and an existing technique can be adopted. For example, using the technique disclosed in Japanese Patent No. 4799563, first, an operation of detecting the refrigerant charge amount filled in the refrigerant circuit from the information of the pressure and temperature of the refrigerant is performed a plurality of times, and the refrigerant charge amount for each time Is calculated. Then, the refrigerant leakage rate can be estimated by dividing the difference between the respective refrigerant charging amounts by the detection operation interval time. In addition, for example, a method disclosed in Japanese Patent Application Laid-Open No. 2002-5548 may be adopted in which the rate of decrease in compressor operating current during compressor operation is estimated as the refrigerant leakage rate. The leak rate estimation unit 32 estimates the leak rate independently of the detection result of the refrigerant leak detection sensor 23.
 劣化検知部33は、冷媒漏洩検知センサー23の検知結果と、漏洩速度推定部32の推定結果とに基づいて冷媒漏洩検知センサー23の検知感度の低下を検知する。具体的には劣化検知部33は、漏洩速度推定部32で検知された冷媒漏洩速度が、検知感度の低下を判断するための基準値以上であって、かつ、冷媒漏洩検知センサー23で冷媒漏洩が一度も検知されていない場合、冷媒漏洩検知センサー23の検知感度が低下している、と判断する。冷媒漏洩検知センサー23の検知感度が低下している状況では、冷媒漏洩検知センサー23で冷媒漏洩有りと検知されたときの実際の冷媒濃度が、本来、冷媒漏洩有りと検知されるべき冷媒濃度よりも高くなっていることになる。 The deterioration detection unit 33 detects a decrease in detection sensitivity of the refrigerant leak detection sensor 23 based on the detection result of the refrigerant leak detection sensor 23 and the estimation result of the leak rate estimation unit 32. Specifically, the deterioration detection unit 33 has a refrigerant leakage rate detected by the leakage rate estimation unit 32 that is equal to or higher than a reference value for determining a decrease in detection sensitivity, and the refrigerant leakage detection sensor 23 performs refrigerant leakage. Is not detected at all, it is determined that the detection sensitivity of the refrigerant leakage detection sensor 23 is lowered. In a situation where the detection sensitivity of the refrigerant leak detection sensor 23 is lowered, the actual refrigerant concentration when the refrigerant leak detection sensor 23 detects that there is a refrigerant leak is higher than the refrigerant concentration that should be detected as having a refrigerant leak. Will be higher.
 次に、図1を参照して空気調和装置の冷凍サイクルの動作について説明する。 Next, the operation of the refrigeration cycle of the air conditioner will be described with reference to FIG.
(暖房運転)
 暖房運転では、四方弁12が図1の点線で示される状態に切り換えられる。空気調和装置において、暖房運転時は、圧縮機11で圧縮された冷媒は高温高圧のガス冷媒となり、四方弁12を通り室内熱交換器21に送り込まれる。室内熱交換器21に流入した冷媒は、室内送風機22で搬送される室内空気と熱交換し、放熱することにより液化する。液化した冷媒は冷媒容器15を経て、減圧装置14で減圧されて気液二相状態となる。気液二相状態の冷媒は、室外熱交換器13に流入し、室外送風機16で搬送される室外空気と熱交換し、吸熱することによりガス化し、圧縮機11へ戻される。以上のように冷媒が冷媒回路を循環することにより暖房運転を行う。
(Heating operation)
In the heating operation, the four-way valve 12 is switched to the state indicated by the dotted line in FIG. In the air conditioner, during the heating operation, the refrigerant compressed by the compressor 11 becomes a high-temperature and high-pressure gas refrigerant and is sent to the indoor heat exchanger 21 through the four-way valve 12. The refrigerant flowing into the indoor heat exchanger 21 is liquefied by exchanging heat with the indoor air conveyed by the indoor blower 22 and dissipating heat. The liquefied refrigerant passes through the refrigerant container 15 and is decompressed by the decompression device 14 to be in a gas-liquid two-phase state. The refrigerant in the gas-liquid two-phase state flows into the outdoor heat exchanger 13, exchanges heat with outdoor air conveyed by the outdoor blower 16, gasifies by absorbing heat, and returns to the compressor 11. As described above, the heating operation is performed by circulating the refrigerant through the refrigerant circuit.
(冷房運転)
 冷房運転では、四方弁12が図1の実線で示される状態に切り換えられる。空気調和装置において、冷房運転時は、圧縮機11で圧縮された冷媒は高温高圧のガス冷媒となり、四方弁12を通り室外熱交換器13に送り込まれる。室外熱交換器13に流入した冷媒は、室外送風機16で搬送される室外空気と熱交換し、放熱することにより液化する。液化した冷媒は減圧装置14で減圧されて気液二相状態となり、冷媒容器15を経て、室内熱交換器21に流入する。室内熱交換器21に流入した冷媒は、室内送風機22で搬送される室内空気と熱交換し、吸熱することによりガス化し、圧縮機11へ戻される。以上のように冷媒が冷媒回路を循環することにより冷房運転を行う。
(Cooling operation)
In the cooling operation, the four-way valve 12 is switched to the state shown by the solid line in FIG. In the air conditioner, during the cooling operation, the refrigerant compressed by the compressor 11 becomes a high-temperature and high-pressure gas refrigerant, which is sent to the outdoor heat exchanger 13 through the four-way valve 12. The refrigerant flowing into the outdoor heat exchanger 13 is liquefied by exchanging heat with the outdoor air conveyed by the outdoor blower 16 and dissipating heat. The liquefied refrigerant is decompressed by the decompression device 14 to become a gas-liquid two-phase state, and flows into the indoor heat exchanger 21 through the refrigerant container 15. The refrigerant that has flowed into the indoor heat exchanger 21 exchanges heat with the indoor air conveyed by the indoor blower 22, gasifies by absorbing heat, and is returned to the compressor 11. As described above, the refrigerant circulates through the refrigerant circuit to perform the cooling operation.
 図3は、本発明の実施の形態1における空気調和装置の冷媒漏洩検知センサー劣化検知処理の流れを示すフローチャートである。図3のフローチャートは、冷媒漏洩検知センサーの劣化検知タイミング毎に行われる。なお、図3に図示していないが、空気調和装置は、常時又は適宜のタイミングで冷媒漏洩検知センサー23にて冷媒漏洩が有るかどうかをチェックしているものとする。 FIG. 3 is a flowchart showing the flow of the refrigerant leak detection sensor deterioration detection process of the air-conditioning apparatus according to Embodiment 1 of the present invention. The flowchart of FIG. 3 is performed at every deterioration detection timing of the refrigerant leakage detection sensor. Although not shown in FIG. 3, it is assumed that the air conditioner checks whether there is a refrigerant leak at the refrigerant leak detection sensor 23 at all times or at an appropriate timing.
 空気調和装置は、冷媒漏洩検知センサー23の劣化検知タイミングとなると、漏洩速度推定部32が冷媒漏洩速度の推定を行う(S1)。漏洩速度推定部32における冷媒漏洩速度の推定は、上述したように従来公知の技術を用いて行えばよい。そして、劣化検知部33は、漏洩速度推定部32で推定された冷媒漏洩速度が基準値以上、かつ、冷媒漏洩検知センサー23で冷媒漏洩が一度も検知されていないかどうかをチェックする(S2)。劣化検知部33は、冷媒漏洩速度が基準値以上であって、かつ、冷媒漏洩検知センサー23で冷媒漏洩が一度も検知されていない場合、冷媒漏洩検知センサー23の検知感度が低下していると判断する。 In the air conditioner, when the deterioration detection timing of the refrigerant leakage detection sensor 23 comes, the leakage speed estimation unit 32 estimates the refrigerant leakage speed (S1). The estimation of the refrigerant leakage rate in the leakage rate estimation unit 32 may be performed using a conventionally known technique as described above. Then, the deterioration detection unit 33 checks whether or not the refrigerant leakage rate estimated by the leakage rate estimation unit 32 is equal to or higher than a reference value and the refrigerant leakage detection sensor 23 has never detected the refrigerant leakage (S2). . When the refrigerant leakage rate is equal to or higher than the reference value and the refrigerant leakage detection sensor 23 has never detected the refrigerant leakage, the deterioration detection unit 33 has a reduced detection sensitivity of the refrigerant leakage detection sensor 23. to decide.
 劣化検知部33におけるこの判断を受けて制御装置31は、冷媒漏洩時の所定制御を実施する(S3)。すなわち、制御装置31は、リモコン34の表示部35に「センサー感度低下」の旨、表示して報知する。この報知は、上述したようにリモコン34の表示部35に限られず、音声により通知してもよいし、また、室内機2の表示部(図示せず)、室外機1の表示部(図示せず)に表示して報知するようにしてもよい。この報知により、冷媒漏洩検知センサー23の感度が低下していることをユーザーあるいはサービスマンに知らせることができ、冷媒漏洩検知センサー23の交換、修理を促すことが可能となる。 In response to this determination in the deterioration detection unit 33, the control device 31 performs predetermined control when the refrigerant leaks (S3). In other words, the control device 31 displays and notifies the display unit 35 of the remote controller 34 that “sensor sensitivity is reduced”. This notification is not limited to the display unit 35 of the remote controller 34 as described above, and may be notified by voice, or the display unit (not shown) of the indoor unit 2 and the display unit (not shown) of the outdoor unit 1. You may make it display and alert | report. By this notification, it is possible to notify the user or service person that the sensitivity of the refrigerant leak detection sensor 23 is reduced, and it is possible to prompt the user to replace or repair the refrigerant leak detection sensor 23.
 また、制御装置31は、冷媒漏洩時の所定制御として、一定時間、室内送風機22を運転して周囲空気の撹拌を行い、室内の冷媒濃度が着火濃度範囲内に入るのを防止する。なお、ここでは、冷媒漏洩検知センサー23の感度低下を検知したのであって、冷媒漏洩自体を検知したわけではないが、冷媒漏洩検知センサー23の感度低下により冷媒漏洩を見過ごしている可能性を否定できないため、冷媒漏洩検知時に通常行う制御と同様の制御を行うようにしている。 In addition, the control device 31 operates the indoor blower 22 for a certain period of time as a predetermined control when the refrigerant leaks, and stirs the ambient air to prevent the indoor refrigerant concentration from entering the ignition concentration range. In addition, although the sensitivity fall of the refrigerant | coolant leak detection sensor 23 was detected here and not the refrigerant | coolant leak itself was detected, possibility that the refrigerant | coolant leak was overlooked by the sensitivity fall of the refrigerant | coolant leak detection sensor 23 is denied. Since this is not possible, control similar to that normally performed when refrigerant leakage is detected is performed.
 一方、ステップS2で冷媒漏洩検知センサー23の感度低下が検知されない場合、冷媒漏洩検知センサー劣化検知処理を終了する。 On the other hand, if the sensitivity decrease of the refrigerant leak detection sensor 23 is not detected in step S2, the refrigerant leak detection sensor deterioration detection process is terminated.
 以上説明したように、本実施の形態1によれば、冷媒漏洩検知センサー23の検知感度の低下を検知して、報知するようにした。このため、冷媒漏洩検知センサー23の検知感度低下をユーザーあるいはサービスマンに知らせ、冷媒漏洩検知センサー23の交換、修理を促すことが可能なる。その結果、冷媒漏洩検知センサー23の検知感度低下による高冷媒濃度領域の発生、冷媒着火の可能性を減らすことができる。 As described above, according to the first embodiment, a decrease in detection sensitivity of the refrigerant leakage detection sensor 23 is detected and notified. For this reason, it is possible to notify the user or serviceman of a decrease in detection sensitivity of the refrigerant leak detection sensor 23 and to prompt replacement or repair of the refrigerant leak detection sensor 23. As a result, it is possible to reduce the possibility of occurrence of a high refrigerant concentration region and refrigerant ignition due to a decrease in detection sensitivity of the refrigerant leakage detection sensor 23.
 また、冷媒漏洩検知センサー23の劣化を検知するアルゴリズムとして、漏洩速度推定部32で検知された冷媒漏洩速度が、検知感度の低下を判断するための基準値以上であって、かつ、冷媒漏洩検知センサー23で冷媒漏洩が一度も検知されていない場合、冷媒漏洩検知センサー23の検知感度が低下していると判断するようにした。このため、冷媒漏洩検知センサー23の検知感度低下による高冷媒濃度領域の発生、冷媒着火の可能性を減らすことができる。従来は冷媒漏洩検知センサー23の検知感度低下を検知して報知するという観点そのものが無かったことから、本実施の形態1の技術は非常に有効である。 Further, as an algorithm for detecting the deterioration of the refrigerant leakage detection sensor 23, the refrigerant leakage speed detected by the leakage speed estimation unit 32 is equal to or higher than a reference value for determining a decrease in detection sensitivity, and the refrigerant leakage detection is performed. When the sensor 23 has never detected the refrigerant leakage, it is determined that the detection sensitivity of the refrigerant leakage detection sensor 23 is lowered. For this reason, generation | occurrence | production of the high refrigerant | coolant concentration area | region by the detection sensitivity fall of the refrigerant | coolant leakage detection sensor 23, and the possibility of refrigerant | coolant ignition can be reduced. Conventionally, the technique of the first embodiment is very effective because there is no viewpoint of detecting and notifying the detection sensitivity decrease of the refrigerant leakage detection sensor 23 in the past.
 なお、本実施の形態1では、劣化検知のタイミングについて、常時又は適宜のタイミングで行うとしたが、冷媒漏洩検知と連携して行うようにしてもよい。すなわち、冷媒漏洩検知を、例えば手動操作あるいはスケジュール設定のタイミングで行うようにしている場合、冷媒漏洩検知タイミングに続いて劣化検知を行うようにしてもよい。 In the first embodiment, the deterioration detection timing is always performed or at an appropriate timing, but may be performed in cooperation with refrigerant leakage detection. That is, when the refrigerant leakage detection is performed, for example, at the timing of manual operation or schedule setting, the deterioration detection may be performed following the refrigerant leakage detection timing.
 また、上記実施の形態1では、冷媒漏洩検知センサー23を室内機側に設けた構成を例示したが、室外機側に設け、室外機側における冷媒漏洩の検知、冷媒漏洩速度の推定を行うようにしてもよい。 Further, in the first embodiment, the configuration in which the refrigerant leakage detection sensor 23 is provided on the indoor unit side is illustrated. However, the refrigerant leakage detection sensor 23 is provided on the outdoor unit side to detect refrigerant leakage and estimate the refrigerant leakage speed. It may be.
 また、上記実施の形態1では、冷凍サイクル装置が空気調和装置であるものとして説明したが、冷蔵冷凍倉庫等を冷却する冷却装置としてもよい。 In the first embodiment, the refrigeration cycle apparatus is described as an air conditioner. However, the refrigeration cycle apparatus may be a cooling apparatus that cools a refrigerated warehouse or the like.
 1 室外機、2 室内機、11 圧縮機、12 四方弁、13 室外熱交換器、14 減圧装置、15 冷媒容器、16 室外送風機、17 吐出温度センサー、21 室内熱交換器、22 室内送風機、23 冷媒漏洩検知センサー、31 制御装置、31a 室外機制御装置、31b 室内機制御装置、32 漏洩速度推定部、33 劣化検知部、34 リモコン、35 表示部。 1 outdoor unit, 2 indoor unit, 11 compressor, 12 four-way valve, 13 outdoor heat exchanger, 14 decompression device, 15 refrigerant container, 16 outdoor blower, 17 discharge temperature sensor, 21 indoor heat exchanger, 22 indoor blower, 23 Refrigerant leak detection sensor, 31 control device, 31a outdoor unit control device, 31b indoor unit control device, 32 leak rate estimation unit, 33 deterioration detection unit, 34 remote control, 35 display unit.

Claims (2)

  1.  圧縮機、凝縮器、減圧装置及び蒸発器を備え、可燃性冷媒が循環する冷媒回路と、
     前記冷媒回路からの冷媒漏洩の速度を推定する漏洩速度推定部と、
     前記冷媒回路からの冷媒漏洩を検知する冷媒漏洩検知センサーと、
     前記漏洩速度推定部で推定された冷媒漏洩速度が基準値以上、かつ、前記冷媒漏洩検知センサーで冷媒漏洩が一度も検知されていない場合、前記冷媒漏洩検知センサーの検知感度が低下したと判断する劣化検知部と、
     前記劣化検知部で前記冷媒漏洩検知センサーの検知感度の低下が検知された場合にその旨を報知する報知部とを備えた冷凍サイクル装置。
    A refrigerant circuit including a compressor, a condenser, a pressure reducing device, and an evaporator, in which a combustible refrigerant circulates;
    A leakage rate estimation unit for estimating a rate of refrigerant leakage from the refrigerant circuit;
    A refrigerant leakage detection sensor for detecting refrigerant leakage from the refrigerant circuit;
    If the refrigerant leak rate estimated by the leak rate estimation unit is equal to or higher than a reference value and no refrigerant leak has been detected by the refrigerant leak detection sensor, it is determined that the detection sensitivity of the refrigerant leak detection sensor has decreased. A degradation detector;
    A refrigeration cycle apparatus comprising: an informing unit for informing that a deterioration in detection sensitivity of the refrigerant leakage detection sensor is detected by the deterioration detection unit.
  2.  前記凝縮器又は前記蒸発器として機能する室内熱交換器を有する室内機を備え、
     前記室内機に前記冷媒漏洩検知センサーが配置されている請求項1記載の冷凍サイクル装置。
    An indoor unit having an indoor heat exchanger that functions as the condenser or the evaporator;
    The refrigeration cycle apparatus according to claim 1, wherein the refrigerant leakage detection sensor is arranged in the indoor unit.
PCT/JP2015/079850 2015-10-22 2015-10-22 Refrigeration cycle device WO2017068686A1 (en)

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