WO2017057169A1 - Garment cleaning agent composition - Google Patents

Abstract

The present invention is a garment cleaning agent composition which includes component (a) and component (b), the ratio of a compound where n is 0 in general formula (1) and a compound where n is 1 in general formula (1) in the component (a) being 65 to 95% by mass, and the mass of the component (b) with respect to 100 parts by mass of a sum of the mass of the compound where n is 0 in general formula (1) and the compound where n is 1 in general formula (1) being 5 to 17 parts by mass. Component (a): Sulfate ester salt represented by general formula (1) R-O-(AO)_n-SO₃M (1) (In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, n is an integer of 0 to 20, and M is a cation.) Component (b): Amphoteric surfactant.

Description

Cleaning composition for clothing

The present invention relates to a cleaning composition for clothing, a hand-washing washing method, and a method for improving the foaming property at the time of rinsing in washing of the cleaning composition for clothing.

BACKGROUND ART Washing machines are spreading in Asian regions such as Greater China and ASEAN, but hand-washing still exists. Even in Japan, hand washing and washing using containers such as washbasins is performed. In hand-washing, many users wash clothes by dissolving detergent in water. In hand-washing, many workers prefer to have moderate foaming during washing.

Japanese Patent Publication No. 10-504049 discloses an anionic surfactant selected from alkyl sulfates and alkyl ethoxy sulfates, polyhydroxy fatty acid amides, and amine oxides under predetermined conditions. A laundry detergent composition having excellent mildness is disclosed.
Japanese National Publication No. 9-512860 discloses a baby duty liquid laundry detergent composition which contains an anionic surfactant, an amine oxide and a fatty acid and which is excellent in terms of grease and oil stain removal. An improvement in cleaning properties by a complex of amine oxide and fatty acid is disclosed.
Japanese Patent Application Laid-Open No. 2001-199993 discloses a liquid cleaning agent containing an anionic surfactant, an amine oxide and a specific compound and having an excellent cleaning effect.
Japanese Patent Application Laid-Open No. 2009-132823 discloses a liquid detergent containing a polyoxyalkylene alkyl sulfate ester salt containing a propylene oxide group and an ethylene oxide group and an amine oxide in a specific ratio and having excellent detergency and low-temperature stability. A composition is disclosed.
It is well known that amine oxides increase foaming during washing.

SUMMARY OF THE INVENTION Any of JP-T-10-504049, JP-A-9-512860, JP-A-2001-199993, and JP-A-2009-132823 relates to the improvement of foaming property during rinsing. There are no assignments.
The present invention provides a detergent composition for clothing that has good foaming properties during washing and excellent foaming properties during rinsing.

The present invention contains the following components (a) and (b):
In the component (a), the ratio of the compound in which n in the general formula (1) is 0 and the compound in which n is 1 in the general formula (1) is 65% by mass or more and 95% by mass or less,
The mass of the component (b) is 5 parts by mass or more and 17 parts by mass with respect to 100 parts by mass in total of the mass of the compound where n in the general formula (1) is 0 and the mass of the compound where n is 1 in the general formula (1). Less than or equal to
The present invention relates to a cleaning composition for clothing.
(A) Component: sulfate ester salt represented by the following general formula (1) R—O— (AO) _n —SO ₃ M (1)
[In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, and n is 0 to 20) The following integers, where M is a cation. ]
(B) Component: Amphoteric surfactant

The present invention also relates to a hand-washing washing method in which clothes are hand-washed using a cleaning solution prepared by mixing the above-described clothes cleaning composition of the present invention and water, and then the clothes are rinsed with water.

In addition, the present invention is a method for improving the foaming property at the time of rinsing in the laundry of the laundry detergent composition containing the following components (a) and (b),
In the component (a), the ratio of the compound in which n in the general formula (1) is 0 and the compound in which n is 1 in the general formula (1) is 65% by mass or more and 95% by mass or less,
The mass of the component (b) is 5 parts by mass or more and 17 parts by mass with respect to 100 parts by mass in total of the mass of the compound in which n in the general formula (1) is 0 and the mass of the compound in which n is 1 in the general formula (1). Less than or equal to
Regarding the method.
(A) Component: sulfate ester salt represented by the following general formula (1) R—O— (AO) _n —SO ₃ M (1)
[In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, and n is 0 to 20) The following integers, where M is a cation. ]
(B) Component: Amphoteric surfactant

According to the present invention, it is possible to obtain a detergent composition for clothing having good foaming properties during washing and excellent foaming properties during rinsing.

MODE FOR CARRYING OUT THE INVENTION [Cleaning Composition for Clothing]
The inventor of the present invention relates to a compound in which n in general formula (1) is 0 and a compound in which n in general formula (1) is 1 (hereinafter collectively referred to as component (a1)) in component (a). It has been found that the ratio and the ratio of the component (b) to the component (a1) are involved in foaming during washing and bubble breakage during rinsing. Based on this, in the present invention, the proportion of (a1) in the component (a) is 65% by mass or more and 95% by mass or less, and (b) with respect to 100 parts by mass in total of the mass of the component (a1) in the composition. The mass of the component is 5 to 17 parts by mass.
The reason why the effect of the present invention is obtained is not necessarily clear, but is estimated as follows. The component (a1) forms a complex with the component (b) in the cleaning liquid having a relatively high concentration, so that the foam film is stabilized and foaming is maintained. On the other hand, in the rinsing step that is the next step of the washing step, the concentration of the components (a1) and (b) in the rinsing water is lowered, so that the complex formed in the washing solution is dissociated and the washing solution contains The bubble film becomes more unstable. Therefore, it is presumed that the foam formed from the rinse water is easily destroyed and the foam breakage is improved.

<(A) component>
The component (a) is a sulfate ester salt represented by the following general formula (1).
R—O— (AO) _n —SO ₃ M (1)
[In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, and n is 0 to 20) The following integers, where M is a cation. ]

In general formula (1), R is preferably an alkyl group, more preferably a chain alkyl group. R is preferably 10 or more and 16 or less in terms of detergency. R is preferably a chain alkyl group having 10 or more carbon atoms and 16 or less carbon atoms.

In General Formula (1), AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms. AO includes, for example, one or more groups selected from an ethyleneoxy group and a propyleneoxy group.
When n in the general formula (1) is an integer of 2 or more and 20 or less, AO can contain an ethyleneoxy group and a propyleneoxy group. When AO contains an ethyleneoxy group and a propyleneoxy group, the bonding mode of the ethyleneoxy group and the propyleneoxy group is bonded to either the random type or the block type, or the random type and the block type are mixed and bonded. It may be a thing. In view of easy availability and production, AO is preferably an ethyleneoxy group. AO preferably contains an ethyleneoxy group.

In general formula (1), n is an integer of 0 or more and 20 or less. n is preferably an integer of 18 or less, more preferably 15 or less.

In the present invention, the proportion of the component (a1) in the component (a), that is, the compound in which n is 0 in the general formula (1) and the compound in which n is 1 in the general formula (1) is 65 masses. % To 95% by mass. When this ratio exceeds 95 mass%, the foamability at the time of washing is inferior. Moreover, when this ratio is less than 65 mass%, the foaming property at the time of a rinse is inferior.
The ratio of the component (a1) in the component (a) is preferably 66% by mass or more, preferably 68% by mass or more, preferably 70% by mass or more, and 73% by mass in terms of further improving the foaming property during rinsing. % Or more, preferably 75% by weight or more, preferably 76% by weight or more, preferably 78% by weight or more, preferably 80% by weight or more, preferably 82% by weight or more, preferably 84% by weight or more, 86% by weight The above is preferable, 88 mass% or more is preferable, 90 mass% or more is preferable, and 92 mass% or more is preferable. The upper limit is 95% by mass.

Moreover, 50 mass% or more is preferable and the ratio of the compound whose n in General formula (1) is 0 is preferable in the point which the foaming property at the time of a rinse improves further, and 52 mass% or more is preferable. 54 mass% or more, preferably 56 mass% or more, preferably 58 mass% or more, preferably 60 mass% or more, preferably 62 mass% or more, preferably 64 mass% or more, preferably 66 mass% or more, 68 mass% or more is preferable, 70 mass% or more is preferable, 72 mass% or more is preferable, 74 mass% or more is preferable, 76 mass% or more is preferable, 78 mass% or more is preferable, 80 mass% or more is preferable, 82 % By mass or more is preferable, 84% by mass or more is preferable, 86% by mass or more is preferable, and the upper limit is preferably 92% by mass.

Moreover, the ratio of the compound in which n in the general formula (1) is 6 or more and 20 or less in the component (a) is preferably 10% by mass or less, and 9% by mass in terms of further improving the foaming property at the time of rinsing. The following is preferable, 8 mass% or less is preferable, 7 mass% or less is preferable, 6 mass% or less is preferable, 5 mass% or less is preferable, 4 mass% or less is preferable, and 3 mass% or less is preferable. The lower limit of this ratio is 0% by mass or more. Furthermore, the lower limit of this ratio is 0 mass% or more than 0 mass%.

In the present invention, in component (a), the component ratio of the general formula (1) different compounds n in the general formula (1) n of different compounds in the compound of the SO 3 _M group is replaced with H in A composition ratio can be adopted. For example, the area ratio obtained by analyzing the distribution of compounds with different n in the compound in which the SO ₃ M group in the general formula (1) is replaced with H is regarded as a mass fraction. Can be used as the constituent ratio of the different compounds of n in the general formula (1) in the component (a).
In addition, even when the component (a) represented by the general formula (1) is available, when it is difficult to measure the composition ratio as it is, the component (a) is acid-decomposed to form a SO ₃ M group. Can be generated, and the constituent ratio of n different compounds in the compound can be used as the constituent ratio of n different compounds in the general formula (1) in the component (a). In this case, specifically, the component (a) was obtained by acid decomposition to produce a compound in which the SO ₃ M group was replaced with H, and then the distribution of n in the compound was analyzed by gas chromatography. The area ratio is regarded as a mass fraction, and this can be used as a constituent ratio of the different compounds of n in the general formula (1) in the component (a).

In the case of employing the above method, an example of analysis conditions by gas chromatography and the above-mentioned acid decomposition conditions are shown below.
<Analysis conditions for gas chromatography>
GC equipment; Agilent Technologies, 7890A
Column: DB-5 manufactured by Agilent Technologies, Inc. (30 m, inner diameter 0.25 mm, film thickness 0.25 μm)
Detector; FID
Carrier; helium gas, 1 mL / min
Temperature raising condition: The temperature is raised from 100 ° C. to 325 ° C. at 5 ° C./min. Thereafter, hold at 325 ° C. for 35 minutes.
Sample pretreatment: 50 mg of a sample is placed in a 2 mL vial, 1 mL of a trimethylsilylating agent (manufactured by GL Sciences) is added and mixed, and reacted at 30 ° C. for 5 minutes.

<Conditions for acid decomposition of component (a)>
Place 4 g of sample into a 300 mL glass Erlenmeyer flask with a slit. 200 mL of 2N hydrochloric acid and zeolite are put into an Erlenmeyer flask, and an air-cooled tube with a slot is set. The Erlenmeyer flask is placed in a 140 ° C. oil bath and refluxed for 3 hours, and then cooled to 30 ° C. Add 1 drop of 1% phenolphthalein solution in a Erlenmeyer flask with a Pasteur pipette. Next, 35% aqueous sodium hydroxide solution is added until the contents in the Erlenmeyer flask become a light pink color.
Transfer the contents to a 1000 mL separatory funnel, add 200 mL petroleum ether and extract 3 times. The petroleum ether layer is washed with 50 mL of a 10% aqueous sodium chloride solution three times, and then 20 g of anhydrous sodium sulfate is added for dehydration. A solution obtained by removing anhydrous sodium sulfate by filtration is placed in a 500 mL triangle, and topped with petroleum ether.

In general formula (1), M is a cation that forms a salt. Examples of M include alkali metal ions such as sodium ion and potassium ion, ammonium ion, and alkanol ammonium ion. The alkanol ammonium ion is preferably an alkanol ammonium ion having 2 to 6 carbon atoms in total.

<(B) component>
Component (b) is an amphoteric surfactant. In this invention, (b) component has the effect | action which improves the foaming property at the time of washing. In addition, in the present invention, the component (b) is used in combination with a specific compound of the component (a) at a specific mass ratio, so that the foaming property at the time of rinsing is maintained while maintaining the foaming property at the time of washing. Can be improved.

Preferred component (b) includes one or more amphoteric surfactants selected from amine oxides and betaines. The component (b) is more preferably an amine oxide.

The amine oxide is preferably an amine oxide having an aliphatic hydrocarbon group having 7 to 18 carbon atoms. Specific examples include compounds represented by the following general formula (b1).

[Wherein, R ^1b is a group having 8 to 18 carbon atoms when k is 0 or when k is 1 and X is a group selected from —O (CO) — and — (NH) (CO) —). An aliphatic hydrocarbon group having 7 to 17 carbon atoms, wherein k is 1 and X is a group selected from — (CO) O— and — (CO) (NH) — R ^2b is an alkylene group having 1 to 6 carbon atoms, and X is — (CO) O—, — (CO) (NH) —, —O (CO) —, — (NH) (CO )-. k is a number of 0 or 1, and R ^3b and R ^4b are each an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms. ]

In the general formula (b1), R ^1b is a group when k is 0 or when k is 1 and X is a group selected from —O (CO) — and — (NH) (CO) — An aliphatic hydrocarbon group having 8 to 16 carbon atoms is preferable, and an aliphatic hydrocarbon group having 10 to 16 carbon atoms is more preferable, in that the foaming property during rinsing can be improved while maintaining foamability. An alkyl group or alkenyl group having 10 to 14 carbon atoms is more preferable, and an alkyl group or alkenyl group having 12 to 14 carbon atoms is preferable.
In the general formula (b1), R ^1b is a group having 7 to 17 carbon atoms when k is 1 and X is a group selected from — (CO) O— and — (CO) (NH) —. The aliphatic hydrocarbon group is preferably an aliphatic hydrocarbon group having 7 to 15 carbon atoms, and having 9 to 15 carbon atoms in that it can improve foaming properties during rinsing while maintaining foamability during washing. The following aliphatic hydrocarbon groups are more preferred, alkyl groups or alkenyl groups having 9 to 13 carbon atoms are more preferred, and alkyl groups or alkenyl groups having 11 to 13 carbon atoms are still more preferred.
In the general formula (b1), X is preferably — (CO) O— or — (CO) (NH) — from the viewpoint that the foaming property at the time of rinsing can be improved while maintaining the foaming property at the time of washing. -(CO) (NH)-is more preferred.
R ^2b preferably has 2 or 3 carbon atoms. R ^3b and R ^4b are preferably a methyl group.

More preferred specific compounds of amine oxide include N-lauryl-N, N-dimethylamine oxide, N-myristyl-N, N-dimethylamine oxide, N-palmityl-N, N-dimethylamine oxide, N- Lauroylaminopropyl-N, N-dimethylamine oxide, N-myristoylaminopropyl-N, N-dimethylamine oxide, N-palmitoylaminopropyl-N, N-dimethylamine oxide, N-lauryl-N-ethyl-N- Methylamine oxide, N-lauryl-N-methyl-N- (2-hydroxyethyl) amine oxide, N-myristyl-N-ethyl-N-methylamine oxide, N-myristyl-N-methyl-N- (2- Hydroxyethyl) amine oxide, N-palmityl-N-ethyl-N- Tylamine oxide, N-palmityl-N-methyl-N- (2-hydroxyethyl) amine oxide, N-lauroylaminopropyl-N-ethyl-N-methylamine oxide, N-lauroylaminopropyl-N-methyl-N -(2-hydroxyethyl) amine oxide, N-myristoylaminopropyl-N-ethyl-N-methylamine oxide, N-myristoylaminopropyl-N-methyl-N- (2-hydroxyethyl) amine oxide, N-palmitoyl Examples thereof include one or more compounds selected from aminopropyl-N-ethyl-N-methylamine oxide and N-palmitoylaminopropyl-N-methyl-N- (2-hydroxyethyl) amine oxide.

More preferred specific compounds of amine oxide include N-lauryl-N, N-dimethylamine oxide, N-myristyl-N, N-dimethylamine oxide, N-palmityl-N, N-dimethylamine oxide, N- One or more compounds selected from lauroylaminopropyl-N, N-dimethylamine oxide, N-myristoylaminopropyl-N, N-dimethylamine oxide, and N-palmitoylaminopropyl-N, N-dimethylamine oxide It is done.

As the betaine, betaine having a hydrocarbon group having 7 to 18 carbon atoms is preferable. Specific examples include compounds represented by the following general formula (b2).

[Wherein R ^5b is a group having 8 to 18 carbon atoms when j is 0 or when j is 1 and Y is a group selected from —O (CO) — and — (NH) (CO) —). An aliphatic hydrocarbon group having 7 to 17 carbon atoms in which j is 1 and Y is a group selected from — (CO) O— and — (CO) (NH) — R ^6b is an alkylene group having 1 to 6 carbon atoms. Y is a group selected from — (CO) O—, — (CO) (NH) —, —O (CO) —, — (NH) (CO) —, —O—, and j is 0 or 1 Is a number. R ^7b and R ^8b are each an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, and R ^9b is an alkylene group having 1 to 5 carbon atoms which may be substituted with a hydroxy group. Z is _{^{-SO 3 -, -OSO 3 -,}} -COO - a group selected from. ]

In the general formula (b2), R ^5b is a group at the time of washing when j is 0 or when j is 1 and Y is a group selected from —O (CO) — and — (NH) (CO) —. An aliphatic hydrocarbon group having 8 or more and 16 or less carbon atoms is preferable, and an aliphatic hydrocarbon group having 10 or more and 16 or less carbon atoms is more preferable, and the number of carbon atoms is more preferable in that the foaming property at the time of rinsing can be improved while maintaining foamability. 10 or more and 14 or less alkyl group or alkenyl group is more preferable.
In the general formula ^{(b2), R 5b} is, j is the Y in 1 - (CO) O -, - (CO) (NH) - from the case a group selected, having 7 to 17 carbon atoms The aliphatic hydrocarbon group is preferably an aliphatic hydrocarbon group having 7 to 15 carbon atoms, and having 9 to 15 carbon atoms in that it can improve foaming properties during rinsing while maintaining foamability during washing. The following aliphatic hydrocarbon groups are more preferable, and alkyl groups or alkenyl groups having 9 to 13 carbon atoms are more preferable.
In the general formula (b2), R ^6b is an alkylene group having 1 to 4 carbon atoms, more preferably an alkylene group having 2 or 3 carbon atoms, from the viewpoint of ease of production. R ^7b and R ^8b are preferably a methyl group, an ethyl group, or a hydroxyethyl group. R ^9b is preferably an alkylene group having 1 to 3 carbon atoms which may be substituted by a hydroxy group.
In general formula (b2), j is preferably 0.
In the general formula (b2), Z is preferably —SO ₃ ^— from the viewpoint that the foaming property at the time of rinsing can be improved while maintaining the foaming property at the time of washing.

More preferred specific compounds of betaine include lauryl (2-hydroxy-3-sulfopropyl) dimethylbetaine, myristyl (2-hydroxy-3-sulfopropyl) dimethylbetaine, and palmityl (2-hydroxy-3-sulfopropyl). ) One or more compounds selected from dimethylbetaine.

<(C) component>
The cleaning composition for clothing of the present invention can contain a nonionic surfactant as the component (c).
(C) Use of the component tends to improve the foaming property at the time of rinsing. Moreover, in the case where the garment cleaning composition of the present invention is a liquid garment cleaning composition containing water, in the present invention, a nonionic surfactant having a polyoxyalkylene group as component (c) is used. The viscosity of the composition can be reduced, and the metering of the composition becomes easier.

Component (c) is preferably a nonionic surfactant having a polyoxyalkylene group. Further, the component (c) is preferably a nonionic surfactant represented by the following general formula (c1).
R ^1c —O— (A′O) _m —H (c1)
[Wherein, R ^1c is an aliphatic hydrocarbon group having 8 to 18 carbon atoms, and A′O is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms. , M is the average added mole number of A′O, and is a number of 3 or more and 20 or less. ]

In the general formula (c1), the number of carbon atoms of R ^1c, while maintaining lathering properties during cleaning, in that it can further improve the defoaming property at the time of rinsing, preferably 10 or more, more preferably 12 or more, and 16 or less Is preferred.
In the general formula (c1), the number of carbon atoms of R ^1c is preferably 10 or more, preferably 16 or less, and more preferably 14 or less, from the viewpoint that the viscosity in the case of a liquid composition can be further reduced.
In addition, examples of the aliphatic hydrocarbon group represented by R ^{1c in} the general formula (c1) include an aliphatic hydrocarbon group selected from an alkyl group and an alkenyl group, and an alkyl group is preferable.
In the general formula (c1), m is an average added mole number of A′O, and is preferably 4 or more from the viewpoint that the foaming property at the time of rinsing can be maintained even if the foaming property at the time of washing is improved. 5 or more is preferable, 6 or more is preferable, 7 or more is preferable, 8 or more is preferable, 18 or less is preferable, 16 or less is preferable, 14 or less is preferable, and 12 or less is more preferable.
Further, in the general formula (c1), m is preferably 4 or more, preferably 5 or more, preferably 6 or more, preferably 7 or more, and 8 or more in that the viscosity of the liquid composition can be further reduced. Is preferable, 9 or more is preferable, 18 or less is preferable, 16 or less is preferable, and 14 or less is preferable.
In the general formula (c1), A′O is an alkyleneoxy group selected from a C 2 alkyleneoxy group and a C 3 alkyleneoxy group. A′O includes, for example, one or more groups selected from an ethyleneoxy group and a propyleneoxy group. It is preferable that A′O contains an ethyleneoxy group in that the foaming property at the time of washing can be maintained. A′O is preferably an ethyleneoxy group.

<Composition of detergent composition for clothing>
The clothing cleaning composition of the present invention uses the component (a) containing a predetermined amount of the component (a1), and the mass of the component (b) is 5 parts by mass or more and 17 parts by mass with respect to 100 parts by mass of the component (a1). By setting it as the following, the foaming property at the time of a rinse can be improved, maintaining the foaming property at the time of washing | cleaning.
In the present invention, the mass of the component (a) including the component (a1) is a value obtained by converting the counter ion to sodium, that is, a value converted to a sodium salt.

In the cleaning composition for clothing of the present invention, the mass of the component (b) is 5 parts by mass or more and 17 parts by mass or less with respect to 100 parts by mass in total of the mass of the component (a1).
The clothing detergent composition of the present invention has a mass of component (b) of 5 parts by mass or more with respect to a total of 100 parts by mass of component (a1) from the viewpoint of improving foamability during washing. 0.5 parts by mass or more, preferably 6 parts by mass or more, more preferably 6.5 parts by mass or more, further preferably 7 parts by mass or more, further preferably 8 parts by mass or more, and further preferably 9 parts by mass or more, 10 parts by mass or more is more preferable. And the washing | cleaning agent composition for clothing of this invention is the mass of (b) component with respect to a total of 100 mass parts of the mass of (a1) component from the point of the improvement of foaming property at the time of a rinse, 17 mass parts or less. Yes, 16.5 parts by mass or less is preferable, 16 parts by mass or less is more preferable, 15.5 parts by mass or less is further preferable, 15 parts by mass or less is further preferable, 14.5 parts by mass or less is further preferable, 14 parts by mass The following is more preferable, 13.5 parts by mass or less is further preferable, 13 parts by mass or less is further preferable, 12.5 parts by mass or less is further preferable, 12 parts by mass or less is further preferable, and 11.5 parts by mass or less is more preferable. 11 parts by mass or less is more preferable, and 10.5 parts by mass or less is more preferable.

The content of the component (a) in the garment cleaning composition of the present invention is the amount used per wash of the composition, the size of the article containing the garment cleaning composition, or one article. It can be determined as appropriate in consideration of the number of times per use and price. Moreover, it can determine suitably also with the kind of form of the cleaning composition for clothes. Examples of the form of the garment cleaning composition of the garment cleaning composition include powders, granules, bars, pastes and liquids.

As an example, the content of the component (a) in the garment cleaning composition of the present invention is 3% by mass or more in the composition from the viewpoint of improving detergency or improving foamability during washing. Is preferably 4% by mass or more, more preferably 5% by mass or more, further preferably 6% by mass or more, further preferably 7% by mass or more, further preferably 8% by mass or more, and further preferably 9% by mass or more. And, from the viewpoint of improving the foamability during rinsing, 30% by mass or less is preferable, 28% by mass or less is more preferable, 26% by mass or less is further preferable, 24% by mass or less is further preferable, and 22% by mass or less. Is more preferable, and 20 mass% or less is still more preferable.

When the washing | cleaning composition for clothing of this invention contains (c) component, it is 100 of mass of (a) component from a viewpoint which can further improve the foaming property at the time of a rinse, maintaining the foamability at the time of washing | cleaning. The mass of component (c) relative to parts by mass is preferably 9 parts by mass or more, preferably 10 parts by mass or more, more preferably 11 parts by mass or more, still more preferably 12 parts by mass or more, still more preferably 13 parts by mass or more, and 30 parts by mass or less, preferably 28 parts by mass or less, more preferably 26 parts by mass or less, further preferably 24 parts by mass or less, further preferably 22 parts by mass or less, and further preferably 20 parts by mass or less.
When the cleaning composition for clothing of the present invention is a liquid composition, particularly a liquid composition containing water, it is preferable to contain the component (c) in order to appropriately adjust the viscosity. When the cleaning composition for clothing of the present invention is a liquid composition, the mass of the component (c) with respect to 100 parts by mass of the mass of the component (a) from the viewpoint of reducing the viscosity of the composition to an appropriate range. Is preferably 10 parts by weight or more, more preferably 11 parts by weight or more, still more preferably 12 parts by weight or more, still more preferably 13 parts by weight or more, and preferably 26 parts by weight or less, more preferably 24 parts by weight or less, 22 mass parts or less are still more preferable, and 20 mass parts or less are still more preferable.

When the cleaning composition for clothing of the present invention is a liquid composition, it can contain water. As water, ion-exchanged water, distilled water, tap water, or ion-exchanged water containing hypochlorite can be used. Water is contained as the remainder of the liquid composition. Water is used in the remaining amount of components other than water. That is, water is used in an amount such that the sum of components other than water is 100% by mass.

When the garment cleaning composition of the present invention is a liquid composition containing water, the pH of the liquid composition itself at 25 ° C. is preferably 6 or more, more preferably 7 or more, still more preferably 8 or more, and , Preferably 11 or less, more preferably 10.5 or less, still more preferably 10 or less. The pH can be measured using a pH meter using a glass electrode.

<Optional component>
In the garment cleaning composition of the present invention, the following components (i) to (viii) can be blended as other components in amounts that do not impair the effects of the present invention.
(I) Water-soluble alkali inorganic salt The detergent composition for clothing of the present invention can contain a water-soluble alkali inorganic salt in order to further improve the detergency.
Here, “water-soluble” for the component (i) means that 1 g or more is dissolved in 100 g of water at 20 ° C. (I) It is preferable that 5 g or more, and also 10 g or more melt | dissolve in 100 g of water at 20 degreeC. The water-soluble alkali inorganic salt can be used alone or in combination of two or more.
Examples of the component (i) include water-soluble inorganic alkali metal salts. Although it does not specifically limit, For example, 1 or more types of water-soluble alkali inorganic salt chosen from carbonate and an amorphous silicate are mentioned. Furthermore, as the component (i), one or more water-soluble alkali inorganic salts selected from alkali metal carbonates, alkali metal hydrogen carbonates, alkali metal percarbonates and amorphous alkali metal silicates can be used. More specifically, one or more water-soluble alkali inorganic salts selected from sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate, sodium percarbonate and amorphous sodium silicate can be mentioned.
From the viewpoint of washing performance, foamability at the time of washing, and solubility, the carbonate is preferably one or more selected from alkali metal carbonates, alkali metal hydrogen carbonates and alkali metal percarbonates, One or more selected from alkali metal hydrogen carbonates are more preferable, alkali metal carbonates are more preferable, and sodium carbonate is still more preferable.
The content of the component (i) in the garment cleaning composition of the present invention is preferably 5% by mass or more, more preferably 10% by mass or more, and preferably 50% by mass or less from the viewpoint of detergency. 40 mass% or less is more preferable.

(Ii) Water-soluble neutral inorganic salt excluding component (i) Component (ii) can be used alone or in combination of two or more selected from water-soluble neutral inorganic salts excluding component (i) .
Here, “water-soluble” for the component (ii) means that 1 g or more is dissolved in 100 g of water at 20 ° C. Component (ii) is preferably dissolved in 5 g or more, more preferably 10 g or more in 100 g of water at 20 ° C.
The component (ii) is not particularly limited, and examples thereof include one or more water-soluble neutral inorganic salts selected from sulfates and metal chlorides. Preferably, it is a sulfate. More preferably, it is at least one water-soluble neutral inorganic salt selected from alkali metal sulfates and alkali metal chlorides. Furthermore, as the component (ii), one or more water-soluble neutral inorganic salts selected from sodium sulfate, potassium sulfate, sodium chloride and potassium chloride can be mentioned. Of these, sodium sulfate and / or sodium chloride is preferable, and sodium sulfate is more preferable from the viewpoint of improving foamability during washing.
The content of the component (ii) in the garment cleaning composition of the present invention is preferably 5% by mass or more, more preferably 10% by mass or more, and more preferably 15% by mass or more from the viewpoint of improving foamability at the time of washing. 20 mass% or more and 25 mass% or more is preferable, 30 mass% or more is more preferable, 70 mass% or less is preferable, 60 mass% or less is preferable, and 55 mass% or less is preferable.

(Iii) one or more metal ion capture builders selected from aluminosilicates, crystalline silicates and phosphates (iii-1), and metal ion capture builders selected from carboxylic acid polymer compounds (iii- One or more metal ion capture builders selected from 2), metal ion capture builders selected from aluminosilicates include crystalline or amorphous aluminosilicates. For example, natural zeolite such as chabazite, mondenite, erionite, faujasite, clinoptilolite, A type zeolite, X type zeolite, Y type zeolite, L type zeolite, omega type zeolite, P type zeolite, MAP type zeolite, etc. Synthetic zeolites can be mentioned.
Examples of the crystalline silicate include those having a molar ratio of SiO ₂ / M ₂ O of alkali metal silicate of 0.5 or more and 2.6 or less. Here, M represents an alkali metal atom.
Examples of the phosphate include orthophosphate, metaphosphate, trimetaphosphate, pyrophosphate, and tripolyphosphate. Examples of the salt include alkali metal salts such as sodium salt and potassium salt.
Examples of the carboxylic acid-based polymer compound include a repeating unit derived from monoethylenic mono- or dicarboxylic acid, and a high weight average molecular weight of 1,000 to 150,000 including a repeating unit derived from acrylic acid or maleic acid. Examples include molecular compounds. Such a polymer compound may be a salt such as an alkali metal salt such as a sodium salt or a potassium salt. Specifically, polyacrylic acid and its salt, polymaleic acid and its salt or acrylic acid-maleic acid copolymer and its salt are mentioned. Polyacrylic acid and its salts are preferred.
The content of the component (iii-1) in the garment cleaning composition of the present invention is preferably 0% by mass or more, preferably 30% by mass or less, more preferably 20% by mass or less, and more preferably. Is 9 mass% or less.
The content of the component (iii-2) in the garment cleaning composition of the present invention is preferably 0% by mass or more, preferably 4% by mass or less, more preferably 3% by mass or less, more preferably 2%. It is not more than mass%, more preferably not more than 1.5 mass%, more preferably not more than 1 mass%, and not less than 0.1 mass%.

(Iv) Anti-staining agent and dispersant [except for component (iii). ]
Examples of the component (iv) include polyacrylic acid, polymaleic acid, and polymers described in claims 1 to 21 (page 1, column 3, line 5 to page 3, column 4, line 14) of JP-A-59-62614. Antifouling agents or dispersants may be mentioned. The component (iv) is preferably polyacrylic acid, polymaleic acid or a salt thereof, more preferably polyacrylic acid or a salt thereof.
The content of the component (iv) in the garment cleaning composition of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 1% by mass or more, and preferably Is 10% by mass or less, more preferably 5% by mass or less, and still more preferably 3% by mass or less.

(V) Fluorescent dye As the component (v), for example, fluorescent dyes commercially available as Chino Pearl CBS (trade name, manufactured by Ciba Specialty Chemicals) and Whitetex SA (trade name, manufactured by Sumitomo Chemical Co., Ltd.) can be used. The content of (v) in the composition is preferably 0.01% by mass or more and 0.3% by mass or less in that the whiteness of the white garment can stand out.

(Vi) C1-C6 monovalent to trivalent alcohol (vi) Examples of the component include one or more alcohols selected from ethanol, ethylene glycol, propylene glycol, and glycerin.
In terms of the effect of easily dispersing the detergent composition for clothing of the present invention in water, the effect of suppressing the composition from separating into two or more phases during storage or the appearance becoming cloudy, etc. The content of (vi) in the composition is preferably 0.5% by mass or more, more preferably 1% by mass or more, and preferably 15% by mass or less, more preferably 10% by mass or less, still more preferably. 5% by mass or less.

(Vii) Dyes, fragrances, antibacterial preservatives, antifoaming agents such as silicone, and pH adjusters.

(Viii) Arbitrary Anionic Surfactant The detergent composition for clothing of the present invention can contain any anionic surfactant other than the component (a). As an arbitrary anionic surfactant, the alkylbenzene sulfonate which has a C8-C18 alkyl group is mentioned, for example. Any anionic surfactant such as the alkylbenzene sulfonate is usually a salt of an acid type compound. Examples of the salt include alkali metal salts such as sodium salt and potassium salt, and alkanol ammonium salt. Examples of the alkanol ammonium salt include alkanol ammonium salts having 2 to 6 carbon atoms in total.
From the standpoint of both maintaining foamability during washing and improving foamability during rinsing, it has an alkylbenzene sulfonate, preferably an alkyl group having 8 to 18 carbon atoms, contained in the detergent composition for clothing. The mass ratio of the content of alkylbenzene sulfonate and the content of total anionic surfactant contained in the cleaning composition for clothing is the content of alkylbenzene sulfonate / content of total anionic surfactant. 0 or more and less than 0.2, more preferably 0.19 or less, further preferably 0.18 or less, further preferably 0.15 or less, still more preferably 0.10 or less, still more preferably 0.05 or less, More preferably, it is 0.03 or less. The lower limit of this mass ratio may be 0 or greater than 0. This mass ratio is preferably zero. In addition, this mass ratio is calculated based on the quantity each converted into the sodium salt of the alkylbenzene sulfonate and the anionic surfactant.

Moreover, in this invention, the ratio of the (a) component in the anionic surfactant contained in the washing | cleaning composition for clothing of this invention is a viewpoint of the improvement of the foaming at the time of washing | cleaning, and the improvement of the foam breakage at the time of a rinse. Preferably, it is 80 mass% or more and 100 mass% or less. This ratio is more preferably 90% by mass or more, still more preferably 95% by mass or more, still more preferably 96% by mass or more, still more preferably 97% by mass or more, and further preferably 98% by mass or more. This proportion may be 100% by weight. This ratio is calculated based on the amounts of the component (a) and the anionic surfactant converted to sodium salts.

According to the present invention, there is provided a method for producing a cleaning composition for clothing containing the following components (a) and (b):
In the component (a), the ratio of the compound in which n in the general formula (1) is 0 and the compound in which n is 1 in the general formula (1) is 65% by mass or more and 95% by mass or less,
The mass of the component (b) is 5 parts by mass or more and 17 parts by mass with respect to 100 parts by mass in total of the mass of the compound in which n in the general formula (1) is 0 and the mass of the compound in which n is 1 in the general formula (1). Less than or equal to
A method for producing a cleaning composition for clothing is provided.
(A) Component: sulfate ester salt represented by the following general formula (1) R—O— (AO) _n —SO ₃ M (1)
[In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, and n is 0 to 20) The following integers, where M is a cation. ]
(B) Component: Amphoteric Surfactant The matters described in the garment cleaning composition of the present invention can be appropriately applied to this production method.

The present invention comprises (a) component and (b) component,
In the component (a), the ratio of the compound in which n in the general formula (1) is 0 and the compound in which n is 1 in the general formula (1) is 65% by mass or more and 95% by mass or less,
The mass of the component (b) is 5 parts by mass or more and 17 parts by mass with respect to 100 parts by mass in total of the mass of the compound in which n in the general formula (1) is 0 and the mass of the compound in which n is 1 in the general formula (1). Less than or equal to
Use of the composition as a cleaning composition for clothing is provided.
The matters described in the garment cleaning composition of the present invention can be appropriately applied to the composition according to this application.

[Method for Improving Foaming Property upon Rinsing in Laundry of Clothes Cleaning Composition]
As above-mentioned, the foaming property at the time of the rinse in washing | cleaning of the washing | cleaning agent composition for clothing containing (a) component and (b) component is (a) component on the specific conditions selected by this invention, (a1 ) Component and (b) component are used to improve.

The present invention is a method for improving the foaming property at the time of rinsing in the laundry of the laundry detergent composition containing the following components (a) and (b),
In the component (a), the ratio of the compound in which n in the general formula (1) is 0 and the compound in which n is 1 in the general formula (1) is 65% by mass or more and 95% by mass or less,
The mass of the component (b) is 5 parts by mass or more and 17 parts by mass with respect to 100 parts by mass in total of the mass of the compound in which n in the general formula (1) is 0 and the mass of the compound in which n is 1 in the general formula (1). Less than or equal to
Provide a method.
(A) Component: sulfate ester salt represented by the following general formula (1) R—O— (AO) _n —SO ₃ M (1)
[In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, and n is 0 to 20) The following integers, where M is a cation. ]
(B) Component: Amphoteric surfactant The matters described in the garment cleaning composition of the present invention can be appropriately applied to this method.

[How to wash clothes]
The detergent composition for clothing of the present invention is suitable for pickling and washing. The garment cleaning composition of the present invention is suitably used for soaking and washing as a cleaning liquid mixed with water. In the present invention, the soaking and laundering means a washing method in which clothes are soaked in a washing solution for a certain period of time. Preferably, in pickling washing, after being soaked in the cleaning liquid for a certain period of time, the clothes and the cleaning liquid are mixed and washed by stirring manually or by mechanical force such as a washing machine. The garment cleaning composition of the present invention is also suitable for washing by hand.

As a method for washing clothes using the detergent composition for clothes of the present invention, the detergent composition for clothes of the present invention and water having a German hardness of 1 ° DH to 30 ° DH are used per 1 liter of water. The washing | cleaning method of clothing which wash | cleans clothing by the washing | cleaning liquid mixed in the ratio of 1 g or more and 10 g or less of the washing | cleaning agent composition for clothing is mentioned.

As a method for cleaning clothing using the cleaning composition for clothing of the present invention, a cleaning liquid obtained by mixing the cleaning composition for clothing of the present invention with water having a German hardness of 1 ° DH to 30 ° DH In addition, there is a method for washing clothes in which the clothes are dipped for 10 to 120 minutes and then stirred and washed.

As a method for washing clothes using the detergent composition for clothes of the present invention, the detergent composition for clothes of the present invention and water having a German hardness of 1 ° DH to 30 ° DH are used per 1 liter of water. The washing | cleaning method of the clothing which stir-washes after immersing clothing for 10 to 120 minutes in the washing | cleaning liquid obtained by mixing in the ratio of 1 g or more and 10 g or less of the washing | cleaning agent composition for clothes is mentioned. .

In the cleaning method of the present invention, the time for immersing the clothing in the cleaning liquid is preferably 10 minutes or more, more preferably 20 minutes or more, from the viewpoint of cleanability of the soil containing protein. 120 minutes or less are preferable and 60 minutes or less are more preferable in terms of shortening the time required for washing.

In the cleaning method of the present invention, the temperature of the cleaning liquid in which the clothes are soaked is preferably 0 ° C. or higher, more preferably 5 ° C. or higher, 50 ° C. or lower, more preferably 40 ° C. or lower. It is preferable that the cleaning liquid has the above-mentioned temperature at the start of the soaking.

In the cleaning method of the present invention, the concentration of the cleaning composition of the present invention in the cleaning liquid is preferably 2.5 g / L or more, more preferably 3 g / L or more, and still more preferably 3.5 g from the viewpoint of detergency. / L or more. On the other hand, from the viewpoint of rinsing properties, it is preferably 10 g / L or less, more preferably 8 g / L or less, and still more preferably 6 g / L or less. This concentration is preferably 3.5 g / L or more and 5 g / L or less.

The total amount of the component (a) and the component (b) in the cleaning liquid used in the cleaning method of the present invention is preferably 0.02% by mass or more, more preferably 0.03% by mass or more, and economical viewpoint Therefore, the content is preferably 0.12% by mass or less, more preferably 0.09% by mass or less. When the said washing | cleaning liquid contains at least one of arbitrary anionic surfactant and (c) component, it is preferable that content including them is the said range.

In the cleaning method of the present invention, the water used for preparing the cleaning liquid can be water having a German hardness of 1 ° DH to 30 ° DH. 1 ° DH or more, and further 3 ° from the point that the effect of the present invention can be more practically realized in terms of detergency of soil containing excellent protein, foaming property at the time of washing, foam persistence, and foaming property at the time of rinsing. Water of DH or higher, 5 ° DH or higher, 6 ° DH or higher, 8 ° DH or higher, 9 ° DH or higher, or 10 ° DH or higher can be used. From the viewpoints of foaming properties during washing and foam persistence, water having a hardness of preferably 30 ° DH or less, more preferably 25 ° DH or less, and even more preferably 20 ° DH or less can be used. Hardness represents the total hardness determined by chelate titration method using ethylenediaminetetraacetic acid disodium salt.

In the garment washing method of the present invention, the German hardness is 1 ° DH or higher, further 3 ° DH or higher, further 5 ° DH or higher, further 6 ° DH or higher, further 8 ° DH or higher, and further 9 ° DH. Above, further 10 ° DH or more, and 30 ° DH or less, further 25 ° DH or less, further 20 ° DH or less, and 1 g or more of the garment cleaning composition of the present invention per liter of the water. And preferably 2.5 g or more, more preferably 3 g or more, more preferably 3.5 g or more, and 10 g or less, preferably 8 g or less, more preferably 6 g or less, more preferably 5 g or less. Can be used. Preferably, the clothes can be pickled and washed, and further pickled and hand-washed with the cleaning liquid prepared in such a ratio.

In the cleaning method of the present invention, the ratio (hereinafter referred to as bath ratio) between the volume (liter) of the cleaning liquid containing the cleaning composition for clothing of the present invention and the mass (kg) of the clothing is the amount of washing during hand washing. From the viewpoint of ease of treatment, 3 or more is preferable, and 5 or more is more preferable in [volume of washing liquid (liter)] / [mass of clothing (kg)]. The bath ratio is preferably 20 or less, more preferably 10 or less, from the viewpoints of detergency, foamability during washing, and foam persistence.

<Hand washing method>
The present invention relates to a hand-washing washing method in which clothes are hand-washed using a cleaning liquid prepared by mixing the clothes cleaning composition of the present invention and water, and then the clothes are rinsed with water.
Furthermore, the present invention provides a method for washing clothes after washing the clothes in a cleaning liquid prepared by mixing the cleaning composition for clothes of the present invention and water, or after applying the cleaning liquid to the clothes. It is related with the hand-washing washing method which rinses with water.

Examples of the hand-washing laundry method of the present invention include a method of washing clothes by bringing the clothes into contact with a cleaning liquid prepared from the clothing cleaning composition of the present invention. In the present invention, it is preferable that the contact time between the cleaning liquid and the clothing is long. The contact between the cleaning liquid and the clothing can be performed by dipping or coating, and is preferably performed by dipping. The hand-washing washing method of the present invention comprises a method of immersing clothing in a cleaning solution prepared by mixing the cleaning composition for clothing of the present invention and water, washing the clothing by hand, and then rinsing the clothing with water. The method is preferred. In the case of immersion, the immersion time is preferably 1 minute or more, more preferably 3 minutes or more, more preferably 5 minutes or more, and 120 minutes or less, further 60 minutes or less, further 45 minutes or less, and further 30 minutes or less. It is. The feature of the present invention is that it can be washed with rich foam even after being soaked in such an immersion time. The temperature of the cleaning liquid used for immersion is preferably 5 ° C. or higher, more preferably 10 ° C. or higher, and preferably 45 ° C. or lower, more preferably 40 ° C. or lower. This temperature may be the temperature at the start of immersion. This temperature may also be maintained during immersion.
Further, a higher effect can be obtained by applying the cleaning liquid to the part of the clothing where the dirt is adhered and leaving it, preferably leaving it for 5 minutes to 30 minutes and then washing it by hand. The standing is preferably performed at an ambient temperature of 5 ° C. or higher, more preferably 10 ° C. or higher, and preferably 40 ° C. or lower, more preferably 35 ° C. or lower.

The cleaning liquid contains the cleaning composition for clothes of the present invention and water. The concentration of the composition of the present invention in the cleaning liquid is 0.3 g / L or more, preferably 0.5 g / L or more, more preferably 1 g / L or more, and 10 g / L or less, preferably 7 g / L. Below, more preferably 5 g / L or less. As the water, water having German hardness as described above can be used.

In the hand-washing washing method of the present invention, the ratio of the mass of the washing liquid to the mass of the clothing is preferably 2 times or more, more preferably 3 times or more, more preferably 5 times or more, and preferably 100 times or less, more Preferably it is 50 times or less, More preferably, it is 25 times or less. That is, in the hand-washing washing method of the present invention, the bath ratio is preferably 2 or more, more preferably 3 or more, more preferably 5 or more, and preferably 100 or less, more preferably 50 or less, more preferably 25. Below, more preferably 20 or less.
It is visually preferred that the clothes, which are brought into contact with, preferably immersed in the cleaning liquid according to the present invention, are thoroughly rubbed by hand, in addition to good detergency and rich foaming.
After hand-washing such as rubbing, the clothes are taken out from the washing liquid, squeezed to remove water or water using a dehydrator, and then immersed again in fresh water (hereinafter referred to as rinse water). The rinsing water may be either water stored in a basin or running water. The ratio of the mass of rinse water to clothing is preferably 2 times or more, more preferably 5 times or more, more preferably 10 times or more, and preferably 1,000 times or less, more preferably 500 times or less, more Preferably it is 100 times or less. When this operation is repeated several times, the foaming disappears, that is, the rinsing is completed when the foam runs out. In the hand-washing washing method of the present invention, it is preferable that the number of times of rinsing is reduced by improving the foaming at the time of rinsing.

More specific embodiments of the present invention are shown below. In these aspects, the matters relating to the detergent composition for clothing, the method for improving the foaming property, the washing method for clothing, and the hand-washing washing method described above can be appropriately applied.
<1>
The following (a) component and (b) component are contained,
In the component (a), the ratio of the compound in which n in the general formula (1) is 0 and the compound in which n is 1 in the general formula (1) is 65% by mass or more, preferably 66% by mass or more. Preferably it is 68 mass% or more, More preferably, it is 70 mass%, More preferably, it is 73 mass% or more, More preferably, it is 75 mass% or more, More preferably, it is 76 mass% or more, More preferably, it is 78 mass% or more, More preferably, it is 80 % By mass or more, more preferably 82% by mass or more, more preferably 84% by mass or more, more preferably 86% by mass or more, further preferably 88% by mass or more, more preferably 90% by mass or more, and further preferably 92% by mass. Or more and 95% by mass or less,
The mass of the component (b) is preferably 5 parts by mass or more with respect to 100 parts by mass in total of the mass of the compound in which n in the general formula (1) is 0 and the mass of the compound in which n is 1 in the general formula (1). Is at least 5.5 parts by mass, more preferably at least 6 parts by mass, even more preferably at least 6.5 parts by mass, even more preferably at least 7 parts by mass, even more preferably at least 8 parts by mass, even more preferably at least 9 parts by mass, More preferably 10 parts by mass or more, and 17 parts by mass or less, preferably 16.5 parts by mass or less, more preferably 16 parts by mass or less, still more preferably 15.5 parts by mass or less, still more preferably 15 parts by mass or less, More preferably 14.5 parts by weight or less, more preferably 14 parts by weight or less, more preferably 13.5 parts by weight or less, further preferably 13 parts by weight or less, more preferably 12.5 parts by weight or less, still more preferably. 12 parts by mass or less, more preferably 11.5 parts by mass or less, more preferably 11 parts by mass or less, even more preferably not more than 10.5 parts by mass,
A cleaning composition for clothing.
(A) Component: sulfate ester salt represented by the following general formula (1) R—O— (AO) _n —SO ₃ M (1)
[In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, and n is 0 to 20) The following integers, where M is a cation. ]
(B) Component: Amphoteric surfactant

<2>
The proportion of the component (a) in the anionic surfactant contained in the detergent composition for clothing is 80% by mass or more, preferably 90% by mass or more, more preferably 95% by mass or more, and still more preferably 96% by mass. As described above, the cleaning composition for clothing according to <1>, more preferably 97% by mass or more, and further preferably 98% by mass or more and 100% by mass or less.

<3>
The mass ratio of the content of alkylbenzene sulfonate contained in the cleaning composition for clothing and the content of all anionic surfactants contained in the cleaning composition for clothing is the content of alkylbenzene sulfonate. / The content of total anionic surfactant is 0 or more, or 0 or more than 0, and less than 0.2, preferably 0.19 or less, more preferably 0.18 or less, more preferably 0.15 or less, More preferably, it is 0.10 or less, More preferably, it is 0.05 or less, More preferably, it is 0.03 or less, The cleaning composition for clothes as described in <1> or <2>.

<4>
The content of the component (a) in the cleaning composition for clothing is 3% by mass or more, preferably 4% by mass or more, more preferably 5% by mass or more, still more preferably 6% by mass or more, and further preferably 7% by mass. Or more, more preferably 8% by mass or more, more preferably 9% by mass or more, and 30% by mass or less, preferably 28% by mass or less, more preferably 26% by mass or less, still more preferably 24% by mass or less, still more preferably The cleaning composition for clothing according to any one of <1> to <3>, wherein is 22% by mass or less, more preferably 20% by mass or less.

<5>
The washing for clothing according to any one of <1> to <4>, wherein in the sulfate ester salt represented by the general formula (1) as the component (A), AO is an alkyleneoxy group having 2 carbon atoms Agent composition.

<6>
The cleaning composition for clothing according to any one of <1> to <5>, wherein AO in the general formula (1) is an alkyleneoxy group containing an ethyleneoxy group, and further an ethyleneoxy group.

<7>
The cleaning composition for clothes according to <1> to <6>, wherein the component (b) is one or more amphoteric surfactants selected from amine oxides and betaines, and further amine oxides.

<8>
The cleaning composition for clothing according to <7>, wherein the amine oxide is a compound represented by the following general formula (b1).

[Wherein, R ^1b is a group having 8 to 18 carbon atoms when k is 0 or when k is 1 and X is a group selected from —O (CO) — and — (NH) (CO) —). An aliphatic hydrocarbon group having 7 to 17 carbon atoms, wherein k is 1 and X is a group selected from — (CO) O— and — (CO) (NH) — a ^{group, R 2b} is an alkylene group having 1 to 6 carbon atoms, X is - (CO) O -, - (CO) (NH) -, - O (CO) -, - (NH) (CO )-. k is a number of 0 or 1, and R ^3b and R ^4b are each an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms. ]

<9>
Amine oxide is N-lauryl-N, N-dimethylamine oxide, N-myristyl-N, N-dimethylamine oxide, N-palmityl-N, N-dimethylamine oxide, N-lauroylaminopropyl-N, N— Dimethylamine oxide, N-myristoylaminopropyl-N, N-dimethylamine oxide, N-palmitoylaminopropyl-N, N-dimethylamine oxide, N-lauryl-N-ethyl-N-methylamine oxide, N-lauryl- N-methyl-N- (2-hydroxyethyl) amine oxide, N-myristyl-N-ethyl-N-methylamine oxide, N-myristyl-N-methyl-N- (2-hydroxyethyl) amine oxide, N- Palmityl-N-ethyl-N-methylamine oxide, N-palmityl N-methyl-N- (2-hydroxyethyl) amine oxide, N-lauroylaminopropyl-N-ethyl-N-methylamine oxide, N-lauroylaminopropyl-N-methyl-N- (2-hydroxyethyl) amine Oxide, N-myristoylaminopropyl-N-ethyl-N-methylamine oxide, N-myristoylaminopropyl-N-methyl-N- (2-hydroxyethyl) amine oxide, N-palmitoylaminopropyl-N-ethyl-N The detergent for clothes according to <7> or <8>, which is one or more compounds selected from -methylamine oxide and N-palmitoylaminopropyl-N-methyl-N- (2-hydroxyethyl) amine oxide Composition.

<10>
Amine oxide is N-lauryl-N, N-dimethylamine oxide, N-myristyl-N, N-dimethylamine oxide, N-palmityl-N, N-dimethylamine oxide, N-lauroylaminopropyl-N, N— <7> to <9>, which is one or more compounds selected from dimethylamine oxide, N-myristoylaminopropyl-N, N-dimethylamine oxide, and N-palmitoylaminopropyl-N, N-dimethylamine oxide. A cleaning composition for clothing according to any one of the above.

<11>
The detergent composition for clothing according to any one of <7> to <10>, wherein betaine is a compound represented by the following general formula (b2).

^{Wherein, R 5b,} when j is 0 or j is Y 1 is -O (CO) -, - ( NH) (CO) - If a group selected from 8 to 18 carbon atoms An aliphatic hydrocarbon group having 7 to 17 carbon atoms in which j is 1 and Y is a group selected from — (CO) O— and — (CO) (NH) — R ^6b is an alkylene group having 1 to 6 carbon atoms. Y is a group selected from — (CO) O—, — (CO) (NH) —, —O (CO) —, — (NH) (CO) —, —O—, and j is 0 or 1 Is a number. R ^7b and R ^8b are each an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, and R ^9b is an alkylene group having 1 to 5 carbon atoms which may be substituted with a hydroxy group. Z is _{^{-SO 3 -, -OSO 3 -,}} -COO - a group selected from. ]

<12>
One type of betaine selected from lauryl (2-hydroxy-3-sulfopropyl) dimethylbetaine, myristyl (2-hydroxy-3-sulfopropyl) dimethylbetaine, and palmityl (2-hydroxy-3-sulfopropyl) dimethylbetaine The cleaning composition for clothing according to any one of <7> to <11>, which is the above compound.

<13>
The clothing cleaning composition according to any one of <1> to <12>, further comprising a nonionic surfactant as component (c).

<14>
(C) The cleaning composition for clothes according to <13>, wherein the nonionic surfactant as a component is a nonionic surfactant having a polyoxyalkylene group.

<15>
(C) The cleaning composition for clothes according to <12> or <14>, wherein the component is a nonionic surfactant represented by the following general formula (c1).
R ^1c —O— (A′O) _m —H (c1)
[Wherein, R ^1c is an aliphatic hydrocarbon group having 8 to 18 carbon atoms, and A′O is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms. , M is the average added mole number of A′O, and is a number of 3 or more and 20 or less. ]

<16>
The content of the component (c) in the cleaning composition for clothing is 9 parts by mass or more, preferably 10 parts by mass or more, more preferably 10 parts by mass or more, based on 100 parts by mass of the mass of the component (a). Is 11 parts by mass or more, more preferably 12 parts by mass or more, more preferably 13 parts by mass or more, and 30 parts by mass or less, preferably 28 parts by mass or less, more preferably 26 parts by mass or less, and still more preferably 24 parts by mass. The garment cleaning composition according to any one of <13> to <15>, further preferably 22 parts by mass or less, and more preferably 20 parts by mass or less.

<17>
The cleaning composition for clothing according to <1> to <16>, wherein the cleaning composition for clothing is a liquid composition containing water.

<18>
The laundry detergent composition according to any one of <1> to <17>, which is for hand-washing.

<19>
<1>-<18> A hand-washing method in which clothes are hand-washed using a cleaning solution prepared by mixing the clothes-cleaning composition according to any one of <18> and water, and then the clothes are rinsed with water.

<20>
It is a method for improving the foaming property at the time of rinsing in washing laundry detergent compositions containing the following components (a) and (b),
In the component (a), the ratio of the compound in which n in the general formula (1) is 0 and the compound in which n is 1 in the general formula (1) is 65% by mass or more and 95% by mass or less,
The mass of the component (b) is 5 parts by mass or more and 17 parts by mass with respect to 100 parts by mass in total of the mass of the compound in which n in the general formula (1) is 0 and the mass of the compound in which n is 1 in the general formula (1). Part or less.
(A) Component: sulfate ester salt represented by the following general formula (1) R—O— (AO) _n —SO ₃ M (1)
[In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, and n is 0 to 20) The following integers, where M is a cation. ]
(B) Component: Amphoteric surfactant

<21>
It is a manufacturing method of the washing | cleaning composition for clothing containing the following (a) component and (b) component,
In the component (a), the ratio of the compound in which n in the general formula (1) is 0 and the compound in which n is 1 in the general formula (1) is 65% by mass or more and 95% by mass or less,
The mass of the component (b) is 5 parts by mass or more and 17 parts by mass with respect to 100 parts by mass in total of the mass of the compound where n in the general formula (1) is 0 and the mass of the compound where n is 1 in the general formula (1). Less than or equal to
A method for producing a cleaning composition for clothing.
(A) Component: sulfate ester salt represented by the following general formula (1) R—O— (AO) _n —SO ₃ M (1)
[In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, and n is 0 to 20) The following integers, where M is a cation. ]
(B) Component: Amphoteric surfactant

<22>
Use of the composition according to any one of <1> to <18> as a cleaning composition for clothing.

<23>
The following (a) component and (b) component are contained,
In the component (a), the ratio of the compound in which n in the general formula (1) is 0 and the compound in which n is 1 in the general formula (1) is 65% by mass or more, preferably 66% by mass or more. Preferably it is 68 mass% or more, More preferably, it is 70 mass%, More preferably, it is 73 mass% or more, More preferably, it is 75 mass% or more, More preferably, it is 76 mass% or more, More preferably, it is 78 mass% or more, More preferably, it is 80 % By mass or more, more preferably 82% by mass or more, more preferably 84% by mass or more, more preferably 86% by mass or more, further preferably 88% by mass or more, more preferably 90% by mass or more, and further preferably 92% by mass. Or more and 95% by mass or less,
The mass of the component (b) is preferably 5 parts by mass or more with respect to 100 parts by mass in total of the mass of the compound in which n in the general formula (1) is 0 and the mass of the compound in which n is 1 in the general formula (1). Is at least 5.5 parts by mass, more preferably at least 6 parts by mass, even more preferably at least 6.5 parts by mass, even more preferably at least 7 parts by mass, even more preferably at least 8 parts by mass, even more preferably at least 9 parts by mass, More preferably 10 parts by mass or more, and 17 parts by mass or less, preferably 16.5 parts by mass or less, more preferably 16 parts by mass or less, still more preferably 15.5 parts by mass or less, still more preferably 15 parts by mass or less, More preferably 14.5 parts by weight or less, more preferably 14 parts by weight or less, more preferably 13.5 parts by weight or less, further preferably 13 parts by weight or less, more preferably 12.5 parts by weight or less, still more preferably. 12 parts by mass or less, more preferably 11.5 parts by mass or less, more preferably 11 parts by mass or less, even more preferably not more than 10.5 parts by mass,
Use of the composition as a cleaning composition for clothing.
(A) Component: sulfate ester salt represented by the following general formula (1) R—O— (AO) _n —SO ₃ M (1)
[In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, and n is 0 to 20) The following integers, where M is a cation. ]
(B) Component: Amphoteric Surfactant The composition relating to this application includes the above-described detergent composition for clothing, the method for improving foaming properties, the washing method for clothing, and the washing method for hand washing. It can be applied as appropriate.

Examples [Examples 1 to 16 and Comparative Examples 1 to 3]
Using the following components, a liquid detergent composition for clothing shown in Tables 3 and 4 was prepared, and using the obtained composition, evaluation of foamability at the time of washing and foamability at the time of rinsing by the following methods Went. The results are shown in Tables 3 and 4. Moreover, about the liquid cleaning composition for clothes of the Example, the cleaning power was evaluated by the following method. The pH of the composition was adjusted to 9.0 with monoethanolamine or citric acid. A pH meter using a glass electrode was used for pH measurement.

<Composition ingredients>
(A) Components a-1 to a-7: Using components (a1) to (a4) listed in Table 1, a-1 to a-7 listed in Table 2 were prepared. The mass% of each compound in Table 2 is a calculated value calculated from the composition of each compound described in Table 1. The mass% of each compound in Table 2 is a value obtained by rounding off the third decimal place. “Total” in Table 2 describes a value obtained by rounding off the second decimal place in the total content of compounds having different n in the general formula (1). The mass% of each compound in Table 2 is a value obtained by calculation. For example, the total content of each compound may be 99.99 mass%, but is regarded as 100.0 mass%. In addition, “Ratio (mass%) of component (a1) in component (a)” in Table 2 is a value obtained by rounding off the second decimal place of the total content of (a1) in Table 2. is doing.

(B) Component b-1: N-lauryl-N, N-dimethylamine oxide b-2: N-lauroylaminopropyl-N, N-dimethylamine oxide b-3: lauryl (2-hydroxy-3 -Sulfopropyl) dimethylbetaine

Component (c): c-1: polyoxyethylene alkyl ether: polyoxyethylene alkyl ether obtained by adding an average of 10 moles of ethylene oxide to a linear primary alcohol having 12 carbon atoms, c-2: polyoxyethylene alkyl ether: carbon Polyoxyethylene alkyl ether with an average of 8 moles of ethylene oxide added to a linear primary alcohol of number 12 c-3: Polyoxyethylene alkyl ether: An average of 6 moles of ethylene oxide was added to a linear primary alcohol with 12 carbons Polyoxyethylene alkyl ether

Other optional components (shown as (d) component in the table)
D-1: sodium sulfate d-2: propylene glycol d-3: linear alkyl (carbon number 8-18) sodium benzenesulfonate, Neoperex G-25 (manufactured by Kao Corporation, the values in the table are Effective content.)

<Method for preparing liquid detergent composition for clothing (1)>
A liquid detergent composition for clothing shown in Table 3 or Table 5 was prepared using the above components.
A stirrer piece made of stick-shaped Teflon (registered trademark) having a diameter of 1 cm and a length of 5 cm was placed in a glass beaker having a capacity of 300 mL. Ion exchange water equivalent to 95% of the amount necessary to make the finished mass of the liquid detergent composition for clothing to 200 g was put into a beaker. Next, the beaker was placed in a water bath and the temperature of the contents was adjusted to 30 ° C. Necessary amounts of component (a), component (a ′), and component (b) were charged into a beaker while rotating at 200 r / min. The stirring of the stirrer piece was stopped 15 minutes after the addition.

<Method for preparing liquid detergent composition for clothing (2)>
A liquid detergent composition for clothing shown in Table 4 was prepared using the above components.
A stirrer piece made of stick-shaped Teflon (registered trademark) having a diameter of 1 cm and a length of 5 cm was placed in a glass beaker having a capacity of 300 mL. Ion exchange water equivalent to 95% of the amount necessary to make the finished mass of the liquid detergent composition for clothing to 200 g was put into a beaker. Next, the beaker was placed in a water bath and the temperature of the contents was adjusted to 30 ° C. While rotating at 200 r / min, necessary amounts of the component (a), the component (b), the component (c), and other optional components were charged into the beaker. The stirring of the stirrer piece was stopped 15 minutes after the addition.

<Measurement method of viscosity>
A 100 mL capacity tall beaker containing the liquid detergent composition for clothing described in Table 4 was placed in a thermostatic bath, and the temperature of the contents was adjusted to 30 ± 1 ° C. The rotor No. is added to the TVB-10M viscometer. 2 was installed, and the viscosity after 1 minute was measured at a rotation speed of 60 rpm. When an upward arrow is displayed next to the value displayed on the display unit, the rotor No. Were measured sequentially. When a downward arrow is displayed next to the value displayed on the display unit, the rotor No. Measured with lowering sequentially. When the value was displayed, the viscosity was calculated based on the value. The results are shown in Table 4. A lower value is preferred.
In Table 4, Example 12 does not include a nonionic surfactant containing a polyoxyalkylene group as component (c). Since Examples 13 to 16 contain the component (c), the viscosity is lower than that of Example 12. Further, comparing Examples 14 to 16, it can be seen that the greater the number of oxyethylene groups, the lower the viscosity.

<Evaluation of foaming property during cleaning>
4 g of liquid detergent composition for clothing is mixed with 996 g of water of German hardness 10 ° dH (Ca / Mg = 7/3) and alkalinity 60, and 50 μL of the following model sebum soil is added and stirred for 3 minutes to 30 ° C. A cleaning solution was prepared after adjustment. 200 g of cleaning liquid is poured over 30 seconds into a cylindrical glass container (inner diameter: 5 cm, inner height: 90 cm) with one side closed and the other side open. The height of the foam 1 minute after pouring was measured. The height of the foam was measured by measuring the height of the foam in contact with the inner wall of the glass container. A bubble height of 160 mm or more was accepted. Larger numbers indicate better foamability.

-Model sebum stain: A model sebum stain in which the following components were mixed at respective ratios was used.
Lauric acid 0.99 mass%, myristic acid 7.09 mass%, pentadecanoic acid 5.29 mass%, palmitic acid 14.21 mass%, heptadecanoic acid 0.99 mass%, stearic acid 3.60 mass%, oleic acid 17.81% by mass, triolein 30.02% by mass, n-hexadecyl palmitate 5.00% by mass, squalene 15.00% by mass

Below, the measuring method of the alkalinity of water is shown. Take 100 ml of test water in a 200 ml beaker, and add 0.15 ml of bromocresol green-methyl red / ethanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) as an indicator. If there is residual chlorine in the test water, add sodium thiosulfate solution (0.3 w / v%) to 100 ml of the test water to remove the residual chlorine. The solution is titrated with 10 mmol / l sulfuric acid with gentle stirring until the color of the solution changes from blue to reddish purple. The alkalinity is calculated by the following formula.
Alkalinity (CaCO ₃ mg / l) = a × 10
Here, a: 10 mmol / l sulfuric acid (ml) required for titration.
When the color change due to the indicator is not clear, such as a colored sample, a pH meter is used instead of the indicator, and the amount of 10 mmol / l sulfuric acid (ml) required until the pH value is 4.8 is defined as a.

<Evaluation of foamability during rinsing>
The cleaning liquid used in the above “evaluation of foaming property during cleaning” was diluted 100 times by mass with water having a German hardness of 10 ° dH (Ca / Mg = 7/3) and an alkalinity of 60 to obtain a rinse liquid. Corresponding solutions were prepared. 200 g of the solution corresponding to the rinsing liquid is poured into a cylindrical glass container (inner diameter: 5 cm, inner height: 90 cm) with one side closed and the other side open over 30 seconds. The foam height 5 minutes after pouring was measured. The height of the foam was measured by measuring the height of the foam in contact with the inner wall of the glass container. When the height of the foam was 10 mm or less, it was judged that the foaming property during rinsing was good. The smaller the number, the better the foaming property when rinsing.

<Evaluation of cleaning power>
5 L of AS-10 artificially contaminated cloth (made by Testfabrics, cut into 10 cm × 10 cm) was placed in 1 L of a cleaning liquid obtained by mixing a liquid cleaning composition for clothing and water, and after immersion for 30 minutes, a targotometer ( Ueshima MS-8212, inner diameter 12 cm, height 17.5 cm) was washed at 100 r / min for 3 minutes. The concentration of the liquid detergent composition in the cleaning liquid was 0.4% by mass. The water used for the preparation of the cleaning liquid was water having an alkalinity of 60, in which calcium chloride was added to ion-exchanged water, and the German hardness was adjusted to 10 ° DH (178 mg CaCO ₃ / L). The water temperature of the cleaning liquid was 30 ° C., and this temperature was maintained during the immersion of the artificially contaminated cloth. After washing, rinsing was performed with the same mass of ion-exchanged water for 1 minute.

The detergency was determined by measuring the reflectance at 550 nm of the raw cloth before contamination and the contaminated cloth before and after washing with a self-recording colorimeter (Shimadzu Corporation), and obtaining the washing rate (%) by the following formula. The washing rate was measured from the reflectance of each of the five contaminated cloths, and the average value was calculated.
As a result of evaluating the detergency of the washing rate of the liquid detergent composition for clothing according to the present invention described in Tables 3 and 4, the average value of the washing rate of each composition was 30% or more, and the liquid washing for clothing It was confirmed to have general detergency as an agent composition.

Example 17
For the compositions of Examples 1 to 16, the foaming property at the time of washing by hand washing and the foaming property at the time of rinsing were evaluated by the following methods.
<Preparation of model sebum stain>
A model sebum soil having the following composition was prepared.
・ Model sebum soil composition:
Lauric acid 0.99 mass%, myristic acid 7.09 mass%, pentadecanoic acid 5.29 mass%, palmitic acid 14.21 mass%, heptadecanoic acid 0.99 mass%, stearic acid 3.60 mass%, oleic acid 17.81% by mass, triolein 30.02% by mass, n-hexadecyl palmitate 5.00% by mass, squalene 15.00% by mass

<Evaluation of foaming property at the time of washing and foaming property at the time of rinsing>
Evaluation clothing Three men's L-sized round neck underwear (manufactured by Gunze Co., Ltd., trade name Gunze YG, 100% cotton, about 100 g / 1) were used as evaluation clothing.

・ Evaluation operation (washing)
A polypropylene basin with a diameter of 36 cm, a depth of 13 cm, and a capacity of 11 L. Calcium chloride is added to ion-exchanged water to adjust the German hardness to 10 ° DH (178 mg CaCO ₃ / L). The alkalinity is 60 and the temperature is 30 ° C. 3 L of water, 12 g of a liquid cleaning composition for clothing, and 0.5 mL of the model sebum stain were placed. Subsequently, it stirred for 30 seconds by hand so that water might not scatter from a washbasin, and prepared the washing | cleaning liquid.
Three pieces of evaluation clothing in which 0.1 mL of the model sebum stain was applied per piece of evaluation clothing was immersed in the cleaning solution in the basin, and the whole was stirred for 30 seconds and then immersed in the cleaning solution for 30 minutes. After the immersion, the evaluation garment was lifted from the surface of the cleaning liquid to such an extent that the cleaning liquid did not scatter from the basin, and then washed back into the cleaning liquid for 1 minute per evaluation garment. Then, after squeezing by hand above the basin so that the water content in the evaluation garment was about 40 to 60%, the evaluation garment was taken out from the basin.
This operation was performed continuously, and the height of the foam was measured immediately after all the clothing for evaluation was taken out. This was taken as the height of the foam at the time of washing.
A larger value for the height of the foam is preferred. The height of the foam of 1.2 cm or more is the height at which the liquid level is difficult to see due to the foam generated by the 3rd evaluation clothing. That's it. Therefore, if the height of the foam is 1.2 cm or more, it can be determined that a foaming property that can be satisfied by a person performing hand-washing is obtained.

・ Evaluation operation (rinse)
Diameter 30 cm, with respect to basin depth 12cm, temperature 30 ° C., addition of calcium chloride in ion-exchanged water, rinsing is water alkalinity 60 was adjusted to a German hardness _{10 ° DH (178mgCaCO 3 / L} ) 3 L of water and three evaluation clothes taken out from the wash basin by the “evaluation operation (washing)” were put. Evaluation clothes were loosened in rinse water. Next, the operation of lifting the neck of the evaluation clothing from the surface of the rinsing water while opening the neck portion of the clothing for evaluation with both hands so that the rinsing water also passes inside the clothing for evaluation was repeated 10 times. Next, the water content in the apparel for evaluation was squeezed by hand so that the water content was about 40 to 60%, and then removed from the washbasin. Furthermore, this series of operations was repeated once more. This series of operations was performed for each piece of clothing for evaluation.
The state of the water surface immediately after taking out all the apparel for evaluation was observed, and points were assigned according to the following criteria to evaluate rinsing properties.
If the remaining amount of foam is less than 2/3 of the liquid level, it can be determined that the person performing hand-washing has good foam loss when rinsed. Therefore, if the following points are 3 or less, it can be judged that the foaming property which a person performing hand-washing can satisfy is obtained.

Point 5: Bubbles remain on almost the entire liquid surface 4: Bubbles remain on 2/3 or more of the entire liquid surface 3: Bubbles remain on 1/3 or more and less than 2/3 of the liquid surface 2: Bubbles remain below 1/3 of the liquid level 1: Little bubbles remain on the liquid level

The compositions of Examples 1 to 16 were excellent in the foaming property at the time of washing by hand washing and the foaming property at the time of rinsing according to the above evaluation.

[Formulation Examples 1 to 5]
Table 5 shows Formulation Examples 1 to 5 of the liquid detergent composition for clothing of the present invention. Formulation Example 3 has the same composition as Example 2, and the effect is shown in Table 3.
Of the liquid detergent compositions for clothing in Table 5, Formulation Examples 1, 2, 4, and 5 are the same as in Example 1 except that the amount of the composition used and the amount of water used are listed in Table 5. When the foaming property at the time of washing is evaluated as the above condition, it is considered that satisfactory foaming property can be obtained in any combination example.
In addition, among the liquid detergent compositions for clothing shown in Table 5, Formulation Examples 1, 2, 4, and 5 are any formulation examples when the foaming property during rinsing is evaluated in the same manner as in Example 1 and the like. It is considered that satisfactory foaming properties can be obtained.

* German hardness 10 ° dH (Ca / Mg = 7/3), water with alkalinity 60

Claims (7)

1. The following (a) component and (b) component are contained,
   In the component (a), the ratio of the compound in which n in the general formula (1) is 0 and the compound in which n is 1 in the general formula (1) is 65% by mass or more and 95% by mass or less,
   The mass of the component (b) is 5 parts by mass or more and 17 parts by mass with respect to 100 parts by mass in total of the mass of the compound in which n in the general formula (1) is 0 and the mass of the compound in which n is 1 in the general formula (1). Less than or equal to
   A cleaning composition for clothing.
   (A) Component: sulfate ester salt represented by the following general formula (1) R—O— (AO) _n —SO ₃ M (1)
   [In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, and n is 0 to 20) The following integers, where M is a cation. ]
   (B) Component: Amphoteric surfactant
2. The cleaning composition for clothing according to claim 1, wherein the proportion of the component (a) in the anionic surfactant contained in the cleaning composition for clothing is 80% by mass or more and 100% by mass or less.
3. The mass ratio of the content of alkylbenzene sulfonate contained in the cleaning composition for clothing and the content of all anionic surfactants contained in the cleaning composition for clothing is the content of alkylbenzene sulfonate. The clothes cleaning composition according to claim 1, wherein the total anionic surfactant content is 0 or more and less than 0.2.
4. The clothing detergent composition according to any one of claims 1 to 3, wherein the component (b) is an amine oxide.
5. The garment cleaning composition according to any one of claims 1 to 4, which is for hand-washing.
6. A hand-washing washing method in which clothes are hand-washed using a cleaning liquid prepared by mixing the detergent composition for clothes according to any one of claims 1 to 5 with water, and then the clothes are rinsed with water.
7. It is a method for improving the foaming property at the time of rinsing in washing laundry detergent compositions containing the following components (a) and (b),
   In the component (a), the ratio of the compound in which n in the general formula (1) is 0 and the compound in which n is 1 in the general formula (1) is 65% by mass or more and 95% by mass or less,
   The mass of the component (b) is 5 parts by mass or more and 17 parts by mass with respect to 100 parts by mass in total of the mass of the compound in which n in the general formula (1) is 0 and the mass of the compound in which n is 1 in the general formula (1). Less than or equal to
   Method.
   (A) Component: sulfate ester salt represented by the following general formula (1) R—O— (AO) _n —SO ₃ M (1)
   [In the formula, R is a hydrocarbon group having 10 to 18 carbon atoms, AO is an alkyleneoxy group selected from an alkyleneoxy group having 2 carbon atoms and an alkyleneoxy group having 3 carbon atoms, and n is 0 to 20) The following integers, where M is a cation. ]
   (B) Component: Amphoteric surfactant