WO2016178299A1

WO2016178299A1 - Internal combustion engine exhaust purification device

Info

Publication number: WO2016178299A1
Application number: PCT/JP2016/001908
Authority: WO
Inventors: 友基藤野
Original assignee: 株式会社デンソー
Priority date: 2015-05-07
Filing date: 2016-04-05
Publication date: 2016-11-10
Also published as: JP6292165B2; DE112016002077T5; JP2016211410A

Abstract

According to the present invention, an exhaust purification device for an internal combustion engine (11) is provided with a storage catalyst (21), a sensor (23) and a determination unit (30). The storage catalyst (21) stores predetermined components of the exhaust gas via a storage reaction wherein the predetermined components react with a storage material. The sensor (23) detects information that changes in response to the state of the storage reaction. The determination unit (30) determines a state immediately preceding saturation on the basis of the output of the sensor (23). The state immediately preceding saturation means a state in which the storage amount of the storage catalyst (21) is approaching saturation and the storage reaction is in decline.

Description

Exhaust gas purification device for internal combustion engine

Cross-reference of related applications

This application is based on Japanese Patent Application No. 2015-94787 filed on May 7, 2015, the contents of which are incorporated herein by reference.

The present disclosure relates to an exhaust gas purification apparatus for an internal combustion engine including an occlusion catalyst that occludes a predetermined component in exhaust gas of the internal combustion engine.

Many vehicles equipped with an internal combustion engine employ an exhaust purification system that purifies exhaust gas using a catalyst installed in an exhaust passage of the internal combustion engine. Such an exhaust purification system is described in Patent Document 1, in which an NO _X storage catalyst that stores NO _{X in} exhaust gas is disposed in an exhaust passage of an internal combustion engine, and the upstream and downstream sides of the NO _X storage catalyst. the NO _X sensor for detecting the respective side NO _X concentration is arranged to determine the deterioration state of the NO _X storage catalyst on the basis of the outputs of the two of the NO _X sensor.

JP 2001-32745 A

However, in the technique of Patent Document 1, in order to determine the state of the NO _X storage catalyst, it is necessary to provide an expensive NO _X sensor on both the upstream and downstream of the NO _X storage catalyst. For this reason, the cost of the exhaust purification system becomes high, and the demand for cost reduction cannot be satisfied.

This disclosure is intended to provide an exhaust purification device for an internal combustion engine that can determine the state of the storage catalyst while satisfying the demand for cost reduction.

In one aspect of the present disclosure, an exhaust purification device for an internal combustion engine includes an occlusion catalyst that occludes by an occlusion reaction that causes a predetermined component in exhaust gas to react with an occlusion material, and a sensor that detects information that changes according to the state of the occlusion reaction. And a determination unit that determines a state immediately before saturation, which is a state where the storage amount of the storage catalyst approaches saturation and the storage reaction tends to decrease based on the output of the sensor.

When the amount of occlusion of the occlusion catalyst is small and the occlusion capacity is high, the occlusion reaction is actively performed and the amount of heat generated by the occlusion reaction increases, and accordingly the temperature of the occlusion catalyst and the temperature of exhaust gas passing through the occlusion catalyst rises. To do. After that, when the occlusion amount of the occlusion catalyst increases to approach saturation and the occlusion capacity decreases, the occlusion reaction decreases and the amount of heat generated by the occlusion reaction decreases, and accordingly the temperature of the occlusion catalyst and the occlusion catalyst are reduced. The temperature of the exhaust gas that passes through decreases. That is, there is a correlation between the storage amount of the storage catalyst and information that changes according to the state of the storage reaction (for example, the temperature of the storage catalyst or the temperature of the exhaust gas).

Therefore, if the output of a sensor that detects information that changes according to the state of the occlusion reaction is monitored, the occlusion catalyst is immediately before saturation (that is, the occlusion amount of the occlusion catalyst approaches saturation and the occlusion reaction tends to decrease). Can be determined. In this case, since the state of the storage catalyst can be determined without providing a sensor for detecting the concentration of the predetermined component on both the upstream side and the downstream side of the storage catalyst, an expensive sensor that detects the concentration of the predetermined component. Therefore, the cost of the exhaust purification system can be reduced.

FIG. 1 is a diagram illustrating a schematic configuration of an engine control system according to the first embodiment. FIG. 2 is a diagram showing a schematic configuration of a test exhaust purification system. FIG. 3 shows the test results. FIG. 4 is a flowchart showing the processing flow of the exhaust purification control routine. FIG. 5 is a diagram showing a schematic configuration of the exhaust purification system of the second embodiment. FIG. 6 is a diagram illustrating a schematic configuration of the exhaust purification system of the third embodiment.

Hereinafter, examples will be described.

Example 1 will be described with reference to FIGS.

The schematic configuration of the engine control system will be described with reference to FIG.

An intake pipe 12 of an engine 11 which is an internal combustion engine is provided with a throttle valve 14 whose opening is adjusted by a motor 13 and a throttle opening sensor 15 which detects a throttle opening which is the opening of the throttle valve 14. ing.

Each cylinder of the engine 11 is provided with a fuel injection valve 16 that directly injects fuel into the cylinder. An ignition plug 17 is attached to the cylinder head of the engine 11 for each cylinder, and the air-fuel mixture in each cylinder is ignited by spark discharge of the ignition plug 17 of each cylinder.

On the other hand, the exhaust pipe 18 of the engine 11 is provided with an air-fuel ratio sensor 19 that detects the air-fuel ratio of the exhaust gas, and purifies CO, HC, NO _{x and the} like in the exhaust gas downstream of the air-fuel ratio sensor 19. A three-way catalyst 20 is provided.

A NO _x storage catalyst 21 is provided on the downstream side of the three-way catalyst 20. This the NO _X storing catalyst 21, when the air-fuel ratio of the exhaust gas is leaner than the stoichiometric air-fuel ratio, the NO _X in the exhaust gas is occluded by occlusion reaction is reacted with absorbing material, the air-fuel ratio of the exhaust gas is the stoichiometric air When the fuel is richer than the fuel ratio, the stored NO _x is released and reduced and purified. NO _x corresponds to the predetermined component, and the NO _x storage catalyst 21 corresponds to the storage catalyst.

The NO _X storing catalyst 21 is divided into an upstream side portion 21a and downstream portion 21b in the direction of the flow of the exhaust gas, between the upstream portion 21a and downstream portion 21b, arranged downstream temperature sensor 23 to be described later A gap 31 is provided for this purpose.

On the upstream side of the NO _X storage catalyst 21 (that is, the upstream side of the upstream portion 21a), the temperature of the exhaust gas flowing into the upstream portion 21a of the NO _X storage catalyst 21 (hereinafter referred to as “inflow gas temperature”) is detected. An upstream temperature sensor 22 is disposed.

Further, on the downstream side of the upstream portion 21 a of the NO _X storage catalyst 21 (that is, the position corresponding to the gap 31 between the upstream portion 21 a and the downstream portion 21 b), the upstream portion 21 a of the NO _X storage catalyst 21. A downstream temperature sensor 23 for detecting the temperature of the exhaust gas flowing out from the exhaust gas (hereinafter referred to as “outflow gas temperature”) is disposed. In other words, the downstream temperature sensor 23 is disposed upstream of the most downstream portion in the exhaust gas flow direction in the NO _x storage catalyst 21. This downstream temperature sensor 23 corresponds to a temperature sensor.

As the upstream temperature sensor 22 and the downstream temperature sensor 23, those having vibration resistance more than a predetermined value are used, and the

temperature sensors

22 and 23 are prevented from being damaged by vibration due to exhaust pulsation.

Further, on the downstream side of the upstream portion 21a of the NO _X storage catalyst 21 (that is, the position corresponding to the gap 31), the air-fuel ratio of the exhaust gas flowing out from the upstream portion 21a of the NO _X storage catalyst 21 (hereinafter referred to as “outflow gas”). An air-fuel ratio sensor 24 for detecting “air-fuel ratio” is disposed. A NO _X sensor 25 that detects the NO _X concentration of the exhaust gas flowing out from the downstream portion 21b of the NO _X storage catalyst 21 is disposed downstream of the NO _X storage catalyst 21 (that is, downstream of the downstream portion 21b). ing.

Further, a cooling water temperature sensor 26 for detecting the cooling water temperature and a knock sensor 27 for detecting knocking are attached to the cylinder block of the engine 11. A crank angle sensor 29 that outputs a pulse signal every time the crankshaft 28 rotates by a predetermined crank angle is attached to the outer peripheral side of the crankshaft 28, and the crank angle and the engine are determined based on the output signal of the crank angle sensor 29. The rotation speed is detected.

The outputs of these various sensors are input to an electronic control unit (hereinafter referred to as “ECU”) 30. The ECU 30 is mainly composed of a microcomputer, and executes various engine control programs stored in a built-in ROM, so that the fuel injection amount, the ignition timing, the throttle opening ( That is, the intake air amount) is controlled.

At that time, ECU 30 by executing the exhaust gas purification control routine of FIG. 4 described later, (a _the NO _X storage temperature range capable for example the NO _X storing catalyst 21) when in the temperature of the exhaust gas is predetermined range, The engine 11 is operated in the lean mode. In the lean mode, the fuel injection amount and the intake air amount are controlled so that the air-fuel ratio of the air-fuel mixture becomes leaner than the stoichiometric air-fuel ratio (stoichiometric), thereby reducing fuel consumption.

During the lean mode, occludes NO _X in the exhaust gas in the NO _X storing catalyst 21, when the storage capacity is lowered by storage amount of the NO _X storage catalyst 21 is increased, if the air-fuel ratio of the exhaust gas rich to release the NO _X which is stored in the NO _X storing catalyst 21 performing the rich purge for reduction purification. The storage capacity of the NO _X storage catalyst 21 is reduced by the rich purge to restore the storage capacity.

The inventor conducted a test using the test exhaust purification system shown in FIG. 2, and the test results are shown in FIG.

In the exhaust purification system shown in FIG. 2, temperature sensors 2 and 3 for detecting the temperature of exhaust gas are arranged on the upstream side and downstream side of the NO _X storage catalyst 1, respectively, and the exhaust gas is discharged downstream of the NO _X storage catalyst 1. A NO _x sensor 4 for detecting the NO _x concentration of the gas is disposed. In the test results shown in FIG. 3, the inflow gas temperature is the temperature of the exhaust gas detected by the upstream temperature sensor 2, and the outflow gas temperature is the temperature of the exhaust gas detected by the downstream temperature sensor 3. Further, the difference between the outflow gas temperature and the inflow gas temperature is used as the catalyst temperature increase amount.

As shown in FIG. 3, after the rich purge is performed, when the storage amount of the NO _x storage catalyst 1 is small and the storage capacity is high, the storage reaction is actively performed and the amount of heat generated by the storage reaction is increased. The temperature of the NO _X storage catalyst 1 and the outflow gas temperature rise. Thereafter, when the storage amount of the NO _X storage catalyst 1 increases and approaches its saturation and the storage capacity decreases, the storage reaction decreases and the amount of heat generated by the storage reaction decreases, and accordingly, the NO _X storage catalyst 1 Temperature and effluent gas temperature decrease. That is, there is a correlation between the storage amount of the NO _X storage catalyst 1 and information that changes according to the state of the storage reaction (for example, the temperature of the NO _X storage catalyst 1 or the outflow gas temperature).

Focusing on such characteristics, in the first embodiment, as information that changes according to the state of the occlusion reaction, the temperature that changes according to the amount of heat generated by the occlusion reaction (for example, the upstream portion 21a of the NO _x storage catalyst 21). A downstream temperature sensor 23 for detecting the temperature of the exhaust gas flowing out from the gas. 4 is executed by the ECU 30, the storage amount of the upstream portion 21a of the NO _X storage catalyst 21 approaches saturation based on the output of the downstream temperature sensor 23, and the storage reaction is performed. A state that tends to decrease (hereinafter referred to as “state immediately before saturation”) is determined.

Specifically, the difference between the outflow gas temperature detected by the downstream temperature sensor 23 and the inflow gas temperature detected by the upstream temperature sensor 22 is calculated as the catalyst temperature increase amount (that is, the upstream portion 21a of the NO _X storage catalyst 21). Calculated as temperature rise). Depending on whether the catalyst temperature increase amount reaches the maximum value, determined catalytic heating value (i.e. the amount of heat generated by the adsorption reaction of the upstream portion 21a of the NO _X storage catalyst 21) whether reaches the maximum value . When it is determined that the catalyst temperature increase amount has reached the maximum value (that is, the catalyst heat generation amount has reached the maximum value), it is determined that the storage reaction in the upstream portion 21a of the NO _x storage catalyst 21 starts to decrease. Then, it is determined that the upstream portion 21a of the NO _x storage catalyst 21 is in a state immediately before saturation.

Hereinafter, the processing content of the exhaust purification control routine of FIG. 4 executed by the ECU 30 in the first embodiment will be described.

The exhaust purification control routine shown in FIG. 4 is repeatedly executed at a predetermined cycle during the power-on period of the ECU 30, and serves as a determination unit and a control unit. When this routine is started, first, at step 101, it is determined whether or not the exhaust gas temperature is within a predetermined range. Here, the exhaust gas temperature is the inflow gas temperature detected by the upstream temperature sensor 22 or the outflow gas temperature detected by the downstream temperature sensor 23. The predetermined range is set to a temperature range (for example, 250 to 400 ° C.) in which NO _X can be stored by the NO _X storage catalyst 21.

If it is determined in step 101 that the exhaust gas temperature is outside the predetermined range, it is determined that the NO _X storage catalyst 21 cannot store NO _X, and the routine proceeds to step 109, where the engine 11 is operated in the stoichiometric mode. To do. In the stoichiometric mode, the fuel injection amount and the intake air amount are controlled so that the air-fuel ratio of the air-fuel mixture becomes the stoichiometric air-fuel ratio.

On the other hand, if it is determined in step 101 that the exhaust gas temperature is within the predetermined range, it is determined that the NO _X storage catalyst 21 can store NO _X, and the routine proceeds to step 102 where the engine 11 is turned on. Drive in lean mode. In the lean mode, the fuel injection amount and the intake air amount are controlled so that the air-fuel ratio of the air-fuel mixture becomes leaner than the stoichiometric air-fuel ratio.

Thereafter, the process proceeds to step 103, and the inflow gas temperature detected by the upstream temperature sensor 22 and the outflow gas temperature detected by the downstream temperature sensor 23 are read. Thereafter, the process proceeds to step 104, and the difference between the outflow gas temperature and the inflow gas temperature is calculated as the catalyst temperature increase amount.

Catalyst temperature increase amount = outflow gas temperature−inflow gas temperature Thereafter, the process proceeds to step 105 to determine whether the catalyst temperature increase amount has reached the maximum value (that is, the peak value), for example, a differential value of the catalyst temperature increase amount, etc. Determine based on.

If it is determined in step 105 that the catalyst temperature increase amount has not reached the maximum value (that is, the catalyst heat generation amount has not reached the maximum value), the process returns to step 103 to obtain the catalyst temperature increase amount. repeat.

Thereafter, when it is determined in step 105 that the catalyst temperature increase amount has reached the maximum value (that is, the catalyst heat generation amount has reached the maximum value), the upstream portion 21a of the NO _X storage catalyst 21 is in a state immediately before saturation. If it is determined that the operation has been completed, the routine proceeds to step 106, where a rich purge is performed. This rich purge is reduced and purified by releasing NO _X which is stored in the NO _X storing catalyst 21 and the air-fuel ratio of the exhaust gas rich.

Thereafter, the routine proceeds to step 107, where it is determined whether the outflow gas air-fuel ratio detected by the air-fuel ratio sensor 24 is richer than the stoichiometric air-fuel ratio, and when the outflow gas air-fuel ratio is determined to be richer than the stoichiometric air-fuel ratio. The process proceeds to step 108, and the rich purge is finished.

In the present embodiment described above, the difference between the outflow gas temperature detected by the downstream temperature sensor 23 and the inflow gas temperature detected by the upstream temperature sensor 22 is calculated as the catalyst temperature increase amount, and this catalyst temperature increase amount is the maximum. It is determined whether or not the heat generation amount of the catalyst has reached the maximum value depending on whether or not the value has been reached. Then, when it is determined that the catalyst temperature increase amount has reached the maximum value (that is, the catalyst heat generation amount has reached the maximum value), it is determined that the upstream portion 21a of the NO _X storage catalyst 21 has just entered saturation. As a result, the state immediately before saturation of the upstream portion 21a of the NO _x storage catalyst 21 can be determined with high accuracy, and the execution timing of the rich purge can be accurately grasped. Further, the deterioration state of the NO _x storage catalyst 21 can be grasped by detecting the maximum value of the catalyst temperature increase amount (that is, the maximum value of the catalyst heat generation amount). In this case, without providing a NO _X sensor on both the upstream and downstream of the NO _X storage catalyst 21, it is possible to determine the state of the NO _X storage catalyst 21, reducing the number of expensive NO _X sensor can do. Moreover, since a temperature sensor that is significantly less expensive than the NO _x sensor is used, the cost of the exhaust purification system can be reduced.

In the first embodiment, the downstream temperature sensor 23 is located upstream of the most downstream portion in the exhaust gas flow direction of the NO _x storage catalyst 21 (that is, between the upstream portion 21a and the downstream portion 21b). Has been placed. In this way, when the upstream portion 21a of the NO _X storage catalyst 21 based on the output of the downstream temperature sensor 23 is determined to become saturated state just before, NO _X is not completely occluded to the upstream side portion 21a Even if it starts to increase, the NO _x can be occluded in the downstream portion 21b.

Further, in the first embodiment, the NO _x storage catalyst 21 is divided into an upstream portion 21a and a downstream portion 21b, and a downstream temperature sensor 23 is disposed between the upstream portion 21a and the downstream portion 21b. A gap 31 is provided for this purpose. In this way, the downstream temperature sensor 23 can be easily disposed at an intermediate position of the NO _x storage catalyst 21 (that is, upstream from the most downstream portion).

In the first embodiment, the rich purge is performed when it is determined that the upstream portion 21a of the NO _x storage catalyst 21 is in a state immediately before saturation. In this way, the rich purge is performed immediately before the NO _X storage catalyst 21 becomes saturated (the NO _X storage amount is saturated) and the NO _X emission amount increases, and the NO _X storage catalyst 21 The occlusion ability can be restored. Thus, while improving the NO _X emissions reduced by exhaust emission and it is possible to save fuel by preventing the carrying out rich purge than necessary.

In the first embodiment, when it is determined that the amount of increase in the catalyst temperature has reached the maximum value, it is determined that the upstream portion 21a of the NO _X storage catalyst 21 is in a state immediately before saturation, and rich purge is performed. .

However, the present invention is not limited to this, and, for example, when the catalyst temperature increase amount exceeds a threshold value (for example, the previous maximum value × 0.9) lower than the maximum value before reaching the maximum value, the NO _X storage catalyst 21. It may be determined that the upstream portion 21a is in a state immediately before saturation, and rich purge may be performed. Thus, it is possible to slightly accelerate the implementation period of the rich purge, increase the NO _X emission reduction effect.

Alternatively, when the catalyst temperature increase amount reaches a maximum value and falls below a threshold value (for example, maximum value × 0.9) lower than the maximum value, the upstream portion 21a of the NO _X storage catalyst 21 is in a state immediately before saturation. The rich purge may be performed by determining that the above has occurred. In this way, it is possible to enhance the fuel consumption saving effect by slightly delaying the execution time of the rich purge.

Example 2 will be described with reference to FIG. However, description of substantially the same parts as those in the first embodiment will be omitted or simplified, and different parts from the first embodiment will be mainly described.

In the second embodiment, as shown in FIG. 5, the temperature sensor 23 is disposed on the downstream side of the upstream portion 21a of the NO _x storage catalyst 21 (that is, the position corresponding to the gap 31). The sensor 22 (see FIG. 1) is omitted.

Further, the air-fuel ratio sensor 24 (see FIG. 1) and the NO _x sensor 25 (see FIG. 1) are also omitted, and instead, the exhaust gas is discharged downstream of the NO _x storage catalyst 21 (that is, downstream of the downstream portion 21b). An air-fuel ratio sensor 32 that detects the air-fuel ratio of the gas is disposed. Air-fuel ratio sensor 32 also functions to detect the concentration of NO _X emissions.

In the second embodiment, the amount of heat generated by the catalyst (that is, the amount of heat generated by the storage reaction of the upstream portion 21a of the NO _X storage catalyst 21) is maximized depending on whether or not the outflow gas temperature detected by the temperature sensor 23 has reached the maximum value. Determine if the value has been reached. Then, when it is determined that the outflow gas temperature has reached the maximum value (that is, the amount of heat generated by the catalyst has reached the maximum value), it is determined that the upstream portion 21a of the NO _X storage catalyst 21 is in a state immediately before saturation, Perform a rich purge.

In the second embodiment described above, substantially the same effect as that of the first embodiment can be obtained. In the second embodiment, the configuration of the first embodiment, since the upstream-side temperature sensor 22 and the air-fuel ratio sensor 24 and the NO _X sensor 25 is omitted, is possible to further lower the cost of the exhaust gas purification system it can.

In the second embodiment, when it is determined that the outflow gas temperature has reached the maximum value, it is determined that the upstream portion 21a of the NO _x storage catalyst 21 is in a state immediately before saturation, and rich purge is performed.

However, the present invention is not limited to this. For example, when the effluent gas temperature exceeds a threshold value lower than the maximum value (for example, the previous maximum value × 0.9) before reaching the maximum value, the NO _X storage catalyst 21 has a lower limit. The rich purge may be performed by determining that the upstream portion 21a is in a state immediately before saturation.

Alternatively, when the effluent gas temperature falls below a threshold value (for example, maximum value × 0.9) lower than the maximum value after reaching the maximum value, the upstream portion 21a of the NO _X storage catalyst 21 is brought into a state immediately before saturation. It may be determined that a rich purge is performed.

Example 3 will be described with reference to FIG. However, description of substantially the same parts as those in the second embodiment will be omitted or simplified, and different parts from the second embodiment will be mainly described.

In the third embodiment, as shown in FIG. 6, a hole 33 for arranging the temperature sensor 23 is provided on the upstream side of the most downstream portion in the exhaust gas flow direction in the NO _X storage catalyst 21. The temperature sensor 23 is disposed at a position corresponding to the hole 33. Even in this case, the temperature sensor 23 can be easily arranged at an intermediate position of the NO _x storage catalyst 21 (that is, upstream from the most downstream portion).

In each of the first to third embodiments, the temperature sensor 23 is disposed at the intermediate position of the NO _X storage catalyst 21 (that is, upstream from the most downstream portion). However, the present invention is not limited to this, and the NO _X storage catalyst 21 The temperature sensor 23 may be disposed on the downstream side. Further, in this case, the NO _X storage catalyst 21 may be configured not to be divided into the upstream portion 21a and the downstream portion 21b (that is, a configuration in which the gap 31 is not provided).

Further, the in the first to third embodiments, as the temperature which changes according to the amount of heat generated by the occlusion reaction of the NO _X storage catalyst 21 is provided with the temperature sensor for detecting the temperature of the exhaust gas is not limited to this, For example, a temperature sensor that detects the temperature of the NO _x storage catalyst 21 may be provided.

In each of the first to third embodiments, the system including the NO _X storage catalyst 21 that stores NO _X in the exhaust gas has been described. However, the present invention is not limited to this, and the predetermined components other than NO _X in the exhaust gas are described. The present disclosure may be applied to a system including an occlusion catalyst that occludes.

In the first to third embodiments, some or all of the functions executed by the ECU 30 may be configured by hardware using one or a plurality of ICs.

The present disclosure is not limited to the in-cylinder injection type engine as shown in FIG. 1, but includes a dual intake port injection type engine and a fuel injection valve for intake port injection and a fuel injection valve for in-cylinder injection. It can also be applied to an injection engine.

Claims

An occlusion catalyst (21) for occlusion by an occlusion reaction for reacting a predetermined component in the exhaust gas of the internal combustion engine (11) with the occlusion material;
A sensor (23) for detecting information that changes according to the state of the occlusion reaction;
An exhaust gas purification system for an internal combustion engine, comprising: a determination unit (30) that determines a state immediately before saturation, which is a state in which the storage amount of the storage catalyst approaches saturation and the storage reaction tends to decrease based on the output of the sensor. apparatus.
2. The exhaust gas purification apparatus for an internal combustion engine according to claim 1, wherein the sensor is a temperature sensor that detects a temperature that changes according to the amount of heat generated by the occlusion reaction as information that changes according to the state of the occlusion reaction.
3. The internal combustion engine according to claim 2, wherein the determination unit determines the state immediately before saturation when it determines that the amount of heat generated by the occlusion reaction has reached a maximum value or a predetermined threshold based on an output of the temperature sensor. Exhaust purification device.
The exhaust gas purification apparatus for an internal combustion engine according to claim 2 or 3, wherein the temperature sensor is disposed upstream of the most downstream portion in the exhaust gas flow direction of the storage catalyst.
The storage catalyst is divided into an upstream portion (21a) and a downstream portion (21b) in the exhaust gas flow direction, and the temperature sensor is disposed between the upstream portion and the downstream portion. The exhaust gas purification apparatus for an internal combustion engine according to claim 4, wherein a clearance (31) is provided.
The exhaust gas purification apparatus for an internal combustion engine according to claim 4, wherein the storage catalyst is provided with a hole (33) for disposing the temperature sensor upstream of the most downstream portion in the flow direction of the exhaust gas.
The exhaust gas purification apparatus for an internal combustion engine according to any one of claims 2 to 6, wherein the temperature sensor has a vibration resistance higher than a predetermined value.
The exhaust purification device for an internal combustion engine according to any one of claims 1 to 7, wherein the storage catalyst is a NO X storage catalyst that stores NO X as the predetermined component when the air-fuel ratio of the exhaust gas is lean.
Wherein when it is determined that the saturation state immediately before the determination unit, a control unit for performing the rich purge to reduce by releasing NO X which the air-fuel ratio of the exhaust gas rich is occluded in the the NO X storage catalyst The exhaust emission control device for an internal combustion engine according to claim 8, further comprising (30).