WO2016134620A1

WO2016134620A1 - Novel water electrolysis device having hole-column-structured electrodes

Info

Publication number: WO2016134620A1
Application number: PCT/CN2016/000099
Authority: WO
Inventors: 罗民雄; 黎明
Original assignee: 罗民雄; 黎明
Priority date: 2015-02-26
Filing date: 2016-02-24
Publication date: 2016-09-01
Also published as: CN104609514A

Abstract

A novel water electrolysis device having hole-column-structured electrodes. The water electrolysis device is characterized by comprising an electrolytic electrode assembly, an electrolytic tank (10) for mounting the electrolytic electrode assembly, and an electrolytic power supply for supplying power to the electrolytic electrode assembly; the electrolytic electrode assembly consists of two electrodes having different polarities (1, 2), the electrodes are cylindrical-hole shaped and column shaped, the number of the cylindrical-hole-shaped electrodes is N, N is equal to or greater than 1; the cylindrical-hole-shaped electrodes (1) are mechanically fixed in position and are mutually electrically connected; the number of the column-shaped electrodes (2) is M, and M is equal to or greater than 1; columns are mechanically fixed in position and are mutually electrically connected; the cylindrical-hole-shaped electrodes (1) and the column-shaped electrodes (2) are correspondingly inserted, that is, columns of the column-shaped electrodes (2) are inserted into corresponding cylindrical holes, a gap (3) for electrolyzing water is reserved between a surface of the column-shaped electrodes (2) and an opposite surface of the cylindrical-hole-shaped electrodes (1) that are correspondingly inserted together; water in the electrode gap (3) can flow during an electrolysis process; and a certain space (11, 12) is reserved outside positions of two ports of the electrode gap (3), so that water can flow in the electrode gap (3) during the electrolysis process.

Description

Novel electrolyzed water device with electrode as pore column structure

Technical field

The invention relates to a novel electrolyzed water device whose electrode is a pore column structure, and belongs to the technical field of electrolysis water without separator.

Background technique

It is well known that drinking electrolyzed water for humans is conducive to the treatment of diseases. Electrolyzed water is not only useful in drinking and food cooking, but also in a wide range of applications such as washing and disinfection as well as industry. The invention belongs to an innovative electrolyzed water device with high electrolysis efficiency in the field of non-isolated membrane electrolyzed water technology.

At present, the common methods and devices for electrolyzing water on the market are mainly divided into two types: a separator and a separator. The biggest common defect is the low electrolysis efficiency. The applicant has conducted long-term research on this problem and invented the electrode as a column. The innovative electrolyzed water device of the structure has greatly improved the efficiency of electrolyzed water.

Summary of the invention

The invention provides a novel electrolyzed water device whose electrode is a pore-column structure, which is based on the applicant's deep understanding of the main defects of the electrolysis water principle of the traditional electrolyzed water machine, and the new principle of electrolyzed water discovered subsequently. The principle of traditional electrolyzed water is limited to the equilibrium of the so-called chemical equations produced by the so-called water molecule electrolysis, completely neglecting the importance of electrons and impurity particles generated by the "impurity electrolysis effect" of the electrolysis process to improve the electrolysis water index and electrolysis efficiency, so there is no explanation. Alkaline water in the cathode region has a higher index of higher reduced water, ie, a higher redox potential (ORP) negative value and a higher hydrogen content (H, H ₂ , H ⁻ ), completely neglecting the higher water formation in the cathode region. The negative value of ORP and H _{2 ,} especially the negative hydrogen H ^- or active hydrogen content, requires a significant amount of active electrons. Therefore, it cannot solve the problem that the existing electrolysis technology is too low, and even if the electrolysis current is increased, the expected higher electrolyzed water cannot be achieved. The problem of indicators. The applicant's long-term research has won six new discoveries:

One of the new discoveries: in the process of electrolyzing water, in order to improve the efficiency of electrolyzed water, the first thing is to electrolyze impurities in water. Impurities are electrolyzed to produce free electrons and impurity particles which are beneficial to increase the index of electrolyzed water, referred to as "impurity electrolysis effect", which forms a certain electrolysis current, which causes water molecules to disintegrate into hydrogen, oxygen ions or hydroxide ions, referred to as "water molecules". Electrolysis effect, referred to as “water electrolysis effect”, electrolysis water efficiency and index are the result of two effects together; the second discovery: reveals the dual meaning of active electrons generated by “impurity electrolysis effect” to improve electrolysis efficiency. Active electrons not only increase the electrolysis current, but also have another important significance for electrolytically producing reduced water, which is to satisfy the negative value of ORP (negative redox potential) and its corresponding hydrogen content (negative hydrogen) of certain electrolyzed water indicators such as electrolytically reduced water. Content) is required for electronics. The "impurity electrolysis effect" should be strengthened as much as possible to produce more active electrons; the newly discovered third: a small gap between the yin and yang electrodes (especially a small gap of less than 1 mm) has a particularly significant effect on strengthening the "impurity electrolysis effect", although before The non-isolated membrane electrolyzed water technology has also mentioned the design considerations of the yin and yang electrode spacing greater than zero and less than 3mm, but did not understand the practical significance of the small spacing, failed to significantly improve the efficiency of electrolysis water; the new discovery four: creating active electrons and The more opportunities and conditions for the binding of active hydrogen H to negative hydrogen can significantly improve the efficiency of electrolytically producing reduced water. The design of small spacing of electrolytic electrode gap is one of the better conditions; the newly discovered five: small gap between yin and yang electrodes is small enough A certain value, the electrolysis efficiency does not rise and fall, the research confirmed: to strengthen the "impurity effect of impurities", also need electrolysis process In the medium to ensure the water in the yin and yang electrode gap has a certain flow, the appropriate use of liquidity, can promote more water molecules and impurities repeatedly repeated electrolysis, thereby strengthening the "impurity of the effect of impurities", improve water electrolysis efficiency and water electrolysis Water reduction index; water circulation study explains why the electrolysis water efficiency does not rise and fall after the electrolysis current increases to a certain value: the ion concentration in the electrode gap is too high, which affects the electrolysis effect; the newly discovered six: for the electrolysis external force drive In the case of running water, such as tap water, a design scheme that reasonably increases the electrolytic gap area in a certain space occupied by the electrode assembly is advantageous for repeated electrolysis of more impurities and water molecules in the water, and can improve water electrolysis efficiency and electrolysis index. In addition, for the channel in which the electrolysis electrode assembly is installed, the design that the water outlet passage (outlet) is appropriately narrower than the inlet passage (inlet) can reduce the flow rate of water passing through the electrolysis electrode assembly, thereby increasing impurities and water molecules. The time and opportunity of electrolysis to increase the index of electrolyzed water.

Through the comprehensive analysis of the above six new discoveries, the applicant proposed the following new principle of electrolyzed water: the process of electrolyzing water, firstly, the process of electrolyzing impurities in the water to generate active electrons to form electric current and convert electric energy into decomposition energy of water molecules, so that more The decomposition of water molecules to obtain larger electric energy is the basis for achieving higher electrolysis efficiency, but it is necessary to have other important conditions to obtain higher electrolysis efficiency; because the electrolysis process is also: various ions released by electrolysis of impurities (especially active The process of physicochemical action of various hydroxide ions and ion roots generated by decomposition of water molecules. First, if more impurities are electrolyzed, more electrons and ions are released, and the probability of combining with hydroxide ions is Higher, the electrolyzed water index may be higher, and the electrolysis efficiency is higher. Second, if the conditions are created, the probability of combining the electron ions released by the electrolysis with the hydroxide ions is higher, the electrolyzed water index may be higher, and the electrolysis efficiency may be higher. It is also higher. For example, the higher ORP negative value and the hydrogen content of electrolytically reduced water (the applicant briefly refers to the two indicators as the "negative hydrogen" index), which requires more active electrons to participate. Therefore, impurities in the water are electrolyzed to release more electrons. Its high probability of combination with hydrogen ions is two important conditions for improving the negative hydrogen index and electrolysis efficiency.

Applicant's new principle of electrolyzed water reveals that it is necessary to adopt a two-pronged process to improve the efficiency of electrolysis to produce reduced water. It is necessary to strengthen the electrolysis of impurities in water, and to increase the probability that electrons released by the electrolysis of impurities and hydrogen are combined into negative hydrogen. Applicant's research found that: First, properly reduce the distance between the electrolysis gap of the yin and yang electrodes, secondly, appropriately enlarge the area of the electrolysis gap of the yin and yang electrodes, and thirdly, properly maintain the fluidity of water in and out of the gap between the yin and yang electrodes in the electrolysis water process. The coordinated realization of the technical conditions can better balance the effect of strengthening the impurity electrolysis and improving the reduction index, thereby significantly improving the efficiency of the electrolysis water. The applicant found through analysis and research:

The invention relates to a novel electrolyzed water device with a pore-column structure, characterized in that: an electrolysis cell assembly, an electrolysis cell for discharging the electrode assembly, and an electrolysis power source for supplying power to the electrolysis electrode assembly; the electrolysis electrode assembly is composed of two One electrode of different polarity is formed, one of the electrodes is in the shape of a cylinder hole, the number of the cylindrical electrode is N, N is equal to or greater than 1, the wall of the tube can be free of gaps or gaps, and the positions of the electrodes of each barrel are mechanically fixed and The electrodes are electrically connected; the electrodes are columnar, the positions of the columns are mechanically fixed and electrically connected to each other, the number of columns of the columnar electrodes is M, M is equal to or greater than 1; the column is hollow or solid, and may be unnotched or notched; The height of the hole electrode and the column electrode is not limited, and is selected according to the requirement; the cylindrical electrode is correspondingly inserted into the column electrode, that is, each column of the column electrode is inserted into each corresponding tube hole, and the surface of the inserted column electrode is opposite to the barrel electrode. There is a gap between the surfaces for electrolysis of water; during the electrolysis work, the water in the electrode gap can flow; there is a certain space outside the two port positions of the electrode gap, so that the water is being In the process solution can flow in the electrode gap, so that the water molecules are more impurities than cathanode electrolytic repeatedly, improving the efficiency of electrolysis of water.

The invention relates to a novel electrolyzed water device whose electrode is a pore column structure, characterized in that: the electrolysis electrode assembly, In the space occupied by the electrolysis electrode assembly, the gap between the yin and yang electrodes is designed according to the principle of reasonable miniaturization. The gap distance is less than 5mm and greater than 0mm, so as to strengthen the electrolysis of impurities and water molecules in the water; Within a certain space occupied by the group, the area of the gap between the yin and yang electrodes is designed according to the principle of reasonable enlargement, so that more impurities and water molecules in the water can be electrolyzed repeatedly in the electrode gap; the electrolysis electrode assembly and its installation process make In the process of electrolyzing water, water can flow smoothly in the gap between the yin and yang electrodes to replace the electrolyzed water in the gap between the yin and yang electrodes, and make more impurities and water molecules repeatedly electrolyzed by the yin and yang electrodes, increasing impurities and water. The probability and quantity of electrolysis of molecules by yin and yang electrodes increases the electrolysis efficiency of water. The design of the electrode as a column-column structure is important: in a certain electrode installation space, the gap between the anode and the cathode can be greatly increased; at the same time, the water in the electrode gap is easy to meet the requirements of better flowability; the process is easy to realize.

The invention relates to a novel electrolyzed water device with a pore-column structure, characterized in that: the electrolysis electrode assembly, if necessary, the spacing between the anode and the cathode electrode of the electrolysis electrode assembly can be as small as 1 mm or less, which is advantageous for Under certain electrolytic power and certain electrolytic electrode assembly structure, it strengthens the electrolysis of impurities and water molecules in water, and improves the efficiency of water electrolysis.

The invention relates to a novel electrolyzed water device with a pore-column structure, wherein the electrolysis electrode assembly can make daily drinking water and water into electrolytic reduced water with a negative oxidation-reduction potential and a hydrogen content greater than zero. .

The invention relates to a novel electrolyzed water device with a pore-column structure, characterized in that: the electrolysis electrode assembly, the structure of the yin and yang electrode is designed such that when the water in the electrode gap is electrolyzed to generate fluidity, the water in the electrode gap is The ions can flow along the potential, so that more water flows through the gap between the yin and yang electrodes, and the water that is electrolyzed in the gap is replaced, so that more impurities and water molecules in the water can be repeatedly electrolyzed by the current between the yin and yang electrodes, and the impurities and water molecules are increased by the yin and yang electrodes. The probability and quantity of electrolysis increase the efficiency of water electrolysis.

The invention relates to a novel electrolyzed water device with a pore-column structure, characterized in that: the electrolysis electrode assembly has a certain space outside the two-port position of the electrode gap, so that water flows when it is electrolyzed, and water It can flow smoothly in the gap between the yin and yang electrodes, improving the efficiency of water electrolysis.

The invention relates to a novel electrolyzed water device with a hole column structure, wherein the electrolysis electrode assembly can extend the flow of water in the electrode gap by reasonably increasing the area of the electrode gap within a certain space occupied by the electrolysis electrode assembly. During the time of electrolysis, more impurities and water molecules are repeatedly electrolyzed by the yin and yang electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by the yin and yang electrodes, and improving the efficiency of water electrolysis.

The invention relates to a novel electrolyzed water device in which the electrode is a pore-column structure, characterized in that: the electrolysis electrode assembly designs the water outlet channel of the electrolysis electrode assembly to be narrower than the water inlet channel, so that the water flowing into the gap of the electrolysis electrode The flow rate is appropriately slowed down, so that more impurities and water molecules can be repeatedly electrolyzed by the current between the yin and yang electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by the yin and yang electrodes, and improving the efficiency of water electrolysis.

The invention relates to a novel electrolyzed water device with a hole column structure, wherein the electrolysis electrode assembly can be appropriately connected when the material and shape of the electrolysis cell wall enclosing the electrolysis electrode assembly are suitable as electrodes. As the electrolysis electrode, the gap area of the electrolysis electrode is increased to improve the electrolysis efficiency of water.

Experiments on the application of electrolytically produced reduced water in water-containing appliances show that the novel electrolyzed water device with the electrode column structure has obtained ultra-efficient electrolyzed water efficiency, and Table 1 lists relevant test data:

Table 1: Experimental test data of natural static water in electrolytic water container by this new method of electrolyzed water

Note: Electrolysis voltage 9V, time 2 minutes, raw water: ORP=+347mv, hydrogen content=0, normal temperature

It can be seen from Table 1 that the method of the present invention can make the electrolyzed water hydrogen content close to the industry-recognized high level of water-saturated hydrogen content of 1.2-1.6 ppm, which is the extremely high electrolysis efficiency that has not been previously achieved without the membrane electrolysis water technology; It can be seen from the comparison data of the two columns in Table 1 that the flowability of water in the electrode gap during electrolysis has a significant influence on the electrolyzed water index, which is the most innovative discovery and design scheme of the present invention. The invention can greatly improve the cost performance, practicability and convenience of the product. For example, using a general non-separating membrane electrolysis method to electrolyze a cup of drinking water of about 350 ml, the ORP reaches about -600 mv, the hydrogen content reaches about 600 ppb, and the electrolysis work needs 8-10 minutes, and the new method for improving the electrolysis water efficiency by the invention is adopted. It takes only 10 seconds to reach the same index, and the electrolysis water efficiency is improved by 40 to 60 times compared with the comparable power.

The invention relates to a novel electrolyzed water device with a pore-column structure, and an experiment for producing reduced water in a disposable electrolyzed flowing water shows that the electrolyzed water device designed according to the applicant's new principle of electrolyzed water and the new method has also obtained super Efficient electrolysis water efficiency, Table 2 lists relevant test data:

Table 2: The new electrolyzed water device of the present invention is applied to the test data of the flow of water driven by a single-time electrolysis external force drive

Note: Electrolytic voltage 9V, raw water: ORP=+345～408mv, hydrogen content=0, normal temperature

The data in Table 2 proves that the new electrolysis device of the present invention can efficiently electrolyze the flow of any temperature and conductivity (including reverse osmosis membrane filtered water, commercially available purified water, distilled water, etc.) flowing through the gap of the yin and yang electrodes at a time. Significantly surpassing the level of the existing non-isolated membrane electrolyzed water technology device, it has been qualified to produce a direct drinking negative hydrogen water machine, the electrolysis power can be less than ten watts, and the membrane electrolyzer needs hundreds of watts of power. The efficiency of the invention is increased by several tens to 100 times, and at the same time, various defects of the electrolysis machine are removed. For example, the electrolysis efficiency of the electrolysis machine is too low, it is fixed in the tap, cannot be carried, and the acidic water is separately discharged. The alkaline water, the negative ORP value and the water-alkaline dependence are interdependent, and only the defects such as normal temperature water can be electrolyzed. The present invention has no such defects, and can design and produce various kinds of portable household drinking water and washing water and the like. Device.

Basic technical solution: A novel electrolyzed water device in which the electrode is a pore-column structure, characterized in that it comprises: An electrolytic electrode assembly, an electrolytic cell for discharging the electrode assembly, and an electrolytic power supply for supplying power to the electrolytic electrode assembly; the electrolytic electrode assembly is composed of two electrodes of different polarities, one of which is a cylindrical hole shape, and the number of the cylindrical electrode For N, N is equal to or greater than 1, the wall of the tube may be free of gaps or gaps, and the positions of the electrodes of the respective barrel holes are mechanically fixed and electrically connected to each other; the second electrode is column-shaped, and the positions of the columns are mechanically fixed and electrically connected to each other. The number of columns of the columnar electrode is M, M is equal to or greater than 1; the column is hollow or solid, and may be unnotched or notched; the height of the cylindrical electrode and the columnar electrode is not limited, and the cylindrical electrode is The columnar electrodes are correspondingly inserted, that is, the columns of the columnar electrodes are inserted into the corresponding barrel holes, and a gap for electrolysis of water is left between the surface of the inserted column electrode and the opposite surface of the barrel electrode; during the electrolysis work, the electrode gap is The water can flow; there is a space outside the two port positions of the electrode gap so that water can flow in the electrode gap during electrolysis. This basic technical solution can increase the probability and quantity of water impurities and water molecules being electrolyzed by the yin and yang electrodes, so that more water impurities and water molecules are repeatedly electrolyzed by the yin and yang electrodes, which significantly improves the electrolysis efficiency of water.

One of the technical solutions of the present invention is that the electrolysis electrode assembly is designed in a certain space occupied by the electrolysis electrode assembly, and the gap between the yin and yang electrodes is designed according to a reasonable and small principle, and the gap distance is less than 5 mm and greater than 0 mm. In order to strengthen the electrolysis of impurities and water molecules in the water; in the space occupied by the electrolysis electrode group, the area of the gap between the yin and yang electrodes is designed according to the principle of reasonable enlargement, so that more impurities and water molecules in the water can be compared in the electrode gap. Electrolytic electrode assembly and its installation process make: in the process of electrolyzing water, water can flow smoothly in the gap between the yin and yang electrodes to replace the electrolyzed water in the gap between the yin and yang electrodes, and make more impurities and water The molecules are repeatedly electrolyzed by the yin and yang electrodes more and more, increasing the probability and quantity of impurities and water molecules being electrolyzed by the yin and yang electrodes, and improving the electrolysis efficiency of the water.

The second technical solution of the present invention is: the electrolysis electrode assembly, if necessary, the spacing between the anode and the cathode of the electrolysis electrode assembly can be as small as 1 mm or less, which is advantageous for a certain electrolysis power and a certain electrolysis electrode assembly structure, Strengthen the electrolysis of impurities and water molecules in water to improve the efficiency of water electrolysis.

The third technical solution of the present invention is that the electrolysis electrode assembly can make daily drinking water and water into electrolytic reduced water having a negative oxidation-reduction potential and a hydrogen content greater than zero.

The fourth technical solution of the present invention is that the electrolysis electrode assembly has a structure of yin and yang electrodes, so that when water in the electrode gap is electrolyzed to generate fluidity, water and ions in the electrode gap can flow with each other so that more water flows through the yin and yang electrodes. The gap replaces the electrolyzed water in the gap, so that more impurities and water molecules in the water can be repeatedly electrolyzed by the current between the yin and yang electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by the yin and yang electrodes, and improving the efficiency of water electrolysis.

According to the fifth aspect of the present invention, the electrolysis electrode assembly has a certain space outside the two port positions of the electrode gap, so that water can flow smoothly in the gap between the yin and yang electrodes when the water flows during the electrolysis, and the water is raised. The efficiency of electrolysis.

According to the sixth aspect of the present invention, the electrolysis electrode assembly can prolong the electrolysis time of the flowing water in the electrode gap by increasing the area of the electrode gap in a certain space occupied by the electrolysis electrode assembly, so that more impurities and water are generated. The molecules are repeatedly electrolyzed by the yin and yang electrodes more and more, increasing the probability and quantity of impurities and water molecules being electrolyzed by the yin and yang electrodes, and improving the efficiency of water electrolysis.

The seventh technical solution of the present invention is that the electrolysis electrode assembly designs the water outlet channel of the electrolysis electrode assembly to be narrower than the water inlet channel, so that the water flow rate flowing into the gap of the electrolysis electrode is appropriately slowed, and more impurities and water molecules can be obtained. The current between the electrodes of yin and yang is repeatedly electrolyzed several times, increasing the probability and quantity of impurities and water molecules being electrolyzed by the yin and yang electrodes, and improving the efficiency of water electrolysis.

According to the eighth aspect of the present invention, in the electrolytic electrode assembly, when the material and shape of the electrolytic cell wall of the electrolytic electrode assembly are suitable as electrodes, the electrode can be appropriately connected as an electrolytic electrode to increase the gap area of the electrolytic electrode and increase the water. Electrolysis efficiency.

DRAWINGS

The invention is further illustrated by the following figures.

1 is a new type of electrolyzed water device in which the electrode is a column-column structure according to Embodiment 1 of the present invention;

2 is a new type of electrolyzed water device in which the electrode is a pore-column structure according to Embodiment 2 of the present invention;

detailed description

The basic structure and basic working principle of the embodiment will be described below with reference to Figs. 1 to 2 of the embodiments 1 and 2.

Example 1

FIG. 1 shows a novel electrolyzed water device in which the electrode is a column-column structure, which is an embodiment applied to an electrolysis external force driven flowing water. 10 is an electrolytic cell, 8 is an electrolytic cell wall, 13 is one of the electrolytic cell inlet and outlet, the electrolytic electrode assembly is composed of two electrodes of different polarity 1, 2, the electrode 1 is a cylindrical hole (referred to as a hole), and the electrode 2 is a column. 1 and 2 can be correspondingly inserted, and the column of the columnar electrode 2 is inserted into the corresponding hole of the hole electrode, and an electrolytic gap 3 is left between the surface of the column and the surface of the hole, and the gap is tubular, which is schematically shown in FIG. a gap 3 formed by the columnar electrode and the hole electrode, the gap spacing may be selected within a certain range, such as less than 5 mm to more than 0 mm; if necessary, the spacing of the gap 3 may take a small value, such as 2 mm or less, In order to strengthen the electrolysis effect of water and impurities therein, when the device requires raw water such as pure water or distilled water with low electrolytic conductivity, high electrolysis water efficiency and index can be obtained; impurities and water molecules are obtained under certain electrode gap distances. The probability and quantity of electrolysis are proportional to the gap area, so that the larger the area of the gap 3 can improve the electrolysis efficiency; in Fig. 1, the electrolysis cell wall 8 is a material suitable for use as an electrolysis electrode, and is connected to the electrolysis power source via the wire 7. A part of the electrode 2 forms an electrolytic gap 4 with the electrode 1 to enhance the electrolysis effect; 11 and 12 are the lower part and the upper space of the electrolytic cell 10, respectively, and a certain volume is designed for the

spaces

11 and 12, which contributes to smooth water in the electrode gap. Smooth flow. Because in the process of electrolyzing water, the water molecules in the gap are electrolytically decomposed, hydrogen and oxygen are generated, and the hydrogen and oxygen bubbles will flow upward along the gap, thereby causing the water in the gap 3 to flow upward, flowing out from the upper port of the gap 3 to Space 12, which causes water to flow from the source of the gap 3, that is, the source of the space 11 into the electrode gap for supplementation. Obviously, if the 11 and 12 are too narrow, the flow of water in the electrode gap may be affected, thereby reducing the electrolysis efficiency of the water; As described above, the gap 3 reasonably selects a small pitch and a large area and satisfies a certain flow property of the water in the gap 3, and the three aspects of the coordinated technical solution can significantly improve the electrolysis efficiency; since the device is used for electrolyzing flowing water, Generally speaking, if the

spaces

11 and 12 outside the gap 3 port are sufficiently wide, it is easy to satisfy the flow of water in the gap; it is worth noting that another problem that may reduce the efficiency of electrolyzing water: if the flow rate of water flowing into the electrolytic cell Too fast, the flow rate of water flowing through the electrode gap will be too fast, which may reduce the electrolysis efficiency. Therefore, when the device is applied to the flow of water with excessively fast flow rate The design of appropriately reducing the flow velocity of the water in the electrolytic cell can be adopted on the basis of satisfying the flow demand of the device. The simpler scheme is to design the outlet of the electrolytic cell 10 to be significantly narrower than the inlet. For example, in Fig. 1, the space 11 is assumed to be The water inlet of the electrolytic cell 8 is 12, and the 12 to 11 is appropriately narrowed, so that the flow rate of water passing through the electrolytic cell is slowed down, and the flow velocity of the water entering the electrode gap is naturally slowed down accordingly, thereby The time during which the water is electrolyzed in the gap is prolonged, thereby enhancing the electrolysis effect of the water. Of course, as mentioned above, the space 12 should not be too narrow, otherwise it will affect the certain flowability required for the water in the gap 3, and will also reduce the electrolysis efficiency and the electrolyzed water index.

For experimental device indicators, please refer to Table 3 for test data:

Table 3: Inventive Example 1 applied to disposable electrolyzed drinking water experimental test data

Note: Electrolytic voltage 12V, raw water: ORP=+368mv, hydrogen content=0, normal temperature

It can be seen that the level of electrolyzed water of the electrolyzed water machine of the separator technology has been reached or exceeded, and the power is only one tenth of it, which satisfies the requirements of practical products.

Example 2

As shown in FIG. 2, when a new type of electrolyzed water device having a hole-column structure is used in the case of natural static water in an electrolytic container, the basic structure and working principle of the present embodiment are similar to those of the first embodiment. 10 is an electrolytic cell, 8 is an electrolytic cell wall, and the electrolytic electrode assembly is composed of two electrodes of different polarity 1, 2, the electrode 1 is in the shape of a hole, the electrode 2 is in the shape of a column, and the electrodes 1 and 2 are correspondingly inserted, and the column of the columnar electrode 2 is connected. Inserting a corresponding hole in the hole electrode, an electrolytic gap 3 is left between the surface of the column and the surface of the hole, and the gap is tubular. The gap 3 between the three column electrodes and the hole electrode is schematically shown in FIG. It may be selected within a certain range as needed, such as a range of less than 5 mm to more than 0 mm; if necessary, the spacing of the gap 3 may take a small value, such as 2 mm or less, in order to strengthen the electrolysis effect of water and impurities therein, which is required in the device. When the raw water such as pure water or distilled water with low electrolytic conductivity is low, the efficiency and index of electrolysis water can be obtained. When the distance between the electrodes is constant, the probability and quantity of impurities and water molecules being electrolyzed are proportional to the gap area. The enlargement of the area of the gap 3 can improve the electrolysis efficiency; in FIG. 1, the cell wall 8 is a material suitable for use as an electrolysis electrode, and is connected to the electrolysis power source via the wire 7 to become a part of the electrode 2, and constitutes an electrolysis gap 4 with the electrode 1. Strengthening the electrolysis effect of the device; 11, 12 are respectively the lower part and the upper space of the electrolytic cell 10, and the space 11 is between the bottom 13 of the electrolytic cell and the bottom of the electrolytic electrode assembly, and a certain volume is designed for the

spaces

11 and 12, which contributes to the electrode gap. The water flows smoothly. Because in the process of electrolyzing water, the water molecules in the gap are electrolytically decomposed, hydrogen and oxygen are generated, and the hydrogen and oxygen bubbles will flow upward along the gap, thereby causing the water in the gap 3 to flow upward, flowing out from the upper port of the gap 3 to Space 12, which causes water to replenish from the source outside the gap 3, that is, the source of the space 11 into the electrode gap, and the water in the

cell spaces

12 and 10 will be supplemented from the

gap

4 or 3, obviously, if 11, 12 is too Narrowness may affect the flow of water in the electrode gap, thereby reducing the electrolysis efficiency of water. During the flow of water in the gap, impurities and water molecules in the water are repeatedly electrolyzed by the electrolysis current in the gap. In this cycle, the water in the electrolytic cell will repeatedly flow into the electrode gap and be repeatedly electrolyzed to continuously strengthen the electrolysis effect; in summary, the gap 3 is reasonably selected for a small spacing and a large area and satisfies the gap 3 with a certain flow of water. These three aspects of coordinated technological solutions can significantly improve the efficiency of electrolysis.

For experimental device indicators, please refer to Table 4 for test data:

Table 4: Experimental test data of natural static water (straight drinking water) in the electrolytic water container of the present invention

Note: Electrolysis voltage 8V, time 1 minute, raw water: ORP=+347mv, hydrogen content=0, normal temperature

It can be seen that the device of the invention can make the electrolyzed water hydrogen content close to the industry-recognized high level of water-saturated hydrogen content of 1.2-1.6 ppm, which is the highest electrolysis efficiency that has not been achieved before. Compared with the comparable power of the non-isolated membrane electrolyzed water technology, the electrolysis water efficiency has increased by several tens to more than one hundred times.

A novel electrolyzed water device in which the electrode is a pore-column structure is not limited to the above-described example device, and any device having the technical features or equivalent features of the present invention falls within the scope of the present invention.

Claims

A novel electrolyzed water device having an electrode column structure, comprising: an electrolysis electrode assembly, an electrolysis cell for discharging the electrode assembly, and an electrolysis power source for supplying power to the electrolysis electrode assembly; the electrolysis electrode assembly is composed of two different One of the electrodes is a cylindrical hole shape, the number of the cylindrical electrode is N, N is equal to or greater than 1, the wall of the cylinder hole can be free of gaps or gaps, and the positions of the electrode holes of each cylinder are mechanically fixed and mutually Electrical connection; the second electrode is columnar, each column position is mechanically fixed and electrically connected to each other, the number of columns of the columnar electrode is M, M is equal to or greater than 1; the column is hollow or solid, no gap or notch; The height of the electrode and the column electrode is not limited, and is selected according to the requirement; the cylindrical electrode is correspondingly inserted into the column electrode, that is, each column of the column electrode is inserted into each corresponding tube hole, and the surface of the inserted column electrode and the surface of the barrel electrode are opposite. There is a gap between the electrolysis of water; during the electrolysis work, the water in the electrode gap can flow; there is a certain space outside the two port positions of the electrode gap, so that the water is electrolyzed Process, can flow in the electrode gap.
A novel electrolyzed water device having a hole-column structure according to claim 1, wherein: the spacing of the gaps between the male and female electrodes of the electrolysis electrode assembly is designed according to a principle of reasonable miniaturization, and the gap is designed. The distance is less than 5mm and greater than 0mm, in order to strengthen the electrolysis of impurities and water molecules in the water; in a certain space occupied by the electrolysis electrode assembly, the area of the gap between the yin and yang electrodes is designed according to a reasonably large size, so that the water is more Impurities and water molecules can be electrolyzed repeatedly in the electrode gap; the characteristics of the electrolysis electrode assembly and its installation process conditions are: in the process of electrolyzing water, water can flow smoothly in the gap between the yin and yang electrodes, so that the gap between the yin and yang electrodes is in the gap The electrolyzed water can be replaced, and more impurities and water molecules are repeatedly electrolyzed by the yin and yang electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by the yin and yang electrodes, thereby improving the electrolysis efficiency of water.
A novel electrolyzed water device having a hole-column structure according to claim 1, wherein: said electrolysis electrode assembly, if necessary, the spacing between the anode and cathode electrodes of the electrolysis electrode assembly can be as small as 1 mm or less In order to strengthen the electrolysis of impurities and water molecules in water under certain electrolysis power and certain electrolysis electrode assembly structure, the efficiency of water electrolysis is improved.
A novel electrolyzed water device having a hole-column structure according to claim 1, wherein the electrolysis electrode assembly can make daily drinking water and water into a redox potential and a hydrogen content greater than Zero electrolytically reduced water.
A novel electrolyzed water device having a hole-column structure according to claim 1, wherein the electro-electrode assembly and the y-yang electrode structure are designed such that when water in the electrode gap is electrolyzed to generate fluidity, Water and ions in the electrode gap can flow along the potential, so that more water flows through the gap between the yin and yang electrodes, and the water that is electrolyzed in the gap is replaced, so that more impurities and water molecules in the water can be repeatedly electrolyzed by the current between the yin and yang electrodes, increasing impurities and The probability and quantity of water molecules being electrolyzed by the yin and yang electrodes increases the efficiency of water electrolysis.
A novel electrolyzed water device having an electrode column structure according to claim 1, wherein the electrolysis electrode assembly has a space outside the two port positions of the electrode gap, so that water is in the process of being electrolyzed. When the flow is generated, the water can flow smoothly in the gap between the yin and theyang electrodes, thereby improving the efficiency of water electrolysis.
A novel electrolyzed water device having a hole-column structure according to claim 1, wherein the electrolysis electrode assembly can increase the area of the electrode gap by a reasonable increase in the area occupied by the electrolysis electrode assembly. Extending the time during which the flowing water is electrolyzed in the electrode gap, so that more impurities and water molecules are repeatedly electrolyzed by the yin and yang electrodes. Increase the probability and quantity of impurities and water molecules being electrolyzed by the yin and yang electrodes, and improve the efficiency of water electrolysis.
A novel electrolyzed water device having a hole-column structure according to claim 1, wherein the electrolysis electrode assembly is designed to narrow the water outlet passage of the electrolysis electrode assembly to be smaller than the water inlet passage, so that the flow enters The water flow rate in the gap of the electrolysis electrode is appropriately slowed down, so that more impurities and water molecules can be repeatedly electrolyzed by the current between the yin and yang electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by the yin and yang electrodes, and improving the efficiency of water electrolysis.
A new type of electrolyzed water device having a hole-column structure according to claim 1, wherein the electrolysis electrode assembly has a material and a shape suitable for the electrode of the electrolytic cell wall of the electrolysis electrode assembly, It can be appropriately connected as an electrolysis electrode to increase the gap area of the electrolysis electrode and improve the electrolysis efficiency of water.