CN104591467A - Electrolytic water vapor generation device - Google Patents

Electrolytic water vapor generation device Download PDF

Info

Publication number
CN104591467A
CN104591467A CN201510088813.5A CN201510088813A CN104591467A CN 104591467 A CN104591467 A CN 104591467A CN 201510088813 A CN201510088813 A CN 201510088813A CN 104591467 A CN104591467 A CN 104591467A
Authority
CN
China
Prior art keywords
electrolysis
water
electrode
gap
electrolytic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510088813.5A
Other languages
Chinese (zh)
Inventor
罗民雄
黎明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201510088813.5A priority Critical patent/CN104591467A/en
Publication of CN104591467A publication Critical patent/CN104591467A/en
Priority to PCT/CN2016/000093 priority patent/WO2016134615A1/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/28Methods of steam generation characterised by form of heating method in boilers heated electrically
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2203/00Apparatus and plants for the biological treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Sustainable Development (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses an electrolytic water vapor generation device which is characterized by comprising a vapor generator, a controllable electrolytic power supply, an electrolytic electrode assembly and a heating system, wherein the vapor generator is provided with a water inlet and a vapor outlet; the heating system can be used for heating the water stored in the vapor generator; the controllable electrolytic power supply supplies electrolytic current for the electrolytic electrode assembly; the electrolytic electrode assembly is used for electrolyzing the water stored in the vapor generator; the heating system is used for heating the electrolytic water in the vapor generator to boil so as to generate vapor; the electrolytic water vapor is outputted from the vapor outlet; the electrolytic electrode assembly adopts a relatively efficient membrane-free electrolytic water technology, so that the water stored in the water storage container in a wide temperature range can be effectively electrolyzed and the electrolytic water vapor can achieve a certain required index; the distance of gaps between electrodes with different polarities of the electrolytic electric assembly is designed according to a reasonable less principle and the area of the gaps is designed according to a reasonable larger principle, so that the water can smoothly flow in the gaps between the electrodes with different polarities and the indexes of the electrolytic water and the water vapor thereof are improved.

Description

A kind of device that electrolysis of water steam occurs
Technical field
The present invention relates to a kind of device that electrolysis of water steam occurs, belong to without film brine electrolysis technical field.
Background technology
Now, people have widely used water vapor cooking food, have steamed face beauty treatment, and do vapor bath promoting health and curing diseases etc., and the electrolysis of water steam that negative potential is rich in hydrogen has anti-oxidant and disinfecting and decontaminating, skin cleaning and beauty effect especially, the effect of removing food peculiar smell, improving taste of food is also had for cooking food, brine electrolysis technology be combined with vapour generator as seen, creating a kind of device that electrolysis of water steam occurs, is very with practical value and many-sided meaning.So, does the device why having no exportable electrolysis of water steam so far come out? one of reason is because popular electrolyzed water machine adopts and inefficient has film brine electrolysis technology, can only electrolysis normal-temperature water, water temperature will disappear more than brine electrolysis index during 50-60 degree Celsius, and there is major defects such as simultaneously must exporting acid-basicity two kinds of water, aquifer yield is little, power consumption is large, obviously do not possess the primary condition manufacturing and designing the device that electrolysis of water steam can occur; Although two of reason is existingly present without film brine electrolysis technology the advantage that film brine electrolysis technology do not have, such as: can the former water of electrolysis arbitrary temp and only export the particular advantages such as a kind of brine electrolysis, but defect is electrolytic efficiency or index or on the low side, is therefore still confined to the electrolysis nature stationary water devices such as glass kettle type that does with the purposes of aspects such as supplying drinking water.Applicant find: adopt electrolytic efficiency higher without film brine electrolysis technology, the device of the generation electrolysis of water steam with practical value can be produced.
Summary of the invention
The present invention proposes a kind of device that electrolysis of water steam occurs, and is to create in order to people can use electrolysis of water steam easily and design.Applicant finds after deliberation: the basis of electrolysis of water steam must have higher and more stable brine electrolysis index based on brine electrolysis under boiling state, therefore, need adopt higher electrolytic efficiency without film brine electrolysis technology, to reach the certain index request of electrolysis of water steam.Adopt applicant to find obtain higher brine electrolysis efficiency and brine electrolysis index with the brine electrolysis new principle of invention and novel method, have very large meaning for the practicality improving brine electrolysis shower.Water electrolysis efficiency or title brine electrolysis efficiency, generally can be defined as: under a certain amount of water of electrolysis and electrolysis certain hour situation, the ratio of certain representative index of made brine electrolysis (the ORP negative value of such as electrolytic reduction water or hydrogen content numerical value) and institute's current consumption.In other words, certain electrolysis process or electrolyzer, it is less that the same water yield of electrolysis reaches same brine electrolysis index institute consuming electric power, and this device brine electrolysis efficiency is higher.
The brine electrolysis new principle that applicant finds and show the method improving brine electrolysis efficiency, root is in deep layer research traditional electrolyte water machine brine electrolysis principle being existed to significant deficiency.Traditional electrolyte water principle is only confined to the ion chemistry molecular balance equation that so-called water molecules electrolysis produces, the impurity ignoring water in electrolytic process completely the electronics that produces by electrolysis and contaminant particles, and to improving the significance of brine electrolysis index and electrolytic efficiency, therefore have no way of explaining that cathodic area alkaline water has comparatively high-reduction water key index and higher oxygen reduction potential (ORP) negative value and higher hydrogeneous (H, H 2, H -) phenomenon measured, ignore cathodic area water completely and form higher ORP negative value and negative hydrogen (H -) content needs the key events of a great deal of active electrons, even if therefore cannot solve the difficult problem that existing electrolysis tech efficiency too low increasing Faradaic current does not reach the higher brine electrolysis index of anticipation yet.Applicant studies for a long period of time acquisition six new discoveries:
One of new discovery: brine electrolysis process, in order to improve brine electrolysis efficiency, the impurity that primary is in brine electrolysis.Impurity is produced unbound electron by electrolysis and is conducive to improving the contaminant particles of brine electrolysis index, be called for short " impurity electrolytic effect " herein, impurity electrolytic effect forms certain Faradaic current, and making water molecules disintegrate becomes hydrogen, oxonium ion or hydroxide ion root, herein referred to as " water molecules electrolytic effect ".Brine electrolysis efficiency and index are " impurity electrolytic effect " and " water molecules electrolytic effect " coefficient result; New discovery two: disclose active electrons that " impurity electrolytic effect " produce for the double meaning improving electrolytic efficiency, active electrons not only can increase Faradaic current, and reductive water is made for electrolysis also there is another significance, meet ORP (negative redox potential) negative value of certain brine electrolysis index such as electrolytic reduction water and corresponding hydrogen richness (negative hydrogen richness) thereof exactly to needed for electronics.Therefore for improving electrolytic efficiency, electrolysis process should be strengthened " impurity electrolytic effect " as far as possible, to produce more active electrons; New discovery three: be that opposing electrode small―gap suture (being especially less than the small―gap suture of 1mm) has unusual effect for strengthening " impurity electrolytic effect ", although non-isolating film brine electrolysis technology before this also once mentioned that opposing electrode spacing was less than the design consideration of 3mm, but do not understand closely spaced practical significance, the technique behave matched with it is not more known where to begin, and can not reach the effect significantly improving brine electrolysis efficiency; New discovery four: another significance of electrolysis electrode gap Small Distance design can create active electrons and active hydrogen H is combined into the more chance of negative hydrogen and better condition, thus significantly improve the efficiency of electrolysis making reductive water; New discovery five: opposing electrode small―gap suture is little of certain value, electrolytic efficiency does not rise counter falling, does is what reason this? research confirms: need to strengthen " impurity electrolytic effect ", also need in electrolytic process, ensure that water has certain circulation in opposing electrode gap, this can impel more water molecules and impurity more repeatedly by electrolysis, thus strengthening " impurity electrolytic effect ", improve water electrolysis efficiency and brine electrolysis and reduce index; To the further investigation of circulation in brine electrolysis process, explain after why Faradaic current is increased to certain value, brine electrolysis efficiency does not rise counter falling.Major reason is: if the circulation of water is bad in electrode gap, can make electrode gap intermediate ion excessive concentration, thus affect electrolytic efficiency; New discovery six: for the outer power-actuated flowing water such as tap water of electrolysis, in certain space shared by electrode assemblie, take the design rationally increasing electrolysis interval area, be conducive to more impurity and water molecules electrolysis more repeatedly in water, water electrolysis efficiency and electrolysis index can be improved.In addition, in the flowing water situation that electrolysis flow velocity is too fast, to the passage installing electrolysis electrode assembly, take the design that water exit (water outlet) is suitably narrower than water entry (water-in), the flow velocity of water through electrolysis electrode assembly can be reduced, thus increase impurity and water molecules are by the time of electrolysis and chance, improve the index of brine electrolysis.
Applicant passes through for above-mentioned six newfound comprehensive analyses, following brine electrolysis new principle is proposed: brine electrolysis process, first, be that the generation of electrolysis impurities in water enlivens electronics, forming electric current, is the process of the decomposition energy of water molecules by electric energy conversion, therefore more water molecules is made to obtain larger electric energy and decompose, be the basis obtaining higher electrolytic efficiency, but obtain higher electrolytic efficiency, also need to possess other essential condition.This is because electrolytic process is simultaneously still: impurity the various ions (especially enlivening electronics) that discharge by electrolysis produce with water-molecule dissociation various hydroxide ions, ion root generation physical and chemical effect process, in the process, for the electrolytic efficiency improving water has two essential condition, first, if more impurity is by electrolysis, electronics, the ion of its release are more, and the probability that itself and hydroxide ion combine is just higher, brine electrolysis index may be higher, and electrolytic efficiency is also just higher; The second, if can create conditions, the probability that the electronic and ionic that impurity is discharged by electrolysis and hydroxide ion combine is higher, and brine electrolysis index may be higher, and electrolytic efficiency is also just higher.The higher ORP negative value of such as electrolytic reduction water and hydrogen content (two indexes is briefly collectively referred to as by applicant " negative hydrogen " index), the more electronics that enlivens is needed to participate in, therefore, impurities in water is discharged by electrolysis that to be combined as the probability of negative hydrogen compared with polyelectrons and electronics and hydrogen ion higher, just can improve negative hydrogen index and electrolytic efficiency.
The brine electrolysis new principle of applicant discloses: improve electrolysis making reductive water efficiency and will take three-pronged processing method, the electrolysis of impurities in water should be strengthened, improve the electronics of impurity electrolysis release again, also will increase the probability that electronics that electrolysis discharges and hydrogen are combined into negative hydrogen.Applicant studies and has found to realize this three-pronged concrete electrolysis process method: one is suitably reduce the distance between opposing electrode electrolysis gap, two is the areas suitably expanding opposing electrode electrolysis gap, three is the mobility suitably remaining on water turnover in brine electrolysis process opposing electrode gap, the coordination of these three technology conditions realizes, strengthening impurity electrolysis can be taken into account preferably and effect of raising reduction index, thus significantly improve brine electrolysis efficiency.A kind of device that electrolysis of water steam occurs of the present invention, need use greater efficiency without film brine electrolysis technology.The brine electrolysis novel method of applicant's invention is adopted to be the better selection improving plant efficiency and performance and cost performance.
A kind of device that electrolysis of water steam occurs of the present invention, is characterized in that: include the vapour generator of water-in and steam outlet, controllable electrolysis power supply, electrolysis electrode assembly, the heating system that can heat water storage in vapour generator; Controllable electrolysis power supply provides Faradaic current to electrolysis electrode assembly, and electrolysis electrode group does electrolysis to water storage in vapour generator; Brine electrolysis in vapour generator is heated to boiling and produces steam by heating system; Electrolysis of water steam exports from steam outlet; Electrolysis electrode assembly adopts greater efficiency without film brine electrolysis technical scheme, and water storage wide temperature range in tank being comprised to boiling can do effective electrolysis, makes certain index that electrolysis of water steam reaches required.
Content two of the present invention: described electrolysis electrode assembly, between its opposing electrode stay the spacing in gap by rationally littleization principle design, clearance distance is being less than 5mm, is being greater than between 0mm, is beneficial to the electrolysis strengthening impurities in water and water molecules; In certain space shared by electrolysis electrode assembly, between opposing electrode, the area in gap is by rationally largeizationr principle design, to make in water more impurity and water molecule energy in electrode gap more repeatedly by electrolysis; The feature of electrolysis electrode assembly and mounting process condition thereof is: in brine electrolysis process, water can comparatively smooth flow in opposing electrode gap, make to be changed by the water of electrolysis in opposing electrode gap, and make more impurity and water molecules by opposing electrode electrolysis more repeatedly, increase impurity and water molecules by the probability of opposing electrode electrolysis and quantity, thus improve the electrolytic efficiency of water.
Content three of the present invention: described electrolysis electrode assembly, if desired, spacing between electrolysis electrode assembly opposing electrode can be as small as 1mm or less, to be comparatively beneficial under certain electrolysis power and certain electrolysis electrode unit construction, the electrolysis of strengthening impurities in water and water molecules, improves the efficiency of water electrolysis.
Content four of the present invention: described electrolysis electrode assembly, by daily drinking-water and can be made into water the electrolytic reduction water that redox potential is negative value, hydrogen content is greater than zero.
Content five of the present invention: described electrolysis electrode assembly, opposing electrode structure design makes: when water in electrode gap is produced mobility by electrolysis, in electrode gap, water and ion can be taken advantage of a situation and be flowed, so that more water flows through opposing electrode gap, change in gap by the water of electrolysis, make more impurities in water and water molecule energy by the electrolysis more repeatedly of electric current between opposing electrode, increase impurity and water molecules, by the probability of opposing electrode electrolysis and quantity, improve the efficiency of water electrolysis.
Content six of the present invention: described electrolysis electrode assembly, certain space is left in outside, electrode gap two-port position, when making water produce flowing in by the process of electrolysis, water can in opposing electrode gap comparatively smooth flow, improve the efficiency of water electrolysis.
Content seven of the present invention: described electrolysis electrode assembly, in certain space shared by electrolysis electrode assembly, by rationally increasing the area of electrode gap, flowing water can be extended in electrode gap by the time of electrolysis, make more impurity and water molecules by opposing electrode electrolysis more repeatedly, increase impurity and water molecules, by the probability of opposing electrode electrolysis and quantity, improve the efficiency of water electrolysis.
Content eight of the present invention: described electrolysis electrode assembly, when the cell wall material and shape of wrapping up electrolysis electrode assembly fit cooperating electrode, suitably can connect it as electrolysis electrode, increase electrolysis electrode interval area, improve the electrolytic efficiency of water.
Content nine of the present invention: described electrolysis electrode assembly, is made up of the electrode of two opposed polarities, one of electrode is bore shape, tubular electrode number is N number of, N is equal to or greater than 1, and barrel can non-notch or jagged, and the position of each bore electrode is fixed and is electrically connected to each other for machinery; Two of electrode is column, and each post position is fixed for mechanical and be electrically connected to each other, and the post number of columnar electrode is M, and M is equal to or greater than 1; Post be hollow or solid, can non-notch or jagged; The height of tubular electrode and columnar electrode is not limit, according to required selection; Tubular electrode grafting corresponding to columnar electrode, namely each post of columnar electrode inserts in each corresponding bore, leaves between the post electrode surface inserted and bore electrode apparent surface gap water being done to electrolysis; In electrolysis working process, the water in electrode gap can flow; Certain space is left in the outside of electrode gap two port position, so that water is by the process of electrolysis, can flow in electrode gap.
Basic technical scheme: a kind of device that electrolysis of water steam occurs of the present invention, is characterized in that: include the vapour generator of water-in and steam outlet, controllable electrolysis power supply, electrolysis electrode assembly, the heating system that can heat water storage in vapour generator; Controllable electrolysis power supply provides Faradaic current to electrolysis electrode assembly, and electrolysis electrode group does electrolysis to water storage in vapour generator; Brine electrolysis in vapour generator is heated to boiling and produces steam by heating system; Electrolysis of water steam exports from steam outlet; Electrolysis electrode assembly adopts greater efficiency without film brine electrolysis technical scheme, and water storage wide temperature range in tank being comprised to boiling can do effective electrolysis, makes certain index that electrolysis of water steam reaches required.
One of concrete technical scheme:: described electrolysis electrode assembly, between its opposing electrode stay the spacing in gap by rationally littleization principle design, clearance distance is being less than 5mm, is being greater than between 0mm, is beneficial to the electrolysis strengthening impurities in water and water molecules; In certain space shared by electrolysis electrode assembly, between opposing electrode, the area in gap is by rationally largeizationr principle design, to make in water more impurity and water molecule energy in electrode gap more repeatedly by electrolysis; The feature of electrolysis electrode assembly and mounting process condition thereof is: in brine electrolysis process, water can comparatively smooth flow in opposing electrode gap, make to be changed by the water of electrolysis in opposing electrode gap, and make more impurity and water molecules by opposing electrode electrolysis more repeatedly, increase impurity and water molecules by the probability of opposing electrode electrolysis and quantity, thus improve the electrolytic efficiency of water.
Concrete technical scheme two:: described electrolysis electrode assembly, if desired, spacing between electrolysis electrode assembly opposing electrode can be as small as 1mm or less, to be comparatively beneficial under certain electrolysis power and certain electrolysis electrode unit construction, the electrolysis of strengthening impurities in water and water molecules, improves the efficiency of water electrolysis.
Concrete technical scheme three:: described electrolysis electrode assembly, by daily drinking-water and can be made into water the electrolytic reduction water that redox potential is negative value, hydrogen content is greater than zero.
Concrete technical scheme four:: described electrolysis electrode assembly, opposing electrode structure design makes: when water in electrode gap is produced mobility by electrolysis, in electrode gap, water and ion can be taken advantage of a situation and be flowed, so that more water flows through opposing electrode gap, change in gap by the water of electrolysis, make more impurities in water and water molecule energy by the electrolysis more repeatedly of electric current between opposing electrode, increase impurity and water molecules, by the probability of opposing electrode electrolysis and quantity, improve the efficiency of water electrolysis.
Concrete technical scheme five:: described electrolysis electrode assembly, certain space is left in outside, electrode gap two-port position, when making water produce flowing in by the process of electrolysis, water can in opposing electrode gap comparatively smooth flow, improve the efficiency of water electrolysis.
Concrete technical scheme six:: described electrolysis electrode assembly, in certain space shared by electrolysis electrode assembly, by rationally increasing the area of electrode gap, flowing water can be extended in electrode gap by the time of electrolysis, make more impurity and water molecules by opposing electrode electrolysis more repeatedly, increase impurity and water molecules, by the probability of opposing electrode electrolysis and quantity, improve the efficiency of water electrolysis.
Concrete technical scheme seven:: described electrolysis electrode assembly, when the cell wall material and shape of wrapping up electrolysis electrode assembly fit cooperating electrode, it suitably can be connected as electrolysis electrode, increase electrolysis electrode interval area, improve the electrolytic efficiency of water.
Concrete technical scheme eight:: described electrolysis electrode assembly, is made up of the electrode of two opposed polarities, and one of electrode is bore shape, tubular electrode number is N number of, N is equal to or greater than 1, and barrel can non-notch or jagged, and the position of each bore electrode is fixed and is electrically connected to each other for machinery; Two of electrode is column, and each post position is fixed for mechanical and be electrically connected to each other, and the post number of columnar electrode is M, and M is equal to or greater than 1; Post be hollow or solid, can non-notch or jagged; The height of tubular electrode and columnar electrode is not limit, according to required selection; Tubular electrode grafting corresponding to columnar electrode, namely each post of columnar electrode inserts in each corresponding bore, leaves between the post electrode surface inserted and bore electrode apparent surface gap water being done to electrolysis; In electrolysis working process, the water in electrode gap can flow; Certain space is left in the outside of electrode gap two port position, so that water is by the process of electrolysis, can flow in electrode gap.
Accompanying drawing explanation
Below by accompanying drawing, the present invention is further explained.
Fig. 1 is the device that electrolysis of water steam occurs the embodiment of the present invention 1 one kinds
Embodiment
Below in conjunction with embodiment 1 accompanying drawing 1 illustrated embodiments basic structure and basic functional principle.
Embodiment 1
As Fig. 1, a kind of device that electrolysis of water steam occurs, comprise vapour generator 14, water-in 18, steam outlet 13, heating system 5, controllable electrolysis power supply 9, the electrolysis electrode assembly that is made up of electrode 1 and 2, electrolyzer 10,15 is gauging lines, and heating system 5 pairs of vapour generator 14 inner storing waters heat, controllable electrolysis power supply 9 is powered to the opposing electrode 1,2 of electrolysis electrode assembly 10 by wire 6,7, does electrolysis to vapour generator 14 water storage, vapour generator 14 water is heated to boiling by heating system 5, exports electrolysis of water steam from steam outlet 13, electrolysis electrode assembly 10 adopts greater efficiency without film brine electrolysis technical scheme, and water storage wide temperature range in vapour generator 14 being comprised to boiling can do effective electrolysis, makes certain index that electrolysis of water steam can reach required, 8 is cell wall, on it, bottom 16, 17 is permeable, electrolysis electrode assembly is by two opposing electrodes 1, 2 are formed, electrode 1 is bore shape (hereinafter referred is poroid), in figure, signal draws 3 poroid electrodes, each bore position machinery is fixing, hole wall is electrically connected to each other, electrode 2 is column, in figure, signal draws 3 posts, each post position machinery is fixing, be electrically connected to each other, 1 and 2 may correspond to grafting, namely the post of columnar electrode 2 inserts in the corresponding aperture of poroid electrode, electrolysis gap 3 is left between post surface and hole surface, this gap in a tubular form, the gap 3 that 3 columnar electrodes and poroid electrode are formed is schematically depict in Fig. 1, gap clearance can optionally be selected within the specific limits, as being less than 5mm to the scope being greater than 0mm, if desired, the desirable smaller value of spacing in gap 3, as being equal to or less than 1mm, so that the electrolysis effectiveness of fortified water and wherein impurity, during the former water such as the pure water that such design needs electrolytic conductivity low at device, distilled water, higher brine electrolysis efficiency and index can be obtained, under electrode gap distance one stable condition, impurity is directly proportional to interval area by the probability of electrolysis and quantity to water molecules, because this gap 3 area largeizationr can improve electrolytic efficiency, in Fig. 1, cell wall 8, for being applicable to the material doing electrolysis electrode use, being connected to via wire 7 part that electrolysis power becomes electrode 2, forming electrolysis gap 4 with electrode 1, stiffening device electrolysis effectiveness, 11,12 bottom and the upper spaces being respectively electrolyzer 10, space 11 is between cell bottom 16 and electrolysis electrode component bottom, designs certain volume to space 11 and 12, contributes to water in electrode gap and smoothly flows.Because in brine electrolysis process, water molecules in gap, by after electrolytic decomposition, can produce hydrogen, oxygen, and hydrogen, oxygen bubbles can be upwards elegant along gap, thus drive water in gap 3 upwards to flow, flow out to space 12 from gap 3 upper port to flow to electrolyzer, this causes water inflow space 11 in a steady stream below electrolyzer bottom 16 again, then flows into electrode gap 3 and supplement, obviously, if 11,12 is too narrow, the circulation of water at electrode gap may be affected, thus reduce the electrolytic efficiency of water.Water is in Clearance Flow process, and impurities in water and water molecules can by Faradaic current electrolysis repeatedly in gap.So move in circles, the water in vapour generator 14 can repeatedly from 8 bottom flow into electrolyzer electrode gap by electrolysis repeatedly, continually strengthen electrolysis effectiveness; In sum, the spacing that gap 3 choose reasonable is less and larger area also meet glassware for drinking water in gap 3 and have certain circulation, and the process technology scheme that this three aspect coordinates to take into account can significantly improve electrolytic efficiency and brine electrolysis index.And brine electrolysis index is high, the ORP negative value of such as brine electrolysis and hydrogen richness high, the anion concentration in electrolysis of water steam is just high.
Table 1: a kind of device embodiment 1 three kinds of electrolysis electrode structures and condition measured data that electrolysis of water steam occurs of the present invention
Note: electrolysis voltage 8V, former water: ORP=+408mv, hydrogen richness=0, normal temperature
Data more visible electrolysis electrode gap 3 area difference half is detected from A, B hurdle or A, C hurdle, or water flow sex differernce in electrode gap, brine electrolysis efficiency is different, and steam index is also significantly different, both the brine electrolysis new principle that applicant proposes and novel method had been confirmed, also verify that the electrolysis of water steam index level of apparatus of the present invention has reached quite high level simultaneously, there is very high practicality.
A kind of device that electrolysis of water steam occurs of the present invention, its electrolysis electrode assembly is not limited to the concrete structure using embodiment 1 to take, and in principle, any one can reach all can applying without film electrolysis electrode construction package of brine electrolysis index required for product.

Claims (9)

1. there is a device for electrolysis of water steam, it is characterized in that: include the vapour generator of water-in and steam outlet, controllable electrolysis power supply, electrolysis electrode assembly, the heating system that can heat water storage in vapour generator; Controllable electrolysis power supply provides Faradaic current to electrolysis electrode assembly, and electrolysis electrode group does electrolysis to water storage in vapour generator; Brine electrolysis in vapour generator is heated to boiling and produces steam by heating system; Electrolysis of water steam exports from steam outlet; Electrolysis electrode assembly adopts greater efficiency without film brine electrolysis technical scheme, and water storage wide temperature range in tank being comprised to boiling can do effective electrolysis, makes certain index that electrolysis of water steam reaches required.
2. a kind of device that electrolysis of water steam occurs according to claim 1, it is characterized in that: described electrolysis electrode assembly, between its opposing electrode stay the spacing in gap by rationally littleization principle design, clearance distance is being less than 5mm, is being greater than between 0mm, is beneficial to the electrolysis strengthening impurities in water and water molecules; In certain space shared by electrolysis electrode assembly, between opposing electrode, the area in gap is by rationally largeizationr principle design, to make in water more impurity and water molecule energy in electrode gap more repeatedly by electrolysis; The feature of electrolysis electrode assembly and mounting process condition thereof is: in brine electrolysis process, water can comparatively smooth flow in opposing electrode gap, make to be changed by the water of electrolysis in opposing electrode gap, and make more impurity and water molecules by opposing electrode electrolysis more repeatedly, increase impurity and water molecules by the probability of opposing electrode electrolysis and quantity, thus improve the electrolytic efficiency of water.
3. a kind of device that electrolysis of water steam occurs according to claim 1, it is characterized in that: described electrolysis electrode assembly, if desired, spacing between electrolysis electrode assembly opposing electrode can be as small as 1mm or less, to be comparatively beneficial under certain electrolysis power and certain electrolysis electrode unit construction, the electrolysis of strengthening impurities in water and water molecules, improves the efficiency of water electrolysis.
4. a kind of device that electrolysis of water steam occurs according to claim 1, is characterized in that: described electrolysis electrode assembly, by daily drinking-water and can be made into water the electrolytic reduction water that redox potential is negative value, hydrogen content is greater than zero.
5. a kind of device that electrolysis of water steam occurs according to claim 1, it is characterized in that: described electrolysis electrode assembly, opposing electrode structure design makes: when water in electrode gap is produced mobility by electrolysis, in electrode gap, water and ion can be taken advantage of a situation and be flowed, so that more water flows through opposing electrode gap, change in gap by the water of electrolysis, make more impurities in water and water molecule energy by the electrolysis more repeatedly of electric current between opposing electrode, increase impurity and water molecules, by the probability of opposing electrode electrolysis and quantity, improve the efficiency of water electrolysis.
6. a kind of device that electrolysis of water steam occurs according to claim 1, it is characterized in that: described electrolysis electrode assembly, certain space is left in outside, electrode gap two-port position, when making water produce flowing in by the process of electrolysis, water can in opposing electrode gap comparatively smooth flow, improve the efficiency of water electrolysis.
7. a kind of device that electrolysis of water steam occurs according to claim 1, it is characterized in that: described electrolysis electrode assembly, in certain space shared by electrolysis electrode assembly, by rationally increasing the area of electrode gap, flowing water can be extended in electrode gap by the time of electrolysis, make more impurity and water molecules by opposing electrode electrolysis more repeatedly, increase impurity and water molecules, by the probability of opposing electrode electrolysis and quantity, improve the efficiency of water electrolysis.
8. a kind of device that electrolysis of water steam occurs according to claim 1, it is characterized in that: described electrolysis electrode assembly, when the cell wall material and shape of wrapping up electrolysis electrode assembly fit cooperating electrode, it suitably can be connected as electrolysis electrode, increase electrolysis electrode interval area, improve the electrolytic efficiency of water.
9. a kind of device that electricity 1 solution water vapor occurs according to claim 1, it is characterized in that: described electrolysis electrode assembly, be made up of the electrode of two opposed polarities, one of electrode is bore shape, tubular electrode number is N number of, N is equal to or greater than 1, and barrel can non-notch or jagged, and the position of each bore electrode is fixed and is electrically connected to each other for machinery; Two of electrode is column, and each post position is fixed for mechanical and be electrically connected to each other, and the post number of columnar electrode is M, and M is equal to or greater than 1; Post be hollow or solid, can non-notch or jagged; The height of tubular electrode and columnar electrode is not limit, according to required selection; Tubular electrode grafting corresponding to columnar electrode, namely each post of columnar electrode inserts in each corresponding bore, leaves between the post electrode surface inserted and bore electrode apparent surface gap water being done to electrolysis; In electrolysis working process, the water in electrode gap can flow; Certain space is left in the outside of electrode gap two port position, so that water is by the process of electrolysis, can flow in electrode gap.
CN201510088813.5A 2015-02-26 2015-02-26 Electrolytic water vapor generation device Pending CN104591467A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201510088813.5A CN104591467A (en) 2015-02-26 2015-02-26 Electrolytic water vapor generation device
PCT/CN2016/000093 WO2016134615A1 (en) 2015-02-26 2016-02-24 Device for generating electrolyzed water vapor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510088813.5A CN104591467A (en) 2015-02-26 2015-02-26 Electrolytic water vapor generation device

Publications (1)

Publication Number Publication Date
CN104591467A true CN104591467A (en) 2015-05-06

Family

ID=53117583

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510088813.5A Pending CN104591467A (en) 2015-02-26 2015-02-26 Electrolytic water vapor generation device

Country Status (2)

Country Link
CN (1) CN104591467A (en)
WO (1) WO2016134615A1 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104962947A (en) * 2015-07-13 2015-10-07 罗民雄 Electrode assembly consisting of N sleeve type electrode groups
WO2016134620A1 (en) * 2015-02-26 2016-09-01 罗民雄 Novel water electrolysis device having hole-column-structured electrodes
WO2016134617A1 (en) * 2015-02-26 2016-09-01 罗民雄 Convenient-to-use portable multi-purpose membraneless water electrolysis device
WO2016134613A1 (en) * 2015-02-26 2016-09-01 罗民雄 Multifunctional membraneless electrolytic boiled water machine
WO2016134621A1 (en) * 2015-02-26 2016-09-01 罗民雄 New membraneless water electrolysis method for significantly improving electrolysis efficiency
WO2016134615A1 (en) * 2015-02-26 2016-09-01 罗民雄 Device for generating electrolyzed water vapor
WO2016134616A1 (en) * 2015-02-26 2016-09-01 罗民雄 Membraneless water electrolysis device for preparing beauty lotion
CN113229708A (en) * 2021-05-27 2021-08-10 珠海格力电器股份有限公司 Steam cooking equipment and disinfection control method, device and storage medium thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009082864A (en) * 2007-10-02 2009-04-23 Matsue Doken Kk Wastewater cleaning method
CN101511740A (en) * 2006-08-08 2009-08-19 株式会社小金井 Water softening method and water softener
CN103857958A (en) * 2011-08-16 2014-06-11 木石创意有限责任公司 Steam generator system
CN104229946A (en) * 2013-06-20 2014-12-24 罗民雄 Simple high-efficiency electrolysis method and device capable of preparing electrolytic water from pure water
CN204689805U (en) * 2015-02-26 2015-10-07 罗民雄 A kind of device that electrolysis of water steam occurs

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4605694B2 (en) * 2004-03-30 2011-01-05 株式会社テックコーポレーション Water quality improvement method and electrolyzed water generating apparatus in electrolyzed water generation
CN103922444B (en) * 2013-01-10 2016-02-03 阿索特·帕比科文西·哈恰特良 A kind of circuit for electrolytic activation hydrous matter and device
CN203668073U (en) * 2013-06-20 2014-06-25 罗民雄 Simple and efficient electrolysis device capable of preparing purified water into electrolyzed water
CN104591467A (en) * 2015-02-26 2015-05-06 罗民雄 Electrolytic water vapor generation device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101511740A (en) * 2006-08-08 2009-08-19 株式会社小金井 Water softening method and water softener
JP2009082864A (en) * 2007-10-02 2009-04-23 Matsue Doken Kk Wastewater cleaning method
CN103857958A (en) * 2011-08-16 2014-06-11 木石创意有限责任公司 Steam generator system
CN104229946A (en) * 2013-06-20 2014-12-24 罗民雄 Simple high-efficiency electrolysis method and device capable of preparing electrolytic water from pure water
CN204689805U (en) * 2015-02-26 2015-10-07 罗民雄 A kind of device that electrolysis of water steam occurs

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016134620A1 (en) * 2015-02-26 2016-09-01 罗民雄 Novel water electrolysis device having hole-column-structured electrodes
WO2016134617A1 (en) * 2015-02-26 2016-09-01 罗民雄 Convenient-to-use portable multi-purpose membraneless water electrolysis device
WO2016134613A1 (en) * 2015-02-26 2016-09-01 罗民雄 Multifunctional membraneless electrolytic boiled water machine
WO2016134621A1 (en) * 2015-02-26 2016-09-01 罗民雄 New membraneless water electrolysis method for significantly improving electrolysis efficiency
WO2016134615A1 (en) * 2015-02-26 2016-09-01 罗民雄 Device for generating electrolyzed water vapor
WO2016134616A1 (en) * 2015-02-26 2016-09-01 罗民雄 Membraneless water electrolysis device for preparing beauty lotion
US10626026B2 (en) 2015-02-26 2020-04-21 Minxiong Luo Multifunctional membraneless boiled water electrolysis machine
CN104962947A (en) * 2015-07-13 2015-10-07 罗民雄 Electrode assembly consisting of N sleeve type electrode groups
CN113229708A (en) * 2021-05-27 2021-08-10 珠海格力电器股份有限公司 Steam cooking equipment and disinfection control method, device and storage medium thereof

Also Published As

Publication number Publication date
WO2016134615A1 (en) 2016-09-01

Similar Documents

Publication Publication Date Title
CN204689805U (en) A kind of device that electrolysis of water steam occurs
CN104591467A (en) Electrolytic water vapor generation device
CN104649374A (en) Multifunctional film-free electrolytic boiled water machine
CN104633912A (en) Water storage type electric water heater capable of draining electrolyzed water
WO2016134621A1 (en) New membraneless water electrolysis method for significantly improving electrolysis efficiency
CN204987427U (en) Water storage formula electric water heater of exportable brineelectrolysis
CN204675865U (en) A kind of multi-functional without film electrolysis boiled water machine
WO2016134616A1 (en) Membraneless water electrolysis device for preparing beauty lotion
CN204675866U (en) A kind of electrode is the Novel electrolytic water device of hole pole structure
CN204675867U (en) A kind of facility use can portable multipurpose without film electrolytic water device
US10421673B2 (en) Simple and efficient electrolysis method and device for making electrolyzed water from pure water
WO2016134620A1 (en) Novel water electrolysis device having hole-column-structured electrodes
WO2016134618A1 (en) New method for membrane-free electrolysis of water capable of controlling acid-base property of the electrolysed water
CN204752287U (en) Show no membrane brineelectrolysis new installation that improves electrolytic efficiency
CN204675868U (en) A kind of device that brine electrolysis atomization gas occurs
CN204689685U (en) A kind of new device adopting two groups of electrolysis electrode assemblies to control brine electrolysis performance
CN104609515A (en) Convenient-to-use portable multi-use membraneless water electrolysis device
CN104709975A (en) Electrolyzed water atomization gas generation device
WO2016134619A1 (en) New method for controlling electrolyzed-water performance by using two sets of electrolytic electrode assemblies
CN204675869U (en) A kind of control brine electrolysis acid-basicity without film brine electrolysis new device
CN204265494U (en) A kind of device having one or more water entrys also water inlet can be made brine electrolysis
CN205011439U (en) A thru hole electrode that is used for material of packed into influence quality of water of brineelectrolysis device
CN105002517A (en) Ozone generating electrode, anode production process and ozone generator
WO2016141768A1 (en) Electrode mainly prepared from ceramic material and applicable to water electrolysis device
CN105060413A (en) Perforated electrode able to load water quality affecting material and used for water electrolysis device

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20150506