WO2016134612A1 - Water storage type electric water heater capable of outputting electrolyzed water - Google Patents

Water storage type electric water heater capable of outputting electrolyzed water Download PDF

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Publication number
WO2016134612A1
WO2016134612A1 PCT/CN2016/000090 CN2016000090W WO2016134612A1 WO 2016134612 A1 WO2016134612 A1 WO 2016134612A1 CN 2016000090 W CN2016000090 W CN 2016000090W WO 2016134612 A1 WO2016134612 A1 WO 2016134612A1
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water
electrolysis
electrolyzed
electrode
gap
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PCT/CN2016/000090
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French (fr)
Chinese (zh)
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罗民雄
黎明
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罗民雄
黎明
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Publication of WO2016134612A1 publication Critical patent/WO2016134612A1/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H1/00Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
    • F24H1/18Water-storage heaters
    • F24H1/20Water-storage heaters with immersed heating elements, e.g. electric elements or furnace tubes

Definitions

  • the invention relates to a water storage type electric water heater capable of outputting electrolyzed water, belonging to the technical field of membrane-free electrolyzed water.
  • the storage type electric water heater is widely used in bathing and using hot water, and the electrolyzed water with negative potential rich in hydrogen has the functions of anti-oxidation, sterilization and decontamination, and beauty cleansing, and is used as a bathing and washing water application.
  • the popular electrolysis machine uses low-efficiency membrane electrolyzed water technology, it can only electrolyze normal temperature water, and when the water temperature exceeds 50-60 degrees Celsius, the electrolyzed water index will disappear, and it is necessary to simultaneously output acid-alkaline Two kinds of water, small amount of water, large power consumption and other serious defects, obviously do not meet the needs of electrolyzed water heaters;
  • the membrane-free electrolyzed water technology shows the advantages of membrane electrolysis water technology, for example: The unique advantage of electrolyzing any temperature raw water and outputting only one type of electrolyzed water, but the defect is that the electrolysis efficiency is still low. In the past, it was limited to the application of drinking pots and other electrolyzed natural static water devices to provide drinking water.
  • the invention provides a water storage type electric water heater capable of outputting electrolyzed water, which is created and designed for people to conveniently use electrolyzed water to bathe. Since the water storage capacity of the electric water heater is large, for the convenience and practical use, the membrane-free electrolyzed water technology with higher electrolysis efficiency should be adopted to meet certain electrolysis water index requirements. If the new principle and new method of electrolyzed water discovered and invented by the applicant are adopted, high electrolysis water efficiency and electrolyzed water index can be obtained, which is of great significance for improving the practicability of the electrolyzed water bath device.
  • the water electrolysis efficiency or electrolysis water efficiency can be generally defined as: a representative index of electrolyzed water produced by electrolysis of a certain amount of water and electrolysis for a certain period of time (for example, ORP negative value or hydrogen content of electrolytically reduced water). The ratio of the quantity) to the amount of electricity consumed. In other words, in an electrolysis method or an electrolysis device, the smaller the electric energy consumed by the same amount of electrolysis to reach the same electrolyzed water index, the higher the electrolysis water efficiency of the device.
  • the new principle of electrolyzed water discovered by the applicant and the method for significantly improving the efficiency of electrolyzed water are rooted in the deep research on the main defects of the electrolysis water principle of the traditional electrolysis machine.
  • the traditional electrolysis water principle is limited to the so-called ion chemical reaction equilibrium equation generated by water molecule electrolysis, completely ignoring the electrons and impurity particles generated by electrolysis of water impurities during electrolysis, and its importance for improving electrolysis water index and electrolysis efficiency.
  • impurities are electrolyzed to produce free electrons and impurity particles which are beneficial to improve the index of electrolyzed water.
  • impurity electrolysis effect forms a certain electrolysis current, which causes the water molecules to disintegrate into hydrogen, oxygen ions or hydroxide ions.
  • the electrolysis process should strengthen the "impurity electrolysis effect" as much as possible to produce more active electrons; the newly discovered three: small gaps of different polarity electrodes (especially small gaps less than 1 mm) for strengthening "impurity electrolysis” "effect” has a significant effect, although the previous non-isolated membrane electrolyzed water technology also mentioned the design considerations of different polarity electrode spacing less than 3mm, but did not understand the practical significance of small spacing, and the matching process measures are even more difficult to talk about.
  • Electrolytic effect improve water electrolysis efficiency and electrolyzed water reduction index; in-depth study of the flowability in the electrolysis water process, explains why the electrolysis water efficiency does not rise and fall after the electrolysis current increases to a certain value.
  • the important reason is that if the flow of water in the electrode gap is not good, the ion concentration in the electrode gap will be too high, which will affect the electrolysis efficiency.
  • the channel for installing the electrolysis electrode assembly adopts a design in which the outlet passage (outlet) is appropriately narrower than the inlet passage (inlet), and the flow rate of water passing through the electrolysis electrode assembly can be reduced. Thereby increasing the time and opportunity for impurities and water molecules to be electrolyzed, and increasing the index of electrolyzed water.
  • electrolyzed water process firstly, the process of generating active electrons by electrolysis of impurities in water, forming electric current, and converting electric energy into decomposition energy of water molecules. Therefore, more water molecules are decomposed by obtaining larger electric energy, which is the basis for obtaining higher electrolysis efficiency, but obtaining higher electrolysis efficiency requires additional important conditions. This is because the electrolysis process is also: the various ions (especially active electrons) released by the electrolysis of the impurities and the various hydroxide ions and ion roots generated by the decomposition of water molecules. In the process of chemical action, there are two important conditions for improving the electrolysis efficiency of water.
  • the electrolyzed water index may be higher, and the electrolysis efficiency is higher.
  • the electrolysis efficiency is also higher. For example, the higher ORP negative value and the hydrogen content of electrolytically reduced water (the applicant briefly refers to the two indicators as the "negative hydrogen" index), which requires more active electrons to participate. Therefore, impurities in the water are electrolyzed to release more electrons. And the combination of electrons and hydrogen ions with a higher probability of negative hydrogen can increase the negative hydrogen index and the electrolysis efficiency.
  • Applicant's new principle of electrolyzed water reveals that it is necessary to adopt a three-pronged process to improve the efficiency of electrolytic reduction water. It is necessary to strengthen the electrolysis of impurities in water, increase the electrons released by the electrolysis of impurities, and increase the electrons released by electrolysis. The probability of combining hydrogen with negative hydrogen.
  • the invention relates to a water storage type electric water heater capable of outputting electrolyzed water.
  • the invention relates to a water storage type electric water heater capable of outputting electrolyzed water, comprising a water storage container, an electric hot water electric control system, a controllable electrolysis power source and a membraneless electrolysis electrode assembly, wherein the water storage container has a water inlet and a water outlet.
  • the raw water enters the water storage container from the water inlet of the water storage container; the electric water electric control system controls the heating of the water in the water storage container; the controllable electrolysis power supply supplies current to the membraneless electrolysis electrode assembly; the membraneless electrolysis electrode assembly is in the water storage container
  • the water is electrolyzed; the electrolyzed water is discharged from the water outlet of the water storage container; the membrane-free electrolysis electrode assembly adopts a high-efficiency membrane-free electrolyzed water technology, and can effectively electrolyze the water stored in the required temperature range in the water storage container.
  • the gap between the electrodes of different polarity electrodes is designed according to the principle of reasonable miniaturization, and the gap distance is less than 5 mm and greater than 0 mm, so as to enhance the impurities in the water.
  • Electrolytic electrode assembly and its installation process conditions are characterized in that water can flow smoothly in the gap of different polarity electrodes during electrolysis of water, so that the electrolyzed water in the gap of different polarity electrodes can be replaced and More impurities and water molecules are repeatedly electrolyzed by different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the electrolysis efficiency of water.
  • the third aspect of the present invention the membraneless electrolytic electrode assembly, if necessary, the spacing between the electrodes of different polarity of the electrolytic electrode assembly can be as small as 1 mm or less, which is advantageous for a certain electrolysis power and a certain electrolysis electrode assembly structure. Strengthen the electrolysis of impurities and water molecules in water to improve the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly can make daily drinking water and water into electrolytic reduction water having a negative oxidation-reduction potential and a hydrogen content greater than zero.
  • the fifth aspect of the invention the membraneless electrolytic electrode assembly, the electrode structure of different polarities is designed to be: when the electrodes are When the water in the gap is electrolyzed to generate fluidity, the water and ions in the electrode gap can flow along the potential, so that more water flows through the gaps of the electrodes of different polarities, and the water that is electrolyzed in the gap is replaced, so that more impurities and water molecules in the water can be
  • the current between the electrodes of different polarities is repeatedly electrolyzed several times, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, and improving the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly has a certain space outside the two-port position of the electrode gap, so that water can flow smoothly in the gap of different polarity electrodes when the water flows during the electrolysis process. Improve the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly can prolong the time during which the flowing water is electrolyzed in the electrode gap by making a reasonable increase in the area of the electrode gap in a certain space occupied by the electrolytic electrode assembly, so that more impurities and water are present.
  • the molecules are repeatedly electrolyzed by different polarity electrodes to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the efficiency of water electrolysis.
  • the electrode in the case of the membrane-free electrolytic electrode assembly, when the material and shape of the electrolytic cell wall of the electrolytic electrode assembly are suitable as electrodes, the electrode can be appropriately connected as an electrolytic electrode to increase the gap area of the electrolytic electrode and increase the water. Electrolysis efficiency.
  • the membraneless electrolytic electrode assembly is composed of two electrodes of different polarities, one of the electrodes is in the shape of a cylindrical hole, the number of cylindrical electrodes is N, N is equal to or greater than 1, and the wall of the tube is absent.
  • the positions of the electrodes of the respective barrel holes are mechanically fixed and electrically connected to each other;
  • the second electrode is columnar, and the positions of the respective columns are mechanically fixed and electrically connected to each other, and the number of columns of the columnar electrodes is M, M is equal to or greater than 1
  • the column is hollow or solid, and may be unnotched or notched;
  • the height of the cylindrical electrode and the columnar electrode is not limited, and is selected according to the requirement;
  • the cylindrical electrode is inserted correspondingly to the columnar electrode, that is, the columnar electrode is inserted into each corresponding cylindrical hole In the middle, the gap between the surface of the inserted column electrode and the opposite surface of the barrel electrode is left to electrolyze the water; during the electrolysis work, the water in the electrode gap can flow; the outside of the two port positions of the electrode gap is fixed Space so that water can flow in the electrode gap during the process of being electrolyzed.
  • the invention relates to a water storage type electric water heater capable of outputting electrolyzed water, comprising a water storage container, an electric hot water electric control system, a controllable electrolysis power source, and a membraneless electrolysis electrode assembly, wherein the water storage container has a feed.
  • the water in the water storage container is electrolyzed; the electrolyzed water is output from the water outlet of the water storage container; the membrane-free electrolysis electrode assembly adopts a high-efficiency membrane-free electrolyzed water technology, and can effectively electrolyze the water stored in the required temperature range in the water storage container.
  • the membrane-free electrolytic electrode assembly the spacing of the gaps between the electrodes of different polarities is designed according to the principle of reasonable miniaturization, and the gap distance is less than 5 mm and greater than 0 mm, so as to enhance the impurities in the water.
  • Electrolysis with water molecules in a certain space occupied by the electrode assembly, the area of the gap between the electrodes of different polarities is designed according to the principle of reasonable enlargement, so that more impurities and water molecules in the water can be repeated many times in the electrode gap.
  • Electrolytic electrode assembly and its installation process conditions are characterized in that water can flow smoothly in the gap of different polarity electrodes during electrolysis of water, so that the electrolyzed water in the gap of different polarity electrodes can be replaced and More impurities and water molecules are repeatedly electrolyzed by different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the electrolysis efficiency of water.
  • the membrane-free electrolytic electrode assembly if necessary, the spacing between the electrodes of different polarity of the electro-electrode assembly can be as small as 1 mm or less, which is advantageous for a certain electrolysis power and a certain electro-electrode assembly structure. Strengthen the electrolysis of impurities and water molecules in water to improve the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly can make daily drinking water and water into electrolytic reduction water with a negative oxidation-reduction potential and a hydrogen content greater than zero.
  • the membrane-free electrolytic electrode assembly the electrode structure of different polarities is designed such that when water in the electrode gap is electrolyzed to generate fluidity, water and ions in the electrode gap can flow with each other so that more water flows.
  • the electrode gaps of different polarities replace the electrolyzed water in the gap, so that more impurities and water molecules in the water can be repeatedly electrolyzed by the currents of different polarity electrodes, increasing the probability of impurities and water molecules being electrolyzed by different polarity electrodes.
  • the quantity increases the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly has a certain space outside the two-port position of the electrode gap, so that when the water flows during the electrolysis, the water can flow smoothly in the gap of the different polarity electrodes. Improve the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly can prolong the time of electrolysis of the flowing water in the electrode gap by increasing the area of the electrode gap within a certain space occupied by the electrolysis electrode assembly, so that more impurities and water are provided.
  • the molecules are repeatedly electrolyzed by different polarity electrodes to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the efficiency of water electrolysis.
  • the electrode in the case of the membrane-free electrolytic electrode assembly, when the material and shape of the electrolytic cell wall of the electrolytic electrode assembly are suitable as an electrode, the electrode can be appropriately connected as an electrolytic electrode to increase the gap area of the electrolytic electrode and increase the water. Electrolysis efficiency.
  • the membrane-free electrolytic electrode assembly is composed of two electrodes of different polarities, one of the electrodes is a cylindrical hole shape, the number of cylindrical electrodes is N, N is equal to or greater than 1, and the wall of the tube can be Notched or notched, the positions of the electrodes of the respective barrel holes are mechanically fixed and electrically connected to each other; the second electrode is columnar, and the positions of the respective columns are mechanically fixed and electrically connected to each other, and the number of columns of the columnar electrodes is M, M is equal to or greater than 1
  • the column is hollow or solid, and may be unnotched or notched; the height of the cylindrical electrode and the columnar electrode is not limited, and is selected according to the requirement; the cylindrical electrode is inserted correspondingly to the columnar electrode, that is, the columnar electrode is inserted into each corresponding cylindrical hole In the middle, the gap between the surface of the inserted column electrode and the opposite surface of the barrel electrode is left to electrolyze the water; during the electrolysis work, the water in the electrode gap
  • Embodiment 1 is a storage type electric water heater capable of outputting electrolyzed water according to Embodiment 1 of the present invention
  • a water storage type electric water heater capable of outputting electrolyzed water comprises a water storage container 14 , an electric hot water electric control system 5 , a controllable electrolysis power source 9 , and a membrane-free electrolysis electrode assembly 10 immersed in water.
  • the water storage container 14 has a water inlet 18 and a water outlet 13; Water enters the water storage container 14 from the water inlet 18 of the water storage container 14; the dotted line 15 in the figure is the water level line of the water in the water storage container 14; the electric hot water electronic control system 5 controls the heating of the water in the water storage container 14; the controllable electrolysis power supply 9 supplying current to the membraneless electrolysis electrode assembly 10; the electrolysis electrode assembly 10 electrolyzing the water in the water storage container; the electrolyzed water is output from the water outlet of the water storage container; the electrolysis electrode assembly adopts a higher efficiency membraneless electrolysis water technology for storage
  • the water storage in the desired temperature range of the water container can be effectively electrolyzed; the electrolysis electrode assembly 8 is characterized in that two electrodes of different polarities are respectively a cylindrical electrode 1 (hereinafter referred to as a hole electrode) and can be correspondingly inserted.
  • the toothed electrode 2, the tooth of the toothed electrode 2 is inserted into the corresponding hole of the hole electrode, and an electrolytic gap 3 is left between the tooth surface and the surface of the hole, and three gaps 3 are schematically illustrated in FIG. If necessary, it is selected in the range of more than 0 to 5 mm: in the case of satisfying the certain flowability of water in the gap 3 during the electrolysis work, the spacing of the gap 3 may take a small value (for example, equal to or even less than 2 mm) to strengthen the water and therein.
  • 11 and 12 are respectively the bottom and upper space of the electrolysis electrode assembly 8, which are designed to make the water flow smoothly in the electrode gap, and in the process of electrolyzing water, the gap After the water molecules are electrolytically decomposed, hydrogen and oxygen bubbles will flow upward along the gap, thereby causing the water in the gap 3 to flow upward and out of the upper port of the gap 3, causing water to continuously flow from the opening of the gap 3, that is, the space 11 In the electrode gap, during the flow of water in the gap, water impurities and water molecules are repeatedly electrolyzed by the electrolysis current in the gap; obviously, the gap 3 is reasonably selected for a small spacing and a large area and satisfies the gap 3 with good circulation of water.
  • these three aspects of the coordination of the technical solutions are conducive to strengthen the electrolysis effect, improve the efficiency of the storage of water in the container 4 and the reference of electrolyzed water (E.g., the ORP of the electrolytic reduced water and negative hydrogen content). If the space of the gap 3 does not leave the space 11 or 11 too narrow, the water in the gap 3 cannot flow smoothly, and the electrolysis efficiency will be significantly reduced. Similarly, the space of the gap 3 does not leave the space 12 or 12 too narrow, and the electrolysis efficiency is also significantly reduced.
  • the treatment method is that the circulation space 12 of the water at the outlet outlet port can be appropriately narrower than the circulation space 11 of the inlet port water to appropriately slow the passage of water.
  • the flow rate of the gap thereby increasing the time during which the water in the gap is electrolyzed, and enhancing the electrolysis effect. Table 1 test data helps to understand the above description.
  • Table 1 The measured data of the first embodiment of the water storage type electric water heater capable of outputting electrolyzed water of the present invention
  • the electrode gap 3 area difference is half, or the electrode
  • the water flow difference in the gap and the electrolyzed water index are significantly different, which confirms the new principle and new method of electrolyzed water proposed by the applicant.
  • the relevant test data proves that the storage type electric water heater capable of outputting electrolyzed water is feasible and innovative. Sexuality, practicality.
  • the invention relates to a water storage type electric water heater capable of outputting electrolyzed water, wherein the electrolysis electrode assembly is not limited to the specific structure adopted in the first embodiment, and in the selection of the actual product technical scheme, the storage of the electrolyzed water which can reach the present invention is used.
  • Any type of membraneless electrolytic electrode structure required for the (electrical, low, high) electrolyzed water index of the water-type electric water heater product belongs to the protection scope of the present invention.

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Abstract

A water storage type electric water heater capable of outputting electrolyzed water comprises a water storage container (14), an electric water heater electronic control system (5), a controllable electrolytic power supply (9) and a membraneless electrolytic electrode assembly (10). The water storage type electric water heater is characterized in that: the water storage container (14) has a water inlet (18) and a water outlet (13); raw water enters the water storage container (14) from the water inlet (18) of the water storage container (14); the electric water heater electronic control system (5) controls heating of the water in the water storage container (14); the controllable electrolytic power supply (9) provides a current to the membraneless electrolytic electrode assembly (10); the membraneless electrolytic electrode assembly (10) electrolyzes the water in the water storage container (14); and electrolyzed water is output from the water outlet (13) of the water storage container (14). A membraneless electrolytic electrode assembly effectively electrolyzes, by using a membraneless water electrolysis technology, water that is stored in the water storage container and that falls within a required temperature range, and the water electrolysis efficiency is improved.

Description

一种可输出电解水的储水式电热水器Storage water electric water heater capable of outputting electrolyzed water 技术领域Technical field
本发明涉及一种可输出电解水的储水式电热水器,属于无膜电解水技术领域。The invention relates to a water storage type electric water heater capable of outputting electrolyzed water, belonging to the technical field of membrane-free electrolyzed water.
背景技术Background technique
储水式电热水器是人们在沐浴与使用热水等方面广泛使用的器具,而负电位富含氢的电解水具有抗氧化与杀菌去污、美容洁肤的功效,作为沐浴与洗涤水应用,至少有六大益处:一是可以少用乃至不用沐浴露等洗洁用化学品,从而减少皮肤过敏瘙痒脱发等不良反应;二是还有治疗一些瘙痒症皮肤病如脚气(香港脚)等的功效;三是具有美容美肤抗氧化抗衰老等保健功效;四是洗涤器具去污能力强;五是洗涤果蔬具有清除农药化肥等污染的功能;六是有利于环保减少化学污染。可见将电解水技术与热水器结合,创造一种可输出电解水的储水式电热水器,是很有实用价值及多方面意义的。那么为什么迄今未见可输出电解水的电热水器问世呢?究其原因:一是因为流行电解水机采用低效率的有膜电解水技术,只能电解常温水,而且水温超过50-60摄氏度时电解水指标就会消失,还有必须同时输出酸碱性两种水、出水量小、耗电大等严重缺陷,显然不符合做电解水电热水器之所需;二是无膜电解水技术虽然展现了有膜电解水技术所未有的优势,例如:可以电解任意温度原水并且只输出一种电解水等独特优点,但是缺陷是电解效率还是偏低,以往尚局限在做杯壶型等电解自然静止水装置提供饮用水方面应用。申请人发现:制造出具有实用价值的储水式电热水器产品,由于储水容量较大,需要配置电解效率较高的无膜电解水技术,无膜电解水技术创新发展已经为此类发明提供了可行性,本发明正是因此应运而生。The storage type electric water heater is widely used in bathing and using hot water, and the electrolyzed water with negative potential rich in hydrogen has the functions of anti-oxidation, sterilization and decontamination, and beauty cleansing, and is used as a bathing and washing water application. There are at least six major benefits: First, it can be used less or even without shower gels, so as to reduce adverse reactions such as skin allergies, itching and hair loss; second, there are some pruritus skin diseases such as athlete's foot (Hong Kong feet). Efficacy; Third, it has the health effects of anti-oxidation and anti-aging; beauty is the strong decontamination ability of washing equipment; fifth, washing fruits and vegetables have the function of removing pollution from pesticides and fertilizers; sixth is beneficial to environmental protection and reducing chemical pollution. It can be seen that the combination of electrolyzed water technology and water heaters to create a storage-type electric water heater that can output electrolyzed water is of great practical value and multi-faceted significance. So why haven't electric water heaters that can output electrolyzed water come out so far? The reason is: First, because the popular electrolysis machine uses low-efficiency membrane electrolyzed water technology, it can only electrolyze normal temperature water, and when the water temperature exceeds 50-60 degrees Celsius, the electrolyzed water index will disappear, and it is necessary to simultaneously output acid-alkaline Two kinds of water, small amount of water, large power consumption and other serious defects, obviously do not meet the needs of electrolyzed water heaters; second, the membrane-free electrolyzed water technology shows the advantages of membrane electrolysis water technology, for example: The unique advantage of electrolyzing any temperature raw water and outputting only one type of electrolyzed water, but the defect is that the electrolysis efficiency is still low. In the past, it was limited to the application of drinking pots and other electrolyzed natural static water devices to provide drinking water. Applicants found that the production of water storage type electric water heaters with practical value, due to the large water storage capacity, requires the use of membrane-free electrolyzed water technology with high electrolysis efficiency. The innovative development of membrane-free electrolyzed water technology has provided such inventions. With the feasibility, the present invention has come into being.
发明内容Summary of the invention
本发明提出一种可输出电解水的储水式电热水器,是为了人们可以方便地使用电解水沐浴而创造与设计。由于电热水器储水容量较大,为方便实用起见,宜采用较高电解效率的无膜电解水技术,以满足一定的电解水指标要求。若采用申请人发现与发明的电解水新原理与新方法,能获得较高电解水效率与电解水指标,对于提高电解水沐浴装置的实用性有很大意义。水电解效率或称电解水效率,一般可以定义为:在电解一定量的水以及电解一定时间情况下,所制成的电解水某种代表性指标(例如电解还原水的ORP负值或含氢量数值)与所耗电量之比。换言之,某种电解方法或电解装置,电解同样水量达到同一电解水指标所耗电能越小,该装置电解水效率就越高。The invention provides a water storage type electric water heater capable of outputting electrolyzed water, which is created and designed for people to conveniently use electrolyzed water to bathe. Since the water storage capacity of the electric water heater is large, for the convenience and practical use, the membrane-free electrolyzed water technology with higher electrolysis efficiency should be adopted to meet certain electrolysis water index requirements. If the new principle and new method of electrolyzed water discovered and invented by the applicant are adopted, high electrolysis water efficiency and electrolyzed water index can be obtained, which is of great significance for improving the practicability of the electrolyzed water bath device. The water electrolysis efficiency or electrolysis water efficiency can be generally defined as: a representative index of electrolyzed water produced by electrolysis of a certain amount of water and electrolysis for a certain period of time (for example, ORP negative value or hydrogen content of electrolytically reduced water). The ratio of the quantity) to the amount of electricity consumed. In other words, in an electrolysis method or an electrolysis device, the smaller the electric energy consumed by the same amount of electrolysis to reach the same electrolyzed water index, the higher the electrolysis water efficiency of the device.
申请人发现的电解水新原理及显著提高电解水效率的方法,根源于对传统电解水机电解水原理存在重大缺陷的深层研究。传统电解水原理仅局限于所谓水分子电解产生的离子化学反应平衡方程,完全忽视了电解过程中水的杂质被电解所产生的电子与杂质微粒,及其对提高电解水指标与电解效率的重要意义,因此无从解释阴极区碱性水具有较 高还原水关键指标即较高氧化还原电位(ORP)负值与较高含氢(H、H2、H-)量的现象,完全忽视了阴极区水形成较高ORP负值与负氢(H-)含量需要相当数量活性电子的关键现象,因此无法解决现有电解技术效率太低、即使加大电解电流也达不到预想较高电解水指标的难题。申请人长期研究获得六个新发现:The new principle of electrolyzed water discovered by the applicant and the method for significantly improving the efficiency of electrolyzed water are rooted in the deep research on the main defects of the electrolysis water principle of the traditional electrolysis machine. The traditional electrolysis water principle is limited to the so-called ion chemical reaction equilibrium equation generated by water molecule electrolysis, completely ignoring the electrons and impurity particles generated by electrolysis of water impurities during electrolysis, and its importance for improving electrolysis water index and electrolysis efficiency. Significance, therefore, it is impossible to explain that the alkaline water in the cathode region has a higher index of higher reducing water, ie, a higher redox potential (ORP) negative value and a higher hydrogen content (H, H 2 , H ), completely ignoring the cathode. The formation of higher ORP negative and negative hydrogen (H - ) content in the zone water requires a significant amount of active electrons, so it cannot solve the problem that the existing electrolysis technology is too low, even if the electrolysis current is increased, it does not reach the expected higher electrolyzed water. The problem of indicators. The applicant's long-term research has won six new discoveries:
新发现之一:电解水过程,为了提高电解水效率,首要的是电解水中的杂质。杂质被电解产生自由电子及有利于提高电解水指标的杂质微粒,本文简称“杂质电解效应”,杂质电解效应形成一定电解电流,令水分子解体成为氢、氧离子或氢氧离子根,本文简称为“水分子电解效应”。电解水效率与指标是“杂质电解效应”与“水分子电解效应”共同作用的结果;新发现之二:揭示了“杂质电解效应”产生的活性电子对于提高电解效率的双重意义,活性电子不仅可增加电解电流,并且对于电解制作还原水还具有另一重要意义,就是满足一定电解水指标例如电解还原水的ORP(负氧化还原电位)负值及其相应的氢含量(负氢含量)对电子之所需。故欲提高电解效率,电解工艺应尽可能强化“杂质电解效应”,以产生较多活性电子;新发现之三:是不同极性电极小间隙(尤其小于1mm的小间隙)对于强化“杂质电解效应”具有显著效果,尽管此前的无隔离膜电解水技术也曾提及不同极性电极间距小于3mm的设计考虑,但是并未了解小间距的实际意义,与之相配的工艺举措更无从谈起,不能达到显著提高电解水效率的效果;新发现之四:电解电极间隙小间距设计的另一重要意义,是可以创造活性电子与活性氢H结合为负氢的较多机会与较好条件,从而显著提高电解制作还原水的效率;新发现之五:不同极性电极小间隙小到某值,电解效率不升反降,这是什么原因呢?研究证实:要强化“杂质电解效应”,还需要在电解过程中保证水在不同极性电极间隙有一定流通性,这可促使较多水分子及杂质较多次反复被电解,从而强化“杂质电解效应”,提高水电解效率与电解水还原指标;对电解水过程中流通性的深入研究,解释了为什么电解电流增加到一定值后,电解水效率不升反降。重要原因在于:若电极间隙中水的流通性不好,会使得电极间隙中离子浓度过高,从而影响电解效率;新发现之六:对于电解外力驱动的流水例如自来水而言,在电极组件所占一定空间内,采取合理增加电解间隙面积的设计方案,有利于水中较多杂质与水分子较多次反复电解,可以提高水电解效率与电解指标。另外,在电解流速过快的流水情况下,对安装电解电极组件的通道,采取出水通道(出水口)比进水通道(进水口)适当狭窄的设计,可以降低水经过电解电极组件的流速,从而增加杂质与水分子被电解的时间与机会,提高电解水的指标。One of the new discoveries: in the process of electrolyzing water, in order to improve the efficiency of electrolyzed water, the first thing is to electrolyze impurities in water. Impurities are electrolyzed to produce free electrons and impurity particles which are beneficial to improve the index of electrolyzed water. This article is referred to as “impurity electrolysis effect”. The impurity electrolysis effect forms a certain electrolysis current, which causes the water molecules to disintegrate into hydrogen, oxygen ions or hydroxide ions. For "water molecule electrolysis effect." The efficiency and index of electrolyzed water are the result of the interaction between “impurity electrolysis effect” and “water molecule electrolysis effect”; the second discovery: reveals the dual meaning of active electrons generated by “impurity electrolysis effect” to improve electrolysis efficiency. It can increase the electrolysis current, and it has another important significance for electrolytically producing reduced water, which is to satisfy the negative value of ORP (negative redox potential) and its corresponding hydrogen content (negative hydrogen content) of certain electrolyzed water indexes such as electrolytically reduced water. The need for electronics. Therefore, in order to improve the electrolysis efficiency, the electrolysis process should strengthen the "impurity electrolysis effect" as much as possible to produce more active electrons; the newly discovered three: small gaps of different polarity electrodes (especially small gaps less than 1 mm) for strengthening "impurity electrolysis" "effect" has a significant effect, although the previous non-isolated membrane electrolyzed water technology also mentioned the design considerations of different polarity electrode spacing less than 3mm, but did not understand the practical significance of small spacing, and the matching process measures are even more difficult to talk about. The effect of significantly improving the efficiency of electrolyzed water cannot be achieved; the fourth finding: another important significance of the design of the small spacing of the electrolysis electrode gap is that it can create more opportunities and better conditions for the combination of active electrons and active hydrogen H into negative hydrogen. Thereby significantly improving the efficiency of electrolytic production of reduced water; the new discovery of five: the small gap of different polarity electrodes is small to a certain value, the electrolysis efficiency does not rise and fall, what is the reason? Studies have confirmed that to strengthen the "impurity effect of impurities", it is also necessary to ensure that the water has a certain flow in the gap between different polar electrodes during the electrolysis process, which can promote more water molecules and impurities to be electrolyzed repeatedly, thereby strengthening the "impurities". Electrolytic effect", improve water electrolysis efficiency and electrolyzed water reduction index; in-depth study of the flowability in the electrolysis water process, explains why the electrolysis water efficiency does not rise and fall after the electrolysis current increases to a certain value. The important reason is that if the flow of water in the electrode gap is not good, the ion concentration in the electrode gap will be too high, which will affect the electrolysis efficiency. The newly discovered six: for the electrolysis externally driven flowing water such as tap water, in the electrode assembly Within a certain space, adopting a design scheme that reasonably increases the area of the electrolytic gap is beneficial to the repeated electrolysis of more impurities and water molecules in the water, which can improve the water electrolysis efficiency and the electrolysis index. In addition, in the case of flowing water with too fast electrolysis flow rate, the channel for installing the electrolysis electrode assembly adopts a design in which the outlet passage (outlet) is appropriately narrower than the inlet passage (inlet), and the flow rate of water passing through the electrolysis electrode assembly can be reduced. Thereby increasing the time and opportunity for impurities and water molecules to be electrolyzed, and increasing the index of electrolyzed water.
申请人通过对于上述六个新发现的综合分析,提出下述电解水新原理:电解水过程,首先,是电解水中杂质产生活跃电子,形成电流,将电能量转换为水分子的分解能量的过程,因此使得较多水分子获得较大电能而分解,是取得较高电解效率的基础,但获得较高电解效率,还需要具备另外的重要条件。这是因为电解过程同时还是:杂质被电解所释放的各种离子(尤其活跃电子)与水分子分解产生的各种氢氧离子、离子根发生理 化作用的过程,在此过程中,为提高水的电解效率有两个重要条件,第一,若较多杂质被电解,其释放的电子、离子较多,其与氢氧离子组合的几率就较高,电解水指标可能较高,电解效率也就较高;第二,若能创造条件,使得杂质被电解释放的电子离子与氢氧离子组合的几率较高,电解水指标可能较高,电解效率也就较高。例如电解还原水的较高ORP负值与含氢量(申请人将两指标简要合称为“负氢”指标),需要较多的活跃电子参与,因此,水中杂质被电解而释放较多电子以及电子与氢离子组合为负氢的几率较高,就可以提高负氢指标与电解效率。Through comprehensive analysis of the above six new findings, the applicant proposed the following new principle of electrolyzed water: electrolyzed water process, firstly, the process of generating active electrons by electrolysis of impurities in water, forming electric current, and converting electric energy into decomposition energy of water molecules. Therefore, more water molecules are decomposed by obtaining larger electric energy, which is the basis for obtaining higher electrolysis efficiency, but obtaining higher electrolysis efficiency requires additional important conditions. This is because the electrolysis process is also: the various ions (especially active electrons) released by the electrolysis of the impurities and the various hydroxide ions and ion roots generated by the decomposition of water molecules. In the process of chemical action, there are two important conditions for improving the electrolysis efficiency of water. First, if more impurities are electrolyzed, more electrons and ions are released, and the probability of combining with hydroxide ions is Higher, the electrolyzed water index may be higher, and the electrolysis efficiency is higher. Second, if conditions can be created, the probability of combining the electron ions released by the electrolysis with the hydroxide ions is higher, and the electrolyzed water index may be higher. The electrolysis efficiency is also higher. For example, the higher ORP negative value and the hydrogen content of electrolytically reduced water (the applicant briefly refers to the two indicators as the "negative hydrogen" index), which requires more active electrons to participate. Therefore, impurities in the water are electrolyzed to release more electrons. And the combination of electrons and hydrogen ions with a higher probability of negative hydrogen can increase the negative hydrogen index and the electrolysis efficiency.
申请人的电解水新原理揭示:提高电解制作还原水效率要采取三管齐下的工艺方法,既要强化水中杂质的电解,又要提高杂质电解释放的电子,还要增加电解所释放的电子与氢结合为负氢的几率。申请人研究发现了实现这三管齐下的具体电解工艺方法:一是适当减小不同极性电极电解间隙之间的距离,二是适当扩大不同极性电极电解间隙的面积,三是适当保持在电解水过程不同极性电极间隙中水进出的流动性,这三个工艺技术条件的协调实现,可以较好地兼顾强化杂质电解并提高还原指标的功效,从而显著提高电解水效率。本发明一种可输出电解水的储水式电热水器,因为储水容量以及电解水时间的一定要求,使用较高效率的无膜电解水技术具有更高的实用性。采用申请人发明的电解水新方法是提高装置效率与性能及性价比的较好选择。Applicant's new principle of electrolyzed water reveals that it is necessary to adopt a three-pronged process to improve the efficiency of electrolytic reduction water. It is necessary to strengthen the electrolysis of impurities in water, increase the electrons released by the electrolysis of impurities, and increase the electrons released by electrolysis. The probability of combining hydrogen with negative hydrogen. Applicant's research found a specific electrolysis process to achieve this three-pronged process: one is to appropriately reduce the distance between the electrolysis gaps of electrodes of different polarities, and the other is to appropriately enlarge the area of the electrolysis gap of electrodes of different polarities, and the third is to properly maintain The fluidity of water in and out of the gap between different polar electrodes in the electrolysis water process, the coordinated realization of these three technological conditions can better balance the effect of strengthening the impurity electrolysis and improving the reduction index, thereby significantly improving the efficiency of electrolysis water. The invention relates to a water storage type electric water heater capable of outputting electrolyzed water. Because of the certain requirements of water storage capacity and electrolysis water time, the use of a higher efficiency membrane-free electrolyzed water technology has higher practicability. The new method of electrolyzed water invented by the applicant is a better choice for improving the efficiency and performance of the device and the cost performance.
本发明一种可输出电解水的储水式电热水器,包括储水容器、电热水电控系统、可控电解电源、无膜电解电极组件,其特征是:储水容器有进水口与出水口;原水从储水容器进水口进入储水容器;电热水电控系统控制储水容器中水的加热;可控电解电源给无膜电解电极组件提供电流;无膜电解电极组件对储水容器中的水进行电解;电解水从储水容器出水口输出;无膜电解电极组件采用较高效率无膜电解水技术,对于储水容器中所需温度范围的储水可以有效电解。The invention relates to a water storage type electric water heater capable of outputting electrolyzed water, comprising a water storage container, an electric hot water electric control system, a controllable electrolysis power source and a membraneless electrolysis electrode assembly, wherein the water storage container has a water inlet and a water outlet. The raw water enters the water storage container from the water inlet of the water storage container; the electric water electric control system controls the heating of the water in the water storage container; the controllable electrolysis power supply supplies current to the membraneless electrolysis electrode assembly; the membraneless electrolysis electrode assembly is in the water storage container The water is electrolyzed; the electrolyzed water is discharged from the water outlet of the water storage container; the membrane-free electrolysis electrode assembly adopts a high-efficiency membrane-free electrolyzed water technology, and can effectively electrolyze the water stored in the required temperature range in the water storage container.
本发明内容之二:所述无膜电解电极组件,其不同极性电极之间所留间隙的间距按合理较小化原则设计,间隙距离在小于5mm、大于0mm之间,以利于强化水中杂质与水分子的电解;在电解电极组件所占一定空间内,不同极性电极之间间隙的面积按合理较大化原则设计,使得水中较多杂质及水分子能在电极间隙中较多次反复被电解;电解电极组件及其安装工艺条件的特征是:在电解水过程中,水在不同极性电极间隙中能较顺利流动,使不同极性电极间隙中被电解的水得以更换,并使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,从而提高水的电解效率。According to the second aspect of the present invention, the gap between the electrodes of different polarity electrodes is designed according to the principle of reasonable miniaturization, and the gap distance is less than 5 mm and greater than 0 mm, so as to enhance the impurities in the water. Electrolysis with water molecules; in a certain space occupied by the electrode assembly, the area of the gap between the electrodes of different polarities is designed according to the principle of reasonable enlargement, so that more impurities and water molecules in the water can be repeated many times in the electrode gap. Electrolytic electrode assembly and its installation process conditions are characterized in that water can flow smoothly in the gap of different polarity electrodes during electrolysis of water, so that the electrolyzed water in the gap of different polarity electrodes can be replaced and More impurities and water molecules are repeatedly electrolyzed by different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the electrolysis efficiency of water.
本发明内容之三:所述无膜电解电极组件,必要时,电解电极组件不同极性电极之间的间距可以小至1mm或更小,以较利于在一定电解功率与一定电解电极组件结构下,强化水中杂质与水分子的电解,提高水电解的效率。The third aspect of the present invention: the membraneless electrolytic electrode assembly, if necessary, the spacing between the electrodes of different polarity of the electrolytic electrode assembly can be as small as 1 mm or less, which is advantageous for a certain electrolysis power and a certain electrolysis electrode assembly structure. Strengthen the electrolysis of impurities and water molecules in water to improve the efficiency of water electrolysis.
本发明内容之四:所述无膜电解电极组件,可以将日常饮水与用水制作成氧化还原电位为负值、含氢量大于零的电解还原水。According to the fourth aspect of the present invention, the membrane-free electrolytic electrode assembly can make daily drinking water and water into electrolytic reduction water having a negative oxidation-reduction potential and a hydrogen content greater than zero.
本发明内容之五:所述无膜电解电极组件,不同极性电极结构设计使得:当电极间 隙中水被电解而产生流动性时,电极间隙中水与离子能够顺势流动,以便更多水流过不同极性电极间隙,更换间隙中被电解的水,使较多水中杂质与水分子能被不同极性电极间电流较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。The fifth aspect of the invention: the membraneless electrolytic electrode assembly, the electrode structure of different polarities is designed to be: when the electrodes are When the water in the gap is electrolyzed to generate fluidity, the water and ions in the electrode gap can flow along the potential, so that more water flows through the gaps of the electrodes of different polarities, and the water that is electrolyzed in the gap is replaced, so that more impurities and water molecules in the water can be The current between the electrodes of different polarities is repeatedly electrolyzed several times, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, and improving the efficiency of water electrolysis.
本发明内容之六:所述无膜电解电极组件,电极间隙两端口位置外部留有一定空间,使得水在被电解的过程中产生流动时,水能在不同极性电极间隙中较顺利流动,提高水电解的效率。According to the sixth aspect of the present invention, the membrane-free electrolytic electrode assembly has a certain space outside the two-port position of the electrode gap, so that water can flow smoothly in the gap of different polarity electrodes when the water flows during the electrolysis process. Improve the efficiency of water electrolysis.
本发明内容之七:所述无膜电解电极组件,在电解电极组件所占一定空间内,通过合理增加电极间隙的面积,可延长流水在电极间隙中被电解的时间,使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。According to the seventh aspect of the present invention, the membrane-free electrolytic electrode assembly can prolong the time during which the flowing water is electrolyzed in the electrode gap by making a reasonable increase in the area of the electrode gap in a certain space occupied by the electrolytic electrode assembly, so that more impurities and water are present. The molecules are repeatedly electrolyzed by different polarity electrodes to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the efficiency of water electrolysis.
本发明内容之八:所述无膜电解电极组件,在包裹电解电极组件的电解槽壁材质与形状适合作电极的情况下,可将其适当连接作为电解电极,增加电解电极间隙面积,提高水的电解效率。According to the eighth aspect of the present invention, in the case of the membrane-free electrolytic electrode assembly, when the material and shape of the electrolytic cell wall of the electrolytic electrode assembly are suitable as electrodes, the electrode can be appropriately connected as an electrolytic electrode to increase the gap area of the electrolytic electrode and increase the water. Electrolysis efficiency.
本发明内容之九:所述无膜电解电极组件,由两个不同极性的电极构成,电极之一为筒孔形状,筒状电极数目为N个,N等于或大于1,筒壁可无缺口或有缺口,各筒孔电极的位置为机械固定并相互电连接;电极之二为柱状,各个柱位置为机械固定并相互电连接,柱状电极的柱数目为M个,M等于或大于1;柱为空心或实心、可无缺口或有缺口;筒状电极与柱状电极的高度不限,据所需选择;筒状电极与柱状电极对应插接,即柱状电极各柱插入各对应筒孔中,对插的柱电极表面与筒孔电极相对表面之间留有对水作电解的间隙;在电解工作过程中,电极间隙内的水可以流动;电极间隙两个端口位置的外部留有一定空间,以便水在被电解的过程中,能在电极间隙中流动。The nineth aspect of the present invention: the membraneless electrolytic electrode assembly is composed of two electrodes of different polarities, one of the electrodes is in the shape of a cylindrical hole, the number of cylindrical electrodes is N, N is equal to or greater than 1, and the wall of the tube is absent. Notched or notched, the positions of the electrodes of the respective barrel holes are mechanically fixed and electrically connected to each other; the second electrode is columnar, and the positions of the respective columns are mechanically fixed and electrically connected to each other, and the number of columns of the columnar electrodes is M, M is equal to or greater than 1 The column is hollow or solid, and may be unnotched or notched; the height of the cylindrical electrode and the columnar electrode is not limited, and is selected according to the requirement; the cylindrical electrode is inserted correspondingly to the columnar electrode, that is, the columnar electrode is inserted into each corresponding cylindrical hole In the middle, the gap between the surface of the inserted column electrode and the opposite surface of the barrel electrode is left to electrolyze the water; during the electrolysis work, the water in the electrode gap can flow; the outside of the two port positions of the electrode gap is fixed Space so that water can flow in the electrode gap during the process of being electrolyzed.
基本技术方案:本发明一种可输出电解水的储水式电热水器,包括储水容器、电热水电控系统、可控电解电源、无膜电解电极组件,其特征是:储水容器有进水口与出水口;原水从储水容器进水口进入储水容器;电热水电控系统控制储水容器中水的加热;可控电解电源给无膜电解电极组件提供电流;无膜电解电极组件对储水容器中的水进行电解;电解水从储水容器出水口输出;无膜电解电极组件采用较高效率无膜电解水技术,对于储水容器中所需温度范围的储水可以有效电解。Basic technical solution: The invention relates to a water storage type electric water heater capable of outputting electrolyzed water, comprising a water storage container, an electric hot water electric control system, a controllable electrolysis power source, and a membraneless electrolysis electrode assembly, wherein the water storage container has a feed. The water inlet and the water outlet; the raw water enters the water storage container from the water inlet of the water storage container; the electric water electric control system controls the heating of the water in the water storage container; the controllable electrolytic power source supplies the current to the membraneless electrolytic electrode assembly; the membraneless electrolytic electrode assembly The water in the water storage container is electrolyzed; the electrolyzed water is output from the water outlet of the water storage container; the membrane-free electrolysis electrode assembly adopts a high-efficiency membrane-free electrolyzed water technology, and can effectively electrolyze the water stored in the required temperature range in the water storage container.
具体技术方案之一:所述无膜电解电极组件,其不同极性电极之间所留间隙的间距按合理较小化原则设计,间隙距离在小于5mm、大于0mm之间,以利于强化水中杂质与水分子的电解;在电解电极组件所占一定空间内,不同极性电极之间间隙的面积按合理较大化原则设计,使得水中较多杂质及水分子能在电极间隙中较多次反复被电解;电解电极组件及其安装工艺条件的特征是:在电解水过程中,水在不同极性电极间隙中能较顺利流动,使不同极性电极间隙中被电解的水得以更换,并使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,从而提高水的电解效率。 One of the specific technical solutions: the membrane-free electrolytic electrode assembly, the spacing of the gaps between the electrodes of different polarities is designed according to the principle of reasonable miniaturization, and the gap distance is less than 5 mm and greater than 0 mm, so as to enhance the impurities in the water. Electrolysis with water molecules; in a certain space occupied by the electrode assembly, the area of the gap between the electrodes of different polarities is designed according to the principle of reasonable enlargement, so that more impurities and water molecules in the water can be repeated many times in the electrode gap. Electrolytic electrode assembly and its installation process conditions are characterized in that water can flow smoothly in the gap of different polarity electrodes during electrolysis of water, so that the electrolyzed water in the gap of different polarity electrodes can be replaced and More impurities and water molecules are repeatedly electrolyzed by different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the electrolysis efficiency of water.
具体技术方案之二:所述无膜电解电极组件,必要时,电解电极组件不同极性电极之间的间距可以小至1mm或更小,以较利于在一定电解功率与一定电解电极组件结构下,强化水中杂质与水分子的电解,提高水电解的效率。The second specific technical solution: the membrane-free electrolytic electrode assembly, if necessary, the spacing between the electrodes of different polarity of the electro-electrode assembly can be as small as 1 mm or less, which is advantageous for a certain electrolysis power and a certain electro-electrode assembly structure. Strengthen the electrolysis of impurities and water molecules in water to improve the efficiency of water electrolysis.
具体技术方案之三:所述无膜电解电极组件,可以将日常饮水与用水制作成氧化还原电位为负值、含氢量大于零的电解还原水。The third technical solution: the membrane-free electrolytic electrode assembly can make daily drinking water and water into electrolytic reduction water with a negative oxidation-reduction potential and a hydrogen content greater than zero.
具体技术方案之四:所述无膜电解电极组件,不同极性电极结构设计使得:当电极间隙中水被电解而产生流动性时,电极间隙中水与离子能够顺势流动,以便更多水流过不同极性电极间隙,更换间隙中被电解的水,使较多水中杂质与水分子能被不同极性电极间电流较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。The fourth technical solution: the membrane-free electrolytic electrode assembly, the electrode structure of different polarities is designed such that when water in the electrode gap is electrolyzed to generate fluidity, water and ions in the electrode gap can flow with each other so that more water flows. The electrode gaps of different polarities replace the electrolyzed water in the gap, so that more impurities and water molecules in the water can be repeatedly electrolyzed by the currents of different polarity electrodes, increasing the probability of impurities and water molecules being electrolyzed by different polarity electrodes. The quantity increases the efficiency of water electrolysis.
具体技术方案之五:所述无膜电解电极组件,电极间隙两端口位置外部留有一定空间,使得水在被电解的过程中产生流动时,水能在不同极性电极间隙中较顺利流动,提高水电解的效率。According to the fifth aspect of the invention, the membrane-free electrolytic electrode assembly has a certain space outside the two-port position of the electrode gap, so that when the water flows during the electrolysis, the water can flow smoothly in the gap of the different polarity electrodes. Improve the efficiency of water electrolysis.
具体技术方案之六:所述无膜电解电极组件,在电解电极组件所占一定空间内,通过合理增加电极间隙的面积,可延长流水在电极间隙中被电解的时间,使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。The sixth technical solution: the membrane-free electrolytic electrode assembly can prolong the time of electrolysis of the flowing water in the electrode gap by increasing the area of the electrode gap within a certain space occupied by the electrolysis electrode assembly, so that more impurities and water are provided. The molecules are repeatedly electrolyzed by different polarity electrodes to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the efficiency of water electrolysis.
具体技术方案之七:所述无膜电解电极组件,在包裹电解电极组件的电解槽壁材质与形状适合作电极的情况下,可将其适当连接作为电解电极,增加电解电极间隙面积,提高水的电解效率。According to a seventh aspect of the present invention, in the case of the membrane-free electrolytic electrode assembly, when the material and shape of the electrolytic cell wall of the electrolytic electrode assembly are suitable as an electrode, the electrode can be appropriately connected as an electrolytic electrode to increase the gap area of the electrolytic electrode and increase the water. Electrolysis efficiency.
具体技术方案之八:所述无膜电解电极组件,由两个不同极性的电极构成,电极之一为筒孔形状,筒状电极数目为N个,N等于或大于1,筒壁可无缺口或有缺口,各筒孔电极的位置为机械固定并相互电连接;电极之二为柱状,各个柱位置为机械固定并相互电连接,柱状电极的柱数目为M个,M等于或大于1;柱为空心或实心、可无缺口或有缺口;筒状电极与柱状电极的高度不限,据所需选择;筒状电极与柱状电极对应插接,即柱状电极各柱插入各对应筒孔中,对插的柱电极表面与筒孔电极相对表面之间留有对水作电解的间隙;在电解工作过程中,电极间隙内的水可以流动;电极间隙两个端口位置的外部留有一定空间,以便水在被电解的过程中,能在电极间隙中流动。A specific technical solution eight: the membrane-free electrolytic electrode assembly is composed of two electrodes of different polarities, one of the electrodes is a cylindrical hole shape, the number of cylindrical electrodes is N, N is equal to or greater than 1, and the wall of the tube can be Notched or notched, the positions of the electrodes of the respective barrel holes are mechanically fixed and electrically connected to each other; the second electrode is columnar, and the positions of the respective columns are mechanically fixed and electrically connected to each other, and the number of columns of the columnar electrodes is M, M is equal to or greater than 1 The column is hollow or solid, and may be unnotched or notched; the height of the cylindrical electrode and the columnar electrode is not limited, and is selected according to the requirement; the cylindrical electrode is inserted correspondingly to the columnar electrode, that is, the columnar electrode is inserted into each corresponding cylindrical hole In the middle, the gap between the surface of the inserted column electrode and the opposite surface of the barrel electrode is left to electrolyze the water; during the electrolysis work, the water in the electrode gap can flow; the outside of the two port positions of the electrode gap is fixed Space so that water can flow in the electrode gap during the process of being electrolyzed.
附图说明DRAWINGS
下面通过附图对本发明作进一步阐释。The invention is further illustrated by the following figures.
所附图1是本发明实施例1一种可输出电解水的储水式电热水器1 is a storage type electric water heater capable of outputting electrolyzed water according to Embodiment 1 of the present invention
具体实施方式detailed description
以下结合实施例1附图1阐述实施例基本结构及基本工作原理。The basic structure and basic working principle of the embodiment will be described below with reference to FIG. 1 of Embodiment 1.
实施例1Example 1
如图1,本发明一种可输出电解水的储水式电热水器,包括储水容器14、电热水电控系统5、可控电解电源9、浸泡在水中的无膜电解电极组件10,其工作过程为:储水容器14有进水口18与出水口13;原 水从储水容器14进水口18进入储水容器14;图中虚线15为储水容器14中水的水位线;电热水电控系统5控制储水容器14中水的加热;可控电解电源9给无膜电解电极组件10提供电流;电解电极组件10对储水容器中的水进行电解;电解水从储水容器出水口输出;电解电极组件采用较高效率无膜电解水技术,对于储水容器中所需温度范围的储水可以有效电解;电解电极组件8的特征为:两个不同极性电极分别为筒孔状电极1(下文简称孔状电极)及与之可对应插接的齿状电极2,齿状电极2的齿插入孔状电极的对应孔中,齿表面与孔表面之间留有电解间隙3,图1中示意性画出了3个间隙3,间隙的间距可视需要在大于0至5mm的范围选择:在满足电解工作过程中水在间隙3中的一定流通性情况下,间隙3的间距可取较小值(如等于乃至小于2mm),以强化水及其中杂质的电解效果,这对于电解纯净水蒸馏水等电导率低的水尤其有利;在间隙距离一定情况下,显然杂质与水分子被电解的几率及数量是与间隙面积成正比的,因此间隙3面积较大化(即孔隙直径与高度取较大值)可提高电解效率;11、12分别为电解电极组件8的底部、上部空间,是为了使得电极间隙中水能畅顺流动而设计的,在电解水过程中,间隙中的水分子被电解分解后,会产生氢、氧气泡沿着间隙向上飘逸,从而带动间隙3中水向上流动,流出间隙3上部端口,引起水从间隙3下开口处即空间11源源不断流入电极间隙中,水在间隙流动的过程中,水杂质与水分子会在间隙中被电解电流反复电解;显然,间隙3合理选择较小的间距与较大面积并满足间隙3中水具有良好流通性,这三个方面协调兼顾的工艺技术方案有利于强化电解效果,提高容器4中储水被电解的效率与电解水的指标(如电解还原水的ORP负值与氢含量)。若间隙3底部不留空间11或者11过于狭窄,间隙3中的水不能畅顺流动,电解效率会显著降低,同理,间隙3上部不留空间12或者12过于狭窄,电解效率也会显著降低;但还有另外一种可能的情况,即电极间隙中水流流速过快,处理办法是间隙出水端口水的流通空间12可以比进水端口水的流通空间11适当狭窄一些,以适当减缓水通过间隙的流速,从而增加间隙中水被电解的时间,强化电解效果。表1检测数据有助于理解以上描述。As shown in FIG. 1 , a water storage type electric water heater capable of outputting electrolyzed water comprises a water storage container 14 , an electric hot water electric control system 5 , a controllable electrolysis power source 9 , and a membrane-free electrolysis electrode assembly 10 immersed in water. The working process is: the water storage container 14 has a water inlet 18 and a water outlet 13; Water enters the water storage container 14 from the water inlet 18 of the water storage container 14; the dotted line 15 in the figure is the water level line of the water in the water storage container 14; the electric hot water electronic control system 5 controls the heating of the water in the water storage container 14; the controllable electrolysis power supply 9 supplying current to the membraneless electrolysis electrode assembly 10; the electrolysis electrode assembly 10 electrolyzing the water in the water storage container; the electrolyzed water is output from the water outlet of the water storage container; the electrolysis electrode assembly adopts a higher efficiency membraneless electrolysis water technology for storage The water storage in the desired temperature range of the water container can be effectively electrolyzed; the electrolysis electrode assembly 8 is characterized in that two electrodes of different polarities are respectively a cylindrical electrode 1 (hereinafter referred to as a hole electrode) and can be correspondingly inserted. The toothed electrode 2, the tooth of the toothed electrode 2 is inserted into the corresponding hole of the hole electrode, and an electrolytic gap 3 is left between the tooth surface and the surface of the hole, and three gaps 3 are schematically illustrated in FIG. If necessary, it is selected in the range of more than 0 to 5 mm: in the case of satisfying the certain flowability of water in the gap 3 during the electrolysis work, the spacing of the gap 3 may take a small value (for example, equal to or even less than 2 mm) to strengthen the water and therein. Electrolytic effect of impurities, this It is especially advantageous to dilute water with low conductivity such as distilled water of purified water; in the case of a certain gap distance, it is obvious that the probability and quantity of impurities and water molecules being electrolyzed are proportional to the gap area, so the area of the gap 3 is larger (ie, pores). The diameter and height take a larger value) to improve the electrolysis efficiency; 11 and 12 are respectively the bottom and upper space of the electrolysis electrode assembly 8, which are designed to make the water flow smoothly in the electrode gap, and in the process of electrolyzing water, the gap After the water molecules are electrolytically decomposed, hydrogen and oxygen bubbles will flow upward along the gap, thereby causing the water in the gap 3 to flow upward and out of the upper port of the gap 3, causing water to continuously flow from the opening of the gap 3, that is, the space 11 In the electrode gap, during the flow of water in the gap, water impurities and water molecules are repeatedly electrolyzed by the electrolysis current in the gap; obviously, the gap 3 is reasonably selected for a small spacing and a large area and satisfies the gap 3 with good circulation of water. Sex, these three aspects of the coordination of the technical solutions are conducive to strengthen the electrolysis effect, improve the efficiency of the storage of water in the container 4 and the reference of electrolyzed water (E.g., the ORP of the electrolytic reduced water and negative hydrogen content). If the space of the gap 3 does not leave the space 11 or 11 too narrow, the water in the gap 3 cannot flow smoothly, and the electrolysis efficiency will be significantly reduced. Similarly, the space of the gap 3 does not leave the space 12 or 12 too narrow, and the electrolysis efficiency is also significantly reduced. However, there is another possibility that the flow velocity of the water in the electrode gap is too fast, and the treatment method is that the circulation space 12 of the water at the outlet outlet port can be appropriately narrower than the circulation space 11 of the inlet port water to appropriately slow the passage of water. The flow rate of the gap, thereby increasing the time during which the water in the gap is electrolyzed, and enhancing the electrolysis effect. Table 1 test data helps to understand the above description.
表1:本发明一种可输出电解水的储水式电热水器实施例1的实测数据Table 1: The measured data of the first embodiment of the water storage type electric water heater capable of outputting electrolyzed water of the present invention
Figure PCTCN2016000090-appb-000001
Figure PCTCN2016000090-appb-000001
注:电解电压12V,原水:ORP=+365-402mv,氢含量=0,常温Note: Electrolytic voltage 12V, raw water: ORP=+365-402mv, hydrogen content=0, normal temperature
从A、B栏或A、C栏检测数据比较可见:电解电极间隙3面积相差一半,或者电极 间隙中水流动性差异,电解水指标均显著不同,证实了申请人提出的电解水新原理以及新方法.有关检测数据证明:本发明可输出电解水的储水式电热水器具有可行性、创新性、实用性。From the A, B column or A, C column detection data can be seen: the electrode gap 3 area difference is half, or the electrode The water flow difference in the gap and the electrolyzed water index are significantly different, which confirms the new principle and new method of electrolyzed water proposed by the applicant. The relevant test data proves that the storage type electric water heater capable of outputting electrolyzed water is feasible and innovative. Sexuality, practicality.
本发明一种可输出电解水的储水式电热水器,其电解电极组件并不限于使用实施例1所采取的具体结构,在实际产品技术方案选择方面,使用达到本发明可输出电解水的储水式电热水器产品所需(低中高)电解水指标的任何一种无膜电解电极结构,都属于本发明保护范围。 The invention relates to a water storage type electric water heater capable of outputting electrolyzed water, wherein the electrolysis electrode assembly is not limited to the specific structure adopted in the first embodiment, and in the selection of the actual product technical scheme, the storage of the electrolyzed water which can reach the present invention is used. Any type of membraneless electrolytic electrode structure required for the (electrical, low, high) electrolyzed water index of the water-type electric water heater product belongs to the protection scope of the present invention.

Claims (9)

  1. 一种可输出电解水的储水式电热水器,包括储水容器、电热水电控系统、可控电解电源、无膜电解电极组件,其特征是:储水容器有进水口与出水口;原水从储水容器进水口进入储水容器;电热水电控系统控制储水容器中水的加热;可控电解电源给无膜电解电极组件提供电流;无膜电解电极组件对储水容器中的水进行电解;电解水从储水容器出水口输出;无膜电解电极组件采用较高效率无膜电解水技术,对于储水容器中所需温度范围的储水可以有效电解。The utility model relates to a water storage type electric water heater capable of outputting electrolyzed water, comprising a water storage container, an electric hot water electric control system, a controllable electrolysis power source and a membraneless electrolysis electrode assembly, wherein the water storage container has a water inlet and a water outlet; the raw water Entering the water storage container from the water inlet of the water storage container; the electric water electric control system controls the heating of the water in the water storage container; the controllable electrolysis power supply supplies the current to the membraneless electrolysis electrode assembly; the membraneless electrolysis electrode assembly supplies the water in the water storage container Electrolysis is carried out; electrolyzed water is output from the water outlet of the water storage container; the membrane-free electrolysis electrode assembly adopts a high-efficiency membrane-free electrolyzed water technology, and can effectively electrolyze the water stored in the required temperature range in the water storage container.
  2. 根据权利要求1所述的一种可输出电解水的储水式电热水器,其特征是:所述无膜电解电极组件,其不同极性电极之间所留间隙的间距按合理较小化原则设计,间隙距离在小于5mm、大于0mm之间,以利于强化水中杂质与水分子的电解;在电解电极组件所占一定空间内,不同极性电极之间间隙的面积按合理较大化原则设计,使得水中较多杂质及水分子能在电极间隙中较多次反复被电解;电解电极组件及其安装工艺条件的特征是:在电解水过程中,水在不同极性电极间隙中能较顺利流动,使不同极性电极间隙中被电解的水得以更换,并使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,从而提高水的电解效率。The water storage type electric water heater capable of outputting electrolyzed water according to claim 1, wherein the gap of the gap between the electrodes of different polarity is substantially reduced according to the principle of the membraneless electrolytic electrode assembly Design, the gap distance is less than 5mm, greater than 0mm, in order to strengthen the electrolysis of impurities and water molecules in the water; in the space occupied by the electrolytic electrode assembly, the area of the gap between the electrodes of different polarities is designed according to the principle of reasonable enlargement Therefore, more impurities and water molecules in the water can be electrolyzed repeatedly in the electrode gap; the characteristics of the electrolysis electrode assembly and its installation process conditions are: water can be smoothly in the gap of different polarity electrodes during the electrolysis of water Flow, so that the electrolyzed water in the gap of different polarity electrodes can be replaced, and more impurities and water molecules are repeatedly electrolyzed by different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes. , thereby increasing the electrolysis efficiency of water.
  3. 根据权利要求1所述的一种可输出电解水的储水式电热水器,其特征是:所述无膜电解电极组件,必要时,电解电极组件不同极性电极之间的间距可以小至1mm或更小,以较利于在一定电解功率与一定电解电极组件结构下,强化水中杂质与水分子的电解,提高水电解的效率。A water storage type electric water heater capable of outputting electrolyzed water according to claim 1, wherein: said membraneless electrolysis electrode assembly, if necessary, the spacing between electrodes of different polarity of the electrolysis electrode assembly can be as small as 1 mm Or smaller, in order to strengthen the electrolysis of impurities and water molecules in water under a certain electrolysis power and certain electrolysis electrode assembly structure, and improve the efficiency of water electrolysis.
  4. 根据权利要求1所述的一种可输出电解水的储水式电热水器,其特征是:所述无膜电解电极组件,可以将日常饮水与用水制作成氧化还原电位为负值、含氢量大于零的电解还原水。The water storage type electric water heater capable of outputting electrolyzed water according to claim 1, wherein the membrane-free electrolytic electrode assembly can make daily drinking water and water into a redox potential and a hydrogen content. Electrolytic reduced water greater than zero.
  5. 根据权利要求1所述的一种可输出电解水的储水式电热水器,其特征是:所述无膜电解电极组件,不同极性电极结构设计使得:当电极间隙中水被电解而产生流动性时,电极间隙中水与离子能够顺势流动,以便更多水流过不同极性电极间隙,更换间隙中被电解的水,使较多水中杂质与水分子能被不同极性电极间电流较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。A water storage type electric water heater capable of outputting electrolyzed water according to claim 1, wherein said membraneless electrolytic electrode assembly has different polarity electrode structure design: when water is electrolyzed in the electrode gap to generate flow When it is sexual, the water and ions in the electrode gap can flow with each other, so that more water flows through the gaps of different polarity electrodes, and the water that is electrolyzed in the gap is replaced, so that more impurities and water molecules in the water can be more current between the electrodes of different polarities. Repeated electrolysis repeatedly increases the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, improving the efficiency of water electrolysis.
  6. 根据权利要求1所述的一种可输出电解水的储水式电热水器,其特征是:所述无膜电解电极组件,电极间隙两端口位置外部留有一定空间,使得水在被电解的过程中产生流动时,水能在不同极性电极间隙中较顺利流动,提高水电解的效率。A water storage type electric water heater capable of outputting electrolyzed water according to claim 1, wherein said membrane-free electrolytic electrode assembly has a space outside the two-port position of the electrode gap, so that water is electrolyzed. When the flow occurs, the water can flow smoothly in the gaps of different polarity electrodes, improving the efficiency of water electrolysis.
  7. 根据权利要求1所述的一种可输出电解水的储水式电热水器,其特征是:所述无膜电解电极组件,在电解电极组件所占一定空间内,通过合理增加电极间隙的面积,可延长流水在电极间隙中被电解的时间,使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。A water storage type electric water heater capable of outputting electrolyzed water according to claim 1, wherein said membrane-free electrolytic electrode assembly has a reasonable increase in the area of the electrode gap within a certain space occupied by the electrolytic electrode assembly. The time during which the flowing water is electrolyzed in the electrode gap can be prolonged, so that more impurities and water molecules are repeatedly electrolyzed by different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, and improving water electrolysis. effectiveness.
  8. 根据权利要求1所述的一种可输出电解水的储水式电热水器,其特征是:所述无膜电解电极组件,在包裹电解电极组件的电解槽壁材质与形状适合作电极的情况下,可将其适当连接作为电解电极,增加电解电极间隙面积,提高水的电解效率。 A water storage type electric water heater capable of outputting electrolyzed water according to claim 1, wherein said membraneless electrolytic electrode assembly is in the case where the material and shape of the electrolytic cell wall of the electrolytic electrode assembly are suitable as electrodes It can be appropriately connected as an electrolysis electrode to increase the gap area of the electrolysis electrode and improve the electrolysis efficiency of water.
  9. 根据权利要求1所述的一种可输出电解水的储水式电热水器,其特征是:所述无膜电解电极组件,由两个不同极性的电极构成,电极之一为筒孔形状,筒状电极数目为N个,N等于或大于1,筒壁可无缺口或有缺口,各筒孔电极的位置为机械固定并相互电连接;电极之二为柱状,各个柱位置为机械固定并相互电连接,柱状电极的柱数目为M个,M等于或大于1;柱为空心或实心、可无缺口或有缺口;筒状电极与柱状电极的高度不限,据所需选择;筒状电极与柱状电极对应插接,即柱状电极各柱插入各对应筒孔中,对插的柱电极表面与筒孔电极相对表面之间留有对水作电解的间隙;在电解工作过程中,电极间隙内的水可以流动;电极间隙两个端口位置的外部留有一定空间,以便水在被电解的过程中,能在电极间隙中流动。 The water storage type electric water heater capable of outputting electrolyzed water according to claim 1, wherein the membraneless electrolysis electrode assembly is composed of two electrodes of different polarities, and one of the electrodes is in the shape of a cylinder hole. The number of cylindrical electrodes is N, N is equal to or greater than 1, the wall of the tube can be free of gaps or gaps, and the positions of the electrodes of the respective barrel holes are mechanically fixed and electrically connected to each other; the second electrode is columnar, and the positions of the respective columns are mechanically fixed and Electrically connected to each other, the number of columns of the columnar electrode is M, M is equal to or greater than 1; the column is hollow or solid, and may be unnotched or notched; the height of the cylindrical electrode and the columnar electrode is not limited, as needed; The electrode is inserted into the column electrode, that is, each column of the column electrode is inserted into each corresponding tube hole, and a gap for electrolysis of water is left between the surface of the inserted column electrode and the opposite surface of the barrel electrode; during the electrolysis work, the electrode The water in the gap can flow; there is a space outside the two port positions of the electrode gap so that water can flow in the electrode gap during the electrolysis process.
PCT/CN2016/000090 2015-02-26 2016-02-24 Water storage type electric water heater capable of outputting electrolyzed water WO2016134612A1 (en)

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