WO2016134612A1 - Chauffe-eau électrique du type à stockage de l'eau capable de produire de l'eau électrolysée - Google Patents

Chauffe-eau électrique du type à stockage de l'eau capable de produire de l'eau électrolysée Download PDF

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Publication number
WO2016134612A1
WO2016134612A1 PCT/CN2016/000090 CN2016000090W WO2016134612A1 WO 2016134612 A1 WO2016134612 A1 WO 2016134612A1 CN 2016000090 W CN2016000090 W CN 2016000090W WO 2016134612 A1 WO2016134612 A1 WO 2016134612A1
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Prior art keywords
water
electrolysis
electrolyzed
electrode
gap
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PCT/CN2016/000090
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English (en)
Chinese (zh)
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罗民雄
黎明
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罗民雄
黎明
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Application filed by 罗民雄, 黎明 filed Critical 罗民雄
Publication of WO2016134612A1 publication Critical patent/WO2016134612A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
    • F24H1/18—Water-storage heaters
    • F24H1/20—Water-storage heaters with immersed heating elements, e.g. electric elements or furnace tubes

Definitions

  • the invention relates to a water storage type electric water heater capable of outputting electrolyzed water, belonging to the technical field of membrane-free electrolyzed water.
  • the storage type electric water heater is widely used in bathing and using hot water, and the electrolyzed water with negative potential rich in hydrogen has the functions of anti-oxidation, sterilization and decontamination, and beauty cleansing, and is used as a bathing and washing water application.
  • the popular electrolysis machine uses low-efficiency membrane electrolyzed water technology, it can only electrolyze normal temperature water, and when the water temperature exceeds 50-60 degrees Celsius, the electrolyzed water index will disappear, and it is necessary to simultaneously output acid-alkaline Two kinds of water, small amount of water, large power consumption and other serious defects, obviously do not meet the needs of electrolyzed water heaters;
  • the membrane-free electrolyzed water technology shows the advantages of membrane electrolysis water technology, for example: The unique advantage of electrolyzing any temperature raw water and outputting only one type of electrolyzed water, but the defect is that the electrolysis efficiency is still low. In the past, it was limited to the application of drinking pots and other electrolyzed natural static water devices to provide drinking water.
  • the invention provides a water storage type electric water heater capable of outputting electrolyzed water, which is created and designed for people to conveniently use electrolyzed water to bathe. Since the water storage capacity of the electric water heater is large, for the convenience and practical use, the membrane-free electrolyzed water technology with higher electrolysis efficiency should be adopted to meet certain electrolysis water index requirements. If the new principle and new method of electrolyzed water discovered and invented by the applicant are adopted, high electrolysis water efficiency and electrolyzed water index can be obtained, which is of great significance for improving the practicability of the electrolyzed water bath device.
  • the water electrolysis efficiency or electrolysis water efficiency can be generally defined as: a representative index of electrolyzed water produced by electrolysis of a certain amount of water and electrolysis for a certain period of time (for example, ORP negative value or hydrogen content of electrolytically reduced water). The ratio of the quantity) to the amount of electricity consumed. In other words, in an electrolysis method or an electrolysis device, the smaller the electric energy consumed by the same amount of electrolysis to reach the same electrolyzed water index, the higher the electrolysis water efficiency of the device.
  • the new principle of electrolyzed water discovered by the applicant and the method for significantly improving the efficiency of electrolyzed water are rooted in the deep research on the main defects of the electrolysis water principle of the traditional electrolysis machine.
  • the traditional electrolysis water principle is limited to the so-called ion chemical reaction equilibrium equation generated by water molecule electrolysis, completely ignoring the electrons and impurity particles generated by electrolysis of water impurities during electrolysis, and its importance for improving electrolysis water index and electrolysis efficiency.
  • impurities are electrolyzed to produce free electrons and impurity particles which are beneficial to improve the index of electrolyzed water.
  • impurity electrolysis effect forms a certain electrolysis current, which causes the water molecules to disintegrate into hydrogen, oxygen ions or hydroxide ions.
  • the electrolysis process should strengthen the "impurity electrolysis effect" as much as possible to produce more active electrons; the newly discovered three: small gaps of different polarity electrodes (especially small gaps less than 1 mm) for strengthening "impurity electrolysis” "effect” has a significant effect, although the previous non-isolated membrane electrolyzed water technology also mentioned the design considerations of different polarity electrode spacing less than 3mm, but did not understand the practical significance of small spacing, and the matching process measures are even more difficult to talk about.
  • Electrolytic effect improve water electrolysis efficiency and electrolyzed water reduction index; in-depth study of the flowability in the electrolysis water process, explains why the electrolysis water efficiency does not rise and fall after the electrolysis current increases to a certain value.
  • the important reason is that if the flow of water in the electrode gap is not good, the ion concentration in the electrode gap will be too high, which will affect the electrolysis efficiency.
  • the channel for installing the electrolysis electrode assembly adopts a design in which the outlet passage (outlet) is appropriately narrower than the inlet passage (inlet), and the flow rate of water passing through the electrolysis electrode assembly can be reduced. Thereby increasing the time and opportunity for impurities and water molecules to be electrolyzed, and increasing the index of electrolyzed water.
  • electrolyzed water process firstly, the process of generating active electrons by electrolysis of impurities in water, forming electric current, and converting electric energy into decomposition energy of water molecules. Therefore, more water molecules are decomposed by obtaining larger electric energy, which is the basis for obtaining higher electrolysis efficiency, but obtaining higher electrolysis efficiency requires additional important conditions. This is because the electrolysis process is also: the various ions (especially active electrons) released by the electrolysis of the impurities and the various hydroxide ions and ion roots generated by the decomposition of water molecules. In the process of chemical action, there are two important conditions for improving the electrolysis efficiency of water.
  • the electrolyzed water index may be higher, and the electrolysis efficiency is higher.
  • the electrolysis efficiency is also higher. For example, the higher ORP negative value and the hydrogen content of electrolytically reduced water (the applicant briefly refers to the two indicators as the "negative hydrogen" index), which requires more active electrons to participate. Therefore, impurities in the water are electrolyzed to release more electrons. And the combination of electrons and hydrogen ions with a higher probability of negative hydrogen can increase the negative hydrogen index and the electrolysis efficiency.
  • Applicant's new principle of electrolyzed water reveals that it is necessary to adopt a three-pronged process to improve the efficiency of electrolytic reduction water. It is necessary to strengthen the electrolysis of impurities in water, increase the electrons released by the electrolysis of impurities, and increase the electrons released by electrolysis. The probability of combining hydrogen with negative hydrogen.
  • the invention relates to a water storage type electric water heater capable of outputting electrolyzed water.
  • the invention relates to a water storage type electric water heater capable of outputting electrolyzed water, comprising a water storage container, an electric hot water electric control system, a controllable electrolysis power source and a membraneless electrolysis electrode assembly, wherein the water storage container has a water inlet and a water outlet.
  • the raw water enters the water storage container from the water inlet of the water storage container; the electric water electric control system controls the heating of the water in the water storage container; the controllable electrolysis power supply supplies current to the membraneless electrolysis electrode assembly; the membraneless electrolysis electrode assembly is in the water storage container
  • the water is electrolyzed; the electrolyzed water is discharged from the water outlet of the water storage container; the membrane-free electrolysis electrode assembly adopts a high-efficiency membrane-free electrolyzed water technology, and can effectively electrolyze the water stored in the required temperature range in the water storage container.
  • the gap between the electrodes of different polarity electrodes is designed according to the principle of reasonable miniaturization, and the gap distance is less than 5 mm and greater than 0 mm, so as to enhance the impurities in the water.
  • Electrolytic electrode assembly and its installation process conditions are characterized in that water can flow smoothly in the gap of different polarity electrodes during electrolysis of water, so that the electrolyzed water in the gap of different polarity electrodes can be replaced and More impurities and water molecules are repeatedly electrolyzed by different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the electrolysis efficiency of water.
  • the third aspect of the present invention the membraneless electrolytic electrode assembly, if necessary, the spacing between the electrodes of different polarity of the electrolytic electrode assembly can be as small as 1 mm or less, which is advantageous for a certain electrolysis power and a certain electrolysis electrode assembly structure. Strengthen the electrolysis of impurities and water molecules in water to improve the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly can make daily drinking water and water into electrolytic reduction water having a negative oxidation-reduction potential and a hydrogen content greater than zero.
  • the fifth aspect of the invention the membraneless electrolytic electrode assembly, the electrode structure of different polarities is designed to be: when the electrodes are When the water in the gap is electrolyzed to generate fluidity, the water and ions in the electrode gap can flow along the potential, so that more water flows through the gaps of the electrodes of different polarities, and the water that is electrolyzed in the gap is replaced, so that more impurities and water molecules in the water can be
  • the current between the electrodes of different polarities is repeatedly electrolyzed several times, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, and improving the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly has a certain space outside the two-port position of the electrode gap, so that water can flow smoothly in the gap of different polarity electrodes when the water flows during the electrolysis process. Improve the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly can prolong the time during which the flowing water is electrolyzed in the electrode gap by making a reasonable increase in the area of the electrode gap in a certain space occupied by the electrolytic electrode assembly, so that more impurities and water are present.
  • the molecules are repeatedly electrolyzed by different polarity electrodes to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the efficiency of water electrolysis.
  • the electrode in the case of the membrane-free electrolytic electrode assembly, when the material and shape of the electrolytic cell wall of the electrolytic electrode assembly are suitable as electrodes, the electrode can be appropriately connected as an electrolytic electrode to increase the gap area of the electrolytic electrode and increase the water. Electrolysis efficiency.
  • the membraneless electrolytic electrode assembly is composed of two electrodes of different polarities, one of the electrodes is in the shape of a cylindrical hole, the number of cylindrical electrodes is N, N is equal to or greater than 1, and the wall of the tube is absent.
  • the positions of the electrodes of the respective barrel holes are mechanically fixed and electrically connected to each other;
  • the second electrode is columnar, and the positions of the respective columns are mechanically fixed and electrically connected to each other, and the number of columns of the columnar electrodes is M, M is equal to or greater than 1
  • the column is hollow or solid, and may be unnotched or notched;
  • the height of the cylindrical electrode and the columnar electrode is not limited, and is selected according to the requirement;
  • the cylindrical electrode is inserted correspondingly to the columnar electrode, that is, the columnar electrode is inserted into each corresponding cylindrical hole In the middle, the gap between the surface of the inserted column electrode and the opposite surface of the barrel electrode is left to electrolyze the water; during the electrolysis work, the water in the electrode gap can flow; the outside of the two port positions of the electrode gap is fixed Space so that water can flow in the electrode gap during the process of being electrolyzed.
  • the invention relates to a water storage type electric water heater capable of outputting electrolyzed water, comprising a water storage container, an electric hot water electric control system, a controllable electrolysis power source, and a membraneless electrolysis electrode assembly, wherein the water storage container has a feed.
  • the water in the water storage container is electrolyzed; the electrolyzed water is output from the water outlet of the water storage container; the membrane-free electrolysis electrode assembly adopts a high-efficiency membrane-free electrolyzed water technology, and can effectively electrolyze the water stored in the required temperature range in the water storage container.
  • the membrane-free electrolytic electrode assembly the spacing of the gaps between the electrodes of different polarities is designed according to the principle of reasonable miniaturization, and the gap distance is less than 5 mm and greater than 0 mm, so as to enhance the impurities in the water.
  • Electrolysis with water molecules in a certain space occupied by the electrode assembly, the area of the gap between the electrodes of different polarities is designed according to the principle of reasonable enlargement, so that more impurities and water molecules in the water can be repeated many times in the electrode gap.
  • Electrolytic electrode assembly and its installation process conditions are characterized in that water can flow smoothly in the gap of different polarity electrodes during electrolysis of water, so that the electrolyzed water in the gap of different polarity electrodes can be replaced and More impurities and water molecules are repeatedly electrolyzed by different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the electrolysis efficiency of water.
  • the membrane-free electrolytic electrode assembly if necessary, the spacing between the electrodes of different polarity of the electro-electrode assembly can be as small as 1 mm or less, which is advantageous for a certain electrolysis power and a certain electro-electrode assembly structure. Strengthen the electrolysis of impurities and water molecules in water to improve the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly can make daily drinking water and water into electrolytic reduction water with a negative oxidation-reduction potential and a hydrogen content greater than zero.
  • the membrane-free electrolytic electrode assembly the electrode structure of different polarities is designed such that when water in the electrode gap is electrolyzed to generate fluidity, water and ions in the electrode gap can flow with each other so that more water flows.
  • the electrode gaps of different polarities replace the electrolyzed water in the gap, so that more impurities and water molecules in the water can be repeatedly electrolyzed by the currents of different polarity electrodes, increasing the probability of impurities and water molecules being electrolyzed by different polarity electrodes.
  • the quantity increases the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly has a certain space outside the two-port position of the electrode gap, so that when the water flows during the electrolysis, the water can flow smoothly in the gap of the different polarity electrodes. Improve the efficiency of water electrolysis.
  • the membrane-free electrolytic electrode assembly can prolong the time of electrolysis of the flowing water in the electrode gap by increasing the area of the electrode gap within a certain space occupied by the electrolysis electrode assembly, so that more impurities and water are provided.
  • the molecules are repeatedly electrolyzed by different polarity electrodes to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the efficiency of water electrolysis.
  • the electrode in the case of the membrane-free electrolytic electrode assembly, when the material and shape of the electrolytic cell wall of the electrolytic electrode assembly are suitable as an electrode, the electrode can be appropriately connected as an electrolytic electrode to increase the gap area of the electrolytic electrode and increase the water. Electrolysis efficiency.
  • the membrane-free electrolytic electrode assembly is composed of two electrodes of different polarities, one of the electrodes is a cylindrical hole shape, the number of cylindrical electrodes is N, N is equal to or greater than 1, and the wall of the tube can be Notched or notched, the positions of the electrodes of the respective barrel holes are mechanically fixed and electrically connected to each other; the second electrode is columnar, and the positions of the respective columns are mechanically fixed and electrically connected to each other, and the number of columns of the columnar electrodes is M, M is equal to or greater than 1
  • the column is hollow or solid, and may be unnotched or notched; the height of the cylindrical electrode and the columnar electrode is not limited, and is selected according to the requirement; the cylindrical electrode is inserted correspondingly to the columnar electrode, that is, the columnar electrode is inserted into each corresponding cylindrical hole In the middle, the gap between the surface of the inserted column electrode and the opposite surface of the barrel electrode is left to electrolyze the water; during the electrolysis work, the water in the electrode gap
  • Embodiment 1 is a storage type electric water heater capable of outputting electrolyzed water according to Embodiment 1 of the present invention
  • a water storage type electric water heater capable of outputting electrolyzed water comprises a water storage container 14 , an electric hot water electric control system 5 , a controllable electrolysis power source 9 , and a membrane-free electrolysis electrode assembly 10 immersed in water.
  • the water storage container 14 has a water inlet 18 and a water outlet 13; Water enters the water storage container 14 from the water inlet 18 of the water storage container 14; the dotted line 15 in the figure is the water level line of the water in the water storage container 14; the electric hot water electronic control system 5 controls the heating of the water in the water storage container 14; the controllable electrolysis power supply 9 supplying current to the membraneless electrolysis electrode assembly 10; the electrolysis electrode assembly 10 electrolyzing the water in the water storage container; the electrolyzed water is output from the water outlet of the water storage container; the electrolysis electrode assembly adopts a higher efficiency membraneless electrolysis water technology for storage
  • the water storage in the desired temperature range of the water container can be effectively electrolyzed; the electrolysis electrode assembly 8 is characterized in that two electrodes of different polarities are respectively a cylindrical electrode 1 (hereinafter referred to as a hole electrode) and can be correspondingly inserted.
  • the toothed electrode 2, the tooth of the toothed electrode 2 is inserted into the corresponding hole of the hole electrode, and an electrolytic gap 3 is left between the tooth surface and the surface of the hole, and three gaps 3 are schematically illustrated in FIG. If necessary, it is selected in the range of more than 0 to 5 mm: in the case of satisfying the certain flowability of water in the gap 3 during the electrolysis work, the spacing of the gap 3 may take a small value (for example, equal to or even less than 2 mm) to strengthen the water and therein.
  • 11 and 12 are respectively the bottom and upper space of the electrolysis electrode assembly 8, which are designed to make the water flow smoothly in the electrode gap, and in the process of electrolyzing water, the gap After the water molecules are electrolytically decomposed, hydrogen and oxygen bubbles will flow upward along the gap, thereby causing the water in the gap 3 to flow upward and out of the upper port of the gap 3, causing water to continuously flow from the opening of the gap 3, that is, the space 11 In the electrode gap, during the flow of water in the gap, water impurities and water molecules are repeatedly electrolyzed by the electrolysis current in the gap; obviously, the gap 3 is reasonably selected for a small spacing and a large area and satisfies the gap 3 with good circulation of water.
  • these three aspects of the coordination of the technical solutions are conducive to strengthen the electrolysis effect, improve the efficiency of the storage of water in the container 4 and the reference of electrolyzed water (E.g., the ORP of the electrolytic reduced water and negative hydrogen content). If the space of the gap 3 does not leave the space 11 or 11 too narrow, the water in the gap 3 cannot flow smoothly, and the electrolysis efficiency will be significantly reduced. Similarly, the space of the gap 3 does not leave the space 12 or 12 too narrow, and the electrolysis efficiency is also significantly reduced.
  • the treatment method is that the circulation space 12 of the water at the outlet outlet port can be appropriately narrower than the circulation space 11 of the inlet port water to appropriately slow the passage of water.
  • the flow rate of the gap thereby increasing the time during which the water in the gap is electrolyzed, and enhancing the electrolysis effect. Table 1 test data helps to understand the above description.
  • Table 1 The measured data of the first embodiment of the water storage type electric water heater capable of outputting electrolyzed water of the present invention
  • the electrode gap 3 area difference is half, or the electrode
  • the water flow difference in the gap and the electrolyzed water index are significantly different, which confirms the new principle and new method of electrolyzed water proposed by the applicant.
  • the relevant test data proves that the storage type electric water heater capable of outputting electrolyzed water is feasible and innovative. Sexuality, practicality.
  • the invention relates to a water storage type electric water heater capable of outputting electrolyzed water, wherein the electrolysis electrode assembly is not limited to the specific structure adopted in the first embodiment, and in the selection of the actual product technical scheme, the storage of the electrolyzed water which can reach the present invention is used.
  • Any type of membraneless electrolytic electrode structure required for the (electrical, low, high) electrolyzed water index of the water-type electric water heater product belongs to the protection scope of the present invention.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
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  • Environmental & Geological Engineering (AREA)
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  • General Engineering & Computer Science (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Cette invention concerne un chauffe-eau électrique du type à stockage de l'eau capable de produire de l'eau électrolysée, comprenant une cuve de stockage d'eau (14), un système de commande électronique de chauffe-eau électrique (5), un dispositif commandable d'alimentation en énergie d'électrolyse (9), et un ensemble d'électrodes électrolytiques sans membrane (10). Ledit chauffe-eau électrique de type à stockage d'eau est caractérisé en ce que : la récipient de stockage de l'eau (14) comprend un orifice d'admission d'eau (18) et un orifice de sortie d'eau (13) ; de l'eau non traitée pénètre dans la cuve de stockage d'eau (14) à partir de l'orifice d'admission d'eau (18) de la cuve de stockage d'eau (14) ; le système de commande électronique de chauffe-eau électrique (5) régule le chauffage de l'eau dans la cuve de stockage d'eau (14) ; le dispositif commandable d'alimentation en énergie d'électrolyse (9) fournit un courant à l'ensemble d'électrodes électrolytiques sans membrane (10) ; l'ensemble d'électrodes électrolytiques sans membrane (10) électrolyse l'eau dans la cuve de stockage d'eau (14) ; et de l'eau électrolysée est fournie en sortie à partir de l'orifice de sortie d'eau (13) de la cuve de stockage d'eau (14). Un ensemble d'électrodes électrolytiques sans membrane électrolyse efficacement par une technique d'électrolyse de l'eau sans membrane, l'eau qui est stockée dans la cube de stockage d'eau et qui atteint une plage de températures requise, et l'efficacité d'électrolyse de l'eau est améliorée.
PCT/CN2016/000090 2015-02-26 2016-02-24 Chauffe-eau électrique du type à stockage de l'eau capable de produire de l'eau électrolysée WO2016134612A1 (fr)

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CN201510087722.X 2015-02-26
CN201510087722.XA CN104633912A (zh) 2015-02-26 2015-02-26 一种可输出电解水的储水式电热水器

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CN111320238A (zh) * 2018-12-14 2020-06-23 罗民雄 用稳定电解电流获得预定电解水负氢含量指标的方法

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CN104649374A (zh) 2015-02-26 2015-05-27 罗民雄 一种多功能的无膜电解开水机
CN104609514A (zh) * 2015-02-26 2015-05-13 罗民雄 一种电极为孔柱式结构的新型电解水装置
CN104628092A (zh) * 2015-02-26 2015-05-20 罗民雄 一种可控制电解水酸碱性的无膜电解水新方法
CN104609515A (zh) * 2015-02-26 2015-05-13 罗民雄 一种便利使用的可便携多用途无膜电解水装置
CN104609513A (zh) * 2015-02-26 2015-05-13 罗民雄 一种显著提高电解效率的无膜电解水新方法
CN104633912A (zh) * 2015-02-26 2015-05-20 罗民雄 一种可输出电解水的储水式电热水器
CN104709976A (zh) * 2015-02-26 2015-06-17 罗民雄 一种制作美容水的无膜电解水装置
CN104962947A (zh) * 2015-07-13 2015-10-07 罗民雄 由n个套筒式电极组构成的电极组件
CN105152275A (zh) * 2015-08-30 2015-12-16 罗民雄 将无膜电解水组件串并联使用提高电解水指标的方法
CN105060417A (zh) * 2015-08-30 2015-11-18 罗民雄 制作宽指标或宽温度范围电解水的无膜电解水新工艺方法
CN106766139A (zh) * 2017-02-21 2017-05-31 扬州工业职业技术学院 双热源储水式电热水器

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