CN105152275A - Method for increasing water electrolysis indexes by using filmless water electrolysis subassemblies in series and parallel - Google Patents
Method for increasing water electrolysis indexes by using filmless water electrolysis subassemblies in series and parallel Download PDFInfo
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- CN105152275A CN105152275A CN201510546110.2A CN201510546110A CN105152275A CN 105152275 A CN105152275 A CN 105152275A CN 201510546110 A CN201510546110 A CN 201510546110A CN 105152275 A CN105152275 A CN 105152275A
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Abstract
A method for increasing water electrolysis indexes by using filmless water electrolysis subassemblies in series and parallel is characterized in that raw water is subjected to multistage electrolysis on the basis of a water electrolysis ion activity energy level principle, and the water electrolysis indexes and an electrolysis efficiency principle are increased; the number of the filmless water electrolysis subassemblies is N; each filmless water electrolysis subassembly is provided with a water feeding channel and a water draining channel; when the N is an integer greater than 1, the N filmless water electrolysis subassemblies are connected to one another in series or parallel; and when N is an integer greater than 3, the N filmless water electrolysis subassemblies are connected to one another in series or in parallel or in series and parallel.
Description
Technical field
The present invention will use raising brine electrolysis to refer to calibration method without the parallel connection of film brine electrolysis component string, belong to without film brine electrolysis technical field.
Background technology
At present, without film brine electrolysis technology be popular in compared with generation traditional barrier film brine electrolysis technology of more than 80 year, there is huge advantage, as not only can electrolysis stationary water but also can electrolysis flowing water, electrolytic efficiency high, only go out a kind of brine electrolysis, temperature of not restricting water supply, adapt to water TDS from be greater than zero to very high on a large scale, environmental protection of saving water and energy, therefore presented the developing state that world's brine electrolysis is shuffled greatly.But in electrolyte flow water, owing to adopting small electric solution power without film brine electrolysis technology, meet higher brine electrolysis index (as brine electrolysis ORP negative electricity place value, hydrogen content and certain water yield etc.) requirement, need innovative solution at electrolysis electrode process structure on the one hand; On the other hand, still need to be innovated in device relevant technological flowage structure, to make to reach and even beyond tradition electrolyzed water machine level without the comparable important indicator of film electrolytic water device, promote, without the universal development of film brine electrolysis technological innovation, to realize brine electrolysis technological revolution.The present inventor finds in studying for a long period of time: without in the larger situation of film electrolytic water device aquifer yield, without film brine electrolysis technology owing to adopting small electric solution power, meet higher brine electrolysis index (as negative potential ORP, hydrogen content etc.) requirement, more difficult.According to usual way, take the process effect increasing single electrolysis electrode assembly, reach comparatively big yield electrolysis index request, doing shortcoming is like this that electrolysis electrode assembly manufacture difficulty is significantly strengthened, and electrolytic efficiency is not good enough, and product cost reduces.Electrode assemblie serial or parallel connection uses with the method and the structure that improve brine electrolysis efficiency by the present invention, that contriver is studying on correlation technique basis for many years, sum up the important technology innovation scheme created, can overcome and adopt the deficiencies such as the relatively large running costs of single electrolysis electrode assembly electrolysis is high, manufacture requirements is higher, electrolytic efficiency is not good enough, the higher brine electrolysis index request of comparatively big yield can be met, there is again higher electrolytic efficiency, higher product cost can be obtained.
Summary of the invention
The present invention proposes raising brine electrolysis to be used to refer to calibration method without the parallel connection of film brine electrolysis component string, and BROAD SUMMARY is: be conducive to improving brine electrolysis index and electrolytic efficiency principle through multistage electrolysis based on brine electrolysis ionic activity energy level principle, former water; Comprise N number of without film brine electrolysis assembly, have water entry and water exit without film brine electrolysis assembly; When N gets the integer being greater than 1, N number of connected in series or in parallel without film brine electrolysis assembly; When N gets the integer being greater than 3, N number of without film brine electrolysis assembly serial or parallel connection or string also series-parallel connection connection.
Two of summary of the invention is: described several without film brine electrolysis assembly, any one, without film brine electrolysis assembly, all has yin, yang electrode, and the electrolysis gap of this yin, yang electrode is continuous print, non-interruption; When employing housing installs multiple electrode assemblie, distinguish with the discontinuous of yin, yang electrolysis gap or interruption without film brine electrolysis component count.
Three of summary of the invention is: described when N be greater than 1 integer, N number of connected in series or in parallel without film brine electrolysis assembly, brine electrolysis assembly is connected in series finger: flow through order with current, the water exit of previous brine electrolysis assembly is communicated with the water entry of a rear brine electrolysis assembly.
Four of summary of the invention is: described N number of or M without film brine electrolysis assembly, when N or M value is greater than 2, more than 2 or 2 can adopt water stream channel parallel without film brine electrolysis assembly; Brine electrolysis modules in parallel connects and refers to: the water entry of more than 2 or 2 brine electrolysis assemblies is all connected to same water entry, and this water entry is called water entry in parallel; The water exit of more than 2 or 2 brine electrolysis assemblies is all connected to identical water exit, and this water exit is called water exit in parallel; The connection of brine electrolysis modules in parallel makes water entry in parallel water inlet be divided into some tributaries, enters each brine electrolysis assembly be connected in parallel respectively and does electrolysis, then flows through water exit in parallel outflow by each water exit.
Five of summary of the invention is: describedly get the integer being greater than 1 as N, N number of connected in series or in parallel without film brine electrolysis assembly, and brine electrolysis component string series-parallel connection connection refer to: N number of brine electrolysis assembly connects by serial or parallel connection mode arbitrarily.
Six of summary of the invention is: described without film brine electrolysis assembly, any one, without film brine electrolysis assembly, all has yin, yang electrode, and the electrolysis gap of this yin, yang electrode is continuous print, non-interruption;
Technical solution of the present invention, first based on new discovery and " the brine electrolysis ionic activity energy level principle " that propose accordingly of the present inventor: at water by electrolytic process, water molecules is not as usually supposed in people: or by electrolysis to falling apart, become the hydrogen of drifting apart, oxonium ion or ion root, still water molecules as usual is stablized, in fact, in brine electrolysis process, absorb electric energy thus each element of water molecules of the active energy of increase, ion or ion root, be in different active-energy intensity level next states: the hydroxide ion (or ion root) of some water moleculess, obtain the activity energy being enough to overcome molecular binding affinities, drift apart, the active energy level of this type of water molecules institute tool may be defined as " the senior secondary active energy of water molecules " or be called " water-molecule dissociation level time active energy ", brine electrolysis index divides primarily of this type of water molecules the ion and is formed, such as: ORP negative value (redox negative potential) and the hydrogen content of hydrogen water are born in electrolysis, mainly produced by negative hydrogen ion H and electron institute, H
-can with the relatively stable existence of plasma state (Japanese expert and river offspring clear " revolution of hydrogen " have this respect to prove), this point is proportional long-time and true the confirming (water that ORP negative value and hydrogen richness exist certain proportional relationship is called by the present inventor accordingly " bearing hydrogen water ") of depositing of ORP negative value and hydrogen richness in the negative hydrogen water that contriver finds, secondly, in brine electrolysis, some water molecules hydroxide ions (or ion root) obtain greater activity energy, but not yet reach the energy intensity can shaking off water molecules power voluntarily, thus water molecules intermediate ion is in partly accepting and partly rejecting but difficulty and cuts difficult point state, the active energy level of this type of water molecules institute tool may be defined as " water molecules critical level time active energy ", the water molecules that this kind is in critical decomposition is less stable, be subject to external energy effect, more easily fall apart for various ion, produce electrolysis water index, again, in brine electrolysis, for the active energy level of several more water molecules is lower than critical decomposition energy level, may be defined as water molecules " rudimentary active energy ", this type of water molecules has the different unstable of degree than the water molecules without electrolysis treatment or says certain activity, is comparatively subject to External Force Acting and decomposes.
What is more important, on above-mentioned basis, the present inventor finds further and proposes " water is conducive to obtaining higher brine electrolysis Indicators ' Principle through multistage electrolysis ": generally think and will obtain higher brine electrolysis index, electrolysis power must be strengthened, really, larger electrolysis power is provided to certain brine electrolysis assembly, brine electrolysis index can be made to increase, but further investigation finds: along with power rises, brine electrolysis index rises and presents the tendency that eases up, so that large, to certain power, brine electrolysis index almost no longer rises, and efficiency can significantly reduce; Reason is: have the narrower feature of electrode gap without film electrolytic water electric, owing to flowing into a variety of causes such as water quality, structural difference in each gap, easy generation current are the problem such as skewness in electrolysis electrode gap, when electrolysis power is larger, hydrogen-oxygen bubble increases, make current problem such as skewness in electrolysis electrode gap even more serious, therefore be difficult to obtain higher brine electrolysis index; According to the technical scheme strengthening electrolysis enlarged areas water stream channel, structural difference impact is comparatively large, and easily occur electric current problem such as skewness in electrolysis gap, brine electrolysis efficiency can decline, and is difficult to equally obtain higher brine electrolysis index.
Based on above-mentioned discovery and principle, adopt the present invention raising brine electrolysis will be used to refer to calibration method without the parallel connection of film brine electrolysis component string, above-mentioned technical barrier can be solved preferably: first, the brine electrolysis power of each brine electrolysis assembly can be determined by better efficiency, if not yet reach requirement through the brine electrolysis index of one-level brine electrolysis assembly electrolysis, one-level of connecting again brine electrolysis assembly intensified electrolysis, consolidate existing brine electrolysis effect on the one hand, make something perfect even more perfect simultaneously, impel the water molecules being in " critical level time active energy " state to be separated by electrolysis, improve brine electrolysis index; Being in " rudimentary active energy " water molecules is also may, by the object of electrolysis, be comparatively improve brine electrolysis index to do certain contribution.The actual test of contriver shows: through the brine electrolysis index of the one-level brine electrolysis assembly electrolysis of experiment, 500 ~ 600ppb can be reached, secondary electrolysis, 800 ~ 900ppb can be reached, three grades of electrolysis, can reach 1100 ~ 1500ppb, and adopt one-level electrolysis, even if electrolysis power is identical with three grades or more greatly, be also difficult to the index reaching three grades of electrolysis.If desired comparatively big yield brine electrolysis, brine electrolysis modules in parallel can be adopted to solve, and such as: two brine electrolysis modules in parallel, just can obtain the brine electrolysis of the twice water yield, index is close with one-level brine electrolysis assembly brine electrolysis index.
Basic technical scheme: be conducive to improving brine electrolysis index and electrolytic efficiency principle through multistage electrolysis based on brine electrolysis ionic activity energy level principle, former water; Comprise N number of without film brine electrolysis assembly, have water entry and water exit without film brine electrolysis assembly; When N gets the integer being greater than 1, N number of connected in series or in parallel without film brine electrolysis assembly; When N gets the integer being greater than 3, N number of without film brine electrolysis assembly serial or parallel connection or string also series-parallel connection connection.
One of concrete technical scheme is: described several without film brine electrolysis assembly, any one, without film brine electrolysis assembly, all has yin, yang electrode, and the electrolysis gap of this yin, yang electrode is continuous print, non-interruption;
Two of concrete technical scheme is: described when N be greater than 1 integer, N number of connected in series or in parallel without film brine electrolysis assembly, brine electrolysis assembly is connected in series finger: flow through order with current, the water exit of brine electrolysis assembly is above communicated with the water entry of brine electrolysis assembly below.
Three of concrete technical scheme is: described N number of or M without film brine electrolysis assembly, when N or M value is greater than 2, more than 2 or 2 can adopt water stream channel parallel without film brine electrolysis assembly; Brine electrolysis modules in parallel connects and refers to: the water entry of more than 2 or 2 brine electrolysis assemblies is all connected to a water entry, and this water entry is called water entry in parallel; The water exit of more than 2 or 2 brine electrolysis assemblies is all connected to identical water exit, and this water exit is called water exit in parallel; The connection of brine electrolysis modules in parallel makes water entry in parallel water inlet be divided into some tributaries, enters each brine electrolysis assembly be connected in parallel respectively and does electrolysis, then flows through water exit in parallel outflow by each water exit.
Four of concrete technical scheme is: describedly get the integer being greater than 1 as N, N number of connected in series or in parallel without film brine electrolysis assembly, and brine electrolysis component string series-parallel connection connection refer to: N number of brine electrolysis assembly connects by serial or parallel connection mode arbitrarily.
Five of concrete technical scheme is: described without film brine electrolysis assembly, any one, without film brine electrolysis assembly, all has yin, yang electrode, and the electrolysis gap of this yin, yang electrode is continuous print, non-interruption;
Accompanying drawing explanation
Below by accompanying drawing, the present invention is further explained.
Fig. 1 is that the embodiment of the present invention 1 will use raising brine electrolysis to refer to calibration method without the parallel connection of film brine electrolysis component string.
Embodiment
Below in conjunction with embodiment 1 and Fig. 1 illustrated embodiments basic structure and basic functional principle.
Embodiment 1
As Fig. 1 will use raising brine electrolysis to refer to calibration method without the parallel connection of film brine electrolysis component string, be conducive to improving brine electrolysis index and electrolytic efficiency principle through multistage electrolysis based on brine electrolysis ionic activity energy level principle, former water; Process structure shown in Fig. 1: comprise brine electrolysis assembly 2, the brine electrolysis assembly 6,7 be connected in parallel, water stream channel 1,3,4,5,8,9, wherein, 3 is brine electrolysis assembly 6,7 water entry in parallel, and 10 is 6,7 water exits in parallel; Fig. 1 process structure and working process thereof and principle are described below: former water flows into 2 from 1, to 3 after 2 electrolysis, is divided into two-way tributary, enters 6,7 respectively, give electrolysis respectively through 4,5, then exports from 8,9 through water exit 10 in parallel respectively.In the present embodiment, the parallel electrolytic wet part 11 (in dotted line frame part) that brine electrolysis assembly 5 and brine electrolysis assembly 9,10 are formed is connected in series, brine electrolysis component string parallel connection (or series-parallel connection) processing method can be called, in like manner, brine electrolysis component string parallel connection (or series-parallel connection) mode can be selected arbitrarily, to meet the aspect needs such as brine electrolysis index and the water yield.
The present invention will use raising brine electrolysis to refer to calibration method without the parallel connection of film brine electrolysis component string, the electrolysis electrode assembly adopted, be not limited to the electrolysis electrode assembly that embodiment 1 is taked, in principle, the electrolysis electrode structure that any one meets this patent feature all can use; The mode of connection of electrolysis electrode assembly does not limit to embodiment form, and every connection meeting the technology of the present invention feature all belongs to scope.
Claims (6)
1. raising brine electrolysis will be used to refer to calibration method without the parallel connection of film brine electrolysis component string, be characterized as: be conducive to improving brine electrolysis index and electrolytic efficiency principle through multistage electrolysis based on brine electrolysis ionic activity energy level principle, former water; Comprise N number of without film brine electrolysis assembly, have water entry and water exit without film brine electrolysis assembly; When N gets the integer being greater than 1, N number of connected in series or in parallel without film brine electrolysis assembly; When N gets the integer being greater than 3, N number of without film brine electrolysis assembly serial or parallel connection or string also series-parallel connection connection.
2. raising brine electrolysis will be used to refer to calibration method without the parallel connection of film brine electrolysis component string according to claim 1, it is characterized in that: described several without film brine electrolysis assembly, any one, without film brine electrolysis assembly, all has yin, yang electrode, and the electrolysis gap of this yin, yang electrode is continuous print, non-interruption; When employing housing installs multiple electrode assemblie, distinguish with the discontinuous of yin, yang electrolysis gap or interruption without film brine electrolysis component count.
3. raising brine electrolysis will be used to refer to calibration method without the parallel connection of film brine electrolysis component string according to claim 1, it is characterized in that: described when N be greater than 1 integer, N number of connected in series or in parallel without film brine electrolysis assembly, brine electrolysis assembly is connected in series finger: flow through order with current, the water exit of previous brine electrolysis assembly is communicated with the water entry of a rear brine electrolysis assembly.
4. raising brine electrolysis will be used to refer to calibration method without the parallel connection of film brine electrolysis component string according to claim 1, it is characterized in that: described N number of or M without film brine electrolysis assembly, when N or M value is greater than 2, more than 2 or 2 can adopt water stream channel parallel without film brine electrolysis assembly; Brine electrolysis modules in parallel connects and refers to: the water entry of more than 2 or 2 brine electrolysis assemblies is all connected to same water entry, and this water entry is called water entry in parallel; The water exit of more than 2 or 2 brine electrolysis assemblies is all connected to identical water exit, and this water exit is called water exit in parallel; The connection of brine electrolysis modules in parallel makes water entry in parallel water inlet be divided into some tributaries, enters each brine electrolysis assembly be connected in parallel respectively and does electrolysis, then flows through water exit in parallel outflow by each water exit.
5. raising brine electrolysis will be used to refer to calibration method without the parallel connection of film brine electrolysis component string according to claim 1, it is characterized in that: the described N that works as gets the integer being greater than 1, N number of connected in series or in parallel without film brine electrolysis assembly, brine electrolysis component string series-parallel connection connect and refer to: N number of brine electrolysis assembly connects by serial or parallel connection mode arbitrarily.
6. raising brine electrolysis will be used to refer to calibration method without the parallel connection of film brine electrolysis component string according to claim 1, it is characterized in that: described without film brine electrolysis assembly, any one, without film brine electrolysis assembly, all has yin, yang electrode, and the electrolysis gap of this yin, yang electrode is continuous print, non-interruption.
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CN104633912A (en) * | 2015-02-26 | 2015-05-20 | 罗民雄 | Water storage type electric water heater capable of draining electrolyzed water |
CN104649374A (en) * | 2015-02-26 | 2015-05-27 | 罗民雄 | Multifunctional film-free electrolytic boiled water machine |
CN104709976A (en) * | 2015-02-26 | 2015-06-17 | 罗民雄 | Membraneless water electrolysis device for preparing beauty lotion |
CN104709974A (en) * | 2015-02-26 | 2015-06-17 | 罗民雄 | Novel method for controlling electrolyzed water performance by adopting two sets of electrolysis electrode assemblies |
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CN104633912A (en) * | 2015-02-26 | 2015-05-20 | 罗民雄 | Water storage type electric water heater capable of draining electrolyzed water |
CN104649374A (en) * | 2015-02-26 | 2015-05-27 | 罗民雄 | Multifunctional film-free electrolytic boiled water machine |
CN104709976A (en) * | 2015-02-26 | 2015-06-17 | 罗民雄 | Membraneless water electrolysis device for preparing beauty lotion |
CN104709974A (en) * | 2015-02-26 | 2015-06-17 | 罗民雄 | Novel method for controlling electrolyzed water performance by adopting two sets of electrolysis electrode assemblies |
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Application publication date: 20151216 |