CN107083557B - A kind of equipment using graphene high-efficiency oxygen and hydrogen-rich ionized water - Google Patents
A kind of equipment using graphene high-efficiency oxygen and hydrogen-rich ionized water Download PDFInfo
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- CN107083557B CN107083557B CN201710094214.3A CN201710094214A CN107083557B CN 107083557 B CN107083557 B CN 107083557B CN 201710094214 A CN201710094214 A CN 201710094214A CN 107083557 B CN107083557 B CN 107083557B
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- hydrogen
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Abstract
The present invention discloses a kind of equipment using graphene high-efficiency oxygen and hydrogen-rich ionized water, it is composed in series including at least one oxyhydrogen generator unit, each oxyhydrogen generator unit includes being fixed at the intracorporal positive plate of case and negative plate, the proton exchange membrane between the positive plate and negative plate, so that cabinet is divided into water storage cavity, hydrogen generation chamber and oxygen generation chamber；Positive plate, negative plate are correspondingly connected with the positive and negative anodes of power supply, and catalyst layer is provided on positive plate, negative plate, and catalyst layer is the carbon fiber layer of surface spraying graphite alkene；Water storage cavity is equipped with inlet and outlet；Electrochemical reaction occurs under the catalyst layer effect of positive plate via the water that water inlet enters water storage cavity, the oxygen of generation enters the oxygen generation chamber；The hydrogen ion of generation passes through proton exchange membrane under the action of electric field, and hydrogen atom is generated in conjunction with free electronics, and forms hydrogen under the catalyst layer effect on negative plate and enter hydrogen generation chamber；The hydrogen-rich water formed after reacted is discharged from water outlet.
Description
Technical field
The present invention relates to water electrolysis hydrogen production oxygen technical field more particularly to it is a kind of using graphene high-efficiency oxygen and hydrogen-rich from
The equipment of sub- water.
Background technique
Oxygen is indispensable elemental gas in life, needs oxygen in life process to participate in various metabolism
Activity, the concentration for properly increasing oxygen in environment are of great benefit to body.Usually we the concentration of oxygen in environment by
21% is increased between 23%~25%, but not above 25%, and partial pressure of oxygen in this case can be improved, and increases histocyte benefit
With the ability of oxygen, human metabolism is improved.
Volume is relatively large mostly for traditional oxygenerator, and use is more troublesome, and service life is also by electronic component
It influences.
Summary of the invention
The purpose of the embodiment of the present invention is that providing a kind of equipment using graphene high-efficiency oxygen and hydrogen-rich ionized water, structure
Simply, water electrolysis hydrogen production oxygen efficiency can be effectively improved.
To achieve the above object, the embodiment of the invention provides setting using graphene high-efficiency oxygen and hydrogen-rich ionized water
It is standby, including at least one oxyhydrogen generator unit is composed in series, each oxyhydrogen generator unit includes being fixed at case
Intracorporal positive plate and negative plate, the proton exchange membrane between the positive plate and negative plate, so that cabinet is divided into
Water storage cavity, hydrogen generation chamber and oxygen generation chamber；The positive plate, negative plate are correspondingly connected with the positive and negative anodes of power supply, the anode
Catalyst layer is provided on plate, negative plate, the catalyst layer is the carbon fiber layer of surface spraying graphite alkene；The water storage cavity
Equipped with inlet and outlet；
Electrification occurs under the catalyst layer effect of the positive plate via the water that the water inlet enters the water storage cavity
Reaction is learned, oxygen, hydrogen ion and free electronics are divided by electrolysis, the oxygen of generation enters the oxygen generation chamber；It generates
Hydrogen ion passes through the proton exchange membrane under the action of electric field, hydrogen atom is generated in conjunction with free electronics, and in institute
It states and forms hydrogen into the hydrogen generation chamber under the catalyst layer effect on negative plate；The hydrogen-rich water formed after reacted is from institute
State water outlet discharge.
As an improvement of the above scheme, the catalyst layer is made of the graphene carbon fiber filament that every diameter is 100nm.
As an improvement of the above scheme, in the case where each oxyhydrogen generator cell capability is 200~300ml,
Each catalyst layer is arranged to make up by 3~50,000 graphene carbon fiber filaments.
As an improvement of the above scheme, the width of the hydrogen generation chamber is equipped with hydrogen outlet on top less than 2 millimeters.
As an improvement of the above scheme, the top of the oxygen generation chamber is equipped with oxygen delivery outlet.
As an improvement of the above scheme, the first connecting terminal is set on the positive plate to connect with extraneous positive pole
It connects；Second connecting terminal is set on the negative plate to connect with extraneous power cathode.
As an improvement of the above scheme, the water inlet of the top setting of the water storage cavity is connected with inlet pipeline, bottom
The water outlet of end setting is connected with outlet pipeline.
As an improvement of the above scheme, the power supply uses the DC power supply of pulsed, is swashed using frequency modulating
The hydrone for the pole plate that generates electricity makes hydrone form resonance electrolysis in electrolytic process.
Compared with prior art, disclosed by the invention passed through using the equipment of graphene high-efficiency oxygen and hydrogen-rich ionized water is adopted
Use the carbon fiber layer of surface spraying graphite alkene that can effectively improve electro-catalysis as the efficient catalytic electrode material of water electrolysis hydrogen production oxygen
The electric conductivity of agent accelerates charge transfer rate in electrochemical process, substantially reduces the catalyst in water electrolysis hydrogen production reaction
Overpotential, can significant catalytic electrolysis water oxygen evolution reaction and evolving hydrogen reaction, be conducive to the diffusion of the oxyhydrogen generated and electrolyte, drop
Resistance to mass tranfer during low electro-catalysis greatly improves electro-catalysis hydrogen manufacturing oxygen activity and stability, to improve electrolysis water
Hydrogen manufacturing oxygen efficiency.And the device structure provided by the invention using graphene high-efficiency oxygen and hydrogen-rich ionized water is simple, and it can
Minimum energy consumption generates useful hydrogen-rich water for using while manufacturing hydrogen, oxygen.
Detailed description of the invention
Fig. 1 is a kind of structural representation of the equipment using graphene high-efficiency oxygen and hydrogen-rich ionized water in the embodiment of the present invention
Figure.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Equipment using graphene high-efficiency oxygen and hydrogen-rich ionized water of the invention includes at least one oxyhydrogen generator list
Member is composed in series.Wherein, as shown in Figure 1, each oxyhydrogen generator unit includes being fixed at the intracorporal positive plate of case
And negative plate, the proton exchange membrane between the positive plate and negative plate, so that it is raw that cabinet is divided into water storage cavity, hydrogen
Coelosis and oxygen generation chamber；The positive plate, negative plate are correspondingly connected with the positive and negative anodes of power supply, on the positive plate, negative plate
It is provided with catalyst layer, the catalyst layer is the carbon fiber layer of surface spraying graphite alkene；The water storage cavity be equipped with water inlet and
Water outlet.
Electrification occurs under the catalyst layer effect of the positive plate via the water that the water inlet enters the water storage cavity
Reaction is learned, oxygen, hydrogen ion and free electronics are divided by electrolysis, the oxygen of generation enters the oxygen generation chamber；It generates
Hydrogen ion passes through the proton exchange membrane under the action of electric field, hydrogen atom is generated in conjunction with free electronics, and in institute
It states and forms hydrogen into the hydrogen generation chamber under the catalyst layer effect on negative plate；The hydrogen-rich water formed after reacted is from institute
State water outlet discharge.
In the present embodiment, the principle that the catalyst layer is adsorbed using high-pressure electrostatic is by graphene with a kind of shape of thin slice
Formula is attached to the filametntary surface pe, and this graphene carbon new fiber materials is made to obtain excellent electric conductivity and stretch-resistance.This
The diameter of kind material is about 100nm.This graphene carbon fiber has super low conductivity, can be used as water electrolysis hydrogen production oxygen
Catalytic electrode material, it is very effective to make electrolysis water conversion oxygen and hydrogen.
In the present embodiment, the catalyst layer is made of the graphene carbon fiber filament that every diameter is 100nm.Each
In the case that the oxyhydrogen generator cell capability is 200~300ml, each catalyst layer is by 3~50,000 graphite
Olefinic carbon fiber filament is arranged to make up.
Specifically, each oxyhydrogen generator unit in the form of a kind of unit existing for, a unit only has one bottle of mineral spring
Water size, multiple units can with tandem compound at big unit, thus adjust manufacture oxygen (hydrogen) in the unit time number.One
The printed words unit of a mineral water size can arrange the graphene carbon fiber of about 100,000 production oxygen, make the effect of oxygen
Rate is very high, can achieve 2.8L per minute or so, and enough normal persons breathe use to this capacity.If it is desired in environment
In largely manufacture oxygen, can be by multiple concatenated oxyhydrogen generators using the equipment of graphene high-efficiency oxygen and hydrogen-rich ionized water
Unit composition carries out, while the consumption of energy and not very big, and production 1L oxygen only needs 0.1 coke.
The present embodiment use spraying graphite alkene carbon fiber have excellent conductivity, surface texture very it is smooth and
It is smooth.Graphene molecules are adsorbed with powerful intermolecular force, and property is stablized.Graphene carbon fiber can be used for a long time, warp
Crossing plasma detergent can be carried out cleaning, and exempt the trouble for constantly updating filter core.
Each oxyhydrogen generator unit of the present embodiment can both manufacture oxygen, manufacture hydrogen, while also producing rich
This water with strong reducing property of hydrogen.That is the utilization graphene high-efficiency oxygen and hydrogen-rich ionized water of the embodiment of the present invention
Equipment can not only manufacture oxygen for using but also useful hydrogen-rich water can be produced.For example, hydrogen-rich water can reduce the intracorporal oxygen of people
Compound, remove free radical, can in the form of a kind of reproducibility water house residential application, can be also used for wipe body surface to go
Except skin surface and the free radical of deep skin, the health status of skin is safeguarded, to increase the resistance and immunity of skin.
Provided in this embodiment using in the equipment of graphene high-efficiency oxygen and hydrogen-rich ionized water, the hydrogen generation chamber
Width less than 2 millimeters, top be equipped with hydrogen outlet.The top of the oxygen generation chamber is equipped with oxygen delivery outlet.It is described just
First connecting terminal is set on pole plate to connect with extraneous positive pole；Be arranged on the negative plate the second connecting terminal with
Extraneous power cathode connection.The water inlet of the top setting of the water storage cavity is connected with inlet pipeline, bottom end setting
The water outlet is connected with outlet pipeline.
In addition, in order to improve water electrolysis efficiency, the power supply uses the DC power supply of pulsed, utilizes frequency tune
The hydrone for becoming exciting electrode plate makes hydrone form resonance electrolysis in electrolytic process, to reach high-effect water electrolysis efficiency.
As it can be seen that the device structure provided in an embodiment of the present invention using graphene high-efficiency oxygen and hydrogen-rich ionized water is simple,
Practicability is wide:
It can be used in house, on the one hand can enjoy the oxygen of manufacture with minimum energy consumption, while can provide enough
Hydrogen-rich water for drinking, wash one's face and rinse one's mouth.
This equipment electrolysis water oxygen by one or two oxyhydrogen generator unit can be used in the car, and alleviation is driven
The state of the long-distance middle anoxic gas of driveing a car of the person of sailing.
It can be applied by multiple oxyhydrogen generator units larger equipment formed of connecting at endowment center, Man Bing recovery centre
Equal medical institutions.Patient can not only enjoy oxygen while can also benefit from a large amount of with also in this medical institutions
The benefit of the hydrogen-rich water of originality.
In addition, there are no pollution to the environment for the equipment provided by the invention using graphene high-efficiency oxygen and hydrogen-rich ionized water,
The purity is high of hydrogen is produced, pressure is big, and it is at low cost, it is high-efficient, without the equipment and technology of cumbersome purified treatment and pressurization, quality
Small, energy consumption is few, and industrialization degree is high, can large-scale industrial production.The technology of the present invention can produce and produce hydrogen-oxygen one by one
Gas cell, the work of each unit be it is independent, in this way in the form of each unit is module, identical unit can be with
Unlimited superposition.Under conditions of electric energy allows, the tolerance that can be arbitrarily needed with output is industrialization large-scale production and each neck
Domain and various industries provide gas source and the energy.
To sum up, the equipment disclosed by the invention using graphene high-efficiency oxygen and hydrogen-rich ionized water is sprayed by using surface
Efficient catalytic electrode material of the carbon fiber layer of graphene as water electrolysis hydrogen production oxygen, can effectively improve the conduction of elctro-catalyst
Property, accelerate charge transfer rate in electrochemical process, substantially reduces overpotential of the catalyst in water electrolysis hydrogen production reaction, it can
Significant catalytic electrolysis water oxygen evolution reaction and evolving hydrogen reaction, are conducive to the diffusion of the oxyhydrogen generated and electrolyte, reduce electro-catalysis
Resistance to mass tranfer in the process greatly improves electro-catalysis hydrogen manufacturing oxygen activity and stability, to improve water electrolysis hydrogen production oxygen effect
Rate.And the device structure provided by the invention using graphene high-efficiency oxygen and hydrogen-rich ionized water is simple, energy that can be minimum
Useful hydrogen-rich water is generated for using while consumption manufacture hydrogen, oxygen.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
There is also other identical elements in process, method, article or equipment including the element.
The above is a preferred embodiment of the present invention, it is noted that for those skilled in the art
For, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also considered as
Protection scope of the present invention.
Claims (8)
1. a kind of equipment using graphene high-efficiency oxygen and hydrogen-rich ionized water, which is characterized in that sent out including at least one hydrogen-oxygen
Raw device unit is composed in series, each oxyhydrogen generator unit include be fixed at the intracorporal positive plate of case and negative plate,
Proton exchange membrane between the positive plate and negative plate, so that cabinet is divided into water storage cavity, hydrogen generation chamber and oxygen
Gas generation chamber；The positive plate, negative plate are correspondingly connected with the positive and negative anodes of power supply, are provided with and urge on the positive plate, negative plate
Agent layer, the catalyst layer are the carbon fiber layer of surface spraying graphite alkene；The water storage cavity is equipped with inlet and outlet；
It is anti-that electrochemistry occurs under the catalyst layer effect of the positive plate via the water that the water inlet enters the water storage cavity
It answers, oxygen, hydrogen ion and free electronics is divided by electrolysis, the oxygen of generation enters the oxygen generation chamber；The hydrogen of generation from
Son passes through the proton exchange membrane under the action of electric field, hydrogen atom is generated in conjunction with free electronics, and described negative
Hydrogen is formed into the hydrogen generation chamber under catalyst layer effect on pole plate；It is reacted after formed hydrogen-rich water from it is described go out
Mouth of a river discharge.
2. the equipment according to claim 1 using graphene high-efficiency oxygen and hydrogen-rich ionized water, it is characterised in that: described
Catalyst layer is made of the graphene carbon fiber filament that every diameter is 100nm.
3. the equipment according to claim 2 using graphene high-efficiency oxygen and hydrogen-rich ionized water, it is characterised in that: every
In the case that the one oxyhydrogen generator cell capability is 200~300ml, each catalyst layer is by 3~50,000 stones
Black olefinic carbon fiber filament is arranged to make up.
4. the equipment according to claim 1 using graphene high-efficiency oxygen and hydrogen-rich ionized water, it is characterised in that: described
The width of hydrogen generation chamber is equipped with hydrogen outlet less than 2 millimeters, on top.
5. the equipment according to claim 1 using graphene high-efficiency oxygen and hydrogen-rich ionized water, it is characterised in that: described
The top of oxygen generation chamber is equipped with oxygen delivery outlet.
6. the equipment according to claim 1 using graphene high-efficiency oxygen and hydrogen-rich ionized water, it is characterised in that: described
First connecting terminal is set on positive plate to connect with extraneous positive pole；Be arranged on the negative plate the second connecting terminal with
It is connect with extraneous power cathode.
7. the equipment according to claim 1 using graphene high-efficiency oxygen and hydrogen-rich ionized water, it is characterised in that: described
The water inlet of the top setting of water storage cavity is connected with inlet pipeline, the water outlet and outlet pipeline phase of bottom end setting
Even.
8. the equipment according to claim 1 using graphene high-efficiency oxygen and hydrogen-rich ionized water, it is characterised in that: described
Power supply is being electrolysed hydrone using the hydrone of frequency modulating exciting electrode plate using the DC power supply of pulsed
Process forms resonance electrolysis.
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| CN201710094214.3A CN107083557B (en) | 2017-02-21 | 2017-02-21 | A kind of equipment using graphene high-efficiency oxygen and hydrogen-rich ionized water |
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| CN110548332A (en) * | 2018-05-31 | 2019-12-10 | 保佳利实业有限公司 | Front-mounted filter faucet with functional water manufacturing structure |
| CN112126939A (en) * | 2020-10-29 | 2020-12-25 | 上海茶源新能源科技有限责任公司 | High-energy hydrogen atom generating device |
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| CN104685104A (en) * | 2012-06-12 | 2015-06-03 | 莫拿什大学 | Gas permeable electrode and method of manufacture |
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