WO2016121895A1 - Composition herbicide - Google Patents

Composition herbicide Download PDF

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Publication number
WO2016121895A1
WO2016121895A1 PCT/JP2016/052570 JP2016052570W WO2016121895A1 WO 2016121895 A1 WO2016121895 A1 WO 2016121895A1 JP 2016052570 W JP2016052570 W JP 2016052570W WO 2016121895 A1 WO2016121895 A1 WO 2016121895A1
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WIPO (PCT)
Prior art keywords
parts
herbicidal composition
group
salt
compound
Prior art date
Application number
PCT/JP2016/052570
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English (en)
Japanese (ja)
Inventor
貴志 重藤
Original Assignee
協友アグリ株式会社
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Publication of WO2016121895A1 publication Critical patent/WO2016121895A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
    • A—HUMAN NECESSITIES
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    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
    • A01N57/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
    • A01N57/30—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing aromatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/08—Alkali metal chlorides; Alkaline earth metal chlorides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/24—Cyanogen or compounds thereof, e.g. hydrogen cyanide, cyanic acid, cyanamide, thiocyanic acid

Definitions

  • the present invention relates to a herbicide composition and the like.
  • Non-Patent Document 1 Currently, many herbicides are sold and used. (For example, see Non-Patent Document 1)
  • Pesticide Manual (The Pesticide Manual) Fifteenth Edition (2009), British Crop Production Council (ISBN: 978-1-901396-18-8)
  • An object of the present invention is to provide a herbicidal composition having an excellent weed control effect.
  • the present inventors have found a pyrazolyl pyrazole derivative represented by the following formula (I) and a specific herbicide other than the pyrazolyl pyrazole derivative: It has been found that a herbicidal composition containing sucrose has an excellent weed control effect, leading to the present invention. That is, the present invention is as follows.
  • R 1 represents a halogen atom
  • R 2 represents a cyano group, a nitro group or a halogen atom
  • R Three represents a hydrogen atom, a trifluoroacetyl group, a pentafluoropropionyl group, a heptaflurobutenyl group
  • R Four ⁇ R 9 May be the same or different and may be a hydrogen atom, a halogen atom, C (optionally substituted by one or more halogen atoms) 1 ⁇ C 6
  • An alkyl group (optionally substituted by one or more halogen atoms) C
  • Three ⁇ C 6 A cycloalkyl group (optionally substituted by one or more halogen atoms) C 2 ⁇ C 6
  • An alkynyl group (optionally substituted by one or more
  • R 1 Represents a chlorine atom or a bromine atom
  • R Four ⁇ R 9 which may be the same or different, may be a hydrogen atom, a halogen atom, or a C (optionally substituted by one or more halogen atoms) 1 ⁇ C
  • An alkyl group (optionally substituted by one or more halogen atoms) C
  • Three ⁇ C 6 A cycloalkyl group (optionally substituted by one or more halogen atoms) C 2 ⁇ C
  • An alkenyl group optionally substituted by one or more halogen atoms) C 2 ⁇ C
  • An alkynyl group (optionally substituted by one or more halogen atoms) C 1 ⁇ C
  • Alkoxy (C 2 ⁇ C Four )
  • herbicidal composition according to [1] or [2], wherein the herbicidal active compound is an ALS inhibitor, germination / elongation inhibitor, photosynthesis inhibitor, PPO inhibitor, whitening agent, VLCFAs inhibitor, hormonal action A herbicidal composition selected from the group consisting of an inhibitor / disturbant, an ACCase inhibitor, and a non-selective herbicide.
  • herbicidal active compound is an ALS inhibitor.
  • [5] The herbicidal composition according to [4], wherein the ALS inhibitor is amidosulfuron, azimsulfuron, bensulfuron-methyl, chlorimuron-ethyl , Chlorosulfuron, cinosulfuron, cyclosulfamuron, ethamethsulfuron-uryl, flusulfuron, flusulfuron, flusulfuron, flusulfuron, flusulfuron.
  • the ALS inhibitor is amidosulfuron, azimsulfuron, bensulfuron-methyl, chlorimuron-ethyl , Chlorosulfuron, cinosulfuron, cyclosulfamuron, ethamethsulfuron-uryl, flusulfuron, flusulfuron, flusulfuron, flusulfuron, flusulfuron.
  • Flupirsulfuron Methi (Flupyrsulfuron-methyl) and salts thereof, foramsulfuron, halosulfuron-methyl, imazosulfuron, iodosulfuron and salt of iodosulfuron Iofensulfuron-sodium, mesosulfuron-methyl, metazosulfuron, metsulfuron-methyl, nicosulfuron, nicosulfuron rhosulfururon, oxasulfuron, primisulfuron-methyl, propylsulfuron, prosulfururon, pyrazosulfuron, pyrazosulfuron, pyrazosulfuron Methyluron-methyl, sulfosulfuron, thifensulfuron-methyl, trisulfuron, tribenuron-methyl, trifurylsulfuron-methyl rifloxysulfuron and its salts, triflusulfur
  • a herbicidal composition selected from the group consisting of fluorlenol, fosamine and prodiamine.
  • [17] The herbicidal composition according to [16], wherein the whitening agent is benzofenap, pyrazosulfol, pyrazolate, pyrazoxifene, topramzone, mesotrione ), Sulcotrione, tembotrione, tefuryltrione, fenquinotrione, isoxaflutole, isoxachlorcycloleone, Bicyclon (benzobi) yclon), diflufenican, picolinafen, norflurazon, amitrole, clomazone, aclonifone, cyclopyrimole, cyclopyrimolate
  • a herbicidal composition selected from the group consisting of flurochloridon, flurtamone, and beflubutamid.
  • VLCFAs inhibitor is acetochlor, alachlor, butachlor, dimethachlor, dimethenamide, dimethenamide-P ( dimethenamid-P), metazachlor (metazachlor), S-metolachlor (S-metolachlor), pesoxamide, pretilachlor, propichlor, propodichlor, propodichlor.
  • [31] The composition according to [31], wherein the safener is benoxacol, cloquintocet-mexyl, cyometrinil, cyprosulfamide, dichlormid , Fenchlorazole-ethyl, fenchlorim, flurazole, furilazole, fluxofenim, isoxadifen-ethyl-diethyl ), Oxabetrinil 1,8-naphthalic anhydride (1,8-naphthalic anhydride), AD67, MG191, daimuron (dymron), the composition selected from the group consisting dimepiperate (dimepiperate).
  • the safener is benoxacol, cloquintocet-mexyl, cyometrinil, cyprosulfamide, dichlormid , Fenchlorazole-ethyl, fenchlorim, flurazole, furilazole, fluxofenim, isoxad
  • R 1 represents a halogen atom
  • R 2 represents a cyano group, a nitro group or a halogen atom
  • R Three represents a hydrogen atom, a trifluoroacetyl group, a pentafluoropropionyl group, a heptaflurobutenyl group
  • R Four ⁇ R 9 May be the same or different and may be a hydrogen atom, a halogen atom, C (optionally substituted by one or more halogen atoms) 1 ⁇ C 6
  • An alkyl group (optionally substituted by one or more halogen atoms) C
  • Three ⁇ C 6 A cycloalkyl group (optionally substituted by one or more halogen atoms) C 2 ⁇ C 6
  • An alkynyl group (optionally substituted by one or more
  • a herbicidal composition having an excellent weed control effect can be provided.
  • the herbicidal composition of the present invention (hereinafter referred to as the present herbicidal composition) has the formula (I) Formula (I): [In the formula, R 1 represents a halogen atom, R 2 represents a cyano group, a nitro group or a halogen atom, R 3 represents a hydrogen atom, a trifluoroacetyl group, a pentafluoropropionyl group or a heptaflurobutenyl group; R 4 to R 9 may be the same or different and are a hydrogen atom, a halogen atom, a C 1 -C 6 alkyl group (optionally substituted by one or more halogen atoms), (optionally 1 A C 3 -C 6 cycloalkyl group (substituted by one or more halogen atoms), a C 2 -C 6 alkenyl group (optionally substituted by one or more halogen atoms), (optionally A C 2 -C
  • Halogen atom includes fluorine, chlorine, bromine and iodine atoms.
  • Alkyl as referred to by itself or as part of a group can be linear or branched and includes, but is not limited to, for example, methyl, ethyl, n- or iso-propyl, n- , Iso-, sec- or tert-butyl, n-pentyl, n-hexyl, and the like, each selected within the specified number of carbon atoms.
  • Alkoxy group means an alkyl-O— group in which the alkyl moiety has the above meanings, including but not limited to, for example, methoxy, ethoxy, n- or iso-propoxy, n-, iso-, sec -Or tert-butoxy group and the like, and each is selected within the range of the designated number of carbon atoms.
  • Cycloalkyl groups include, but are not limited to, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl groups, and the like, each selected within the specified number of carbon atoms.
  • Alkenyl group means an unsaturated hydrocarbon group which is linear or branched and has one or more double bonds in the molecule. Specific examples include 1-propenyl group, 2-propenyl group, 2-butenyl group, 2-methyl-2-propenyl group, 3-methyl-2-butenyl group, 1,1-dimethyl-2-propenyl group, and the like. Each of which is selected for each specified number of carbon atoms.
  • Alkynyl group means an unsaturated hydrocarbon group which is linear or branched and has one or more triple bonds in the molecule, and is not limited to, for example, ethynyl group, 1 Specific examples include -propynyl group, 2-propynyl group, 1-butynyl group, 2-butynyl group, 3-butynyl group, 1,1-dimethyl-2-propynyl group and the like. Selected by range.
  • alkyl group In the “alkyl group”, “cycloalkyl group”, “alkenyl group”, “alkynyl group”, “alkoxy group”, at least one hydrogen atom contained in these groups may be substituted with a halogen atom
  • alkyl groups include, but are not limited to, chloromethyl, dichloromethyl, trifluoromethyl, chloroethyl, dichloroethyl, trifluoroethyl, tetrafluoropropyl, bromoethyl, bromopropyl, chlorobutyl, chlorohexyl, perfluoro It can be a hexyl group and is selected for each specified number of carbon atoms.
  • the groups or moieties are polysubstituted by halogen atoms, or the phenyl group is a halogen atom, nitro group, cyano group, optionally substituted by one or more halogen atoms, C 1 -C 4
  • this group can be substituted by more than one identical or different halogen atom and / or substituent.
  • the compound can exist as a stereoisomer.
  • stereoisomers can be enantiomers and diastereomers.
  • Stereoisomers can be obtained from the mixtures obtained in the preparation by conventional separation methods, for example chromatographic separation steps.
  • Stereoisomers can also be prepared by using stereoselective reactions, employing optically active starting materials and / or auxiliaries.
  • the invention also relates to all stereoisomers and mixtures thereof which are encompassed by the compounds represented by formula (I) but are not specifically defined.
  • a known herbicidal active compound may be used, but preferably an ALS inhibitor, germination / elongation inhibitor, photosynthesis inhibitor, PPO inhibitor, whitening agent, It is at least one herbicidally active compound selected from a VLCFAs inhibitor, a hormone action inhibitor / disturber, an ACCase inhibitor, and a non-selective herbicide.
  • the ALS inhibitor which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that inhibits acetolactate synthase involved in the biosynthesis of amino acids such as valine, leucine and isoleucine. .
  • the ALS inhibitors include sulfonylurea herbicides, triazolopyrimidine herbicides, pyrimidinyloxybenzoic acid herbicides, imidazolinone herbicides, sulfonylaminocarbonyltriazolinone herbicides, pyrimidinylthiobenzoic acid herbicides, respectively. And so on.
  • Suitable pyrimidinyloxybenzoic acid-based ALS inhibitors for the herbicidal composition of the present invention include, but are not limited to, for example, bispyribac and salts thereof, pyribenzoxim, pyriminobac-methyl. ), Pyrimisulfan, pyriftalid, triafamon, and the like, and preferred are bispyribac and salts thereof, pyriminobacmethyl, pyrimisulfan, pyriftalide, and triafamon.
  • imidazolinone-based ALS inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, imazametabenz-methyl, imazamox and salts thereof, imazapic And its salt, imazapyr and its salt, imazaquin and its salt, imazethapyr and its salt, preferably imazamox and its salt, imazapic and its salt, imazapyr and its salt, Imazetapyr and its salts are mentioned.
  • sulfonylaminocarbonyltriazolinone-based ALS inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, flucarbazone and its salt, propoxycarbazone and its salt, thien And carbazone methyl (thiencarbazone-methyl).
  • the pyrimidinylthiobenzoic acid ALS inhibitor suitable for the herbicidal composition of the present invention is not limited, and examples thereof include pyrithiobac and salts thereof.
  • Germination / elongation inhibitor which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is cell division, cell hypertrophy, cell elongation, protein synthesis, nucleic acid synthesis, nucleus of germination and elongation process of plants It is a compound that acts on membrane formation, spindle microtubule formation, spindle microtubule polymerization, folic acid production, etc., and inhibits cell division.
  • the germination / elongation inhibitor is thiocarbamate herbicide, dinitroaniline herbicide, carbamate herbicide, chlorocarbonate herbicide, benzamide herbicide, urea herbicide, benzofuran herbicide, organophosphorus. It is classified into herbicides, pyridine herbicides, nitrile herbicides, acid amide herbicides and the like.
  • Examples of the thiocarbamate germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, butyrate, hexyl-thiocarbam, dimethylpiperate, and EPTC. , Esprocarb, molinate, olvencarb, pebrate, prosulfocarb, thiobencarb, thiocarbazyl, triate valate, triate Preferably, esprocarb, molinate, olvencarb, pro Ruhokarubu, it includes the thiobencarb.
  • dinitroaniline germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, benfluralin, butralin, dinitramine, ethalfluralin. , Oryzalin, pendimethalin, trifluralin, and the like, preferably pendimethalin and trifluralin.
  • carbamate germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, carbetamide, chlorprophum, propham, pyributycarb (pyribitucarb), Asuram etc. are mentioned, Preferably, a pyributicarb and an ashram are mentioned.
  • chlorocarbonic acid germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, TCA, dalapon, flupropanate, and salts thereof. May include full propanate.
  • benzamide germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, propyzamide, tebutam, isoxaben, etc. Propizzamid is mentioned.
  • urea germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, cumylron, dymron, methyldymron, and the like, preferably , Cumylron, and dimron.
  • benzofuran germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, benfrateate, etofumesate, and preferably benfrecetate.
  • organic phosphorus germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, butamifos, amiprophos-methyl, anilofos, benzulide (Bensulide), piperophos (piperophos), etc. are mentioned, Preferably, butamifos, anilophos, and benzulide are mentioned.
  • Examples of the pyridine-based germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, dithiopyr and thiazopyr, and preferably dithiopyr.
  • nitrile germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, diclobenil, chlorthiamid, and preferably diclobenil.
  • Examples of the acid amide germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, bromobutide, etobenzanide and the like.
  • germination / elongation inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chlorthal-dimethyl, fluoxam, indaziflam, methiozoline. ), Triaziflam, cinmethylin, chlorflurenol, fosamine, prodiamine and the like, and preferably, triaziflam.
  • the photosynthesis inhibitor which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that acts on the electron transfer system in photosynthesis and inhibits photosynthesis.
  • the photosynthesis inhibitors are urea herbicide, 1,3,5-triazine herbicide, phenyl carbamate herbicide, triazinone herbicide, uracil herbicide, hydroxybenzonitrile herbicide, phenyl pyridazine herbicide, respectively. And anilide herbicides.
  • urea photosynthesis inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chlorbromulon, chlorotoluron, chloroxuron, dimefuron, diuron ( diuron, ethidimuron, fenuron, fluometuron, isoproturon, isouron, linuron, mebenzenthuron, methabenzthuron ), Monolinuron (m novoluron, neburon, siduron, tebuthiuron, carbbutyrate, and the like, preferably chlorbromulone, diuron, fluometuron, isoproturon, isoururon, linuronthlon, metabenzuron And carbbutylate.
  • 1,3,5-triazine-based photosynthesis inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, amethrin, atrazine cyananadine, desmethrin. , Dimethametrin, promethon, promethrin, propazine, simazine, ziterin, terbetine, terbetetone, terbetetone
  • atrazine, cyanazine, dimetametho Down, propazine, simazine include the simetryn.
  • bromoxynil and its salt are mentioned.
  • the phenylpyridazine-based photosynthesis inhibitor suitable for the herbicidal composition of the present invention is not limited, and examples thereof include pyridate, pyridafol, and preferably pyridate.
  • anilide-based photosynthesis inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, propanil, pentanochlor, and preferably propanil.
  • Examples of other photosynthesis inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chloridazon, quinoclamamine, amicarbazone, bentazone, and salts thereof. Preferably, amicarbazone, bentazone and a salt thereof are mentioned.
  • the PPO inhibitor which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that inhibits protoporphyrinogen oxidase involved in chlorophyll biosynthesis.
  • the PPO inhibitors are diphenyl ether herbicide, N-phenylphthalimide herbicide, triazolinone herbicide, pyrimidinedione herbicide, phenylpyrazole herbicide, thiadiazole herbicide, oxadiazole herbicide, etc. being classified.
  • diphenyl ether PPO inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, aciflufen and salts thereof, bifenox, clomethoxyphene, oxyfluorfen. (Oxyfluorfen), lactofen, fomesafen and its salts, fluoroglycofen-ethyl, halosafen, etc., preferably biphenox, oxyfluorfen, lactofen, fluoroglycopheneethyl Can be mentioned.
  • N-phenylphthalimide PPO inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, cinidon-ethyl, flumioxazin, full-microlac-pentyl. ) And the like, preferably flumioxazin.
  • triazolinone-based PPO inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, carfentrazone-ethyl, sulfentrazone, azaphenidin, and the like.
  • carfentrazone ethyl is used.
  • Pyrimidinedione PPO inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, benzfendizone, butafenacil, saflufenacil, etc. Includes butafenacyl and saflufenacyl.
  • thiadiazole PPO inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, fluthiacet-methyl, thiazimine, and the like, preferably fluthiaset methyl. Is mentioned.
  • PPO inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chlorphthalim, pentoxazone, pyraclonil, flufenpyr-ethyl. , Profluazole, and the like, preferably chlorphthalim, pentoxazone, and pyraclonyl.
  • the whitening agent which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that inhibits the synthesis of pigments such as carotenoids and chlorophylls involved in plant photosynthesis.
  • the whitening agents are classified into pyrazole herbicides, triketone herbicides, isoxazole herbicides, bicyclo herbicides, pyridinecarboxamide herbicides, and the like.
  • pyrazole-based whitening agents suitable for the herbicidal composition of the present invention include, but are not limited to, for example, benzofenap, pyrasulfotole, pyrazolate, pyrazoxifene, and topramezone. (Topramzone) etc. are mentioned, Preferably a benzophenap, a pyrazolate, a pyrazoxifene, and a topramone are mentioned.
  • triketone-based whitening agent suitable for the herbicidal composition of the present invention include, but are not limited to, for example, mesotrione, sulcotrione, tembotrione, tefriltrione, and fenquino.
  • a trione (fenquintrione) etc. are mentioned, Preferably, a mesotrione, a tefryl trione, a fenquinotrione is mentioned.
  • isoxazole-based whitening agent suitable for the herbicidal composition of the present invention include, but are not limited to, isoxaflutole, isoxachlortole, etc. Flutol is mentioned.
  • bicyclo whitening agent suitable for the herbicidal composition of the present invention include, but are not limited to, for example, bicyclopyrone, benzobicyclone, and preferably benzobicyclone. It is done.
  • Examples of the pyridinecarboxamide-based whitening agent suitable for the herbicidal composition of the present invention include, but are not limited to, diflufenican, picolinafen, and preferably diflufenican.
  • whitening agents suitable for the herbicidal composition of the present invention include, but are not limited to, for example, norflurazon, amitrole, clomazone, aclonifen, cyclopyrimoleate ( Cyclopyrimorate, fluridone, flurochloridone, flurtamone, beflubutamide, and the like, preferably amitrol, chromazone, cyclopyrimoleate, and beflumide.
  • VLCFAs inhibitors which are part of the herbicidal active compounds that can be included in the herbicidal composition of the present invention, are fatty acid elongations involved in the production of very long chain fatty acids that are the main components of plant cuticular wax layers and cell membrane sphingolipids. A compound that inhibits the enzyme system.
  • VLCFAs inhibitors are classified into chloroacetamide herbicides, acetamide herbicides, oxyacetamide herbicides and the like, respectively.
  • chloroacetamide-based VLCFAs inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, acetochlor, alachlor, butachlor, dimethachlor, dimethenamide. (Dimethenamide), dimethenamide-P (dimethenamide-P), metazachlor (metazachlor), S-metolachlor (S-metolachlor), pexoxamid (pretilachlor), proprochlor (pro), proprochlor (pro) ), Tenylchlor, etc. Is preferably acetochlor, alachlor, butachlor, dimethenamid -P, S- metolachlor, pretilachlor, include Thenylchlor.
  • acetamide-based VLCFAs inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, diphenamide, napropamide, and preferably diphenamide.
  • oxyacetamide-based VLCFAs inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, flufenacet, mefenacet and the like.
  • VLCFAs inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, fentrazamide, fenoxasulfone, indanofan, caffentrol, piroxaz A sulfone (pyroxasulfone), an ipfencarbazone (ipfencarbazone), etc. are mentioned.
  • the hormonal action inhibiting / disturbing agent which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that inhibits or disturbs phytohormonal actions such as auxin and gibberellin related to plant growth. It is.
  • the hormone action inhibiting / disturbing agents are classified into phenoxycarboxylic acid herbicides, pyridinecarboxylic acid herbicides, benzoic acid herbicides, quinolinecarboxylic acid herbicides, phthalamate semicarbazone herbicides, respectively.
  • phenoxycarboxylic acid hormone action inhibitor / disturber suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chromeprop, 2,4-D and salts thereof, 2,4-DB And salts thereof, dichloroprop and salts thereof, MCPA and salts thereof, MCPB and salts thereof, mecoprop and salts thereof, 2,4-PA ethyl (2,4-PA-ethyl), phenothiol (Phenothiol) and the like, and preferable examples include chromeprop, 2,4-D and salts thereof, 2,4-DB and salts thereof, MCPA and salts thereof, MCPB and salts thereof, mecoprop and salts thereof.
  • pyridinecarboxylic acid hormone inhibiting / disturbing agent suitable for the herbicidal composition of the present invention include, but are not limited to, for example, aminopyralide and its salt, clopyralid and its salt, fluroxypyr-1 -Methyl beptyl ester (methylpropyl-1-ester), picloram and its salt, triclopyr and its salt, etc., preferably triclopyr and its salt.
  • benzoic acid hormone action inhibitor / disturber suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chloramben cocoon, dicamba and salts thereof, 2,3,6-TBA Preferably, dicamba and its salt are mentioned.
  • quinolinecarboxylic acid hormone action inhibitor / disturber suitable for the herbicidal composition of the present invention include, but are not limited to, quinchlorac, quinmerac, and the like, Kinclorac is mentioned.
  • the phthalamate semicarbazone hormone action inhibitor / disturber suitable for the herbicidal composition of the present invention is not limited, and examples thereof include naptalam, diflufenzopyr and salts thereof. Preferably, diflufenzopyr and its salt are mentioned.
  • hormonal action inhibiting / disturbing agents suitable for the herbicidal composition of the present invention include, but are not limited to, for example, oxadiclomephone, benazoline, aminocyclopyrachlor, and the like.
  • oxadichrome mehon is used.
  • the ACCase inhibitor which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that inhibits acetyl-CoA carboxylase involved in fatty acid biosynthesis.
  • the ACCase inhibitors are classified into aryloxyphenoxypropionic acid herbicides, cyclohexanedione oxime herbicides, phenylpyrazoline herbicides, and the like.
  • aryloxyphenoxypropionic acid-based ACCase inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, clodinafop-propargyl, cyhalofop-butyl, Diclohop-methyl, phenoxaprop-P-ethyl, fluazifop-P-butyl, haloxyhop-P-methyl, haloxyhop-P-methyl, Metamihop, propaquizahop, quizalofop-P-ethyl, etc.
  • Gerare preferably clodinafop-propargyl, cyhalofop-butyl, fenoxaprop -P- ethyl, fluazifop -P- butyl, metamifop, include quizalofop -P- ethyl.
  • cyclohexanedione oxime ACCase inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, alloxydim and salts thereof, cetoxydim, butroxydim, cletodim. , Cycloxydim, teplaloxidim, tralkoxydim, profoxydim, and the like, and preferably cetoxydim and cretodim.
  • phenylpyrazoline-based ACCase inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, pinoxaden.
  • herbicidally active compounds that can be contained in the herbicidal composition of the present invention are known as non-selective herbicides, exhibiting herbicidal activity on plants grown in treated parts without distinction between crops and weeds, mainly non-agricultural It is a herbicide used on the ground.
  • glyphosate is a compound that inhibits 5-enolpyruvylshikimate-3-phosphate synthase involved in the biosynthesis of aromatic amino acids such as tyrosine, phenylalanine, and tryptophan.
  • Glufosinate ammonium and the like are compounds that inhibit glutamate synthase, which is important for ammonia assimilation.
  • Chlorates and the like are compounds that exhibit a strong oxidizing action and cause cell protoplast separation. Cyanate and the like are compounds that cause cell cytoplasmic destruction. Paraquat and the like are compounds that cause cell destruction by the generation of active oxygen. Pelargonic acid or the like is a compound that drastically lowers the intracellular pH and causes cell destruction.
  • the non-selective herbicides are classified into inorganic herbicides, dinitrophenol herbicides, organic arsenic herbicides, phosphinic acid herbicides, bipyridinium herbicides, and the like.
  • Examples of the inorganic non-selective herbicides suitable for the herbicidal composition of the present invention include, but are not limited to, for example, sodium cyanate, sodium chlorate, endothal and the like. Examples thereof include salts, lime nitrogen (sulfamic acid), sulfamic acid (sulfamic acid), and salts thereof, preferably sodium cyanate and sodium chlorate.
  • Non-selective dinitrophenol-based herbicides suitable for the herbicidal composition of the present invention include, but are not limited to, for example, DNOC, dinoseb, dinoterb, etc., preferably dinoseb. It is done.
  • organic arsenic non-selective herbicide suitable for the herbicidal composition of the present invention include, but are not limited to, for example, DSMA, MSMA, and preferably DSMA.
  • phosphinic acid-based non-selective herbicide suitable for the herbicidal composition of the present invention include, but are not limited to, bialaphos and salts thereof, glufosinate-ammonium, and the like.
  • the bipyridinium non-selective herbicide suitable for the herbicidal composition of the present invention is not limited, and examples thereof include diquat dibromide and paraquat dichloride.
  • non-selective herbicides suitable for the herbicidal composition of the present invention include, but are not limited to, for example, d-limonene, glyphosate and salts thereof, difenzoquat, pelargon An acid (pelargonic acid) etc. are mentioned, Preferably, a glyphosate and its salt, difenzocoat, and pelargonic acid are mentioned.
  • the herbicidal active compound is a known compound and is commercially available. Further, for example, it can be produced according to the literature described in the Pesticide Manual, The Fifteenth Edition (2009), the British Crop Production Council (ISBN: 978-1-901396-18-8), and the like.
  • a generally known compound may be used, and is not limited, and examples thereof include, but are not limited to, benoxacol, cloquintocet-mexyl. , Ciometrinil, cyprosulfamide, dichlormid, fenchlorazole-ethyl, fenchlorim, fluzole, fluzole, fluzole, fluzole, fluzole.
  • Examples include setmexyl, thiomethrinyl, fenchlorazole ethyl, flurazole, mefenpyr diethyl, 1,8-naphthalic anhydride, and diimron.
  • the above-mentioned safener is a known compound and is commercially available. Further, for example, it can be produced according to the literature described in the Pesticide Manual, The Fifteenth Edition (2009), the British Crop Production Council (ISBN: 978-1-901396-18-8), and the like.
  • the herbicidal composition of the present invention has herbicidal activity against a wide range of weeds and is effective in paddy fields, crop fields, vegetable fields, orchards, or non-agricultural lands where ordinary tillage cultivation and non-tillage cultivation are performed. A wide range of weeds can be controlled.
  • control target of the herbicidal composition of the present invention examples include, but are not limited to, the following. Crabgrass (Digitaria ciliaris), goosegrass (Eleusineindica), green foxtail (Setaria viridis), giant foxtail (Setaria faberi), Kin green foxtail (Setaria glauca), barnyardgrass (Echinochloa crus-galli), creeping bentgrass (Agrostis alba), fall panicum (Panicum dichotomiflorum), Texas Panicum (Panicum texanum), Meriken Acne (Brachiaria platyphylla), Alexander Grass (Brachiaria plantagenea), Suriname Grass (Brachiaria decumbens), Seban Sorghum (Sorghum) um halepense), shutter Kane (Andropogon sorghum) bermudagrass (Cynodon dactylon), oats (Avena fatua), darnel (Lolium mult
  • Potamogeton Pectinatus Water meal (Wolffia genus), water mills foil such (Myriophyllum spicatum, Myriophyllum heterophyllum etc.), water hyacinth (Eichhornia crassipes) or the like aquatic plants.
  • the herbicidal composition of the present invention is used as a herbicide in agricultural land such as paddy fields, fields, lawns, orchards, or non-agricultural land.
  • the composition for herbicidal use of the present invention is not limited, but can control weeds in the cultivated land, for example, in cultivated lands where the “plants” listed below are cultivated.
  • Plant Agricultural crops: corn, rice, wheat, barley, rye, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane, tobacco, hop, etc.
  • Vegetables Solanum vegetables (eggplants, tomatoes, peppers, peppers, potatoes, etc.), cucurbits (cucumbers, pumpkins, zucchini, watermelons, melons, cucumbers, etc.), cruciferous vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage) , Cabbage, mustard, broccoli, cauliflower, etc.), asteraceae vegetables (burdock, garlic, artichoke, lettuce, etc.), liliaceae vegetables (leek, onion, garlic, asparagus, etc.), celery family vegetables (carrot, parsley, celery, American Bow Fu etc.), Rubiaceae vegetables (spinach, chard, etc.), Lamiaceae vegetables (shiso, mint, basil, etc.), Legumes (peas, kidney beans, azuki bean, broad beans, chickpeas, etc.), strawberry, sweet potato, yam, taro , Konnyuk, ginger, ok Etc..
  • Fruit trees fruits (apples, pears, pears, quince, quince, etc.), nuclear fruits (peaches, plums, nectarines, umes, sweet cherry, apricots, prunes, etc.), citrus (citrus oranges, oranges, lemons, limes, grapefruits) ), Nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, banana, coffee, Date palm, coconut palm, oil palm etc.
  • Trees other than fruit trees tea, mulberry, flowering trees (Satsuki, camellia, hydrangea, sasanqua, shikimi cherry tree, yurinoki, crape myrtle, eustoma, etc.), roadside trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak, poplar) , Japanese red clover, flatfish, plane tree, Japanese zelkova, blackfish, Japanese cypress, Japanese pine, spruce, yew, elm, Japanese cypress, coral, Japanese cypress, Japanese cedar, Japanese cypress, croton, Japanese cypress, kanamochi.
  • plants include genetically modified crops.
  • the herbicide of the present invention contains the herbicidal composition of the present invention, that is, the present compound and at least one herbicidally active compound, may contain a safener, and in some cases, two or more herbicidal activities.
  • a compound may be contained.
  • the herbicide of the present invention usually contains formulation aids and the like according to conventional methods, and is not limited to, for example, powders, emulsions, oils, solubilizers, suspoemulsions, fine granules, sprays DL powder, fine granule F, fine granule F, granule, wettable powder, wettable granule, flowable, jumbo, tablet, paste, oily suspension, aqueous solvent, granular aqueous solvent, liquid, It is preferable to formulate and use it in any dosage form such as a microcapsule.
  • Formulation aids that can be used for formulation are not limited, and examples include solid carriers, liquid carriers, binders, thickeners, surfactants, antifreeze agents, and preservatives.
  • solid carrier examples include, but are not limited to, for example, talc, bentonite, montmorillonite, clay, kaolin, calcium carbonate, sodium carbonate, sodium bicarbonate, sodium sulfate, zeolite, starch, acid clay, diatomaceous earth, white carbon, vermiculite, Examples include slaked lime, vegetable powder, alumina, activated carbon, saccharides, glass hollow bodies, silica sand, ammonium sulfate, urea, and the like.
  • liquid carrier examples include, but are not limited to, hydrocarbons (eg, kerosene, mineral oil, etc.); aromatic hydrocarbons (eg, toluene, xylene, dimethylnaphthalene, phenylxylylethane, etc.); chlorine Hydrocarbons (eg, chloroform, carbon tetrachloride, etc.); ethers (eg, dioxane, tetrahydrofuran, etc.); ketones (eg, acetone, cyclohexanone, isophorone, etc.); esters (eg, ethyl acetate, ethylene glycol acetate) Alcohols (eg, methanol, n-hexanol, ethylene glycol, etc.); polar solvents (eg, N, N-dimethylformamide, dimethyl sulfoxide, N-methylpyrrolidone, etc.); water, etc. It is done.
  • hydrocarbons eg, keros
  • binder and the thickener examples include, but are not limited to, for example, dextrin, sodium salt of carboxymethyl cellulose, polycarboxylic acid polymer compound, polyvinyl pyrrolidone, polyvinyl alcohol, sodium lignin sulfonate, calcium lignin sulfonate. , Sodium polyacrylate, gum arabic, sodium alginate, mannitol, sorbitol, bentonite minerals, polyacrylic acid and its derivatives, white carbon, natural sugar derivatives (eg, xanthan gum, guar gum, etc.), and the like.
  • surfactant examples include, but are not limited to, for example, fatty acid salts, benzoates, alkylsulfosuccinates, dialkylsulfosuccinates, polycarboxylates, alkyl sulfate esters, alkyl sulfates, alkylaryl sulfates.
  • antifreezing agent examples include, but are not limited to, ethylene glycol, diethylene glycol, propylene glycol, and glycerin.
  • preservative examples include, but are not limited to, for example, benzoic acid, sodium benzoate, methyl paraoxybenzoate, butyl paraoxybenzoate, isopropylmethylphenol, benzalkonium chloride, chlorhexidine hydrochloride, hydrogen peroxide, glucone Chlorhexidine acid, salicylic acid, sodium salicylate, zinc pyrithione, sorbic acid, potassium sorbate, dehydroacetic acid, sodium dehydroacetate, phenoxyethanol, 5-chloro-2-methyl-4-isothiazoline-3-one, 2-methyl-4-isothiazoline- Examples include isothiazoline derivatives such as 3-one, 2-bromo-2-nitropropane-1,3-diol, and salicylic acid derivatives.
  • solid carriers liquid carriers, binders, thickeners, surfactants, antifreezing agents and preservatives described above can be used alone or in appropriate combination depending on the purpose of use.
  • an adjuvant may be added to the sprayed solution.
  • the auxiliary agent that can be added is not limited, but includes, for example, surfactants (nonionic surfactants such as fatty acid alkyl esters and alkyl polyoxyethylene ethers, alkylbenzene sulfonates, dialkyldimethylammonium salts, and the like). Ionic surfactants), crop oil, vital oil, crop oil concentrate, methylated seed oil, organosilicon spreader, liquid fertilizer (ammonium sulfate, urea ammonia nitrate, etc.). These adjuvants may be used alone or in combination of two or more.
  • the compounding ratio of the present compound and the herbicidally active compound as an active substance of the herbicidal composition of the present invention can be varied in a wide range depending on the form of the preparation and the purpose of use. 1000, preferably 1: 0.01 to 100, more preferably 1: 0.1 to 100.
  • the method for controlling weeds with the herbicidal composition of the present invention comprises applying an effective amount of the present compound and an effective amount of the herbicidally active compound, and optionally an effective amount of at least one safener to a weed or soil where weeds grow. It is.
  • Examples of the method for applying the herbicidal composition of the present invention include a method of treating the herbicidal composition of the present invention with a foliage treatment on weeds, a method of treating the present herbicidal composition on the soil surface where weeds grow, and the present herbicidal process. And a method of admixing the composition for use in soil where weeds grow.
  • the total amount of the present compound and the herbicidal active compound per 1000 m 2 area to control weeds, and optionally the safener is usually 1 to 10000 g, preferably 1 to 5000 g, more preferably. 1 to 1000 g.
  • the herbicidal composition of the present invention can also be prepared by formulating each active ingredient and then mixing them.
  • the herbicidal composition of the present invention can be mixed or used in combination with insecticides, acaricides, nematicides, fungicides, plant growth regulators, fertilizers, soil conditioners and the like.
  • Formulation Example 3 Compound 1 1 part Propyrisulfuron 0.9 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 75.1 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring. And granulated with an extrusion granulator and dried to obtain a preparation.
  • Formulation Example 4 (Granule wettable powder) Compound 1 20 parts Halosulfuron methyl 10 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligline sulfonate 5 parts Clay 56 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 5 (wettable powder) Compound 2 10 parts Bensulfuron methyl 5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 80 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 7 Compound 2 1 part Metazosulfuron 1 part Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 75 parts Granulate and dry to obtain the formulation.
  • Formulation Example 8 (Granule wettable powder) Compound 2 20 parts Limsulfuron 2.4 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 63.6 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 9 (wettable powder) Compound 9 10 parts Thifensulfuron methyl 1.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 83.5 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 11 Compound 9 1 part Propyrisulfuron 0.9 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 75.1 parts And granulated with an extrusion granulator and dried to obtain a preparation.
  • Formulation Example 12 (Granular wettable powder) Compound 9 20 parts Halosulfuron methyl 10 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 56 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 15 Compound 147 1 part Metazosulfuron 1 part Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 75 parts Granulate and dry to obtain the formulation.
  • Formulation Example 16 (Granule wettable powder) Compound 147 20 parts Limsulfuron 2.4 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 63.6 parts After mixing and crushing uniformly, a small amount of water is added and mixed with stirring, and extruded. Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 17 Compound 1 1 part Imazosulfuron 0.9 part Bromobutide 9 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66.1 parts Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 18 Compound 2 1 part Imazosulfuron 0.9 part Bromobutide 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66.1 parts Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 19 Compound 9 1 part Imazosulfuron 0.9 part Bromobutide 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66.1 parts Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 20 Compound 185 1 part Imazosulfuron 0.9 part Bromobutide 9 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66.1 parts Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 21 Compound 1 1 part Propyrisulfuron 0.9 part Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 22 Compound 2 1 part Propyrisulfuron 0.9 part Daimlone 4.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 23 Compound 9 1 part Propyrisulfuron 0.9 part Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 24 Compound 147 1 part propyrisulfuron 0.9 part diimron 4.5 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 70.6 parts Is added and stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 25 Compound 185 1 part Propyrisulfuron 0.9 part Daimlone 4.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 26 (wettable powder) Compound 1 5 parts Pendimethalin 30 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 60 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 28 Compound 1 1 part Molinate 24 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 52 parts After mixing and pulverizing uniformly, a small amount of water is added and stirred and mixed, and an extrusion granulator Granulate and dry to obtain the formulation.
  • Formulation Example 29 (Granule wettable powder) Compound 1 10 parts Triadifram 20 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligulin sulfonate 5 parts Clay 56 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 30 (wettable powder) Compound 2 10 parts isoxaben 18 parts polyoxyethylene alkyl ether sulfate 5 parts clay 67 parts uniformly mixed and pulverized to obtain a preparation.
  • Formulation Example 32 Compound 2 1 part Benthuride 30 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 46 parts After mixing and grinding uniformly, a small amount of water is added and stirred and mixed, and an extrusion granulator Granulate and dry to obtain the formulation.
  • Formulation Example 33 (granular wettable powder) Compound 2 10 parts Dithiopyr 20 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 56 parts And dried to obtain a preparation.
  • Formulation Example 34 (wettable powder) Compound 9 5 parts Pendimethalin 30 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 60 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 36 Compound 9 1 part Molinate 24 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 52 parts After mixing and grinding uniformly, a small amount of water is added and stirred and mixed, and an extrusion granulator Granulate and dry to obtain the formulation.
  • Formulation Example 37 (Granule wettable powder) Compound 9 10 parts Triadifram 20 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 56 parts After mixing and crushing uniformly, a small amount of water is added and mixed with stirring. And dried to obtain a preparation.
  • Formulation Example 38 (wettable powder) Compound 147 10 parts Isoxaben 18 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 67 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 40 Compound 147 1 part benzulide 30 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 46 parts Granulate and dry to obtain the formulation.
  • Formulation Example 41 (Granule wettable powder) Compound 147 10 parts Dithiopyr 20 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 56 parts After mixing and grinding uniformly, a small amount of water is added and stirred and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 42 Compound 1 1 part Diclobenil 7.5 parts Diuron 10 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 58.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 43 Compound 2 1 part Diclobenil 7.5 parts Diuron 10 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 58.5 parts After mixing and grinding uniformly, add a small amount of water and stir Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 44 Compound 9 1 part Diclobenil 7.5 parts Diuron 10 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 58.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 45 Compound 185 1 part Diclobenil 7.5 parts Diuron 10 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 58.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 46 Compound 1 1 part Bromobutide 9 parts Daimlon 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 62.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 47 Compound 2 1 part Bromobutide 9 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 62.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 48 Compound 9 1 part Bromobutide 9 parts Daimlon 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 62.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 49 Compound 147 1 part Bromobutide 9 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 62.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 50 Compound 185 1 part Bromobutide 9 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 62.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 51 (wettable powder) Compound 1 5 parts Diuron 24 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 66 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 53 Compound 1 1 part propanyl 17.5 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 58.5 parts Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 54 (Granule wettable powder) Compound 1 10 parts Linuron 50 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 26 parts After mixing and crushing uniformly, a small amount of water is added and mixed with stirring, and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 55 (wettable powder) Compound 2 10 parts Bromoxinyl 50 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 35 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 56 (Flowable) Compound 2 2 parts pyridate 1.6 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.4 parts Wet mill to obtain the formulation.
  • Formulation Example 57 Compound 2 1 part Cymetrin 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred and mixed. Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 58 (Granule wettable powder) Compound 2 10 parts Aioxynil 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 54 parts And dried to obtain a preparation.
  • Formulation Example 59 (wettable powder) Compound 9 5 parts Diuron 24 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 66 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 61 Compound 9 1 part propanyl 17.5 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 58.5 parts Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 62 (granular wettable powder) Compound 9 10 parts Linuron 50 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 26 parts After mixing and crushing uniformly, a small amount of water is added and stirred and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 63 (wettable powder) Compound 147 10 parts Bromoxinil 50 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 35 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 65 Compound 147 1 part Cymetrine 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.5 parts Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 66 (Granule wettable powder) Compound 147 10 parts Aioxynil 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 54 parts And dried to obtain a preparation.
  • Formulation Example 67 Compound 1 1 part Cymetrine 4.5 parts MCPB 0.24 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.26 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 68 (Granule) Compound 2 1 part Cymetrine 4.5 parts MCPB 0.24 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.26 parts After mixing and grinding uniformly, a small amount of water is added The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 69 Compound 9 1 part Cymetrine 4.5 parts MCPB 0.24 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.26 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 70 Compound 185 1 part Cymetrine 4.5 parts MCPB 0.24 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.26 parts After mixing and grinding uniformly, a small amount of water is added The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 71 Compound 1 1 part Bromoxinyl 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 72 Compound 2 1 part Bromoxinyl 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 73 Compound 9 1 part Bromoxinyl 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 74 (Granule) Compound 147 1 part Bromoxinyl 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 75 Compound 185 1 part Bromoxinyl 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 76 (wettable powder) Compound 1 10 parts flumioxazin 5 parts polyoxyethylene alkyl ether sulfate 5 parts clay 80 parts uniformly mixed and pulverized to obtain a preparation.
  • Formulation Example 77 (Flowable) Compound 1 2 parts carfentrazone ethyl 1.8 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.2 parts Are mixed and wet pulverized to obtain a preparation.
  • Formulation Example 78 (Granule) Compound 1 1 part Pyraclonil 2 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 74 parts Granulate and dry to obtain the formulation.
  • Formulation Example 79 (Granule wettable powder) Compound 1 20 parts Fruthiaset methyl 10 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 56 parts Granulate and dry to obtain the formulation.
  • Formulation Example 80 (wettable powder) Compound 2 10 parts Saflufenacil 7.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 77.5 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 82 Compound 2 1 part Lactofen 1 part Dialkyl sulfosuccinate ester 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 75 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 83 (Granule wettable powder) Compound 2 20 parts Butaphenacil 36 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 30 parts And dried to obtain a preparation.
  • Formulation Example 84 (wettable powder) Compound 9 10 parts Flumioxazin 5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 80 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 85 (Flowable) Compound 9 2 parts carfentrazone ethyl 1.8 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.2 parts Are mixed and wet pulverized to obtain a preparation.
  • Formulation Example 86 (Granule) Compound 9 1 part Pyraclonil 2 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 74 parts Granulate and dry to obtain the formulation.
  • Formulation Example 87 (Granule wettable powder) Compound 9 20 parts Fruthiaset methyl 10 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 56 parts After mixing and crushing uniformly, a small amount of water is added and mixed with stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 88 (wettable powder) Compound 147 10 parts Saflufenacyl 7.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 77.5 parts are uniformly mixed and ground to obtain a preparation.
  • Formulation Example 90 Compound 147 1 part Lactofen 1 part Dialkylsulfosuccinate 1 part Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 75 parts Granulate and dry to obtain the formulation.
  • Formulation Example 91 (Granule wettable powder) Compound 147 20 parts Butaphenacil 36 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 30 parts After mixing and crushing uniformly, a small amount of water is added and stirred and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 92 Compound 1 1 part Pyraclonil 1 part Bromobutide 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 93 (Granule) Compound 2 1 part Pyraclonil 1 part Bromobutide 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66 parts After mixing and grinding uniformly, a small amount of water is added to the mixture and stirred and extruded. Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 94 Compound 9 1 part Pyraclonil 1 part Bromobutide 9 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 95 Compound 185 1 part Pyraclonil 1 part Bromobutide 9 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 96 (Granule) Compound 1 1 part Pyraclonil 2 parts Daimron 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 69.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 97 Compound 2 1 part Pyraclonil 2 parts Daimron 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 69.5 parts After mixing and grinding uniformly, add a small amount of water and stir Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 98 Compound 9 1 part Pyraclonil 2 parts Daimron 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 69.5 parts Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 99 Compound 147 1 part Pyraclonil 2 parts Daimlon 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 69.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 100 Compound 185 1 part Pyraclonil 2 parts Diimron 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 69.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 101 (wettable powder) Compound 1 5 parts Mesotrione 2.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 87.5 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 102 (Flowable) Compound 1 2 parts isoxaflutol 1.5 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.5 parts Mix and wet mill to obtain the formulation.
  • Formulation Example 103 Compound 1 1 part Tefryltrione 3 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 73 parts After mixing and crushing uniformly, a small amount of water is added and stirred to mix Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 104 (Granule wettable powder) Compound 1 10 parts Beflubutamide 50 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 26 parts After mixing and crushing uniformly, a small amount of water is added and stirred and granulated with an extrusion granulator And dried to obtain a preparation.
  • Formulation Example 105 (wettable powder) Compound 2 10 parts Diflufenican 8 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 77 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 106 (Flowable) Compound 2 2 parts benzophenap 3.8 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 83.2 parts mixed And wet pulverized to obtain a preparation.
  • Formulation Example 107 (Granule) Compound 2 1 part Pyrazolate 30 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 46 parts Granulate and dry to obtain the formulation.
  • Formulation Example 108 (Granule wettable powder) Compound 2 10 parts Topramison 3.6 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligulin sulfonate 5 parts Clay 80.4 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 109 (wettable powder) Compound 9 5 parts Mesotrione 2.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 87.5 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 110 (Flowable) Compound 9 2 parts isoxaflutol 1.5 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.5 parts Mix and wet mill to obtain the formulation.
  • Formulation Example 111 Compound 9 1 part Tefryltrione 3 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 73 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 112 (Granule wettable powder) Compound 9 10 parts Beflubutamide 50 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 26 parts After mixing and crushing uniformly, a small amount of water is added and stirred and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 115 (Granule) Compound 147 1 part pyrazolate 30 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 46 parts Granulate and dry to obtain the formulation.
  • Formulation Example 116 (Granule wettable powder) Compound 147 10 parts Topramison 3.6 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligulin sulfonate 5 parts Clay 80.4 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, and extruded granulation. Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 117 Compound 1 1 part benzophenap 1.9 parts benzobicyclone 2 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 72.1 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 118 (Granule) Compound 2 1 part benzophenap 1.9 parts benzobicyclone 2 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 72.1 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 119 Compound 9 1 part benzophenap 1.9 parts benzobicyclone 2 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 72.1 parts Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 120 Compound 185 1 part benzophenap 1.9 parts benzobicyclone 2 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 72.1 parts Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 121 (Granule) Compound 1 1 part Tefryltrione 3 parts Daimlon 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 68.5 parts After mixing and grinding uniformly, add a small amount of water The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 122 (Granule) Compound 2 1 part Tefryltrione 3 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 68.5 parts After mixing and grinding uniformly, add a small amount of water The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 123 Compound 9 1 part Tefryltrione 3 parts Daimlon 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 68.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 124 (Granule) Compound 147 1 part Tefryltrione 3 parts Daimron 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 68.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 125 (Granule) Compound 185 1 part Tefryltrione 3 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 68.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 126 (wettable powder) Compound 1 5 parts alachlor 30 parts polyoxyethylene alkyl ether sulfate 5 parts clay 60 parts uniformly mixed and pulverized to obtain a preparation.
  • Formulation Example 127 (Flowable) Compound 1 2 parts S-metolachlor 10 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 77 parts Grind to obtain the formulation.
  • Formulation Example 128 Compound 1 1 part Butachlor 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 67 parts After uniformly mixing and pulverizing, a small amount of water is added and mixed by stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 129 (granular wettable powder) Compound 1 10 parts Dimethenamide-P 40 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 36 parts After mixing and crushing uniformly, a small amount of water is added and mixed with stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 130 (wettable powder) Compound 2 10 parts Flufenacet 50 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 35 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 132 (Granule) Compound 2 1 part Acetochlor 5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71 parts After uniformly mixing and pulverizing, a small amount of water is added and mixed with stirring, followed by extrusion granulation Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 133 (granular wettable powder) Compound 2 20 parts Indanophan 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 36 parts After mixing and crushing uniformly, a small amount of water is added and stirred and granulated using an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 134 (wettable powder) Compound 9 5 parts alachlor 30 parts polyoxyethylene alkyl ether sulfate 5 parts clay 60 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 135 (Flowable) Compound 9 2 parts S-metolachlor 10 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 77 parts Grind to obtain the formulation.
  • Formulation Example 136 (Granule) Compound 9 1 part Butachlor 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 67 parts Granulate and dry to obtain the formulation.
  • Formulation Example 137 (Granule wettable powder) Compound 9 10 parts Dimethenamide-P 40 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 36 parts After mixing and crushing uniformly, a small amount of water is added and mixed with stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 138 (wettable powder) Compound 147 10 parts Flufenacet 50 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 35 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 140 (Granule) Compound 147 1 part acetochlor 5 parts dialkyl sulfosuccinate ester 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 71 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 141 (Granule wettable powder) Compound 147 20 parts Indanophan 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 36 parts And dried to obtain a preparation.
  • Formulation Example 142 Compound 1 1 part S-metolachlor 5 parts croquintoset mexil 0.25 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 70.75 parts A small amount of water is added, mixed with stirring, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 143 Compound 2 1 part S-metolachlor 5 parts croquintoset mexil 0.25 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 70.75 parts A small amount of water is added, mixed with stirring, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 144 Compound 9 1 part S-metolachlor 5 parts croquintoset mexil 0.25 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 70.75 parts A small amount of water is added, mixed with stirring, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 145 Compound 185 1 part S-metolachlor 5 parts croquintoset mexil 0.25 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 70.75 parts A small amount of water is added, mixed with stirring, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 146 Compound 1 1 part F Caunule 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 147 (Granule) Compound 2 1 part F Cauntoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 148 Compound 9 1 part F Caunule 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 149 (Granule) Compound 147 1 part Flufenacet 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 150 Compound 185 1 part Flufenacet 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 151 (wettable powder) Compound 1 5 parts Quinchlorac 20 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 70 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 152 (Flowable) Compound 1 2 parts Triclopyr 2 parts Polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts Ethylene glycol 5 parts Silicone emulsion 0.5 parts Sorbic acid 0.5 parts Sodium montmorillonite 2 parts Water 85 parts A formulation is obtained.
  • Formulation Example 153 Compound 1 1 part Chlomeprop 4.5 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.5 parts Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 154 (Granular wettable powder) Compound 1 10 parts Diflufenzopyr 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 46 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, and an extrusion granulator Granulate and dry to obtain the formulation.
  • Formulation Example 155 (wettable powder) Compound 2 10 parts Dichloroprop 3 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 82 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 156 (Flowable) Compound 2 2 parts oxadichromephone 1.2 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.8 parts Wet mill to obtain the formulation.
  • Formulation Example 157 (granule) Compound 2 1 part 2,4-D amine salt 5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring And granulated with an extrusion granulator and dried to obtain a preparation.
  • Formulation Example 158 (granular wettable powder) Compound 2 20 parts MCPB 4.8 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 61.2 parts After mixing and crushing uniformly, a small amount of water is added and mixed with stirring, followed by extrusion granulation. Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 159 (wettable powder) Compound 9 5 parts Quinchlorac 20 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 70 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 161 Compound 9 1 part Chlomeprop 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.5 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring. Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 162 (Granule wettable powder) Compound 9 10 parts Diflufenzopyr 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 46 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, and an extrusion granulator Granulate and dry to obtain the formulation.
  • Formulation Example 163 (wettable powder) Compound 147 10 parts Dichloroprop 3 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 82 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 164 (Flowable) Compound 147 2 parts oxadichromephone 1.2 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.8 parts Wet mill to obtain the formulation.
  • Formulation Example 165 Compound 147 1 part 2,4-D amine salt 5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71 parts And granulated with an extrusion granulator and dried to obtain a preparation.
  • Formulation Example 166 (Granule wettable powder) Compound 147 20 parts MCPB 4.8 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 61.2 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, followed by extrusion granulation. Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 167 (Granule) Compound 1 1 part Chromprop 4.5 parts Imazosulfuron 0.9 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water is added The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 168 (Granule) Compound 2 1 part Chlomeprop 4.5 parts Imazosulfuron 0.9 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 169 (Granule) Compound 9 1 part Chlomeprop 4.5 parts Imazosulfuron 0.9 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 170 Compound 147 1 part Chromprop 4.5 parts Imazosulfuron 0.9 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water is added The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 171 Compound 185 1 part Chromprop 4.5 parts Imazosulfuron 0.9 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 172 (wettable powder) Compound 1 10 parts Metamihop 10 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 75 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 174 Compound 1 1 part Cyhalohop butyl 3 parts Dialkyl sulfosuccinate ester 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 73 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 175 (granular wettable powder) Compound 1 20 parts Fluazifop-P-butyl 24 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 42 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, followed by extrusion granulation Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 176 (wettable powder) Compound 2 10 parts Crodina hop propargyl 10 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 75 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 177 (Flowable) Compound 2 2 parts Phenoxaprop-P-ethyl 2 parts Polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts Ethylene glycol 5 parts Silicone emulsion 0.5 parts Sorbic acid 0.5 parts Sodium montmorillonite 2 parts Water 85 parts And wet pulverized to obtain a preparation.
  • Formulation Example 178 Compound 2 1 part Cyhalohop butyl 3 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 73 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 179 (granular wettable powder) Compound 2 20 parts fluazifop-P-butyl 24 parts polyoxyethylene alkyl ether sulfate 9 parts lignosulfonate 5 parts clay 42 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 180 (wettable powder) Compound 9 10 parts Metamihop 10 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 75 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 182 Compound 9 1 part Cyhalohop butyl 3 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 73 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 183 (Granule wettable powder) Compound 9 20 parts Fluazifop-P-butyl 24 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligline sulfonate 5 parts Clay 42 parts Granulate with a machine and dry to obtain a preparation.
  • Formulation Example 184 (wettable powder) Compound 147 10 parts Crodina hop propargyl 10 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 75 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 185 (Flowable) Compound 147 2 parts Phenoxaprop-P-ethyl 2 parts Polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts Ethylene glycol 5 parts Silicone emulsion 0.5 parts Sorbic acid 0.5 parts Sodium montmorillonite 2 parts Water 85 parts And wet pulverized to obtain a preparation.
  • Formulation Example 186 (granule) Compound 147 1 part Cyhalohop butyl 3 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 73 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 187 (granular wettable powder) Compound 147 20 parts Fully adihop-P-butyl 24 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligulin sulfonate 5 parts Clay 42 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring. Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 188 Compound 1 1 part Cyhalohop butyl 3 parts Penox slam 0.36 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding, a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 189 (Granule) Compound 2 1 part Cyhalohop butyl 3 parts Penox slum 0.36 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding, a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 190 (Granule) Compound 9 1 part Cyhalohop butyl 3 parts Penoxsulam 0.36 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 191 Compound 185 1 part Cyhalohop butyl 3 parts Penox slam 0.36 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding, a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 192 (Granule) Compound 1 1 part Cyhalohop butyl 3 parts Mesotrione 0.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding, a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 193 Compound 2 1 part Cyhalohop butyl 3 parts Mesotrione 0.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 194 Compound 9 1 part Cyhalohop butyl 3 parts Mesotrione 0.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 195 (Granule) Compound 147 1 part Cyhalohop butyl 3 parts Mesotrione 0.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding, a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 196 (Granule) Compound 185 1 part Cyhalohop butyl 3 parts Mesotrione 0.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 197 (wettable powder) Compound 1 5 parts Biaraphos 67.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 22.5 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 199 Compound 1 1 part Glyphosate ammonium 40 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 36 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 200 (Granule wettable powder) Compound 1 10 parts Endotal 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 46 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 201 (wettable powder) Compound 2 10 parts d-limonene 15 parts polyoxyethylene alkyl ether sulfate 5 parts clay 70 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 202 (Flowable) Compound 2 1 part Diquat dibromide 50 parts Polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts Ethylene glycol 5 parts Silicone emulsion 0.5 parts Sorbic acid 0.5 parts Sodium montmorillonite 2 parts Water 38 parts To obtain a formulation.
  • Formulation Example 203 Compound 2 1 part Pelargonic acid 25 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 51 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 204 (wettable powder) Compound 9 5 parts Biarafos 67.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 22.5 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 205 (Flowable) Compound 9 2 parts Glyphosate ammonium 60 parts Polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts Ethylene glycol 5 parts Silicone emulsion 0.5 parts Sorbic acid 0.5 parts Sodium montmorillonite 2 parts Water 27 parts Grind to obtain the formulation.
  • Formulation Example 206 Compound 9 1 part Glyphosate ammonium 40 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 36 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 207 (Granule wettable powder) Compound 9 10 parts End tar 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 46 parts After mixing and crushing uniformly, a small amount of water is added and stirred and mixed, and the mixture is made with an extrusion granulator. Granulate and dry to obtain the formulation.
  • Formulation Example 208 (wettable powder) Compound 147 10 parts d-limonene 15 parts polyoxyethylene alkyl ether sulfate 5 parts clay 70 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 210 Compound 147 1 part pelargonic acid 25 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 51 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 211 Compound 1 1 part Glyphosate ammonium 40 parts Flumioxazin 0.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 35.5 parts After mixing and grinding uniformly, a small amount of water is added The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 212 (Granule) Compound 2 1 part Glyphosate ammonium 40 parts Flumioxazin 0.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 35.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 213 Compound 9 1 part Glyphosate ammonium 40 parts Flumioxazin 0.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 35.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 214 (Granule) Compound 185 1 part Glyphosate ammonium 40 parts Flumioxazin 0.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 35.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Test Example 1 Field Cropping Soil Treatment Test A 1/6000 are pot was filled with field soil and seeded with seeds of Dingitaria ciriaris, Shiroza (Chenopodium album) and Agateanth (Amaranthus retroflexus). After the sowing and before the generation of weeds, the spraying solution of the herbicidal composition of the present invention was uniformly sprayed over the entire surface of the soil so as to have a predetermined dosage. The spray solution was prepared by diluting a predetermined amount of each compound, polyoxyethylene alkyl ether sulfate, and clay obtained by uniformly mixing and pulverizing them with water.
  • Test Example 2 Field crop foliage treatment test 1/6000 are pot filled with field soil, seeds of tiger beetle (Digitaria ciriaris), white crow (Chenopodium album), Agateanthus (Amaranthus retroflexus) are seeded and covered, glass room with an average temperature of 25 ° C Cultivated in At the time when the bark was grown at the leaf stage of 1.0 to 2.0, the entire plant was sprayed uniformly with the spray solution of the herbicidal composition of the present invention so as to have a predetermined dosage.
  • the spray solution was prepared by diluting a predetermined amount of each compound, polyoxyethylene alkyl ether sulfate, and clay obtained by uniformly mixing and pulverizing them with water. And after managing for 3 weeks in the glass room of average temperature 25 degreeC, those weeding effects were investigated. Evaluation of the herbicidal effect was performed in the same manner as in Test Example 1. The results are shown in Table 3.
  • Test Example 3 Paddy field weeding test 1 / 10,000 are pot filled with paddy soil, kneaded with appropriate amount of water and chemical fertilizer, seeded with Echinochloa oryzicola, Monochoria vaginalis, and firefly (Sirpus juncoides) seeds The submerged state was maintained at a depth of 3 cm.
  • the spray solution of the herbicidal composition of the present invention was dropped using a pipette so as to have a predetermined dosage.
  • the spray solution was prepared by diluting a predetermined amount of each compound, polyoxyethylene alkyl ether sulfate, and clay obtained by uniformly mixing and pulverizing them with water. And after managing for 30 days in the glass room of average temperature 30 degreeC, those weeding effects were investigated. Evaluation of the herbicidal effect was performed in the same manner as in Test Example 1. The results are shown in Table 4.
  • the herbicidal composition of the present invention is useful for controlling weeds.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
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Abstract

L'invention concerne une composition herbicide ayant une excellente action de lutte contre les mauvaises herbes. La composition herbicide est caractérisée en ce qu'elle contient un dérivé de pyrazolyl-pyrazole représenté par la formule (I) et au moins un type de composé choisi parmi des composés à action herbicide, en particulier des inhibiteurs d'ALS, des inhibiteurs de germination/croissance, des inhibiteurs de photosynthèse, des inhibiteurs de PPO, des agents induisant une chlorose, des inhibiteurs de VLCFA, des agents qui inhibent/perturbent l'action hormonale, des inhibiteurs de l'ACCase, et des herbicides non-sélectifs.
PCT/JP2016/052570 2015-01-30 2016-01-29 Composition herbicide WO2016121895A1 (fr)

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JP2015016904A JP6584079B2 (ja) 2015-01-30 2015-01-30 除草剤組成物

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021148304A1 (fr) * 2020-01-23 2021-07-29 Basf Se Formulations de ppo contenant des sulfates d'éther
WO2021151753A1 (fr) 2020-01-31 2021-08-05 Basf Se Associations d'herbicides comprenant du glufosinate et des inhibiteurs de ppo sélectionnés

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019089827A (ja) * 2019-02-13 2019-06-13 住友化学株式会社 除草剤組成物および雑草防除方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08506086A (ja) * 1992-10-12 1996-07-02 ヘキスト．シェーリング アーグレヴオ ゲゼルシャフト ミット ベシュレンクテル ハフツング 新規の置換ピラゾール誘導体、その製造法および該化合物の除草剤としての使用
JP2007186460A (ja) * 2006-01-13 2007-07-26 Bayer Cropscience Kk 水田用除草剤組成物
WO2008099889A1 (fr) * 2007-02-15 2008-08-21 Ishihara Sangyo Kaisha, Ltd. Composition herbicide
WO2015020156A1 (fr) * 2013-08-09 2015-02-12 協友アグリ株式会社 Dérivé pyrazolylpyrazole substitué et utilisation de celui-ci comme herbicide

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08506086A (ja) * 1992-10-12 1996-07-02 ヘキスト．シェーリング アーグレヴオ ゲゼルシャフト ミット ベシュレンクテル ハフツング 新規の置換ピラゾール誘導体、その製造法および該化合物の除草剤としての使用
JP2007186460A (ja) * 2006-01-13 2007-07-26 Bayer Cropscience Kk 水田用除草剤組成物
WO2008099889A1 (fr) * 2007-02-15 2008-08-21 Ishihara Sangyo Kaisha, Ltd. Composition herbicide
WO2015020156A1 (fr) * 2013-08-09 2015-02-12 協友アグリ株式会社 Dérivé pyrazolylpyrazole substitué et utilisation de celui-ci comme herbicide

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021148304A1 (fr) * 2020-01-23 2021-07-29 Basf Se Formulations de ppo contenant des sulfates d'éther
WO2021151753A1 (fr) 2020-01-31 2021-08-05 Basf Se Associations d'herbicides comprenant du glufosinate et des inhibiteurs de ppo sélectionnés

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