WO2016062482A1 - Agents de traitement capillaire contenant un copolymère en peigne i - Google Patents

Agents de traitement capillaire contenant un copolymère en peigne i Download PDF

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Publication number
WO2016062482A1
WO2016062482A1 PCT/EP2015/071720 EP2015071720W WO2016062482A1 WO 2016062482 A1 WO2016062482 A1 WO 2016062482A1 EP 2015071720 W EP2015071720 W EP 2015071720W WO 2016062482 A1 WO2016062482 A1 WO 2016062482A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair treatment
meth
alkyl
acrylate
hair
Prior art date
Application number
PCT/EP2015/071720
Other languages
German (de)
English (en)
Inventor
Volker Scheunemann
Erik Schulze Zur Wiesche
Sören SCHEELE
Original Assignee
Henkel Ag & Co. Kgaa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Ag & Co. Kgaa filed Critical Henkel Ag & Co. Kgaa
Publication of WO2016062482A1 publication Critical patent/WO2016062482A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87—Polyurethanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the present invention relates to hair treatment compositions containing a comb copolymer.
  • these include the so-called "2 in 1" shampoos, which not only cleanse the hair, but also condition it.
  • These products are highly appreciated by the consumer because of their product performance, at least one process step, for example, conditioning with a classical hair conditioner;
  • these products which clean and condition the hair at the same time, are not suitable for all hairs, especially fine hair is overconditioned by such products, for example, in one insufficient hairstyle structure with low volume, little hold and fullness of the hairstyle noticeable.
  • the object of the present invention is therefore to cleanse the hair on the one hand, to condition it sufficiently, in particular to provide improved combability of dry and wet hair, and yet to allow a good hairstyle structure with support, fullness and volume after washing.
  • a hair treatment agent containing a selected comb copolymer and a surfactant mixture of anionic and amphoteric / zwitterionic surfactants are dissolved.
  • This hair treatment agent cleanses the hair and leads to the improvement of the finish, in particular the wet and dry combability, to improve the gloss and to improve the moisture balance without negatively affecting the manageability in terms of volume, hold and fullness.
  • a first subject of the present invention is therefore a hair treatment composition containing - based on the weight of the total composition - a) 0.0001 to 1, 0 wt .-% of a comb copolymer containing
  • amphoteric / zwitterionic surfactants as well
  • Hair treatment agents are therefore hair shampoos, for example.
  • the hair treatment composition contains as component a) a selected comb copolymer.
  • Comb polymers contain on a linear main chain at more or less regular intervals longer, almost equally long side chains.
  • Z may be a linear, branched or cyclic alkyl or alkenyl group, an aryl group or an aralkyl group each having 8 to 50 carbon atoms, preferably 10 to 22
  • Carbon atoms and most preferably 10 to 18 carbon atoms.
  • Z is an alkyl group selected from the group consisting of octyl, nonyl, decyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, Eicosyl, Arachinyl and Behenyl. It is further preferred that the alkyl group of a
  • Z may also contain a mixture of different alkyl groups.
  • the alkyl groups are preferably derived from fatty alcohol mixtures, which are sold, for example, under the names Alfol® and Novel® (ex Sasol) or Unilin® (ex Baker Petrolite), in which the average
  • Chain length C25, C30, C40 or C50, or of alcohols from the coconut or other natural oils are examples.
  • R 1 may be hydrogen or a methyl group.
  • x, y and z can each have values between 0 and 50, where the sum of x, y and z is greater than 2. Repeating units of x, y, and z may be random, alternating, block, ascending, or descending. In preferred embodiments, y and z each assume the value 0 and x is correspondingly greater than 2. In a most preferred embodiment, y and z are each 0 and x assumes a value between 3 and 30.
  • Preferred structural units A) are stearylpoly (oxyethyl) [25] methacrylate,
  • the comb copolymer may contain one, two or more of said structural units A).
  • the structural unit B) of the comb copolymer is nonionic and is preferably selected from the group consisting of acrylamide, methacrylamide, N-methylacrylamide, N-methylmethacrylamide, ⁇ , ⁇ -dimethylacrylamide, N, N-dimethylmethacrylamide, ⁇ , ⁇ -diethylacrylamide, diacetoneacrylamide , ⁇ , ⁇ -dimethylaminopropylacrylamide, N-butoxymethylacrylamide, N-ethoxymethylacrylamide, N, N-butylacrylamide, N-ferric-butylacrylamide, N- / so-propylacrylamide, N-methylolacrylamide, N-methoxymethylacrylamide, N-ethylacrylamide, N- ( 3-methoxypropyl) acrylamide, Nn-propylacrylamide, N-Trimethylbutylacrylamid, N / 'so-octylacrylamide, N-acetylmethacrylamide, N-but
  • Vinylamides, styrene and p-alkylstyrenes Vinylamides, styrene and p-alkylstyrenes.
  • the comb copolymer may contain one, two or more of said nonionic repeating units B).
  • the structural unit C) of the comb copolymer is cationic and is preferably selected from the group consisting of ammonium salt-containing (meth) acrylates, the chloride of trimethylammoniumethyl methacrylate, methacrylamidopropyltrimethylammonium chloride, the chloride of trimethylammonium methylmethacrylate, the methylsulfate salt of
  • Methacrylamidopropyltrimethylammonium chloride used.
  • a suitable 2- (acryloyloxy) ethyl] trimethylammonium chloride is obtainable, for example, under the name Ageflex FA1 Q80MC 500 (ex BASF SE).
  • the comb copolymer may contain one, two or more of said cationic repeating units C).
  • the comb copolymer may contain further structural units, which may be anionic, zwitterionic and / or amphoteric.
  • further structural units include, for example, structural units with COOH groups such as
  • the comb copolymer may be crosslinked. In a particularly preferred embodiment, the comb copolymer is not crosslinked.
  • An especially preferred comb copolymer contains
  • the hair treatment composition contains a comb copolymer, which is available under the name Deposilk Q1 (ex Air Products) and is referred to in the INCI nomenclature as Polyquaternium-101.
  • the hair treatment compositions contain the comb copolymer in an amount of 0.0001 to 2.0 wt .-%, preferably from 0.001 to 0.5 wt .-%, most preferably from 0.05 to 0.3 wt% , in each case based on the weight of the ready-to-use hair treatment agent.
  • a second essential ingredient b) in the hair treatment compositions is a surfactant mixture of anionic and amphoteric / zwitterionic surfactants.
  • Suitable anionic surfactants are the hair treatment agents - based on their total weight - preferably in amounts of 0.1 to 30 wt .-%, more preferably from 1 to 20% by weight, particularly preferably from 2 to 17.5 wt .-% and in particular from 3 to 15 wt .-% added.
  • Suitable anionic surfactants which can be used in the hair treatment compositions include:
  • n 0 or 1 to 12 and X is an alkali or alkaline earth metal ion or protonated triethanolamine or
  • anionic surfactants are straight-chain or branched alkyl ether sulfates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 C atoms and 1 to 6 and in particular 2 to 4 ethylene oxide units.
  • the surfactant mixture contains anionic and amphoteric / zwitterionic surfactants
  • anionic surfactants are straight-chain or branched
  • Alkyl sulfonates containing an alkyl radical having 8 to 18 and in particular having 10 to 16 carbon atoms. Particular preference is given to the sodium, magnesium and / or triethanolamine salts of linear or branched lauryl, tridecyl and / or myristyl sulfates which have a degree of ethoxylation of from 2 to 4.
  • Suitable amphoteric / zwitterionic surfactants may in the hair treatment compositions - based on their total weight - preferably in amounts of from 0.1 to 25 wt .-%, more preferably from 0.25 to 20 wt .-%, particularly preferably from 0.5 to 15 , 0 and in particular from 1 to 10 wt .-% are added.
  • Suitable amphoteric / zwitterionic surfactants may be selected from compounds of the following formulas (i) to (v) in which the radical R is in each case straight-chain or straight-chain
  • amphoteric / zwitterionic surfactants include the surfactants cocamidopropyl betaine and disodium cocoamphodiacetate known under the INCI name.
  • hair-treatment compositions contain at least one anionic surfactant and at least one amphoteric / zwitterionic surfactant in a ratio of 6: 1 to 1: 1, preferably 5: 1 to 1: 5: 1 and especially from 4: 1 to 2: 1.
  • the total amount of anionic and amphoteric / zwitterionic surfactants, based on their total weight, is preferably 0.1 to 40.0% by weight in total, more preferably 1.0 to 35.0% by weight and more preferably 3.0 to 30.0% by weight.
  • the hair treatment composition further contains an aqueous carrier.
  • An aqueous carrier contains at least 50% by weight, preferably at least 60% by weight of water.
  • More preferred hair treatment agents are characterized as follows: 0.05 to 0.3% by weight of at least one comb copolymer and
  • suitable ingredients include nonionic surfactants, nonionic polymers, anionic polymers, other cationic polymers, fatty substances, waxes, protein hydrolysates, amino acids, oligopetides, vitamins, provitamins, vitamin precursors, betaines, biochinones,
  • Purines derivatives
  • taurine derivatives
  • plant extracts silicones, ester oils, ultraviolet light stabilizers, structurants, thickeners, electrolytes, pH modifiers, swelling agents, dyes, anti-dandruff agents, chelating agents, opacifiers, pearlescers, pigments,
  • Stabilizers for propellants, antioxidants, perfume oils and / or preservatives.
  • nonionic surfactants are nonionic surfactants.
  • Suitable nonionic surfactants may in the hair treatment compositions - based on their total weight - preferably in an amount of 0.05 to 10 wt .-%, more preferably from 0.1 to 7.5 wt .-%, particularly preferably from 0.2 to 5 wt .-% and in particular in an amount of 0.25 to 4 wt .-% are used.
  • the amount of nonionic surfactants does not count to the amount
  • nonionic surfactants are included in the hair treatment compositions in addition to the surfactant mixture of anionic and amphoteric / zwitterionic surfactants.
  • preferred nonionic surfactants include
  • Alkyloligoglucoside Alkyloligoglucoside.
  • alkyl oligoglucosides especially alkyl oligoglucosides based on hydrogenated C 12/14 coconut oil having a degree of oligomerization (DP) of 1 to 3, as described, for example, under the INCI name " Coco-glucosides "are commercially available.
  • DP degree of oligomerization
  • Another object of the invention is a method for hair treatment, in which a
  • Hair treatment composition according to claim 1 is applied to the hair and rinsed after a period of action of the hair.
  • the exposure time is preferably a few seconds to 100 minutes, more preferably 1 to 50 minutes and most preferably 1 to 5 minutes.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des agents de traitement capillaire contenant un copolymère en peigne sélectionné, un mélange de tensioactifs constitué de tensioactifs amphotères/zwitterioniques, et un support aqueux. Ce copolymère en peigne contient une unité structurale A) de formule (I) dans laquelle R1 désigne H ou CH3; x est compris entre 0 et 50, y est compris entre 0 et 50; z est compris entre 0 et 50, la somme x+y+z est supérieure à 2, et Z désigne alkyle, alcényle, aryle ou aralkyle; une unité structurale non ionique B) et une unité structurale cationique C). Cet agent de traitement capillaire sert au lavage et au soin de cheveux humains.
PCT/EP2015/071720 2014-10-22 2015-09-22 Agents de traitement capillaire contenant un copolymère en peigne i WO2016062482A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102014221402.5A DE102014221402A1 (de) 2014-10-22 2014-10-22 Haarbehandlungsmittel enthaltend ein Kamm-Copolymer I
DE102014221402.5 2014-10-22

Publications (1)

Publication Number Publication Date
WO2016062482A1 true WO2016062482A1 (fr) 2016-04-28

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Application Number Title Priority Date Filing Date
PCT/EP2015/071720 WO2016062482A1 (fr) 2014-10-22 2015-09-22 Agents de traitement capillaire contenant un copolymère en peigne i

Country Status (2)

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DE (1) DE102014221402A1 (fr)
WO (1) WO2016062482A1 (fr)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120251474A1 (en) * 2011-03-28 2012-10-04 Coatex S.A.S. Comb polymers for the hair
WO2013089720A1 (fr) * 2011-12-15 2013-06-20 Colgate-Palmolive Company Compositions nettoyantes au polyuréthane-34

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120251474A1 (en) * 2011-03-28 2012-10-04 Coatex S.A.S. Comb polymers for the hair
WO2013089720A1 (fr) * 2011-12-15 2013-06-20 Colgate-Palmolive Company Compositions nettoyantes au polyuréthane-34

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
"Deposilk Q1 Polymer Quick Start Guide", 1 January 2012 (2012-01-01), XP055226106, Retrieved from the Internet <URL:http://www.airproducts.com/microsite/deposilk/deposilk-Q1-quick-start-guide.pdf> [retrieved on 20151105] *
"Enlivened Facial Cleansing with Deposilk Q1 Polymer", IP.COM JOURNAL, IP.COM INC., WEST HENRIETTA, NY, US, 18 May 2011 (2011-05-18), XP013161496, ISSN: 1533-0001 *
"Surfactant Base Formulation with DeposilkTM Q Series Polymers", 12 December 2013 (2013-12-12), São Paulo, XP055226099, Retrieved from the Internet <URL:http://www.airproducts.com/~/media/downloads/d/deposilk-q1/guide/Deposilk-B002-Formulating-Guide-165-11-007-GLB.pdf?tradeName=Deposilk-Q1&D> [retrieved on 20151105] *
DEPOSILK: "Deposilk (TM) Q1 Polymer INCI: Polyquaternium-101", 1 January 2012 (2012-01-01), XP055226116, Retrieved from the Internet <URL:http://www.airproducts.de/~/media/downloads/d/deposilk-q1/data-sheets/en-deposilk-q1-datasheet-165-11-011-GLB-Jan12.pdf?tradeName=Deposilk-Q1&D> [retrieved on 20151105] *

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