WO2016058812A3 - Lithium-schwefel-akkumulator - Google Patents

Lithium-schwefel-akkumulator Download PDF

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Publication number
WO2016058812A3
WO2016058812A3 PCT/EP2015/072203 EP2015072203W WO2016058812A3 WO 2016058812 A3 WO2016058812 A3 WO 2016058812A3 EP 2015072203 W EP2015072203 W EP 2015072203W WO 2016058812 A3 WO2016058812 A3 WO 2016058812A3
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WO
WIPO (PCT)
Prior art keywords
lithium
sulphur
accumulator
sulphur accumulator
cathode
Prior art date
Application number
PCT/EP2015/072203
Other languages
English (en)
French (fr)
Other versions
WO2016058812A2 (de
Inventor
Simon LUX
Philipp OBERHUMER
Barbara Stiaszny
Ann-Christin GENTSCHEV
Jakub REITER
Original Assignee
Bayerische Motoren Werke Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayerische Motoren Werke Aktiengesellschaft filed Critical Bayerische Motoren Werke Aktiengesellschaft
Priority to CN201580051270.8A priority Critical patent/CN106688122B/zh
Publication of WO2016058812A2 publication Critical patent/WO2016058812A2/de
Publication of WO2016058812A3 publication Critical patent/WO2016058812A3/de
Priority to US15/488,048 priority patent/US10658668B2/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/628—Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

Die Erfindung betrifft einen Lithium-Schwefel-Akkumulator (1), umfassend einen Lithium-Ionen enthaltenden Elektrolyten (2), eine Anode (3) und eine Schwefel enthaltende Kathode (4). Der erfindungsgemäße Lithium-Schwefel-Akkumulator umfasst außerdem eine Oberflächenschicht (5), die zwischen Anode (3) und Kathode (4) angeordnet ist. Der Lithium-Schwefel- Akkumulator (1) umfasst zudem kathodenseitig Bereiche, die Polysulfide aufweisen. Die Oberflächenschicht (5) des Lithium-Schwefel-Akkumulators umfasst zumindest eine Graphen- Schicht, die durchlässig für Lithium-Ionen und nicht durchlässig für Polysulfide ist.
PCT/EP2015/072203 2014-10-16 2015-09-28 Lithium-schwefel-akkumulator WO2016058812A2 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201580051270.8A CN106688122B (zh) 2014-10-16 2015-09-28 锂硫蓄电池
US15/488,048 US10658668B2 (en) 2014-10-16 2017-04-14 Lithium-sulfur accumulator

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102014221046.1 2014-10-16
DE102014221046.1A DE102014221046A1 (de) 2014-10-16 2014-10-16 Lithium-Schwefel-Akkumulator

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US15/488,048 Continuation US10658668B2 (en) 2014-10-16 2017-04-14 Lithium-sulfur accumulator

Publications (2)

Publication Number Publication Date
WO2016058812A2 WO2016058812A2 (de) 2016-04-21
WO2016058812A3 true WO2016058812A3 (de) 2016-07-21

Family

ID=54199661

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2015/072203 WO2016058812A2 (de) 2014-10-16 2015-09-28 Lithium-schwefel-akkumulator

Country Status (4)

Country Link
US (1) US10658668B2 (de)
CN (1) CN106688122B (de)
DE (1) DE102014221046A1 (de)
WO (1) WO2016058812A2 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101930130B1 (ko) * 2016-06-10 2018-12-17 한양대학교 산학협력단 질소가 도핑된 탄소를 함유하는 양극 활물질층 및 보호막을 구비하는 금속-황 전지용 양극, 이의 제조방법
EP3712988A4 (de) * 2017-11-16 2020-12-02 LG Chem, Ltd. Schwefel-kohlenstoff-verbundmaterial, herstellungsverfahren dafür und lithium-sekundärbatterie damit
DE102018200973A1 (de) 2018-01-23 2019-07-25 Robert Bosch Gmbh Festelektrolyt-Flüssigelektrolyt-Hybrid-Zelle
KR20220019408A (ko) * 2020-08-10 2022-02-17 주식회사 엘지에너지솔루션 리튬 이차전지용 양극 코팅재, 이의 제조방법, 상기 코팅재를 포함하는 양극 및 리튬 이차전지

Citations (3)

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US20130309571A1 (en) * 2012-05-16 2013-11-21 Industry-University Cooperation Foundation Hanyang University Negative electrode for lithium battery, lithium battery including the same, and methods of manufacture thereof
CN103950239A (zh) * 2014-04-24 2014-07-30 合肥国轩高科动力能源股份公司 化学电源用多功能复合膜
CN103972467A (zh) * 2013-02-06 2014-08-06 中国科学院金属研究所 一种锂硫电池多层复合正极及其制备方法

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JP2004179160A (ja) 2002-11-26 2004-06-24 Samsung Sdi Co Ltd リチウム−硫黄電池用正極
US8753772B2 (en) * 2010-10-07 2014-06-17 Battelle Memorial Institute Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes
US8889298B2 (en) * 2011-08-30 2014-11-18 Nanotek Instruments, Inc. Surface-mediated lithium ion-exchanging energy storage device
WO2013028826A2 (en) 2011-08-25 2013-02-28 Wisconsin Alumni Research Foundation Barrier guided growth of microstructured and nanostructured graphene and graphite
WO2013049663A1 (en) * 2011-09-30 2013-04-04 The Regents Of The University Of California Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells
CN102683659A (zh) 2012-05-31 2012-09-19 中国科学院物理研究所 一种锂-硫电池正极材料及其制备方法
KR20150045484A (ko) * 2012-08-17 2015-04-28 더 보드 오브 리전츠 오브 더 유니버시티 오브 텍사스 시스템 리튬-황 배터리용 다공성 카본 간층
DE102013209982B4 (de) * 2013-05-28 2023-02-16 Technische Universität Dresden Alkalimetall-Schwefel-Batterie sowie Verfahren zu deren Betreibung
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Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130309571A1 (en) * 2012-05-16 2013-11-21 Industry-University Cooperation Foundation Hanyang University Negative electrode for lithium battery, lithium battery including the same, and methods of manufacture thereof
CN103972467A (zh) * 2013-02-06 2014-08-06 中国科学院金属研究所 一种锂硫电池多层复合正极及其制备方法
CN103950239A (zh) * 2014-04-24 2014-07-30 合肥国轩高科动力能源股份公司 化学电源用多功能复合膜

Also Published As

Publication number Publication date
WO2016058812A2 (de) 2016-04-21
CN106688122A (zh) 2017-05-17
DE102014221046A1 (de) 2016-05-19
US10658668B2 (en) 2020-05-19
CN106688122B (zh) 2020-06-05
US20170222227A1 (en) 2017-08-03

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