WO2016032357A1 - Catalyseur pour la conversion de dioxyde de carbone de gaz naturel - Google Patents

Catalyseur pour la conversion de dioxyde de carbone de gaz naturel Download PDF

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WO2016032357A1
WO2016032357A1 PCT/RU2014/000638 RU2014000638W WO2016032357A1 WO 2016032357 A1 WO2016032357 A1 WO 2016032357A1 RU 2014000638 W RU2014000638 W RU 2014000638W WO 2016032357 A1 WO2016032357 A1 WO 2016032357A1
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oxide
catalyst
perovskite
fluorite
carbon dioxide
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PCT/RU2014/000638
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Russian (ru)
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Наталья Васильевна МЕЗЕНЦЕВА
Владислав Александрович САДЫКОВ
Светлана Николаевна ПАВЛОВА
Захар Юрьевич ВОСТРИКОВ
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Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук
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Priority to PCT/RU2014/000638 priority Critical patent/WO2016032357A1/fr
Publication of WO2016032357A1 publication Critical patent/WO2016032357A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B1/00—Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Definitions

  • the invention relates to the field of development and production of catalysts and can be used in the chemical industry for the process of carbon dioxide conversion of natural gas and / or methane in order to produce synthesis gas in a wide temperature range and high feed rates of reagents.
  • PCM ⁇ Methane steam reforming
  • Carbon dioxide methane conversion with C0 2 is an alternative route for producing synthesis gas with obvious advantages, such as the ratio of H 2 / CO in the synthesis gas is 1: 1. So, in the process of the MSN is possible to adjust the ratio of H 2 / CO, as for Different applications require different H 2 / CO ratios. This is achieved by combining the UKM reaction with steam reforming or with partial oxidation of methane. Finally, one can consider UKM as a “green” process, since the greenhouse gas CO2 is consumed in the process. The UKM process was first studied Fisher and Tropsch in 1928 on metal catalysts [1], and recent studies of this reaction have revealed a number of typical UKM catalysts containing Fe [2], Co [3], Ni [4]. The results of numerous studies have shown that noble metal catalysts exhibit higher activity and are less prone to carbonization.
  • the CCM reaction is an endothermic process and the combination with the PCM endothermic process is more energy efficient.
  • the stoichiometric reaction of methane and carbon dioxide with the participation of group VIII transition metals at a temperature of 780 ° C and atmospheric pressure provides synthesis gas selectivity of about 90%, with a methane and carbon dioxide conversion of more than 85% [5].
  • These mixed ion-electron conductive materials include ceramic additives, such as doped cerium oxides or perovskite-like oxides such as doped LaCr0 3 and SrTi0 3 [6].
  • ceramic additives such as doped cerium oxides or perovskite-like oxides such as doped LaCr0 3 and SrTi0 3 [6].
  • Cerium oxide doped with trivalent rare earths oxides (Gd 2 0 3 , Sm 2 0 3 , and Y 2 0 3 ) is a mixed ion-electron material that has an ionic conductivity of about 10 times higher than that of YSZ.
  • the ability to store oxygen and migrate into the volume of cerium oxide can also increase the oxidation of hydrocarbons.
  • these materials have good electrocatalytic activity and the ability to suppress the formation of carbon.
  • the performance of the catalyst can be improved by the addition of metals such as Ni.
  • metals such as Ni.
  • materials based on doped Ni-Gd and Ru-Ni-Gd cerium oxide were studied for direct electrochemical oxidation of hydrocarbon fuels.
  • the promotion of platinum group metals increases the activity of the catalysts in the steam and carbon dioxide fuel conversions.
  • Nickel deposited on cermets from perovskite-like oxides such as La-Sr-Mn-CrO 3 , La-Pr-Mn-CrO3 and La-Sr-Ti0 3 were also investigated in the oxidative conversion of methane.
  • Ni particles dispersed in cerium-zirconium-based mixed fluorite-like oxides doped with rare-earth elements (Sm, Pr, Gd, La), as well as primoscite-like oxides (AB0 3 ) are the main materials presented in this work. According to the literature, the addition of Zr0 2 , Zr-Y-0 2 , Ce-Gd-0 2 , A1 2 0 3 increases the thermal stability and specific surface area of the oxides, especially under reducing conditions. Nickel particles and small additions of platinum group metals should activate fuel molecules, and rare-earth elements in the composition of the oxides should increase the oxygen mobility of the catalyst.
  • the closest to the claimed technical essence and the achieved effect is a catalyst for the process of carbon dioxide conversion of methane [RU 2453366, 20.06.2012].
  • the catalyst is a carrier based on a complex mixed oxide containing at least 3 metals, based on cerium-zirconium doped with rare-earth metals coated with an active component of Ni and / or La and / or platinum group metals (Pt, Ru).
  • a and / or B are selected from metals of rare earth elements Pr, La, Sm.
  • Mi - choose from metals of the platinum group - Pt or Ru, with a content of from 0 to 1.4 wt.%
  • M 2 is nickel with a content of from 0 to 1, 9 to 6.6 wt.%
  • M 3 is La with a content from May 0 to 4.7. %
  • the technical result consists in the high activity and stability of the inventive catalysts, which allow the process of carbon dioxide conversion of methane, including natural gas, at higher loads up to 540,000 h "1 (with shorter contact times up to 0.015 s).
  • the invention solves the problem of creating a stabilized bulk catalyst for the process of producing synthesis gas by carbon dioxide conversion of methane, including as an active component for a structured catalyst of carbon dioxide natural gas, capable of working in real mixtures and with short contact times.
  • the problem is solved by creating a highly efficient and stable catalyst capable of working at short contact times (at high volumetric feed rates) in the process of producing synthesis gas by carrying out the reaction of carbon dioxide conversion of methane or carbon dioxide conversion of natural gas with a wide variation of process parameters (mixture composition, temperature, loads )
  • the catalyst for producing synthesis gas in the process of carbon dioxide conversion of natural gas which is a nanocomposite Ni-containing material, characterized in that it consists of oxide with A perovskite-like or fluorite-like structure with high oxygen mobility, platinum metals, nickel Ni and an oxide additive having a high specific surface area and / or good thermal stability, the composition of the catalyst has the following general formula:
  • Me is a platinum group metal
  • JO is an oxide additive having high dispersion and / or good thermal stability and / or high oxygen mobility
  • Ni is an active component. which can be introduced into the volume of a perovskite-like or fluorite-like oxide at the stage of synthesis, when a polymer oxide precursor is formed or can be represented in the nanocomposite catalyst as an individual Ni or NiO phase deposited by impregnation or other method.
  • the content in the catalyst of the active component of Nickel is from 1 to 60 wt.%.
  • the metal content of the platinum group of Pt and / or Ru is from 0 to 5 wt.%.
  • the catalyst contains perovskite-like or fluorite-like oxide with high oxygen mobility; in an amount of from 10 to 95 wt.%.
  • the catalyst can be used as an active component for the manufacture of structured catalysts on heat-conducting media with a catalyst content until May 10. %
  • Ln x Ln i, x M y Nii -y 0 3 5 in the catalyst varies from 60 to 95 May. %, and JO from 5 to 88 wt. %, respectively.
  • JO is A1 2 0 3 or Ce x Gd ,. x 0 2 (GDC) or Zr y Yi -y 0 2 (YSZ).
  • Crystalline hydrates of nitrates La, Fe, Ni, Pr, Sm, Ce, Gd, and RuOHCl 3 were used as initial raw materials.
  • Perovskite was synthesized by the Pekini method using metal nitrates (Me), RuOHCl 3 taken in the appropriate ratios, citric acid (LA), ethylene glycol (EG) and ethylene diamine (ED) as reagents.
  • the molar ratio of the reagents LC: EG: ED: ⁇ is 3.75: 1 1.25: 3.75: 1.
  • Citric acid and metal nitrates were dissolved at 80 ° C in distilled water, respectively.
  • the prepared solutions were combined together with stirring, followed by the addition of ED.
  • the prepared solution was stirred for 60 min and then heated at 70 ° C for 24 h, allowing the gel to form.
  • the gel was calcined in the range of 600 - 900 ° C for 2 hours, followed by obtaining a solid.
  • Catalysts were prepared using GDC powder or
  • the powders were subjected to ultrasonic dispersion using an Ika T25 ULTRA-TURRAX basic installation (IKA, Germany) with the addition of polyvinyl butyral as a surfactant, followed by drying and sintering in air in temperature range 700 - 900 ° ⁇ .
  • the catalysts could be prepared by impregnating the moisture content of the powder of the oxide additive GDC or A1 2 0 3 with an aqueous solution of the salts of the corresponding oxide Ln ' x Ln 2 i. xM y Nii -y 03.s, followed by drying and calcination in air in the temperature range 600 - 900 ° ⁇ .
  • Table 1 presents the test results of the nanocomposite catalyst in real mixtures in the reaction of carbon dioxide conversion of natural gas.
  • the content of fluorite-like oxide Ln ' x Ln iCeyZi iC in the catalyst varies from 10 to 95 wt.%, Ni - from 2 to 60 wt.% And YSZ from 2 to 60 may. %
  • aqueous nitrate solutions (Y, Sm, Ce, La, Gd, Pr), an aqueous solution of zirconium oxychloride, citric acid (LA), ethylene glycol (EG), and ethylene diamine (ED) were used.
  • the optimal molar ratio of reagents used for the preparation of the gel is LK: EG: ED: E e this is 3.75: 1 1.25: 3.75: 1.
  • Citric acid was dissolved in ethylene glycol at 60 ° C. Then, aqueous salts of metal nitrates were added to the solution of LA and EG in the required ratio - Y (N0 3 ) 2 .nH 2 0, Ce (N0 3 ) 3 nH 2 0, Pr (N0 3 ) 3 nH 2 0, Sm (N0 3 ) 3 nH 2 0 dissolved in a small amount of disilitated water, followed by the addition of ZrOCl 2 . ED was added to the solution at room temperature to give a gel after stirring.
  • YSZ the resulting gel containing yttrium and zirconium salts was heated at 100 ° C to remove traces of water. This gel was subsequently calcined in air in the temperature range 300-800 ° C for 1-5 hours to obtain a fine powder of YSZ powder.
  • YSZ powder and NiO powder were then added to the polymer precursor, Lnl x Ln2 x .iCeo gel. 3 5Zro. 3 50 2 . Then the mixture was heated at a temperature of 100 ° C to remove traces of water. This gel was subsequently calcined in air in the temperature range 300-800 ° C for 1-5 hours to obtain a powder.
  • Pt and / or Ru were applied by moisture absorption to a powder (Ln ' x Ln 2 x- iCe y Zr y-1 0 2 + YSZ) from H 2 PtCl 6 and / or Ru (OH) Cl 3 solutions with appropriate concentrations followed by drying and calcining for 1 h at 800 or 900 ° C.
  • Table 4 presents the results of catalytic experiments on CM in real conditions with natural gas.
  • the conditions of the catalytic tests in real conditions with natural gas were the same as in example 1.
  • Table 5 presents the results of UKM at different temperatures, the yield of synthesis gas (H 2 + CO), the ratio of the target products of H 2 / CO for 1% Ru / NiO + YSZ + SmPrCeZrO.
  • Nanocomposite catalysts provide a high yield of synthesis gas in the carbon dioxide conversion of real natural gas with a content of up to 6% of a mixture of C 2 -C 4 alkanes (table 7).
  • Nanocomposite catalysts were investigated in UKM as structured catalysts on thermally conductive carriers.
  • various types of heat-conducting media fechral foil or mesh protected by a corundum layer; Ni-Al porous plates; SiC / Al-Si-0 foams; Fechral microchannel plates protected by a layer of corundum.
  • the nanocomposite active component (content until May 10,%) was deposited on a structured heat-conducting carrier by applying layers of a suspension in isopropanol with polyvinyl butyral followed by drying and calcination in air in the temperature range 700 - 900 ° ⁇ for 2 hours.
  • Platinum group metals and / or Ni was deposited on a structured catalyst by impregnation followed by drying and calcination in the temperature range of 700 - 900 ° C.
  • Table 9 presents the results of long-term experiments on a UKM structured catalyst with a nanocomposite active component l% Ru + 99% (80% Lao .5 Pr 0.5 Mno .2 Cr 0.8 0 3 + 10% YSZ + 10% NiO). table 9.

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Abstract

L'invention se rapporte au domaine de de l'élaboration et de la production de catalyseurs, et peut être utilisée dans l'industrie chimique dans un processus de conversion de dioxyde de carbone de gaz naturel et/ou de méthane afin de produire un gaz de synthèse dans une grande plage de température et à des vitesses d'alimentation élevées en réactifs. L'invention concerne un catalyseur comprenant un matériau nano-composite contenant du Ni qui se compose d'un oxyde ayant une structure de type pérovskite ou fluorite avec une mobilité élevée de l'oxygène, de métaux à base de platine, de nickel et d'un additif oxyde ayant une surface spécifique élevée et/ou une bonne stabilité thermique. Ce catalyseur peut être utilisé en qualité de composant actif lors de l'application sur un support conducteur de chaleur de type divers (feuille ou maillage de FeCrAl, supports poreux à base de nickel et d'aluminium ou de carbure de silicium, plaques à micro-canaux et autres). Le résultat technique consiste en une grande activité et une grande stabilité des catalyseurs qui permettent d'effectuer un processus de conversion de dioxyde de carbone de méthane, y compris de gaz naturel, à des charges plus élevées allant jusqu'à 540000 h-1 (avec des temps de contact plus courts allant jusqu'à 0,015 s).
PCT/RU2014/000638 2014-08-26 2014-08-26 Catalyseur pour la conversion de dioxyde de carbone de gaz naturel WO2016032357A1 (fr)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019009754A1 (fr) * 2017-07-07 2019-01-10 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Procédé de préparation d'un catalyseur destiné à la conversion carbonique du méthane
US20230050019A1 (en) * 2021-08-12 2023-02-16 Saudi Arabian Oil Company Dry reforming of methane using a nickel-based bi-metallic catalyst

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100168257A1 (en) * 2007-03-13 2010-07-01 Matthias Duisberg Metal-doped nickel oxides as catalysts for the methanation of carbon monoxide
RU2453366C1 (ru) * 2010-11-29 2012-06-20 Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН Катализатор и способ получения синтез-газа

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100168257A1 (en) * 2007-03-13 2010-07-01 Matthias Duisberg Metal-doped nickel oxides as catalysts for the methanation of carbon monoxide
RU2453366C1 (ru) * 2010-11-29 2012-06-20 Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН Катализатор и способ получения синтез-газа

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Title
GUBANOVA E.L. ET AL.: "Vliyanie podvizhnosti kisloroda slozhnogo oksidnogo nositeliya na mekhanizm partsialnogo okislenia metana", ROP. KHIM. ZH., vol. LII, no. 1, 2008, pages 21 - 31 *
KAPOKOVA L.G. ET AL.: "Perovskity nFeO.7NiO.303-b i nanokompozity na ikh osnove-predshestvenniki perspektivnykh katalizatorov uglekislotnoi konversii metana.", VSEROSSYSKAYA KONFERENTSIA S MEZHDUNARODNYM UCHASTIEM TVERDOOKSIDNYE TOPLIVNYE ELEMENTY I ENERAOUSTANOVKI NA IKH OSNOVE., 2010, CHernoaolovka., pages 23 - 24 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019009754A1 (fr) * 2017-07-07 2019-01-10 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Procédé de préparation d'un catalyseur destiné à la conversion carbonique du méthane
US20230050019A1 (en) * 2021-08-12 2023-02-16 Saudi Arabian Oil Company Dry reforming of methane using a nickel-based bi-metallic catalyst

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