WO2015196326A1 - Neutral density filter having multiple film layers, manufacturing device thereof and manufacturing method therefor - Google Patents

Neutral density filter having multiple film layers, manufacturing device thereof and manufacturing method therefor Download PDF

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Publication number
WO2015196326A1
WO2015196326A1 PCT/CN2014/080488 CN2014080488W WO2015196326A1 WO 2015196326 A1 WO2015196326 A1 WO 2015196326A1 CN 2014080488 W CN2014080488 W CN 2014080488W WO 2015196326 A1 WO2015196326 A1 WO 2015196326A1
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Prior art keywords
film
vacuum chamber
manufacturing
filter
multilayer film
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PCT/CN2014/080488
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French (fr)
Chinese (zh)
Inventor
孙义昌
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孙义昌
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Priority to PCT/CN2014/080488 priority Critical patent/WO2015196326A1/en
Publication of WO2015196326A1 publication Critical patent/WO2015196326A1/en

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters

Definitions

  • Neutral gray-scale dimming filter of multilayer film layer manufacturing device thereof and manufacturing method thereof
  • the present invention relates to a neutral grayscale dimming filter, and more particularly to a medium gray fixed value dimming filter and a medium gray gradient dimming filter and a manufacturing apparatus therefor. Background technique
  • the neutral gray filter is an energy splitting element that balances light attenuation. It is mainly used to filter light during photographic photography. It has the advantages of simple structure and wide wavelength range.
  • the neutral gray filter includes a Neutral Density Filter (ND Mirror) and a graduated Neutral Density Filter (Journey Neutral Density Filter).
  • the ND mirror is mainly used to reduce the amount of exposure of the camera. When the subject is bright, the D mirror is required to reduce the exposure.
  • the ND mirror filter is non-selective to the light.
  • the ND mirror is equally and uniform in reducing the light of different wavelengths. It only acts to attenuate the light and has no effect on the color of the original object.
  • the optical density does not change with position, and the overall part is uniform.
  • the optical density of the GND mirror varies with position and has different darkness variations, ie different optical densities.
  • the GND mirror does not change the color balance of the picture, but it can change the contrast of the light.
  • FIG. 1 is a schematic view showing a transmittance spectrum curve of a GND mirror manufactured by a resin dyeing method, a glass lamination method, and a medium gray glass bonding method in the prior art. As shown in FIG.
  • curve 1 represents a light transmittance spectrum curve of a GND mirror manufactured by a resin dyeing method, and resin dyeing is required to be deformed in a high-temperature liquid during the dyeing process and the resin lens itself is easily deformed, thereby causing deformation of the resin sheet, thereby It is difficult to achieve high definition images that affect the imaging quality of photographic cameras.
  • the light cannot be balanced and attenuated. It can be seen from the spectrum that the transmittance has increased significantly since the wavelength of 650 nm, which is the main cause of redness in photography.
  • Curve 2 represents the transmittance spectrum curve of the GND mirror manufactured by the glass lamination method, and the glass clip film is composed of two pieces of glass intermediate clips, and has a disadvantage of having a large thickness in addition to the above disadvantages of resin dyeing.
  • Curve 3 represents the middle gray glass glue
  • FIG. 2a is a schematic view showing a transmittance spectrum curve of a GND mirror manufactured by a vacuum neutral metal film method in the prior art.
  • Fig. 2b is a schematic view showing a reflectance spectrum curve of a GND mirror manufactured by a vacuum neutral metal film method in the prior art.
  • curve 1 represents the transmittance spectrum curve
  • Fig. 2b curve 1 represents the reflectance spectrum curve
  • the vacuum neutral metal film process better solves the problem of affecting imaging quality and is ideal.
  • the light balance attenuation function because of the high reflectivity, it is easy to produce ghosts during use. Summary of the invention
  • the technical problem to be solved by the present invention is to provide a neutral gray-scale dimming filter of a multilayer film layer and a manufacturing method thereof, which can produce an ND mirror and a GND mirror with good light balance attenuation effect and low reflectivity. At the same time, the manufacturing process does not affect the image quality.
  • the present invention provides a neutral grayscale dimming filter of a multilayer film layer and a method of fabricating the same, comprising a substrate, the substrate being plated with a plurality of film layers, the film layer comprising a laminate
  • the antireflection film and the metal film, the constituent material of the antireflection film has a refractive index of more than 1.30.
  • the constituent material of the anti-reflection film comprises at least one selected from the group consisting of A1 2 0 3 , A1F 3 , BeO, CaF 2 , CeF 3 , CeO 3 , Cr 2 0 3 , Dy 2 0 3 , Gd 2 0 3 , Hf0 2 , Ho 2 0 3 , ln 2 0 3 , : LaF 3 , MgF 2 , MgO, NiO, Nd 2 0 3 , Sn0 3, SiO, Si0 2, Sm 2 0 3, Ti0 2, Ta 2 0 5, Thi0 2, compound or a mixture composed of the compound of Zr0 2.
  • the constituent material of the metal film includes at least one metal element selected from the group consisting of Al, Ag, Cr, Ni, Au, Cu, Fe, Zn, Sn, Mo or an alloy composed of the above-mentioned metal element.
  • the substrate is plated with at least two layers of the film layer.
  • the optical thickness of the film of the anti-reflection film ranges from 1 to 300 nm, and the optical thickness of the film of the metal film ranges from 1 to 320 nm.
  • the reflectance ranges from 1.50% to 2.30% in the wavelength range of 420 to 680 nm, and the transmittance ranges from 47.8% to 51.3%.
  • the range of the reflectance at the maximum end of the attenuation is 2.5% to 3.1%, and the range of the transmittance is 11.45% to 12.06%, and the range of the reflectance at the minimum end of the attenuation is 1.5% ⁇ 2.3%, the range of transmittance is 47.8% ⁇ 96.3% 0
  • the apparatus for manufacturing a neutral grayscale filter of a multilayer film layer comprises: a vacuum chamber, a coated umbrella and a power source, the coated umbrella being fixed on the top of the cavity of the vacuum chamber, the coating The rotating shaft of the umbrella is connected to the power source, and the bottom of the cavity of the vacuum chamber is provided with two symmetrically distributed sources of coating materials, two of which are located under the coated umbrella; the correction plate is fixed in the vacuum chamber. One end is located on the same side of the two coated materials.
  • the apparatus for manufacturing a neutral gray-scale dimming filter of a multi-layer film layer further includes a baffle plate, wherein the baffle plate is provided with a plurality of symmetrically distributed gradation holes, and the gradation hole has a blade shape .
  • the method for manufacturing a neutral gray-scale dimming filter of a multi-layer film layer comprises the steps of: (1) placing the substrate in the vacuum chamber, and pumping the vacuum chamber to a vacuum pump Predetermining the degree of vacuum, fixing the correction plate in the vacuum chamber; (2) the power source drives the coating umbrella to rotate, and the two coating materials alternately vapor-deposit the film layer, wherein the film layer is a predetermined thickness and a predetermined order, in addition, preferably, a method of manufacturing a neutral gray scale filter of a multilayer film layer, wherein the correction plate in the step (1) is removed, in the step (1) Between the step (2) and the step (2), the step of installing the baffle under the film umbrella is also included.
  • the neutral grayscale filter of the multilayer film provided by the present invention and the manufacturing method thereof wherein the neutral grayscale filter of the multilayer film layer is provided with anti-reflection
  • the film is separated by a compound layer having a refractive index higher than 1.30, and the multilayer anti-reflection film is laminated with the multilayer metal film, so that the reflectance of the ND mirror and the GND mirror is low, and the light balance can be attenuated;
  • the ND mirror and the GND mirror manufactured by the method for manufacturing the neutral gray-scale dimming filter of the multi-layer film have low reflectance, good effect on light balance attenuation, and the manufacturing process does not affect the image quality;
  • the same plating device can be used with the correction plate or the baffle plate to manufacture the ND mirror and the GMD mirror respectively.
  • the baffle plate can make the plated neutral metal show a thin thickness change on the substrate, thereby achieving the gradual effect.
  • 1 is a schematic view showing a transmittance spectrum curve of a GND mirror manufactured by resin dyeing, glass lamination, and medium gray glass bonding in the prior art
  • 2a is a schematic view showing a transmittance spectrum curve of a GND mirror manufactured by a vacuum neutral metal film method in the prior art
  • 2b is a schematic view showing a reflectance spectrum curve of a GND mirror manufactured by a vacuum neutral metal film method in the prior art
  • 3a is a schematic view of an ND mirror of a neutral grayscale filter of a multilayer film layer according to an embodiment of the present invention
  • Figure 3b is a schematic view of the ND mirror plating apparatus of the neutral gray scale filter of the multilayer film layer shown in Figure 3a;
  • FIG. 4 is a schematic view of a baffle plate of a GND mirror of a neutral gray scale filter of a multilayer film according to still another embodiment of the present invention.
  • Figure 5a is a schematic illustration of the spectral curve of the transmittance of the GKD mirror of the neutral grayscale filter of the multilayer film of Figure 4;
  • Figure 5b is a graphical representation of the spectral curve of the reflectivity of the GND mirror of the neutral gray scale filter of the multilayer film of Figure 4. ' Reference mark:
  • Substrate 1000; manufacturing device 100;
  • the neutral gray-scale dimming filter of the multilayer film layer comprises a substrate on which a plurality of film layers are plated, the film layer comprises a laminated anti-reflection film and a metal film, and the refractive index of the constituent material of the anti-reflection film is greater than 1.30.
  • the constituent material of the anti-reflection film includes at least one selected from the group consisting of A1 2 0 3 , A1F 3 , BeO, CaF 2 , CeF 3 , CeO 3 , Cr 2 0 3 , Dy 2 0 3 , Gd 2 0 3 , Hf0. 2 , Ho 2 0 3 , ln 2 0 3 , LaF 3 , MgF 2 , MgO, MO, Nd 2 0 3 , Pb 6 0 consider Sn0 3 , SiO, Si0 2 , Sm 2 0 3 , Ti0 2 , Ta 2 0 5, Thi0 2, compound mixture composed of the above compound or Zr0 2.
  • the antireflection film may be a compound having a refractive index greater than 1.30, may be a mixture of 1.30 greater than the refractive index of compounds of general.
  • the constituent material of the metal film includes at least one metal element selected from the group consisting of Al, Ag, Cr, Ni, Au, Cu, Fe, Zn, Sn, Mo or an alloy composed of the above-mentioned metal element.
  • the metal film may be a single element of a metal or an alloy of a plurality of metal elements.
  • the substrate is plated with at least two film layers.
  • the optical thickness of the film of the anti-reflection film ranges from 1 to 300 nm, and the optical thickness of the film of the metal film ranges from 1 to 320 nm.
  • Fig. 3a is a schematic view of a M) mirror of a neutral gray-scale dimming filter of a multilayer film layer according to an embodiment of the present invention.
  • the single film layers in the first film layer to the eighth film layer are anti-reflection films
  • the double film layers are metal films
  • the film layer is an anti-reflection film.
  • Table 1 is a table of ten layers of layers deposited on the substrate.
  • Table 1 Table of the ten layers of layers deposited on the substrate
  • the manufacturing apparatus of the neutral gray reduction filter includes a manufacturing apparatus of the D mirror and a manufacturing apparatus of the GND mirror.
  • Fig. 3b is a schematic view showing the apparatus for manufacturing the ND mirror of the neutral gray scale filter of the multilayer coating shown in Fig. 3a.
  • the manufacturing apparatus 100 of the ND mirror includes a vacuum chamber 10, a coated umbrella 11 and a power source 12, and a coated umbrella 1 is fixed to the top of the cavity of the vacuum chamber 10, and a rotating shaft of the coated umbrella 1 is connected with a power source 12
  • the power source 12 drives the coated umbrella 11 to rotate, and the power source 12 is located outside the vacuum chamber 10, and the vacuum chamber
  • the bottom of the cavity of the 10 is provided with two symmetrically distributed coating material sources, namely a coating material source 14 and a coating material source 15, respectively, and the coating material source 14 and the coating material source 15 are located below the coated umbrella 11.
  • the correction plate 13 is fixed in the vacuum chamber 10, and the correction plate 13-end is located on the same side of the coating material source 14 and the coating material source 15, and the uniformity of the coating material source 14 and the coating material source 15 can be corrected.
  • FIG. 4 is a schematic view of a baffle plate of a GND mirror of a neutral gray reduction filter of a multi-layer coating according to still another embodiment of the present invention.
  • the main difference between the manufacturing apparatus and the manufacturing of the GND mirror is that the manufacturing apparatus for manufacturing the GND mirror does not include the correction plate 13, but the baffle 16 is mounted under the coated umbrella 11, about 0.1 to 50 cm from the coated umbrella 11.
  • a baffle 16 is provided, and the distance between the baffle 16 and the coated umbrella 11 will affect the decay rate of the coating.
  • the baffle 16 has a circular cross section, and may be 60° or 120° or 0 to 360° - a fan shape at any angle.
  • the baffle 16 allows the plated neutral metal to exhibit a thin change in the substrate to achieve a gradual effect. It is also possible to cause the plated neutral metal film to exhibit a thin thickness change by means of a motor dragging the baffle parallel to the substrate or other occlusion means.
  • the neutral grayscale filter includes an ND mirror and a GND mirror.
  • Figure 3b is a schematic view of the ND mirror plating apparatus of the neutral gray scale filter of the multilayer film layer shown in Figure 3a.
  • the substrate 1000 is placed within the vacuum chamber 10, the vacuum chamber 10 using a vacuum pump evacuated to a predetermined degree of vacuum, preferably, a predetermined degree of vacuum chamber was 3.5 X 10_ 3 Pa or 9.0X l (T 3 Pa. Fixing the correction plate 13 in the vacuum chamber 10; -
  • the power source 12 drives the film umbrella 11 to rotate, and the film layer source 14 and the film layer source 15 are alternately vapor-deposited.
  • the film layers are formed on the substrate 1000, and the film layers are sequentially laminated in a predetermined optical thickness and a predetermined order. In the present embodiment, the film layers are laminated in the optical thickness and order shown in Table 1.
  • FIG. 4 is a perspective view showing a baffle plate of a GND mirror of a neutral gray scale filter of a multilayer film according to still another embodiment of the present invention.
  • the main difference between the manufacture of the GND mirror and the manufacture of the D mirror is that the correction plate 13 in the step (1) is removed, and the following steps are added between the steps (1) and (2), in the film.
  • a baffle 16 is installed below the layer umbrella 11, and a baffle 16 is disposed at about 0.1 to 50 cm from the film umbrella 11. The distance between the baffle 16 and the film umbrella 11 will affect the attenuation rate of the film layer.
  • the baffle 16 can cause the plated neutral metal to be on the substrate 1000 A thin and thick change is made to achieve a gradual effect. It is also possible to make the plated neutral metal film exhibit a thin thickness change by means of a motor dragging the baffle parallel to the substrate or other shielding means.
  • the transmittance and reflectance of the ND mirror and the GND mirror manufactured by the method of manufacturing the neutral gray reduction filter of the multilayer film layer are described below.
  • the reflectance ranges from 1.50% to 2.30%, and the transmittance ranges from 47.8% to 51.3%.
  • the range of the reflectance at the maximum end of the attenuation is 2.5% to 3.1%, and the range of the transmittance is 11.45% to 12.06%, and the range of the reflectance at the minimum end of the attenuation is
  • the D-mirror plated by the spectrometer is concluded as follows: In the wavelength range of 420 nm to 680 nm, the transmittance is the highest at a wavelength of 580 nm, and the maximum transmittance is 51.3%. At a wavelength of 440 nm, the transmittance is the smallest. The minimum transmittance is 47.8%, and the average transmittance is 50.5% in the range of 420 nm to 680 nm.
  • the reflectance In the interval of 420nm- ⁇ 80nm, the reflectance is the largest at a wavelength of 420nm, the maximum reflectance is 2.3%, the reflectance is the smallest at a wavelength of 493nm, the minimum reflectance is 1.5%, and M is in the range of 420nm-680nm.
  • the average transmission rate is 1.8%.
  • Figure 5a is a graphical representation of the spectral curve of the transmittance of a GM mirror of a neutral gray scale filter of the multilayer film of Figure 4.
  • Figure 5b is a graphical representation of the spectral curve of the reflectivity of the GND mirror of the neutral gray scale filter of the multilayer film of Figure 4.
  • Curve 1 represents the maximum attenuation at the wavelength of 420 nm to 680 nm, and the maximum transmittance at the wavelength of 580 nm.
  • the rate is 12.06%
  • the transmittance is the smallest at the wavelength of 440nm
  • the minimum transmittance is
  • curve 1 represents the reflectance at the maximum end of the attenuation in the interval of 420 nm to 680 nm, the maximum reflectance at a wavelength of 420 nm, the maximum reflectance of 3.1%, the minimum reflectance at a wavelength of 493 nm, and the minimum reflectance. It is 2.5%, and the average transmittance is 1.8% in the range of 420 nm to 680 nm.
  • the transmittance at the minimum end of the attenuation is the largest at a wavelength of 580 nm, and the maximum transmittance is 96.3%.
  • the transmittance at the minimum end of the attenuation is the smallest at a wavelength of 440 nm, and the minimum transmittance is 47.8%.
  • the average transmittance was 50.5% in the range of 420 nm to 680 nm.
  • the reflectance at the minimum end of the attenuation is the largest at a wavelength of 420nm, the maximum reflectance is 2.3%, and the reflectance at the minimum end of the attenuation is the smallest at a wavelength of 493nm, the minimum reflectance is 1.5%, and at a wavelength of 420nm-680nm. Within the interval, the average transmission rate was 1.8%.
  • the neutral gray-scale dimming filter of the multilayer film layer provided by the embodiment provided by the present invention and the manufacturing method thereof, wherein the neutral gray-scale dimming filter of the multi-layer film layer is provided with an anti-reflection film.
  • the metal element layer is separated by a compound layer having a refractive index higher than 1.30, and the multilayer anti-reflection film is laminated with the multilayer metal film, so that the reflectance of the ND mirror and the GND mirror is low, and the light balance can be attenuated;
  • the ND mirror and the GND mirror manufactured by the method for manufacturing the neutral gray-scale dimming filter of the multi-layer film have low reflectance, good effect on light balance attenuation, and the manufacturing process does not affect the image quality;
  • the device can be used with the correction plate or the baffle to manufacture the D mirror and the GND mirror respectively. Fourthly, the baffle can make the plated neutral metal show a thin thickness change on the substrate to achieve the gradual effect.

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  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Optical Elements Other Than Lenses (AREA)

Abstract

A neutral density filter having multiple film layers, a manufacturing device thereof and a manufacturing method therefor. The neutral density filter comprises a substrate (1000) plated with a plurality of film layers, the film layers comprise antireflection films and metal films that are laminated, and the refractive index of the materials forming the antireflection films is higher than 1.3. The manufacturing device of the neutral density filter having multiple film layers comprises a vacuum chamber (10), a film plating umbrella (11) and a power source (12). The film plating umbrella (11) is fixed to the top of the cavity of the vacuum chamber (10), a rotary shaft of the film plating umbrella (11) is connected to the power source (12), and the bottom of the cavity of the vacuum chamber (10) is provided with two film plating material sources (14, 15) that are located below the film plating umbrella (11). A correction plate (13) is fixed in the vacuum chamber (10), and one end of the correction plate (13) is located on the same side of the two film plating material sources (14, 15). The manufacturing method for the neutral density filter having multiple film layers comprises the steps of: (1) placing a substrate in the vacuum chamber (10), pumping the vacuum chamber (10) to a preset vacuum degree, and fixing the correction plate (13) in the vacuum chamber (10); and (2) driving the film plating umbrella (11) to rotate by using the power source (12), wherein the two film plating material sources (14, 15) are used for evaporation of the film layers in an alternating mode, and the film layers are sequentially laminated according to the preset optical thickness and a preset order.

Description

多层膜层的中性灰度减光滤镜及其制造装置及其制造方法 技术领域  Neutral gray-scale dimming filter of multilayer film layer, manufacturing device thereof and manufacturing method thereof
本发明涉及一种中性灰度减光滤镜, 具体地说, 涉及多层膜层的中灰定值 减光滤镜和中灰渐变减光 _滤镜及其制造装置及其制造方法。 背景技术  The present invention relates to a neutral grayscale dimming filter, and more particularly to a medium gray fixed value dimming filter and a medium gray gradient dimming filter and a manufacturing apparatus therefor. Background technique
中性灰度滤镜是对光线进行平衡衰减的能量分光元件, 其主要用于摄影摄 像时过滤光线, 具有结构简单, 使用波长范围广等优点。 中性灰度滤镜包括中 灰定值减光滤镜 (Neutral Density Filter, 简称 ND 镜) 和中灰渐变减光滤镜 ( Graduated Neutral Density Filter, 简禾尔 GND镜)。  The neutral gray filter is an energy splitting element that balances light attenuation. It is mainly used to filter light during photographic photography. It has the advantages of simple structure and wide wavelength range. The neutral gray filter includes a Neutral Density Filter (ND Mirror) and a Graduated Neutral Density Filter (Journey Neutral Density Filter).
ND镜主要是用来降低相机曝光量, 当被摄物体光线较亮时, 需要用 D镜 来降低曝光量。 ND镜滤对光作用是非选择性的, ND镜对各种不同波长的光线 的减少能力是同等的、 均匀的, 只起到减弱光线的作用, 而对原物体的颜色不 会产生任何影响, 其光密度不随位置变化, 整体零件是均匀一致的。 GND镜的 光密度随着位置发生变化, 有着不同的暗度变化, 即不同的光密度。 GND镜不 会改变画面的色彩平衡, 但可以改变感光的反差。 例如, 遇到光线差很大的情 况时, 如果光线强一侧曝光准确, 光线弱一侧则曝光不足; 如果光线弱一侧曝 光准确, 则光线强一侧曝光过度。 在镜头前加上 GND镜就可以解决该问题。  The ND mirror is mainly used to reduce the amount of exposure of the camera. When the subject is bright, the D mirror is required to reduce the exposure. The ND mirror filter is non-selective to the light. The ND mirror is equally and uniform in reducing the light of different wavelengths. It only acts to attenuate the light and has no effect on the color of the original object. The optical density does not change with position, and the overall part is uniform. The optical density of the GND mirror varies with position and has different darkness variations, ie different optical densities. The GND mirror does not change the color balance of the picture, but it can change the contrast of the light. For example, in the case of a large difference in light, if the light is strongly exposed on one side, the weak side is underexposed; if the weak side is exposed accurately, the strong side is overexposed. This problem can be solved by adding a GND mirror in front of the lens.
在生产 ND镜或' G D镜时, 由于树脂片或胶层的变形会影响成像质量, 或 是因高反射率导致使用过程中产生鬼影等现象。 以制作 GND镜为例, 包括以下 四种制作方式。 图 1 是现有技术中采用树脂染色、 玻璃夹胶和中灰玻璃胶合方 法制造的 GND镜的透光率光谱曲线的示意图。如图 1所示, 曲线 1代表树脂染 色方法制造的 GND镜的透光率光谱曲线,树脂染色由于染色过程中需要在高温 液体中泡煮和树脂镜片本身容易变形, 导致树脂片产生形变, 从而影响摄影摄 像的成像质量难以达到高清效果。 同时因为染料的色散问题, 导致不能对光线 进行平衡衰减。从图谱可以看出, 从波长 650nm开始, 透过率发生了明显升高, 这也是摄影中产生偏红的主要原因。曲线 2代表玻璃夹胶方法制造的 GND镜的 透光率光谱曲线, 玻璃夹胶片是由 2片玻璃中间夹一片染色片组成, 在具有树 脂染色的上述缺点外, 还增加一个厚度大的缺点。 曲线 3 代表中灰玻璃胶合方 法制造的 GND镜的透光率光谱曲线, 中灰玻璃和无色透明玻璃胶合后, 斜着研 磨, 使中灰玻璃产生厚薄变化来实现平衡衰减作用。 由于胶层导致产生形变, 影响摄影摄像的成像质量且不能实现高透过区域的真正高透过率和不能对光线 真正平衡衰减。 图 2a是现有技术中采用真空中性金属膜方法制造的 GND镜的 透光率光谱曲线的示意图。 图 2b是现有技术中釆用真空中性金属膜方法制造的 GND镜的反射率光谱曲线的示意图。如图 2a所示,曲线 1代表透过率光谱曲线, 如图 2b所示, 曲线 1代表反射率光谱曲线, 真空中性金属膜工艺虽然较好的解 决了影响成像质量的问题且有较理想的对光线平衡衰减功能。 但是却因为有较 高的反射率, 导致使用过程中易产生鬼影等现象。 发明内容 When producing ND mirrors or 'GD mirrors, the deformation of the resin sheet or the adhesive layer may affect the image quality, or the phenomenon of ghosting during use due to high reflectance. Take the GND mirror as an example, including the following four production methods. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing a transmittance spectrum curve of a GND mirror manufactured by a resin dyeing method, a glass lamination method, and a medium gray glass bonding method in the prior art. As shown in FIG. 1, curve 1 represents a light transmittance spectrum curve of a GND mirror manufactured by a resin dyeing method, and resin dyeing is required to be deformed in a high-temperature liquid during the dyeing process and the resin lens itself is easily deformed, thereby causing deformation of the resin sheet, thereby It is difficult to achieve high definition images that affect the imaging quality of photographic cameras. At the same time, due to the dispersion problem of the dye, the light cannot be balanced and attenuated. It can be seen from the spectrum that the transmittance has increased significantly since the wavelength of 650 nm, which is the main cause of redness in photography. Curve 2 represents the transmittance spectrum curve of the GND mirror manufactured by the glass lamination method, and the glass clip film is composed of two pieces of glass intermediate clips, and has a disadvantage of having a large thickness in addition to the above disadvantages of resin dyeing. Curve 3 represents the middle gray glass glue The light transmittance spectrum curve of the GND mirror manufactured by the method, after the gray glass and the colorless transparent glass are glued, is obliquely ground, so that the medium gray glass is changed in thickness to achieve the balance attenuation effect. Due to the deformation caused by the glue layer, the imaging quality of the photographic image is affected and the true high transmittance of the high transmission region cannot be achieved and the true balance of the light cannot be attenuated. 2a is a schematic view showing a transmittance spectrum curve of a GND mirror manufactured by a vacuum neutral metal film method in the prior art. Fig. 2b is a schematic view showing a reflectance spectrum curve of a GND mirror manufactured by a vacuum neutral metal film method in the prior art. As shown in Fig. 2a, curve 1 represents the transmittance spectrum curve, as shown in Fig. 2b, curve 1 represents the reflectance spectrum curve, and the vacuum neutral metal film process better solves the problem of affecting imaging quality and is ideal. The light balance attenuation function. However, because of the high reflectivity, it is easy to produce ghosts during use. Summary of the invention
本发明所要解决的技术问题是提供一种多层膜层的中性灰度减光滤镜及其 制造方法, 可以制造出对光线平衡衰减效果好且具有低反射率的 ND镜和 GND 镜, 同时制造过程不会影响成像质量。  The technical problem to be solved by the present invention is to provide a neutral gray-scale dimming filter of a multilayer film layer and a manufacturing method thereof, which can produce an ND mirror and a GND mirror with good light balance attenuation effect and low reflectivity. At the same time, the manufacturing process does not affect the image quality.
为实现上述目的, 本发明提供一种多层膜层的中性灰度减光滤镜及其制造 方法, 其包括基片, 所述基片上镀有若干层膜层, 所述膜层包括层叠的减反射 · 膜和金属膜, 所述减反射膜的构成材料的折射率大于 1.30。  In order to achieve the above object, the present invention provides a neutral grayscale dimming filter of a multilayer film layer and a method of fabricating the same, comprising a substrate, the substrate being plated with a plurality of film layers, the film layer comprising a laminate The antireflection film and the metal film, the constituent material of the antireflection film has a refractive index of more than 1.30.
优选地, 所述减反射膜的构成材料包括至少一种选自 A1203、 A1F3、 BeO、 CaF2、 CeF3、 Ce03、 Cr203、 Dy203、 Gd203、 Hf02、 Ho203、 ln203、 : LaF3、 MgF2、 MgO、 NiO、 Nd203
Figure imgf000004_0001
Sn03、 SiO、 Si02、 Sm203、 Ti02、 Ta205、 Thi02、 Zr02的化合物或由上述化合物构成的混合物。
Preferably, the constituent material of the anti-reflection film comprises at least one selected from the group consisting of A1 2 0 3 , A1F 3 , BeO, CaF 2 , CeF 3 , CeO 3 , Cr 2 0 3 , Dy 2 0 3 , Gd 2 0 3 , Hf0 2 , Ho 2 0 3 , ln 2 0 3 , : LaF 3 , MgF 2 , MgO, NiO, Nd 2 0 3 ,
Figure imgf000004_0001
Sn0 3, SiO, Si0 2, Sm 2 0 3, Ti0 2, Ta 2 0 5, Thi0 2, compound or a mixture composed of the compound of Zr0 2.
优选地, 所述金属膜的构成材料包括至少一种选自 Al、 Ag、 Cr、 Ni、 Au、 Cu、 Fe、 Zn、 Sn、 Mo的金属单质或由上述金属单质构成的合金。  Preferably, the constituent material of the metal film includes at least one metal element selected from the group consisting of Al, Ag, Cr, Ni, Au, Cu, Fe, Zn, Sn, Mo or an alloy composed of the above-mentioned metal element.
优选地, 所述基片上镀有至少两层所述膜层。  Preferably, the substrate is plated with at least two layers of the film layer.
优选地, 所述减反射膜的膜层光学厚度的范围是 l~300nm, 所述金属膜的 膜层光学厚度的范围是 l~320nm。  Preferably, the optical thickness of the film of the anti-reflection film ranges from 1 to 300 nm, and the optical thickness of the film of the metal film ranges from 1 to 320 nm.
优选地, 在波长 420〜680nm的区间内, 反射率的范围是 1.50%〜2.30%, .透 过率的范围是 47.8%〜51.3%。  Preferably, the reflectance ranges from 1.50% to 2.30% in the wavelength range of 420 to 680 nm, and the transmittance ranges from 47.8% to 51.3%.
优选地, 在波长 _420〜680nm 的区间内, 衰减最大端的反射率的范围是 2.5%〜3.1%, 透过率的范围是 11.45%〜12.06%, 衰减最小端的反射率的范围是 1.5%~2.3%, 透过率的范围是 47.8%~96.3%0 Preferably, in the interval of wavelength _420 to 680 nm, the range of the reflectance at the maximum end of the attenuation is 2.5% to 3.1%, and the range of the transmittance is 11.45% to 12.06%, and the range of the reflectance at the minimum end of the attenuation is 1.5%~2.3%, the range of transmittance is 47.8%~96.3% 0
优选地, 多层膜层的中性灰度减光滤镜的制造装置, 其包括: 真空室, 镀 膜伞和动力源, 所述镀膜伞固定在所述真空室的腔体顶部, 所述镀膜伞的旋转 轴连接所述动力源, 所述真空室的腔体底部设有两个对称分布的镀膜材源, 两 个所述镀膜材源位于所述镀膜伞下方; 修正板固定在真空室内, 一端位于两个 镀膜材源同一侧。  Preferably, the apparatus for manufacturing a neutral grayscale filter of a multilayer film layer comprises: a vacuum chamber, a coated umbrella and a power source, the coated umbrella being fixed on the top of the cavity of the vacuum chamber, the coating The rotating shaft of the umbrella is connected to the power source, and the bottom of the cavity of the vacuum chamber is provided with two symmetrically distributed sources of coating materials, two of which are located under the coated umbrella; the correction plate is fixed in the vacuum chamber. One end is located on the same side of the two coated materials.
优选.地, 多层膜层的中性灰度减光滤镜的制造装置, 还包括挡板, 所述挡 板上设有多个对称分布的渐变孔, 所述渐变孔的截面为叶片形。  Preferably, the apparatus for manufacturing a neutral gray-scale dimming filter of a multi-layer film layer further includes a baffle plate, wherein the baffle plate is provided with a plurality of symmetrically distributed gradation holes, and the gradation hole has a blade shape .
优选地, 多层膜层的中性灰度减光滤镜的制造方法, 其包括的步骤有: (1 ) 将所述基片置于所述真空室内, 采用真空泵将所述真空室抽至预定真空度, 将 所述修正板固定在所述真空室内; (2) 所述动力源驱动所述镀膜伞旋转, 两个 所述镀膜材源交替蒸镀所述膜层, 所述膜层以预定的厚度和预定的次序依次层 另外, 优选地, 多层膜层的中性灰度减光滤镜的制造方法, 其中, 将步骤 ( 1 ) 中的所述修正板取下, 在步骤 (1 ) 和步骤 (2) 之间还包括如下步骤, 在 所述膜层伞下方安装所述挡板。  Preferably, the method for manufacturing a neutral gray-scale dimming filter of a multi-layer film layer comprises the steps of: (1) placing the substrate in the vacuum chamber, and pumping the vacuum chamber to a vacuum pump Predetermining the degree of vacuum, fixing the correction plate in the vacuum chamber; (2) the power source drives the coating umbrella to rotate, and the two coating materials alternately vapor-deposit the film layer, wherein the film layer is a predetermined thickness and a predetermined order, in addition, preferably, a method of manufacturing a neutral gray scale filter of a multilayer film layer, wherein the correction plate in the step (1) is removed, in the step (1) Between the step (2) and the step (2), the step of installing the baffle under the film umbrella is also included.
从上述的描述和实践可知, 本发明提供的多层膜层的中性灰度减光滤镜及 其制造方法, 其一, 多层膜层的中性灰度减光滤镜设有减反射膜, 采用折射率 高于 1.30的化合物层将金属单质层分隔开, 多层减反射膜与多层金属膜层叠, 则 ND镜和 GND镜的反射率低, 可以对光线平衡衰减; 其二, 由多层膜层的中 性灰度减光滤镜的制造方法制造的 ND镜和 GND镜的反射率低,对光线平衡衰 减效果好, 而且制作过程不会影响成像质量; 其三, 采用同一镀制装置配合修 正板或挡板使用, 可以分别制造 ND镜和 GMD镜; 其四, 挡板可以使所镀的中 性金属在基片上呈现薄厚的变化, 从而达到渐变的效果。 附图说明  As can be seen from the above description and practice, the neutral grayscale filter of the multilayer film provided by the present invention and the manufacturing method thereof, wherein the neutral grayscale filter of the multilayer film layer is provided with anti-reflection The film is separated by a compound layer having a refractive index higher than 1.30, and the multilayer anti-reflection film is laminated with the multilayer metal film, so that the reflectance of the ND mirror and the GND mirror is low, and the light balance can be attenuated; The ND mirror and the GND mirror manufactured by the method for manufacturing the neutral gray-scale dimming filter of the multi-layer film have low reflectance, good effect on light balance attenuation, and the manufacturing process does not affect the image quality; The same plating device can be used with the correction plate or the baffle plate to manufacture the ND mirror and the GMD mirror respectively. Fourthly, the baffle plate can make the plated neutral metal show a thin thickness change on the substrate, thereby achieving the gradual effect. DRAWINGS
通过下面结合附图对实施例的描述, 本发明的上述特征和技术优点将会变 得更加清楚和容易理解。 在附图中,  The above features and technical advantages of the present invention will become more apparent and understood from the <RTIgt; In the drawing,
图 1 是现有技术中采用树脂染色、 玻璃夹胶和中灰玻璃胶合方法制造的 GND镜的透光率光谱曲线的示意图; 图 2a是现有技术中采用真空中性金属膜方法制造的 GND镜的透光率光谱 曲线的示意图; 1 is a schematic view showing a transmittance spectrum curve of a GND mirror manufactured by resin dyeing, glass lamination, and medium gray glass bonding in the prior art; 2a is a schematic view showing a transmittance spectrum curve of a GND mirror manufactured by a vacuum neutral metal film method in the prior art;
图 2b是现有技术中采用真空中性金属膜方法制造的 GND镜的反射率光谱 曲线的示意图;  2b is a schematic view showing a reflectance spectrum curve of a GND mirror manufactured by a vacuum neutral metal film method in the prior art;
图 3a是本发明一个实施例所述的多层膜层的中性灰度减光滤镜的 ND镜的 示意图;  3a is a schematic view of an ND mirror of a neutral grayscale filter of a multilayer film layer according to an embodiment of the present invention;
图 3b是图 3a所示的多层膜层的中性灰度减光滤镜的 ND镜的镀制装置示意 图;  Figure 3b is a schematic view of the ND mirror plating apparatus of the neutral gray scale filter of the multilayer film layer shown in Figure 3a;
图 4是本发明又一实施例所述的多层膜层的中性灰度减光滤镜的 GND镜的 镀制装置的挡板的示意图;  4 is a schematic view of a baffle plate of a GND mirror of a neutral gray scale filter of a multilayer film according to still another embodiment of the present invention;
图 5a是图 4的多层膜层的中性灰度减光滤镜的 GKD镜的透射率的光谱曲 线的示意图;  Figure 5a is a schematic illustration of the spectral curve of the transmittance of the GKD mirror of the neutral grayscale filter of the multilayer film of Figure 4;
图 5b是图 4的多层膜层的中性灰度减光滤镜的 GND镜的反射率的光谱曲 线的示意图。 ' 附图标记:  Figure 5b is a graphical representation of the spectral curve of the reflectivity of the GND mirror of the neutral gray scale filter of the multilayer film of Figure 4. ' Reference mark:
基片: 1000; 制造装置 100;  Substrate: 1000; manufacturing device 100;
10: 真空室; 11 : 镀膜伞; 12: 动力源; 13 : 修正板;  10: vacuum chamber; 11: coated umbrella; 12: power source; 13: correction plate;
14: 镀膜材源; 15: 镀膜材源; 16: 挡板; 161 : 渐变孔;- 具体实施方式  14: coating material source; 15: coating material source; 16: baffle; 161: gradient hole; - specific embodiment
为使本发明的上述目的、 特征和优点能够更加明显易懂, 下面结合附图和 具体实施方式对本发明作进一步详细的说明。  The above described objects, features and advantages of the present invention will become more apparent from the aspects of the appended claims.
多层膜层的中性灰度减光滤镜包括基片, 基片上镀有若干层膜层, 膜层包 括层叠的减反射膜和金属膜, 减反射膜的构成材料的折射率大于 1.30。  The neutral gray-scale dimming filter of the multilayer film layer comprises a substrate on which a plurality of film layers are plated, the film layer comprises a laminated anti-reflection film and a metal film, and the refractive index of the constituent material of the anti-reflection film is greater than 1.30.
优选地,减反射膜的构成材料包括至少一种选自 A1203、 A1F3、 BeO、 CaF2、 CeF3、 Ce03、 Cr203、 Dy203、 Gd203、 Hf02、 Ho203、 ln203、 LaF3、 MgF2、 MgO、 MO、 Nd203、 Pb60„ Sn03、 SiO、 Si02、 Sm203、 Ti02、 Ta205、 Thi02、 Zr02的化合物或由上述化合物构成的混合物。 减反射膜可以是一种折射率大于 1.30的化合物, 也可以是多种化合物构成的折射率大于 1.30的混合物。 优选地, 金属膜的构成材料包括至少一种选自 Al、 Ag、 Cr、 Ni、 Au、 Cu、 Fe、 Zn、 Sn、 Mo的金属单质或由上述金属单质构成的合金。 金属膜可以是一种 金属单质, 也可以是多种金属单质构成的合金。 Preferably, the constituent material of the anti-reflection film includes at least one selected from the group consisting of A1 2 0 3 , A1F 3 , BeO, CaF 2 , CeF 3 , CeO 3 , Cr 2 0 3 , Dy 2 0 3 , Gd 2 0 3 , Hf0. 2 , Ho 2 0 3 , ln 2 0 3 , LaF 3 , MgF 2 , MgO, MO, Nd 2 0 3 , Pb 6 0 „ Sn0 3 , SiO, Si0 2 , Sm 2 0 3 , Ti0 2 , Ta 2 0 5, Thi0 2, compound mixture composed of the above compound or Zr0 2. antireflection film may be a compound having a refractive index greater than 1.30, may be a mixture of 1.30 greater than the refractive index of compounds of general. Preferably, the constituent material of the metal film includes at least one metal element selected from the group consisting of Al, Ag, Cr, Ni, Au, Cu, Fe, Zn, Sn, Mo or an alloy composed of the above-mentioned metal element. The metal film may be a single element of a metal or an alloy of a plurality of metal elements.
优选地, 基片上镀有至少两层膜层。 优选地, 减反射膜的膜层光学厚度的 范围是 l〜300nm, 金属膜的膜层光学厚度的范围是 l~320nm。  Preferably, the substrate is plated with at least two film layers. Preferably, the optical thickness of the film of the anti-reflection film ranges from 1 to 300 nm, and the optical thickness of the film of the metal film ranges from 1 to 320 nm.
在本实施例中, 以衰减 88%的 ND镜为例, 图 3a是本发明一个实施例所述 的多层膜层的中性灰度减光滤镜的 M)镜的示意图。 如图 3a所示, 基片 1000 上有十层膜层, 第一膜层至第八膜层中的单数膜层为减反射膜, 双数膜层为金 属膜, 第九膜层和第十膜层为减反射膜。 基片 1000上膜层的构成、 光学厚度和 分布如表 1 -所示。 -表 1是基片上方蒸镀的十层膜层构成表。  In the present embodiment, an ND mirror having an attenuation of 88% is taken as an example, and Fig. 3a is a schematic view of a M) mirror of a neutral gray-scale dimming filter of a multilayer film layer according to an embodiment of the present invention. As shown in FIG. 3a, there are ten film layers on the substrate 1000, the single film layers in the first film layer to the eighth film layer are anti-reflection films, the double film layers are metal films, the ninth film layer and the tenth layer. The film layer is an anti-reflection film. The composition, optical thickness and distribution of the film layer on the substrate 1000 are shown in Table 1 -. - Table 1 is a table of ten layers of layers deposited on the substrate.
表 1基片上方蒸镀的十层膜层构成表  Table 1 Table of the ten layers of layers deposited on the substrate
Figure imgf000007_0001
Figure imgf000007_0001
下面介绍多层镀膜的中性灰度减光滤镜的制造装置。 中性灰度减光滤镜的 制造装置包括 D镜的制造装置和 GND镜的制造装置。  Next, a manufacturing apparatus of a multi-layer coated neutral gray reduction filter will be described. The manufacturing apparatus of the neutral gray reduction filter includes a manufacturing apparatus of the D mirror and a manufacturing apparatus of the GND mirror.
首先,介绍 ND镜的制造装置。图 3b是图 3a所示的多层镀膜的中性灰度减 光滤镜的 ND镜的制造装置示意图。  First, introduce the manufacturing equipment of the ND mirror. Fig. 3b is a schematic view showing the apparatus for manufacturing the ND mirror of the neutral gray scale filter of the multilayer coating shown in Fig. 3a.
如图 3b所示, ND镜的制造装置 100包括真空室 10, 镀膜伞 11和动力源 12, 镀膜伞 1 Γ固定到真空室 10的腔体顶部, 镀膜伞 1Γ的旋转轴连接有动力源 12, 动力源 12驱动镀膜伞 11旋转, 动力源 12位于真空室 10的外部, 真空室 10 的腔体底部设有两个对称分布的镀膜材源, 分别是镀膜材源 14和镀膜材源 15, 镀膜材源 14和镀膜材源 15均位于镀膜伞 11下方。 修正板 13固定在真空 室 10内, 修正板 13—端位于镀膜材源 14和镀膜材源 15的同一侧, 可以修正 镀膜材源 14和镀膜材源 15的均匀性。 As shown in FIG. 3b, the manufacturing apparatus 100 of the ND mirror includes a vacuum chamber 10, a coated umbrella 11 and a power source 12, and a coated umbrella 1 is fixed to the top of the cavity of the vacuum chamber 10, and a rotating shaft of the coated umbrella 1 is connected with a power source 12 The power source 12 drives the coated umbrella 11 to rotate, and the power source 12 is located outside the vacuum chamber 10, and the vacuum chamber The bottom of the cavity of the 10 is provided with two symmetrically distributed coating material sources, namely a coating material source 14 and a coating material source 15, respectively, and the coating material source 14 and the coating material source 15 are located below the coated umbrella 11. The correction plate 13 is fixed in the vacuum chamber 10, and the correction plate 13-end is located on the same side of the coating material source 14 and the coating material source 15, and the uniformity of the coating material source 14 and the coating material source 15 can be corrected.
下面介绍 GND镜的制造装置。图 4是本实用新型又一实施例所述的多层镀 膜的中性灰度减光滤镜的 GND镜的镀制装置的挡板示意图。  The following describes the manufacturing equipment of the GND mirror. 4 is a schematic view of a baffle plate of a GND mirror of a neutral gray reduction filter of a multi-layer coating according to still another embodiment of the present invention.
制造 GND镜的制造装置与制造 )镜制造装置的主要区别在于,制造 GND 镜的制造装置不包括修正板 13, 而是在镀膜伞 11下方安装挡板 16, 在距镀膜 伞 11约 0.1~50cm处设置挡板 16, 挡板 16与镀膜伞 11的距离将影响镀膜的衰 减率。 如图 4所示, 挡板 16的截面为圆形, 也可以是 60° 或 120° 或 0〜360°- 任意角度的扇形。 挡板 16可以使所镀的中性金属在基片上呈现薄厚的变化, 从 而达到渐变的效果。 也可以通过电机拖动平行于基片的挡板移动的方式或其他 遮挡方式使所镀的中性金属膜呈现薄厚变化。  The main difference between the manufacturing apparatus and the manufacturing of the GND mirror is that the manufacturing apparatus for manufacturing the GND mirror does not include the correction plate 13, but the baffle 16 is mounted under the coated umbrella 11, about 0.1 to 50 cm from the coated umbrella 11. A baffle 16 is provided, and the distance between the baffle 16 and the coated umbrella 11 will affect the decay rate of the coating. As shown in Fig. 4, the baffle 16 has a circular cross section, and may be 60° or 120° or 0 to 360° - a fan shape at any angle. The baffle 16 allows the plated neutral metal to exhibit a thin change in the substrate to achieve a gradual effect. It is also possible to cause the plated neutral metal film to exhibit a thin thickness change by means of a motor dragging the baffle parallel to the substrate or other occlusion means.
下面介绍多层膜层的中性灰度减光滤镜的制造方法。 中性灰度减光滤镜包 括 ND镜和 GND镜。  Next, a method of manufacturing a neutral gray scale filter of a multilayer film layer will be described. The neutral grayscale filter includes an ND mirror and a GND mirror.
首先,介绍 ND镜的制造方法。图 3b是图 3a所示的多层膜层的中性灰度减 光滤镜的 ND镜的镀制装置示意图。  First, introduce the manufacturing method of the ND mirror. Figure 3b is a schematic view of the ND mirror plating apparatus of the neutral gray scale filter of the multilayer film layer shown in Figure 3a.
如图 3b所示, 第一步, 基片 1000置于真空室 10内, 采用真空泵将真空室 10抽至预定真空度,优选地,真空室的预定真空度为 3.5 X 10_3Pa或 9.0X l(T3Pa。 将修正板 13固定在真空室 10内; - 第二步, 动力源 12驱动膜层伞 11旋转, 采用膜层材源 14和膜层材源 15 交替蒸镀基片, 以在基片 1000上形成膜层, 膜层以预定的光学厚度和预定的次 序依次层叠。 在本实施例中, 膜层以表 1所示的光学厚度和次序层叠。 3b, the first step, the substrate 1000 is placed within the vacuum chamber 10, the vacuum chamber 10 using a vacuum pump evacuated to a predetermined degree of vacuum, preferably, a predetermined degree of vacuum chamber was 3.5 X 10_ 3 Pa or 9.0X l (T 3 Pa. Fixing the correction plate 13 in the vacuum chamber 10; - In the second step, the power source 12 drives the film umbrella 11 to rotate, and the film layer source 14 and the film layer source 15 are alternately vapor-deposited. The film layers are formed on the substrate 1000, and the film layers are sequentially laminated in a predetermined optical thickness and a predetermined order. In the present embodiment, the film layers are laminated in the optical thickness and order shown in Table 1.
下面, 介绍 GN 镜的制造方法。 图 4是本发明又一实施例所述的多层膜层 的中性灰度减光滤镜的 GND镜的镀制装置的挡板示意图。  Next, the manufacturing method of the GN mirror is introduced. Fig. 4 is a perspective view showing a baffle plate of a GND mirror of a neutral gray scale filter of a multilayer film according to still another embodiment of the present invention.
如图 ·4所示, 制造 GND镜与制造 D镜的主要区别在于, 将步骤 (1 ) 中 的修正板 13 取下, 在步骤 (1 ) 和步骤 (2) 之间增加如下步骤, 在膜层伞 11 下方安装挡板 16, 在距膜层伞 11约 0.1~50cm处设置挡板 16, 挡板 16与膜层 伞 11的距离将影响膜层的衰减率。 挡板 16可以使所镀的中性金属在基片 1000 上呈现薄厚的变化, 从而达到渐变的效果。 也可以通过电机拖动平行于基片的 挡板移动的方式或其他遮挡方式使所镀的中性金属膜呈现薄厚变化。 As shown in Fig. 4, the main difference between the manufacture of the GND mirror and the manufacture of the D mirror is that the correction plate 13 in the step (1) is removed, and the following steps are added between the steps (1) and (2), in the film. A baffle 16 is installed below the layer umbrella 11, and a baffle 16 is disposed at about 0.1 to 50 cm from the film umbrella 11. The distance between the baffle 16 and the film umbrella 11 will affect the attenuation rate of the film layer. The baffle 16 can cause the plated neutral metal to be on the substrate 1000 A thin and thick change is made to achieve a gradual effect. It is also possible to make the plated neutral metal film exhibit a thin thickness change by means of a motor dragging the baffle parallel to the substrate or other shielding means.
下面介绍由多层膜层的中性灰度减光滤镜的制造方法制造的 ND镜和 GND 镜的透射率和反射率。  The transmittance and reflectance of the ND mirror and the GND mirror manufactured by the method of manufacturing the neutral gray reduction filter of the multilayer film layer are described below.
优选地, 在波长 420〜680nm的区间内, 反射率的范围是 1.50%〜2.30%, 透 过率的范围是 47.8%〜51.3%。  Preferably, in the interval of wavelength 420 to 680 nm, the reflectance ranges from 1.50% to 2.30%, and the transmittance ranges from 47.8% to 51.3%.
优选地, 在波长 420~680nm 的区间内, 衰减最大端的反射率的范围是 2.5%~3.1%, 透过率的范围是 11.45%〜12.06%, 衰减最小端的反射率的范围是 Preferably, in the interval of 420 to 680 nm, the range of the reflectance at the maximum end of the attenuation is 2.5% to 3.1%, and the range of the transmittance is 11.45% to 12.06%, and the range of the reflectance at the minimum end of the attenuation is
I.5%~2.3%, 透过率的范围是 47.8%~96.3%。 I.5%~2.3%, the transmittance range is 47.8%~96.3%.
通过光谱仪测试镀制的 D镜得出结论如下: 在波长 420nm-680nm的区间 内, 在波长 580nm处, 透过率最大, 最大透过率为 51.3%, 在波长 440nm处, 透过率最小, 最小透过率为 47.8%, 而在波长 420nm-680nm的区间内, 平均透 过率 50.5%。 在波长 420nm-^80nm的区间内, 在波长 420nm处反射率最大, 最 大反射率为 2.3%, 在波长 493nm处反射率最小, 最小反射率为 1.5%, M在波 长 420nm-680nm的区间内, 平均透过率 1.8%。  The D-mirror plated by the spectrometer is concluded as follows: In the wavelength range of 420 nm to 680 nm, the transmittance is the highest at a wavelength of 580 nm, and the maximum transmittance is 51.3%. At a wavelength of 440 nm, the transmittance is the smallest. The minimum transmittance is 47.8%, and the average transmittance is 50.5% in the range of 420 nm to 680 nm. In the interval of 420nm-^80nm, the reflectance is the largest at a wavelength of 420nm, the maximum reflectance is 2.3%, the reflectance is the smallest at a wavelength of 493nm, the minimum reflectance is 1.5%, and M is in the range of 420nm-680nm. The average transmission rate is 1.8%.
图 5a是图 4的多层膜层的中性灰度减光滤镜的 GM 镜的透射率的光谱曲 线的示意图。 图 5b是图 4的多层膜层的中性灰度减光滤镜的 GND镜的反射率 的光谱曲线的示意图。  Figure 5a is a graphical representation of the spectral curve of the transmittance of a GM mirror of a neutral gray scale filter of the multilayer film of Figure 4. Figure 5b is a graphical representation of the spectral curve of the reflectivity of the GND mirror of the neutral gray scale filter of the multilayer film of Figure 4.
如图 5a所示, 通过光谱仪测试镀制的 GND镜得出结论如下: 曲线 1代表 在波长 420nm-680nm的区间内的衰减最大端的透过率, 在 波长 580nm处透过 率最大, 最大透过率为 12.06%, 在波长 440nm处透过率最小, 最小透过率为 As shown in Fig. 5a, the GND mirror is tested by spectrometer. The conclusion is as follows: Curve 1 represents the maximum attenuation at the wavelength of 420 nm to 680 nm, and the maximum transmittance at the wavelength of 580 nm. The rate is 12.06%, the transmittance is the smallest at the wavelength of 440nm, and the minimum transmittance is
II.45%, 而在波长 420nm-680nm的可视区域内, 平均透过率 11.95%; II.45%, and in the visible region of wavelength 420nm-680nm, the average transmittance is 11.95%;
如图 5b所示,曲线 1代表在波长 420nm-680nm的区间内的衰减最大端的反 射率, 在波长 420nm处反射率最大, 最大反射率为 3.1%, 在波长 493nm处反射 率最小, 最小反射率为 2.5%, 而在波长 420nm-680nm的区间内, 平均透过率 1.8%。  As shown in Fig. 5b, curve 1 represents the reflectance at the maximum end of the attenuation in the interval of 420 nm to 680 nm, the maximum reflectance at a wavelength of 420 nm, the maximum reflectance of 3.1%, the minimum reflectance at a wavelength of 493 nm, and the minimum reflectance. It is 2.5%, and the average transmittance is 1.8% in the range of 420 nm to 680 nm.
在波长 420nm-680nm的区间内,衰减最小端的透过率在波长 580nm处最大, 最大透过率为 96.3%, 衰减最小端的透过率在波长 440nm处最小, 最小透过率 为 47.8%, 而在波长 420nm-680nm 的区间内, 平均透过率 50.5%。 在波长 420nm- 680nm的区间内, 衰减最小端的反射率在波长 420nm处最大, 最大反射 率为 2.3%, 衰减最小端的反射率在波长 493nm处最小, 最小反射率为 1.5%, 而在波长 420nm-680nm的区间内, 平均透过率 1.8%。 In the wavelength range of 420 nm to 680 nm, the transmittance at the minimum end of the attenuation is the largest at a wavelength of 580 nm, and the maximum transmittance is 96.3%. The transmittance at the minimum end of the attenuation is the smallest at a wavelength of 440 nm, and the minimum transmittance is 47.8%. The average transmittance was 50.5% in the range of 420 nm to 680 nm. At wavelength In the interval from 420nm to 680nm, the reflectance at the minimum end of the attenuation is the largest at a wavelength of 420nm, the maximum reflectance is 2.3%, and the reflectance at the minimum end of the attenuation is the smallest at a wavelength of 493nm, the minimum reflectance is 1.5%, and at a wavelength of 420nm-680nm. Within the interval, the average transmission rate was 1.8%.
通过上述本发明提供的实施例提供的多层膜层的中性灰度减光滤镜及其制 造方法, 其一, 多层膜层的中性灰度减光滤镜设有减反射膜, 采用折射率高于 1.30的化合物层将金属单质层分隔开, 多层减反射膜与多层金属膜层叠, 则 ND 镜和 GND镜的反射率低, 可以对光线平衡衰减; 其二, 由多层膜层的中性灰度 减光滤镜的制造方法制造的 ND镜和 GND镜的反射率低,对光线平衡衰减效果 好, 而且制作过程不会影响成像质量; 其三, 采用同一镀制装置配合修正板或 挡板使用, 可以分别制造 D镜和 GND镜; 其四, 挡板可以使所镀的中性金属 在基片上呈现薄厚的变化, 从而达到渐变的效果。  The neutral gray-scale dimming filter of the multilayer film layer provided by the embodiment provided by the present invention and the manufacturing method thereof, wherein the neutral gray-scale dimming filter of the multi-layer film layer is provided with an anti-reflection film. The metal element layer is separated by a compound layer having a refractive index higher than 1.30, and the multilayer anti-reflection film is laminated with the multilayer metal film, so that the reflectance of the ND mirror and the GND mirror is low, and the light balance can be attenuated; The ND mirror and the GND mirror manufactured by the method for manufacturing the neutral gray-scale dimming filter of the multi-layer film have low reflectance, good effect on light balance attenuation, and the manufacturing process does not affect the image quality; The device can be used with the correction plate or the baffle to manufacture the D mirror and the GND mirror respectively. Fourthly, the baffle can make the plated neutral metal show a thin thickness change on the substrate to achieve the gradual effect.
以上所述, 仅为本发明较佳的具体实施方式, 但本发明的保护范围并不局 限于此, 任何熟悉该技术的人在本发明所揭露的技术范围内, 可轻易想到的变 化或替换, 都应涵盖在本发明的保护范围之内。 因此, 本发明的保护范围应该 以权利要求的保护范围为准。  The above is only a preferred embodiment of the present invention, but the scope of protection of the present invention is not limited thereto, and any person skilled in the art can easily think of changes or replacements within the technical scope of the present invention. All should be covered by the scope of the present invention. Therefore, the scope of protection of the present invention should be determined by the scope of the claims.

Claims

权 利 要 求 书 Claim
1.一种多层膜层的中性灰度减光滤镜, 其包括基片, 其特征在于, 所述基片 上镀有若干层膜层, 所述膜层包括层叠的减反射膜和金属膜, 所述减反射膜的 构成材料的折射率大于 1.30。 A neutral gray-scale dimming filter for a multilayer film layer, comprising: a substrate, wherein the substrate is plated with a plurality of film layers, the film layer comprising a laminated anti-reflection film and a metal The film, the constituent material of the anti-reflection film has a refractive index greater than 1.30.
2.如权利要求 1所述的多层膜层的中性灰度减光滤镜, 其特征在于, 所述减 反射膜的构成材料包括至少一种选自 A1203、 A1F3、 BeO、 CaF2、 CeF3、 Ce03、 Cr203、Dy203、 Gd203、 Hf02、 Ho203、 ln203、 LaF3、 MgF2、 MgO、 NiO、 Nd203、 Pb60„、 Sn03、 Si〇、 Si02、 Sm203、 Ti02、 Ta205、 Thi02、 Zr02的化合物或由上 述化合物构成的混合物。 The neutral gray-scale dimming filter of the multilayer film layer according to claim 1, wherein the constituent material of the anti-reflection film comprises at least one selected from the group consisting of A1 2 0 3 , A1F 3 , BeO , CaF 2 , CeF 3 , CeO 3 , Cr 2 0 3 , Dy 2 0 3 , Gd 2 0 3 , Hf0 2 , Ho 2 0 3 , ln 2 0 3 , LaF 3 , MgF 2 , MgO, NiO, Nd 2 0 3, Pb 6 0 ", Sn0 3, Si〇, Si0 2, Sm 2 0 3 , Ti0 2, Ta compound or a mixture composed of the compound 2 0 5, Thi0 2, Zr0 2 in.
: 3.如权利要求 1所述的多层膜层的中性灰度减光滤镜, 其特征在 -于, 所述金- 属膜的构成材料包括至少一种选自 Al、 Ag、 Cr、 Ni、 Au、 Qi、 Fe、 Zn、 Sn、 Mo的金属单质或由上述金属单质构成的合金。  The neutral gray-scale dimming filter of the multilayer film layer according to claim 1, wherein the constituent material of the gold-based film comprises at least one selected from the group consisting of Al, Ag, and Cr. a metal element of Ni, Au, Qi, Fe, Zn, Sn, Mo or an alloy composed of the above-mentioned metal element.
4.如权利要求 1所述的多层膜层的中性灰度减光滤镜, 其特征在于, 所述基 片上镀有至少两层所述膜层。  The neutral gradation filter for a multilayer film layer according to claim 1, wherein the substrate is plated with at least two layers of the film layer.
5.如权利要求 1、 2或 3所述的多层膜层的中性灰度减光滤镜, 其特征在于, 所述减反射膜的膜层光学厚度的范围是 l〜300nm, 所述金属膜的膜层光学厚度 的范围是 l~320nm。 .  The neutral gray-scale dimming filter of the multilayer film layer according to claim 1, 2 or 3, wherein the optical thickness of the film of the anti-reflection film ranges from 1 to 300 nm, The optical thickness of the film of the metal film ranges from 1 to 320 nm. .
6.如权利要求 1所述的多层膜层的中性灰度减光滤镜, 其特征在于, 在波长 420~680nm 的区间内, 反射率的范围是 1.50%~2.30%, 透过率的范围是 47.8%~51.3%。  The neutral gradation filter for a multilayer film according to claim 1, wherein the reflectance ranges from 1.50% to 2.30% in a wavelength range of 420 to 680 nm, and the transmittance is The range is 47.8%~51.3%.
7.如权利要求 1所述的多层膜层的中性灰度减光滤镜, 其特征在于, 在波长 420~680nm的区间内, 衰减最大端的反射率的范围是 2.5%~3.1%, 透过率的范 围是 11.45%〜12.06%,衰减最小端的反射率的范围是 1.5%~2.3%,透过率的范围 是 47.8%~96.3%0 The neutral gray-scale dimming filter of the multilayer film according to claim 1, wherein the reflectance of the maximum end of the attenuation is in the range of 2.5% to 3.1% in the wavelength range of 420 to 680 nm. range of transmittance was 11.45% ~12.06%, the range of the minimum reflectance end attenuation of 1.5% to 2.3%, a transmittance in the range of 47.8% -96.3% 0
8.如权利要求 1所述的多层膜层的中性灰度减光滤镜的制造装置, 其包括: 真空室, 镀膜伞和动力源, 所述镀膜伞固定在所述真空室的腔体顶部, 所述镀 膜伞的旋转轴连接所述动力源,'其特征在于:  The apparatus for manufacturing a neutral gray scale filter of a multilayer film according to claim 1, comprising: a vacuum chamber, a coated umbrella and a power source, wherein the coated umbrella is fixed in a cavity of the vacuum chamber At the top of the body, the rotating shaft of the coated umbrella is connected to the power source, and is characterized by:
所述真空室的腔体底部设有两个对称分布的镀膜材源, 两个所述镀膜材源 . 位于所述镀膜伞下方; 修正板固定在真空室内, 一端位于两个镀膜材源同一侧。 The bottom of the cavity of the vacuum chamber is provided with two symmetrically distributed sources of coated material, two of which are located under the coated umbrella; The correction plate is fixed in the vacuum chamber, and one end is located on the same side of the two coated materials.
9.如权利要求 8所述的多层膜层的中性灰度减光滤镜的制造装置,其特征在 于, 还包括挡板, 所述挡板上设有多个对称分布的渐变孔, 所述渐变孔的截面 为叶片形。  The apparatus for manufacturing a neutral gray-scale dimming filter of a multilayer film according to claim 8, further comprising a baffle, wherein the baffle is provided with a plurality of symmetrically distributed gradient holes, The gradient hole has a blade shape in cross section.
10.如权利要求 1所述的多层膜层的中性灰度减光滤镜的制造方法, 其包括 的步骤有:  The method of manufacturing a neutral gray-scale dimming filter for a multilayer film according to claim 1, comprising the steps of:
( 1 )将所述基片置于所述真空室内, 采用真空泵将所述真空室抽至预定真 空度, 将所述修正板固定在所述真空室内;  (1) placing the substrate in the vacuum chamber, pumping the vacuum chamber to a predetermined vacuum using a vacuum pump, and fixing the correction plate in the vacuum chamber;
. (2)所述动力源驱动所述镀膜伞旋转, 两个所述镀膜材源交替蒸镀所述膜 层—, 所述膜层以预定的厚度和预定的次序依次层叠。  (2) The power source drives the coating umbrella to rotate, and the two coating materials alternately vapor-deposit the film layer, and the film layers are sequentially laminated in a predetermined thickness and in a predetermined order.
11.如权利要求 10所述的多层膜层的中性灰度减光滤镜的制造方法, 其中, 将步骤 (1 ) 中的所述修正板取下, 在步骤 (1 ) 和步骤 (2) 之间还包括如下步 骤, 在所述膜层伞下方安装所述挡板。  The method of manufacturing a neutral gray scale filter of a multilayer film according to claim 10, wherein the correction plate in the step (1) is removed, in the step (1) and the step (2) The method further includes the step of installing the baffle under the film umbrella.
PCT/CN2014/080488 2014-06-23 2014-06-23 Neutral density filter having multiple film layers, manufacturing device thereof and manufacturing method therefor WO2015196326A1 (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5715103A (en) * 1993-08-26 1998-02-03 Canon Kabushiki Kaisha Neutral density (ND) filter
JP2002350610A (en) * 2001-05-23 2002-12-04 Sony Corp Thin film nd filter and method for manufacturing the same
CN1779493A (en) * 2004-11-24 2006-05-31 住友金属矿山株式会社 Absorption type multi-layer film nd filter
TWI265202B (en) * 2005-03-02 2006-11-01 Asia Optical Co Inc Tool and device for dedicate coating a photochemical film on a substrate
JP2009145596A (en) * 2007-12-13 2009-07-02 Sumitomo Metal Mining Co Ltd Absorption type multi-layer film nd filter
CN104049291A (en) * 2014-06-23 2014-09-17 孙义昌 Neutral grey level ND filter of multiple film layers and manufacturing method thereof
CN204044387U (en) * 2014-06-23 2014-12-24 孙义昌 A kind of neutral gray scale dim light filter of stratified film and manufacturing installation thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5715103A (en) * 1993-08-26 1998-02-03 Canon Kabushiki Kaisha Neutral density (ND) filter
JP2002350610A (en) * 2001-05-23 2002-12-04 Sony Corp Thin film nd filter and method for manufacturing the same
CN1779493A (en) * 2004-11-24 2006-05-31 住友金属矿山株式会社 Absorption type multi-layer film nd filter
TWI265202B (en) * 2005-03-02 2006-11-01 Asia Optical Co Inc Tool and device for dedicate coating a photochemical film on a substrate
JP2009145596A (en) * 2007-12-13 2009-07-02 Sumitomo Metal Mining Co Ltd Absorption type multi-layer film nd filter
CN104049291A (en) * 2014-06-23 2014-09-17 孙义昌 Neutral grey level ND filter of multiple film layers and manufacturing method thereof
CN204044387U (en) * 2014-06-23 2014-12-24 孙义昌 A kind of neutral gray scale dim light filter of stratified film and manufacturing installation thereof

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