WO2015185329A1 - Shampooings cosmétiques contenant des résines de silicone dispersées dans de l'huile de silicone - Google Patents

Shampooings cosmétiques contenant des résines de silicone dispersées dans de l'huile de silicone Download PDF

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Publication number
WO2015185329A1
WO2015185329A1 PCT/EP2015/060300 EP2015060300W WO2015185329A1 WO 2015185329 A1 WO2015185329 A1 WO 2015185329A1 EP 2015060300 W EP2015060300 W EP 2015060300W WO 2015185329 A1 WO2015185329 A1 WO 2015185329A1
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WO
WIPO (PCT)
Prior art keywords
preparations according
units
silicone resin
silicone
siloxane
Prior art date
Application number
PCT/EP2015/060300
Other languages
German (de)
English (en)
Inventor
Julia NEMNICH
Maren Wilken
Anna Christina REISER
Nathalie Sors
Robert Klauck
Original Assignee
Beiersdorf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf Ag filed Critical Beiersdorf Ag
Priority to EP15723676.1A priority Critical patent/EP3151922A1/fr
Publication of WO2015185329A1 publication Critical patent/WO2015185329A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/004—Preparations used to protect coloured hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/592—Mixtures of compounds complementing their respective functions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Definitions

  • the invention relates to cosmetic shampoos containing silicone resins dispersed in silicone oil.
  • Hair shampoos contain a variety of different components to meet the individual requirements of the product:
  • the oxidation dyes are characterized by excellent, long-lasting dyeing results. For naturally acting dyeings but usually a mixture of a larger number of oxidation dye precursors must be used; In many cases, direct dyes are still used for shading. If the dyes formed or used directly in the course of color formation have significantly different fastnesses (eg UV stability, perspiration fastness, washfastness, etc.), then a noticeable and therefore undesirable color shift can occur over time. This phenomenon occurs more frequently when the hairstyle has hair or hair zones of different degrees of damage. An example of this is long hair, in which the hair tips exposed for a long time to all sorts of environmental influences are usually much more damaged than the relatively newly regrown hair zones.
  • fastnesses eg UV stability, perspiration fastness, washfastness, etc.
  • dyeing or tinting agents which contain so-called direct drawers as a coloring component. These are dye molecules that attach directly to the hair and do not require an oxidative process to form the paint. These dyes include, for example, the henna already known from antiquity for coloring body and hair. These dyeings are generally much more sensitive to shampooing than the oxidative dyeings, so that a much more undesirable change in shade or even a visible "discoloration" occurs much faster.
  • silicone resin it is desirable to incorporate a silicone resin quickly and without much effort in common cosmetic preparations, in particular surfactant-containing preparations.
  • cold-working is preferred, as compared to a rinse, the silicone resin can not be heated and melted as part of the process.
  • a sparingly soluble silicone resin requires a large amount of energy in the form of agitation and heat to melt.
  • An object of this invention was to develop a hair cleanser, which on the one hand ensures better adhesion of the hair dyes on the keratin fibers and thus contributes to color retention and color protection and on the other hand protects the dyed hair from external environmental influences. Furthermore, this special hair cleanser should naturally ensure the cleaning and especially the care of the hair, because tinted and colored hair requires special, intensive care, as it is often heavily damaged by the dyeing process and damaged.
  • silicone resins for example trimethylsiloxysilicate or mixtures of trimethylsiloxysilicates and polypropylsilsesquioxanes
  • silicone resins for example trimethylsiloxysilicate or mixtures of trimethylsiloxysilicates and polypropylsilsesquioxanes
  • cosmetic preparations in particular shampoos, which comprise
  • a disperse phase chosen from the group of b1) comprising fully methylated linear siloxane polymers having terminal trimethylsiloxane units with chain lengths of about 100-500, preferably 200-350, siloxane units, the
  • the fully methylated linear siloxane polymers having terminal hydroxy-dimethylsiloxate units with chain lengths of about 100-500, preferably 200-350 siloxane units may be included, the
  • b4) contains one or more silicone resins.
  • Silicone resins advantageous according to the invention are crosslinked polysiloxanes. A distinction is made between silicone resins on the basis of different monomer units as follows: R3Si01 / 2 (M), R2Si02 / 2 (D), RSi03 / 2 (T), Si04 / 2 (Q).
  • MQ silicone resin trimethylsiloxysilicate
  • MQ / TPr silicone resin mixtures of trimethylsiloxysilicate and polypropylsilsesquioxane
  • Silicone resins are widely used in car care, household and leather care products; but they are also already used in the cosmetics sector.
  • the document EP 0 560 879 B1 already discloses a hair treatment preparation with 0, 1% to 10% of dispersed silicone which, inter alia, contains certain silicone-soluble but water-insoluble silicone resins.
  • US 20070269389 A1 already discloses formulations with film-forming systems, which may also contain trimethylsiloxysilicates.
  • the document WO 2009/080964 A3 already discloses make-up products with certain silicone resins.
  • the document US Pat. No. 7,601,179 B2 already discloses a method for protecting keratinic fibers, which makes use of silsesquioxanes or trimethylsiloxysilicates in combination with a nylon 61 / dimethicone copolymer.
  • the documents WO 2005/075542 A1 and WO 2005/075567 A1 already disclose specific silicone resins.
  • the document WO 2005/100444 A1 already discloses silsesquioxane resin waxes.
  • WO 2012/041756 describes preparations which comprise one or more completely methylated linear siloxane polymers having terminal trimethylsiloxate units of indefinite chain length ("dimethicone") and which also contains one or more silicone resins show that the silicone resins were incorporated into the dimethicone.
  • hair care formulations according to the invention it is possible from various application forms (rinse-off, leave-on) to leave an occlusive film on the hair which protects the hair color from being washed out with water and shampoo. Hair treated with semipermanent hair colors can be protected particularly well by the preparations according to the invention.
  • the silicone resin has a molecular weight of 12 to 35 kg / mol, more preferably 15 to 32 kg / mol.
  • the silicone resin additionally contains T or D monomer units. It is particularly preferred if the silicone resin contains M and Q and either T or D monomer units whose ratio M: Q is from 0.5: 1 to 1: 1 and the weight fraction of D or T units is 30 to 70 wt .-% is.
  • T-propyl or D are used as the T or D monomer units. It is thus preferred if, in addition to trimethylsiloxysilicates, polypropylsilsesquioxanes are present.
  • linear and / or volatile dimethicones are used as the D monomer units, preferably a linear polydimethylsiloxane with low viscosity (90 to 110 mm 2 / s) and low molecular weight or instead cyclopentasiloxane is contained.
  • Silicone resins which are particularly preferred are the products trimethylsiloxysilicate + cyclomethicone, Momentive® 4230, trimethylsiloxysilicate + dimethicone, Dow Corning 593 fluid, blend of trimethylsiloxysilicate and polypropylsilsesquioxane, Dow Corning MQ-1640.
  • polydimethylsiloxane is additionally present, preferably a linear polydimethylsiloxane with low viscosity (90 to 1 10 mm2 / s) and low molecular weight is contained, more preferably in concentrations of 2 to 7 wt .-%, most preferably in a concentration of 4.6 wt .-%, and the preparation while 0 to 0.5 wt .-% water. It is particularly preferred if in addition 0.2 to
  • the preparations are advantageously prepared by initially introducing one or more substances from groups b1, b2, or b3, in particular dimethicone, and heating with stirring, temperatures of about 65 ° C. being advantageous.
  • the silicone resin or the silicone resins are then added gradually with stirring and stirred until it or they have clearly dissolved or have.
  • Up to 50% silicone resin in the phase of b1, b2 and / or b3, in particular dimethicone, can be dissolved.
  • This preliminary solution can then be combined with the aqueous phase of the preparations. Dimethicone with a viscosity of 5 mm 2 / s is particularly preferred.
  • cationic surfactants which can be used in the context of the present invention are, in particular, quaternary ammonium compounds.
  • antimony halides such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, eg. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride.
  • Alkylamidoamines in particular fatty acid amidoamines, such as the stearylamidopropyldimethylamine obtainable under the name Tego Amid TM S 18, are further distinguished by their good biodegradation behavior. availability. Likewise very readily biodegradable are quaternary ester compounds, so-called “esterquats", such as the methylhydroxyalkyldialkoyloxyalkylammonium methosulphates sold under the trademark Stepantex TM, and the corresponding products which are commercially available under the trademark Dehyquart TM.
  • esterquats such as the methylhydroxyalkyldialkoyloxyalkylammonium methosulphates sold under the trademark Stepantex TM, and the corresponding products which are commercially available under the trademark Dehyquart TM.
  • quaternary sugar derivative which can be used as cationic surfactant is the commercial product Glucquat TM 100, according to CTFA nomenclature a "Lauryl Methyl Gluceth-10 Hydroxypropyl Dimonium Chloride”.
  • Suitable anionic surfactants are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. Example, a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 10 to 22 carbon atoms.
  • anionic group such as. Example, a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 10 to 22 carbon atoms.
  • glycol or polyglycol ether groups, ether, amide and hydroxyl groups and, as a rule, ester groups can also be present in the molecule.
  • Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids having 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule, and in particular salts of saturated and in particular unsaturated C 8 -C 22 -carboxylic acids, such as oleic acid, stearic acid, isostearic acid and palmitic acid. Particularly preferred are the anionic surfactants containing at least one carboxylate group.
  • Preparations according to the invention comprise at least one or more border-active or surface-active substance or substances, commonly referred to as surfactants, where in principle both anionic and zwitterionic, ampholytic, nonionic and cationic surfactants are suitable. In many cases, however, it has proved to be advantageous to select the surfactants from anionic, zwitterionic or nonionic surfactants. Anionic surfactants may be very particularly preferred.
  • Zwitterionic surfactants are surface-active compounds which carry at least one quaternary ammonium group and at least one -COO (-) or -SO 3 (-) group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinates, for example the kosalkyl-dimethylammoniumglycinat, N-acyl-aminopropyl-N, N-dimethyl-ammoniumglycinate, for example, the cocoacylamino-propyl dimethylammonium glycinate, and 2-alkyl-3-carboxymethyl-3-hydroxyethyl-imidazolines each having 8 to 18 C atoms in the alkyl or acyl group, and the cocoacyl aminoethyl-hydroxyethylcarboxymethylglycinat.
  • a favorite The zwitterionic ionic surfactant is the
  • Ampholytic surfactants are understood as meaning those surface-active compounds which, apart from a C 8 -C 18 -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO 3 H group and are capable of forming internal salts.
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 18 C Atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C12-18-acylsarcosine.
  • Nonionic surfactants contain as hydrophilic group z.
  • a polyol group a polyalkylene glycol ether group or a combination of polyol and polyglycol ether group.
  • Such compounds are, for example:
  • the compounds containing alkyl groups used as surfactants may each be uniform substances. However, it is generally preferred to use native plant or animal raw materials in the production of these substances, so that substance mixtures having different alkyl chain lengths depending on the respective raw material are obtained.
  • both products with a "normal” homolog distribution are meant mixtures of homologs which are obtained in the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alkoxides as catalysts. Narrowed homolog distributions, on the other hand, are obtained when, for example, hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates are used as catalysts. The use of products with narrow homolog distribution may be preferred.
  • auxiliaries and additives are, for example, nonionic polymers such as, for example, vinylpyrrolidone / vinyl acrylate copolymers, polyvinylpyrrolidone and vinylpyrrolidone / vinyl acetate copolymers and polysiloxanes,
  • cationic polymers such as quaternized cellulose ethers, quaternary group polysiloxanes, dimethyldiallylammonium chloride polymers, acrylamide-dimethyldiallylammonium chloride copolymers, diethyl sulfate-quaternized dimethylaminoethylmethacrylate-vinylpyrrolidone copolymers, vinylpyrrolidone-imidazolinium methochloride copolymers, and quaternized polyvinyl alcohol;
  • zwitterionic and amphoteric polymers such as, for example, acrylamidopropyl trimethyl ammonium chloride / acrylate copolymers and octyl acrylamide / methyl methacrylate / tert.butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers, anionic polymers such as polyacrylic acids, crosslinked polyacrylic acids, vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers , Vinyl acetate / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / maleic anhydride copolymers and acrylic acid / ethyl acrylate / N-tert-butyl acrylamide terpolymers,
  • Thickeners such as agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. For example, methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays such. As bentonite or fully synthetic hydrocolloids such. For example, polyvinyl alcohol,
  • Structurants such as maleic acid and lactic acid
  • hair-conditioning compounds such as phospholipids, for example soya lecithin, egg lecithin and cephalins, and silicone oils,
  • Protein hydrolysates in particular elastin, collagen, keratin, milk protein, soy protein and wheat protein hydrolysates, their condensation products with fatty acids and quaternized protein hydrolysates,
  • Dimethylisosorbide and cyclodextrins Dimethylisosorbide and cyclodextrins, Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol,
  • Anti-dandruff agents such as Piroctone Olamine and Zinc Omadine
  • Active substances such as panthenol, pantothenic acid, allantoin, pyrrolidonecarboxylic acids and their salts, plant extracts and vitamins,
  • Bodying agents such as sugar esters, polyol esters or polyol alkyl ethers,
  • Fats and waxes such as spermaceti, beeswax and montan wax,
  • Swelling and penetration substances such as glycerol, propylene glycol monoethyl ether, carbonates, bicarbonates, guanidines, ureas and primary, secondary and tertiary phosphates,
  • Opacifiers such as latex,
  • Propellants such as propane-butane mixtures, N 2 O, dimethyl ether, CO 2 and air,
  • the constituents of the water-containing carrier are used to prepare the agents according to the invention in amounts customary for this purpose; z. B. emulsifiers in concentrations of 0.5 to 30 wt .-% and thickening agents in concentrations of 0.1 to 25 wt .-% of the total preparation used.
  • Dimethicone is introduced and heated with stirring to about 65 ° C. Dimethicone DM5 with a viscosity of 5mm 2 / s is particularly suitable for dissolving the silicone resin. Subsequently, the silicone resin is added gradually with stirring to the dimethicone and stirred until it has dissolved clear. Up to 50% silicone resin can be dissolved in the dimethicone.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne des préparations cosmétiques, notamment des shampooings contenant a) une phase aqueuse renfermant une ou plusieurs substances tensioactives, b) une phase dispersée choisie dans le groupe b1) des polymères de siloxane linéaires entièrement méthylés comprenant des unités triméthylsiloxate terminales présentant des longueurs de chaîne d'environ 100 - 500, de préférence de 200 - 350 unités siloxane, b2) des polymères de siloxane linéaires entièrement méthylés comprenant des unités hydroxy-diméthylsiloxate terminales présentant des longueurs de chaîne d'environ 100 - 500, de préférence de 200 - 350 unités siloxane, b3) des polymères de siloxane cycliques entièrement méthylés comprenant 3 à 10 unités siloxane, et b4) une ou plusieurs résines de silicone.
PCT/EP2015/060300 2014-06-04 2015-05-11 Shampooings cosmétiques contenant des résines de silicone dispersées dans de l'huile de silicone WO2015185329A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP15723676.1A EP3151922A1 (fr) 2014-06-04 2015-05-11 Shampooings cosmétiques contenant des résines de silicone dispersées dans de l'huile de silicone

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102014210575.7 2014-06-04
DE102014210575.7A DE102014210575A1 (de) 2014-06-04 2014-06-04 Kosmetische Shampoos mit einem Gehalt an in Silikonöl dispergierten Silikonharzen

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WO2015185329A1 true WO2015185329A1 (fr) 2015-12-10

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PCT/EP2015/060300 WO2015185329A1 (fr) 2014-06-04 2015-05-11 Shampooings cosmétiques contenant des résines de silicone dispersées dans de l'huile de silicone

Country Status (4)

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EP (1) EP3151922A1 (fr)
DE (1) DE102014210575A1 (fr)
MA (1) MA40187A (fr)
WO (1) WO2015185329A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180214369A1 (en) * 2017-01-31 2018-08-02 L'oréal Long-wear compositions containing silicone resin and silicone elastomer resin
CN114539526A (zh) * 2020-11-24 2022-05-27 陈才虎 一种个人护理用液体丙基硅树脂共混物的制备方法

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JPS61161214A (ja) * 1985-01-11 1986-07-21 Shiseido Co Ltd 毛髪化粧料
US5286476A (en) * 1987-03-30 1994-02-15 Shiseido Company Ltd. Hair cosmetic composition
US5302382A (en) * 1993-06-03 1994-04-12 Dow Corning Corporation Silicone containing personal care products
EP0560879B1 (fr) 1990-12-05 1996-01-17 The Procter & Gamble Company Compositions pour cheveux a base d'un conditionneur aux silicones contenant une resine de silicones
US5536493A (en) * 1989-10-13 1996-07-16 L'oreal Composition for washing keratinous materials in particular hair and/or skin
WO2005075567A1 (fr) 2004-02-02 2005-08-18 Dow Corning Corporation Compositions de resine siloxane mq et t-propyle
WO2005075542A1 (fr) 2004-02-02 2005-08-18 Dow Corning Corporation Resines au propyle siloxane mq-t
WO2005100444A1 (fr) 2004-04-12 2005-10-27 Dow Corning Corporation Cire de resine silsesquioxane
US20060165628A1 (en) * 2003-08-21 2006-07-27 Kao Corporation Hair care product
EP1119339B1 (fr) 1998-10-09 2007-09-26 Colgate-Palmolive Company Shampooing stabilise contenant des matieres siloxysilicates
US20070269389A1 (en) 2003-12-15 2007-11-22 Rodrigo Fuscelli Pytel Base Composition for Preparing Multi-Functional Formulations for Care and Protection of the Skin and Hair
EP2016933A1 (fr) 2007-07-13 2009-01-21 L'Oréal Composition cosmétique anhydre comprenant un copolymère silicone adhésif sensible à la pression, une silicone volatile et une silicone fluide particulière
WO2009080964A2 (fr) 2007-12-05 2009-07-02 L'oreal Procede cosmetique utilisant une composition comprenant une resine de siloxane et une huile non volatile
US7601179B2 (en) 2007-09-14 2009-10-13 L'oreal S.A. Methods of preserving artificial coloring on keratin materials
US20110308541A1 (en) * 2009-02-04 2011-12-22 Wi-Soon Chia Hair treatment composition
WO2012041756A2 (fr) 2010-10-01 2012-04-05 Beiersdorf Ag Produits de soin pour protéger des cheveux colorés comprenant des résines de silicone

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61161214A (ja) * 1985-01-11 1986-07-21 Shiseido Co Ltd 毛髪化粧料
US5286476A (en) * 1987-03-30 1994-02-15 Shiseido Company Ltd. Hair cosmetic composition
US5536493A (en) * 1989-10-13 1996-07-16 L'oreal Composition for washing keratinous materials in particular hair and/or skin
EP0560879B1 (fr) 1990-12-05 1996-01-17 The Procter & Gamble Company Compositions pour cheveux a base d'un conditionneur aux silicones contenant une resine de silicones
US5710113A (en) * 1990-12-05 1998-01-20 The Procter & Gamble Company Hair conditioning compositions with silicone conditioning agent containing silicone resin
US5302382A (en) * 1993-06-03 1994-04-12 Dow Corning Corporation Silicone containing personal care products
EP1119339B1 (fr) 1998-10-09 2007-09-26 Colgate-Palmolive Company Shampooing stabilise contenant des matieres siloxysilicates
US20060165628A1 (en) * 2003-08-21 2006-07-27 Kao Corporation Hair care product
US20070269389A1 (en) 2003-12-15 2007-11-22 Rodrigo Fuscelli Pytel Base Composition for Preparing Multi-Functional Formulations for Care and Protection of the Skin and Hair
WO2005075567A1 (fr) 2004-02-02 2005-08-18 Dow Corning Corporation Compositions de resine siloxane mq et t-propyle
WO2005075542A1 (fr) 2004-02-02 2005-08-18 Dow Corning Corporation Resines au propyle siloxane mq-t
WO2005100444A1 (fr) 2004-04-12 2005-10-27 Dow Corning Corporation Cire de resine silsesquioxane
EP2016933A1 (fr) 2007-07-13 2009-01-21 L'Oréal Composition cosmétique anhydre comprenant un copolymère silicone adhésif sensible à la pression, une silicone volatile et une silicone fluide particulière
US7601179B2 (en) 2007-09-14 2009-10-13 L'oreal S.A. Methods of preserving artificial coloring on keratin materials
WO2009080964A2 (fr) 2007-12-05 2009-07-02 L'oreal Procede cosmetique utilisant une composition comprenant une resine de siloxane et une huile non volatile
US20110308541A1 (en) * 2009-02-04 2011-12-22 Wi-Soon Chia Hair treatment composition
WO2012041756A2 (fr) 2010-10-01 2012-04-05 Beiersdorf Ag Produits de soin pour protéger des cheveux colorés comprenant des résines de silicone

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180214369A1 (en) * 2017-01-31 2018-08-02 L'oréal Long-wear compositions containing silicone resin and silicone elastomer resin
CN114539526A (zh) * 2020-11-24 2022-05-27 陈才虎 一种个人护理用液体丙基硅树脂共混物的制备方法
CN114539526B (zh) * 2020-11-24 2023-11-07 陈才虎 一种个人护理用液体丙基硅树脂共混物的制备方法

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MA40187A (fr) 2017-04-12
DE102014210575A1 (de) 2015-12-17

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