WO2015182152A1 - 乗用車用空気入りラジアルタイヤ - Google Patents
乗用車用空気入りラジアルタイヤ Download PDFInfo
- Publication number
- WO2015182152A1 WO2015182152A1 PCT/JP2015/002710 JP2015002710W WO2015182152A1 WO 2015182152 A1 WO2015182152 A1 WO 2015182152A1 JP 2015002710 W JP2015002710 W JP 2015002710W WO 2015182152 A1 WO2015182152 A1 WO 2015182152A1
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- WIPO (PCT)
- Prior art keywords
- tire
- rubber
- tread
- width
- width direction
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C3/00—Tyres characterised by the transverse section
- B60C3/04—Tyres characterised by the transverse section characterised by the relative dimensions of the section, e.g. low profile
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0041—Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/03—Tread patterns
- B60C11/04—Tread patterns in which the raised area of the pattern consists only of continuous circumferential ribs, e.g. zig-zag
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/03—Tread patterns
- B60C11/12—Tread patterns characterised by the use of narrow slits or incisions, e.g. sipes
- B60C11/1236—Tread patterns characterised by the use of narrow slits or incisions, e.g. sipes with special arrangements in the tread pattern
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C17/00—Tyres characterised by means enabling restricted operation in damaged or deflated condition; Accessories therefor
- B60C17/0009—Tyres characterised by means enabling restricted operation in damaged or deflated condition; Accessories therefor comprising sidewall rubber inserts, e.g. crescent shaped inserts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0008—Tyre tread bands; Tread patterns; Anti-skid inserts characterised by the tread rubber
- B60C2011/0016—Physical properties or dimensions
- B60C2011/0025—Modulus or tan delta
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/01—Shape of the shoulders between tread and sidewall, e.g. rounded, stepped or cantilevered
- B60C2011/016—Shape of the shoulders between tread and sidewall, e.g. rounded, stepped or cantilevered different rubber for tread wings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C17/00—Tyres characterised by means enabling restricted operation in damaged or deflated condition; Accessories therefor
- B60C17/0009—Tyres characterised by means enabling restricted operation in damaged or deflated condition; Accessories therefor comprising sidewall rubber inserts, e.g. crescent shaped inserts
- B60C2017/0054—Physical properties or dimensions of the inserts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C2200/00—Tyres specially adapted for particular applications
- B60C2200/04—Tyres specially adapted for particular applications for road vehicles, e.g. passenger cars
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Definitions
- the present invention relates to a pneumatic radial tire for passenger cars.
- Patent Document 1 Conventional vehicles up to about 1960 used a bias tire with a light weight and a low cruising speed required for the vehicle, so the burden on the tire was light and the cross-sectional width of the tire was narrow. With increasing weight and speed of vehicles, radial and wide tires are being promoted (for example, Patent Document 1).
- the applicant of the present invention has a specific relationship between the tire internal pressure, the cross-sectional width (SW), and the tire outer diameter (OD).
- a technology related to a pneumatic radial tire for passenger cars having a large tire outer diameter) is proposed (for example, Patent Document 2).
- wet performance is an index relating to braking performance on a wet road surface.
- an object of the present invention is to provide a pneumatic radial tire for a passenger car that has improved wet performance and rolling resistance performance in a radial tire having a narrow width and a large diameter.
- a pneumatic radial tire for a passenger car includes a carcass made of a carcass ply of a radial arrangement cord straddling a toroidal shape between a pair of bead parts, and a tread rubber provided on the outer side in the tire radial direction of the carcass to form a tread tread surface
- a pneumatic radial tire for a passenger car that is located on the outer side in the tire width direction of the tread rubber and forms a buttress portion, when the tire is incorporated in a rim and the internal pressure is 250 kPa or more
- the cross-sectional width SW of the tire is less than 165 (mm)
- the ratio SW / OD of the cross-sectional width SW of the tire to the outer diameter OD (mm) is 0.26 or less
- the cross-section of the tire When the width SW is 165 (mm) or more, the cross-sectional width SW and the outer diameter OD (mm) of the tire are represented by the relational expression: 2.135 ⁇ SW +
- the loss tangent tan ⁇ of the tread rubber at 60 ° C. is 0.05 to 0. .15
- the dynamic storage elastic modulus E ′ at 30 ° C. of the buttress rubber is 1 ⁇ 2 or less of the dynamic storage elastic modulus E ′ of the tread rubber
- the buttress rubber has a 60 ° C.
- the loss tangent tan ⁇ at is 0.1 or less.
- the sectional width SW and the outer diameter OD of the tire are the same as the sectional width and outer diameter specified in JIS D 4202-1994, respectively, when the tire is mounted on a rim and the inner pressure is 250 kPa or more.
- rim is an industrial standard effective for the area where tires are produced and used.
- JATMA Japanese Automobile Tire Association
- JATMA YEAR BOOK and in Europe, ETRTO (The European Tire and RIM Technical Organization's STANDARDDS MANUAL, TRA (The Tile and Rim Association, Inc.) YEAR BOOK, etc.
- rims in applicable sizes include the sizes described as “FUTURE DEVELOPMENTS” in the 2013 edition of ETRTO.) are described in the industrial standards. In the case of a size having no, it means a rim having a width corresponding to the tire bead width.
- dynamic storage elastic modulus E ′ MPa and loss tangent tan ⁇ (ratio of dynamic loss elastic modulus (E ′′) and dynamic storage elastic modulus (E ′) (E ′′ / E ′)) ) Is a value obtained by applying an initial load of 160 g to a test piece having a thickness of 2 mm, a width of 5 mm, and a length of 20 mm, and an initial strain of 1% and a frequency of 50 Hz.
- the dynamic storage elastic modulus E ′ is a value measured at a temperature of 30 ° C. unless otherwise specified (hereinafter, the dynamic storage elastic modulus E ′ at 30 ° C. may be simply referred to as “E ′”).
- the loss tangent tan ⁇ is a value measured at a temperature of 60 ° C. unless otherwise specified (hereinafter, the loss tangent tan ⁇ at 60 ° C. may be simply referred to as “tan ⁇ ”).
- the buttress portion is a virtual line extending in the tire radial direction through the tread contact end in the tire width direction cross-sectional view, and a peripheral length from the tread contact end to the tire surface position corresponding to the tire cross-sectional width SW. It refers to a tire portion that is sandwiched between imaginary lines that extend in the tire width direction through the tire surface position that is half the length.
- the tread ground contact edge is the outermost position of the tread surface in the tread width direction.
- tread surface is a tire that is incorporated in the rim and applied with an internal pressure of 250 kPa or more and has a maximum load capacity of 75.
- tread rubber and buttress rubber mean rubber that does not include members such as a belt and a carcass optionally included in the tread portion and buttress portion.
- the buttress rubber has the desired dynamic storage elastic modulus E ′ at 30 ° C. and the desired loss tangent tan ⁇ at 60 ° C. in the cross-sectional view in the tire width direction.
- the rubber sandwiched between the tire radial inner end and the imaginary line extending in the tire radial direction through the tire surface position moved by 10 mm from the tread contact edge to the outer side in the tire width direction is at least a desired E ′ and It means tan ⁇ .
- the dynamic storage elastic modulus E ′ of the tread rubber at 30 ° C. is 7.9 to 11.0 MPa, and the dynamic storage of the buttress rubber at 30 ° C.
- the elastic modulus E ′ is preferably 3 MPa or less. According to this configuration, wet performance and rolling resistance performance can be further improved.
- FIG. 1 is a tire width direction sectional view showing a pneumatic radial tire for a passenger car according to a first embodiment of the present invention.
- A It is a figure for demonstrating the wet performance of a wide radial tire
- b It is a figure for demonstrating the wet performance of a radial radial tire.
- It is a schematic development view showing a first example of a tread pattern.
- It is a schematic expanded view which shows the 2nd example of a tread pattern.
- It is a schematic expanded view which shows the 3rd example of a tread pattern.
- tire 1 a pneumatic radial tire for passenger cars (hereinafter, also simply referred to as “tire”) 1 according to a first embodiment of the present invention will be described in detail with reference to the drawings.
- tire also simply referred to as “tire”
- the following description and drawing are examples for demonstrating the tire 1 which concerns on this invention, and this invention is not limited to the form shown and illustrated at all.
- the tire 1 according to the first embodiment of the present invention includes, for example, a carcass 3 composed of a carcass ply of a radial arrangement cord straddling a toroidal shape between a pair of bead portions 2 as shown in a cross-sectional view in the tire width direction of FIG. And a tread rubber 41 provided on the outer side in the tire radial direction of the carcass 3, and a buttress rubber 51 which is located on the outer side in the tire width direction of the tread rubber 41 and forms the buttress portion 5.
- the tire 1 includes a tread portion 4, a pair of buttress portions 5 extending continuously to the side portions of the tread portion 4, and a pair of sides extending radially inward from the buttress portions 5.
- a wall portion 6 and a bead portion 2 continuous to the inner end in the tire radial direction of each sidewall portion 6 are provided.
- the tire 1 includes a carcass 3 composed of one or more (one in the illustrated example) carcass plies that extend in a toroidal shape from one bead portion 2 to the other bead portion 2, and a tread portion.
- a belt 7 composed of one or more layers (three layers in the illustrated example) that reinforce the belt 4.
- the tread tread surface T can be provided with a circumferential main groove 8 continuously extending in the tire circumferential direction.
- the two circumferential main grooves 8 are provided.
- Three rib-shaped land portions are formed on the tread surface T.
- the circumferential main groove 8 is not an essential configuration.
- the buttress portion 5 is located on the outer surface side of the tire from the carcass 3, more specifically, on the outer surface side of the tire from the carcass 3 and the belt 7, adjacent to the outer side in the tire width direction of the tread rubber 41.
- a rubber 51 is provided.
- the buttress portion 5 specifically includes a virtual line Le that extends in the tire radial direction through the tread ground end E and a cross section width SW of the tire 1 from the tread ground end E in the tire width direction cross-sectional view. This is a tire portion that is sandwiched between a virtual line Lh that extends in the tire width direction through the tire surface position that is half the length of the peripheral length to the position.
- the cross-sectional width SW of the tire 1 when the tire 1 is incorporated in the rim and the internal pressure is 250 kPa or more and the cross-sectional width SW of the tire 1 is less than 165 (mm), the cross-sectional width SW of the tire 1 and the outer diameter
- the ratio SW / OD with respect to OD (mm) is 0.26 or less and the sectional width SW of the tire 1 is 165 (mm) or more
- the sectional width SW and the outer diameter OD (mm) of the tire 1 are Relational expression, 2.135 ⁇ SW + 282.3 ⁇ OD (Hereinafter also referred to as satisfying relational expression (1)).
- the tire 1 Since the tire 1 has the above-described relationship, the tire 1 has a narrow shape and a large diameter, can improve the rolling resistance performance of the tire 1 (reduce the rolling resistance value), and can reduce the weight of the tire 1. .
- the internal pressure of the tire 1 is preferably 250 kPa or more, and more preferably 250 to 350 kPa.
- the contact length tends to increase, but by increasing the contact length to 250 kPa or more, the increase in the contact length is suppressed, the deformation amount of the tread rubber is reduced, and the rolling resistance is further reduced. Because it can.
- the cross-sectional width SW and the outer diameter OD of the tire 1 are ⁇ 0.0187. It is preferable that ⁇ SW 2 + 9.15 ⁇ SW ⁇ 380 ⁇ OD (hereinafter, this equation is also referred to as a relational expression (2)).
- the belt 7 can be constituted by an arbitrary number of belt layers of one or more layers.
- the belt cords are sequentially arranged in the tire radial direction with respect to the tire circumferential direction on the outer side in the tire radial direction of the carcass 3.
- the belt is composed of two layers of inclined belt layers 71 and 72 that are inclined in the opposite direction and intersect with each other, and one belt reinforcing layer 73 in which the belt cord extends along the tire circumferential direction.
- the two inclined belt layers 71 and 72 are inclined at an angle of 35 ° or more with respect to the tire circumferential direction, respectively, and the inclined belt layer 71 on the inner side in the tire radial direction is the outer inclined belt layer 72. Wider than.
- the single belt reinforcing layer 73 has a width that covers the inclined belt layers 71 and 72.
- the inclined belt layers 71 and 72 are inclined by 35 ° or more with respect to the tire circumferential direction, the rolling resistance performance and the cornering power during cornering in the tire 1 in which the cross-sectional width SW and the outer diameter OD of the tire 1 are in the above-described ranges. Can be improved.
- the dynamic storage elastic modulus E ′ of the tread rubber 41 at 30 ° C. is 6.0 to 12.0 MPa.
- the friction coefficient ⁇ in the wet state can be improved, so that the wet performance is improved. be able to.
- the dynamic storage elastic modulus E ′ it is possible to improve cornering power during cornering and improve steering stability.
- the dynamic storage elastic modulus E ′ is preferably 7.9 to 12.0 MPa, and more preferably 8.0 to 11.0 MPa.
- the loss tangent tan ⁇ at 60 ° C. of the tread rubber 41 is 0.05 to 0.15. Thereby, rolling resistance performance can be improved.
- the tire 1 since the tire 1 includes the tread rubber 41 as described above, the wet performance and the rolling resistance performance can be improved, but further improvement of the wet performance and the rolling resistance performance has been demanded. Therefore, in the tire 1, the dynamic storage elastic modulus E ′ at 30 ° C. of the buttress rubber 51 is set to 1 ⁇ 2 or less of the dynamic storage elastic modulus E ′ of the tread rubber 41, and the 60 The loss tangent tan ⁇ at 0 ° C. is set to 0.1 or less.
- the rolling resistance performance of the tire 1 can be improved. Specifically, when the tire 1 rolls, the buttress rubber 51 adjacent to the ground contact surface of the tire 1 is bent and distorted, so that the rolling resistance value obtained by the product of the rubber distortion and the rubber rigidity is obtained. Had an influence. In particular, since the tire 1 has a narrow and large-diameter shape, strain energy loss due to wiping when the tire 1 is in contact tends to be large.
- the E ′ and tan ⁇ of the buttress rubber 51 are outside the above ranges, for example, the buttress rubber 51 Compared to the case where the rubber has the same physical properties as the tread rubber 41, the rigidity of the buttress rubber 51 is reduced, so that the rolling resistance value can be reduced (that is, the rolling resistance performance can be improved).
- the wiping is a road surface when the tire 1 is grounded due to a difference between the tire width direction length of the tread tread surface T and the tire width direction length of the belt 7 of the tread portion 4 in a cross-sectional view in the tire width direction. This is because the tread rubber 41 that is in contact with the ground is pulled by the belt together with the buttress rubber 51 to cause shear strain in the tire width direction inside.
- the dynamic storage elastic modulus E ′ of the buttress rubber 51 is more than half of the dynamic storage elastic modulus E ′ of the tread rubber 41, and the loss tangent tan ⁇ of the buttress rubber 51 is 0.1 or less. In some cases, the hysteresis loss due to the viscoelasticity of the rubber is small, but the strain energy (strain ⁇ stress) of the buttress rubber 51 is large and the strain energy loss is large, so that the rolling resistance value cannot be reduced. Further, the dynamic storage elastic modulus E ′ of the buttress rubber 51 is less than or equal to 1 ⁇ 2 of the dynamic storage elastic modulus E ′ of the tread rubber 41, and the loss tangent tan ⁇ of the buttress rubber 51 is more than 0.1.
- the strain energy (strain ⁇ stress) of the buttress rubber 51 is small, but the hysteresis loss due to the viscoelasticity of the rubber is large and the strain energy loss is large, so that the rolling resistance value cannot be reduced.
- the dynamic storage elastic modulus E ′ of the buttress rubber 51 is defined with respect to the dynamic storage elastic modulus E ′ of the tread rubber 41. The higher the dynamic storage elastic modulus E ′ of the tread rubber 41, the greater the strain energy. This is because, although (strain ⁇ stress) is small, but the buttress rubber 51 has higher strain energy (strain ⁇ stress) as the dynamic storage elastic modulus E ′ increases.
- the dynamic storage elastic modulus E ′ at 30 ° C. of the tread rubber 41 is 7.9 to 11.0 MPa
- the dynamic storage elastic modulus E ′ at 30 ° C. of the buttress rubber 51 is 3 MPa or less. Is preferred.
- wet performance and rolling resistance performance can be further improved.
- the dynamic storage elastic modulus E ′ of the tread rubber 41 is set within the above range.
- the friction coefficient ⁇ at the time of wet is improved to improve the wet performance
- the cornering power is improved to improve the steering stability.
- the dynamic storage elastic modulus E ′ of the buttress rubber 51 is set to 3 MPa or less. The strain energy loss of the buttress rubber 51 can be reduced.
- the buttress rubber 51 forming the buttress portion 5 as a whole has the dynamic storage elastic modulus E ′ and the loss tangent tan ⁇ within the predetermined ranges described above.
- the imaginary line Le extending in the tire radial direction through the tread grounding end E and the tire moved from the tread grounding end E to the outer side in the tire width direction by 10 mm in peripheral length The rubber sandwiched between the virtual line Le ′ extending in the tire radial direction through the surface position may be out of the range of E ′ and tan ⁇ .
- the rubber sandwiched between the inner end in the tire radial direction (imaginary line Lh) of the buttress portion 5 and the imaginary line Le ′ is at least E ′ and tan ⁇ within the predetermined range. I just need it.
- the rubber sandwiched between the virtual line Le and the virtual line Le ′ can have, for example, a dynamic storage elastic modulus E ′ and a loss tangent tan ⁇ similar to those of the tread rubber 41. . In such a case, the rolling resistance performance can be further improved.
- the buttress rubber 51 can be configured by a rubber member that is separate from the side wall rubber that forms the side wall portion 6, or can be configured integrally by the same rubber member.
- the two inclined belt layers 71 and 72 are inclined at an angle of 35 ° or more with respect to the tire circumferential direction.
- the buttress portion 5 is likely to be distorted as compared to the inclination of less than 35 °. Therefore, the buttress rubber 51 of the tire 1 having the belt layer inclined to 35 ° or more is described above. It is particularly effective to set the dynamic storage elastic modulus E ′ and the loss tangent tan ⁇ in the range of
- the tread rubber 41 and the buttress rubber 51 are optionally made of conventionally known fillers, anti-aging agents, vulcanizing agents, vulcanization accelerators, process oils, scorch preventing agents, zinc, in addition to conventionally known rubber components. It can be formed by kneading and vulcanizing a rubber composition containing flower, stearic acid and the like according to a conventional method.
- the kneading conditions are not particularly limited, and using a Banbury mixer, roll, internal mixer, etc., depending on the compounding formulation, the input volume to the kneading apparatus, etc., the rotational speed of the rotor, ram pressure, kneading temperature, as appropriate.
- the kneading time may be adjusted.
- the vulcanization temperature can be set to 100 to 190 ° C., for example.
- the vulcanization time can be, for example, 5 to 80 minutes.
- Examples of the rubber components of the tread rubber 41 and the buttress rubber 51 include modified or unmodified styrene-butadiene copolymer rubber (SBR), butadiene rubber (BR), polyisoprene rubber (IR), and isobutylene isoprene rubber (IIR). ), Halogenated butyl rubber, styrene-isoprene copolymer rubber (SIR), synthetic rubber such as chloroprene rubber (CR), and natural rubber (NR).
- SBR styrene-butadiene copolymer rubber
- BR butadiene rubber
- IR polyisoprene rubber
- IIR isobutylene isoprene rubber
- SBR styrene-butadiene copolymer rubber
- BR
- conjugated diene polymer A method in which a modifier is reacted with the active terminal and a condensation reaction involving the modifier in the presence of a titanium-based condensation accelerator can be used.
- a preferred example of the conjugated diene polymer is a copolymer of 1,3-butadiene and styrene.
- the modifier include N, N-bis (trimethylsilyl) aminopropylmethyldimethoxysilane, N, N-bis (trimethylsilyl) aminopropylmethyldiethoxysilane, 1-trimethylsilyl-2-ethoxy-2-methyl-1- Aza-2-silacyclopentane is preferred.
- titanium condensation accelerators examples include tetrakis (2-ethyl-1,3-hexanediolato) titanium, tetrakis (2-ethylhexoxy) titanium, titanium di-n-butoxide (bis-2,4-pentanedionate).
- titanium condensation accelerators include tetrakis (2-ethyl-1,3-hexanediolato) titanium, tetrakis (2-ethylhexoxy) titanium, titanium di-n-butoxide (bis-2,4-pentanedionate).
- filler examples include conventionally known carbon black, silica, calcium carbonate, talc, and clay. You may use said filler individually by 1 type or in combination of 2 or more types.
- the rubber composition forming the tread rubber 41 includes at least a rubber component and a filler.
- the filler includes 50 to 100 parts by mass with respect to 100 parts by mass of the rubber component. It is preferable that Thereby, there exists an advantage that it is excellent in abrasion resistance and workability.
- the filler is more preferably contained in an amount of 55 to 85 parts by mass, further preferably 75 to 85 parts by mass with respect to 100 parts by mass of the rubber component. More preferably, the filler is contained in an amount of 50 to 90 parts by mass with respect to 100 parts by mass of the diene polymer (diene rubber).
- the filler of the tread rubber 41 preferably contains silica, and the silica is preferably contained in an amount of 25 to 100 parts by mass with respect to 100 parts by mass of the rubber component.
- the silica is more preferably contained in an amount of 50 to 75 parts by mass, and more preferably 60 to 75 parts by mass with respect to 100 parts by mass of the rubber component.
- the silica may be treated with a silane coupling agent.
- the modified S-SBR is 20 to 70 phr.
- the silica may be appropriately changed within the range of 30 to 80 phr in the range of 50 to 80 phr of the filler.
- the blend is 100 phr of diene polymer
- the NR is in the range of 0 to 20 phr
- the modified S-SBR The silica may be appropriately changed within the range of 20 to 70 phr and the silica within the range of 30 to 80 phr among the fillers of 50 to 80 phr.
- “Phr” refers to the amount (parts by mass) of various components based on 100 parts by mass of the rubber component.
- the tire size of the pneumatic radial tire for passenger cars of the present invention is specifically 105 / 50R16, 115 / 50R17, 125 / 55R20, 125 / 60R18, 125 / 65R19, 135 / 45R21, 135 / 55R20, 135 / 60R17, 135 / 60R18, 135 / 60R19, 135 / 65R19, 145 / 45R21, 145 / 55R20, 145 / 60R16, 145 / 60R17, 145 / 60R18, 145 / 60R19, 145 / 65R19, 155 / 45R18, 155 / 45R21, 155 / 55R18, 155 / 55R19, 155 / 55R21, 155 / 60R17, 155 / 65R13, 155 / 65R18, 155 / 70R17, 155 / 70R19, 165 / 45R22, 165
- the groove volume ratio (groove volume V2 / tread rubber volume V1) is preferably 20% or less, and the negative ratio (ratio of groove area to tread tread area) is 20% or less. It is preferable. These values are lower than the standard values for conventional size pneumatic radial tires for passenger cars. In order to improve the wet performance, it is a general idea to increase the groove amount. However, a pneumatic radial for a passenger car having a narrow and large diameter that satisfies the above relational expression (1) and / or (2).
- the groove volume ratio is, for example, the tire diameter at the center in the tire width direction at the inner side in the tire width direction from the both ends in the width direction of the maximum width belt layer having the maximum width in the tire width direction of the belt layer.
- the ratio is defined as V2 / V1. Is done.
- the pattern is mainly a rib-like land portion that is partitioned by the end E in the tire width direction.
- the rib-shaped land portion refers to a land portion extending in the tire circumferential direction without having a width-direction groove traversing in the tire width direction, and the rib-shaped land portion is a width-direction groove terminating in the sipe or the rib-shaped land portion. May have.
- various performances can be improved by providing the sipe 100 on the tread surface.
- a one-sided open sipe 100 in which one end of both ends of the sipe is opened in the groove and the other end is terminated in the land portion.
- the circumferential shear rigidity can be increased in comparison with the case of the both-end opening sipe, so that the effect of improving the wet performance by improving the circumferential shear rigidity is obtained. Because it can.
- the one-side opening sipe 100 in combination with a pattern mainly composed of rib-like land portions.
- the circumferential sipe 110 and / or the small holes 111 are provided. It is preferable to provide it.
- the circumferential shear rigidity is increased and drainage is promoted.
- the actual contact area between the tire and the road surface is reduced, which may be a factor for depressing the wet performance. Therefore, by using the circumferential sipe 110 and / or the small holes 111 that reduce the compression rigidity of the rubber, it is possible to reduce the compression rigidity of the rubber and increase the actual contact area.
- the circumferential direction sipe 110 and / or the small holes 111 have a sufficiently small effect of reducing the circumferential shear rigidity, the effect of improving the wet performance due to the improvement of the circumferential shear rigidity can be maintained.
- a negative rate is obtained between the tire width direction half of the vehicle mounting inner side and the vehicle mounting outer side with the tire equator plane CL as a boundary. A difference may be provided.
- a pattern having a width direction groove 120 extending in the tire width direction from the vicinity of the tire equatorial plane CL to the tread ground contact end E may be used. May not be included. According to such a pattern mainly composed of the width direction groove 120, it is possible to effectively exhibit the performance on snow.
- the shoulder rib-shaped land portions that are separated by the outermost circumferential main groove in the tire width direction and the tread contact end E.
- the width in the tire width direction of the shoulder rib-shaped land portion on the vehicle mounting outside and inside can be changed.
- the width in the tire width direction of the shoulder rib-shaped land portion outside the vehicle mounting is larger than the width in the tire width direction of the shoulder rib-shaped land portion inside the vehicle mounting.
- the buckling is suppressed and the cornering power is improved.
- the tire is mounted on the vehicle, it is preferable to provide an end opening groove extending from the circumferential main groove to the vehicle mounting inner side.
- the tread surface with the tire equatorial plane CL as a boundary is adjacent to the tread ground contact E and in the tread width direction with the tread ground contact E.
- a tread ground end side land portion having a tread end side main groove 130 extending in the tread circumferential direction and having a distance of 25% or more of the tread width TW and defined by the tread end side main groove 130 and the tread ground end E.
- At least one end opening groove 132 extending in the tread width direction from the tread ground end side main groove 130 and staying in the adjacent land portion 131 is provided in one of the land portions 131 adjacent to the land portion 131.
- 6 is a shallow groove having a groove depth smaller than that of the main groove.
- a pneumatic radial tire for a passenger car having a narrow width and large diameter that satisfies the above relational expression (1) and / or (2), it receives a compressive stress on the outside of the vehicle and receives a tensile stress on the inside of the vehicle.
- the tread rubber is deformed by these stresses, the belt is deformed, and the ground contact surface is lifted.
- the one end opening groove 132 since there is one end opening groove 132 extending in the tread width direction from the tread grounding end side main groove 130 and staying in the land portion 131, the one end opening groove 132 is closed by the compressive stress on the vehicle mounting outside in the land portion. Therefore, as compared with the case where the one-end opening groove 132 is not provided or the one-end opening groove 132 does not extend to the outside of the vehicle, deformation of the tread and the belt due to compressive stress is suppressed. Furthermore, since the one end opening groove 132 stays in the land portion, the rigidity against the tensile stress inside the vehicle mounting becomes higher compared to the case where the one end opening groove 132 extends to the vehicle mounting inner side. Belt deformation is suppressed.
- the tire radial direction of the straight line m1 and the straight line m2 is a straight line passing through the point P on the tread surface on the equator plane CL and parallel to the tire width direction as m1, and a straight line passing through the ground contact E 'and parallel to the tire width direction as m2.
- the “grounding end E ′” refers to each vehicle on which a tire is mounted on a rim, filled with a maximum air pressure specified for each vehicle on which the tire is mounted, and placed vertically on a flat plate. It refers to both end points in the tire width direction on the contact surface with the flat plate when a weight corresponding to the specified maximum load is applied.
- the tread rubber may be formed by laminating a plurality of different rubber layers in the tire radial direction.
- the plurality of rubber layers those having different tangent loss, modulus, hardness, glass transition temperature, material and the like can be used.
- the ratio of the thickness in the tire radial direction of the plurality of rubber layers may be changed in the tire width direction, or only the circumferential main groove bottom or the like may be a rubber layer different from the periphery thereof.
- the tread rubber may be formed of a plurality of rubber layers different in the tire width direction.
- the plurality of rubber layers those having different tangent loss, modulus, hardness, glass transition temperature, material and the like can be used.
- the dynamic storage elastic modulus E ′ of the tread rubber at 30 ° C.” and “the loss tangent tan ⁇ of the tread rubber at 60 ° C.” The value obtained by adding the dynamic storage elastic modulus E ′ and loss tangent tan ⁇ of each rubber layer to the tire width direction length of the rubber layer and dividing the sum by the tire width direction length of the entire rubber layer.
- the tire of the present invention preferably has an inclined belt layer composed of a rubberized layer of cords extending incline with respect to the tire circumferential direction.
- the inclined belt layer may be only one layer.
- the shape of the ground contact surface during turning tends to be distorted.
- an inclined belt layer extending in a direction in which the cords cross each other between two or more layers.
- a belt structure in which two belt layers form an inclined belt layer is most preferable.
- the width in the tire width direction of the maximum width inclined belt layer having the largest width in the tire width direction is preferably 90% to 115% of the tread width TW, and is 100% to 105% of the tread width TW. It is particularly preferred.
- a metal cord particularly a steel cord is most commonly used as the belt cord of the inclined belt layer, but an organic fiber cord can also be used.
- the steel cord is mainly composed of steel and can contain various trace contents such as carbon, manganese, silicon, phosphorus, sulfur, copper, and chromium.
- a monofilament cord or a cord obtained by twisting a plurality of filaments can be used as the belt cord of the inclined belt layer.
- Various designs can be adopted for the twist structure, and various cross-sectional structures, twist pitches, twist directions, and distances between adjacent filaments can be used.
- the cord which twisted the filament of a different material can also be used, and it does not specifically limit as a cross-sectional structure, Various twisted structures, such as a single twist, a layer twist, a double twist, can be taken.
- the inclination angle of the belt cord of the inclined belt layer is preferably 10 ° or more with respect to the tire circumferential direction.
- the inclination angle of the belt cord of the inclined belt layer is preferably set to a high angle, specifically 35 ° or more with respect to the tire circumferential direction, and particularly within a range of 55 ° to 85 ° with respect to the tire circumferential direction. .
- This is because by setting the inclination angle to 35 ° or more, the rigidity in the tire width direction can be increased, and in particular, the steering stability performance during cornering can be improved.
- the rolling resistance performance can be improved by reducing the shear deformation of the interlayer rubber.
- the tire of the present invention can have a circumferential belt composed of one or more circumferential belt layers outside the inclined belt layer in the tire radial direction.
- the circumferential belt has a tire circumferential rigidity per unit width of the central region C including the tire equatorial plane CL, and other regions. It is preferably higher than the tire circumferential rigidity per unit width.
- FIG. 8 schematically shows an example of a belt structure, in which circumferential belt layers 143 and 144 are laminated on the outer side in the tire radial direction of the inclined belt layers 141 and 142, and in the central region C, the circumferential belt layers 143 and 144 overlap each other in the tire radial direction.
- the tire circumferential rigidity per unit width of the central region C is determined as a unit of other regions. It can be higher than the tire circumferential rigidity per width.
- the tread in a tire having increased rigidity in the tire circumferential direction in the central region including the tire equatorial plane CL, the tread has a land portion continuous in the tire circumferential direction in the region including at least the tire equatorial plane CL of the tread surface. It is preferable to have. If the circumferential main groove is disposed on or near the tire equator plane CL, the rigidity of the tread in the region may be reduced, and the contact length in the land portion defining the circumferential main groove may be extremely short. Therefore, it is preferable to dispose land portions (rib-shaped land portions) continuous in the tire circumferential direction over a certain region including the tire equatorial plane CL from the viewpoint of improving noise performance without reducing cornering power.
- FIG. 9 schematically shows another example of the belt structure, in which one circumferential belt layer 153 is laminated on the outer side in the tire radial direction of the two inclined belt layers 151 and 152.
- the inclined belt layer is inclined in two layers having different widths in the tire width direction.
- the inclination angle ⁇ 1 with respect to the tire circumferential direction of the cord that includes at least the belt layer and forms the widest inclined belt layer, and the inclination angle ⁇ 2 with respect to the tire circumferential direction of the cord that forms the narrowest inclined belt layer are 35 ° ⁇ ⁇ 1 It is preferable that ⁇ 85 °, 10 ° ⁇ ⁇ 2 ⁇ 30 °, and ⁇ 1> ⁇ 2 are satisfied.
- Many tires having an inclined belt layer having a belt cord inclined at an angle of 35 ° or more with respect to the tire circumferential direction have first, second and third vibration modes in the cross-sectional direction in a high frequency range of 400 Hz to 2 kHz.
- the tread surface Since the tread surface has a shape that vibrates greatly uniformly, a large radiated sound is generated. Therefore, if the tire circumferential direction rigidity of the tread tire width direction central region is locally increased, the tread tire width direction central region becomes difficult to spread in the tire circumferential direction, and the spread of the tread surface in the tire circumferential direction is suppressed. As a result, radiated sound can be reduced.
- FIG. 10 schematically shows another example of the belt structure, in which one circumferential belt layer 163 is laminated on the outer side in the tire radial direction of the two inclined belt layers 161 and 162.
- the circumferential belt layer is preferably highly rigid, and more specifically, the tire circumference.
- the contact surface tends to have a substantially triangular shape, that is, a shape in which the contact length in the circumferential direction varies greatly depending on the position in the tire width direction.
- a highly rigid circumferential belt layer by using a highly rigid circumferential belt layer, the ring rigidity of the tire is improved, and deformation in the tire circumferential direction is suppressed. Deformation is also suppressed, and the ground contact shape is less likely to change.
- the eccentric rigidity is promoted by improving the ring rigidity, and the rolling resistance is simultaneously improved. The effect of improving the rolling resistance is particularly large in a pneumatic radial tire for a passenger car having a narrow width and a large diameter that satisfies the above relational expressions (1) and / or (2).
- the inclination angle of the inclined belt layer with respect to the tire circumferential direction of the belt cord is a high angle, specifically 35 ° or more.
- the contact length may be reduced depending on the tire due to the increased rigidity in the tire circumferential direction. Therefore, by using a high-angle inclined belt layer, it is possible to reduce the out-of-plane bending rigidity in the tire circumferential direction, increase the elongation in the tire circumferential direction of the rubber when the tread surface is deformed, and suppress the decrease in the contact length. it can.
- a wavy cord may be used for the circumferential belt layer in order to increase the breaking strength.
- a high elongation cord (for example, elongation at break is 4.5 to 5.5%) may be used.
- various materials can be used for the circumferential belt layer.
- Typical examples include rayon, nylon, polyethylene naphthalate (PEN), polyethylene terephthalate (PET), aramid, and glass fiber.
- Carbon fiber, steel, etc. can be used. From the viewpoint of weight reduction, an organic fiber cord is particularly preferable.
- the cord of the circumferential belt layer may be a monofilament cord, a cord in which a plurality of filaments are combined, or a hybrid cord in which filaments of different materials are combined.
- the number of circumferential belt layers to be driven can be in the range of 20 to 60/50 mm, but is not limited to this range.
- the distribution of rigidity, material, number of layers, driving density, etc. can be given in the tire width direction.
- the number of circumferential belt layers can be increased only at the end in the tire width direction.
- the number of circumferential belt layers can be increased only in the center portion.
- the circumferential belt layer can be designed to be wider or narrower than the inclined belt layer.
- the width in the tire width direction can be 90% to 110% of the maximum width inclined belt layer having the largest width in the tire width direction among the inclined belt layers.
- the circumferential belt layer is configured as a spiral layer.
- the carcass maximum width position can be brought closer to the bead portion side or closer to the tread side.
- the carcass maximum width position can be provided in the range of 50% to 90% relative to the tire cross-section height on the outer side in the tire radial direction from the bead base portion.
- the carcass can adopt various structures.
- the number of carcass shots can be in the range of 20 to 60 pieces / 50 mm, but is not limited thereto.
- the folded end of the carcass can be positioned on the inner side in the tire radial direction of the end of the bead filler in the tire radial direction, and the folded end of the carcass is positioned in the tire radial direction from the outer end of the bead filler in the tire radial direction or the maximum tire width position. It can be located on the outer side, and in some cases, it can extend to the inner side in the tire width direction from the end in the tire width direction of the inclined belt layer. Furthermore, when the carcass is constituted by a plurality of carcass plies, the position of the carcass folded end in the tire radial direction can be varied. In addition, a structure in which a plurality of bead core members are sandwiched or wound around a bead core without using a carcass folded portion can be employed.
- the tire side portion In a pneumatic radial tire for a passenger car having a narrow and large diameter that satisfies the above relational expression (1) and / or (2), it is preferable to make the tire side portion thin.
- “To thin the tire side portion” means, for example, that the cross-sectional area S1 of the bead filler in the tire width direction is 1 to 4 times the cross-sectional area S2 of the bead core in the tire width direction.
- the ratio Ts / Tb between the gauge Ts of the sidewall portion at the tire maximum width portion and the bead width Tb at the tire radial direction center position of the bead core can be 15% or more and 40% or less.
- the ratio Ts / Tc between the gauge Ts of the sidewall portion in the tire maximum width portion and the diameter Tc of the carcass cord can be set to 5 or more and 10 or less.
- the gauge Ts is the sum of the thicknesses of all members such as rubber, a reinforcing member, and an inner liner. In the case where the bead core is divided into a plurality of small bead cores by the carcass, the distance between the innermost end in the width direction and the outermost end of all the small bead cores is Tb.
- the tire maximum width position can be provided in the range of 50% to 90% in comparison with the tire cross-section height, on the outer side in the tire radial direction from the bead base portion.
- the tire of the present invention may have a structure having a rim guard.
- the tire according to the present invention may have a structure without a bead filler.
- the bead core can adopt various structures such as a circular cross section and a polygonal cross section.
- a structure in which the carcass is wound around the bead core a structure in which the carcass is sandwiched between a plurality of bead core members may be employed.
- the bead portion may be further provided with a rubber layer, a cord layer, or the like for the purpose of reinforcement or the like.
- additional members can be provided at various positions with respect to the carcass and the bead filler.
- the thickness of the inner liner from the viewpoint of reducing in-vehicle noise of 80-100 Hz. Specifically, it is preferably about 1.5 mm to 2.8 mm thicker than usual (about 1.0 mm). It has been found that pneumatic radial tires for passenger cars with narrow and large diameters satisfying the above relational expression (1) and / or (2) tend to deteriorate the in-vehicle noise of 80-100 Hz especially when high internal pressure is used. Yes. By increasing the thickness of the inner liner, it is possible to improve vibration damping and reduce in-vehicle noise of 80-100 Hz. In addition, since the loss which contributes to rolling resistance is small compared with other members, such as a tread, an inner liner can improve noise performance, suppressing deterioration of rolling resistance to the minimum.
- the inner liner can be formed of a film layer mainly composed of a resin in addition to a rubber layer mainly composed of butyl rubber.
- a porous member in order to reduce cavity resonance noise, can be disposed on the tire inner surface, or electrostatic flocking can be performed.
- the tire of the present invention can also be provided with a sealant member for preventing air leakage during puncture on the tire inner surface.
- the pneumatic radial tire for passenger cars of the present invention can also be a side-reinforced run-flat tire having a crescent-shaped reinforcing rubber in the tire side portion.
- a side-reinforced run-flat tire when a side-reinforced run-flat tire is used, it is possible to achieve both run-flat durability and fuel efficiency by adopting a simplified side part. it can.
- the side portion and the tread portion are This is based on the knowledge that the deformation is relatively small, while the deformation is relatively large from the shoulder portion to the buttress portion. This deformation is in contrast to the relatively large deformation at the side portion in the conventional size.
- FIG. 11 is a tire width direction cross-sectional view of a tire according to a third embodiment of the present invention when the tire of the present invention is a run-flat tire.
- the turn-up end A of the carcass turn-up portion is located on the inner side in the tire radial direction from the tire maximum width position P.
- FIG. 12 is a tire width direction cross-sectional view of a tire according to a fourth embodiment of the present invention when the tire of the present invention is a run-flat tire.
- the tire has a maximum width in the tire width direction among one or more belt layers in a cross section of the tire width direction in a reference state in which the tire is incorporated into the rim, filled with a predetermined internal pressure, and is unloaded.
- the half width of the belt layer in the tire width direction is WB, and the outermost circumferential main groove 181 of the outermost tire width direction of one or more circumferential main grooves from the tire width direction end of the belt layer having the largest width in the tire width direction.
- the distance in the tire width direction to the center position in the tire width direction is WG, it is preferable that the relational expression 0.5 ⁇ WG / WB ⁇ 0.8 is satisfied.
- the tire of Example 1 is a tire having a tire size of 165 / 60R19 as shown in FIG. 1 and has the specifications shown in Table 1.
- the tire of Example 1 includes a two-layer inclined belt layer and a belt-reinforcing layer in which belt cords incline in an opposite direction with respect to the tire circumferential direction, and a tread belt. Three circumferential main grooves (groove width: 7.5 mm) are disposed on the tread surface. In the tire of Example 1, the width of the tread surface in the tire width direction is 125 mm.
- the tires of Examples 2 to 4 are the same as the tire of Example 1 except that the specifications are changed as shown in Table 1.
- the tires of Comparative Examples 1 to 3 and 6 are tires having a tire size of 195 / 65R15, and have the specifications shown in Table 1.
- the tire of Comparative Example 1 includes a two-layer inclined belt layer and a belt reinforcing layer in which belt cords incline with each other in an opposite direction with respect to the tire circumferential direction, and a tread. Three circumferential main grooves (groove width: 8.5 mm) are disposed on the tread surface. In the tire of Comparative Example 1, the width of the tread surface in the tire width direction is 145 mm.
- the tires of Comparative Examples 4, 5, and 7 are the same as the tire of Example 1 except that the specifications are changed as shown in Table 1.
- the evaluation results are indicated by an index with the tire described in Comparative Example 1 as 100, with the value for each test tire being the reciprocal. A larger index value means better wet performance.
- Examples 1 to 4, Comparative Examples 4, 5, and 7 Rim size 5.5 J19, internal pressure 300 kPa Comparative Examples 1 to 3, 6: rim size 6.5 J15, internal pressure 220 kPa [Rolling resistance performance]
- Each of the above test tires is mounted on the rim under the same conditions as the wet performance measurement conditions, filled with the internal pressure, loaded with the maximum load specified for each tire, and adjusted to a drum rotation speed of 100 km / h. The rolling resistance value was measured.
- the evaluation results are indicated by an index with the tire described in Comparative Example 1 as 100, with the value for each test tire being the reciprocal. It means that rolling resistance performance is so good that this index value is large.
- the dynamic storage elastic modulus E ′ and loss tangent tan ⁇ were obtained by applying an initial load of 160 g to a test piece having a thickness of 2 mm, a width of 5 mm, and a length of 20 mm using a spectrometer manufactured by Toyo Seiki Seisakusho Co., Ltd.
- the initial storage strain was measured at 1% and the frequency was 50 Hz.
- the dynamic storage elastic modulus E ′ was measured at 30 ° C.
- the loss tangent tan ⁇ was measured at 0 ° C. and 60 ° C.
- Table 1 shows that Examples 1 to 4 have improved wet performance and rolling resistance performance as compared with the tires of Comparative Examples 1 to 7.
Abstract
Description
近年、環境問題への関心の高まりにより、低燃費性への要求が厳しくなってきている。かかる低燃費性は、転がり抵抗(RR)によって評価することができ、低転がり抵抗であるほど、低燃費となることが知られている。
2.135×SW+282.3≦OD
を満たし、前記トレッドゴムの、30℃における動的貯蔵弾性率E’が、6.0~12.0MPaであり、且つ、当該トレッドゴムの、60℃における損失正接tanδが、0.05~0.15であり、前記バットレスゴムの、30℃における動的貯蔵弾性率E’が、前記トレッドゴムの動的貯蔵弾性率E’の1/2以下であり、且つ、当該バットレスゴムの、60℃における損失正接tanδが、0.1以下であることを特徴とする。
本発明によれば、狭幅、大径のラジアルタイヤにおいて、ウェット性能および転がり抵抗性能を向上させることができる。
なお、上記の「リム」とは、タイヤが生産され、使用される地域に有効な産業規格であって、日本ではJATMA(日本自動車タイヤ協会)のJATMA YEAR BOOK、欧州ではETRTO(The European Tyre and Rim Technical Organization)のSTANDARDS MANUAL、米国ではTRA(The Tire and Rim Association,Inc.)のYEAR BOOK等に記載されているまたは将来的に記載される、適用サイズにおける標準リム(ETRTOのSTANDARDS MANUALではMeasuring Rim、TRAのYEAR BOOKではDesign Rim)を指す(即ち、上記の「リム」には、現行サイズに加えて将来的に上記産業規格に含まれ得るサイズも含む。「将来的に記載されるサイズ」の例としては、ETRTO 2013年度版において「FUTURE DEVELOPMENTS」として記載されているサイズを挙げることができる。)が、上記産業規格に記載のないサイズの場合は、タイヤのビード幅に対応した幅のリムをいう。
本発明において、バットレス部とは、タイヤ幅方向断面視において、トレッド接地端を通りタイヤ半径方向に延びる仮想線と、トレッド接地端からタイヤの断面幅SWとなるタイヤ表面位置までのペリフェリ長さの半分の長さとなるタイヤ表面位置を通りタイヤ幅方向に延びる仮想線と、で挟まれるタイヤ部分を指す。
本発明において、トレッド接地端とは、トレッド踏面の、トレッド幅方向の最外位置をいい、トレッド踏面とは、上記のリムに組み込むとともに250kPa以上の内圧を適用したタイヤを、最大負荷能力の75%の負荷を加えた状態でタイヤを転動させた際に、路面に接触することになる、タイヤの全周にわたる外周面を指す。
本発明において、トレッドゴムおよびバットレスゴムとは、トレッド部およびバットレス部に任意に含まれるベルトおよびカーカス等の部材を含まないゴムを意味する。
本発明において、バットレスゴムが、所望の30℃における動的貯蔵弾性率E’、および、所望の60℃における損失正接tanδであるとは、タイヤ幅方向断面視において、バットレスゴムのうち、バットレス部のタイヤ半径方向内端と、トレッド接地端からペリフェリ長さで10mmだけタイヤ幅方向外側に移動したタイヤ表面位置を通りタイヤ半径方向に延びる仮想線と、に挟まれるゴムが少なくとも所望のE’およびtanδであることを意味する。
この構成によれば、ウェット性能および転がり抵抗性能をより向上させることができる。
また、図1に例示するこの実施形態では、トレッド踏面Tに、タイヤ周方向に連続して延びる周方向主溝8を設けることができ、図示の例では、2本の周方向主溝8によって、トレッド踏面Tに3本のリブ状の陸部が形成されている。なお、本発明では、周方向主溝8は必須の構成ではない。
なお、バットレス部5は、具体的には、タイヤ幅方向断面視において、トレッド接地端Eを通りタイヤ半径方向に延びる仮想線Leと、トレッド接地端Eからタイヤ1の断面幅SWとなるタイヤ表面位置までのペリフェリ長さの半分の長さとなるタイヤ表面位置を通りタイヤ幅方向に延びる仮想線Lhと、で挟まれるタイヤ部分である。
2.135×SW+282.3≦OD
を満たす(以下、関係式(1)を満たすとも称す)。タイヤ1が、上記の関係であることにより、狭幅、大径の形状となり、タイヤ1の転がり抵抗性能を向上させ(転がり抵抗値を低減させ)、かつ、タイヤ1を軽量化することができる。
また、タイヤ1の内圧は、250kPa以上であることが好ましく、250~350kPaであることがより好ましい。上記関係式(1)を満たすようなタイヤでは、接地長が増大しやすいが、250kPa以上とすることにより接地長の増大を抑えて、トレッドゴムの変形量を低減し、転がり抵抗をさらに低減することができるからである。
また、タイヤ1の転がり抵抗値を低減し、かつ、タイヤ1を軽量化する観点から、タイヤ1の内圧が250kPa以上の場合に、タイヤ1の断面幅SWと外径ODは、-0.0187×SW2+9.15×SW-380≦ODであることが好ましい(以下この式を関係式(2)とも称す)。
この例では、2層の傾斜ベルト層71、72は、それぞれタイヤ周方向に対して35°以上の角度で傾斜しており、タイヤ半径方向内側の傾斜ベルト層71が、外側の傾斜ベルト層72よりも広幅である。また、1層のベルト補強層73は、傾斜ベルト層71、72を覆うような幅を有している。傾斜ベルト層71、72がタイヤ周方向に対して35°以上傾斜することにより、タイヤ1の断面幅SWおよび外径ODが上記の範囲であるタイヤ1において、転がり抵抗性能およびコーナリング時のコーナリングパワーを向上させることができる。
そこで、このタイヤ1では、バットレスゴム51の、30℃における動的貯蔵弾性率E’を、トレッドゴム41の動的貯蔵弾性率E’の1/2以下とし、且つ、バットレスゴム51の、60℃における損失正接tanδを、0.1以下としている。
また、バットレスゴム51の動的貯蔵弾性率E’が、トレッドゴム41の動的貯蔵弾性率E’の1/2以下であり、且つ、バットレスゴム51の損失正接tanδが、0.1超である場合には、バットレスゴム51の歪エネルギー(歪×応力)は小さいが、ゴムの粘弾性に起因するヒステリシスロスが大きく、歪エネルギーロスが大きくなるので転がり抵抗値を低減させることができない。
またなお、バットレスゴム51の動的貯蔵弾性率E’を、トレッドゴム41の動的貯蔵弾性率E’に対して規定するのは、トレッドゴム41は高い動的貯蔵弾性率E’ほど歪エネルギー(歪×応力)は小さいが、バットレスゴム51は逆に高い動的貯蔵弾性率E’ほど歪エネルギー(歪×応力)が大きいためである。
混練の条件としては、特に制限はなく、バンバリーミキサー、ロール、インターナルミキサー等を用いて、配合処方、混練装置への投入体積等に応じて、適宜、ローターの回転速度、ラム圧、混練温度、混練時間を調節すればよい。
また、ゴム組成物を加硫する際の条件としては、加硫温度は、例えば、100~190℃とすることができる。加硫時間は、例えば、5~80分とすることができる。
SBR、BRなどの共役ジエン重合体を変性する方法は、特に限定されず、従来公知の方法を用いることができ、例えば、国際公開第2008/050845号に記載の方法(共役ジエン系重合体の活性末端に、変性剤を反応させ、チタン系縮合促進剤の存在下、当該変性剤が関与する縮合反応を行う方法)等を用いることができる。
前記共役ジエン系重合体としては、例えば、1,3-ブタジエンとスチレンとの共重合体が好適に挙げられる。
変性剤としては、例えば、N,N-ビス(トリメチルシリル)アミノプロピルメチルジメトキシシラン、N,N-ビス(トリメチルシリル)アミノプロピルメチルジエトキシシラン、1-トリメチルシリル-2-エトキシ-2-メチル-1-アザ-2-シラシクロペンタンが好適に挙げられる。
チタン系縮合促進剤としては、例えば、テトラキス(2-エチル-1,3-ヘキサンジオラト)チタン、テトラキス(2-エチルヘキソキシ)チタン、チタンジ-n-ブトキサイド(ビス-2,4-ペンタンジオネート)が好適に挙げられる。
上述したゴム成分を1種単独で、または2種以上を組み合わせて用いてもよい。
充填剤としてシリカを用いる場合は、シリカをシランカップリング剤で処理してもよい。
また、上記のようにトレッドゴム41の損失正接tanδを0.05~0.15とするためには、例えば、配合をジエン系ポリマー100phrのうち、NRを0~20phrの範囲、変性S-SBRを20~70phrの範囲、且つ、充填剤50~80phrのうち、シリカを30~80phrの範囲で適宜変更すればよい。
なお、「phr」は、ゴム成分100質量部に対する各種成分の配合量(質量部)をいう。
ウェット性能を向上させるには、溝量を増やすのが一般的な考え方であるが、上記関係式(1)及び/又は(2)を満たすような、狭幅大径サイズの乗用車用空気入りラジアルタイヤの場合には、接地面の幅Wが狭くなるため、図2(b)に、図2(a)との対比で示すように、水がタイヤ幅方向に排出されやすくなる。このため、溝量を減らしてもウェット性能は維持され、かつ陸部剛性の向上によりコーナリングパワーなど他性能も向上させることができるのである。
なお、溝体積率は、例えば、ベルト層のうちタイヤ幅方向に最大幅を有する、最大幅ベルト層の幅方向両端部よりタイヤ幅方向内側にあり、且つ、タイヤ幅方向中央位置における、タイヤ径方向最外側の補強部材(ベルト層及びベルト補強層)よりタイヤ径方向外側にあるトレッドゴムの体積をV1とし、トレッド踏面に形成した溝の合計体積をV2とするとき、比V2/V1と定義される。
これは、上記の関係式(1)及び/又は(2)を満たすような狭幅大径サイズの乗用車用空気入りラジアルタイヤでは、接地幅が狭く、また、特に高内圧(例えば250kPa以上)使用下において高接地圧となるため、周方向せん断剛性を増加させることによりウェット路面上での接地性が向上するためと考えられる。
リブ状陸部を主体とするパターンの例としては、例えば図3に示す実施形態のように、タイヤ赤道面CLを中心とするトレッド幅TWの80%のタイヤ幅方向領域(図3において、2本の境界線mに挟まれる領域)においてリブ状陸部のみからなる(すなわち、幅方向溝を有しない)トレッドパターンとすることができる。このタイヤ幅方向領域における排水性能が特にウェット性能への寄与が大きいためである。
特にウェット性能を向上させる観点からは、サイプの両端部のうち一方の端が溝に開口し他方の端が陸部内で終端する片側開口サイプ100とすることがましい。片側開口サイプ100によって接地面内の水膜を除去しつつ、両端開口サイプの場合との対比で周方向せん断剛性を増大させることができるため、周方向せん断剛性向上によるウェット性能向上の効果を得ることができるためである。同様の理由により、図3に示すように、片側開口サイプ100をリブ状陸部主体のパターンと組み合わせて用いることが好ましい。
具体的には、図6に示すように、トレッド踏面における、タイヤ赤道面CLを境界とする少なくとも一方の半部において、トレッド接地端Eに隣接し、且つトレッド接地端Eとのトレッド幅方向の距離が、トレッド幅TWの25%以上離間した、トレッド周方向に延びるトレッド端側主溝130を有し、トレッド端側主溝130とトレッド接地端Eとによって区画されるトレッド接地端側陸部に隣接する陸部131の1つに、トレッド接地端側主溝130からトレッド幅方向に延びて隣接陸部131内に留まる、少なくとも1本の一端開口溝132を有することが好ましい。なお、図6における、溝133は、主溝より溝深さの小さい浅溝である。
上記関係式(1)及び/又は(2)を満たす、狭幅大径サイズの乗用車用空気入りラジアルタイヤの場合には、車両装着外側では圧縮応力を受け、車両装着内側では引張応力を受けることとなり、これらの応力により、トレッドゴムが変形し、ベルトが変形して、接地面が浮き上がってしまう。
ここで、トレッド接地端側主溝130からトレッド幅方向に延びて陸部131内に留まる一端開口溝132を有するため、陸部内の車両装着外側においては、圧縮応力により一端開口溝132が閉じる構造となるため、一端開口溝132を設けない場合や、一端開口溝132が車両装着外側まで延びていない場合と比べて、圧縮応力によるトレッドやベルトの変形が抑制される。
さらに、一端開口溝132が陸部内に留まるため、車両装着内側まで一端開口溝132が延在している場合と比較して、車両装着内側での引張応力に対する剛性が高くなり、これによりトレッドやベルトの変形が抑制される。
ここで、上記「接地端E’」とは、タイヤをリムに装着し、タイヤを装着する車両毎に規定される最高空気圧を充填して平板上に垂直に置き、タイヤを装着する車両毎に規定される最大負荷に相当する重量を負荷した際の、平板との接触面における、タイヤ幅方向両端点をいう。
傾斜角度を35°以上とすることにより、タイヤ幅方向に対する剛性を高め、特にコーナリング時の操縦安定性能を向上させることができるからである。また、層間ゴムのせん断変形を減少させて、転がり抵抗性能を向上させることができるからである。
傾斜ベルト層のベルトコードの傾斜角度θ1、θ2が35°以上の場合には、周方向ベルトは、タイヤ赤道面CLを含む中央領域Cの単位幅あたりのタイヤ周方向剛性が、その他の領域の単位幅あたりのタイヤ周方向剛性より高いことが好ましい。
図8は、ベルト構造の一例を概略的に示しており、傾斜ベルト層141、142のタイヤ径方向外側に周方向ベルト層143、144が積層されており、中央領域Cにおいて、周方向ベルト層143、144が互いにタイヤ径方向に重なっている。
例えば、図8に示すように、当該中央領域Cにおける周方向ベルト層の層数をその他の領域より多くすることにより、中央領域Cの単位幅あたりのタイヤ周方向剛性を、その他の領域の単位幅あたりのタイヤ周方向剛性より高くすることができる。
傾斜ベルト層のベルトコードがタイヤ周方向に対して35°以上で傾斜するタイヤの多くは、400Hz~2kHzの高周波域において、断面方向の1次、2次および3次等の振動モードにて、トレッド踏面が一律に大きく振動する形状となるため、大きな放射音が生じる。そこで、トレッドのタイヤ幅方向中央領域のタイヤ周方向剛性を局所的に増加させると、トレッドのタイヤ幅方向中央領域がタイヤ周方向に広がり難くなり、トレッド踏面のタイヤ周方向への広がりが抑制される結果、放射音を減少させることができる。
さらに、上述のごとく、タイヤ赤道面CLを含む中央領域のタイヤ周方向の剛性を高めたタイヤでは、トレッドはトレッド踏面の少なくともタイヤ赤道面CLを含む領域に、タイヤ周方向に連続する陸部を有することが好ましい。タイヤ赤道面CL上又はその付近に周方向主溝を配置すると、当該領域におけるトレッドの剛性が低下して、該周方向主溝を区画する陸部における接地長が極端に短くなる場合がある。そこで、タイヤ赤道面CLを含む一定領域にわたって、タイヤ周方向に連続する陸部(リブ状陸部)を配置することが、コーナリングパワーを低減させることなく騒音性能を改善する観点から好ましい。
本発明にあっては、図9に示す例のように、傾斜ベルト層のベルトコードの傾斜角度が35°以上の場合には、傾斜ベルト層は、タイヤ幅方向の幅の異なる2層の傾斜ベルト層を少なくとも含み、最広幅の傾斜ベルト層をなすコードのタイヤ周方向に対する傾斜角度θ1と、最狭幅の傾斜ベルト層をなすコードのタイヤ周方向に対する傾斜角度θ2とが、35°≦θ1≦85°、10°≦θ2≦30°、及び、θ1>θ2を満たすことが好ましい。
タイヤ周方向に対して35°以上で傾斜するベルトコードを有する傾斜ベルト層を備えたタイヤの多くは、400Hz~2kHzの高周波域において、断面方向の1次、2次および3次等の振動モードにて、トレッド踏面が一律に大きく振動する形状となるため、大きな放射音が生じる。そこで、トレッドのタイヤ幅方向中央領域のタイヤ周方向剛性を局所的に増加させると、トレッドのタイヤ幅方向中央領域がタイヤ周方向に広がり難くなり、トレッド面のタイヤ周方向への広がりが抑制される結果、放射音を減少させることができる。
上記関係式(1)及び/又は(2)を満たすような、狭幅大径サイズの乗用車用ラジアルタイヤにおいては、周方向ベルト層は高剛性であることが好ましく、より具体的にはタイヤ周方向に延びるコードのゴム引き層からなり、コードのヤング率をY(GPa)、打ち込み数をn(本/50mm)とし、周方向ベルト層をm層として、X=Y×n×mと定義するとき、1500≧X≧750であることが好ましい。上記関係式(1)及び/又は(2)を満たすような、狭幅大径サイズの乗用車用ラジアルタイヤにおいては、路面からの旋回時における入力に対しタイヤ周方向において局所的な変形を起こし、接地面は略三角形状、すなわち、タイヤ幅方向の位置によって周方向の接地長が大きく変化する形状となりやすい。これに対し、高剛性の周方向ベルト層とすることにより、タイヤのリング剛性が向上して、タイヤ周方向の変形が抑制されることとなるため、ゴムの非圧縮性により、タイヤ幅方向の変形も抑制され、接地形状が変化しにくくなる。さらには、リング剛性が向上することにより偏心変形が促進され、転がり抵抗も同時に向上する。この転がり抵抗の向上効果は、上記関係式(1)及び/又は(2)を満たすような、狭幅大径サイズの乗用車用空気入りラジアルタイヤにおいて、特に向上効果の幅が大きくなる。
なお、ゲージTsはゴム、補強部材、インナーライナーなどすべての部材の厚みの合計となる。また、ビードコアがカーカスによって複数の小ビードコアに分割されている構造の場合には、全小ビードコアのうち幅方向最内側端部と最外側端部の距離をTbとする。
上記関係式(1)及び/又は(2)を満たす、狭幅大径サイズの乗用車用空気入りラジアルタイヤは特に高内圧使用化において80-100Hzの車内騒音が悪化しやすいという知見が得られている。インナーライナーを厚くすることで振動減衰性を高め、80-100Hzの車内騒音を低減することができる。なお、インナーライナーは転がり抵抗に寄与するロスが、トレッド等の他の部材と比較すると小さいため、転がり抵抗の悪化を最小限にとどめつつ、騒音性能を改善することができる。
このような、上記関係式(1)及び/又は(2)を満たすような、狭幅大径サイズに特徴的な変形のために、簡素化構造によってもランフラット耐久性を十分に確保し、かつ燃費性能をさらに向上させることができる。
具体的な簡素化手法としては少なくとも以下の(i)~(iii)のいずれか一つの条件を満たすことにより可能となる。
図11は、本発明のタイヤがランフラットタイヤである場合における、本発明の第3の実施形態にかかるタイヤのタイヤ幅方向断面図である。
(i)図11に示すように、カーカス折り返し部の折り返し端Aが、タイヤ最大幅位置Pよりタイヤ径方向内側に位置する、(ii)タイヤをリムに組み込み、所定の内圧を充填し、無負荷とした、基準状態の際のタイヤ幅方向断面における、サイド補強ゴム171のタイヤ径方向最大長さをH1とし、ビードフィラのタイヤ径方向最外側点とビードコアのタイヤ径方向最外側点とを結んだ線分の長さをH2とするとき、1.8≦H1/H2≦3.5、を満たす、(iii)タイヤをリムに組み込み、所定の内圧を充填し、無負荷とした、基準状態の際のタイヤ幅方向断面における、サイド補強ゴム171のタイヤ径方向最大長さをH1(mm)とするとき、関係式、10(mm)≦(SW/OD)×H1≦20(mm)を満たす。
図12は、本発明のタイヤがランフラットタイヤである場合における、本発明の第4の実施形態にかかるタイヤのタイヤ幅方向断面図である。
具体的には、タイヤをリムに組み込み、所定の内圧を充填し、無負荷とした、基準状態の際のタイヤ幅方向断面における、1層以上のベルト層のうちタイヤ幅方向の幅が最大のベルト層のタイヤ幅方向の半幅をWBとし、タイヤ幅方向の幅が最大のベルト層のタイヤ幅方向端部から1本以上の周方向主溝のうちタイヤ幅方向最外側の周方向主溝181のタイヤ幅方向中心位置までのタイヤ幅方向距離をWGとするとき、関係式、0.5≦WG/WB≦0.8を満たすことが好ましい。
実施例2~4のタイヤは、各諸元を表1に示すように変化させた以外、実施例1のタイヤと同様である。
比較例1~3、6のタイヤは、タイヤサイズ195/65R15であるタイヤであって、表1に示す諸元の構成を有している。また、比較例1のタイヤは、ベルトコードが相互にタイヤ周方向に対して逆向きに傾斜して交錯する2層の傾斜ベルト層と1層のベルト補強層とを備えており、また、トレッド踏面に、3本の周方向主溝(溝幅:8.5mm)が配設されている。なお、比較例1のタイヤは、トレッド踏面のタイヤ幅方向の幅は145mmである。
比較例4、5、7のタイヤは、各諸元を表1に示すように変化させた以外、実施例1のタイヤと同様である。
[ウェット性能]
上記の各供試タイヤを、下記の条件でリムに装着し内圧を充填して、車両に装着した後、ウェット路面を時速80km/hで走行させた。そして、上記状態で走行後、フルブレーキを行った際の、停止距離(m)を計測し、このときの平均減速度(m/s2)=V2/25.92Lを算出した(平均減速度a、初速v、質量m、停止距離Lとすると、mv2/2=maLより、a=v2/2Lと計算できる。ウェット時の摩擦係数(wet μ))。評価結果は、各供試タイヤについての値を逆数にして、比較例1に記載のタイヤを100とする指数にて示した。この指数値が大きいほどウェット性能がよいことを意味する。
実施例1~4、比較例4、5、7:リムサイズ5.5J19、内圧300kPa
比較例1~3、6:リムサイズ6.5J15、内圧220kPa
[転がり抵抗性能]
上記の各供試タイヤを、ウェット性能の測定条件と同じ条件で、リムに装着し内圧を充填して、各タイヤに規定される最大荷重を負荷して、ドラム回転速度100km/hの条件にて転がり抵抗値を測定した。
評価結果は、各供試タイヤについての値を逆数にして、比較例1に記載のタイヤを100とする指数にて示した。この指数値が大きいほど転がり抵抗性能がよいことを意味する。
2:ビード部
3:カーカス
4:トレッド部
41:トレッドゴム
5:バットレス部
51:バットレスゴム
6:サイドウォール部
7:ベルト
71、72:傾斜ベルト層
73:ベルト補強層
8:周方向主溝
100:サイプ
110:周方向サイプ
111:小穴
120:幅方向溝
130:トレッド端側主溝
131:隣接陸部
132:一端開口溝
133:浅溝
141、142:傾斜ベルト層
143、144:周方向ベルト層
151、152:傾斜ベルト層
153:周方向ベルト層
161、162:傾斜ベルト層
163:周方向ベルト層
171:サイド補強ゴム
181:周方向主溝
CL:タイヤ赤道面
E:トレッド接地端
Le、Lh、Le’:仮想線
T:トレッド踏面
Claims (2)
- 一対のビード部間でトロイダル状に跨るラジアル配列コードのカーカスプライからなるカーカスと、当該カーカスのタイヤ半径方向外側に設けられ、トレッド踏面を形成するトレッドゴムと、当該トレッドゴムのタイヤ幅方向外側に位置し、バットレス部を形成するバットレスゴムと、を備えた乗用車用空気入りラジアルタイヤであって、
前記タイヤをリムに組み込み、内圧を250kPa以上とした際に、
前記タイヤの断面幅SWが165(mm)未満である場合は、前記タイヤの断面幅SWと外径OD(mm)との比SW/ODが0.26以下であり、
前記タイヤの断面幅SWが165(mm)以上である場合は、前記タイヤの断面幅SWおよび外径OD(mm)が、関係式、
2.135×SW+282.3≦OD
を満たし、
前記トレッドゴムの、30℃における動的貯蔵弾性率E’が、6.0~12.0MPaであり、且つ、当該トレッドゴムの、60℃における損失正接tanδが、0.05~0.15であり、
前記バットレスゴムの、30℃における動的貯蔵弾性率E’が、前記トレッドゴムの動的貯蔵弾性率E’の1/2以下であり、且つ、当該バットレスゴムの、60℃における損失正接tanδが、0.1以下であることを特徴とする、乗用車用空気入りラジアルタイヤ。 - 前記トレッドゴムの30℃における動的貯蔵弾性率E’が、7.9~11.0MPaであり、
前記バットレスゴムの30℃における動的貯蔵弾性率E’が、3MPa以下である、請求項1に記載の乗用車用空気入りラジアルタイヤ。
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JP2016523163A JP6581574B2 (ja) | 2014-05-30 | 2015-05-28 | 乗用車用空気入りラジアルタイヤ |
US15/314,728 US20170197465A1 (en) | 2014-05-30 | 2015-05-28 | Passenger-vehicle pneumatic radial tire |
CN201580028912.2A CN106457915B (zh) | 2014-05-30 | 2015-05-28 | 乘用车用充气子午线轮胎 |
EP15798673.8A EP3130479B1 (en) | 2014-05-30 | 2015-05-28 | Pneumatic radial tire for use on passenger vehicle |
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Cited By (3)
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EP3466720A4 (en) * | 2016-05-26 | 2019-05-15 | Bridgestone Corporation | TIRE |
EP3466722A4 (en) * | 2016-05-26 | 2019-05-15 | Bridgestone Corporation | TIRE |
WO2024034260A1 (ja) * | 2022-08-08 | 2024-02-15 | 株式会社ブリヂストン | 乗用車用空気入りラジアルタイヤ |
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JP5810204B1 (ja) | 2014-10-08 | 2015-11-11 | 株式会社ブリヂストン | 乗用車用空気入りラジアルタイヤ |
CN109863044B (zh) * | 2017-07-13 | 2020-04-17 | 住友橡胶工业株式会社 | 充气轮胎以及轮胎用橡胶组合物 |
WO2019102148A1 (fr) * | 2017-11-24 | 2019-05-31 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour vehicule de tourisme |
JP7397272B2 (ja) * | 2017-12-08 | 2023-12-13 | 横浜ゴム株式会社 | 空気入りタイヤ |
JP2020093677A (ja) * | 2018-12-13 | 2020-06-18 | 株式会社ブリヂストン | 乗用車用空気入りラジアルタイヤ |
WO2020141012A1 (en) * | 2018-12-31 | 2020-07-09 | Goldhofer Ag | Heavy-load vehicle |
CN111159874A (zh) * | 2019-12-25 | 2020-05-15 | 江苏大学 | 一种降低轮胎风阻的轮胎外轮廓结构的设计方法 |
JP2021130442A (ja) * | 2020-02-21 | 2021-09-09 | 住友ゴム工業株式会社 | タイヤ |
JP6769573B1 (ja) * | 2020-02-28 | 2020-10-14 | 住友ゴム工業株式会社 | タイヤ |
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- 2015-05-28 US US15/314,728 patent/US20170197465A1/en not_active Abandoned
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- 2015-05-28 WO PCT/JP2015/002710 patent/WO2015182152A1/ja active Application Filing
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WO2024034260A1 (ja) * | 2022-08-08 | 2024-02-15 | 株式会社ブリヂストン | 乗用車用空気入りラジアルタイヤ |
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JP6581574B2 (ja) | 2019-09-25 |
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US20170197465A1 (en) | 2017-07-13 |
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