WO2015177940A1 - Decorative component and process for producing same - Google Patents

Decorative component and process for producing same Download PDF

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Publication number
WO2015177940A1
WO2015177940A1 PCT/JP2014/071725 JP2014071725W WO2015177940A1 WO 2015177940 A1 WO2015177940 A1 WO 2015177940A1 JP 2014071725 W JP2014071725 W JP 2014071725W WO 2015177940 A1 WO2015177940 A1 WO 2015177940A1
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WO
WIPO (PCT)
Prior art keywords
layer
decorative
gloss
pattern
clear
Prior art date
Application number
PCT/JP2014/071725
Other languages
French (fr)
Japanese (ja)
Inventor
足立 浩司
達己 落合
圭佑 磯貝
Original Assignee
トリニティ工業株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by トリニティ工業株式会社 filed Critical トリニティ工業株式会社
Priority to US15/312,195 priority Critical patent/US20170087928A1/en
Priority to CN201480078891.0A priority patent/CN106457883B/en
Publication of WO2015177940A1 publication Critical patent/WO2015177940A1/en
Priority to US16/655,457 priority patent/US11738594B2/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44FSPECIAL DESIGNS OR PICTURES
    • B44F9/00Designs imitating natural patterns
    • B44F9/02Designs imitating natural patterns wood grain effects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/02Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a matt or rough surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/061Special surface effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/36Removing material
    • B23K26/40Removing material taking account of the properties of the material involved
    • B23K26/402Removing material taking account of the properties of the material involved involving non-metallic material, e.g. isolators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
    • B32B37/025Transfer laminating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/175Transfer using solvent
    • B44C1/1758Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/22Removing surface-material, e.g. by engraving, by etching
    • B44C1/228Removing surface-material, e.g. by engraving, by etching by laser radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/24Pressing or stamping ornamental designs on surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00Processes, not specifically provided for elsewhere, for producing ornamental structures
    • B44C3/02Superimposing layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44FSPECIAL DESIGNS OR PICTURES
    • B44F1/00Designs or pictures characterised by special or unusual light effects
    • B44F1/02Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/16Composite materials, e.g. fibre reinforced
    • B23K2103/166Multilayered materials
    • B23K2103/172Multilayered materials wherein at least one of the layers is non-metallic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B32B2037/246Vapour deposition
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/408Matt, dull surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/60In a particular environment
    • B32B2309/66Fluid other than air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00Decorative or ornamental articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/003Interior finishings

Definitions

  • the present invention relates to a decorative part in which a high-gloss area and a low-gloss area are mixed on the surface of the part, and a manufacturing method thereof.
  • Water pressure transfer is a technique in which a special film is floated on the surface of the water, and a predetermined pattern printed on the film (a pattern such as a wood grain pattern or a geometric pattern) is transferred onto the surface of the resin molded body by water pressure.
  • a predetermined pattern printed on the film a pattern such as a wood grain pattern or a geometric pattern
  • the decorative layer (printing layer) transferred to the surface of the resin molded body is weak and insufficient in durability as compared with the coating film.
  • the clear coat layer surface protective layer which protects the surface of a decoration layer by performing clear coating is formed.
  • a glossy clear coat layer may be formed or a matte clear coat layer may be formed according to the pattern of the pattern.
  • Patent Document 1 discloses a technique in which a film having an ink layer (decorative layer) is hydraulically transferred, and unevenness is formed on the surface of the component by the repelling action of the ink layer and the collective force of the activator. By forming irregularities on the surface of the component, a visual three-dimensional effect and a tactile three-dimensional effect (uneven texture) can be obtained.
  • the present invention has been made in view of the above problems, and its purpose is to provide a decorative part excellent in design by partially removing the gloss of the surface in a clear coat layer that protects the decorative layer and its It is to provide a manufacturing method.
  • the invention described in means 1 includes a component having a decorative layer on a surface layer portion and a clear coat layer for protecting the surface of the decorative layer, on the surface of the clear coat layer.
  • a method for producing a decorative part in which a high-gloss area having a relatively high gloss level and a low-gloss area having a relatively low gloss level are mixed, wherein the decorative layer is formed on a surface layer portion of the part.
  • a decorative layer forming step in which irregularities are formed on the surface of the decorative layer later on the surface immediately below the low gloss region, and a low boiling point solvent having a boiling point of less than 100 ° C. as a main solvent.
  • the decorative component manufacturing method which comprises a coating layer formation step and the gist thereof.
  • the decorative layer is formed on the surface layer part of the component in the decorative layer forming step, and after forming irregularities on the surface of the decorative layer, the clear coat layer forming step is performed.
  • a clear paint having a boiling point of less than 100 ° C. (for example, an ester solvent) as a main solvent and having a solid content of 10% by mass to 55% by mass is used.
  • This clear paint has a lower boiling point of the main solvent and a lower solid content in the paint as compared with a hydrocarbon-based clear paint generally used conventionally.
  • the ester-based main solvent volatilizes before the surface is smoothed, so a clear coat layer is formed along the surface shape of the decorative layer. Is done.
  • the region having the unevenness of the decoration layer immediately below becomes a surface shape having fine unevenness, and becomes a low gloss region having a relatively low gloss level.
  • the region where the decorative layer is not directly below is a flat surface shape, which is a high gloss region having a relatively high gloss level.
  • the gloss of the low gloss region can be partially dropped on the surface of the component, so that a visual three-dimensional expression corresponding to the decorative layer is possible, and the design of the decorative component is sufficiently achieved. Can be increased.
  • the clear paint preferably has a solid content of 30% by mass to 50% by mass, and more preferably 35% by mass to 40% by mass. If it does in this way, in the surface of a clear coat layer, the difference of the grade of the glossiness in a low gloss area and a high gloss area becomes large, and the design nature of a decoration part can be improved more.
  • the clear coat layer forming step it is preferable to spray the clear paint under a coating condition in which the atomization pressure of the atomization type coating machine is 0.06 MPa or more and 0.09 MPa or less. Further, it is preferable to spray the clear paint according to the coating conditions in which the discharge amount of the atomizing type coating machine is 50 cc / min or more, and the coating conditions in which the discharge amount of the atomizing type coating machine is from 50 cc / min to 65 cc / min. More preferably, the clear paint is sprayed. Under such application conditions, the particle size of the paint mist sprayed from the atomizing coater becomes large, and the paint is easily adapted to the unevenness of the decorative layer. As a result, the clear coat layer along the uneven shape on the surface of the decorative layer can be more reliably formed.
  • the decorative layer may be formed by hydraulic transfer of a transfer film having irregularities on the pattern layer.
  • a decorative layer having irregularities can be reliably formed by hydraulic transfer.
  • unevenness may be formed on the surface layer portion of the component by embossing, or unevenness may be formed on the surface layer portion of the component by laser processing.
  • a transfer film formed by laminating a pattern layer for imparting a pattern, a gloss layer for imparting gloss, and a mat layer having irregularities is hydraulically transferred to the decorative layer.
  • the region directly above the unevenness of the mat layer becomes a low gloss region, and the gloss can be surely erased.
  • the region directly above the gloss layer with few irregularities is a high gloss region, and the degree of gloss can be increased. If it does in this way, the three-dimensional effect according to the pattern of the pattern layer can be obtained reliably, and the designability of a decorative part can be improved.
  • the invention described in Means 2 includes a part having a decorative layer on a surface layer portion and a clear coat layer that protects the surface of the decorative layer, and is relatively glossy on the surface of the clear coat layer.
  • a decorative part in which a high-gloss area having a high gloss and a low-gloss area having a relatively low gloss level are mixed, and irregularities are formed on the surface of the decorative layer immediately below the low-gloss area.
  • the low gloss region of the clear coat layer has a surface shape along the irregularities
  • the clear coat layer has a surface roughness Ra of 1 ⁇ m or less
  • the high gloss region and the low gloss region The gist of the decorative part is characterized in that the difference in glossiness is twice or more.
  • the decorative layer has a decorative layer on the surface layer portion, and the surface of the decorative layer is protected by the clear coat layer.
  • corrugation of a decoration layer directly under the surface of a clearcoat layer turns into a surface shape along the unevenness
  • the region where the decorative layer is not directly below is a flat surface shape, which is a high gloss region having a relatively high gloss level.
  • the difference in glossiness between the high gloss area and the low gloss area on the clear coat layer surface is more than twice, visual three-dimensional expression is possible and the design is sufficiently enhanced. be able to.
  • the surface roughness Ra of the clear coat layer is 1 ⁇ m or less, there is little change in stereoscopic effect due to wear on the surface of the component, and the design of the decorative component can be maintained in a good state even when used for a long time. it can.
  • the mat layer constituting the decorative layer has a surface roughness Ra of 2 ⁇ m or less.
  • the surface roughness Ra of the clear coat layer can be 1 ⁇ m or less.
  • a mat layer is comprised including the same pigment as the pigment contained in the handle layer formed in the lower layer side. In this case, unevenness according to the pattern can be reliably imparted.
  • the pattern is a woodgrain pattern
  • a matte layer is formed in a portion corresponding to the grain node. In this case, a stereoscopic effect corresponding to the actual grain can be obtained.
  • a transparent resin layer made of, for example, an acrylic polyol resin or the like is suitable, and is formed with a uniform thickness over the entire surface of the pattern layer to which the pattern is applied.
  • the gloss value indicating the glossiness of the high gloss region is 30 or more and the gloss value of the low gloss region is 10 or less.
  • the gloss of the surface of the clear coat layer can be partially reduced, and the design of the decorative part can be enhanced.
  • the top view which shows a part of decoration component for motor vehicles of one Embodiment.
  • the expanded sectional view which shows the decoration component for motor vehicles of one Embodiment.
  • Explanatory drawing which shows a decoration layer formation process.
  • Explanatory drawing which shows a clear coat layer formation process.
  • Explanatory drawing which shows the surface of the sample goods used as the reference
  • the graph which shows the relationship between solid content and expression property.
  • the graph which shows the relationship between the main solvent boiling point and expression property.
  • the graph which shows the relationship between atomization pressure and expression property.
  • Graph showing the relationship between solid content and expression The graph which shows the relationship between atomization pressure and expression property.
  • Explanatory drawing which shows the SEM photograph of the decorative component for motor vehicles of this Embodiment.
  • an automotive decorative component 1 includes a resin molded body 3 (component) having a decorative layer 2 on a surface layer portion, and a clear coat layer 4 that protects the surface of the decorative layer 2. And.
  • the automotive decorative component 1 is an interior component that constitutes an armrest of a door.
  • the decorative layer 2 includes a handle layer 5, a gloss layer 6, and a mat layer 7, and is formed on the surface layer portion of the resin molded body 3 by hydraulic transfer.
  • the pattern layer 5 has a thickness of about 4 ⁇ m
  • the gloss layer 6 has a thickness of about 1 ⁇ m
  • the mat layer 7 has a thickness of about 2 ⁇ m.
  • the pattern layer 5 is a printing layer for applying the pattern 8 and includes nitrocellulose and a pigment.
  • a woodgrain pattern 8 is drawn.
  • the gloss layer 6 is a transparent resin layer formed in order to give gloss to the pattern 8 of the pattern layer 5, and is made of, for example, an acrylic polyol resin.
  • the gloss layer 6 is provided on the upper layer side of the handle layer 5 and is formed with a uniform thickness on the entire surface thereof.
  • the mat layer 7 is a matte layer provided on the upper side of the gloss layer 6 and is formed at a position corresponding to the pattern 8 of the pattern layer 5, specifically, at a position corresponding to a node of the grain.
  • the mat layer 7 is configured to include nitrocellulose, a pigment, and silica, and the unevenness 7a is formed on the surface thereof.
  • the mat layer 7 has a surface roughness Ra of about 1 ⁇ m.
  • the pigment of the mat layer 7 includes the same pigment (specifically, black pigment) as the handle layer 5 formed on the lower layer side.
  • the clear coat layer 4 formed on the uppermost layer of the automobile decorative part 1 is formed by applying a transparent clear paint containing a matting agent.
  • the thickness of the clear coat layer 4 is about 10 ⁇ m to 30 ⁇ m, and is formed along the uneven shape on the surface of the mat layer 7.
  • the surface of the clear coat layer 4 has a high gloss region R1 having a relatively high gloss level and a low gloss region R2 having a relatively low gloss level.
  • the mat layer 7 (unevenness 7 a) is formed immediately below the low gloss region R 2, and the fine unevenness 4 a is formed on the surface of the low gloss region R 2. Is done. Further, the mat layer 7 is not formed immediately below the high gloss region R1, and the surface of the high gloss region R1 is a flat surface.
  • the unevenness 4a is formed on the surface of the clear coat layer 4 in the portion where the mat layer 7 is formed according to the pattern 8 (low gloss region R2 corresponding to the node of the grain).
  • the gloss level of the low gloss region R2 is low, and the gloss value indicating the glossiness is about 10.
  • the gloss layer 6 is exposed in the high gloss region R1 where the mat layer 7 is not formed. For this reason, the glossiness of the high gloss region R1 becomes high, and the gloss value indicating the glossiness is about 30.
  • the luster is reduced in the portion corresponding to the node of the wood grain in the woodgrain pattern 8, so that the same three-dimensional effect as the actual wood grain is obtained.
  • the fine unevenness 4a on the surface of the clear coat layer 4 is an unevenness that cannot be recognized by touch feeling with a hand.
  • the surface roughness Ra of the clear coat layer 4 is 1 ⁇ m or less even in the low gloss region R2 where the fine irregularities 4a are present.
  • a decoration layer forming step is performed.
  • the pattern layer 5, the gloss layer 6 and the mat layer 7 constituting the decorative layer 2 are transferred to the surface layer portion of the resin molded body 3 by water pressure using a hydraulic transfer device (see FIG. 3).
  • the water pressure transfer apparatus is provided with a transfer tank for storing treated water.
  • the hydraulic transfer device floats a transfer film (not shown) formed with a mat layer 7, a gloss layer 6 and a handle layer 5 on a substrate on the surface of treated water in a transfer tank, and in that state, above the transfer film.
  • the resin molded body 3 is pressed. Thereby, the pattern layer 5, the gloss layer 6, and the mat layer 7 are transferred onto the surface of the resin molded body 3 by water pressure. As a result, the pattern layer 5 is formed on the surface layer portion of the resin molded body 3, and the unevenness 7 a of the mat layer 7 is formed at a location directly below the low gloss region R ⁇ b> 2 later.
  • clear coating is performed as a clear coat layer forming process.
  • the decorative layer 2 (the pattern layer 5, the gloss layer 6, and the mat layer 7) is formed by spraying the transparent clear paint P ⁇ b> 1 using the atomization type coating machine 11.
  • the clear coat layer 4 is applied to the surface of the formed resin molded body 3.
  • an ester-based clear paint P1 containing a low-boiling solvent having a boiling point of 70 ° C. to 90 ° C. (in this embodiment, ethyl acetate) as a main solvent is used.
  • the clear paint P1 a two-component urethane paint containing a solid content (such as a matting agent or a resin material) at a ratio of 35% by mass to 40% by mass is used.
  • the distance (gun distance) between the discharge port 12 of the atomizing type coating machine 11 and the surface of the resin molded body 3 is 100 mm, depending on the coating conditions where the discharge amount is 50 cc / min and the atomization pressure is 0.08 MPa. In this state, four times of overcoating are performed. Thereafter, the resin molded body 3 is placed in a drying device (not shown), and the clear coat layer 4 is dried at a temperature of about 80 ° C. As a result, the clear coat layer 4 having the low gloss region R2 of the surface shape along the unevenness 7a of the mat layer 7 is formed, and the automobile decorative part 1 as shown in FIGS. 1 and 2 is manufactured.
  • the present inventor conducted a coating experiment in order to determine the optimum conditions for clear coating.
  • factors estimated to contribute to the degree of gloss and matte appearance specifically, the solid content ratio of the clear paint P1, the boiling point of the main solvent of the clear paint P1, the discharge amount, The atomization pressure, gun distance, and the number of coatings were used as experimental factors, and the coating experiment was performed with these factors changed.
  • the resin molding 3 in which the decorative layer 2 was formed by the above-described manufacturing method (hydraulic transfer or the like) was used, and the conditions were the same except for clear coating.
  • Table 1 shows the levels of the factors A to F and the factors A to F changed in the coating experiment, and Table 2 shows the experimental results.
  • the GM expression degree on the surface of the clear coat layer 4 (the surface of the decorative part 1) after the painting was sensitively evaluated, and the evaluation result is shown in Table 2 as five-stage characteristic values. More specifically, as shown in FIG. 5, a sample product serving as a reference for the degree of GM expression (characteristic values 1 to 5) is prepared in advance, and the decorative part 1 (experiment No. 1) obtained in the painting experiment is prepared. 1 to No. 16) are compared with the GM expression level of the surface and the GM expression level of the sample product, and the matching GM expression level is visually determined. The characteristic value indicating the degree of GM expression is “1” when the expression is the worst and “5” when the expression is the best.
  • the ratio of the solid content of factor A is significant at a significance level of 1%, and as shown in FIG. 6, the clear paint P1 having a low solid content ratio (the solid content is 30% by mass to 40% by mass). ), The GM expression is improved.
  • the boiling point of the main solvent of factor B is significant at a significant level of 1%.
  • the clear paint P1 having a low main solvent boiling point (ester-based solvent having a main solvent boiling point of 70 ° C. to 90 ° C.) is used.
  • the atomization pressure of factor D is significant at a significance level of 5%. As shown in FIG. 8, when the atomization pressure is lowered, the GM expression is improved.
  • the ratio of the solid content of factor A is significant at the significance level of 5%, and when the ratio of the solid content is 35% by mass to 40% by mass as shown in FIG. GM expression was the best.
  • the atomization pressure of factor D was significant at a significance level of 1%, and as shown in FIG. 10, when the atomization pressure was 0.08 MPa, GM expression was the best.
  • an ester-based clear paint P1 having a solid content of 35 mass% to 40 mass% and a main solvent boiling point of 70 ° C. to 90 ° C. is used, and the discharge amount is 50 cc / min. Clear coating was performed under the conditions that the atomization pressure was 0.08 MPa, the gun distance was 100 mm, and the number of overcoating was four. As a result, the decorative part 1 for an automobile having gloss and matting is produced.
  • the cross section was confirmed using a scanning electron microscope (SEM).
  • SEM scanning electron microscope
  • FIG. 11 the SEM photograph of the cross section of the decorative component 1 for motor vehicles is shown.
  • the high gloss region R1 in the clear coat layer 4 has a smooth surface because the mat layer 7 does not exist immediately below.
  • the low gloss region R2 in the clear coat layer 4 since the mat layer 7 exists immediately below, the fine unevenness 4a is formed on the surface.
  • This clear paint P1 has a lower boiling point of the main solvent compared to the conventionally used hydrocarbon-based clear paint (boiling point 110 ° C. to 140 ° C., solid content 50 mass% to 60 mass%). There is less solid content in the paint.
  • this clear paint P1 is sprayed onto the surface of the component by the atomizing coater 11, the main solvent of the ester is volatilized before the surface is smoothed.
  • the clear paint along the surface shape of the mat layer 7 in the decorative layer 2 is cleared.
  • Coat layer 4 is formed.
  • the region having the unevenness 7 a of the mat layer 7 immediately below becomes a surface shape having fine unevenness 4 a and becomes a low gloss region R ⁇ b> 2 having a relatively low gloss.
  • a region where the unevenness 7 a of the mat layer 7 is not directly below becomes a flat surface shape and becomes a high gloss region R 1 having a relatively high gloss level.
  • the gloss of the low gloss region R2 can be partially removed on the surface of the clear coat layer 4, so that the visual according to the decorative layer 2 (the pattern 8 of the pattern layer 5) is visually reduced. 3D expression is possible, and the design of the decorative part 1 for automobiles can be sufficiently enhanced.
  • the clear paint P1 having a solid content of 35% by mass or more and 40% by mass or less is used as the optimum condition. When the range of conditions is widened with respect to this optimum condition, specifically, even when a clear paint having a solid content of 10% by mass or more and 55% by mass or less is used, compared with the conventional decorative part 100 for automobiles. Thus, it was possible to produce a decorative part 1 for an automobile having gloss and mattness.
  • the decorative layer 2 (pattern layer 5, gloss layer 6 and mat layer 7) is obtained by hydraulically transferring the transfer film to the surface layer portion of the resin molded body 3.
  • the clear coat layer 4 is formed by clear coating. If it does in this way, the decoration layer 2 which has the unevenness
  • the clear coat layer 4 the region immediately above the irregularities 7 a of the mat layer 7 formed according to the pattern 8 of the pattern layer 5 becomes the low gloss region R 2, and the gloss can be surely erased.
  • the gloss layer 6 is exposed in the area where the mat layer 7 is not formed, so that it becomes a high gloss area R ⁇ b> 1 and the gloss level can be increased. If it does in this way, the three-dimensional effect according to the pattern 8 (wood grain) of the pattern layer 5 can be obtained reliably, and the design property of the decorative part 1 for motor vehicles can be improved.
  • the difference in glossiness between the high gloss region R1 and the low gloss region R2 on the surface of the clear coat layer 4 is three times, so that the visual three-dimensional expression Can be achieved, and the design can be sufficiently enhanced.
  • the surface roughness Ra of the clear coat layer 4 is 1 ⁇ m or less, there is little change in the three-dimensional effect due to wear on the surface of the component, and the design of the decorative component 1 for automobiles is kept in a good state even after long-term use. Can be maintained.
  • the decorative layer 2 is formed by hydraulically transferring a transfer film having the unevenness 7a of the mat layer 7 on the handle layer 5 to the surface layer portion of the resin molded body 3.
  • unevenness may be formed on the surface layer portion of the resin molded body 3 by embossing, or unevenness may be formed on the surface layer portion of the resin molded body 3 by laser processing.
  • the surface layer portion where unevenness is formed in the resin molded body 3 is a decorative layer.
  • a two-component urethane paint is used as the clear paint, but a one-component urethane paint may be used.
  • other clear paint such as acrylic paint may be used in addition to urethane paint.
  • the decorative part 1 for an automobile is embodied as an armrest of a door, but other than this, it may be embodied as a decorative part such as a console box or an instrument panel.
  • a decorative part such as a console box or an instrument panel.
  • the clear paint is sprayed under a coating condition in which a discharge amount of the atomizing coater is 50 cc / min or more and 65 cc / min or less. Manufacturing method of decorative parts.
  • a transfer film is formed by laminating a pattern layer for imparting a pattern, a gloss layer for imparting gloss, and a mat layer having the irregularities.
  • a method for producing a decorative part, wherein the pattern layer, the gloss layer, and the mat layer to be the decorative layer are formed by hydraulic transfer.
  • the mat layer has a surface roughness Ra of 2 ⁇ m or less.
  • the mat layer is configured to include the same pigment as the pigment included in the handle layer formed on the lower layer side thereof.
  • the pattern is a woodgrain pattern
  • the mat layer is formed in a portion corresponding to a node of the wood grain.
  • the gloss layer is a transparent resin layer made of an acrylic polyol resin, and is formed with a uniform thickness on the entire surface of the pattern layer to which the pattern is applied.

Abstract

A decorative component (1) for motor vehicles which comprises a molded resin (3) having a decorative layer (2) on a surface layer part thereof and a clear coating layer (4) that protects the surface of the decorative layer (2), the surface of the clear coating layer (4) having high-gloss regions (R1), which have a relatively high gloss, and, intermingled therewith, low-gloss regions (R2), which have a relatively low gloss. The clear coating layer (4) is formed by spraying a clear coating composition over the surface of the decorative layer (2) with an atomization-type coater, the clear coating composition containing an ester-based solvent that is a low-boiling-point solvent having a boiling point below 100°C, as the main solvent, and having a solid content of 35-40 mass%. Thus, the clear coating layer has a surface partly reduced in gloss, and a decorative component having a highly attractive appearance is produced.

Description

加飾部品及びその製造方法Decorative parts and manufacturing method thereof
 本発明は、部品表面において艶の程度の高い領域と低い領域とが混在する加飾部品及びその製造方法に関するものである。 The present invention relates to a decorative part in which a high-gloss area and a low-gloss area are mixed on the surface of the part, and a manufacturing method thereof.
 自動車の内装部品などでは、デザイン性や品質を高めるために樹脂成形体の表面に装飾を加えるようにした加飾部品(例えば、コンソールボックス、インストルメントパネル、アームレストなど)が多く実用化されている。このような加飾部品に装飾を加える加飾方法としては、水圧転写が一般的に用いられている(例えば特許文献1参照)。 In automotive interior parts, many decorative parts (for example, console boxes, instrument panels, armrests, etc.) that add decoration to the surface of the resin molded body in order to improve design and quality have been put to practical use. . As a decoration method for adding decoration to such a decorative part, hydraulic transfer is generally used (see, for example, Patent Document 1).
 水圧転写とは、水面上に特殊フィルムを浮かべ、そのフィルムに印刷された所定の絵柄(木目模様や幾何学模様などの絵柄)を水圧によって樹脂成形体の表面に転写する技術である。この水圧転写を行う場合、樹脂成形体の表面に転写された加飾層(印刷層)は、塗装膜と比べて弱く耐久性が十分ではない。このため、クリア塗装を行うことで加飾層の表面を保護するクリアコート層(表面保護層)が形成される。さらに、部品表面の意匠性を高めるために、絵柄の模様に応じて、艶のあるクリアコート層を形成したり、艶のないクリアコート層を形成したりする場合もある。 Water pressure transfer is a technique in which a special film is floated on the surface of the water, and a predetermined pattern printed on the film (a pattern such as a wood grain pattern or a geometric pattern) is transferred onto the surface of the resin molded body by water pressure. When this hydraulic transfer is performed, the decorative layer (printing layer) transferred to the surface of the resin molded body is weak and insufficient in durability as compared with the coating film. For this reason, the clear coat layer (surface protective layer) which protects the surface of a decoration layer by performing clear coating is formed. Furthermore, in order to enhance the design of the part surface, a glossy clear coat layer may be formed or a matte clear coat layer may be formed according to the pattern of the pattern.
 因みに、特許文献1では、インク層(加飾層)を有するフィルムを水圧転写し、インク層によるはじき作用と活性剤の集合力とによって部品表面に凹凸を形成する手法が開示されている。部品表面に凹凸を形成することで、視覚的な立体感や触感的な立体感(凹凸触感)が得られる。 Incidentally, Patent Document 1 discloses a technique in which a film having an ink layer (decorative layer) is hydraulically transferred, and unevenness is formed on the surface of the component by the repelling action of the ink layer and the collective force of the activator. By forming irregularities on the surface of the component, a visual three-dimensional effect and a tactile three-dimensional effect (uneven texture) can be obtained.
特開2009-101657号公報JP 2009-101657 A
 ところで、クリア塗装を行って部品表面にクリアコート層を形成した従来の加飾部品では、一定調子(具体的には、表面全体に艶がある状態、または表面全体の艶が消された状態)の艶表現しか行うことができなかった。このため、部品表面において、艶を部分的に変化させて視覚的な立体表現を行うことができなかった。 By the way, with conventional decorative parts that have been coated with clear coating to form a clear coat layer on the surface of the part, it is in a certain condition (specifically, the entire surface is glossy or the entire surface is delustered) Only glossy expression was possible. For this reason, it has been impossible to perform a visual three-dimensional expression by partially changing the gloss on the surface of the component.
 特許文献1の転写フィルムを用いて水圧転写を行う場合、部品表面に凹凸が付与される。しかしながら、部品表面を保護するためのクリアコート層を形成する場合には、凹凸による立体感を損ねてしまうといった問題が生じる。また、表面保護層を形成しない場合、部品表面から突出する凸部の高低差は12μm程度であり、長期間使用すると、摩耗によってその凸部が削られることで立体感が得られなくなり、意匠性が低下してしまうといった問題が生じる。 When water pressure transfer is performed using the transfer film of Patent Document 1, irregularities are imparted to the component surface. However, when a clear coat layer for protecting the component surface is formed, there arises a problem that the three-dimensional effect due to the unevenness is impaired. In addition, when the surface protective layer is not formed, the height difference of the protruding portion protruding from the component surface is about 12 μm, and when used for a long period of time, the protruding portion is scraped off due to wear, so that the three-dimensional effect cannot be obtained, and the design property This causes a problem of lowering.
 本発明は上記の課題に鑑みてなされたものであり、その目的は、加飾層を保護するクリアコート層において、表面の艶を部分的に落すことで意匠性に優れた加飾部品及びその製造方法を提供することにある。 The present invention has been made in view of the above problems, and its purpose is to provide a decorative part excellent in design by partially removing the gloss of the surface in a clear coat layer that protects the decorative layer and its It is to provide a manufacturing method.
 上記課題を解決するために、手段1に記載の発明は、表層部に加飾層を有する部品と、前記加飾層の表面を保護するクリアコート層とを備え、前記クリアコート層の表面上に、相対的に艶の程度が高い高艶領域と、相対的に艶の程度の低い低艶領域とが混在する加飾部品の製造方法であって、前記部品の表層部に前記加飾層を形成するとともに、前記加飾層の表面において後に前記低艶領域の直下となる箇所に凹凸を形成しておく加飾層形成工程と、沸点が100℃未満である低沸点溶剤を主溶剤として含み、固形分が10質量%以上55質量%以下であるクリア塗料を用い、霧化式塗装機により前記クリア塗料を前記加飾層の表面に噴霧することで、前記凹凸に沿った表面形状の前記低艶領域を有する前記クリアコート層を形成するクリアコート層形成工程とを含むことを特徴とする加飾部品の製造方法をその要旨とする。 In order to solve the above-mentioned problem, the invention described in means 1 includes a component having a decorative layer on a surface layer portion and a clear coat layer for protecting the surface of the decorative layer, on the surface of the clear coat layer. A method for producing a decorative part in which a high-gloss area having a relatively high gloss level and a low-gloss area having a relatively low gloss level are mixed, wherein the decorative layer is formed on a surface layer portion of the part. And a decorative layer forming step in which irregularities are formed on the surface of the decorative layer later on the surface immediately below the low gloss region, and a low boiling point solvent having a boiling point of less than 100 ° C. as a main solvent. Including a clear paint having a solid content of 10% by mass or more and 55% by mass or less, and spraying the clear paint on the surface of the decorative layer with an atomizing coating machine, the surface shape along the unevenness A clear coat layer forming the clear coat layer having the low gloss region. The decorative component manufacturing method which comprises a coating layer formation step and the gist thereof.
 手段1に記載の発明によると、加飾層形成工程にて部品の表層部に加飾層を形成するとともに、その加飾層の表面に凹凸を形成した後、クリアコート層形成工程が行われる。本発明のクリアコート層形成工程では、沸点が100℃未満である低沸点溶剤(例えばエステル系溶剤)を主溶剤として含み、固形分が10質量%以上55質量%以下であるクリア塗料が用いられる。このクリア塗料は、従来一般的に用いられている炭化水素系のクリア塗料と比較すると、主溶剤の沸点が低く塗料中に含まれる固形分が少なくなっている。このクリア塗料を霧化式塗装機により加飾層の表面に噴霧すると、表面が平滑化する前にエステル系の主溶剤が揮発するため、加飾層の表面形状に沿ったクリアコート層が形成される。この結果、クリアコート層の表面において、直下に加飾層の凹凸がある領域は、微細な凹凸がある表面形状となり、相対的に艶の程度が低い低艶領域となる。一方、クリアコート層の表面において、直下に加飾層の凹凸がない領域は、平坦な表面形状となり、相対的に艶の程度が高い高艶領域となる。このように、本発明では、部品表面において低艶領域の艶を部分的に落すことができるため、加飾層に応じた視覚的な立体表現が可能となり、加飾部品の意匠性を十分に高めることができる。 According to the invention described in Means 1, the decorative layer is formed on the surface layer part of the component in the decorative layer forming step, and after forming irregularities on the surface of the decorative layer, the clear coat layer forming step is performed. . In the clear coat layer forming step of the present invention, a clear paint having a boiling point of less than 100 ° C. (for example, an ester solvent) as a main solvent and having a solid content of 10% by mass to 55% by mass is used. . This clear paint has a lower boiling point of the main solvent and a lower solid content in the paint as compared with a hydrocarbon-based clear paint generally used conventionally. When this clear paint is sprayed onto the surface of the decorative layer with an atomizing coater, the ester-based main solvent volatilizes before the surface is smoothed, so a clear coat layer is formed along the surface shape of the decorative layer. Is done. As a result, on the surface of the clear coat layer, the region having the unevenness of the decoration layer immediately below becomes a surface shape having fine unevenness, and becomes a low gloss region having a relatively low gloss level. On the other hand, on the surface of the clear coat layer, the region where the decorative layer is not directly below is a flat surface shape, which is a high gloss region having a relatively high gloss level. As described above, in the present invention, the gloss of the low gloss region can be partially dropped on the surface of the component, so that a visual three-dimensional expression corresponding to the decorative layer is possible, and the design of the decorative component is sufficiently achieved. Can be increased.
 クリア塗料は、固形分が30質量%以上50質量%以下が好ましく、35質量%以上40質量%以下であることがより好ましい。このようにすると、クリアコート層の表面において、低艶領域と高艶領域とにおける艶の程度の差が大きくなり、加飾部品の意匠性をより高めることができる。 The clear paint preferably has a solid content of 30% by mass to 50% by mass, and more preferably 35% by mass to 40% by mass. If it does in this way, in the surface of a clear coat layer, the difference of the grade of the glossiness in a low gloss area and a high gloss area becomes large, and the design nature of a decoration part can be improved more.
 クリアコート層形成工程では、霧化式塗装機の霧化圧が0.06MPa以上0.09MPa以下である塗装条件にてクリア塗料を噴霧することが好ましい。また、霧化式塗装機の吐出量が50cc/min以上である塗装条件によってクリア塗料を噴霧することが好ましく、霧化式塗装機の吐出量が50cc/min以上65cc/min以下である塗装条件によってクリア塗料を噴霧することがより好ましい。このような塗布条件とすると、霧化式塗装機から噴霧される塗料ミストの粒径が大きくなり、加飾層の凹凸に塗料がなじみ易くなる。この結果、加飾層の表面における凹凸形状に沿ったクリアコート層をより確実に形成することができる。 In the clear coat layer forming step, it is preferable to spray the clear paint under a coating condition in which the atomization pressure of the atomization type coating machine is 0.06 MPa or more and 0.09 MPa or less. Further, it is preferable to spray the clear paint according to the coating conditions in which the discharge amount of the atomizing type coating machine is 50 cc / min or more, and the coating conditions in which the discharge amount of the atomizing type coating machine is from 50 cc / min to 65 cc / min. More preferably, the clear paint is sprayed. Under such application conditions, the particle size of the paint mist sprayed from the atomizing coater becomes large, and the paint is easily adapted to the unevenness of the decorative layer. As a result, the clear coat layer along the uneven shape on the surface of the decorative layer can be more reliably formed.
 加飾層形成工程では、柄層上に凹凸を有する転写フィルムを水圧転写することにより加飾層を形成してもよい。この場合、水圧転写することで凹凸を有する加飾層を確実に形成することができる。なお、加飾層形成工程では、シボ加工によって前記部品の表層部に凹凸を形成してもよいし、レーザ加工によって前記部品の表層部に凹凸を形成してもよい。 In the decorative layer forming step, the decorative layer may be formed by hydraulic transfer of a transfer film having irregularities on the pattern layer. In this case, a decorative layer having irregularities can be reliably formed by hydraulic transfer. In the decorative layer forming step, unevenness may be formed on the surface layer portion of the component by embossing, or unevenness may be formed on the surface layer portion of the component by laser processing.
 また、加飾層形成工程では、絵柄を付与するための柄層と、艶を付与するためのグロス層と、凹凸を有するマット層とが積層されてなる転写フィルムを水圧転写することにより、加飾層となる柄層、グロス層及びマット層を形成してもよい。この場合、クリアコート層において、マット層の凹凸の直上となる領域が低艶領域となり、艶を確実に消すことができる。一方、クリアコート層において、凹凸の少ないグロス層の直上となる領域は高艶領域となり、艶の程度を高めることができる。このようにすると、柄層の絵柄に応じた立体感を確実に得ることができ、加飾部品の意匠性を高めることができる。 In addition, in the decorative layer forming step, a transfer film formed by laminating a pattern layer for imparting a pattern, a gloss layer for imparting gloss, and a mat layer having irregularities is hydraulically transferred to the decorative layer. You may form the pattern layer used as a decoration layer, a gloss layer, and a mat | matte layer. In this case, in the clear coat layer, the region directly above the unevenness of the mat layer becomes a low gloss region, and the gloss can be surely erased. On the other hand, in the clear coat layer, the region directly above the gloss layer with few irregularities is a high gloss region, and the degree of gloss can be increased. If it does in this way, the three-dimensional effect according to the pattern of the pattern layer can be obtained reliably, and the designability of a decorative part can be improved.
 手段2に記載の発明は、表層部に加飾層を有する部品と、前記加飾層の表面を保護するクリアコート層とを備え、前記クリアコート層の表面上に、相対的に艶の程度が高い高艶領域と、相対的に艶の程度の低い低艶領域とが混在する加飾部品であって、前記加飾層の表面において前記低艶領域の直下となる箇所に凹凸が形成されるとともに、前記クリアコート層の前記低艶領域は前記凹凸に沿った表面形状を有し、前記クリアコート層は表面粗さRaが1μm以下であり、前記高艶領域と前記低艶領域とにおける光沢度の差が2倍以上であることを特徴とする加飾部品をその要旨とする。 The invention described in Means 2 includes a part having a decorative layer on a surface layer portion and a clear coat layer that protects the surface of the decorative layer, and is relatively glossy on the surface of the clear coat layer. Is a decorative part in which a high-gloss area having a high gloss and a low-gloss area having a relatively low gloss level are mixed, and irregularities are formed on the surface of the decorative layer immediately below the low-gloss area. In addition, the low gloss region of the clear coat layer has a surface shape along the irregularities, the clear coat layer has a surface roughness Ra of 1 μm or less, and the high gloss region and the low gloss region The gist of the decorative part is characterized in that the difference in glossiness is twice or more.
 手段2に記載の発明によると、加飾部品の表層部に加飾層を有し、その加飾層の表面がクリアコート層によって保護されている。そして、クリアコート層の表面において、直下に加飾層の凹凸がある領域は、凹凸に沿った表面形状となり、相対的に艶の程度が低い低艶領域となる。一方、クリアコート層の表面において、直下に加飾層の凹凸がない領域は、平坦な表面形状となり、相対的に艶の程度が高い高艶領域となる。本発明の加飾部品において、クリアコート層表面の高艶領域と低艶領域とにおける光沢度の差が2倍以上であるため、視覚的な立体表現が可能となり、その意匠性を十分に高めることができる。また、クリアコート層の表面粗さRaが1μm以下であるため、部品表面の摩耗による立体感の変化が少なく、長期間使用しても加飾部品の意匠性を良好な状態に維持することができる。 According to the invention described in Means 2, the decorative layer has a decorative layer on the surface layer portion, and the surface of the decorative layer is protected by the clear coat layer. And the area | region which has the unevenness | corrugation of a decoration layer directly under the surface of a clearcoat layer turns into a surface shape along the unevenness | corrugation, and becomes a low glossiness area | region where the degree of gloss is relatively low. On the other hand, on the surface of the clear coat layer, the region where the decorative layer is not directly below is a flat surface shape, which is a high gloss region having a relatively high gloss level. In the decorative part of the present invention, since the difference in glossiness between the high gloss area and the low gloss area on the clear coat layer surface is more than twice, visual three-dimensional expression is possible and the design is sufficiently enhanced. be able to. In addition, since the surface roughness Ra of the clear coat layer is 1 μm or less, there is little change in stereoscopic effect due to wear on the surface of the component, and the design of the decorative component can be maintained in a good state even when used for a long time. it can.
 加飾層を構成するマット層は、表面粗さRaが2μm以下であることが好ましい。このマット層上にクリア塗料を塗装することで、クリアコート層の表面粗さRaを1μm以下とすることが可能となる。また、マット層は、その下層側に形成される柄層に含まれる顔料と同一の顔料を含んで構成されることが好ましい。この場合、絵柄に応じた凹凸を確実に付与することができる。具体的には、絵柄が木目調の柄である場合、木目の節に対応する部分にマット層が形成される。この場合、実際の木目に応じた立体感を得ることができる。 It is preferable that the mat layer constituting the decorative layer has a surface roughness Ra of 2 μm or less. By applying a clear paint on the mat layer, the surface roughness Ra of the clear coat layer can be 1 μm or less. Moreover, it is preferable that a mat layer is comprised including the same pigment as the pigment contained in the handle layer formed in the lower layer side. In this case, unevenness according to the pattern can be reliably imparted. Specifically, when the pattern is a woodgrain pattern, a matte layer is formed in a portion corresponding to the grain node. In this case, a stereoscopic effect corresponding to the actual grain can be obtained.
 加飾層を構成するグロス層としては、例えばアクリルポリオール樹脂等からなる透明な樹脂層が好適であり、絵柄を付与する柄層の表面全体に均一の厚さで形成される。このようにグロス層を形成することにより、柄層の絵柄に確実に艶を付与することができる。 As the gloss layer constituting the decorative layer, a transparent resin layer made of, for example, an acrylic polyol resin or the like is suitable, and is formed with a uniform thickness over the entire surface of the pattern layer to which the pattern is applied. By forming the gloss layer in this way, gloss can be surely imparted to the pattern of the pattern layer.
 また、クリアコート層の表面において、高艶領域の光沢度を示すグロス値が30以上であり、低艶領域のグロス値が10以下であることが好ましい。このように、クリアコート層の表面において光沢度の差を大きくすることにより、加飾部品の立体感を確実に得ることができる。 Further, on the surface of the clear coat layer, it is preferable that the gloss value indicating the glossiness of the high gloss region is 30 or more and the gloss value of the low gloss region is 10 or less. Thus, by increasing the difference in glossiness on the surface of the clear coat layer, the three-dimensional effect of the decorative part can be obtained with certainty.
 以上詳述したように、手段1または2に記載の発明によると、クリアコート層の表面の艶を部分的に落すことができ、加飾部品の意匠性を高めることができる。 As described in detail above, according to the invention described in Means 1 or 2, the gloss of the surface of the clear coat layer can be partially reduced, and the design of the decorative part can be enhanced.
一実施の形態の自動車用加飾部品の一部を示す平面図。The top view which shows a part of decoration component for motor vehicles of one Embodiment. 一実施の形態の自動車用加飾部品を示す拡大断面図。The expanded sectional view which shows the decoration component for motor vehicles of one Embodiment. 加飾層形成工程を示す説明図。Explanatory drawing which shows a decoration layer formation process. クリアコート層形成工程を示す説明図。Explanatory drawing which shows a clear coat layer formation process. 特性値の基準となるサンプル品の表面を示す説明図。Explanatory drawing which shows the surface of the sample goods used as the reference | standard of a characteristic value. 固形分と発現性との関係を示すグラフ。The graph which shows the relationship between solid content and expression property. 主溶剤沸点と発現性との関係を示すグラフ。The graph which shows the relationship between the main solvent boiling point and expression property. 霧化圧と発現性との関係を示すグラフ。The graph which shows the relationship between atomization pressure and expression property. 固形分と発現性との関係を示すグラフGraph showing the relationship between solid content and expression 霧化圧と発現性との関係を示すグラフ。The graph which shows the relationship between atomization pressure and expression property. 本実施の形態の自動車用加飾部品のSEM写真を示す説明図。Explanatory drawing which shows the SEM photograph of the decorative component for motor vehicles of this Embodiment.
 以下、本発明を自動車用加飾部品に具体化した一実施の形態を図面に基づき詳細に説明する。 Hereinafter, an embodiment in which the present invention is embodied in a decorative part for an automobile will be described in detail with reference to the drawings.
 図1及び図2に示されるように、自動車用加飾部品1は、表層部に加飾層2を有する樹脂成形体3(部品)と、加飾層2の表面を保護するクリアコート層4とを備えている。なお、自動車用加飾部品1は、ドアのアームレストを構成する内装部品である。加飾層2は、柄層5、グロス層6及びマット層7からなり、水圧転写によって樹脂成形体3の表層部に形成されている。本実施の形態において、柄層5の厚さは4μm程度であり、グロス層6の厚さは1μm程度であり、マット層7の厚さは2μm程度である。 As shown in FIGS. 1 and 2, an automotive decorative component 1 includes a resin molded body 3 (component) having a decorative layer 2 on a surface layer portion, and a clear coat layer 4 that protects the surface of the decorative layer 2. And. The automotive decorative component 1 is an interior component that constitutes an armrest of a door. The decorative layer 2 includes a handle layer 5, a gloss layer 6, and a mat layer 7, and is formed on the surface layer portion of the resin molded body 3 by hydraulic transfer. In the present embodiment, the pattern layer 5 has a thickness of about 4 μm, the gloss layer 6 has a thickness of about 1 μm, and the mat layer 7 has a thickness of about 2 μm.
 柄層5は、絵柄8を付与するための印刷層であり、ニトロセルロース及び顔料を含んで構成される。本実施の形態の柄層5には、例えば木目調の絵柄8が描画されている。グロス層6は、柄層5の絵柄8に艶を付与するために形成される透明な樹脂層であり、例えばアクリルポリオール樹脂からなる。グロス層6は、柄層5の上層側に設けられ、その表面全体に均一の厚さで形成される。マット層7は、グロス層6の上層側に設けられる艶消し層であり、柄層5の絵柄8に応じた位置、具体的には、木目の節に対応する位置に形成されている。マット層7は、ニトロセルロース、顔料及びシリカを含んで構成されており、その表面に凹凸7aが形成されている。なお、マット層7の表面粗さRaは1μm程度となっている。また、マット層7の顔料としては、その下層側に形成される柄層5と同一の顔料(具体的には、黒色の顔料)を含んでいる。 The pattern layer 5 is a printing layer for applying the pattern 8 and includes nitrocellulose and a pigment. In the pattern layer 5 of the present embodiment, for example, a woodgrain pattern 8 is drawn. The gloss layer 6 is a transparent resin layer formed in order to give gloss to the pattern 8 of the pattern layer 5, and is made of, for example, an acrylic polyol resin. The gloss layer 6 is provided on the upper layer side of the handle layer 5 and is formed with a uniform thickness on the entire surface thereof. The mat layer 7 is a matte layer provided on the upper side of the gloss layer 6 and is formed at a position corresponding to the pattern 8 of the pattern layer 5, specifically, at a position corresponding to a node of the grain. The mat layer 7 is configured to include nitrocellulose, a pigment, and silica, and the unevenness 7a is formed on the surface thereof. The mat layer 7 has a surface roughness Ra of about 1 μm. Further, the pigment of the mat layer 7 includes the same pigment (specifically, black pigment) as the handle layer 5 formed on the lower layer side.
 自動車用加飾部品1の最上層に形成されるクリアコート層4は、艶消し剤を含んだ透明クリア塗料を塗装することで形成される。クリアコート層4の厚さは10μm~30μm程度であり、マット層7表面の凹凸形状に沿って形成されている。 The clear coat layer 4 formed on the uppermost layer of the automobile decorative part 1 is formed by applying a transparent clear paint containing a matting agent. The thickness of the clear coat layer 4 is about 10 μm to 30 μm, and is formed along the uneven shape on the surface of the mat layer 7.
 本実施の形態の自動車用加飾部品1において、クリアコート層4の表面には、相対的に艶の程度の高い高艶領域R1と、相対的に艶の程度の低い低艶領域R2とが混在する。具体的には、クリアコート層4の表面において、低艶領域R2の直下となる箇所にマット層7(凹凸7a)が形成されており、低艶領域R2の表面には微細な凹凸4aが形成される。また、高艶領域R1の直下にはマット層7が形成されておらず、高艶領域R1の表面は平坦面となっている。 In the automotive decorative component 1 of the present embodiment, the surface of the clear coat layer 4 has a high gloss region R1 having a relatively high gloss level and a low gloss region R2 having a relatively low gloss level. Mixed. Specifically, on the surface of the clear coat layer 4, the mat layer 7 (unevenness 7 a) is formed immediately below the low gloss region R 2, and the fine unevenness 4 a is formed on the surface of the low gloss region R 2. Is done. Further, the mat layer 7 is not formed immediately below the high gloss region R1, and the surface of the high gloss region R1 is a flat surface.
 自動車用加飾部品1の表層部において、絵柄8に応じてマット層7を形成した部分(木目の節に対応する低艶領域R2)には、クリアコート層4の表面に凹凸4aが形成される。このため、低艶領域R2の艶の程度が低くなり、光沢度を示すグロス値が10程度となる。一方、マット層7を形成していない高艶領域R1ではグロス層6が露出する。このため、高艶領域R1の艶の程度が高くなり、光沢度を示すグロス値が30程度となる。このように、本実施の形態の自動車用加飾部品1では、木目調の絵柄8において木目の節に対応する部分で艶が低くなるため、実際の木目と同様の立体感が得られる。 In the surface layer portion of the decorative part 1 for automobiles, the unevenness 4a is formed on the surface of the clear coat layer 4 in the portion where the mat layer 7 is formed according to the pattern 8 (low gloss region R2 corresponding to the node of the grain). The For this reason, the gloss level of the low gloss region R2 is low, and the gloss value indicating the glossiness is about 10. On the other hand, the gloss layer 6 is exposed in the high gloss region R1 where the mat layer 7 is not formed. For this reason, the glossiness of the high gloss region R1 becomes high, and the gloss value indicating the glossiness is about 30. Thus, in the automotive decorative component 1 of the present embodiment, the luster is reduced in the portion corresponding to the node of the wood grain in the woodgrain pattern 8, so that the same three-dimensional effect as the actual wood grain is obtained.
 なお、クリアコート層4の表面における微細な凹凸4aは、手で触った触感ではわからない程度の凹凸である。具体的には、クリアコート層4の表面粗さRaは、微細な凹凸4aがある低艶領域R2においても1μm以下となっている。 In addition, the fine unevenness 4a on the surface of the clear coat layer 4 is an unevenness that cannot be recognized by touch feeling with a hand. Specifically, the surface roughness Ra of the clear coat layer 4 is 1 μm or less even in the low gloss region R2 where the fine irregularities 4a are present.
 次に、本実施の形態における自動車用加飾部品1の製造方法について説明する。 Next, the manufacturing method of the automotive decorative part 1 in the present embodiment will be described.
 先ず、樹脂材料(例えばABS樹脂)を用いて所定の立体形状に成形した樹脂成形体3を準備した後、加飾層形成工程を行う。加飾層形成工程では、水圧転写装置を用い、樹脂成形体3の表層部に、加飾層2を構成する柄層5、グロス層6及びマット層7を水圧にて転写する(図3参照)。詳述すると、水圧転写装置には、処理水を溜めておく転写槽が設けられている。水圧転写装置は、転写槽の処理水の水面において、基材上にマット層7、グロス層6及び柄層5を形成してなる転写フィルム(図示略)を浮かべ、その状態で転写フィルムの上方から樹脂成形体3を押し付ける。これにより、樹脂成形体3の表面上に、柄層5、グロス層6及びマット層7を水圧で転写する。この結果、樹脂成形体3の表層部に柄層5が形成されるとともに、後に低艶領域R2の直下となる箇所にマット層7の凹凸7aが形成される。 First, after preparing a resin molding 3 molded into a predetermined three-dimensional shape using a resin material (for example, ABS resin), a decoration layer forming step is performed. In the decorative layer forming step, the pattern layer 5, the gloss layer 6 and the mat layer 7 constituting the decorative layer 2 are transferred to the surface layer portion of the resin molded body 3 by water pressure using a hydraulic transfer device (see FIG. 3). ). More specifically, the water pressure transfer apparatus is provided with a transfer tank for storing treated water. The hydraulic transfer device floats a transfer film (not shown) formed with a mat layer 7, a gloss layer 6 and a handle layer 5 on a substrate on the surface of treated water in a transfer tank, and in that state, above the transfer film. Then, the resin molded body 3 is pressed. Thereby, the pattern layer 5, the gloss layer 6, and the mat layer 7 are transferred onto the surface of the resin molded body 3 by water pressure. As a result, the pattern layer 5 is formed on the surface layer portion of the resin molded body 3, and the unevenness 7 a of the mat layer 7 is formed at a location directly below the low gloss region R <b> 2 later.
 その後、クリアコート層形成工程としてのクリア塗装を行う。具体的には、図4に示されるように、霧化式塗装機11を用いて透明クリア塗料P1を噴霧することにより、加飾層2(柄層5、グロス層6及びマット層7)が形成された樹脂成形体3の表面にクリアコート層4を塗装する。なお、クリア塗装では、沸点が70℃~90℃である低沸点溶剤(本実施の形態では、酢酸エチル)を主溶剤として含んだエステル系のクリア塗料P1が用いられる。より詳しくは、クリア塗料P1として、固形分(艶消し剤や樹脂材料など)を35質量%以上40質量%以下の割合で含む二液型のウレタン塗料が用いられている。またここでは、吐出量が50cc/min、霧化圧が0.08MPaの塗装条件により、霧化式塗装機11の吐出口12と樹脂成形体3の表面との距離(ガン距離)を100mmとした状態で4回の重ね塗りを行う。その後、図示しない乾燥装置内に樹脂成形体3を入れ、80℃程度の温度でクリアコート層4を乾燥させる。この結果、マット層7の凹凸7aに沿った表面形状の低艶領域R2を有するクリアコート層4が形成され、図1及び図2に示されるような自動車用加飾部品1が製造される。 After that, clear coating is performed as a clear coat layer forming process. Specifically, as shown in FIG. 4, the decorative layer 2 (the pattern layer 5, the gloss layer 6, and the mat layer 7) is formed by spraying the transparent clear paint P <b> 1 using the atomization type coating machine 11. The clear coat layer 4 is applied to the surface of the formed resin molded body 3. In the clear coating, an ester-based clear paint P1 containing a low-boiling solvent having a boiling point of 70 ° C. to 90 ° C. (in this embodiment, ethyl acetate) as a main solvent is used. More specifically, as the clear paint P1, a two-component urethane paint containing a solid content (such as a matting agent or a resin material) at a ratio of 35% by mass to 40% by mass is used. In addition, here, the distance (gun distance) between the discharge port 12 of the atomizing type coating machine 11 and the surface of the resin molded body 3 is 100 mm, depending on the coating conditions where the discharge amount is 50 cc / min and the atomization pressure is 0.08 MPa. In this state, four times of overcoating are performed. Thereafter, the resin molded body 3 is placed in a drying device (not shown), and the clear coat layer 4 is dried at a temperature of about 80 ° C. As a result, the clear coat layer 4 having the low gloss region R2 of the surface shape along the unevenness 7a of the mat layer 7 is formed, and the automobile decorative part 1 as shown in FIGS. 1 and 2 is manufactured.
 本発明者は、クリア塗装における最適な条件を決定するために、塗装実験を行った。塗装実験では、艶及び艶消しの発現度合(GM発現度合)に寄与すると推定される因子、具体的には、クリア塗料P1の固形分の割合、クリア塗料P1の主溶剤の沸点、吐出量、霧化圧、ガン距離、塗り重ね回数を実験因子とし、それら因子を変更して塗装実験を行った。ここでは、上述した製造方法(水圧転写等)によって加飾層2を形成した樹脂成形体3を用い、クリア塗装以外は同じ条件とした。 The present inventor conducted a coating experiment in order to determine the optimum conditions for clear coating. In the painting experiment, factors estimated to contribute to the degree of gloss and matte appearance (GM development degree), specifically, the solid content ratio of the clear paint P1, the boiling point of the main solvent of the clear paint P1, the discharge amount, The atomization pressure, gun distance, and the number of coatings were used as experimental factors, and the coating experiment was performed with these factors changed. Here, the resin molding 3 in which the decorative layer 2 was formed by the above-described manufacturing method (hydraulic transfer or the like) was used, and the conditions were the same except for clear coating.
 表1には、各因子A~F、及び塗装実験にて変更した各因子A~Fの水準を示し、表2にはその実験結果を示している。
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
Table 1 shows the levels of the factors A to F and the factors A to F changed in the coating experiment, and Table 2 shows the experimental results.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
 実験結果としては、塗装後においてクリアコート層4の表面(加飾部品1の表面)におけるGM発現度合を感応評価し、その評価結果を5段階の特性値として表2に示している。より詳しくは、図5に示されるように、GM発現度合(特性値1~5)の基準となるサンプル品を予め準備しておき、塗装実験にて得られた加飾部品1(実験No.1~No.16)の表面のGM発現度合とサンプル品のGM発現度合とを比較し、一致するGM発現度合を目視にて判断している。なお、GM発現度合を示す特性値としては、発現性が最も悪い場合を「1」、発現性が最も良い場合を「5」としている。 As an experimental result, the GM expression degree on the surface of the clear coat layer 4 (the surface of the decorative part 1) after the painting was sensitively evaluated, and the evaluation result is shown in Table 2 as five-stage characteristic values. More specifically, as shown in FIG. 5, a sample product serving as a reference for the degree of GM expression (characteristic values 1 to 5) is prepared in advance, and the decorative part 1 (experiment No. 1) obtained in the painting experiment is prepared. 1 to No. 16) are compared with the GM expression level of the surface and the GM expression level of the sample product, and the matching GM expression level is visually determined. The characteristic value indicating the degree of GM expression is “1” when the expression is the worst and “5” when the expression is the best.
 そして、表2に示される実験結果に基づいて分散分析を行った。その分析結果を表3の分散分析表に示している。
Figure JPOXMLDOC01-appb-T000003
Based on the experimental results shown in Table 2, analysis of variance was performed. The analysis results are shown in the ANOVA table of Table 3.
Figure JPOXMLDOC01-appb-T000003
 表3に示されるように、因子Aの固形分、因子Bの主溶剤沸点、因子Dの霧化圧について有意差があり、これら因子がGM発現性に寄与する条件であることがわかった。より詳しくは、因子Aの固形分の割合は、有意水準1%で有意であり、図6に示されるように、固形分の割合が低いクリア塗料P1(固形分が30質量%~40質量%)を用いると、GM発現性が良好となる。また、因子Bの主溶剤沸点は、有意水準1%で有意であり、図7に示されるように、主溶剤沸点が低いクリア塗料P1(主溶剤沸点が70℃~90℃であるエステル系のクリア塗料)を用いると、GM発現性が良好となる。さらに、因子Dの霧化圧は、有意水準5%で有意であり、図8に示されるように、霧化圧を低くすると、GM発現性が良好となる。 As shown in Table 3, there was a significant difference in the solid content of factor A, the boiling point of the main solvent of factor B, and the atomization pressure of factor D, and it was found that these factors contributed to the GM expression. More specifically, the ratio of the solid content of factor A is significant at a significance level of 1%, and as shown in FIG. 6, the clear paint P1 having a low solid content ratio (the solid content is 30% by mass to 40% by mass). ), The GM expression is improved. The boiling point of the main solvent of factor B is significant at a significant level of 1%. As shown in FIG. 7, the clear paint P1 having a low main solvent boiling point (ester-based solvent having a main solvent boiling point of 70 ° C. to 90 ° C.) is used. When a clear paint is used, the GM expression is improved. Furthermore, the atomization pressure of factor D is significant at a significance level of 5%. As shown in FIG. 8, when the atomization pressure is lowered, the GM expression is improved.
 次に、GM発現性に寄与する因子Aの固形分の割合、因子Dの霧化圧について、それらの最適条件を決定するために、水準を細かく変更して塗装実験を行った。表4には、各因子A,D及び塗装実験にて変更した各因子A,Dの水準を示し、表5にはその実験結果を示している。なお、他の因子B,C,E,Fについては固定条件とした。具体的には、因子Bの主溶剤沸点は70℃~90℃、因子Cの吐出量は50cc/min、因子Eのガン距離は100mm、因子Fの塗り重ね回数は4回、といった条件を固定し、各因子A,Dの水準を変更して塗装実験を行った。
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000005
Next, in order to determine the optimum conditions for the ratio of the solid content of factor A contributing to the GM expression and the atomization pressure of factor D, coating experiments were performed with finely changing levels. Table 4 shows the factors A and D and the levels of the factors A and D changed in the coating experiment, and Table 5 shows the experimental results. The other factors B, C, E, and F were fixed conditions. Specifically, the conditions such that the boiling point of the main solvent of factor B is 70 ° C to 90 ° C, the discharge amount of factor C is 50 cc / min, the gun distance of factor E is 100 mm, and the number of coating times of factor F is four times are fixed. Then, the painting experiment was performed by changing the levels of the factors A and D.
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000005
 そして、表5に示される実験結果に基づいて分散分析を行い、その分析結果を表6の分散分析表に示している。
Figure JPOXMLDOC01-appb-T000006
Then, analysis of variance is performed based on the experimental results shown in Table 5, and the analysis results are shown in the analysis of variance table of Table 6.
Figure JPOXMLDOC01-appb-T000006
 表6に示されるように、因子Aの固形分の割合は、有意水準5%で有意であり、図9に示されるように、固形分の割合が35質量%~40質量%である場合に、GM発現性が最も良くなった。また、因子Dの霧化圧は、有意水準1%で有意であり、図10に示されるように、霧化圧が0.08MPaである場合に、GM発現性が最も良くなった。 As shown in Table 6, the ratio of the solid content of factor A is significant at the significance level of 5%, and when the ratio of the solid content is 35% by mass to 40% by mass as shown in FIG. GM expression was the best. In addition, the atomization pressure of factor D was significant at a significance level of 1%, and as shown in FIG. 10, when the atomization pressure was 0.08 MPa, GM expression was the best.
 従って、本実施の形態では、固形分を35質量%~40質量%の割合で含みかつ主溶剤沸点が70℃~90℃であるエステル系のクリア塗料P1を用い、吐出量が50cc/min、霧化圧が0.08MPa、ガン距離が100mm、重ね塗り回数が4回といった条件でクリア塗装を行った。この結果、艶及び艶消しの発現性のある自動車用加飾部品1が製造される。 Therefore, in the present embodiment, an ester-based clear paint P1 having a solid content of 35 mass% to 40 mass% and a main solvent boiling point of 70 ° C. to 90 ° C. is used, and the discharge amount is 50 cc / min. Clear coating was performed under the conditions that the atomization pressure was 0.08 MPa, the gun distance was 100 mm, and the number of overcoating was four. As a result, the decorative part 1 for an automobile having gloss and matting is produced.
 上記のように製造した本実施の形態の自動車用加飾部品1において、その断面を走査型電子顕微鏡(SEM)を用いて確認した。図11には、自動車用加飾部品1の断面のSEM写真を示している。図11に示されるように、クリアコート層4における高艶領域R1では、その直下にマット層7が存在しないため、滑らかな表面となっている。これに対して、クリアコート層4における低艶領域R2では、その直下にマット層7が存在するため、表面に微細な凹凸4aが形成されている。 In the automobile decorative part 1 of the present embodiment manufactured as described above, the cross section was confirmed using a scanning electron microscope (SEM). In FIG. 11, the SEM photograph of the cross section of the decorative component 1 for motor vehicles is shown. As shown in FIG. 11, the high gloss region R1 in the clear coat layer 4 has a smooth surface because the mat layer 7 does not exist immediately below. On the other hand, in the low gloss region R2 in the clear coat layer 4, since the mat layer 7 exists immediately below, the fine unevenness 4a is formed on the surface.
 従って、本実施の形態によれば以下の効果を得ることができる。 Therefore, according to the present embodiment, the following effects can be obtained.
 (1)本実施の形態のクリア塗装では、沸点が100℃未満である低沸点溶剤としてのエステル系溶剤を主溶剤として含み、固形分が35質量%以上40質量%以下であるクリア塗料P1が用いられる。このクリア塗料P1は、従来一般的に用いられている炭化水素系のクリア塗料(沸点が110℃~140℃、固形分が50質量%~60質量%)と比較すると、主溶剤の沸点が低く塗料中に含まれる固形分が少なくなっている。このクリア塗料P1を霧化式塗装機11により部品表面に噴霧すると、表面が平滑化する前にエステル系の主溶剤が揮発するため、加飾層2におけるマット層7の表面形状に沿ったクリアコート層4が形成される。この結果、クリアコート層4の表面において、直下にマット層7の凹凸7aがある領域は、微細な凹凸4aのある表面形状となり、相対的に艶の程度が低い低艶領域R2となる。一方、クリアコート層4の表面において、直下にマット層7の凹凸7aがない領域は、平坦な表面形状となり、相対的に艶の程度が高い高艶領域R1となる。このように、本実施の形態では、クリアコート層4の表面において低艶領域R2の艶を部分的に落すことができるため、加飾層2(柄層5の絵柄8)に応じた視覚的な立体表現が可能となり、自動車用加飾部品1の意匠性を十分に高めることができる。なお、本実施の形態では、最適条件として固形分が35質量%以上40質量%以下であるクリア塗料P1を用いた。この最適条件に対して条件の範囲を広くした場合、具体的には固形分が10質量%以上55質量%以下であるクリア塗料を用いた場合でも、従来の自動車用加飾部品100と比較すると、艶及び艶消しの発現性のある自動車用加飾部品1を製造することができた。 (1) In the clear coating of the present embodiment, a clear paint P1 containing an ester solvent as a low-boiling solvent having a boiling point of less than 100 ° C. as a main solvent and having a solid content of 35% by mass to 40% by mass. Used. This clear paint P1 has a lower boiling point of the main solvent compared to the conventionally used hydrocarbon-based clear paint (boiling point 110 ° C. to 140 ° C., solid content 50 mass% to 60 mass%). There is less solid content in the paint. When this clear paint P1 is sprayed onto the surface of the component by the atomizing coater 11, the main solvent of the ester is volatilized before the surface is smoothed. Therefore, the clear paint along the surface shape of the mat layer 7 in the decorative layer 2 is cleared. Coat layer 4 is formed. As a result, on the surface of the clear coat layer 4, the region having the unevenness 7 a of the mat layer 7 immediately below becomes a surface shape having fine unevenness 4 a and becomes a low gloss region R <b> 2 having a relatively low gloss. On the other hand, on the surface of the clear coat layer 4, a region where the unevenness 7 a of the mat layer 7 is not directly below becomes a flat surface shape and becomes a high gloss region R 1 having a relatively high gloss level. As described above, in the present embodiment, the gloss of the low gloss region R2 can be partially removed on the surface of the clear coat layer 4, so that the visual according to the decorative layer 2 (the pattern 8 of the pattern layer 5) is visually reduced. 3D expression is possible, and the design of the decorative part 1 for automobiles can be sufficiently enhanced. In the present embodiment, the clear paint P1 having a solid content of 35% by mass or more and 40% by mass or less is used as the optimum condition. When the range of conditions is widened with respect to this optimum condition, specifically, even when a clear paint having a solid content of 10% by mass or more and 55% by mass or less is used, compared with the conventional decorative part 100 for automobiles. Thus, it was possible to produce a decorative part 1 for an automobile having gloss and mattness.
 (2)本実施の形態のクリア塗装において、霧化式塗装機11の霧化圧が0.06MPa以上0.09MPa以下である塗装条件にてクリア塗料P1を噴霧すると、霧化式塗装機11から噴霧される塗料ミストの粒径が大きくなり、マット層7の凹凸7aに塗料P1がなじみ易くなる。この結果、加飾層2を構成するマット層7の表面における凹凸形状に沿ったクリアコート層4をより確実に形成することができる。 (2) In the clear coating of the present embodiment, when the clear paint P1 is sprayed under the coating conditions in which the atomization pressure of the atomization type coating machine 11 is 0.06 MPa or more and 0.09 MPa or less, the atomization type coating machine 11 The particle size of the paint mist sprayed from the inside becomes large, and the paint P1 becomes easy to become familiar with the unevenness 7a of the mat layer 7. As a result, the clear coat layer 4 along the uneven shape on the surface of the mat layer 7 constituting the decorative layer 2 can be more reliably formed.
 (3)本実施の形態の加飾層形成工程では、樹脂成形体3の表層部に、転写フィルムを水圧転写することにより、加飾層2(柄層5、グロス層6及びマット層7)を形成した後、クリア塗装によってクリアコート層4を形成している。このようにすると、樹脂成形体3の表層部において、柄層5の木目調の絵柄8に対応した位置にマット層7の凹凸7aを有する加飾層2を確実に形成することができる。またこの場合、クリアコート層4において、柄層5の絵柄8に応じて形成されたマット層7の凹凸7aの直上となる領域が低艶領域R2となり、艶を確実に消すことができる。一方、クリアコート層4において、マット層7を形成していない領域はグロス層6が露出するため、高艶領域R1となり艶の程度を高めることができる。このようにすると、柄層5の絵柄8(木目)に応じた立体感を確実に得ることができ、自動車用加飾部品1の意匠性を高めることができる。 (3) In the decorative layer forming step of the present embodiment, the decorative layer 2 (pattern layer 5, gloss layer 6 and mat layer 7) is obtained by hydraulically transferring the transfer film to the surface layer portion of the resin molded body 3. After forming, the clear coat layer 4 is formed by clear coating. If it does in this way, the decoration layer 2 which has the unevenness | corrugation 7a of the mat | matte layer 7 in the position corresponding to the grain-like pattern 8 of the pattern layer 5 can be reliably formed in the surface layer part of the resin molding 3. FIG. Further, in this case, in the clear coat layer 4, the region immediately above the irregularities 7 a of the mat layer 7 formed according to the pattern 8 of the pattern layer 5 becomes the low gloss region R 2, and the gloss can be surely erased. On the other hand, in the clear coat layer 4, the gloss layer 6 is exposed in the area where the mat layer 7 is not formed, so that it becomes a high gloss area R <b> 1 and the gloss level can be increased. If it does in this way, the three-dimensional effect according to the pattern 8 (wood grain) of the pattern layer 5 can be obtained reliably, and the design property of the decorative part 1 for motor vehicles can be improved.
 (4)本実施の形態の自動車用加飾部品1では、クリアコート層4の表面における高艶領域R1と低艶領域R2とにおける光沢度の差が3倍であるため、視覚的な立体表現が可能となり、その意匠性を十分に高めることができる。また、クリアコート層4の表面粗さRaが1μm以下であるため、部品表面の摩耗による立体感の変化が少なく、長期間使用しても自動車用加飾部品1の意匠性を良好な状態に維持することができる。 (4) In the automobile decorative component 1 of the present embodiment, the difference in glossiness between the high gloss region R1 and the low gloss region R2 on the surface of the clear coat layer 4 is three times, so that the visual three-dimensional expression Can be achieved, and the design can be sufficiently enhanced. Moreover, since the surface roughness Ra of the clear coat layer 4 is 1 μm or less, there is little change in the three-dimensional effect due to wear on the surface of the component, and the design of the decorative component 1 for automobiles is kept in a good state even after long-term use. Can be maintained.
 なお、本発明の実施の形態は以下のように変更してもよい。 The embodiment of the present invention may be modified as follows.
 ・上記実施の形態では、加飾層形成工程において、樹脂成形体3の表層部に、柄層5上にマット層7の凹凸7aを有する転写フィルムを水圧転写することにより、加飾層2を形成するものであったが、これに限定されるものではない。例えば、シボ加工によって樹脂成形体3の表層部に凹凸を形成してもよいし、レーザ加工によって樹脂成形体3の表層部に凹凸を形成してもよい。なおこの場合、樹脂成形体3において凹凸が形成される表層部が加飾層となる。また、樹脂成形体3の表層部に塗装を行うことで加飾層としての塗膜層を形成した後、その塗膜層にレーザ加工による凹凸を形成してもよい。さらに、サンドブラストやショットブラスト等によって、樹脂成形体3の表層部(塗膜層)に凹凸を形成してもよい。 In the above embodiment, in the decorative layer forming step, the decorative layer 2 is formed by hydraulically transferring a transfer film having the unevenness 7a of the mat layer 7 on the handle layer 5 to the surface layer portion of the resin molded body 3. Although formed, it is not limited to this. For example, unevenness may be formed on the surface layer portion of the resin molded body 3 by embossing, or unevenness may be formed on the surface layer portion of the resin molded body 3 by laser processing. In this case, the surface layer portion where unevenness is formed in the resin molded body 3 is a decorative layer. Moreover, after forming the coating-film layer as a decoration layer by coating on the surface layer part of the resin molding 3, you may form the unevenness | corrugation by laser processing in the coating-film layer. Furthermore, you may form an unevenness | corrugation in the surface layer part (coating layer) of the resin molding 3 by sandblasting, shot blasting, etc.
 ・上記実施形態では、クリア塗料として、二液型のウレタン塗料を用いたが、一液型のウレタン塗料を用いてもよい。勿論、ウレタン塗料以外にアクリル塗料などの他のクリア塗料を用いてもよい。 In the above embodiment, a two-component urethane paint is used as the clear paint, but a one-component urethane paint may be used. Of course, other clear paint such as acrylic paint may be used in addition to urethane paint.
 ・上記実施形態は、自動車用加飾部品1をドアのアームレストに具体化するものであったが、これ以外に、コンソールボックス、インストルメントパネルなどの加飾部品に具体化してもよい。勿論、自動車用加飾部品以外に、家具や家電などの化粧パネルなどの加飾部品に本発明を具体化してもよい。 In the above embodiment, the decorative part 1 for an automobile is embodied as an armrest of a door, but other than this, it may be embodied as a decorative part such as a console box or an instrument panel. Of course, you may embody this invention in decorative parts, such as decorative panels, such as furniture and a household appliance, besides the decorative parts for motor vehicles.
 次に、特許請求の範囲に記載された技術的思想のほかに、前述した実施の形態によって把握される技術的思想を以下に列挙する。 Next, in addition to the technical ideas described in the claims, the technical ideas grasped by the embodiment described above are listed below.
 (1)手段1において、前記クリアコート層形成工程では、前記霧化式塗装機の吐出量が50cc/min以上65cc/min以下である塗装条件にて前記クリア塗料を噴霧することを特徴とする加飾部品の製造方法。 (1) In the first means, in the clear coat layer forming step, the clear paint is sprayed under a coating condition in which a discharge amount of the atomizing coater is 50 cc / min or more and 65 cc / min or less. Manufacturing method of decorative parts.
 (2)手段1において、前記加飾層形成工程では、絵柄を付与するための柄層と、艶を付与するためのグロス層と、前記凹凸を有するマット層とが積層されてなる転写フィルムを水圧転写することにより、前記加飾層となる前記柄層、前記グロス層及び前記マット層を形成することを特徴とする加飾部品の製造方法。 (2) In means 1, in the decorative layer forming step, a transfer film is formed by laminating a pattern layer for imparting a pattern, a gloss layer for imparting gloss, and a mat layer having the irregularities. A method for producing a decorative part, wherein the pattern layer, the gloss layer, and the mat layer to be the decorative layer are formed by hydraulic transfer.
 (3)技術的思想(2)において、前記マット層は、表面粗さRaが2μm以下であることを特徴とする加飾部品の製造方法。 (3) In the technical idea (2), the mat layer has a surface roughness Ra of 2 μm or less.
 (4)技術的思想(2)において、前記マット層は、その下層側に形成される前記柄層に含まれる顔料と同一の顔料を含んで構成されることを特徴とする加飾部品の製造方法。 (4) In the technical idea (2), the mat layer is configured to include the same pigment as the pigment included in the handle layer formed on the lower layer side thereof. Method.
 (5)技術的思想(2)において、前記絵柄は木目調の柄であり、木目の節に対応する部分に前記マット層が形成されることを特徴とする加飾部品の製造方法。 (5) In the technical idea (2), the pattern is a woodgrain pattern, and the mat layer is formed in a portion corresponding to a node of the wood grain.
 (6)技術的思想(2)において、前記グロス層は、アクリルポリオール樹脂かならなる透明な樹脂層であり、前記絵柄を付与する前記柄層の表面全体に均一の厚さで形成されることを特徴とする加飾部品の製造方法。 (6) In the technical idea (2), the gloss layer is a transparent resin layer made of an acrylic polyol resin, and is formed with a uniform thickness on the entire surface of the pattern layer to which the pattern is applied. A method for producing a decorative part characterized by the above.
 (7)手段1において、前記高艶領域の光沢度を示すグロス値が30以上であり、前記低艶領域の前記グロス値が10以下であることを特徴とする加飾部品の製造方法。 (7) A method for manufacturing a decorative part in the means 1, wherein the gloss value indicating the glossiness of the high gloss region is 30 or more and the gloss value of the low gloss region is 10 or less.
 (8)手段1において、前記加飾層形成工程では、シボ加工によって前記部品の表層部に凹凸を形成することを特徴とする加飾部品の製造方法。 (8) The method of manufacturing a decorative part according to means 1, wherein, in the decorative layer forming step, irregularities are formed on a surface layer portion of the part by embossing.
 (9)手段1において、前記加飾層形成工程では、レーザ加工によって前記部品の表層部に凹凸を形成することを特徴とする加飾部品の製造方法。 (9) The method for manufacturing a decorative part according to means 1, wherein in the decorative layer forming step, irregularities are formed on a surface layer portion of the part by laser processing.
 (10)手段1において、前記加飾部品は、自動車用加飾部品であることを特徴とする加飾部品の製造方法。 (10) The method of manufacturing a decorative part according to means 1, wherein the decorative part is a decorative part for an automobile.
1…加飾部品としての自動車用加飾部品
2…加飾層
3…部品としての樹脂成形体
4…クリアコート層
5…柄層
7a…凹凸
11…霧化式塗装機
P1…クリア塗料
R1…高艶領域
R2…低艶領域
DESCRIPTION OF SYMBOLS 1 ... Decorative part for automobiles as a decorative part 2 ... Decorative layer 3 ... Resin molded body 4 as part ... Clear coat layer 5 ... Pattern layer 7a ... Concavity and convexity 11 ... Atomization type coating machine P1 ... Clear paint R1 ... High gloss area R2 ... Low gloss area

Claims (21)

  1.  表層部に加飾層を有する部品と、前記加飾層の表面を保護するクリアコート層とを備え、前記クリアコート層の表面上に、相対的に艶の程度が高い高艶領域と、相対的に艶の程度の低い低艶領域とが混在する加飾部品の製造方法であって、
     前記部品の表層部に前記加飾層を形成するとともに、前記加飾層の表面において後に前記低艶領域の直下となる箇所に凹凸を形成しておく加飾層形成工程と、
     沸点が100℃未満である低沸点溶剤を主溶剤として含み、固形分が10質量%以上55質量%以下であるクリア塗料を用い、霧化式塗装機により前記クリア塗料を前記加飾層の表面に噴霧することで、前記凹凸に沿った表面形状の前記低艶領域を有する前記クリアコート層を形成するクリアコート層形成工程と
    を含むことを特徴とする加飾部品の製造方法。
    A component having a decorative layer on the surface layer portion, and a clear coat layer that protects the surface of the decorative layer, on the surface of the clear coat layer, a high gloss region having a relatively high gloss level, and a relative A method for manufacturing a decorative part in which a low gloss region with a low gloss level is mixed,
    The decorative layer forming step of forming the decorative layer on the surface layer of the component, and forming irregularities in a location directly below the low gloss area later on the surface of the decorative layer;
    Using a clear paint having a low boiling point solvent having a boiling point of less than 100 ° C. as a main solvent and having a solid content of 10% by mass to 55% by mass, the clear paint is applied to the surface of the decorative layer by an atomizing coating machine And a clear coat layer forming step of forming the clear coat layer having the low gloss region of the surface shape along the irregularities by spraying on the surface.
  2.  前記クリア塗料は、固形分が35質量%以上40質量%以下であることを特徴とする請求項1に記載の加飾部品の製造方法。 The method for producing a decorative part according to claim 1, wherein the clear paint has a solid content of 35% by mass or more and 40% by mass or less.
  3.  前記クリアコート層形成工程では、前記霧化式塗装機の霧化圧が0.06MPa以上0.09MPa以下である塗装条件にて前記クリア塗料を噴霧することを特徴とする請求項1または2に記載の加飾部品の製造方法。 3. The clear coating layer forming step, wherein the clear paint is sprayed under a coating condition in which an atomizing pressure of the atomizing coating machine is 0.06 MPa or more and 0.09 MPa or less. The manufacturing method of the decorative component of description.
  4.  前記クリアコート層形成工程では、前記霧化式塗装機の吐出量が50cc/min以上である塗装条件にて前記クリア塗料を噴霧することを特徴とする請求項1乃至3のいずれか1項に記載の加飾部品の製造方法。 4. The clear coating layer forming step, wherein the clear paint is sprayed under a coating condition in which a discharge amount of the atomizing coating machine is 50 cc / min or more. The manufacturing method of the decorative component of description.
  5.  前記クリアコート層形成工程では、前記霧化式塗装機の吐出量が50cc/min以上65cc/min以下である塗装条件にて前記クリア塗料を噴霧することを特徴とする請求項1乃至4のいずれか1項に記載の加飾部品の製造方法。 5. The clear coating layer forming step, wherein the clear paint is sprayed under a coating condition in which a discharge amount of the atomizing coating machine is 50 cc / min or more and 65 cc / min or less. The manufacturing method of the decorative component of Claim 1.
  6.  前記加飾層形成工程では、柄層上に前記凹凸を有する転写フィルムを水圧転写することにより前記加飾層を形成することを特徴とする請求項1乃至5のいずれか1項に記載の加飾部品の製造方法。 The said decoration layer formation process forms the said decoration layer by carrying out the hydraulic transfer of the transfer film which has the said unevenness | corrugation on a pattern layer, The addition of any one of Claim 1 thru | or 5 characterized by the above-mentioned. A method for manufacturing decorative parts.
  7.  前記加飾層形成工程では、絵柄を付与するための柄層と、艶を付与するためのグロス層と、前記凹凸を有するマット層とが積層されてなる転写フィルムを水圧転写することにより、前記加飾層となる前記柄層、前記グロス層及び前記マット層を形成することを特徴とする請求項1乃至6のいずれか1項に記載の加飾部品の製造方法。 In the decorative layer forming step, the transfer film formed by laminating a pattern layer for imparting a pattern, a gloss layer for imparting gloss, and a mat layer having the unevenness is hydraulically transferred, The method for manufacturing a decorative part according to any one of claims 1 to 6, wherein the pattern layer, the gloss layer, and the mat layer that are to be decorated layers are formed.
  8.  前記マット層は、表面粗さRaが2μm以下であることを特徴とする請求項7に記載の加飾部品の製造方法。 The method for manufacturing a decorative part according to claim 7, wherein the mat layer has a surface roughness Ra of 2 µm or less.
  9.  前記マット層は、その下層側に形成される前記柄層に含まれる顔料と同一の顔料を含んで構成されることを特徴とする請求項7または8に記載の加飾部品の製造方法。 The method for manufacturing a decorative part according to claim 7 or 8, wherein the mat layer is configured to include the same pigment as the pigment included in the handle layer formed on the lower layer side.
  10.  前記絵柄は木目調の柄であり、木目の節に対応する部分に前記マット層が形成されることを特徴とする請求項7乃至9のいずれか1項に記載の加飾部品の製造方法。 The method of manufacturing a decorative part according to any one of claims 7 to 9, wherein the pattern is a grain-like pattern, and the mat layer is formed at a portion corresponding to a node of the grain.
  11.  前記グロス層は、アクリルポリオール樹脂かならなる透明な樹脂層であり、前記絵柄を付与する前記柄層の表面全体に均一の厚さで形成されることを特徴とする請求項7乃至10のいずれか1項に記載の加飾部品の製造方法。 The gloss layer is a transparent resin layer made of acrylic polyol resin, and is formed with a uniform thickness over the entire surface of the pattern layer to which the pattern is applied. The manufacturing method of the decorative component of Claim 1.
  12.  前記高艶領域の光沢度を示すグロス値が30以上であり、前記低艶領域の前記グロス値が10以下であることを特徴とする請求項1乃至11のいずれか1項に記載の加飾部品の製造方法。 12. The decoration according to claim 1, wherein the gloss value indicating the glossiness of the high gloss region is 30 or more, and the gloss value of the low gloss region is 10 or less. Manufacturing method of parts.
  13.  前記加飾層形成工程では、シボ加工によって前記部品の表層部に前記凹凸を形成することを特徴とする請求項1乃至5のいずれか1項に記載の加飾部品の製造方法。 The method for manufacturing a decorative part according to any one of claims 1 to 5, wherein, in the decorative layer forming step, the unevenness is formed on a surface layer portion of the part by a texture process.
  14.  前記加飾層形成工程では、レーザ加工によって前記部品の表層部に前記凹凸を形成することを特徴とする請求項1乃至5のいずれか1項に記載の加飾部品の製造方法。 The method for manufacturing a decorative part according to any one of claims 1 to 5, wherein, in the decorative layer forming step, the irregularities are formed on a surface layer portion of the part by laser processing.
  15.  表層部に加飾層を有する部品と、前記加飾層の表面を保護するクリアコート層とを備え、前記クリアコート層の表面上に、相対的に艶の程度が高い高艶領域と、相対的に艶の程度の低い低艶領域とが混在する加飾部品であって、
     前記加飾層の表面において前記低艶領域の直下となる箇所に凹凸が形成されるとともに、前記クリアコート層の前記低艶領域は前記凹凸に沿った表面形状を有し、前記クリアコート層は表面粗さRaが1μm以下であり、前記高艶領域と前記低艶領域とにおける光沢度の差が2倍以上であることを特徴とする加飾部品。
    A component having a decorative layer on the surface layer portion, and a clear coat layer that protects the surface of the decorative layer, on the surface of the clear coat layer, a high gloss region having a relatively high gloss level, and a relative It is a decorative part that is mixed with a low gloss area with a low gloss level.
    Concavities and convexities are formed at locations immediately below the low-gloss area on the surface of the decorative layer, the low-gloss area of the clear coat layer has a surface shape along the irregularities, and the clear coat layer is A decorative part having a surface roughness Ra of 1 μm or less and a difference in glossiness between the high gloss region and the low gloss region is twice or more.
  16.  前記加飾層は、絵柄を付与するための柄層と、艶を付与するためのグロス層と、前記凹凸を有するマット層とからなることを特徴とする請求項15に記載の加飾部品。 The decorative part according to claim 15, wherein the decorative layer includes a pattern layer for imparting a pattern, a gloss layer for imparting gloss, and a mat layer having the unevenness.
  17.  前記マット層は、表面粗さRaが2μm以下であることを特徴とする請求項16に記載の加飾部品。 The decorative part according to claim 16, wherein the mat layer has a surface roughness Ra of 2 µm or less.
  18.  前記マット層は、その下層側に形成される前記柄層に含まれる顔料と同一の顔料を含んで構成されることを特徴とする請求項16または17に記載の加飾部品。 The decorative part according to claim 16 or 17, wherein the mat layer is configured to include the same pigment as the pigment included in the handle layer formed on a lower layer side thereof.
  19.  前記絵柄は木目調の柄であり、木目の節に対応する部分に前記マット層が形成されることを特徴とする請求項16乃至18のいずれか1項に記載の加飾部品。 The decorative part according to any one of claims 16 to 18, wherein the pattern is a woodgrain pattern, and the mat layer is formed at a portion corresponding to a node of the wood grain.
  20.  前記グロス層は、アクリルポリオール樹脂からなる透明な樹脂層であり、前記絵柄を付与する前記柄層の表面全体に均一の厚さで形成されることを特徴とする請求項16乃至19のいずれか1項に記載の加飾部品。 The gloss layer is a transparent resin layer made of an acrylic polyol resin, and is formed with a uniform thickness over the entire surface of the pattern layer to which the pattern is applied. The decorative part according to item 1.
  21.  前記高艶領域の光沢度を示すグロス値が30以上であり、前記低艶領域の前記グロス値が10以下であることを特徴とする請求項16乃至20のいずれか1項に記載の加飾部品。 21. The decoration according to claim 16, wherein the gloss value indicating the glossiness of the high gloss region is 30 or more, and the gloss value of the low gloss region is 10 or less. parts.
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