WO2015153188A1 - Conception de grille à air améliorée pour un réacteur d'oxydation ou d'ammoxydation - Google Patents

Conception de grille à air améliorée pour un réacteur d'oxydation ou d'ammoxydation Download PDF

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Publication number
WO2015153188A1
WO2015153188A1 PCT/US2015/022190 US2015022190W WO2015153188A1 WO 2015153188 A1 WO2015153188 A1 WO 2015153188A1 US 2015022190 W US2015022190 W US 2015022190W WO 2015153188 A1 WO2015153188 A1 WO 2015153188A1
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WO
WIPO (PCT)
Prior art keywords
feed
reactor
metal plate
continuous metal
air
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Application number
PCT/US2015/022190
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English (en)
Inventor
Timothy Robert Mcdonel
Jay Robert COUCH
David Rudolph Wagner
Paul Trigg Wachtendorf
Thomas George TRAVERS
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Ineos Europe Ag
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Filing date
Publication date
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Publication of WO2015153188A1 publication Critical patent/WO2015153188A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B01J8/1827—Feeding of the fluidising gas the fluidising gas being a reactant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/44—Fluidisation grids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons

Definitions

  • ammoxidation This process, which is commonly referred to as ammoxidation, is carried out in the gas phase at elevated temperature in the presence of a suitable fluid bed ammoxidation catalyst.
  • Fig. 1 illustrates a typical ammoxidation reactor used to carry out this process.
  • reactor 10 comprises reactor wall 12, air grid 14, feed sparger 16, cooling coils 18 and cyclones 20.
  • process air is charged into reactor 10 through air inlet 22, while a mixture of propylene and ammonia is charged into reactor 10 through feed sparger 16.
  • the flow rates of both are high enough to fluidize a bed 24 of ammoxidation catalyst in the reactor interior, where the catalytic ammoxidation of the propylene and ammonia to acrylonitrile occurs.
  • reaction gases produced by the reaction exit reactor 10 through reactor effluent outlet 26. Before doing so, they pass through cyclones 20, which remove any ammoxidation catalyst these gases may have entrained for return to catalyst bed 24 by diplegs 25. Ammoxidation is highly exothermic, and so cooling coils 18 are used to withdraw excess heat and thereby keep the reaction temperature at an appropriate level.
  • Propylene and ammonia can form explosive mixtures with oxygen.
  • explosions are prevented inside reactor 10 by the fluidized ammonization catalyst, which preferentially catalyzes the ammoxidation reaction before an explosion can occur.
  • reactor 10 is designed and operated so that the only place process air is allowed to contact propylene and ammonia during normal operation is within the fluidized bed of ammoxidation catalyst 24, and then only when the temperature of the catalyst is high enough to catalyze the ammoxidation reaction.
  • feed sparger 16 takes the form of a series of supply pipes or conduits including main header 30 and laterals 32 attached to and branching out from header 30.
  • a system of downwardly facing feed nozzles 34 is defined in header 30 and laterals 34 through which a mixture of propylene and ammonia is charged during normal reactor operation.
  • the number and spacing laterals 32 and feed nozzles 34 is such that, in the aggregate, about 10 to 30 feed nozzles per square meter are located approximately uniformly across the entire cross-sectional area of reactor 10.
  • each feed nozzle 34 is surrounded by a feed shroud 36, which takes the form a short section of conduit having an inside diameter several times larger than the diameter of nozzle 34.
  • Feed shrouds 34 enable the velocity of gas passing out of nozzles 10 to slow considerably before exiting into catalyst bed 24, which prevents disintegration of the catalyst which might otherwise occur.
  • Process air typically enters catalyst bed 24 (Fig. 1) after passing through air grid 14, which is located below feed sparger 16.
  • air grid 14 typically takes the form of a continuous metal sheet which defines a series of air holes or nozzles therein. The diameter of the air nozzles, the mass flow rate of process air passing through air grid 14 and the mass flow rate of the propylene/ammonia mixture passing through feed sparger 16 are selected so that the ammoxidation catalyst in catalyst bed 24 is fully fluidized by these gases during normal operation.
  • Air holes 76 are typically provided with their own protective air shrouds (not shown), which are normally located below air grid 14.
  • feed nozzles 34 are provided in a one-to-one relationship with the air nozzles in air grid 14, with each feed shroud 36 being aimed directly at its corresponding air nozzle to promote rapid and thorough mixing of the gases passing out of these two different nozzles.
  • air nozzles are referred to as uncapped. See, U.S. 4,801,731.
  • the air nozzles can have caps installed directly above them to preferentially disperse the air horizontally (in a directional or uniform manner) along the grid rather than vertically directly towards the feed shroud.
  • caps can be small metal covers welded above such air nozzles.
  • the design of the legs attaching the cap to the grid can be selected to optimized horizontal gas distribution pattern.
  • These caps above the air holes can also be designed to prevent catalyst under de fluidized conditions from (i) falling through the air holes and/or (ii) settling on the cap itself (such as by having a sloping surface or being fabricated from angle iron) .
  • propylene/ammonia feed systems of this general type work well, they can suffer certain disadvantages. For example, mixing of the propylene/ammonia feed mixture passing out of feed sparger 16 with the air passing out of air grid 14 can be inadequate. This can compromise reactor performance, leading to a less than desirable conversion of reactants to products.
  • molybdenum scale given off by the ammoxidation catalyst can cause small piles of this molybdenum scale plus additional amounts of entrained catalyst to accumulate on the upper surface of air grid 14 in the form of small catalyst piles.
  • These piles act like mini- stationary or "fixed" catalyst beds in which the ammoxidation reaction continues to occur. Because heat transfer inside a fixed catalyst bed is much poorer than in a fluidized bed, these catalyst piles produce localized hot spots having temperatures which are high enough to damage any fluidized catalyst that happens to come near. For example, these temperatures are high enough to calcine the surface of any fluidized catalyst coming near, which in turn reduces surface area and hence catalyst activity. And, because the individual catalyst particles forming a bed of fluidized catalyst are free to circulate throughout its entire volume, over time, these hot spots can damage the entire charge of fluidized bed catalyst in the reactor.
  • Additional disadvantages include mechanical problems with the structure of the acrylonitrile reactor.
  • a typical commercial acrylonitrile reactor operates at a relatively constant temperature of approximately 400 to 550° C, although fluctuations do occur.
  • an ammoxidation reactor must be shut down periodically for normal maintenance, catalyst change out, etc., as well as for unexpected upsets such as a power failure, for example.
  • the change in temperature inside the reactor can be as much as 500° C or more as the reactor transitions between ambient and normal operating temperatures.
  • This cycling between low and high temperatures can exert a considerable stress on the structural members forming the reactor, especially where they are connected to one another, because of the inherent expansion and contraction of these structural members undergo in response to temperature changes. Over time, these stresses can lead to mechanical failure, especially at junctions formed by welding.
  • air grid 14 which takes the form of an essentially flat metal plate 40 with a series of holes therein, is attached to side wall 12 of the reactor by knuckle 44.
  • knuckle 44 in cross section takes the form of a concave section of metal with its upper end 46 being essentially flush with and welded to side wall 36 by weld 48 and its lower end 50 being essentially coplanar with and welded to the facing edge of air grid plate 40 by weld 52.
  • air grid plate 40 can horizontally expand and contract by as much as 1 ⁇ 2 inch (1.27 cm) in response to the temperature changes experienced during reactor start up and shut down. This puts large stresses on knuckle 44, and especially on welds 48 and 52 used to attach knuckle 44 to air grid plate 40 and reactor side wall 36. Unfortunately over time, these stresses can lead to mechanical failure, which in turn requires extensive downtime for repair and/or replacement.
  • Still another disadvantage associated with the above conventional design relates to air grid flexing. Because air grid 16 must support the entire weight of the catalyst charge inside reactor 10 when it is shut down, air grid plate 40 needs to be supported from below to accommodate this weight. Normally, this is done by means of a system of I-beams on which air grid plate 40 sits. In some reactor design, air grid plate 40 simply rests on these I-beams. Unfortunately, in these designs, air grid plate 40 has a tendency to flutter during normal operation, which is due not only to the force of the air moving upwardly through this air grid plate but also due to its inherent expansion when its temperature is raised to normal operating temperatures. In other designs, air grid plate 40 is welded to the tops of these I-beams. Unfortunately, in these designs the force of the upwardly moving air plus the inherent expansion of the air grid plate can cause mechanical failure of these welds.
  • an improved feed system for a commercial oxidation or ammoxidation reactor such as an acrylonitrile reactor, includes a feed sparger for supplying a mixture of unsaturated and/or saturated C3 to C4 hydrocarbons and ammonia to the inside of the reactor and an air grid system for supplying air to the inside of the reactor, the feed sparger comprising a main header conduit and lateral conduits fluidly attached to and branching out from the main header conduit, both the main header conduit and the lateral conduits defining downwardly facing feed nozzles, the feed sparger system further comprising feed shrouds associated with respective feed nozzles, each feed shroud comprising a proximal end connected to a respective lateral conduit or header conduit and being arranged to direct C3 to C4 hydrocarbons and ammonia passing out of its respective feed nozzle downwardly into the interior of the reactor, the air grid system comprising a continuous metal plate arranged below the feed sparger system, the continuous metal plate defining a series of
  • a process for supplying an oxidation or ammoxiodation reactor that includes supplying a mixture of saturated and/or unsaturated C3 to C4 hydrocarbons and ammonia to the inside of the reactor through a feed sparger.
  • the feed sparger includes a main header conduit and lateral conduits fluidly attached to and branching out from the main header conduit, both the main header conduit and the lateral conduits defining downwardly facing feed nozzles.
  • the feed sparger system further includes feed shrouds associated with respective feed nozzles, each feed shroud comprising a proximal end connected to a respective lateral conduit or header conduit and being arranged to direct saturated and/or unsaturated C3 to C4 hydrocarbons and ammonia passing out of its respective feed nozzle downwardly into the interior of the acrylonitrile reactor.
  • the process further includes supplying air to the inside of the reactor through an air grid system.
  • the air grid system comprising a continuous metal plate arranged below the feed sparger system, the continuous metal plate defining a series of air holes therein for directing process air from below the continuous metal plate to above the continuous metal plate towards the sparger system.
  • the distance between the upper surface of the continuous metal plate and the distal ends of the feed shrouds is about 6 to about 24 inches (about 15 to about 61 cm).
  • this disclosure in accordance with another feature provides an improved air grid system for use in a commercial oxidation or ammoxidation reactor, such as an acrylonitrile reactor, the improved air grid system comprising a continuous metal plate defining an upper surface, a lower surface and a periphery extending there between, the continuous metal plate further defining a series of air holes for directing process air from below the continuous metal plate towards a sparger feed system located above the continuous metal plate, and a support system for supporting the weight of the continuous metal plate and any oxidation or ammoxidation catalyst that may be resting on the continuous metal plate, wherein the support system comprises a series of support beams each having a upper support surface engaging the underside of the continuous metal plate and a series of support hold-downs fixedly attached to the underside of the continuous metal plate, each support hold-down being arranged to engage a mating surface defined in a respective support beam below its upper surface in a manner so that the support hold-downs prevent the continuous metal plate from being lifted off the series of support beam
  • a process for reducing movement in an air grid system in a commercial oxidation or ammoxiodation reactor.
  • the process includes providing an air grid system that includes a continuous metal plate defining an upper surface, a lower surface and a periphery extending there between.
  • the continuous metal plate further defining a series of air holes for directing process air from below the continuous metal plate to above the continuous metal plate, and a support system for supporting the weight of the continuous metal plate and any oxidation or ammoxidation catalyst that may be resting on the continuous metal plate.
  • the support system comprises a series of support beams each having an upper support surface engaging the underside of the continuous metal plate and a series of support hold-downs fixedly attached to the underside of the continuous metal plate.
  • Each support hold-down is arranged to engage a mating surface defined in a respective support beam below its upper surface in a manner so that the support hold-downs prevent the continuous metal plate from being lifted off the series of support beams.
  • this disclosure in accordance with still another feature provides an improved air grid system for use in a commercial oxidation or ammoxidation reactor, such as an acrylonitrile reactor, the improved air grid system comprising a continuous metal plate defining an upper surface, a lower surface and a periphery extending therebtween, the continuous metal plate further defining a series of air holes for directing process air from below the continuous metal plate towards a sparger feed system located above the continuous metal plate, and a connection assembly for attaching the periphery of the continuous metal plate to the side wall of the oxidation or ammoxidation reactor, wherein the connection assembly comprises a flex plate and a mating standoff plate each of which comprises an annular sheet of metal defining a top and a bottom, both the flex plate and standoff plates being arranged essentially congruent with the side wall of the oxidation or ammoxidation reactor, wherein the standoff plate is attached to the side wall of the oxidation or ammoxidation reactor, wherein the bottom of the
  • a process for accommodating flexing in an air grid system, the process includes providing a continuous metal plate defining an upper surface, a lower surface and a periphery extending therebetween.
  • the continuous metal plate further defines a series of air holes for directing process air from below the continuous metal plate to above the continuous metal plate, and a connection assembly for attaching the periphery of the continuous metal plate to the side wall of the reactor.
  • the connection assembly comprises a flex plate and a mating standoff plate each of which comprises an annular sheet of metal defining a top and a bottom.
  • Both the flex plate and standoff plated are arranged essentially congruent with the side wall of the reactor, wherein the standoff plate is attached to the side wall of the reactor, wherein the bottom of the flex plate is attached to the periphery of the continuous metal plate, and wherein the flex plate is attached to the standoff plate in a manner such that the flex plate defines a lower portion which extends below the bottom of the standoff plate so that variations in the diameter of the continuous metal plate due to temperature changes inside the acrylonitrile can be accommodated by the flexing of the lower portion of the flex plate Brief Description of the Drawings
  • Fig. 1 is a schematic view showing the reactor section of a conventional ammoxidation reactor used for making acrylonitrile
  • Fig. 2 is a plan view showing the underside of the conventional sparger system of the ammoxidation reactor of Fig. 1;
  • Fig. 3 is a cross sectional view taken on line 3-3 of Fig 2, Fig. 3 showing the feed nozzles and associated feed shrouds of the conventional sparger system of Fig 2;
  • Fig. 4 illustrates a conventional way of attaching the air grid of an acrylonitrile reactor to the wall of the reactor
  • Fig. 5 is a partial sectional view of an acrylonitrile reactor illustrating a first feature of this disclosure in which the performance of a conventional acrylonitrile reactor is improved and mechanical damage to certain parts of the acrylonitrile reactor are reduced by spacing the air grid and feed sparger apart from one another by a suitable distance;
  • Fig. 6 illustrates a second feature of this disclosure in which a novel support system is provided for supporting the air grid of an acrylonitrile reactor
  • Fig. 7 illustrates a third feature of this disclosure in which a unique connection assembly is provided for securing the air grid 14 of an acrylonitrile reactor to the side wall of the reactor.
  • Fig. 5 illustrates a first feature of the technology of this disclosure in which air grid 14 is spaced from feed sparger 16 by a suitable distance, in particular 6 to 24 inches (-15 to -61 cm).
  • feed sparger 16 includes multiple feed shrouds 60, each of which is associated with a respective feed nozzle defined in header 30 or a lateral 32 of the sparger system.
  • Each feed shroud defines a proximal end 62 which is connected to its respective header 30 or a lateral 32 and distal end 64 remote therefrom, with feed shrouds 60 being arranged to direct propylene and ammonia passing feed out of their respective feed nozzles downwardly into the interior of the acrylonitrile reactor, towards air grid 14.
  • air grid 14 takes the form of a continuous metal plate 70 which is arranged below feed sparger 16, and which defines an upper surface 72, a lower surface 74 and series of air holes 76 extending therebetween for directing process air entering the ammoxidation reactor from below the continuous metal plate upwards towards feed sparger 16.
  • distal ends 64 of feed shrouds 60 are arranged to be at a distance of 6 to 24 inches (-15 to -61 cm) from upper surface 72 of continuous metal plate 70.
  • distal ends 64 of feed shrouds 60 are arranged to be at a distance of 8 to 12 inches (-20 to -30.5 cm) from upper surface 72 of continuous metal plate 70.
  • the distance been air grid 14 and feed sparger 16, as measured between the distal ends 64 of feed shrouds 60 and the upper surface 72 of continuous metal plate, should be at least 6 inches (-15 cm) and preferably at least about 8 inches (-20 cm) to avoid this problem.
  • the maximum distance between air grid 14 and feed sparger 16, as measured between the distal ends 64 of feed shrouds 60 and the upper surface 72 of continuous metal plate 70, is kept at no more than about 24 inches (-61 cm), preferably no more than 18 inches (-45.7 cm), in another aspect, no more than 14 inches (-35.5 cm), and in another aspect, no more than 12 inches (-30.5 cm), to prevent this from occurring.
  • Fig. 6 illustrates a second feature of the technology of this disclosure in which a novel support system, generally indicated at 80, is provided for supporting the weight of continuous metal plate 70 of air grid 14, including the weight of any ammoxidation catalyst that may be resting on this continuous metal plate.
  • support system 80 takes the form of a series of support beams 82, which in the particular embodiment shown are conventional I- beams.
  • Each I-beam 82 includes an upper transverse section 84 which defines an upper surface 86 on which continuous metal plate 70 rests.
  • the underside of each upper transverse section 86 defines mating surface 88 for engaging with a support hold-down carried by continuous metal plate 70 of air grid 14, as further discussed below.
  • each support bar 90 serves as a hold-down for holding continuous metal plate 70 in contact with the upper surfaces 86 of I-beams 82, thereby preventing this continuous metal plate from being lifted off these I-beams as a result of the force of the process air flowing upwardly through air holes 76 in this metal plate.
  • suitable spaces 94 and 96 are arranged between the end of each support bar 82 and the facing portions of I-beams 82 for accommodating changes in the lengths of these support bars which inherently occur as a result of the temperature changes experienced inside the reactor during startup and shutdown.
  • continuous metal plate 70 is securely held down on the upper surfaces 86 of I-beams by noses 92 of support bars 90 engaging respective mating surfaces 88 of I-beams 82.
  • other structures which provide a similar manner of attachment can be used in place of support bars 90 and their associated noses 92.
  • spaces 94 and 96 arranged between the ends of each support bar 82 and the facing portions of I-beams 82 variations in the lengths of support bars 90 which occur as a result of the significant changes in temperature occurring inside reactor 10 during start up and shut down are easily accommodated by these spaces. As a result, mechanical failure of support system 80 is largely eliminated.
  • Fig. 7 illustrates a third feature of the technology of this disclosure in which a unique connection assembly is provided for securing the periphery of continuous metal plate 70 of air grid 14 to side wall 36 of reactor 10.
  • this connection assembly which is generally indicated at 100, comprises flex plate 102 and mating standoff plate 104.
  • Flex plate 102 comprises an elongated sheet of metal whose two ends are welded together so that flex plate 102 assumes an annular shape, in particular the shape of a right section of a cylinder. With this shape, flex plate 102 is essentially congruent with side wall 36 of reactor 10 to which air grid 14 is attached, since the midsection of reactor 10 is also shaped in the form of a cylinder.
  • standoff plate 104 also comprises an elongated sheet of metal whose two ends are welded together so that standoff plate 104 also assumes an annular shape.
  • standoff plate 104 is arranged between flex plate 102 and side wall 36 of reactor 10 in a manner such that flex plate 102 defines a lower portion 114 which extends below the bottom 112 of standoff plate 104.
  • the bottom 110 of flex plate 102 extends below the bottom 112 of standoff plate 104 by a distance ofabout 6 to about 10 inches (about 15 to about 25 cm), more desirably about 7 to about 9 inches (about 18 to about 23 cm).
  • bottom 110 of flex plate 102 is attached, preferably by welding, to the periphery of continuous metal plate 70 of air grid 14.
  • changes in the diameter of continuous metal plate 70 of air grid 14 which occur as a result of the significant changes in temperature occurring inside reactor 10 during start up and shut down, are easily accommodated by the flexing of lower portion 114 of flex plate 102, i.e., the portion of flex plate 102 which extends below bottom 112 of standoff plate 102.
  • mechanical failure of the joints connecting the periphery of continuous metal plate 70 of air grid 14 to side wall 12 of reactor 10 are largely eliminated.
  • reactors may have external diameters from about 5 to about 12 meters, in another aspect, about 8 to about 12 meters, and in another aspect, about 9 to about 11 meters.
  • external reactor diameters between about 8 to about 12 meters, or about 9 to about 11 meters
  • air nozzles are uncapped, the air being introduced vertically into the reactor, most preferably directed vertically towards a feed shroud.
  • air nozzles in air grid are capped, the air being preferentially distributed horizontally into the reactor by the cap

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

Selon l'invention, on peut réduire considérablement le mélange inadéquat des réactifs ainsi que des points chauds de réacteur localisés dans un réacteur de production d'acrylonitrile industriel si la distance entre le système arroseur (16) et une grille à air (14) est réglée pour être dans la plage de 6 à 24 pouces (~15 à ~61 cm), de préférence de 8 à 12 pouces (~20 à ~30,5 cm). De plus, les problèmes de déplacement de grille à air sur le support ou hors de ce dernier et de défaillance mécanique de la grille à air peuvent être presque totalement éliminés au moyen d'un système modifié pour la fixation de la grille à air aux parois du réacteur ainsi qu'à ses barres de support internes.
PCT/US2015/022190 2014-03-31 2015-03-24 Conception de grille à air améliorée pour un réacteur d'oxydation ou d'ammoxydation WO2015153188A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201410124984.4 2014-03-31
CN201410124984.4A CN104941535A (zh) 2014-03-31 2014-03-31 用于氧化或氨氧化反应器的改进的空气格栅设计

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WO2015153188A1 true WO2015153188A1 (fr) 2015-10-08

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Publication number Priority date Publication date Assignee Title
CN112439368B (zh) * 2019-09-05 2023-11-10 中石油吉林化工工程有限公司 一种用于制丙烯腈的反应器

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US4801731A (en) 1987-12-14 1989-01-31 E. I. Du Pont De Nemours And Company Preparation of acrylonitrile
EP0446379A1 (fr) * 1989-10-04 1991-09-18 Asahi Kasei Kogyo Kabushiki Kaisha Appareil de production de nitrile alpha-beta-insature
US5256810A (en) 1992-10-14 1993-10-26 The Standard Oil Company Method for eliminating nitriding during acrylonitrile production
EP0832877A2 (fr) * 1996-09-25 1998-04-01 Nitto Kagaku Kogyo Kabushiki Kaisha Procédé d'ammoxydation dans un réacteur à lit fluidisé
US5866708A (en) * 1995-04-07 1999-02-02 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing α β-unsaturated nitrile
US20020182123A1 (en) * 2001-03-21 2002-12-05 Ramakrishnan Ramachandran Sparger configuration for fluidized bed hydrocarbon partial oxidation reactors
CN102753262A (zh) * 2010-01-25 2012-10-24 旭化成化学株式会社 气相反应方法
US20130272946A1 (en) * 2007-10-25 2013-10-17 Mitsubishi Materials Corporation Hydrogen chrolide gas ejecting nozzle, reaction apparatus for producing trichlorosilane and method for producing trichlorosilane

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CN1041413C (zh) * 1990-10-20 1998-12-30 旭化成工业株式会社 α、β-不饱和腈的制造装置
CN1080208A (zh) * 1992-06-25 1994-01-05 中国石油化工总公司 流化床催化氧化反应器的气体分布装置
CN103097014B (zh) * 2010-09-14 2015-12-09 旭化成化学株式会社 气相放热反应方法及气相放热反应装置
CN103566838B (zh) * 2012-08-02 2018-04-13 宁波科元塑胶有限公司 丙烯腈流化反应系统及丙烯腈流化床生产方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4801731A (en) 1987-12-14 1989-01-31 E. I. Du Pont De Nemours And Company Preparation of acrylonitrile
EP0446379A1 (fr) * 1989-10-04 1991-09-18 Asahi Kasei Kogyo Kabushiki Kaisha Appareil de production de nitrile alpha-beta-insature
US5256810A (en) 1992-10-14 1993-10-26 The Standard Oil Company Method for eliminating nitriding during acrylonitrile production
US5866708A (en) * 1995-04-07 1999-02-02 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing α β-unsaturated nitrile
EP0832877A2 (fr) * 1996-09-25 1998-04-01 Nitto Kagaku Kogyo Kabushiki Kaisha Procédé d'ammoxydation dans un réacteur à lit fluidisé
US20020182123A1 (en) * 2001-03-21 2002-12-05 Ramakrishnan Ramachandran Sparger configuration for fluidized bed hydrocarbon partial oxidation reactors
US20130272946A1 (en) * 2007-10-25 2013-10-17 Mitsubishi Materials Corporation Hydrogen chrolide gas ejecting nozzle, reaction apparatus for producing trichlorosilane and method for producing trichlorosilane
CN102753262A (zh) * 2010-01-25 2012-10-24 旭化成化学株式会社 气相反应方法

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CN104941535A (zh) 2015-09-30
TW201544174A (zh) 2015-12-01

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