WO2015118242A1 - Glazing for motor vehicle, comprising an opaque or transparent active film and a photochromic layer - Google Patents

Glazing for motor vehicle, comprising an opaque or transparent active film and a photochromic layer Download PDF

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Publication number
WO2015118242A1
WO2015118242A1 PCT/FR2015/050152 FR2015050152W WO2015118242A1 WO 2015118242 A1 WO2015118242 A1 WO 2015118242A1 FR 2015050152 W FR2015050152 W FR 2015050152W WO 2015118242 A1 WO2015118242 A1 WO 2015118242A1
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WO
WIPO (PCT)
Prior art keywords
glazing
active film
transparent
layer
opaque
Prior art date
Application number
PCT/FR2015/050152
Other languages
French (fr)
Inventor
Frederic Guidez
Gerard Jeuffe
Nicolas RILAT
Original Assignee
Peugeot Citroen Automobiles Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Peugeot Citroen Automobiles Sa filed Critical Peugeot Citroen Automobiles Sa
Publication of WO2015118242A1 publication Critical patent/WO2015118242A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10431Specific parts for the modulation of light incorporated into the laminated safety glass or glazing
    • B32B17/10467Variable transmission
    • B32B17/10495Variable transmission optoelectronic, i.e. optical valve
    • B32B17/10513Electrochromic layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10431Specific parts for the modulation of light incorporated into the laminated safety glass or glazing
    • B32B17/10467Variable transmission
    • B32B17/10486Variable transmission photochromic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10431Specific parts for the modulation of light incorporated into the laminated safety glass or glazing
    • B32B17/10467Variable transmission
    • B32B17/10495Variable transmission optoelectronic, i.e. optical valve
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J3/00Antiglare equipment associated with windows or windscreens; Sun visors for vehicles
    • B60J3/04Antiglare equipment associated with windows or windscreens; Sun visors for vehicles adjustable in transparency

Definitions

  • the present invention relates to a motor vehicle glazing comprising two glass sheets separated by an intermediate layer or intermediate layers of transparent plastic material.
  • the invention is preferably applied to the roof glazing or roof of a motor vehicle to replace the curtain called velum or windshields to replace sunshades.
  • Figure 1 shows the interior of a motor vehicle whose roof or roof is equipped with a glazing 1.
  • Motor vehicle roof or pavilion glazings generally have an internal blackout curtain.
  • This curtain (not shown in Figure 1) is slidably mounted in a frame located under the glazing between an open position and a closed position of concealment.
  • This curtain is necessary to protect the occupants of the vehicle in case of strong sunlight.
  • This curtain and the frame that supports it increases the cost of the entire glazing.
  • this curtain which is mounted inside the vehicle under the roof glazing, decreases the height of the space above the head of the occupants of the vehicle.
  • roof or roof glazings comprising, as shown in the sectional views of Figures 2 to 5, two glass sheets 2, 3 separated by a layer 4 of transparent plastic material, such as PVB (polyvinyl butyral) .
  • PVB polyvinyl butyral
  • an active film 5 which can be powered by a source of electrical energy connected to a conductor 6.
  • the active film 5 can thus pass from a substantially opaque state, when this film 5 is not powered (see FIG. 2), to a substantially transparent state, when this film 5 is powered by the source of electrical energy, as shown in FIG.
  • Figures 2 and 3 illustrate the case of moderate sunshine of less than 850 W / m 2 and a moderate temperature of 20 ° C.
  • the luminosity transmitted through the glazing is equal to approximately 3% of the incident luminosity F ,, given the opacity of the active film 5 and the fact that the glass of leaves 2 and 3 is tinted.
  • the transmitted brightness F t is equal to approximately 10% of the incident luminosity F ,, given the transparency of the active film 5.
  • the roof glazing shown in Figures 2 and 3, therefore does not have the drawbacks mentioned above, concerning the obligation to mount a blackout curtain under the glazing to protect the occupants with respect to solar radiation.
  • the active film 5 instead of being opaque when it is not powered by the source electric loss of opacity, so much so that the transmitted brightness F t becomes greater than 3% of the incident light F , when the active film 5 is not powered, which is not acceptable to the occupants of the vehicle.
  • the object of the present invention is to overcome the disadvantages of the glazing above.
  • a motor vehicle glazing comprising two sheets of glass separated by an intermediate layer of transparent plastic material and an active film that can be powered by a source of electrical energy to be able to pass from a substantially opaque state when this film is not supplied to a substantially transparent state, when this film is powered by said source of electrical energy
  • this glazing being characterized in that it further comprises a passive photochromic layer which is suitable to darken when the sun exceeds a predetermined threshold and causes the reduction of the opacity of the glazing.
  • the photochromic passive layer integrated into the glazing unit according to the invention thus compensates for the reduction in the opacity of the active film when it is not electrically powered and the sunshine is very strong, for example greater than 850 W / m 2. .
  • the glazing is constituted by a glazing roof or roof of a motor vehicle.
  • the glazing according to the invention effectively protects and ensures a well being to the occupants of the vehicle, even in case of high heat and strong sunshine and without the need to equip the glazing with a curtain occultation bulky and expensive.
  • said opaque or transparent active film is embedded in the transparent plastic layer.
  • said opaque or transparent active film may also be located at the interface between one of the glass sheets and the plastic layer.
  • This active film may be composed of liquid crystals comprising molecules whose electric dipoles can be oriented by virtue of the electric field created by the electric current supplied by said source.
  • the passive photochromic layer is deposited on the face of one of the glass sheets adjacent to the intermediate layer of plastics material.
  • the photochromic layer may be deposited on the face of the glass sheet intended to be directed towards the inside of the vehicle.
  • the photochromic passive layer consists of photochromic compound pigments embedded in the plastic interlayer or in the opaque or transparent active film.
  • the invention also relates to a motor vehicle equipped with a glazing unit according to the invention.
  • This glazing has in particular the advantage of being devoid of blackout curtain, because of the opacity that is provided by the photochromic layer in case of strong sunlight.
  • FIG. 5 is a partial cross-sectional view of a glazing unit according to the invention in which the active film is not electrically powered and is opaque, the photochromic layer being transparent,
  • FIG. 6 is a view similar to FIG. 5 showing the active film electrically powered and transparent, the photochromic layer being transparent,
  • FIG. 7 is a view analogous to FIGS. 5 to 6, showing the unpowered active film having lost its opacity and the photochromic layer having become opaque due to strong sunlight,
  • FIG. 8 is a diagram showing the evolution of the light transmission through the glazing according to the invention, as a function of the power per m 2 of sunshine for different power states of the active film.
  • Figures 5 to 7 show a roof glazing or roof of a motor vehicle comprising, as in the case of Figures 2 to 4, two sheets of glass 2, 3 tinted, separated by one or more layers of transparent plastic material 4 for example in PVB. If necessary, these PVB sheets may have anti-infrared or anti-ultraviolet properties.
  • the glass sheet 3 adjacent to the passenger compartment of the vehicle may comprise at its periphery an opaque serigraphy 7, as in the case of Figures 2 to 4.
  • the glazing further comprises an active film 5, which in the example shown is embedded in the intermediate layer of plastic material 4.
  • This active film 5 may be electrically powered by a source, such as the vehicle battery, in order to be able to pass from a substantially opaque state, as shown in FIG. 5, when the film 5 is not powered, to a state substantially transparent, when the film is powered by the source of electrical energy, as shown in Figure 6.
  • a source such as the vehicle battery
  • the roof glazing shown in FIGS. 5 to 7, comprises, in accordance with the invention, a photochromic passive layer 8 which can darken when the sunlight exceeds a certain threshold, as shown in FIG.
  • the active film 5 When the power per m 2 of sunshine exceeds 850 W / m 2 , the active film 5 partially loses its opacity (see Figure 7), as in the case of known glazing. However, this loss of opacity of the film 5 is compensated by the darkening of the photochromic layer 8 which has been added to the glazing according to the invention.
  • the opaque or transparent active film 5 may be embedded in the plastic layer 4, as shown in FIGS. 5 to 7, or may be located at the interface between one of the glass sheets 2 or 3 and the plastic material.
  • the active film 5 may be composed of liquid crystals consisting of molecules whose electric dipoles can be oriented in the same direction by virtue of an electric field created by the electric current which supplies the film 5.
  • the film 5 When the dipoles are oriented by the electric field, the film 5 is transparent, whereas when these dipoles are not oriented, the film 5 is opaque.
  • the passive photochromic layer 8 is preferably deposited on the face of one of the two glass sheets 2, 3 adjacent to the intermediate layer of plastic material 4, or on the inner face of the inner glass, or on a sheet of PVB or on the active film, or in a PVB sheet or in the active film.
  • the photochromic layer 8 is deposited on the inner face of the glass sheet 3 directed towards the passenger compartment of the vehicle.
  • This passive photochromic layer 8 may also consist of pigments of photochromic compounds embedded in the plastic of the intermediate layer 4 or in the active film 5 opaque or transparent.
  • the active film 5 is not powered, as shown in Figure 5, it is therefore opaque.
  • the photochromic layer 8 is transparent.
  • the transmitted brightness F t through the glazing is equal to only 3% of the incident light F ,.
  • the atmospheric conditions are the same as in the case of FIG. 5, namely:
  • the active film 5 is fed and becomes transparent.
  • the photochromic layer is also transparent.
  • the transmitted brightness F t is equal to 10% of the incident light F ,.
  • the temperature is high (over 40 ° C).
  • Active film 5 is not electrically powered.
  • this film 5 undergoes a loss of opacity and passes light.
  • the photochromic layer 8 becomes opaque due to the strong sunlight of the glazing and thus compensates for the loss of opacity of the active film 5.
  • the transmitted brightness F t is equal to 3%, as in the case of Figure 5, which ensures excellent comfort to the occupants of the vehicle.
  • FIG. 8 represents various curves showing the evolution of the light transmission F t through the glazing according to the invention as a function of the sun exposure E.
  • the curve Ci shows that when the active film 5 is not powered, the light transmission F t remains at 3% up to a sunshine threshold E equal to 850 W / m 2 .
  • the transmitted brightness F t increases when the photochromic layer 8 is absent.
  • the curve C 2 shows that the transmitted brightness remains equal to 3% even beyond the threshold of 850 K / m 2 .
  • the dotted curve C 3 shows the contribution of the photochromic layer 8.
  • the curve C 4 shows that when the active film 5 is fed and the photochromic layer 8 is absent, the light transmission F t remains equal to 10% beyond the sunshine threshold equal to 850 W / m 2 .
  • the curve C 5 shows that the glazing according to the invention undergoes a slight loss of opacity, when the irradiation is greater than 850 W / m 2 .
  • the amount of light received is perceived as identical by the occupants of the vehicle.
  • the combination of the active film 5 and the photochromic layer 8 ensures that the opacity of the glazing according to the invention is no longer variable as a function of the power of the sun.

Abstract

The invention relates to a motor vehicle comprising two sheets of glass (2, 3) separated by an intermediate layer of transparent plastic material (4) and an active film (5) that can be powered by an electrical energy source in order to switch from a substantially opaque state, when the film is not being powered, to a substantially transparent state, when the film (5) is being powered by said electrical energy source, said glazing being characterised in that it also comprises a passive photochromic layer (8) which can darken when the sunlight exceeds a pre-determined threshold and reduces the opacity of the glazing.

Description

VITRAGE POUR VÉHICULE AUTOMOBILE COMPRENANT UN FILM ACTIF OPAQUE OU TRANSPARENT ET UNE COUCHE PHOTOCHROMIQUE  GLAZING FOR A MOTOR VEHICLE COMPRISING AN OPAQUE OR TRANSPARENT ACTIVE FILM AND A PHOTOCHROMIC LAYER
La présente invention concerne un vitrage de véhicule automobile comprenant deux feuilles de verre séparées par une couche intermédiaire une ou des couches intermédiaires de matière plastique transparente. The present invention relates to a motor vehicle glazing comprising two glass sheets separated by an intermediate layer or intermediate layers of transparent plastic material.
L'invention s'applique de préférence aux vitrages de toit ou de pavillon de véhicule automobile en remplacement du rideau appelé vélum ou aux pare-brise en remplacement des pare-soleil.  The invention is preferably applied to the roof glazing or roof of a motor vehicle to replace the curtain called velum or windshields to replace sunshades.
La figure 1 montre l'intérieur d'un véhicule automobile dont le toit ou le pavillon est équipé d'un vitrage 1 .  Figure 1 shows the interior of a motor vehicle whose roof or roof is equipped with a glazing 1.
Les vitrages de toit ou de pavillon de véhicule automobile comportent généralement un rideau intérieur d'occultation.  Motor vehicle roof or pavilion glazings generally have an internal blackout curtain.
Ce rideau (non représenté sur la figure 1 ) est monté coulissant dans un cadre situé sous le vitrage entre une position ouverte et une position fermée d'occultation.  This curtain (not shown in Figure 1) is slidably mounted in a frame located under the glazing between an open position and a closed position of concealment.
Ce rideau est nécessaire pour protéger les occupants du véhicule en cas de fort ensoleillement.  This curtain is necessary to protect the occupants of the vehicle in case of strong sunlight.
Ce rideau ainsi que le cadre qui le supporte augmente le coût de l'ensemble du vitrage.  This curtain and the frame that supports it increases the cost of the entire glazing.
De plus, ce rideau, qui est monté à l'intérieur du véhicule sous le vitrage de toit, diminue la hauteur de l'espace situé au-dessus de la tête des occupants du véhicule.  In addition, this curtain, which is mounted inside the vehicle under the roof glazing, decreases the height of the space above the head of the occupants of the vehicle.
On connaît par ailleurs des vitrages de toit ou de pavillon comprenant, comme montré sur les vues en coupe des figures 2 à 5, deux feuilles de verre 2, 3 séparées par une couche 4 de matière plastique transparente, telle que du PVB (polyvinylbutyral).  Also known are roof or roof glazings comprising, as shown in the sectional views of Figures 2 to 5, two glass sheets 2, 3 separated by a layer 4 of transparent plastic material, such as PVB (polyvinyl butyral) .
Dans cette couche de matière plastique transparente est noyée un film actif 5 pouvant être alimenté par une source d'énergie électrique reliée à un conducteur 6.  In this layer of transparent plastic material is embedded an active film 5 which can be powered by a source of electrical energy connected to a conductor 6.
Le film actif 5 peut ainsi passer d'un état sensiblement opaque, lorsque ce film 5 n'est pas alimenté (voir figure 2), à un état sensiblement transparent, lorsque ce film 5 est alimenté par la source d'énergie électrique, comme montré sur la figure 3. The active film 5 can thus pass from a substantially opaque state, when this film 5 is not powered (see FIG. 2), to a substantially transparent state, when this film 5 is powered by the source of electrical energy, as shown in FIG.
Les figures 2 et 3 illustrent le cas d'un ensoleillement modéré de moins de 850 W/m2 et d'une température également modérée de 20 °C. Figures 2 and 3 illustrate the case of moderate sunshine of less than 850 W / m 2 and a moderate temperature of 20 ° C.
Dans le cas de la figure 2, la luminosité transmise au travers du vitrage, représentée par la flèche Ft est égale à environ 3% de la luminosité incidente F,, compte tenu de l'opacité du film actif 5 et du fait que le verre des feuilles 2 et 3 soit teinté. In the case of FIG. 2, the luminosity transmitted through the glazing, represented by the arrow F t, is equal to approximately 3% of the incident luminosity F ,, given the opacity of the active film 5 and the fact that the glass of leaves 2 and 3 is tinted.
Dans le cas de la figure 3, la luminosité transmise Ft est égale à environ 10% de la luminosité incidente F,, compte tenu de la transparence du film actif 5. In the case of FIG. 3, the transmitted brightness F t is equal to approximately 10% of the incident luminosity F ,, given the transparency of the active film 5.
Le vitrage de toit, représenté sur les figures 2 et 3, ne présente par conséquent pas les inconvénients mentionnés plus haut, concernant l'obligation de monter un rideau d'occultation sous le vitrage pour protéger les occupants à l'égard du rayonnement solaire.  The roof glazing, shown in Figures 2 and 3, therefore does not have the drawbacks mentioned above, concerning the obligation to mount a blackout curtain under the glazing to protect the occupants with respect to solar radiation.
Cependant, le vitrage, représenté sur les figures 2 et 3, présente un autre inconvénient qui est illustré par la figure 4.  However, the glazing, shown in Figures 2 and 3, has another drawback which is illustrated in Figure 4.
En cas de température très élevée par exemple supérieure à 40 ° C et d'ensoleillement très important (supérieur à 850 W/m2), le film actif 5 au lieu d'être opaque lorsqu'il n'est pas alimenté par la source électrique subit une perte d'opacité, à tel point que la luminosité transmise Ft devient supérieure à 3% de la luminosité incidente F,, lorsque le film actif 5 n'est pas alimenté, ce qui n'est pas acceptable pour les occupants du véhicule. In case of very high temperature, for example greater than 40 ° C and very significant sunshine (greater than 850 W / m 2 ), the active film 5 instead of being opaque when it is not powered by the source electric loss of opacity, so much so that the transmitted brightness F t becomes greater than 3% of the incident light F ,, when the active film 5 is not powered, which is not acceptable to the occupants of the vehicle.
Le but de la présente invention est de remédier aux inconvénients du vitrage ci-dessus.  The object of the present invention is to overcome the disadvantages of the glazing above.
Ce but est atteint, selon l'invention, grâce à un vitrage de véhicule automobile comprenant deux feuilles de verre séparées par une couche intermédiaire de matière plastique transparente et un film actif pouvant être alimenté par une source d'énergie électrique pour pouvoir passer d'un état sensiblement opaque lorsque ce film n'est pas alimenté à un état sensiblement transparent, lorsque ce film est alimenté par ladite source d'énergie électrique, ce vitrage étant caractérisé en ce qu'il comporte en outre une couche passive photochromique qui est apte à s'assombrir lorsque l'ensoleillement dépasse un seuil prédéterminé et provoque la diminution de l'opacité du vitrage. La couche passive photochromique intégrée dans le vitrage selon l'invention compense ainsi la diminution de l'opacité du film actif lorsque celui-ci n'est pas alimenté électriquement et que l'ensoleillement est très puissant par exemple supérieur à 850 W/m2. This object is achieved, according to the invention, thanks to a motor vehicle glazing comprising two sheets of glass separated by an intermediate layer of transparent plastic material and an active film that can be powered by a source of electrical energy to be able to pass from a substantially opaque state when this film is not supplied to a substantially transparent state, when this film is powered by said source of electrical energy, this glazing being characterized in that it further comprises a passive photochromic layer which is suitable to darken when the sun exceeds a predetermined threshold and causes the reduction of the opacity of the glazing. The photochromic passive layer integrated into the glazing unit according to the invention thus compensates for the reduction in the opacity of the active film when it is not electrically powered and the sunshine is very strong, for example greater than 850 W / m 2. .
Dans l'application préférée de l'invention, le vitrage est constitué par un vitrage de toit ou de pavillon de véhicule automobile.  In the preferred application of the invention, the glazing is constituted by a glazing roof or roof of a motor vehicle.
Dans cette application, le vitrage selon l'invention protège efficacement et assure un bien être aux occupants du véhicule, même en cas de forte chaleur et de fort ensoleillement et ce, sans qu'il soit nécessaire d'équiper le vitrage d'un rideau d'occultation encombrant et onéreux.  In this application, the glazing according to the invention effectively protects and ensures a well being to the occupants of the vehicle, even in case of high heat and strong sunshine and without the need to equip the glazing with a curtain occultation bulky and expensive.
De préférence, ledit film actif opaque ou transparent est noyé dans la couche de matière plastique transparente.  Preferably, said opaque or transparent active film is embedded in the transparent plastic layer.
Cependant, ledit film actif opaque ou transparent peut également être situé à l'interface entre l'une des feuilles de verre et la couche de matière plastique.  However, said opaque or transparent active film may also be located at the interface between one of the glass sheets and the plastic layer.
Ce film actif peut être composé de cristaux liquides comprenant des molécules dont les dipôles électriques peuvent être orientés grâce au champ électrique créé par le courant électrique fourni par ladite source.  This active film may be composed of liquid crystals comprising molecules whose electric dipoles can be oriented by virtue of the electric field created by the electric current supplied by said source.
Dans un mode de réalisation avantageux de l'invention, la couche passive photochromique est déposée sur la face de l'une des feuilles de verre adjacente à la couche intermédiaire de matière plastique.  In an advantageous embodiment of the invention, the passive photochromic layer is deposited on the face of one of the glass sheets adjacent to the intermediate layer of plastics material.
Cependant, la couche photochromique peut être déposée sur la face de la feuille de verre destinée à être dirigée vers l'intérieur du véhicule.  However, the photochromic layer may be deposited on the face of the glass sheet intended to be directed towards the inside of the vehicle.
Dans un autre mode de réalisation, la couche passive photochromique est constituée de pigments de composés photochromiques noyés dans la couche intermédiaire de matière plastique ou dans le film actif opaque ou transparent.  In another embodiment, the photochromic passive layer consists of photochromic compound pigments embedded in the plastic interlayer or in the opaque or transparent active film.
Selon un autre aspect, l'invention concerne également un véhicule automobile équipé d'un vitrage selon l'invention.  According to another aspect, the invention also relates to a motor vehicle equipped with a glazing unit according to the invention.
Ce vitrage présente en particulier l'avantage d'être dépourvu de rideau d'occultation, en raison de l'opacité qui est apportée par la couche photochromique en cas de fort ensoleillement.  This glazing has in particular the advantage of being devoid of blackout curtain, because of the opacity that is provided by the photochromic layer in case of strong sunlight.
D'autres particularités et avantages de l'invention apparaîtront encore tout au long de la description ci-après.  Other features and advantages of the invention will become apparent throughout the description below.
Aux dessins annexés, donnés à titre d'exemples, non limitatifs : - la figure 5 est une vue en coupe transversale partielle d'un vitrage selon l'invention dans lequel le film actif n'est pas alimenté électriquement et est opaque, la couche photochromique étant transparente, In the accompanying drawings, given by way of nonlimiting examples: FIG. 5 is a partial cross-sectional view of a glazing unit according to the invention in which the active film is not electrically powered and is opaque, the photochromic layer being transparent,
- la figure 6 est une vue analogue à la figure 5 montrant le film actif alimenté électriquement et transparent, la couche photochromique étant transparente,  FIG. 6 is a view similar to FIG. 5 showing the active film electrically powered and transparent, the photochromic layer being transparent,
- la figure 7 est une vue analogue aux figures 5 à 6, montrant le film actif non alimenté ayant perdu son opacité et la couche photochromique devenue opaque du fait d'un fort ensoleillement,  FIG. 7 is a view analogous to FIGS. 5 to 6, showing the unpowered active film having lost its opacity and the photochromic layer having become opaque due to strong sunlight,
- la figure 8 est un diagramme montrant l'évolution de la transmission lumineuse à travers le vitrage selon l'invention, en fonction de la puissance par m2 de l'ensoleillement pour différents états d'alimentation du film actif. - Figure 8 is a diagram showing the evolution of the light transmission through the glazing according to the invention, as a function of the power per m 2 of sunshine for different power states of the active film.
Les figures 5 à 7 représentent un vitrage de toit ou de pavillon d'un véhicule automobile comprenant, comme dans le cas des figures 2 à 4, deux feuilles de verre 2, 3 teintées, séparées par une ou plusieurs couches de matière plastique transparente 4 par exemple en PVB. Si besoin, ces feuilles de PVB peuvent avoir des propriétés anti-infrarouge ou anti-ultraviolets.  Figures 5 to 7 show a roof glazing or roof of a motor vehicle comprising, as in the case of Figures 2 to 4, two sheets of glass 2, 3 tinted, separated by one or more layers of transparent plastic material 4 for example in PVB. If necessary, these PVB sheets may have anti-infrared or anti-ultraviolet properties.
La feuille de verre 3 adjacente à l'habitacle du véhicule peut comporter à sa périphérie une sérigraphie opaque 7, comme dans le cas des figures 2 à 4.  The glass sheet 3 adjacent to the passenger compartment of the vehicle may comprise at its periphery an opaque serigraphy 7, as in the case of Figures 2 to 4.
Le vitrage comporte en outre un film actif 5, qui dans l'exemple représenté, est noyé dans la couche intermédiaire en matière plastique 4.  The glazing further comprises an active film 5, which in the example shown is embedded in the intermediate layer of plastic material 4.
Ce film actif 5 peut être alimenté électriquement pas une source, telle que la batterie du véhicule, pour pouvoir passer d'un état sensiblement opaque, comme montré par la figure 5, lorsque le film 5 n'est pas alimenté, à un état sensiblement transparent, lorsque le film est alimenté par la source d'énergie électrique, comme indiqué sur la figure 6.  This active film 5 may be electrically powered by a source, such as the vehicle battery, in order to be able to pass from a substantially opaque state, as shown in FIG. 5, when the film 5 is not powered, to a state substantially transparent, when the film is powered by the source of electrical energy, as shown in Figure 6.
Le vitrage de toit, représenté sur les figures 5 à 7, comprend, conformément à l'invention, une couche passive photochromique 8 qui peut s'assombrir, lorsque l'ensoleillement dépasse un certain seuil, comme montré sur la figure 7.  The roof glazing, shown in FIGS. 5 to 7, comprises, in accordance with the invention, a photochromic passive layer 8 which can darken when the sunlight exceeds a certain threshold, as shown in FIG.
Lorsque la puissance par m2 de l'ensoleillement dépasse 850 W/m2, le film actif 5 perd partiellement son opacité (voir figure 7), comme dans le cas du vitrage connu. Toutefois, cette perte d'opacité du film 5 est compensée par l'assombrissement de la couche photochromique 8 qui a été ajoutée au vitrage selon l'invention. When the power per m 2 of sunshine exceeds 850 W / m 2 , the active film 5 partially loses its opacity (see Figure 7), as in the case of known glazing. However, this loss of opacity of the film 5 is compensated by the darkening of the photochromic layer 8 which has been added to the glazing according to the invention.
Le film actif 5 opaque ou transparent peut être noyé dans la couche en matière plastique 4, comme montré sur les figures 5 à 7, ou peut être situé à l'interface entre l'une des feuilles de verre 2 ou 3 et la couche de matière plastique.  The opaque or transparent active film 5 may be embedded in the plastic layer 4, as shown in FIGS. 5 to 7, or may be located at the interface between one of the glass sheets 2 or 3 and the plastic material.
Le film actif 5 peut être composé de cristaux liquides constitués de molécules dont les dipoles électriques peuvent être orientés dans la même direction grâce à un champ électrique créé par le courant électrique qui alimente le film 5.  The active film 5 may be composed of liquid crystals consisting of molecules whose electric dipoles can be oriented in the same direction by virtue of an electric field created by the electric current which supplies the film 5.
Lorsque les dipoles sont orientés par le champ électrique, le film 5 est transparent, tandis que lorsque ces dipoles ne sont pas orientés, le film 5 est opaque.  When the dipoles are oriented by the electric field, the film 5 is transparent, whereas when these dipoles are not oriented, the film 5 is opaque.
La couche passive photochromique 8 est déposée de préférence sur la face de l'une des deux feuilles de verre 2, 3 adjacente à la couche intermédiaire de matière plastique 4, ou sur la face intérieure du verre intérieur, ou encore sur une feuille de PVB ou sur le film actif, ou dans une feuille de PVB ou dans le film actif.  The passive photochromic layer 8 is preferably deposited on the face of one of the two glass sheets 2, 3 adjacent to the intermediate layer of plastic material 4, or on the inner face of the inner glass, or on a sheet of PVB or on the active film, or in a PVB sheet or in the active film.
Dans l'exemple montré sur les figures 5 à 7, la couche photochromique 8 est déposée sur la face intérieure de la feuille de verre 3 dirigée vers l'habitacle du véhicule.  In the example shown in Figures 5 to 7, the photochromic layer 8 is deposited on the inner face of the glass sheet 3 directed towards the passenger compartment of the vehicle.
Cette couche passive photochromique 8 peut également être constituée de pigments de composés photochromiques noyés dans la matière plastique de la couche intermédiaire 4 ou dans le film actif 5 opaque ou transparent.  This passive photochromic layer 8 may also consist of pigments of photochromic compounds embedded in the plastic of the intermediate layer 4 or in the active film 5 opaque or transparent.
On va maintenant expliquer en détail le fonctionnement du vitrage de toit que l'on vient de décrire.  We will now explain in detail the operation of the roof glazing that has just been described.
Dans le cas de la figure 5, les conditions atmosphériques sont les suivantes : In the case of Figure 5, the atmospheric conditions are as follows:
- l'ensoleillement est modéré (inférieur à 850 W/m2) ; - the sunshine is moderate (less than 850 W / m 2 );
- la température est modérée (20 °C).  - the temperature is moderate (20 ° C).
Le film actif 5 n'est pas alimenté, comme montré sur la figure 5, il est par conséquent opaque.  The active film 5 is not powered, as shown in Figure 5, it is therefore opaque.
La couche photochromique 8 est transparente.  The photochromic layer 8 is transparent.
La luminosité transmise Ft à travers le vitrage est égale seulement à 3% de la luminosité incidente F,. Dans le cas de la figure 6, les conditions atmosphériques sont les mêmes que dans le cas de la figure 5, à savoir : The transmitted brightness F t through the glazing is equal to only 3% of the incident light F ,. In the case of FIG. 6, the atmospheric conditions are the same as in the case of FIG. 5, namely:
- l'ensoleillement est modéré (inférieur à 850 W/m2) ; - the sunshine is moderate (less than 850 W / m 2 );
- la température est modérée (20 °C).  - the temperature is moderate (20 ° C).
Le film actif 5 est alimenté et devient transparent.  The active film 5 is fed and becomes transparent.
La couche photochromique est également transparente.  The photochromic layer is also transparent.
La luminosité transmise Ft est égale à 10% de la luminosité incidente F,. The transmitted brightness F t is equal to 10% of the incident light F ,.
Dans le cas de la figure 7, les conditions atmosphériques sont les suivantes : In the case of Figure 7, the atmospheric conditions are as follows:
- l'ensoleillement est fort (supérieur à 850 W/m2) ; - the sunshine is strong (higher than 850 W / m 2 );
- la température est élevée (plus de 40 °C).  - the temperature is high (over 40 ° C).
Le film actif 5 n'est pas alimenté électriquement.  Active film 5 is not electrically powered.
Cependant, au lieu d'être opaque, ce film 5 subit une perte d'opacité et laisse passer de la luminosité.  However, instead of being opaque, this film 5 undergoes a loss of opacity and passes light.
Toutefois, la couche photochromique 8 s'opacifie en raison du fort ensoleillement du vitrage et compense ainsi la perte d'opacité du film actif 5.  However, the photochromic layer 8 becomes opaque due to the strong sunlight of the glazing and thus compensates for the loss of opacity of the active film 5.
De ce fait, la luminosité transmise Ft est égale à 3%, comme dans le cas de la figure 5, ce qui permet d'assurer un excellent confort aux occupants du véhicule. Therefore, the transmitted brightness F t is equal to 3%, as in the case of Figure 5, which ensures excellent comfort to the occupants of the vehicle.
Le diagramme de la figure 8 représente différentes courbes montrant l'évolution de la transmission lumineuse Ft à travers le vitrage selon l'invention en fonction de l'ensoleillement E. The diagram of FIG. 8 represents various curves showing the evolution of the light transmission F t through the glazing according to the invention as a function of the sun exposure E.
La courbe Ci montre que lorsque le film actif 5 n'est pas alimenté, la transmission lumineuse Ft reste à 3% jusqu'à un seuil d'ensoleillement E égal à 850 W/m2. The curve Ci shows that when the active film 5 is not powered, the light transmission F t remains at 3% up to a sunshine threshold E equal to 850 W / m 2 .
Au-delà de ce seuil, la luminosité transmise Ft augmente lorsque la couche photochromique 8 est absente. Beyond this threshold, the transmitted brightness F t increases when the photochromic layer 8 is absent.
Lorsque cette couche 8 est présente, la courbe C2 montre que la luminosité transmise reste égale à 3% même au-delà du seuil de 850 K/m2. When this layer 8 is present, the curve C 2 shows that the transmitted brightness remains equal to 3% even beyond the threshold of 850 K / m 2 .
La courbe en pointillé C3 montre la contribution de la couche photochromique 8. The dotted curve C 3 shows the contribution of the photochromic layer 8.
La courbe C4 montre que lorsque le film actif 5 est alimenté et que la couche photochromique 8 est absente, la transmission lumineuse Ft reste égale à 10% au-delà du seuil d'ensoleillement égal à 850 W/m2. Lorsque la couche photochromique 8 est présente, la courbe C5 montre que le vitrage selon l'invention subit une légère perte d'opacité, lorsque l'ensoleillement est supérieur à 850 W/m2. The curve C 4 shows that when the active film 5 is fed and the photochromic layer 8 is absent, the light transmission F t remains equal to 10% beyond the sunshine threshold equal to 850 W / m 2 . When the photochromic layer 8 is present, the curve C 5 shows that the glazing according to the invention undergoes a slight loss of opacity, when the irradiation is greater than 850 W / m 2 .
Cependant, la quantité de lumière reçue est perçue comme identique par les occupants du véhicule.  However, the amount of light received is perceived as identical by the occupants of the vehicle.
Ainsi, la combinaison du film actif 5 et de la couche photochromique 8 assure que l'opacité du vitrage selon l'invention ne soit plus variable en fonction de la puissance de l'ensoleillement.  Thus, the combination of the active film 5 and the photochromic layer 8 ensures that the opacity of the glazing according to the invention is no longer variable as a function of the power of the sun.

Claims

REVENDICATIONS
1 . Vitrage de véhicule automobile comprenant deux feuilles de verre (2, 3) séparées par une couche intermédiaire de matière plastique transparente (4) et un film actif (5) pouvant être alimenté par une source d'énergie électrique pour pouvoir passer d'un état sensiblement opaque, lorsque ce film n'est pas alimenté à un état sensiblement transparent, lorsque ce film (5) est alimenté par ladite source d'énergie électrique, ce vitrage étant caractérisé en ce qu'il comporte en outre une couche passive photochromique (8) qui est apte à s'assombrir lorsque l'ensoleillement dépasse un seuil prédéterminé et provoque la diminution de l'opacité du vitrage. 1. Motor vehicle glazing comprising two glass sheets (2, 3) separated by an intermediate layer of transparent plastic material (4) and an active film (5) which can be powered by a source of electrical energy in order to be able to pass from a state substantially opaque, when this film is not fed to a substantially transparent state, when this film (5) is powered by said source of electrical energy, this glazing being characterized in that it further comprises a passive photochromic layer ( 8) which is able to darken when the sun exceeds a predetermined threshold and causes the reduction of the opacity of the glazing.
2. Vitrage selon la revendication 1 , caractérisé en ce qu'il est constitué par un vitrage de toit ou de pavillon d'un véhicule automobile.  2. Glazing according to claim 1, characterized in that it consists of a roof glazing or roof of a motor vehicle.
3. Vitrage selon l'une des revendications 1 ou 2, caractérisé en ce que ledit film actif opaque ou transparent (5) est noyé dans la couche de matière plastique transparente (4).  3. Glazing according to one of claims 1 or 2, characterized in that said active film opaque or transparent (5) is embedded in the transparent plastic layer (4).
4. Vitrage selon l'une des revendications 1 ou 2, caractérisé en ce que ledit film actif opaque ou transparent (5) est situé à l'interface entre l'une des feuilles de verre (2, 3) et la couche de matière plastique (4).  4. Glazing according to one of claims 1 or 2, characterized in that said active film opaque or transparent (5) is located at the interface between one of the glass sheets (2, 3) and the layer of material plastic (4).
5. Vitrage selon l'une des revendications 1 à 4, caractérisé en ce que le film actif (5) est composé de cristaux liquides comprenant des molécules dont les dipôles électriques peuvent être orientés grâce au champ électrique créé par le courant électrique fourni par ladite source.  5. Glazing according to one of claims 1 to 4, characterized in that the active film (5) is composed of liquid crystals comprising molecules whose electric dipoles can be oriented by the electric field created by the electric current supplied by said source.
6. Vitrage selon l'une des revendications 1 à 5, caractérisé en ce que la couche passive photochromique (8) est déposée sur la face de l'une des feuilles de verre (2, 3) adjacente à la couche intermédiaire de matière plastique (4).  6. Glazing according to one of claims 1 to 5, characterized in that the passive photochromic layer (8) is deposited on the face of one of the glass sheets (2, 3) adjacent to the intermediate layer of plastic material (4).
7. Vitrage selon la revendication 6, caractérisé en ce que la couche photochromique (8) est déposée sur la face de la feuille de verre (3) destinée à être dirigée vers l'intérieur du véhicule.  7. Glazing according to claim 6, characterized in that the photochromic layer (8) is deposited on the face of the glass sheet (3) intended to be directed towards the inside of the vehicle.
8. Vitrage selon l'une des revendications 1 à 5, caractérisé en ce que la couche passive photochromique (8) est constituée de pigments de composés photochromiques noyés dans la couche intermédiaire de matière plastique (4) ou dans le film actif opaque ou transparent (5). 8. Glazing according to one of claims 1 to 5, characterized in that the passive photochromic layer (8) consists of photochromic compound pigments embedded in the intermediate layer of plastic material (4) or in the opaque or transparent active film. (5).
9. Véhicule automobile équipé d'un vitrage selon l'une des revendications à 8. 9. Motor vehicle equipped with a glazing unit according to one of claims 8.
10. Véhicule automobile équipé d'un vitrage selon l'une des revendications à 8 et dépourvu de rideau d'occultation.  10. Motor vehicle equipped with a glazing according to one of claims 8 and without obscuration curtain.
PCT/FR2015/050152 2014-02-07 2015-01-22 Glazing for motor vehicle, comprising an opaque or transparent active film and a photochromic layer WO2015118242A1 (en)

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FR1450941 2014-02-07
FR1450941A FR3017331A1 (en) 2014-02-07 2014-02-07 GLAZING FOR MOTOR VEHICLE COMPRISING AN OPAQUE OR TRANSPARENT ACTIVE FILM AND A PHOTOCHROMIC LAYER

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CN110753618A (en) * 2017-03-30 2020-02-04 Agp美洲股份公司 Opaque laminated glass roof with panoramic glass appearance
WO2020212094A1 (en) * 2019-04-16 2020-10-22 Saint-Gobain Glass France Glazing unit and vehicle having same

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