WO2015099434A1 - Method for producing egg including gold nanoparticles using water containing gold nanoparticles - Google Patents
Method for producing egg including gold nanoparticles using water containing gold nanoparticles Download PDFInfo
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- WO2015099434A1 WO2015099434A1 PCT/KR2014/012771 KR2014012771W WO2015099434A1 WO 2015099434 A1 WO2015099434 A1 WO 2015099434A1 KR 2014012771 W KR2014012771 W KR 2014012771W WO 2015099434 A1 WO2015099434 A1 WO 2015099434A1
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- Prior art keywords
- gold nanoparticles
- water containing
- gold
- egg
- water
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 158
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 158
- 239000010931 gold Substances 0.000 title claims abstract description 158
- 239000002105 nanoparticle Substances 0.000 title claims abstract description 111
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 101
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 235000013601 eggs Nutrition 0.000 claims description 47
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 22
- 239000011593 sulfur Substances 0.000 claims description 22
- 229910052717 sulfur Inorganic materials 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 16
- 238000005507 spraying Methods 0.000 claims description 6
- 238000007865 diluting Methods 0.000 claims description 3
- 230000003628 erosive effect Effects 0.000 claims description 3
- 239000002245 particle Substances 0.000 abstract description 13
- 239000003651 drinking water Substances 0.000 abstract description 7
- 235000020188 drinking water Nutrition 0.000 abstract description 7
- 241000287828 Gallus gallus Species 0.000 description 27
- 235000013330 chicken meat Nutrition 0.000 description 27
- 239000007788 liquid Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 240000000560 Citrus x paradisi Species 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 206010061218 Inflammation Diseases 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- 241000219095 Vitis Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000036772 blood pressure Effects 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 238000012364 cultivation method Methods 0.000 description 1
- 206010012601 diabetes mellitus Diseases 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 230000008821 health effect Effects 0.000 description 1
- 239000006049 herbal material Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K45/00—Other aviculture appliances, e.g. devices for determining whether a bird is about to lay
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K31/00—Housing birds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K20/00—Accessory food factors for animal feeding-stuffs
- A23K20/20—Inorganic substances, e.g. oligoelements
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K29/00—Other apparatus for animal husbandry
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K50/00—Feeding-stuffs specially adapted for particular animals
- A23K50/70—Feeding-stuffs specially adapted for particular animals for birds
- A23K50/75—Feeding-stuffs specially adapted for particular animals for birds for poultry
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L15/00—Egg products; Preparation or treatment thereof
- A23L15/30—Addition of substances other than those covered by A23L15/20 – A23L15/25
Definitions
- the present invention relates to a method for producing an egg comprising gold nanoparticles using water containing gold nanoparticles, wherein the gold particles and water sprayed are worn together by strong water pressure, and the stored water
- the present invention relates to an egg manufacturing method including gold nanoparticles using water containing gold nanoparticles to allow gold nanoparticles to be contained in eggs that are ovulated in a chicken being bred in a breeding chicken.
- Prior art Republic of Korea Patent No. 10-897582 (2009.05.07) 'Gold nano-containing grape cultivation method and cultivated gold nano grapes' is a gold nano aqueous solution and sulfur aqueous solution in herbal fertilizer liquid containing herbal materials After preparing a herbal liquid ratio containing gold nanoparticles by mixing the water, the technique of the grape fruit to contain the gold component by irrigation of the prepared herbal liquid ratio to the vine.
- the grape fruit is limited in time of shipment depending on the season, there is a problem that the user is difficult to continuously consume, there is also a problem that is difficult to store or move due to the appearance of the grape fruit.
- Republic of Korea Patent Registration No. 10-0565013 (2006.03.22) of the prior art 'chicken feed to obtain the nutritional egg and its manufacturing method' includes the gold in the process of manufacturing the chicken feed to ingest the gold to chicken Combine various additives.
- the chicken feed is classified into chicken chicks, chicks, medium chicks, large chicks, early spawning chickens, late spawning chickens, medium chickens, late chickens, etc.
- the manufacturing process is complicated because the combination of the chicken feed according to various additives in various mixing ratios, thereby increasing the production cost.
- the present invention devised to solve the problems of the prior art as described above does not use any chemical compounds or methods such as electrolysis, and nanoparticles produced by eroding gold with strong water pressure sprayed from the injection nozzle of the injection means;
- the purpose is to store the water to erode gold and use it as drinking water for chickens.
- Another object of the present invention is to provide a chicken breeding method for laying eggs containing gold nanoparticles by using water containing gold nanoparticles as drinking water for chickens.
- the present invention is another object to provide an egg containing gold nanoparticles by producing an egg from chickens drinking water containing gold nanoparticles.
- the present invention can produce nano-sized gold particles by spraying pure water to pure gold, there is another object to solve the side effects caused by using other chemical methods.
- the above object of the present invention is a method for producing an egg using water containing gold nanoparticles generated by the erosion of gold by spraying pure water on gold and gold nanoparticles containing the injected pure water, wherein the gold nanoparticles
- a first step of ingesting water containing the hen to the hen and a second step of the hen to lay eggs, and the eggs that are laid contain gold nanoparticles, characterized in that it contains 0.50 ⁇ g / kg of gold. It is achieved by a method for producing eggs containing gold nanoparticles using water.
- the egg manufacturing method including the gold nanoparticles using water containing the gold nanoparticles of the present invention does not use any chemical compounds or electrolysis methods to produce gold nanoparticles does not cause environmental pollution It works.
- the present invention by using the water for producing gold nanoparticles and the gold nanoparticles produced through the use together as drinking water for chickens to be bred, so that no additional additives or compounds are included to produce eggs containing gold nanoparticles There are other effects that can lower costs.
- the present invention can lower the content of gold nanoparticles contained in the water provided as drinking water, because the water containing the gold nanoparticles that chickens ingest must be continuously consumed a predetermined amount or more daily as an essential element for maintaining life.
- the present invention can lower the content of gold nanoparticles contained in the water provided as drinking water, because the water containing the gold nanoparticles that chickens ingest must be continuously consumed a predetermined amount or more daily as an essential element for maintaining life.
- by allowing chickens to continuously absorb gold nanoparticles there is another effect that certain gold nanoparticles may be included in eggs produced daily.
- the present invention can generate nano-sized gold particles by spraying pure water to pure gold, there is another effect that can solve the side effects caused by using other chemical methods. .
- FIG. 1 is a flow chart for showing a method of manufacturing an egg according to the present invention
- Figure 2 is a micrograph 1 to show the size of the gold particles contained in the water containing gold nanoparticles according to the present invention
- Figure 3 is a micrograph 2 to show the size of the gold particles contained in the water containing gold nanoparticles according to the present invention
- Figure 4 is a micrograph 2 to show the size of the gold particles contained in the water containing gold nanoparticles according to the present invention
- Figure 6 is a test report measuring the gold content contained in eggs prepared using water containing gold nanoparticles according to the present invention.
- FIG. 1 is a flow chart illustrating a method of manufacturing an egg according to the present invention. As shown in Figure 1, by spraying high-pressure pure water to edible gold to store the gold nanoparticles and sprayed pure water generated by abrasion of gold by pure water (S110).
- the size of the gold nanoparticles sprayed by the high pressure pure water is worn to 59.5 nm, 63.5 nm, 65.5 nm, ..., 119 nm, etc. It is shown that, preferably gold nanoparticles of 40nm to 150nm size is included. On the other hand, as shown in Figure 5, it was analyzed that 1kg of pure water sprayed at high pressure to wear gold contains about 0.45mg of nano-sized gold.
- pure water sprayed at high pressure to wear gold contains gold nanoparticles of 0.25 mg / kg or more.
- sulfur is added to the water containing the stored gold nanoparticles (S120).
- Sulfur inhibits cholesterol, helps with diabetes and blood pressure, reduces free radicals, harmful substances, and is effective in removing inflammation and sterilizing. Accordingly, when the hens laying eggs are ingested with sulfur-containing water, sulfur is contained in the eggs to provide a variety of health effects to those who eat the eggs.
- the sulfur added to the water containing the gold nanoparticles preferably contains 1 g to 25 g in 1 kg of water containing the gold nanoparticles, and the hens bred by ingesting water containing the gold nanoparticles to which the sulfur is added. Eggs spawned in were found to contain 0.188 wt% sulfur, as shown in FIG. 6.
- pure water is added to the water containing the gold nanoparticles to which sulfur is added, thereby diluting the water containing the gold nanoparticles (S130).
- the chicken may be provided with water containing gold nanoparticles with sulfur added in step S120, but even if the chicken is ingested with a high content of gold nanoparticles and sulfur, it is discharged as feces and so on. Dilute to provide a lower concentration.
- the hens of the laying period provide the water containing the gold nanoparticles to drink 24 hours a day, so that the chicken can ingest the water containing the gold nanoparticles at any time, and the water intake period is 4 weeks or more. Intake period may vary depending on the amount of pure water diluted in step S130.
- eggs are spawned from hens who have consumed water containing gold nanoparticles for 4 weeks or more (S150).
- the amount of gold nanoparticles contained in eggs produced from hens ingested for 4 weeks or more of water containing gold nanoparticles is 0.5 ⁇ g / kg or more, and the amount of sulfur is included in 0.01 wt% or more.
- FIG. 2 is a first microscopic picture for showing the size of the gold particles contained in the water containing gold nanoparticles according to the present invention
- Figure 3 is a gold particle contained in the water containing gold nanoparticles according to the present invention
- the second microscopic picture for showing the size of and Figure 4 is a third microscopic picture for showing the size of the gold particles contained in the water containing gold nanoparticles according to the present invention.
- the gold particles for measurement is measured by collecting the remaining gold particles after evaporating the water containing the gold nanoparticles, the size of the gold particles in the measurement picture is 59.5 It is shown that it is formed in the magnitude
- the gold nanoparticles detected in the water containing the gold nanoparticles have a size of 40 nm to 150 nm.
- FIG. 5 is a test report measuring the gold content contained in the water containing gold nanoparticles according to the present invention. As shown in FIG. 5, the gold is eroded by spraying high-pressure pure water, thereby analyzing how much gold is substantially contained in the water containing the gold nanoparticles generated and the gold nanoparticles storing the injected pure water together. It is a resource. In the test report, the gold component in water containing gold nanoparticles was analyzed as 0.45 mg / kg.
- the gold nanoparticles detected in the water containing the gold nanoparticles are contained 0.25 mg / kg or more.
- Figure 6 is a test report measuring the gold content contained in eggs prepared using water containing gold nanoparticles according to the present invention. As shown in FIG. 6, it is data analyzing how substantially the gold component is contained in the eggs laid in hens bred using water containing sulfur and gold nanoparticles diluted with pure water. The results of the test report showed that the eggs contained in the chickens fed with water containing gold nanoparticles containing sulfur were 4.35 ⁇ g / kg and the sulfur contained 0.188% by weight of the eggs. .
- the gold component contained in eggs laid in hens fed with water containing gold nanoparticles to which sulfur was added is 0.50 ⁇ g / kg or more, and the sulfur component contains 0.01 wt% or more of the eggs.
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Environmental Sciences (AREA)
- Animal Husbandry (AREA)
- Birds (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Zoology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Feed For Specific Animals (AREA)
- Meat, Egg Or Seafood Products (AREA)
- Fodder In General (AREA)
Abstract
The present invention relates to a method for producing an egg including gold nanoparticles using water containing gold nanoparticles, and more specifically, to a method for producing an egg including gold nanoparticles using water containing gold nanoparticles, wherein gold particles, which are abraded by a strong water pressure, and sprayed water are stored together, and the stored water is supplied as drinking water for a hen bred in a henhouse, thereby allowing an egg ovulated in the bred hen to include gold nanoparticles. The method for producing an egg including gold nanoparticles using water containing gold nanoparticles of the present invention comprises: a first step of feeding a hen with water containing gold nanoparticles; and a second step of producing an egg by the hen, wherein the produced egg contains 0.50 ㎍/㎏ of gold.
Description
본 발명은 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법에 관한 것으로, 강한 수압에 의해 마모되는 금 입자와 분사된 물을 함께 저장하고, 저장된 물을 계사(鷄舍)에서 사육되는 닭의 음용수로 제공함에 따라 사육되는 닭에서 배란되는 달걀에 금 나노 입자가 포함되도록 하기 위한 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법에 관한 것이다.The present invention relates to a method for producing an egg comprising gold nanoparticles using water containing gold nanoparticles, wherein the gold particles and water sprayed are worn together by strong water pressure, and the stored water The present invention relates to an egg manufacturing method including gold nanoparticles using water containing gold nanoparticles to allow gold nanoparticles to be contained in eggs that are ovulated in a chicken being bred in a breeding chicken.
금이 신체에 흡수되는 경우, 해독 작용과 심신을 안정화시키는 작용을 하는 것으로 알려져 있다. 그러나, 금을 사람이 직접 식용으로 섭취하기에는 다소 거부감이 들기 때문에 다른 음식에 함유된 금을 간접적으로 섭취함으로써 사람의 거부감을 감소시키면서 보다 간편하게 섭취할 수 있는 방법이 개발되고 있다.When gold is absorbed into the body, it is known to act as a detoxifying and stabilizing mind and body. However, since gold is somewhat refusal to be consumed directly by humans, a method of inducing gold in other foods by indirectly reducing the objection of humans has been developed.
종래기술인 대한민국등록특허 제10-897582호(2009.05.07)의 '금 나노를 함유한 포도 재배방법 및 그에 의해 재배된 금 나노 포도'는 한방재료를 포함하는 한방비료액에 금 나노 수용액 및 유황 수용액을 혼합하여 금 나노를 함유한 한방액비를 제조한 후, 제조된 한방액비를 포도나무에 관수함으로써 포도과실이 금 성분을 함유하도록 하는 기술이다.Prior art Republic of Korea Patent No. 10-897582 (2009.05.07) 'Gold nano-containing grape cultivation method and cultivated gold nano grapes' is a gold nano aqueous solution and sulfur aqueous solution in herbal fertilizer liquid containing herbal materials After preparing a herbal liquid ratio containing gold nanoparticles by mixing the water, the technique of the grape fruit to contain the gold component by irrigation of the prepared herbal liquid ratio to the vine.
이러한 종래기술은 금이 포함된 한방액비를 포도나무에 관수함으로써, 포도나무가 금 성분을 흡수하는 양보다 토양에 잔존하게 되는 양이 더 많아 실용적이지 않은 문제점이 있다. This prior art has a problem that it is not practical because the amount of the remaining liquid in the soil than the amount of the vine absorbs the gold component by watering the herbal liquid ratio containing gold to the vine.
또한, 포도과실은 계절에 따라 출하 시기가 제한되어 있어, 사용자가 지속적으로 섭취하기 어려운 문제가 있고, 포도과실의 외형적인 특성상 보관이나 이동이 어려운 문제점도 있다.In addition, the grape fruit is limited in time of shipment depending on the season, there is a problem that the user is difficult to continuously consume, there is also a problem that is difficult to store or move due to the appearance of the grape fruit.
또한, 종래기술인 대한민국등록특허 제10-0565013호(2006.03.22)의 '영양란을 얻기 위한 닭 사료 및 그 제조 방법'은 황금을 닭에게 섭취시키기 위하여 닭의 사료를 제조하는 공정에서 황금을 포함하여 다양한 첨가물을 배합한다.In addition, the Republic of Korea Patent Registration No. 10-0565013 (2006.03.22) of the prior art 'chicken feed to obtain the nutritional egg and its manufacturing method' includes the gold in the process of manufacturing the chicken feed to ingest the gold to chicken Combine various additives.
그러나, 종래기술에 따르면 닭의 생육에 따라 어린 병아리, 병아리, 중 병아리, 큰 병아리, 산란 초기 닭, 산란 말기 닭, 중기 닭, 말기 닭 등으로 닭 사료를 분류하여 제조되고 있어, 닭의 생육에 따라 닭 사료를 바꿔줘야 하는 문제점이 있다. 또한, 다양한 첨가물을 다양한 배합비율에 따라 닭 사료를 배합하기 때문에 제조공정이 복잡해지고, 이에 따라 생산원가도 증가되는 문제점이 있다.However, according to the prior art, according to the growth of chickens, the chicken feed is classified into chicken chicks, chicks, medium chicks, large chicks, early spawning chickens, late spawning chickens, medium chickens, late chickens, etc. There is a problem to change the chicken feed accordingly. In addition, there is a problem in that the manufacturing process is complicated because the combination of the chicken feed according to various additives in various mixing ratios, thereby increasing the production cost.
상기와 같은 종래 기술의 문제점을 해결하기 위하여 안출된 본 발명은 화학 합성물 또는 전기분해 등의 방법을 전혀 사용하지 않으며, 분사수단의 분사노즐에서 분사되는 강한 수압으로 금을 침식시켜 생성된 나노 입자와 금을 침식시키기 위한 물을 함께 저장하여 닭의 음용수로 사용하기 위한 목적이 있다.The present invention devised to solve the problems of the prior art as described above does not use any chemical compounds or methods such as electrolysis, and nanoparticles produced by eroding gold with strong water pressure sprayed from the injection nozzle of the injection means; The purpose is to store the water to erode gold and use it as drinking water for chickens.
또한, 본 발명은 금 나노 입자를 함유하는 물을 닭의 음용수로 사용함으로써 금 나노 입자를 포함하는 달걀을 산란하는 닭의 사육 방법을 제공하기 위한 다른 목적이 있다.Another object of the present invention is to provide a chicken breeding method for laying eggs containing gold nanoparticles by using water containing gold nanoparticles as drinking water for chickens.
또한, 본 발명은 금 나노 입자를 함유하는 물을 음용한 닭에서 달걀을 생산함으로써, 금 나노 입자를 포함하는 달걀을 제공하기 위한 또 다른 목적이 있다.In addition, the present invention is another object to provide an egg containing gold nanoparticles by producing an egg from chickens drinking water containing gold nanoparticles.
또한, 본 발명은 순수한 금에 강한 순수를 분사함으로써, 나노 크기의 금 입자를 생성할 수 있어, 다른 화학적 방법을 사용함으로써 발생하는 부작용을 해결하기 위한 또 다른 목적이 있다.In addition, the present invention can produce nano-sized gold particles by spraying pure water to pure gold, there is another object to solve the side effects caused by using other chemical methods.
본 발명의 상기 목적은 금에 순수를 분사하여 금의 침식작용에 의해 생성되는 금 나노 입자와 분사된 순수가 포함된 금 나노 입자를 함유한 물을 사용하는 달걀 제조방법에 있어서, 상기 금 나노 입자를 함유한 물을 암닭에게 섭취시키는 제1 단계 및 상기 암닭이 달걀을 산란하는 제2 단계를 포함하며, 산란된 상기 달걀은 0.50 ㎍/㎏의 금을 함유하는 것을 특징으로 하는 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법에 의해 달성된다.The above object of the present invention is a method for producing an egg using water containing gold nanoparticles generated by the erosion of gold by spraying pure water on gold and gold nanoparticles containing the injected pure water, wherein the gold nanoparticles A first step of ingesting water containing the hen to the hen and a second step of the hen to lay eggs, and the eggs that are laid contain gold nanoparticles, characterized in that it contains 0.50 μg / kg of gold. It is achieved by a method for producing eggs containing gold nanoparticles using water.
따라서, 본 발명의 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법은 금 나노 입자를 제조함에 있어서 화학 합성물 또는 전기분해 등의 방법을 전혀 사용하지 않아 환경 오염을 유발하지 않는 효과가 있다.Therefore, the egg manufacturing method including the gold nanoparticles using water containing the gold nanoparticles of the present invention does not use any chemical compounds or electrolysis methods to produce gold nanoparticles does not cause environmental pollution It works.
또한, 본 발명은 금 나노 입자를 생성하기 위한 물과 이를 통해 생성된 금 나노 입자를 함께 저장하여 사육되는 닭의 음용수로 사용함으로써 별도의 첨가물이나 합성물이 포함되지 않으므로 금 나노 입자를 포함하는 달걀 생산비용을 낮출 수 있는 다른 효과가 있다.In addition, the present invention by using the water for producing gold nanoparticles and the gold nanoparticles produced through the use together as drinking water for chickens to be bred, so that no additional additives or compounds are included to produce eggs containing gold nanoparticles There are other effects that can lower costs.
또한, 본 발명은 닭이 섭취하는 금 나노 입자를 함유하는 물은 생명유지에 필수 요소로써 매일 소정량 이상을 지속적으로 섭취해야함으로 음용수로 제공되는 물에 포함된 금 나노 입자의 함유량을 낮출 수 있으며, 닭으로 하여금 금 나노 입자를 지속적으로 흡수하도록 함으로써 매일 생산되는 달걀에 일정한 금 나노 입자가 포함될 수 있는 또 다른 효과가 있다.In addition, the present invention can lower the content of gold nanoparticles contained in the water provided as drinking water, because the water containing the gold nanoparticles that chickens ingest must be continuously consumed a predetermined amount or more daily as an essential element for maintaining life. In addition, by allowing chickens to continuously absorb gold nanoparticles, there is another effect that certain gold nanoparticles may be included in eggs produced daily.
또한, 본 발명은 순수한 금에 강한 순수를 분사함으로써, 나노 크기의 금 입자를 생성할 수 있어, 다른 화학적 방법을 사용함으로써 발생하는 부작용을 해결할 있는 또 다른 효과가 있다.하기 위한 또 다른 목적이 있다.In addition, the present invention can generate nano-sized gold particles by spraying pure water to pure gold, there is another effect that can solve the side effects caused by using other chemical methods. .
도 1은 본 발명에 따른 달걀의 제조방법을 나타내기 위한 순서도, 1 is a flow chart for showing a method of manufacturing an egg according to the present invention,
도 2는 본 발명에 따른 금 나노 입자를 함유하는 물에 포함된 금 입자의 크기를 나타내기 위한 현미경 사진 1, Figure 2 is a micrograph 1 to show the size of the gold particles contained in the water containing gold nanoparticles according to the present invention,
도 3은 본 발명에 따른 금 나노 입자를 함유하는 물에 포함된 금 입자의 크기를 나타내기 위한 현미경 사진 2, Figure 3 is a micrograph 2 to show the size of the gold particles contained in the water containing gold nanoparticles according to the present invention,
도 4는 본 발명에 따른 금 나노 입자를 함유하는 물에 포함된 금 입자의 크기를 나타내기 위한 현미경 사진 2, Figure 4 is a micrograph 2 to show the size of the gold particles contained in the water containing gold nanoparticles according to the present invention,
도 5는 본 발명에 따른 금 나노 입자를 함유하는 물에 포함된 금 함유량을 측정한 시험성적서, 5 is a test report measuring the gold content contained in the water containing gold nanoparticles according to the present invention,
도 6은 본 발명에 따른 금 나노 입자를 함유한 물을 이용하여 제조된 달걀에 포함된 금 함유량을 측정한 시험성적서이다.Figure 6 is a test report measuring the gold content contained in eggs prepared using water containing gold nanoparticles according to the present invention.
본 명세서 및 청구범위에 사용된 용어나 단어는 통상적이거나 사전적인 의미로 한정해서 해석되어서는 아니되며, 발명자는 그 자신의 발명을 가장 최선의 방법으로 설명하기 위해 용어의 개념을 적절하게 정의할 수 있다는 원칙에 입각하여 본 발명의 기술적 사상에 부합하는 의미와 개념으로 해석되어야만 한다.The terms or words used in this specification and claims are not to be construed as being limited to their ordinary or dictionary meanings, and the inventors may appropriately define the concept of terms in order to best describe their invention. It should be interpreted as meaning and concept corresponding to the technical idea of the present invention based on the principle that the present invention.
따라서, 본 명세서에 기재된 실시예와 도면에 도시된 구성은 본 발명의 가장 바람직한 일 실시예에 불과할 뿐이고 본 발명의 기술적 사상을 모두 대변하는 것은 아니므로, 본 출원시점에 있어서 이들을 대체할 수 있는 다양한 균등물과 변형예들이 있을 수 있음을 이해하여야 한다.Therefore, the embodiments described in the specification and the drawings shown in the drawings are only the most preferred embodiment of the present invention and do not represent all of the technical idea of the present invention, various modifications that can be replaced at the time of the present application It should be understood that there may be equivalents and variations.
이하 첨부된 도면을 참조하여 본 발명의 바람직한 실시예를 상세히 설명하기로 한다. Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.
도 1은 본 발명에 따른 달걀의 제조방법을 나타내기 위한 순서도이다. 도 1에 도시된 바와 같이, 식용이 가능한 금에 고압의 순수를 분사하여 순수에 의해 금을 마모시킴으로써 발생하는 금 나노 입자와 분사된 순수를 함께 저장한다(S110).1 is a flow chart illustrating a method of manufacturing an egg according to the present invention. As shown in Figure 1, by spraying high-pressure pure water to edible gold to store the gold nanoparticles and sprayed pure water generated by abrasion of gold by pure water (S110).
즉, 금에 순수를 분사하면 금 표면이 고압의 순수에 의해 나노 입자 크기로 마모되며, 그로 인해 생성된 금 나노 입자는 분사된 순수에 포함되어 있다. 따라서 금 나노 입자를 함유한 물을 저장하여 사육되는 닭의 음용수로 제공할 수 있다.That is, when pure water is sprayed on gold, the surface of the gold is abraded to nanoparticle size by high pressure pure water, and the resulting gold nanoparticles are included in the sprayed pure water. Therefore, water containing gold nanoparticles can be stored and provided as drinking water for chickens.
고압의 순수에 의해 분사되는 금 나노 입자의 크기는 도 2 내지 도 5에 도시된 바와 같이, 59.5㎚, 63.5㎚, 65.5㎚, ..., 119㎚ 등의 크기로 마모되어 순수에 포함되어 있는 것으로 나타나며, 바람직하게는 40㎚ 내지 150㎚ 크기의 금 나노 입자가 포함된다. 한편, 도 5에 도시된 바와 같이, 고압으로 분사되어 금을 마모시킨 순수 1㎏에는 나노 크기의 금이 약 0.45㎎ 포함되어 있는 것으로 분석되었다.As shown in FIGS. 2 to 5, the size of the gold nanoparticles sprayed by the high pressure pure water is worn to 59.5 nm, 63.5 nm, 65.5 nm, ..., 119 nm, etc. It is shown that, preferably gold nanoparticles of 40nm to 150nm size is included. On the other hand, as shown in Figure 5, it was analyzed that 1kg of pure water sprayed at high pressure to wear gold contains about 0.45mg of nano-sized gold.
따라서, 고압으로 분사되어 금을 마모시킨 순수에는 0.25 ㎎/㎏ 이상의 금 나노 입자를 포함한다.Therefore, pure water sprayed at high pressure to wear gold contains gold nanoparticles of 0.25 mg / kg or more.
다음으로 저장된 금 나노 입자를 함유한 물에 유황을 첨가한다(S120). 유황은 콜레스테롤을 억제하고 당뇨, 혈압에 도움을 주며, 유해물질인 활성산소를 감소시키며, 염증제거 및 살균작용에도 효과가 있는 것으로 나타났다. 이에 따라 달걀을 산란하는 암닭에게 유황이 함유된 물을 섭취하도록 하면, 달걀 내에 유황 성분이 포함되어 해당 달걀을 섭취하는 사람에게 다양한 건강상의 효과를 제공한다.Next, sulfur is added to the water containing the stored gold nanoparticles (S120). Sulfur inhibits cholesterol, helps with diabetes and blood pressure, reduces free radicals, harmful substances, and is effective in removing inflammation and sterilizing. Accordingly, when the hens laying eggs are ingested with sulfur-containing water, sulfur is contained in the eggs to provide a variety of health effects to those who eat the eggs.
금 나노 입자를 함유한 물에 첨가되는 유황은 금 나노 입자를 함유한 물 1㎏에 1g 내지 25g을 포함하는 것이 바람직하며, 이러한 유황이 첨가된 금 나노 입자를 함유한 물을 섭취하여 사육된 암닭에게서 산란된 달걀은 도 6에 도시된 바와 같이, 0.188 중량%의 유황을 함유하는 것으로 나타났다.The sulfur added to the water containing the gold nanoparticles preferably contains 1 g to 25 g in 1 kg of water containing the gold nanoparticles, and the hens bred by ingesting water containing the gold nanoparticles to which the sulfur is added. Eggs spawned in were found to contain 0.188 wt% sulfur, as shown in FIG. 6.
한편, 유황이 첨가된 금 나노 입자를 함유한 물에 순수를 첨가함으로써, 금 나노 입자를 함유한 물을 희석한다(S130). S120 단계에서의 유황이 첨가된 금 나노 입자를 함유한 물을 닭에게 제공하여도 무방하지만, 금 나노 입자 및 유황을 높은 함유량으로 닭이 섭취하도록 하여도, 배설물 등으로 배출되기 때문에 일정량 이상의 순수를 희석하여 농도를 낮추어 제공한다.On the other hand, pure water is added to the water containing the gold nanoparticles to which sulfur is added, thereby diluting the water containing the gold nanoparticles (S130). The chicken may be provided with water containing gold nanoparticles with sulfur added in step S120, but even if the chicken is ingested with a high content of gold nanoparticles and sulfur, it is discharged as feces and so on. Dilute to provide a lower concentration.
따라서, 금 나노 입자를 함유한 물의 0.5배 이상의 순수를 첨가하여 희석한다. 희석되는 순수의 양에 따라 닭에게 금 나노 입자를 함유한 물을 제공하는 기간을 변경할 수 있다.Therefore, 0.5 times or more pure water of water containing gold nanoparticles is added and diluted. Depending on the amount of pure water to be diluted, the time period for providing the chicken with water containing gold nanoparticles can be changed.
이후, 유황이 첨가되고, 순수가 희석된 금 나노 입자를 함유한 물을 산란기의 암닭에게 4주 이상 섭취하도록 한다(S140).Thereafter, sulfur is added and water containing gold nanoparticles in which pure water is diluted is consumed by the hens of the laying season for at least 4 weeks (S140).
이때, 산란기의 암닭은 금 나노 입자를 함유한 물을 하루 24시간 음용할 수 있도록 제공함으로써, 언제든지 금 나노 입자를 함유한 물을 닭이 섭취할 수 있도록 하며, 물을 섭취하는 기간은 4주 이상이나 S130 단계에서 희석되는 순수의 양에 따라 섭취 기간은 상이할 수 있다.In this case, the hens of the laying period provide the water containing the gold nanoparticles to drink 24 hours a day, so that the chicken can ingest the water containing the gold nanoparticles at any time, and the water intake period is 4 weeks or more. Intake period may vary depending on the amount of pure water diluted in step S130.
다음으로 금 나노 입자를 함유한 물을 4주 이상 섭취한 암닭에게서 달걀을 산란시키다(S150).Next, eggs are spawned from hens who have consumed water containing gold nanoparticles for 4 weeks or more (S150).
금 나노 입자를 함유한 물을 4주 이상 섭취한 암닭에게서 생산되는 달걀은 도 6에 도시된 바와 같이, 4.35 ㎍/㎏의 금이 함유된 것으로 분석되었으며, 달걀 무게에서 0.188 중량% 이상의 유황이 함유된 것으로 분석되었다.Eggs produced from hens who consumed water containing gold nanoparticles for 4 weeks or more were analyzed to contain 4.35 μg / kg of gold, as shown in FIG. 6, and contained more than 0.188% by weight of sulfur in egg weight. Was analyzed.
따라서, 금 나노 입자를 함유한 물을 4주 이상 섭취한 암닭에게서 생산되는 달걀에 함유된 금 나노 입자의 양은 0.5 ㎍/㎏ 이상이며, 유황의 양은 0.01 중량% 이상으로 포함된다.Therefore, the amount of gold nanoparticles contained in eggs produced from hens ingested for 4 weeks or more of water containing gold nanoparticles is 0.5 µg / kg or more, and the amount of sulfur is included in 0.01 wt% or more.
도 2는 본 발명에 따른 금 나노 입자를 함유하는 물에 포함된 금 입자의 크기를 나타내기 위한 제1 현미경 측정사진, 도 3은 본 발명에 따른 금 나노 입자를 함유하는 물에 포함된 금 입자의 크기를 나타내기 위한 제2 현미경 측정사진 및 도 4는 본 발명에 따른 금 나노 입자를 함유하는 물에 포함된 금 입자의 크기를 나타내기 위한 제3 현미경 측정사진이다. 도 2 내지 도 4에 도시된 바와 같이, 측정을 위한 금 입자는 금 나노 입자를 함유한 물을 증발시킨 후, 남은 금 입자를 취합하여 측정한 것으로써, 측정사진에서의 금 입자의 크기는 59.5㎚ 내지 119㎚의 크기로 형성되어 있는 것으로 나타난다.2 is a first microscopic picture for showing the size of the gold particles contained in the water containing gold nanoparticles according to the present invention, Figure 3 is a gold particle contained in the water containing gold nanoparticles according to the present invention The second microscopic picture for showing the size of and Figure 4 is a third microscopic picture for showing the size of the gold particles contained in the water containing gold nanoparticles according to the present invention. As shown in Figures 2 to 4, the gold particles for measurement is measured by collecting the remaining gold particles after evaporating the water containing the gold nanoparticles, the size of the gold particles in the measurement picture is 59.5 It is shown that it is formed in the magnitude | size of nm-119 nm.
따라서, 금 나노 입자를 함유한 물에서 검출되는 금 나노 입자는 40㎚ 내지 150㎚의 크기이다.Therefore, the gold nanoparticles detected in the water containing the gold nanoparticles have a size of 40 nm to 150 nm.
도 5는 본 발명에 따른 금 나노 입자를 함유하는 물에 포함된 금 함유량을 측정한 시험성적서이다. 도 5에 도시된 바와 같이, 금을 고압의 순수를 분사하여 침식시킴으로써, 생성되는 금 나노 입자와 분사된 순수를 함께 저장한 금 나노 입자를 함유한 물에서 실질적으로 금 성분이 얼마나 포함되어 있는지 분석한 자료이다. 시험성적서 결과에서는 금 나노 입자를 함유한 물에 포함된 금 성분은 0.45 ㎎/㎏으로 분석되었다.5 is a test report measuring the gold content contained in the water containing gold nanoparticles according to the present invention. As shown in FIG. 5, the gold is eroded by spraying high-pressure pure water, thereby analyzing how much gold is substantially contained in the water containing the gold nanoparticles generated and the gold nanoparticles storing the injected pure water together. It is a resource. In the test report, the gold component in water containing gold nanoparticles was analyzed as 0.45 mg / kg.
따라서, 금 나노 입자를 함유한 물에서 검출되는 금 나노 입자는 0.25 ㎎/㎏ 이상 포함된다.Therefore, the gold nanoparticles detected in the water containing the gold nanoparticles are contained 0.25 mg / kg or more.
도 6은 본 발명에 따른 금 나노 입자를 함유한 물을 이용하여 제조된 달걀에 포함된 금 함유량을 측정한 시험성적서이다. 도 6에 도시된 바와 같이, 유황을 첨가하고, 순수를 희석한 금 나노 입자를 함유한 물을 이용하여 사육한 암닭에서 산란된 달걀에 실질적으로 금 성분이 얼마나 포함되어 있는지 분석한 자료이다. 시험성적서 결과에서는 유황이 첨가된 금 나노 입자를 함유한 물을 섭취하여 사육된 암닭에서 산란된 달걀에 포함된 금 성분은 4.35 ㎍/㎏이며, 유황 성분은 달걀의 0.188 중량% 포함된 것으로 분석되었다.Figure 6 is a test report measuring the gold content contained in eggs prepared using water containing gold nanoparticles according to the present invention. As shown in FIG. 6, it is data analyzing how substantially the gold component is contained in the eggs laid in hens bred using water containing sulfur and gold nanoparticles diluted with pure water. The results of the test report showed that the eggs contained in the chickens fed with water containing gold nanoparticles containing sulfur were 4.35 ㎍ / kg and the sulfur contained 0.188% by weight of the eggs. .
따라서, 유황이 첨가된 금 나노 입자를 함유한 물을 섭취하여 사육된 암닭에서 산란된 달걀에 포함된 금 성분은 0.50 ㎍/㎏ 이상이며, 유황 성분은 달걀의 0.01 중량% 이상 포함된다.Therefore, the gold component contained in eggs laid in hens fed with water containing gold nanoparticles to which sulfur was added is 0.50 µg / kg or more, and the sulfur component contains 0.01 wt% or more of the eggs.
본 발명은 이상에서 살펴본 바와 같이 바람직한 실시예를 들어 도시하고 설명하였으나, 상기한 실시예에 한정되지 아니하며 본 발명의 정신을 벗어나지 않는 범위 내에서 당해 발명이 속하는 기술분야에서 통상의 지식을 가진 자에 의해 다양한 변경과 수정이 가능할 것이다.Although the present invention has been shown and described with reference to the preferred embodiments as described above, it is not limited to the above embodiments and those skilled in the art without departing from the spirit of the present invention. Various changes and modifications will be possible.
Claims (8)
- 금에 순수를 분사하여 금의 침식작용에 의해 생성되는 금 나노 입자와 분사된 순수가 포함된 금 나노 입자를 함유한 물을 사용하는 달걀 제조방법에 있어서, In the egg production method using water containing gold nanoparticles generated by gold erosion by spraying pure water on gold and gold nanoparticles containing the injected pure water,상기 금 나노 입자를 함유한 물을 암닭에게 섭취시키는 제1 단계; 및 A first step of ingesting the water containing the gold nanoparticles to the hen; And상기 암닭이 달걀을 산란하는 제2 단계A second step in which the hen lays eggs를 포함하며, 산란된 상기 달걀은 0.50 ㎍/㎏의 금을 함유하는 것을 특징으로 하는 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법.It includes, the egg is egg production method comprising gold nanoparticles using water containing gold nanoparticles, characterized in that the egg contains 0.50 μg / kg of gold.
- 제 1 항에 있어서, The method of claim 1,상기 금 나노 입자를 함유한 물은 상기 암닭에게 하루 24시간 음용할 수 있도록 제공하는 것을 특징으로 하는 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법.The water containing the gold nanoparticles is a method of producing an egg comprising gold nanoparticles using water containing gold nanoparticles, characterized in that to provide the hen to drink 24 hours a day.
- 제 1 항에 있어서, The method of claim 1,상기 달걀은 산란기의 상기 암닭에게 상기 금 나노 입자를 함유한 물을 4주 이상 섭취하도록 하여 제조되는 것을 특징으로 하는 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법.The egg is a method of producing an egg comprising gold nanoparticles using water containing gold nanoparticles, characterized in that the hens in the egg is prepared by taking the water containing the gold nanoparticles more than 4 weeks.
- 제 1 항에 있어서, The method of claim 1,상기 금 나노 입자를 함유한 물은 0.25 ㎎/㎏ 이상의 금 나노 입자를 포함하는 것을 특징으로 하는 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법.The water containing the gold nanoparticles is a method of producing an egg comprising gold nanoparticles using water containing gold nanoparticles, characterized in that it comprises a gold nanoparticles of 0.25 mg / kg or more.
- 제 4 항에 있어서, The method of claim 4, wherein상기 금 나노 입자는 40㎚ 내지 150㎚의 크기인 것을 특징으로 하는 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법.The gold nanoparticles are egg manufacturing method comprising gold nanoparticles using water containing gold nanoparticles, characterized in that the size of 40nm to 150nm.
- 제 1 항에 있어서, The method of claim 1,상기 제1 단계 이전에Before the first step상기 금 나노 입자를 함유한 물에 0.5배 이상의 순수를 희석하는 것을 특징으로 하는 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법.Egg production method comprising gold nanoparticles using water containing gold nanoparticles, characterized in that diluting 0.5 times or more pure water in the water containing the gold nanoparticles.
- 제 6 항에 있어서, The method of claim 6,상기 순수를 희석하기 이전에 1 내지 25 g/㎏의 유황을 상기 금 나노 입자를 함유한 물에 첨가하는 것을 특징으로 하는 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법.1 to 25 g / kg of sulfur is added to the water containing the gold nanoparticles before diluting the pure water, wherein the egg production method comprising gold nanoparticles using water containing gold nanoparticles.
- 제 7 항에 있어서, The method of claim 7, wherein상기 유황이 첨가된 상기 금 나노 입자를 함유한 물을 섭취한 상기 암닭이 산란한 상기 달걀은 0.01 중량% 이상의 상기 유황을 함유하는 것을 특징으로 하는 금 나노 입자를 함유하는 물을 이용한 금 나노 입자를 포함하는 달걀 제조방법.The egg in which the hens ingested the water containing the gold nanoparticles to which the sulfur is added, the egg contains gold nanoparticles using water containing gold nanoparticles, characterized in that it contains 0.01% by weight or more of the sulfur. Egg manufacturing method comprising.
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| KR20060085777A (en) * | 2005-01-25 | 2006-07-28 | 주식회사 이노바이오 | Additives containing nano type silver for feed and process for preparing it |
| KR20060112083A (en) * | 2005-04-26 | 2006-10-31 | 권석은 | Nutrition solution containing methyl sulfonyl methane, the method of manufacturing the same, the method of raising chicken by feeding the same, the chicken by the method, and egg containing methyl sulfonyl methane |
| KR100890245B1 (en) * | 2007-11-23 | 2009-03-24 | (주)하이드로 비티 | Drinking water composition for poultry farming and preparation method thereof |
| KR20110043394A (en) * | 2010-02-08 | 2011-04-27 | 엄기만 | An egg comprising gold and a manufacturing mehtods thereof |
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| CA3182519A1 (en) * | 2011-04-29 | 2012-11-01 | Selecta Biosciences, Inc. | Tolerogenic synthetic nanocarriers for antigen-specific deletion of t effector cells |
| CN102283173B (en) * | 2011-09-21 | 2013-08-14 | 福建省新闽科生物科技开发有限公司 | Production method of eggs with high immune globulin content |
| CN103357886B (en) * | 2013-06-28 | 2016-09-07 | 上海纳米技术及应用国家工程研究中心有限公司 | A kind of preparation method of the noble metal nano cluster for fluorescent optical sensor |
| CN103737017B (en) * | 2014-01-14 | 2016-06-22 | 山西大学 | A kind of preparation method of Fluorescence gold nanoparticle |
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| KR20060085777A (en) * | 2005-01-25 | 2006-07-28 | 주식회사 이노바이오 | Additives containing nano type silver for feed and process for preparing it |
| KR20060112083A (en) * | 2005-04-26 | 2006-10-31 | 권석은 | Nutrition solution containing methyl sulfonyl methane, the method of manufacturing the same, the method of raising chicken by feeding the same, the chicken by the method, and egg containing methyl sulfonyl methane |
| KR100890245B1 (en) * | 2007-11-23 | 2009-03-24 | (주)하이드로 비티 | Drinking water composition for poultry farming and preparation method thereof |
| KR20110043394A (en) * | 2010-02-08 | 2011-04-27 | 엄기만 | An egg comprising gold and a manufacturing mehtods thereof |
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