WO2015099222A1 - Hot-rolled steel plate having excellent welding property and burring property and method for manufacturing same - Google Patents

Hot-rolled steel plate having excellent welding property and burring property and method for manufacturing same Download PDF

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WO2015099222A1
WO2015099222A1 PCT/KR2013/012166 KR2013012166W WO2015099222A1 WO 2015099222 A1 WO2015099222 A1 WO 2015099222A1 KR 2013012166 W KR2013012166 W KR 2013012166W WO 2015099222 A1 WO2015099222 A1 WO 2015099222A1
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steel sheet
hot
weight
rolled steel
property
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PCT/KR2013/012166
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French (fr)
Korean (ko)
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서석종
김성일
주세돈
조원태
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주식회사 포스코
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Priority to CN201380081907.9A priority Critical patent/CN105849295B/en
Priority to PCT/KR2013/012166 priority patent/WO2015099222A1/en
Priority to JP2016543061A priority patent/JP6368785B2/en
Publication of WO2015099222A1 publication Critical patent/WO2015099222A1/en

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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips

Definitions

  • the present invention relates to a hot rolled steel sheet excellent in weldability and burring properties and a method of manufacturing the same.
  • High-strength steel is a cost-effective material for realizing these conflicting demands, and its application is expected to increase over time to meet increasingly stringent regulations. In particular, as interest in collision safety increases, its role is increasing.
  • the strength of the welded part when it is molded or when it is assembled and used as a part is very important from the viewpoint of molding limit and safety. Therefore, in the application of a high strength steel sheet to automobile parts and the like, the strength of the welded part also becomes an important examination subject along with its burring workability.
  • Patent Literature 1 proposes a technique for improving the elongation flangeability by forming ferrite-bainite structure by using three-stage cooling after cooling to a temperature around 700 ° C. after hot rolling, followed by air cooling for a predetermined time, and then cooling and winding again. .
  • the ferrite-bainite structure is controlled so that the ferrite ratio is 80% or more, and the ratio of the crystal grains having a short diameter (ds) and a long diameter (dl) of 0.1 is 80% or more.
  • a technique for producing a hot rolled steel sheet having strength of more than 69 kg / cm 2 and excellent in elongation and stretch flangeability is proposed.
  • the above technique mainly uses the alloying components of Si, Mn, Al, Mo, etc. to manufacture the abnormal composite tissue steel of ferrite-bainite, and such alloying components increase resistance by increasing electrical resistance during electrical resistance welding. There is a problem that the heat generation is severe, or cold welding occurs when the operation lowers the input current value. In addition, Si, Mn, Al and the like to form an oxide during welding, there is a problem of reducing the integrity of the weld.
  • Patent Document 1 Japanese Unexamined Patent Application Publication No. 6-293910
  • Patent Document 2 Korean Patent Publication No. 2003-0055339
  • One aspect of the present invention is to provide a hot rolled steel sheet excellent in electrical resistance weldability and easy welding work, excellent burring properties and a method of manufacturing the same.
  • One aspect of the present invention is a weight%, C: 0.03 ⁇ 0.1%, Si: 0.01 ⁇ 1.2%, Mn: 1.2 ⁇ 1.9%, Al: 0.01 ⁇ 0.08%, Cr: 0.005 ⁇ 0.8%, Mo: 0.01 ⁇ 0.12 %, P: 0.01% to 0.05%, S: 0.001% to 0.005%, N: 0.001% to 0.01%, the balance Fe and other unavoidable impurities, and each of the above components satisfy the following Equation 1, and the tensile strength and elongation plan Provided is a hot rolled steel sheet excellent in weldability and burring property of multiplying 48000 or more.
  • Equation 1 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ⁇ 11.1
  • Equation 1 C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V represent the content (weight%) of the corresponding element, respectively.
  • Another aspect of the present invention is a method for producing a hot rolled steel sheet having excellent weldability and burring property, in weight%, C: 0.03 to 0.1%, Si: 0.01 to 1.2%, Mn: 1.2 to 1.9%, Al: 0.01 to 0.08% , Cr: 0.005 to 0.8%, Mo: 0.01 to 0.12%, P: 0.01 to 0.05%, S: 0.001 to 0.005%, N: 0.001 to 0.01%, balance Fe and other unavoidable impurities
  • Preparing a steel slab satisfying Equation 1 below reheating the steel slab at 1200 to 1300 ° C., and hot rolling the reheated steel slab to a finish rolling temperature of 850 to 1000 ° C. to obtain a steel sheet.
  • Equation 1 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ⁇ 11.1
  • Equation 1 C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V represent the content (weight%) of the corresponding element, respectively.
  • the product of tensile strength and extension flange is 48000 or more, and the integrity of the welded portion is improved during welding, thereby ensuring a hot rolled steel sheet excellent in weldability and burring property.
  • FIG. 1 is a graph showing a value obtained by substituting the product of the tensile strength (TS) and the elongation flange property (HER) of all the steels of the examples and the formula (1).
  • the present inventors have conducted research to develop a hot rolled steel sheet capable of overcoming the problems that the above-described technologies have not solved. As a result, the hot rolled steel sheet having excellent weldability and burring property can be produced by controlling the composition, microstructure, and processing conditions of the steel. The present invention was confirmed.
  • One aspect of the present invention is a weight%, C: 0.03 ⁇ 0.1%, Si: 0.01 ⁇ 1.2%, Mn: 1.2 ⁇ 1.9%, Al: 0.01 ⁇ 0.08%, Cr: 0.005 ⁇ 0.8%, Mo: 0.01 ⁇ 0.12 %, P: 0.01% to 0.05%, S: 0.001% to 0.005%, N: 0.001% to 0.01%, the balance Fe and other unavoidable impurities, and each of the above components satisfy the following Equation 1, and the tensile strength and elongation plan Provides hot-rolled steel sheet with excellent weldability and burring property of multiplying 48000 or more.
  • Equation 1 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ⁇ 11.1
  • Equation 1 C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V represent the content (weight%) of the corresponding element, respectively.
  • C is the most economical and effective element for strengthening steel. As the amount of carbon added increases, the martensite fraction of the ferritic-martensitic composite steel increases and the tensile strength increases. If the carbon content is less than 0.03% by weight, it is not easy to form martensite phase during cooling after hot rolling. On the other hand, when the carbon content exceeds 0.1% by weight, there is a problem in that excessive strength increase and weldability, formability and toughness are reduced. Therefore, the content of C is preferably contained in 0.03 ⁇ 0.1% by weight.
  • Si deoxidizes molten steel and has a solid solution strengthening effect.
  • a ferrite stabilizing element it has an effect of promoting ferrite transformation during cooling after hot rolling, and is an effective element for increasing the ferrite fraction constituting the matrix of ferritic martensite composite steel.
  • the content of the silicon is less than 0.01% by weight, the ferrite stabilization effect is small, making it difficult to make the matrix into a ferrite structure.
  • the silicon content exceeds 1.2% by weight red scales formed by Si are formed on the surface of the steel sheet during hot rolling, so that the surface quality of the steel sheet is not very bad, and the ductility and weldability are also reduced. Therefore, the content of the silicon is preferably contained in 0.01 to 1.2% by weight.
  • Mn is an effective element to solidify steel and increases the hardenability of steel to facilitate the formation of bainite phase during cooling after hot rolling.
  • the content of the manganese exceeds 1.9% by weight excessively delay the ferrite transformation is difficult to secure the appropriate fraction of the ferrite known matrix.
  • the segregation part in the thickness center during the slab casting in the playing process greatly develops, which impairs the weldability of the final product. Therefore, the content of Mn is preferably contained in 1.2 to 1.9% by weight.
  • Al is a component mainly added for deoxidation, and is a ferrite stabilizing element, and has an effect of helping to form a ferrite phase in steel during cooling after hot rolling.
  • the content of aluminum is less than 0.01% by weight, it is impossible to secure the effect intended for the present invention.
  • the content of aluminum exceeds 0.08% by weight, defects such as corner cracks are easily generated in the slab during continuous casting, and surface defects occur after hot rolling, thereby deteriorating surface quality. Therefore, the content of aluminum is preferably contained in 0.01 to 0.08% by weight.
  • Cr hardens the steel and assists bainite formation by retarding ferrite phase transformation during cooling.
  • the content of Cr is preferably contained in 0.005 ⁇ 0.8% by weight.
  • Mo has the effect of increasing the hardenability of the steel to facilitate the formation of bainite structure. In order to exhibit such an effect of the present invention, it is preferable that 0.01 wt% or more is included. On the other hand, when the content of molybdenum exceeds 0.12% by weight, the weldability is deteriorated due to excessive increase in hardenability, which is also economically disadvantageous. Therefore, the content of Mo is preferably contained in 0.01 to 0.12% by weight.
  • Phosphorus (P) 0.01% to 0.05% by weight
  • the P like Si, has the effect of strengthening solid solution and promoting ferrite transformation. If the content of phosphorus is less than 0.01% by weight is insufficient to obtain the strength to be secured by the present invention. On the other hand, when the content of phosphorus exceeds 0.05% by weight, ductility is lowered due to band organization by micro segregation. Therefore, the P is preferably contained in 0.01 to 0.05% by weight.
  • N is a representative solid solution strengthening element with C, and forms coarse precipitate with Ti, Al, and the like.
  • the solid solution strengthening effect of N is better than carbon, but the problem of toughness is greatly reduced as the amount of N in the steel increases.
  • the nitrogen content of nitrogen is less than 0.001% by weight, the steelmaking industry takes a lot of time, resulting in decreased productivity.
  • the nitrogen content exceeds 0.01% by weight the risk of brittleness is greatly increased. Therefore, the nitrogen is preferably contained in 0.001 to 0.01 wt%.
  • the remaining component of the present invention is iron (Fe).
  • impurities which are not intended from the raw material or the surrounding environment may be inevitably mixed, and thus cannot be excluded. Since these impurities are known to those skilled in the art, all of them are not specifically mentioned in the present specification.
  • the sulfur is inevitably contained as an impurity, and combines with Mn to form a non-metallic inclusion and thus greatly reduces the elongation flangeability of the steel.
  • the theoretical sulfur content is advantageously limited to 0% by weight, but inevitably contained in the manufacturing process. Therefore, it is important to manage the upper limit, the upper limit of the sulfur content in the present invention is preferably limited to 0.01% by weight.
  • the steel of the present invention may further improve the effect of the present invention when additionally adding one or more elements selected from the group consisting of niobium (Nb), titanium (Ti) and vanadium (V) described below. More preferably, the total content of one or more elements selected from the group is 0.001 to 0.15% by weight.
  • Ti is present in the steel as TiN, thereby suppressing the growth of grains during heating for hot rolling.
  • Ti remaining after reacting with nitrogen is dissolved in the steel and bonded with carbon to form TiC precipitates, which is a useful component for improving the strength of steel.
  • Nb and V form carbides in the steel, which are effective for grain refinement, and fine precipitates are formed to improve the strength and toughness of the steel. It stabilizes the solid solution elements such as C and N, which increase the electrical resistivity, thereby mitigating the phenomenon of local spark generation during electric resistance welding, and also suppressing softening of the weld.
  • C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V preferably satisfy Equation 1 below.
  • the electrical resistivity at high temperatures is high, and the weldability is significantly lowered.
  • the lower limit need not be particularly limited, but the lower limit may be limited to 10.5 in consideration of elongation flangeability and elongation. If it is added below, there is a problem that the strength or elongation is inferior rapidly.
  • Equation 1 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ⁇ 11.1
  • Equation 1 C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V represent the content (weight%) of the corresponding element, respectively.
  • the hot rolled high burring steel has a product of tensile strength and extension flange property of 48000 or more.
  • the hot rolled steel sheet preferably comprises a microstructure including a bainite phase in the ferrite structure.
  • a microstructure including a bainite phase in the ferrite structure By including such a microstructure, it is possible to suppress the formation of coarse carbides and to prevent destruction at the interface during plastic deformation.
  • the bainite phase fraction in the ferrite structure is more preferably contained 5 to 20%. If the included bainite phase fraction is less than 5%, the present invention does not secure the strength to be secured, whereas if it exceeds 20%, the elongation is inferior.
  • Another aspect of the present invention is a method for producing a hot rolled steel sheet having excellent weldability and burring property, in weight%, C: 0.03 to 0.1%, Si: 0.01 to 1.2%, Mn: 1.2 to 1.9%, Al: 0.01 to 0.08% , Cr: 0.005 to 0.8%, Mo: 0.01 to 0.12%, P: 0.01 to 0.05%, S: 0.001 to 0.005%, N: 0.001 to 0.01%, balance Fe and other unavoidable impurities
  • Preparing a steel slab satisfying Equation 1 below reheating the steel slab at 1200 to 1300 ° C., and hot rolling the reheated steel slab to a finish rolling temperature of 850 to 1000 ° C. to obtain a steel sheet.
  • Equation 1 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ⁇ 11.1
  • Equation 1 C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V represent the content (weight%) of the corresponding element, respectively.
  • the slab which satisfies the above-mentioned component system it is preferable to reheat the slab which satisfies the above-mentioned component system at 1200-1300 degreeC.
  • the reheating temperature is less than 1200 ° C, the precipitates are not sufficiently reused, so that precipitates such as NbC and TiC are reduced in the process after hot rolling.
  • strength falls by abnormal grain growth of austenite grains. Therefore, it is preferable to limit the reheating temperature of the slab to 1200 to 1300 ° C.
  • Hot rolling may be performed on the slab reheated as described above. At this time, it is preferable to perform finish rolling at 850-1000 degreeC. If the hot finish rolling temperature is less than 850 °C rolling load is greatly increased. On the other hand, when the hot finishing rolling temperature exceeds 1000 ° C., the structure of the steel sheet becomes coarse and the steel becomes brittle, the scale becomes thick, and surface quality deterioration such as hot rolling scale defect occurs. Therefore, the hot finish rolling is preferably limited to 850 ⁇ 1000 °C.
  • the hot rolled steel sheet it is preferable to primary-cool the hot rolled steel sheet as described above. In addition, it is preferable to primary cool until it reaches 500-750 degreeC from the said finishing hot rolling temperature of the said hot rolled sheet steel.
  • the temperature at which the primary cooling is terminated is less than 500 ° C., most of the microstructures in the steel have bainite, and thus the microstructures of the present invention cannot be secured.
  • the temperature exceeds 750 ° C. coarse ferrite and pearlite structures are formed to reduce the strength of the steel.
  • the cooled steel sheet is subjected to air cooling for 4 to 10 seconds.
  • air cooling for 4 to 10 seconds.
  • the ferrite fraction is increased to decrease the martensite fraction, thereby failing to secure the strength and elongation to be secured by the present invention.
  • After the cooling step may further comprise the step of winding to facilitate storage and movement of the cooled steel sheet.
  • the pickled steel sheet may be manufactured by further including the step of removing the surface layer portion scale and oiling the steel sheet prepared by the above method after natural cooling.
  • the steel slab satisfying the component system shown in Table 1 below was heated to 1250 ° C. and hot-rolled at the temperature shown in Table 2 below. Thereafter, primary cooling at a cooling rate of 70 ° C./sec to a temperature of 680 ° C., air cooling for 6 seconds, and secondary cooling at a cooling rate of 70 ° C./sec to a temperature of 450 ° C., followed by the temperatures shown in Table 2 below Wound up in.
  • Yield strength (YS), tensile strength (TS), elongation at break (T-El), and elongated flange property (Hole Expanding Ratio, HER) of the final hot-rolled steel sheet obtained by completing the winding process were shown in Table 2 below.
  • the bainite fraction in the ferrite structure was observed at 500 magnification using an optical microscope after etching the final hot rolled steel sheet, and then fractionated with an image analyzer.
  • weldability of the final hot rolled steel sheet is also shown in Table 2 below.
  • the weldability was measured by the uniaxial tensile test method after welding under the conditions shown in Table 3. At this time, the weldability was evaluated as being poor when the welded part was broken.
  • Inventive Examples 1 to 6 satisfy the component range and manufacturing conditions proposed by the present invention, it is possible to secure a hot rolled steel sheet having a high value of the product of tensile strength and elongated flange property and excellent weldability. You can check it.
  • Comparative Examples 1, 4, 5, 6 and 7 do not satisfy the equation (1) can be confirmed that the weldability is inferior.
  • Comparative Examples 2, 3 and 8 although the value of the product of tensile strength and extension flange property satisfied the value of the range proposed by the present invention, it does not satisfy the equation 1, it can be confirmed that the weldability is inferior.

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Abstract

The purpose of an aspect of the present invention is to provide hot-rolled high-burring steel having excellent electric resistance welding property, thereby facilitating welding operations, and a method for manufacturing the same.

Description

용접성 및 버링성이 우수한 열연강판 및 그 제조방법Hot rolled steel sheet with excellent weldability and burring property and manufacturing method
본 발명은 용접성 및 버링성이 우수한 열연강판 및 그 제조방법에 관한 것이다.The present invention relates to a hot rolled steel sheet excellent in weldability and burring properties and a method of manufacturing the same.
자동차 업계에서는 최근에 CO2 배출량 저감을 위한 경량화와 충돌안전성 향상을 위한 차체 강화를 양립시키기 위해 자동차 차체에의 고강도 강판(High Tensile Strength Steel) 적용이 확대되고 있다. 고강도 강판은 이러한 상반된 요청을 실현하는 비용대비 효과가 뛰어난 재료이며, 앞으로 더욱 엄격해지는 규제에 대응하기 위해 그 적용량이 점점 증대될 것으로 생각한다. 특히 충돌안전성에 대한 관심이 높아짐에 따라 그 역할이 점점 커지고 있다.In the automotive industry, the application of high tensile strength steel to automobile bodies has recently been expanded to achieve both weight reduction for reducing CO 2 emissions and reinforcement of bodies to improve crash safety. High-strength steel is a cost-effective material for realizing these conflicting demands, and its application is expected to increase over time to meet increasingly stringent regulations. In particular, as interest in collision safety increases, its role is increasing.
일반적으로 재료는 고강도가 될수록 성형성이 나빠진다. 철강 재료에 있어서도 예외가 아니고, 지금까지 고강도와 고연성의 양립의 시도가 이루어져 왔다. 또한, 자동차 부품에 사용되는 재료에 요구되는 특성으로서는 연성 외에 버링 가공성이 있다. 그러나, 버링 가공성도 고강도화에 따라서 저하되는 경향을 나타내므로, 버링 가공성의 향상도 고강도 강판의 자동차 부품으로의 적용의 과제로 되어 있다. 한편, 자동차 부품은 프레스 성형 등에 의해 가공된 부재를 스폿, 아크, 플라즈마, 레이저 등의 용접에 의해 조립된다. 또한, 최근에는 강판을 이들 용접에 의해 접합한 후에 프레스 성형되는 경우도 있다. 성형 시 혹은 부품으로서 조립 부착되어 사용되었을 때의 용접부 강도는 성형 한계, 안전성의 면으로부터 매우 중요하다. 따라서, 자동차 부품 등으로의 고강도 강판의 적용에 있어서는 그 버링 가공성과 함께 용접부 강도도 중요한 검토 과제가 된다In general, the higher the material, the worse the formability. The steel material is no exception, and attempts to achieve both high strength and high ductility have been made. Moreover, as a characteristic requested | required of the material used for automobile parts, there are burring processability besides ductility. However, since the burring workability also tends to be lowered with higher strength, the improvement of burring workability also becomes a subject of application of high strength steel sheet to automobile parts. On the other hand, automobile parts are assembled by welding such as spot, arc, plasma, laser, etc., the processed member by press molding. Moreover, in recent years, after joining a steel plate by these welding, it may be press-molded. The strength of the welded part when it is molded or when it is assembled and used as a part is very important from the viewpoint of molding limit and safety. Therefore, in the application of a high strength steel sheet to automobile parts and the like, the strength of the welded part also becomes an important examination subject along with its burring workability.
특허문헌 1에서는 열간 압연 후 700℃전후의 온도까지 냉각시킨 후 일정 시간을 공냉하고 다시 냉각하여 권취하는 3단 냉각을 사용함으로써 페라이트-베이나이트 조직을 형성하여 신장 플랜지성을 향상시키는 기술을 제안하였다. 또한 특허문헌 2에서는 페라이트-베이나이트 조직으로 제어하고 이때 페라이트 비율이 80%이상이 되며, 결정 입자의 짧은 직경(ds)와 긴 직경(dl)의 비가 0.1인 결정입자가 80%이상이 되도록 하여 69kg/㎠이상의 강도를 가지며 연신율과 연신 플랜지성이 동시에 우수한 열연강판을 제조하는 기술을 제안하였다. Patent Literature 1 proposes a technique for improving the elongation flangeability by forming ferrite-bainite structure by using three-stage cooling after cooling to a temperature around 700 ° C. after hot rolling, followed by air cooling for a predetermined time, and then cooling and winding again. . In addition, in Patent Document 2, the ferrite-bainite structure is controlled so that the ferrite ratio is 80% or more, and the ratio of the crystal grains having a short diameter (ds) and a long diameter (dl) of 0.1 is 80% or more. A technique for producing a hot rolled steel sheet having strength of more than 69 kg / cm 2 and excellent in elongation and stretch flangeability is proposed.
그러나, 상기와 같은 기술은 Si, Mn, Al, Mo등의 합금성분을 주로 활용하여 페라이트-베이나이트의 이상복합조직강을 제조하는데, 이와 같은 합금성분은 전기저항 용접시 전기저항을 증가시켜 저항발열이 심해지거나, 입력 전류치를 낮춰 작업할 경우 냉접이 발생하는 문제가 있다. 또한, Si, Mn, Al 등은 용접시 산화물을 형성하여 용접부의 건전성을 떨어뜨리는 문제가 있다.However, the above technique mainly uses the alloying components of Si, Mn, Al, Mo, etc. to manufacture the abnormal composite tissue steel of ferrite-bainite, and such alloying components increase resistance by increasing electrical resistance during electrical resistance welding. There is a problem that the heat generation is severe, or cold welding occurs when the operation lowers the input current value. In addition, Si, Mn, Al and the like to form an oxide during welding, there is a problem of reducing the integrity of the weld.
(특허문헌 1) 일본 특허공개 특개평6-293910호 공보(Patent Document 1) Japanese Unexamined Patent Application Publication No. 6-293910
(특허문헌 2) 한국 특허공개 2003-0055339호 공보(Patent Document 2) Korean Patent Publication No. 2003-0055339
본 발명의 일측면은 전기 저항 용접성이 우수하여 용접 작업이 용이하고, 버링성이 우수한 열연강판 및 그 제조방법을 제공하고자 한다.One aspect of the present invention is to provide a hot rolled steel sheet excellent in electrical resistance weldability and easy welding work, excellent burring properties and a method of manufacturing the same.
본 발명의 일측면은 중량%로, C:0.03~0.1%, Si: 0.01~1.2%, Mn: 1.2~1.9%, Al: 0.01~0.08%, Cr: 0.005~0.8%, Mo: 0.01~0.12%, P: 0.01~0.05%, S: 0.001~0.005%, N: 0.001~0.01%, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 동시에 상기 각 성분들은 하기 수학식 1을 만족하고, 인장강도와 신장플랜지성의 곱이 48000 이상인 용접성 및 버링성이 우수한 열연강판을 제공한다. One aspect of the present invention is a weight%, C: 0.03 ~ 0.1%, Si: 0.01 ~ 1.2%, Mn: 1.2 ~ 1.9%, Al: 0.01 ~ 0.08%, Cr: 0.005 ~ 0.8%, Mo: 0.01 ~ 0.12 %, P: 0.01% to 0.05%, S: 0.001% to 0.005%, N: 0.001% to 0.01%, the balance Fe and other unavoidable impurities, and each of the above components satisfy the following Equation 1, and the tensile strength and elongation plan Provided is a hot rolled steel sheet excellent in weldability and burring property of multiplying 48000 or more.
수학식 1: 10.646 + 0.2[C] + 0.25[Si] +0.3[Mn] - 0.1[Cr]+ 0.55[Al] +0.2[Mo] -4.23[Ti] -2.5[Nb] - 2.9[V] ≤ 11.1 Equation 1: 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ≤ 11.1
단, 상기 수학식 1에서 C, Si, Mn, Cr, Al, Mo, Ti, Nb 및 V는 각각 해당원소의 함량(중량%)을 나타낸다. However, in Equation 1, C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V represent the content (weight%) of the corresponding element, respectively.
본 발명의 다른 일측면인 용접성 및 버링성이 우수한 열연강판의 제조방법은 중량%로, C:0.03~0.1%, Si: 0.01~1.2%, Mn: 1.2~1.9%, Al: 0.01~0.08%, Cr: 0.005~0.8%, Mo: 0.01~0.12%, P: 0.01~0.05%, S: 0.001~0.005%, N: 0.001~0.01%, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 동시에, 상기 각 성분들이 하기 수학식 1을 만족하는 강 슬라브를 준비하는 단계, 상기 강 슬라브를 1200~1300℃에서 재가열 하는 단계, 상기 재가열된 강 슬라브를 850~1000℃의 마무리압연온도로 열간압연하여 강판을 얻는 단계, 상기 열간압연된 강판을 500~750℃의 온도까지 10~100℃/초의 냉각속도로 1차 냉각하는 단계, 상기 냉각된 강판을 4~10초 동안 공냉하는 단계 및 상기 공냉된 강판을 300~500℃의 온도까지 10~100℃/초의 냉각속도로 2차 냉각하는 단계를 포함한다. Another aspect of the present invention is a method for producing a hot rolled steel sheet having excellent weldability and burring property, in weight%, C: 0.03 to 0.1%, Si: 0.01 to 1.2%, Mn: 1.2 to 1.9%, Al: 0.01 to 0.08% , Cr: 0.005 to 0.8%, Mo: 0.01 to 0.12%, P: 0.01 to 0.05%, S: 0.001 to 0.005%, N: 0.001 to 0.01%, balance Fe and other unavoidable impurities Preparing a steel slab satisfying Equation 1 below, reheating the steel slab at 1200 to 1300 ° C., and hot rolling the reheated steel slab to a finish rolling temperature of 850 to 1000 ° C. to obtain a steel sheet. The first step of cooling the hot rolled steel sheet at a cooling rate of 10 ~ 100 ℃ / second to a temperature of 500 ~ 750 ℃, air cooling the cooled steel sheet for 4 to 10 seconds and the air-cooled steel sheet 300 ~ Secondary cooling at a cooling rate of 10-100 ° C./sec to a temperature of 500 ° C .;
수학식 1: 10.646 + 0.2[C] + 0.25[Si] +0.3[Mn] - 0.1[Cr]+ 0.55[Al] +0.2[Mo] -4.23[Ti] -2.5[Nb] - 2.9[V] ≤ 11.1 Equation 1: 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ≤ 11.1
단, 상기 수학식 1에서 C, Si, Mn, Cr, Al, Mo, Ti, Nb 및 V는 각각 해당원소의 함량(중량%)을 나타낸다. However, in Equation 1, C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V represent the content (weight%) of the corresponding element, respectively.
덧붙여 상기한 과제의 해결수단은, 본 발명의 특징을 모두 열거한 것은 아니다. 본 발명의 다양한 특징과 그에 따른 장점과 효과는 아래의 구체적인 실시형태를 참조하여 보다 상세하게 이해될 수 있을 것이다.In addition, the solution of the said subject does not enumerate all the characteristics of this invention. Various features of the present invention and the advantages and effects thereof may be understood in more detail with reference to the following specific embodiments.
본 발명에 따르면, 강성분 및 열연조직을 최적화함으로써, 인장강도와 신장플랜지성의 곱이 48000이상이며, 용접시 용접부의 건전성이 향상되어 용접성 및 버링성이 우수한 열연강판을 확보하는 효과가 있다.According to the present invention, by optimizing the steel component and the hot rolled structure, the product of tensile strength and extension flange is 48000 or more, and the integrity of the welded portion is improved during welding, thereby ensuring a hot rolled steel sheet excellent in weldability and burring property.
도 1은 실시예의 모든 강의 인장강도(TS)와 신장플랜지성(HER)의 곱한 값과 수학식 1에 대입했을 때의 값을 나타낸 그래프이다.FIG. 1 is a graph showing a value obtained by substituting the product of the tensile strength (TS) and the elongation flange property (HER) of all the steels of the examples and the formula (1).
본 발명자들은 상기 전술한 기술들이 해결하지 못한 문제점을 극복이 가능한 열연강판을 개발하기 위하여 연구를 행한 결과, 강의 조성성분, 미세조직 및 공정조건을 제어함으로써 용접성 및 버링성이 우수한 열연강판을 생산할 수 있음을 확인하고 본 발명에 이르게 되었다.The present inventors have conducted research to develop a hot rolled steel sheet capable of overcoming the problems that the above-described technologies have not solved. As a result, the hot rolled steel sheet having excellent weldability and burring property can be produced by controlling the composition, microstructure, and processing conditions of the steel. The present invention was confirmed.
이하, 본 발명의 일측면인 용접성 및 버링성이 우수한 열연강판에 대하여 상세히 설명한다. Hereinafter, a hot rolled steel sheet excellent in weldability and burring property as one side of the present invention will be described in detail.
본 발명의 일측면은 중량%로, C:0.03~0.1%, Si: 0.01~1.2%, Mn: 1.2~1.9%, Al: 0.01~0.08%, Cr: 0.005~0.8%, Mo: 0.01~0.12%, P: 0.01~0.05%, S: 0.001~0.005%, N: 0.001~0.01%, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 동시에 상기 각 성분들은 하기 수학식 1을 만족하고, 인장강도와 신장플랜지성의 곱이 48000이상인 용접성 및 버링성이 우수한 열연강판을 제공한다.One aspect of the present invention is a weight%, C: 0.03 ~ 0.1%, Si: 0.01 ~ 1.2%, Mn: 1.2 ~ 1.9%, Al: 0.01 ~ 0.08%, Cr: 0.005 ~ 0.8%, Mo: 0.01 ~ 0.12 %, P: 0.01% to 0.05%, S: 0.001% to 0.005%, N: 0.001% to 0.01%, the balance Fe and other unavoidable impurities, and each of the above components satisfy the following Equation 1, and the tensile strength and elongation plan Provides hot-rolled steel sheet with excellent weldability and burring property of multiplying 48000 or more.
수학식 1: 10.646 + 0.2[C] + 0.25[Si] +0.3[Mn] - 0.1[Cr]+ 0.55[Al] +0.2[Mo] -4.23[Ti] -2.5[Nb] - 2.9[V] ≤ 11.1 Equation 1: 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ≤ 11.1
단, 상기 수학식 1에서 C, Si, Mn, Cr, Al, Mo, Ti, Nb 및 V는 각각 해당원소의 함량(중량%)을 나타낸다. However, in Equation 1, C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V represent the content (weight%) of the corresponding element, respectively.
탄소(C): 0.03~0.1중량%Carbon (C): 0.03-0.1 weight%
C는 강을 강화시키는데 가장 경제적이며 효과적인 원소이다. 상기 탄소의 첨가량이 증가하면 페라이트-마르텐사이트 복합조직강의 마르텐사이트 분율이 증가하여 인장강도가 증가하게된다. 상기 탄소의 함량이 0.03중량% 미만인 경우에는 열연 후 냉각 중 마르텐사이트상의 형성이 용이하지 않다. 반면에, 상기 탄소의 함량이 0.1중량%를 초과하는 경우에는 과도한 강도상승과 용접성, 성형성 및 인성이 저하되는 문제점이 있다. 따라서, 상기 C의 함량은 0.03~0.1중량%로 포함되는 것이 바람직하다.C is the most economical and effective element for strengthening steel. As the amount of carbon added increases, the martensite fraction of the ferritic-martensitic composite steel increases and the tensile strength increases. If the carbon content is less than 0.03% by weight, it is not easy to form martensite phase during cooling after hot rolling. On the other hand, when the carbon content exceeds 0.1% by weight, there is a problem in that excessive strength increase and weldability, formability and toughness are reduced. Therefore, the content of C is preferably contained in 0.03 ~ 0.1% by weight.
실리콘(Si): 0.01~1.2중량%Silicon (Si): 0.01 ~ 1.2 wt%
Si는 용강을 탈산시키고 고용강화 효과가 있고, 페라이트 안정화 원소로서 열연 후 냉각중 페라이트 변태를 촉진하는 효과가 있어 페라이트 마르텐사이트 복합조직강의 기지를 구성하는 페라이트 분율 증대에 효과적인 원소이다. 상기 실리콘의 함량이 0.01중량%미만인 경우에는 페라이트 안정화 효과가 적어 기지조직을 페라이트 조직으로 만들기 어렵다. 반면에, 상기 실리콘의 함량이 1.2중량%를 초과하면 열간압연시 강판표면에 Si에 의한 붉은색 스케일이 형성되어 강판표면 품질이 매우 나빠질 뿐만 아니라 연성과 용접성도 저하되는 문제가 있다. 따라서, 상기 실리콘의 함량은 0.01~1.2중량%로 포함되는 것이 바람직하다. Si deoxidizes molten steel and has a solid solution strengthening effect. As a ferrite stabilizing element, it has an effect of promoting ferrite transformation during cooling after hot rolling, and is an effective element for increasing the ferrite fraction constituting the matrix of ferritic martensite composite steel. When the content of the silicon is less than 0.01% by weight, the ferrite stabilization effect is small, making it difficult to make the matrix into a ferrite structure. On the other hand, when the silicon content exceeds 1.2% by weight, red scales formed by Si are formed on the surface of the steel sheet during hot rolling, so that the surface quality of the steel sheet is not very bad, and the ductility and weldability are also reduced. Therefore, the content of the silicon is preferably contained in 0.01 to 1.2% by weight.
망간(Mn): 1.2~1.9중량%Manganese (Mn): 1.2-1.9 wt%
Mn은 Si과 마찬가지로 강을 고용 강화시키는데 효과적인 원소이며 강의 경화능을 증가시켜 열연 후 냉각 중 베이나이트상의 형성을 용이하게 하는 효과가 있다. 본 발명에서 이러한 효과를 나타내기 위하여 1.2중량% 이상 포함되는 것이 바람직하다. 그러나, 상기 망간의 함량이 1.9중량%를 초과하는 경우에는 과도하게 페라이트 변태를 지연하여 기지조직인 페라이트의 적정분율을 확보하는데 어려움이 있다. 또한, 연주공정에서 슬라브 주조시 두께중심부에서 편석부가 크게 발달되어 최종제품의 용접성을 해치는 문제점이 있다. 따라서, 상기 Mn의 함량은 1.2~1.9중량%로 포함되는 것이 바람직하다.Mn, like Si, is an effective element to solidify steel and increases the hardenability of steel to facilitate the formation of bainite phase during cooling after hot rolling. In order to exhibit such an effect in the present invention, it is preferable that 1.2 wt% or more is included. However, if the content of the manganese exceeds 1.9% by weight excessively delay the ferrite transformation is difficult to secure the appropriate fraction of the ferrite known matrix. In addition, there is a problem in that the segregation part in the thickness center during the slab casting in the playing process greatly develops, which impairs the weldability of the final product. Therefore, the content of Mn is preferably contained in 1.2 to 1.9% by weight.
알루미늄(Sol.Al): 0.01∼0.08중량%,Aluminum (Sol.Al): 0.01 to 0.08% by weight,
Al은 주로 탈산을 위하여 첨가하는 성분이며, 페라이트 안정화 원소로서, 열간압연 후 냉각 중 강에 페라이트 상의 형성을 도와주는 효과가 있다. 상기 알루미늄의 함량이 0.01중량% 미만인 경우에는 본 발명에서 의도하고자 하는 효과를 확보할 수 없다. 반면에, 상기 알루미늄의 함량이 0.08중량%를 초과하는 경우에는 연속주조시에 슬라브에 코너크랙과 같은 결함이 발생하기 쉬우며 열연 후 표면 결함 발생하여 표면품질이 떨어지는 문제가 있다. 따라서, 상기 알루미늄의 함량은 0.01~0.08중량%로 포함되는 것이 바람직하다.Al is a component mainly added for deoxidation, and is a ferrite stabilizing element, and has an effect of helping to form a ferrite phase in steel during cooling after hot rolling. When the content of aluminum is less than 0.01% by weight, it is impossible to secure the effect intended for the present invention. On the other hand, when the content of aluminum exceeds 0.08% by weight, defects such as corner cracks are easily generated in the slab during continuous casting, and surface defects occur after hot rolling, thereby deteriorating surface quality. Therefore, the content of aluminum is preferably contained in 0.01 to 0.08% by weight.
크롬(Cr): 0.005~0.8중량%Chromium (Cr): 0.005 to 0.8 wt%
Cr은 강을 고용강화시키며 냉각시 페라이트 상변태를 지연시켜 베이나이트 형성을 도와주는 역할을 한다. 본 발명에서 의도하고자 하는 효과를 확보하기 위해서는 0.005중량% 이상 포함되는 것이 바람직하다. 반면에, 상기 크롬의 함량이 0.8중량%를 초과하는 경우에는 페라이트 변태를 과도하게 지연하여 필요이상의 마르텐사이트 분율증가로 인하여 연신율이 감소하게된다. 따라서, 상기 Cr의 함량은 0.005~0.8중량%로 포함되는 것이 바람직하다. Cr hardens the steel and assists bainite formation by retarding ferrite phase transformation during cooling. In order to secure the effect to be intended in the present invention, it is preferable to include 0.005% by weight or more. On the other hand, when the content of chromium exceeds 0.8% by weight, the ferrite transformation is excessively delayed and the elongation is reduced due to the increase of martensite fraction more than necessary. Therefore, the content of Cr is preferably contained in 0.005 ~ 0.8% by weight.
몰리브덴(Mo): 0.01~0.12중량%Molybdenum (Mo): 0.01 ~ 0.12% by weight
Mo는 강의 경화능을 증가시켜 베이나이트 조직 형성을 용이하게 하는 효과가 있다. 본 발명의 이러한 효과를 나타내기 위하여 0.01중량% 이상 포함되는 것이 바람직하다. 반면에, 상기 몰리브덴의 함량이 0.12중량%를 초과하는 경우에는 과도한 소입성 증가로 용접성을 악화시키며, 경제적으로도 불리하다. 따라서, 상기 Mo의 함량은 0.01~0.12중량%로 포함되는 것이 바람직하다.Mo has the effect of increasing the hardenability of the steel to facilitate the formation of bainite structure. In order to exhibit such an effect of the present invention, it is preferable that 0.01 wt% or more is included. On the other hand, when the content of molybdenum exceeds 0.12% by weight, the weldability is deteriorated due to excessive increase in hardenability, which is also economically disadvantageous. Therefore, the content of Mo is preferably contained in 0.01 to 0.12% by weight.
인(P): 0.01∼0.05중량%Phosphorus (P): 0.01% to 0.05% by weight
P는 Si과 마찬가지로 고용강화 및 페라이트 변태 촉진효과가 있다. 상기 인의 함량이 0.01중량% 미만인 경우에는 본 발명이 확보하고자 하는 강도를 얻기에 불충분 하다. 반면에, 상기 인의 함량이 0.05중량%를 초과하는 경우에는 마이크로 편석에 의한 밴드조직화로 인하여 연성이 저하된다. 따라서 상기 P는 0.01~0.05중량%로 포함되는 것이 바람직하다. P, like Si, has the effect of strengthening solid solution and promoting ferrite transformation. If the content of phosphorus is less than 0.01% by weight is insufficient to obtain the strength to be secured by the present invention. On the other hand, when the content of phosphorus exceeds 0.05% by weight, ductility is lowered due to band organization by micro segregation. Therefore, the P is preferably contained in 0.01 to 0.05% by weight.
질소(N): 0.001∼0.01중량%Nitrogen (N): 0.001-0.01 wt%
N은 C와 함께 대표적인 고용강화 원소이며, Ti, Al 등과 함께 조대한 석출물을 형성한다. 일반적으로, N의 고용강화 효과는 탄소보다 우수하지만, 강 중에 N의 양이 증가될수록 인성이 크게 떨어지는 문제점이 있다. 상기 질소의 함량이 0.001중량% 미만인 경우에는 제강조업시 시간이 많이 소요되어 생산성이 떨어지게 된다. 반면에, 상기 질소의 함량이 0.01중량%를 초과하는 경우에는 취성이 발생할 위험이 크게 증가된다. 따라서, 상기 질소는 0.001~0.01중량%로 포함되는 것이 바람직하다. N is a representative solid solution strengthening element with C, and forms coarse precipitate with Ti, Al, and the like. In general, the solid solution strengthening effect of N is better than carbon, but the problem of toughness is greatly reduced as the amount of N in the steel increases. When the content of nitrogen is less than 0.001% by weight, the steelmaking industry takes a lot of time, resulting in decreased productivity. On the other hand, when the nitrogen content exceeds 0.01% by weight, the risk of brittleness is greatly increased. Therefore, the nitrogen is preferably contained in 0.001 to 0.01 wt%.
본 발명의 나머지 성분은 철(Fe)이다. 다만, 통상의 제조과정에서는 원료 또는 주위 환경으로부터 의도되지 않는 불순물들이 불가피하게 혼입될 수 있으므로, 이를 배제할 수는 없다. 이들 불순물들은 통상의 제조과정의 기술자라면 누구라도 알 수 있는 것이기 때문에 그 모든 내용을 특별히 본 명세서에서 언급하지는 않는다.The remaining component of the present invention is iron (Fe). However, in the conventional manufacturing process, impurities which are not intended from the raw material or the surrounding environment may be inevitably mixed, and thus cannot be excluded. Since these impurities are known to those skilled in the art, all of them are not specifically mentioned in the present specification.
다만, 그 중 황은 일반적으로 많이 언급되는 불순물이기 때문에 이에 대하여 간략히 설명하면 다음과 같다.However, since sulfur is a commonly mentioned impurity, a brief description thereof is as follows.
황(S): 0.001∼0.005%Sulfur (S): 0.001-0.005%
상기 황은 불가피하게 함유되는 불순물로써, Mn 등과 결합하여 비금속개재물을 형성하며 이에 따라 강의 신장 플랜지성을 크게 떨어뜨리기 때문에 그 함량을 최대한 억제하는 것이 바람직하다. 이론상의 황의 함량은 0중량%로 제한하는 것이 유리하나, 제조공정상 필연적으로 함유될 수 밖에 없다. 따라서, 상한을 관리하는 것이 중요하며, 본 발명에서 상기 황 함량의 상한은 0.01중량%로 한정하는 것이 바람직하다. The sulfur is inevitably contained as an impurity, and combines with Mn to form a non-metallic inclusion and thus greatly reduces the elongation flangeability of the steel. The theoretical sulfur content is advantageously limited to 0% by weight, but inevitably contained in the manufacturing process. Therefore, it is important to manage the upper limit, the upper limit of the sulfur content in the present invention is preferably limited to 0.01% by weight.
더불어, 본 발명의 강재는 하기 설명하는 니오븀(Nb), 티타늄(Ti) 및 바나듐(V)으로 이루어진 그룹 중에서 선택된 1종 이상의 원소를 추가적으로 첨가하는 경우 본 발명의 효과를 더욱 향상시킬 수 있다. 보다 바람직하게는 상기 그룹 중에서 선택된 1종 이상의 원소를 합하여 0.001~0.15중량% 포함한다. In addition, the steel of the present invention may further improve the effect of the present invention when additionally adding one or more elements selected from the group consisting of niobium (Nb), titanium (Ti) and vanadium (V) described below. More preferably, the total content of one or more elements selected from the group is 0.001 to 0.15% by weight.
Ti는 강중에 TiN으로 존재하여 열간압연을 위한 가열과정에서 결정립이 성장되는 것을 억제하는 효과가 있다. 또한, 질소와 반응하고 남은 Ti이 강 중에 고용되어 탄소와 결합함으로써 TiC 석출물이 형성되어 강의 강도를 향상시키는데 유용한 성분이다. Ti is present in the steel as TiN, thereby suppressing the growth of grains during heating for hot rolling. In addition, Ti remaining after reacting with nitrogen is dissolved in the steel and bonded with carbon to form TiC precipitates, which is a useful component for improving the strength of steel.
Nb와 V은 강중 탄화물을 형성하여 결정립 미세화에 효과적이며 미세한 석출물을 형성하여 강의 강도와 인성을 향상시킨다. 전기비저항을 증가시키는 C, N 등의 고용원소를 안정화시켜 주므로 전기저항 용접시 국부적인 불꽃발생을 현상을 완화시켜 주며, 용접부 연화를 억제하는 효과도 있다. Nb and V form carbides in the steel, which are effective for grain refinement, and fine precipitates are formed to improve the strength and toughness of the steel. It stabilizes the solid solution elements such as C and N, which increase the electrical resistivity, thereby mitigating the phenomenon of local spark generation during electric resistance welding, and also suppressing softening of the weld.
더불어, 용접성 향상을 위해서 상기 C, Si, Mn, Cr, Al, Mo, Ti, Nb 및 V는 하기 수학식 1을 만족하는 것이 바람직한데, 수학식 1에서 경계로 설정한 11.1을 초과하는 경우에는 고온에서의 전기비저항이 높아져 용접성이 현저히 낮아진다. 하한은 특별히 한정될 필요는 없으나, 신장플랜지성 및 연신율을 고려하여 그 하한은 10.5로 제한될 수 있다. 그 이하로 첨가될 경우에는 강도 또는 연신율이 급격히 열위하게 되는 문제가 있다. In addition, in order to improve weldability, C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V preferably satisfy Equation 1 below. The electrical resistivity at high temperatures is high, and the weldability is significantly lowered. The lower limit need not be particularly limited, but the lower limit may be limited to 10.5 in consideration of elongation flangeability and elongation. If it is added below, there is a problem that the strength or elongation is inferior rapidly.
수학식 1: 10.646 + 0.2[C] + 0.25[Si] +0.3[Mn] - 0.1[Cr]+ 0.55[Al] +0.2[Mo] -4.23[Ti] -2.5[Nb] - 2.9[V] ≤ 11.1 Equation 1: 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ≤ 11.1
단, 상기 수학식 1에서 C, Si, Mn, Cr, Al, Mo, Ti, Nb 및 V는 각각 해당원소의 함량(중량%)을 나타낸다.However, in Equation 1, C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V represent the content (weight%) of the corresponding element, respectively.
또한, 상기 열연 고버링성 강은 인장강도와 신장플랜지성의 곱이 48000이상인 것이 바람직하다. In addition, it is preferable that the hot rolled high burring steel has a product of tensile strength and extension flange property of 48000 or more.
또한, 상기 열연강판은 페라이트 조직 내에 베이나이트 상을 포함하는 미세조직을 포함하는 것이 바람직하다. 이와 같은 미세조직을 포함함으로써 조대한 탄화물의 형성을 억제하여 소성변형중 상기 계면에서의 파괴를 방지하는 효과가 있다. 더불어, 페라이트 조직 내에 베이나이트 상 분율은 5~20%로 포함되는 것이 보다 바람직하다. 포함되는 베이나이트 상의 분율이 5%미만인 경우에는 본 발명이 확보하고자 하는 강도를 확보하지 못하며, 반면에 20%를 초과하는 경우에는 연신율이 열위하게 된다. In addition, the hot rolled steel sheet preferably comprises a microstructure including a bainite phase in the ferrite structure. By including such a microstructure, it is possible to suppress the formation of coarse carbides and to prevent destruction at the interface during plastic deformation. In addition, the bainite phase fraction in the ferrite structure is more preferably contained 5 to 20%. If the included bainite phase fraction is less than 5%, the present invention does not secure the strength to be secured, whereas if it exceeds 20%, the elongation is inferior.
이하, 본 발명의 다른 일측면인 용접성 및 버링성이 우수한 열연강판의 제조방법에 대하여 상세히 설명한다. Hereinafter, a method of manufacturing a hot rolled steel sheet excellent in weldability and burring property as another aspect of the present invention will be described in detail.
본 발명의 다른 일측면인 용접성 및 버링성이 우수한 열연강판의 제조방법은 중량%로, C:0.03~0.1%, Si: 0.01~1.2%, Mn: 1.2~1.9%, Al: 0.01~0.08%, Cr: 0.005~0.8%, Mo: 0.01~0.12%, P: 0.01~0.05%, S: 0.001~0.005%, N: 0.001~0.01%, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 동시에, 상기 각 성분들이 하기 수학식 1을 만족하는 강 슬라브를 준비하는 단계, 상기 강 슬라브를 1200~1300℃에서 재가열 하는 단계, 상기 재가열된 강 슬라브를 850~1000℃의 마무리압연온도로 열간압연하여 강판을 얻는 단계, 상기 열간압연된 강판을 500~750℃의 온도까지 10~100℃/초의 냉각속도로 1차 냉각하는 단계, 상기 냉각된 강판을 4~10초 동안 공냉하는 단계 및 상기 공냉된 강판을 300~500℃의 온도까지 10~100℃/초의 냉각속도로 2차 냉각하는 단계를 포함한다.Another aspect of the present invention is a method for producing a hot rolled steel sheet having excellent weldability and burring property, in weight%, C: 0.03 to 0.1%, Si: 0.01 to 1.2%, Mn: 1.2 to 1.9%, Al: 0.01 to 0.08% , Cr: 0.005 to 0.8%, Mo: 0.01 to 0.12%, P: 0.01 to 0.05%, S: 0.001 to 0.005%, N: 0.001 to 0.01%, balance Fe and other unavoidable impurities Preparing a steel slab satisfying Equation 1 below, reheating the steel slab at 1200 to 1300 ° C., and hot rolling the reheated steel slab to a finish rolling temperature of 850 to 1000 ° C. to obtain a steel sheet. The first step of cooling the hot rolled steel sheet at a cooling rate of 10 ~ 100 ℃ / second to a temperature of 500 ~ 750 ℃, air cooling the cooled steel sheet for 4 to 10 seconds and the air-cooled steel sheet 300 ~ Secondary cooling at a cooling rate of 10-100 ° C./sec to a temperature of 500 ° C .;
수학식 1: 10.646 + 0.2[C] + 0.25[Si] +0.3[Mn] - 0.1[Cr]+ 0.55[Al] +0.2[Mo] -4.23[Ti] -2.5[Nb] - 2.9[V] ≤ 11.1 Equation 1: 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ≤ 11.1
단, 상기 수학식 1에서 C, Si, Mn, Cr, Al, Mo, Ti, Nb 및 V는 각각 해당원소의 함량(중량%)을 나타낸다.However, in Equation 1, C, Si, Mn, Cr, Al, Mo, Ti, Nb, and V represent the content (weight%) of the corresponding element, respectively.
재가열 단계Reheating stage
상술한 성분계를 만족하는 슬라브를 1200~1300℃에서 재가열 하는 것이 바람직하다. 상기 재가열 온도가 1200℃ 미만인 경우에는 석출물이 충분히 재고용되지 않아 열간압연 이후의 공정에서 NbC, TiC 등의 석출물이 감소하게 된다. 반면에, 1300℃를 초과하면 오스테나이트 결정립의 이상입성장에 의하여 강도가 저하된다. 그러므로, 슬라브의 재가열온도는 1200~1300℃로 한정하는 것이 바람직하다. It is preferable to reheat the slab which satisfies the above-mentioned component system at 1200-1300 degreeC. When the reheating temperature is less than 1200 ° C, the precipitates are not sufficiently reused, so that precipitates such as NbC and TiC are reduced in the process after hot rolling. On the other hand, when it exceeds 1300 degreeC, intensity | strength falls by abnormal grain growth of austenite grains. Therefore, it is preferable to limit the reheating temperature of the slab to 1200 to 1300 ° C.
열간압연 단계Hot rolling stage
상기와 같이 재가열된 슬라브에 열간압연을 실시할 수 있다. 이때, 마무리압연은 850~1000℃에서 행하는 것이 바람직하다. 상기 열간 마무리압연 온도가 850℃미만인 경우에는 압연하중이 크게 증가한다. 반면에, 상기 열간마무리 압연온도가 1000℃를 초과하는 경우에는 강판의 조직이 조대화되어 강재가 취약해지며, 스케일이 두꺼워지고, 고온압연성 스케일 결함 등의 표면 품질 저하가 발생한다. 따라서, 상기 열간마무리압연은 850~1000℃로 한정하는 것이 바람직하다. Hot rolling may be performed on the slab reheated as described above. At this time, it is preferable to perform finish rolling at 850-1000 degreeC. If the hot finish rolling temperature is less than 850 ℃ rolling load is greatly increased. On the other hand, when the hot finishing rolling temperature exceeds 1000 ° C., the structure of the steel sheet becomes coarse and the steel becomes brittle, the scale becomes thick, and surface quality deterioration such as hot rolling scale defect occurs. Therefore, the hot finish rolling is preferably limited to 850 ~ 1000 ℃.
1차 냉각단계1st cooling stage
상기와 같이 열간압연된 강판을 1차 냉각하는 것이 바람직하다. 또한, 상기 열간압연된 강판의 상기 마무리 열간압연 온도로부터 500~750℃에 도달할 때까지 1차 냉각하는 것이 바람직하다. 1차 냉각이 종료되는 온도가 500℃미만인 경우에는 강중 미세조직이 대부분 베이나이트를 가짐으로써, 본 발명이 확보하고자 하는 미세조직을 확보할 수 없다. 반면에, 750℃를 초과하는 경우에는 조대한 페라이트와 펄라이트 조직이 형성되어 강의 강도가 감소된다. 또한 10~100℃/초의 냉각속도로 1차 냉각하는 것이 바람직하다. 10℃/초 미만인 경우에는 페라이트 결정립의 조대화가 일어나고 석출물 또한 조대화가 되어 본 발명이 얻고자 하는 강도를 확보하는데 문제가 있으며, 100℃/초를 초과하는 경우에는 열연판의 형상이 불량해진다. It is preferable to primary-cool the hot rolled steel sheet as described above. In addition, it is preferable to primary cool until it reaches 500-750 degreeC from the said finishing hot rolling temperature of the said hot rolled sheet steel. When the temperature at which the primary cooling is terminated is less than 500 ° C., most of the microstructures in the steel have bainite, and thus the microstructures of the present invention cannot be secured. On the other hand, when the temperature exceeds 750 ° C., coarse ferrite and pearlite structures are formed to reduce the strength of the steel. In addition, it is preferable to perform primary cooling at a cooling rate of 10 to 100 ° C / sec. If it is less than 10 ° C / second coarsening of the ferrite grains occurs and the precipitate is also coarse to secure the strength to be obtained by the present invention, if the temperature exceeds 100 ° C / second the shape of the hot rolled sheet is poor .
공냉단계Air cooling stage
상기와 같이 냉각된 강판을 공냉하는 것이 바람직하다. 상기 냉각된 강판을 4~10초 동안 공냉을 행하는 것이 바람직하다. 4초 미만으로 공냉을 행할 경우에는 페라이트 조직을 충분히 형성시키지 못하여 연성이 크게 떨어지는 문제가 있다. 반면에 10초 초과하여 공냉을 행할 경우에는 페라이트 분율이 증가하여 마르텐사이트 분율이 감소하여 본 발명이 확보하고자 하는 강도와 연신율을 확보하지 못한다. It is preferable to air-cool the steel plate cooled as mentioned above. Preferably, the cooled steel sheet is subjected to air cooling for 4 to 10 seconds. In the case of performing air cooling for less than 4 seconds, there is a problem in that ductility is greatly deteriorated due to insufficient formation of ferrite structure. On the other hand, if air cooling is performed for more than 10 seconds, the ferrite fraction is increased to decrease the martensite fraction, thereby failing to secure the strength and elongation to be secured by the present invention.
2차 냉각단계2nd cooling stage
상기와 같이 공냉된 강판을 2차 냉각하는 것이 바람직하다. 또한, 상기 공냉된 강판의 온도로부터 300~500℃에 도달할 때까지 10~100℃/초의 냉각속도로 2차 냉각하는 것이 바람직하다. 2차 냉각이 종료되는 온도가 300℃미만인 경우에는 마르텐사이트 상이 형성되어 신장플랜지성이 열위해진다. 반면에, 500℃를 초과하는 경우에는 조대한 탄화물의 형성으로 신장플랜지성이 열위해진다. 또한 10~100℃/초의 냉각속도로 1차 냉각하는 것이 바람직하다. 10℃/초 미만인 경우에는 조대한 탄화물이 형성되어 본 발명이 확보하고자하는 신장플랜지성을 확보하는데 문제가 있으며, 100℃/초를 초과하는 경우에는 열연판의 형성이 불량해지는 문제가 있다.It is preferable to secondary-cool the steel plate cooled by air as mentioned above. In addition, it is preferable to perform secondary cooling at a cooling rate of 10 ~ 100 ℃ / sec until reaching 300 ~ 500 ℃ from the temperature of the air-cooled steel sheet. If the temperature at which the secondary cooling is terminated is less than 300 ° C, the martensite phase is formed and the extension flange is inferior. On the other hand, when it exceeds 500 degreeC, extension flange property is inferior by formation of coarse carbide. In addition, it is preferable to perform primary cooling at a cooling rate of 10 to 100 ° C / sec. If it is less than 10 ° C / second coarse carbide is formed there is a problem to secure the stretch flange to be secured by the present invention, if it exceeds 100 ° C / second there is a problem that the formation of the hot rolled sheet is poor.
상기 냉각 단계 후에는 냉각된 강판의 보관 및 이동을 용이하게 하기 위하여 권취하는 단계를 추가로 포함할 수 있다. After the cooling step may further comprise the step of winding to facilitate storage and movement of the cooled steel sheet.
상기와 같은 방법에 의하여 제조된 강판을 자연냉각을 한 후 산세하여 표층부 스케일을 제거하고 도유하는 단계를 추가로 포함함으로써 산세강판을 제조할 수 있다. The pickled steel sheet may be manufactured by further including the step of removing the surface layer portion scale and oiling the steel sheet prepared by the above method after natural cooling.
또한, 상기 산세강판을 450~480℃로 재가열한 후, 용융아연도금욕을 통과시키는 단계를 추가로 포함함으로써, 용융아연도금강판을 제조할 수 있다.In addition, after reheating the pickling steel sheet to 450 ~ 480 ℃, by further comprising the step of passing through a hot dip galvanizing bath, it is possible to manufacture a hot dip galvanized steel sheet.
이하, 실시예를 통하여 본 발명을 보다 구체적으로 설명하고자 한다. 다만, 하기의 실시예는 본 발명을 예시하여 보다 상세하게 설명하기 위한 것일 뿐, 본 발명의 권리범위를 한정하기 위한 것이 아니라는 점에 유의할 필요가 있다. 본 발명의 권리범위는 특허청구범위에 기재된 사항과 이로부터 합리적으로 유추되는 사항에 의해 결정되는 것이기 때문이다.Hereinafter, the present invention will be described in more detail with reference to Examples. However, it is necessary to note that the following examples are only for illustrating the present invention in more detail, and are not intended to limit the scope of the present invention. This is because the scope of the present invention is determined by the matters described in the claims and the matters reasonably inferred therefrom.
(실시예)(Example)
하기 표 1에 기재된 성분계를 만족하는 강슬라브를 1250℃로 가열하고 하기 표 2에 기재되어 있는 온도에서 열간마무리압연을 행하였다. 그 후, 680℃의 온도까지 70℃/초의 냉각속도로 1차 냉각, 6초 동안 공냉, 450℃의 온도까지 70℃/초의 냉각속도로 2차 냉각을 행한 후 하기 표 2에 기재되어 있는 온도에서 권취하였다. The steel slab satisfying the component system shown in Table 1 below was heated to 1250 ° C. and hot-rolled at the temperature shown in Table 2 below. Thereafter, primary cooling at a cooling rate of 70 ° C./sec to a temperature of 680 ° C., air cooling for 6 seconds, and secondary cooling at a cooling rate of 70 ° C./sec to a temperature of 450 ° C., followed by the temperatures shown in Table 2 below Wound up in.
권취 공정을 완료하여 얻은 최종 열연강판의 항복강도(YS), 인장강도(TS), 파괴연신율(T-El), 신장플렌지성(Hole Expanding Ratio, HER) 평가하여 하기 표 2에 나타내었다.Yield strength (YS), tensile strength (TS), elongation at break (T-El), and elongated flange property (Hole Expanding Ratio, HER) of the final hot-rolled steel sheet obtained by completing the winding process were shown in Table 2 below.
또한, 페라이트 조직 내의 베이나이트 분율은 최종 열연강판을 에칭한 후 광학현미경을 이용하여 500배율로 관찰 한 후 이미지 분석기로 분삭한 후, 하기 표 2에 상분율을 기재하였다.In addition, the bainite fraction in the ferrite structure was observed at 500 magnification using an optical microscope after etching the final hot rolled steel sheet, and then fractionated with an image analyzer.
더불어, 상기 최종 열연강판의 용접성도 하기 표 2에 나타내었다. 상기 용접성은 표 3에 나타난 조건으로 용접을 행한 후 강판의 용접부 강도를 일축 인장시험법으로 측정하였다. 이때, 용접부가 파단될 경우 용접성이 열위한 것으로 평가하였다.In addition, the weldability of the final hot rolled steel sheet is also shown in Table 2 below. The weldability was measured by the uniaxial tensile test method after welding under the conditions shown in Table 3. At this time, the weldability was evaluated as being poor when the welded part was broken.
표 1
구분 C Si Mn Cr Al P S N Ti Mo Nb V
비교예1 0.05 0.6 1.5 0 0.03 0.01 0.003 0.004 0 0.01 0.05 0
비교예2 0.06 0.5 1.6 0 0.1 0.01 0.003 0.004 0 0.01 0.02 0.02
비교예3 0.06 0.8 1.8 0 0.03 0.01 0.003 0.004 0.04 0.01 0 0
비교예4  0.06 1.2 1.6 0 0.03 0.01 0.003 0.004 0.02 0.01 0.05 0
비교예5 0.07 1 1.6 0 0.03 0.01 0.003 0.004 0.04 0.01 0 0.025
비교예6  0.07 0.8 1.8 0 0.03 0.01 0.003 0.004 0.02 0.01 0.02 0.03
비교예7 0.08 1.2 1.6 0 0.1 0.01 0.003 0.004 0.04 0.01 0.03 0
비교예8 0.08 1.5 1.8 0 0.03 0.01 0.003 0.004 0.06 0.04 0.025 0
비교예9 0.1 1 1.8 0.3 0.03 0.01 0.003 0.004 0.06 0.01 0.05 0.02
발명예1 0.08 0.05 1.5 0 0.03 0.01 0.003 0.005 0 0.01 0.05 0
발명예2 0.07 0.7 1.4 0.1 0.03 0.01 0.003 0.005 0.03 0.04 0.03 0
발명예3 0.04 1.1 1.7 0.7 0.03 0.01 0.003 0.005 0.06 0.01 0.03 0
발명예4 0.07 0.8 1.8 0.4 0.03 0.01 0.003 0.005 0.08 0.1 0.03 0.02
발명예5 0.08 0.6 1.8 0.4 0.03 0.01 0.003 0.004 0.03 0.01 0.02 0.03
발명예6 0.09 0.8 1.6 0.2 0.03 0.01 0.003 0.004 0.04 0.04 0.02 0.02
Table 1
division C Si Mn Cr Al P S N Ti Mo Nb V
Comparative Example 1 0.05 0.6 1.5 0 0.03 0.01 0.003 0.004 0 0.01 0.05 0
Comparative Example 2 0.06 0.5 1.6 0 0.1 0.01 0.003 0.004 0 0.01 0.02 0.02
Comparative Example 3 0.06 0.8 1.8 0 0.03 0.01 0.003 0.004 0.04 0.01 0 0
Comparative Example 4 0.06 1.2 1.6 0 0.03 0.01 0.003 0.004 0.02 0.01 0.05 0
Comparative Example 5 0.07 One 1.6 0 0.03 0.01 0.003 0.004 0.04 0.01 0 0.025
Comparative Example 6 0.07 0.8 1.8 0 0.03 0.01 0.003 0.004 0.02 0.01 0.02 0.03
Comparative Example 7 0.08 1.2 1.6 0 0.1 0.01 0.003 0.004 0.04 0.01 0.03 0
Comparative Example 8 0.08 1.5 1.8 0 0.03 0.01 0.003 0.004 0.06 0.04 0.025 0
Comparative Example 9 0.1 One 1.8 0.3 0.03 0.01 0.003 0.004 0.06 0.01 0.05 0.02
Inventive Example 1 0.08 0.05 1.5 0 0.03 0.01 0.003 0.005 0 0.01 0.05 0
Inventive Example 2 0.07 0.7 1.4 0.1 0.03 0.01 0.003 0.005 0.03 0.04 0.03 0
Inventive Example 3 0.04 1.1 1.7 0.7 0.03 0.01 0.003 0.005 0.06 0.01 0.03 0
Inventive Example 4 0.07 0.8 1.8 0.4 0.03 0.01 0.003 0.005 0.08 0.1 0.03 0.02
Inventive Example 5 0.08 0.6 1.8 0.4 0.03 0.01 0.003 0.004 0.03 0.01 0.02 0.03
Inventive Example 6 0.09 0.8 1.6 0.2 0.03 0.01 0.003 0.004 0.04 0.04 0.02 0.02
표 2
구분 FDT(℃) CT(℃) 수학식1 YS(MPa) TS(MPa) T-El(%) HER(%) TSxHER 베이나이트 분율(%) 용접성
비교예1 886 461 11.150 420 420 29 91 44317 7 X
비교예2 893 452 11.212 504 573 27 87 49851 9 X
비교예3 899 455 11.247 522 634 25 80 50720 8 X
비교예4 902 460 11.247 577 710 54 65 46150 9 X
비교예5 903 453 11.167 543 656 53 56 36736 10 X
비교예6 905 443 11.197 605 722 50 50 36100 11 X
비교예7 907 434 11.255 697 785 18 52 40820 8 X
비교예8 912 441 11.285 743 833 17 58 48314 10 X
비교예9 922 438 11.008 905 1011 14 35 35385 13 X
발명예1 892 440 11.018 548 636 25 89 56604 10 O
발명예2 887 443 11.068 537 622 26 79 49138 9 O
발명예3 882 467 11.059 736 862 21 62 53444 10 O
발명예4 891 445 10.925 866 1006 15 50 50300 14 O
발명예5 895 436 11.067 774 932 15 54 50328 12 O
발명예6 893 432 11.071 793 966 14 50 48300 13 O
TABLE 2
division FDT (℃) CT (℃) Equation 1 YS (MPa) TS (MPa) T-El (%) HER (%) TSxHER Bainite fraction (%) Weldability
Comparative Example 1 886 461 11.150 420 420 29 91 44317 7 X
Comparative Example 2 893 452 11.212 504 573 27 87 49851 9 X
Comparative Example 3 899 455 11.247 522 634 25 80 50720 8 X
Comparative Example 4 902 460 11.247 577 710 54 65 46150 9 X
Comparative Example 5 903 453 11.167 543 656 53 56 36736 10 X
Comparative Example 6 905 443 11.197 605 722 50 50 36100 11 X
Comparative Example 7 907 434 11.255 697 785 18 52 40820 8 X
Comparative Example 8 912 441 11.285 743 833 17 58 48314 10 X
Comparative Example 9 922 438 11.008 905 1011 14 35 35385 13 X
Inventive Example 1 892 440 11.018 548 636 25 89 56604 10 O
Inventive Example 2 887 443 11.068 537 622 26 79 49138 9 O
Inventive Example 3 882 467 11.059 736 862 21 62 53444 10 O
Inventive Example 4 891 445 10.925 866 1006 15 50 50300 14 O
Inventive Example 5 895 436 11.067 774 932 15 54 50328 12 O
Inventive Example 6 893 432 11.071 793 966 14 50 48300 13 O
표 3
용접조건 초기간극(㎜) 최종간극(㎜) 업셋길이(㎜) 용접시간(초) 업셋시간(초) 업셋전류(%) 업셋압력(kgf/㎠)
13 13 2.0 4 0.5 60 60
TABLE 3
Welding condition Initial clearance (mm) Final clearance (mm) Upset length (mm) Welding time (sec) Upset time (seconds) Upset Current (%) Upset pressure (kgf / ㎠)
13 13 2.0 4 0.5 60 60
상기 표 2에 나타난 바와 같이, 발명예 1 내지 6은 본 발명이 제안한 성분 범위 및 제조조건을 만족함으로써, 인장강도와 신장플랜지성의 곱의 값이 높고 용접성이 우수한 열연강판을 확보할 수 있음을 확인할 수 있다.As shown in Table 2, Inventive Examples 1 to 6 satisfy the component range and manufacturing conditions proposed by the present invention, it is possible to secure a hot rolled steel sheet having a high value of the product of tensile strength and elongated flange property and excellent weldability. You can check it.
반면에, 비교예 1,4, 5, 6 및 7은 수학식 1을 만족하지 못하여 용접성이 열위한 것을 확인할 수 있다.On the other hand, Comparative Examples 1, 4, 5, 6 and 7 do not satisfy the equation (1) can be confirmed that the weldability is inferior.
또한, 비교예 2,3 및 8은 인장강도와 신장플랜지성 곱의 값이 본 발명이 제안한 범위의 값을 만족하였지만, 수학식 1을 만족하지 않아, 용접성이 열위한 것을 확인 할 수 있다. In addition, Comparative Examples 2, 3 and 8, although the value of the product of tensile strength and extension flange property satisfied the value of the range proposed by the present invention, it does not satisfy the equation 1, it can be confirmed that the weldability is inferior.

Claims (7)

  1. 중량%로, C:0.03~0.1%, Si: 0.01~1.2%, Mn: 1.2~1.9%, Al: 0.01~0.08%, Cr: 0.005~0.8%, Mo: 0.01~0.12%, P: 0.01~0.05%, S: 0.001~0.005%, N: 0.001~0.01%, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 동시에 상기 각 성분들은 하기 수학식 1을 만족하고, 인장강도와 신장플랜지성의 곱이 48000이상인 용접성 및 버링성이 우수한 열연강판.By weight%, C: 0.03 to 0.1%, Si: 0.01 to 1.2%, Mn: 1.2 to 1.9%, Al: 0.01 to 0.08%, Cr: 0.005 to 0.8%, Mo: 0.01 to 0.12%, P: 0.01 to 0.05%, S: 0.001% to 0.005%, N: 0.001% to 0.01%, balance Fe and other unavoidable impurities, each of the above components satisfy the following Equation 1, and the weldability of which the product of tensile strength and extension flange property is 48000 or more. And hot rolled steel sheet having excellent burring property.
    수학식 1: 10.646 + 0.2[C] + 0.25[Si] +0.3[Mn] - 0.1[Cr]+ 0.55[Al] +0.2[Mo] -4.23[Ti] -2.5[Nb] - 2.9[V] ≤ 11.1 Equation 1: 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ≤ 11.1
    (단, 상기 수학식 1에서 C, Si, Mn, Cr, Al, Mo, Ti, Nb 및 V는 각각 해당원소의 함량(중량%)임)(However, in the above Equation 1, C, Si, Mn, Cr, Al, Mo, Ti, Nb and V are the content (weight%) of the corresponding element, respectively)
  2. 제 1 항에 있어서,The method of claim 1,
    Nb, Ti 및 V 중에서 선택된 1종 이상의 중량을 합하여 0.001~0.15중량% 더 포함하는 용접성 및 버링성이 우수한 열연강판.Hot-rolled steel sheet excellent in weldability and burring properties, including 0.001 to 0.15% by weight of at least one selected from Nb, Ti, and V in total.
  3. 제 1항에 있어서,The method of claim 1,
    페라이트 조직 내에 베이나이트 상 분율이 5~20%를 포함하는 미세조직을 가지는 용접성 및 버링성이 우수한 열연강판.Hot-rolled steel sheet having excellent weldability and burring property having a microstructure containing 5-20% of bainite phase fraction in a ferrite structure.
  4. 중량%로, C:0.03~0.1%, Si: 0.01~1.2%, Mn: 1.2~1.9%, Al: 0.01~0.08%, Cr: 0.005~0.8%, Mo: 0.01~0.12%, P: 0.01~0.05%, S: 0.001~0.005%, N: 0.001~0.01%, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 동시에, 상기 각 성분들이 하기 수학식 1을 만족하는 강 슬라브를 준비하는 단계;By weight%, C: 0.03 to 0.1%, Si: 0.01 to 1.2%, Mn: 1.2 to 1.9%, Al: 0.01 to 0.08%, Cr: 0.005 to 0.8%, Mo: 0.01 to 0.12%, P: 0.01 to Preparing a steel slab containing 0.05%, S: 0.001% to 0.005%, N: 0.001% to 0.01%, residual Fe and other unavoidable impurities, wherein each of the components satisfies Equation 1 below;
    상기 강 슬라브를 1200~1300℃에서 재가열 하는 단계;Reheating the steel slab at 1200-1300 ° C .;
    상기 재가열된 강 슬라브를 850~1000℃의 마무리압연온도로 열간압연하여 강판을 얻는 단계;Hot rolling the reheated steel slab to a finish rolling temperature of 850 to 1000 ° C. to obtain a steel sheet;
    상기 열간압연된 강판을 500~750℃의 온도까지 10~100℃/초의 냉각속도로 1차 냉각하는 단계;Primary cooling the hot rolled steel sheet at a cooling rate of 10 to 100 ° C./sec to a temperature of 500 to 750 ° C .;
    상기 냉각된 강판을 4~10초 동안 공냉하는 단계; 및Air cooling the cooled steel sheet for 4 to 10 seconds; And
    상기 공냉된 강판을 300~500℃의 온도까지 10~100℃/초의 냉각속도로 2차 냉각하는 단계를 포함하는 용접성 및 버링성이 우수한 열연강판의 제조방법.The method of manufacturing a hot rolled steel sheet having excellent weldability and burring property comprising the step of second cooling the air-cooled steel sheet to a temperature of 300 ~ 500 ℃ at a cooling rate of 10 ~ 100 ℃ / sec.
    수학식 1: 10.646 + 0.2[C] + 0.25[Si] +0.3[Mn] - 0.1[Cr]+ 0.55[Al] +0.2[Mo] -4.23[Ti] -2.5[Nb] - 2.9[V] ≤ 11.1 Equation 1: 10.646 + 0.2 [C] + 0.25 [Si] +0.3 [Mn]-0.1 [Cr] + 0.55 [Al] +0.2 [Mo]-4.23 [Ti] -2.5 [Nb]-2.9 [V] ≤ 11.1
    (단, 상기 수학식 1에서 C, Si, Mn, Cr, Al, Mo, Ti, Nb 및 V는 각각 해당원소의 함량(중량%)임)(However, in the above Equation 1, C, Si, Mn, Cr, Al, Mo, Ti, Nb and V are the content (weight%) of the corresponding element, respectively)
  5. 제 4항에 있어서,The method of claim 4, wherein
    상기 슬라브는 Nb, Ti 및 V 중에서 선택된 1종 이상의 중량을 합하여 0.001~0.15중량% 더 포함하는 용접성 및 버링성이 우수한 열연강판의 제조방법.The slab is a method of manufacturing a hot-rolled steel sheet having excellent weldability and burring properties further comprises 0.001 to 0.15% by weight of one or more weights selected from Nb, Ti and V.
  6. 제 4항에 있어서,The method of claim 4, wherein
    상기 강판을 자연냉각한 후 산세하는 단계를 더 포함하는 용접성 및 버링성이 우수한 열연강판의 제조방법.The method of manufacturing a hot rolled steel sheet having excellent weldability and burring property, further comprising the step of pickling the steel sheet after natural cooling.
  7. 제 6항에 있어서,The method of claim 6,
    상기 산세하는 단계 후 450~480℃에서 재가열하고 용융아연도금을 행하는 단계를 더 포함하는 용접성 및 버링성이 우수한 열연강판의 제조방법.Re-heating at 450 ~ 480 ° C after the pickling and hot-dip galvanizing method further comprising the step of performing hot dip galvanizing.
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