WO2015085536A1 - Multi-component bristle having components with different oral care additives, and oral care implement comprising the same - Google Patents

Multi-component bristle having components with different oral care additives, and oral care implement comprising the same Download PDF

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Publication number
WO2015085536A1
WO2015085536A1 PCT/CN2013/089206 CN2013089206W WO2015085536A1 WO 2015085536 A1 WO2015085536 A1 WO 2015085536A1 CN 2013089206 W CN2013089206 W CN 2013089206W WO 2015085536 A1 WO2015085536 A1 WO 2015085536A1
Authority
WO
WIPO (PCT)
Prior art keywords
oral care
component
bristle
core
sheath
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2013/089206
Other languages
English (en)
French (fr)
Inventor
Wen Jin Xi
Ting YAN
Bo Zhang
Guang Sheng Guo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to KR1020167014466A priority Critical patent/KR20160098211A/ko
Priority to RU2016123145A priority patent/RU2639640C1/ru
Priority to EP13899050.2A priority patent/EP3068263B1/en
Priority to JP2016537985A priority patent/JP2016539730A/ja
Priority to CN201380081417.9A priority patent/CN105813504B/zh
Priority to AU2013407533A priority patent/AU2013407533B2/en
Priority to PCT/CN2013/089206 priority patent/WO2015085536A1/en
Priority to MX2016007271A priority patent/MX376267B/es
Priority to US15/102,817 priority patent/US10299580B2/en
Priority to BR112016012422-7A priority patent/BR112016012422B1/pt
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Priority to TW103142949A priority patent/TW201534250A/zh
Publication of WO2015085536A1 publication Critical patent/WO2015085536A1/en
Anticipated expiration legal-status Critical
Priority to AU2017202293A priority patent/AU2017202293B2/en
Priority to US15/595,640 priority patent/US10477958B2/en
Ceased legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/023Bristles with at least a core and at least a partial sheath
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B9/00Arrangements of the bristles in the brush body
    • A46B9/02Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
    • A46B9/04Arranged like in or for toothbrushes
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B11/00Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water
    • A46B11/0003Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water containing only one dose of substance, e.g. single-use toothbrushes
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B9/00Arrangements of the bristles in the brush body
    • A46B9/02Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
    • A46B9/028Bristle profile, the end of the bristle defining a surface other than a single plane or deviating from a simple geometric form, e.g. cylinder, sphere or cone
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0276Bristles having pointed ends
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0284Bristles having rounded ends
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B11/00Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water
    • A46B11/0072Details
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/10For human or animal care
    • A46B2200/1066Toothbrush for cleaning the teeth or dentures

Definitions

  • Toothbrushes are typically used by applying toothpaste or dentifrice to a bristle section on the h ad of the toothbrush, followed by brushing regions of the oral vity (e .g., the teeth or soft tissue such as the tongue and/or gums) with the bristle section.
  • regions of the oral vity e .g., the teeth or soft tissue such as the tongue and/or gums
  • Some toothbrushes have been equipped with internal reservoirs and systems for delivering dentifrice to a user's oral cavity
  • Other toothbrushes have been developed that include dentifrice that is pre-coated onto the bristles.
  • dentifrice or a single oral care additive is available for application to a user's oral cavity.
  • Exemplary embodiments according to the present dis losure are directed to oral care implements that have at l st one multi-component bristle xtending from the head thereof.
  • the multi-component bristle is formed by a core component and a sheath component surrounding at least a portion of the core component.
  • each of the core and sheath components comprises a different oral care additive.
  • only one of the core and sheath components comprises an oral care additive.
  • each of the core and she th components comprises the same oral care additive.
  • t e invention c n be an oral care implement comprising a handle ; a head coupled to the handle; at least one bristle tuft extending from the head, the at least one bristle tuft comprising at least one multi-component bristle comprising coextruded core and sheath components, the sheath component surrounding a first portion of the core component, and a second portion of the core component protruding from the she th component at a tip portion of the multi-component bristle; the sheath component comprismg a first plastic and a first oral care additive; the core component comprising a second plastic and a second oral care additive, wherein the first oral care additive is different than the second oral care additive.
  • the invention can be an oral care implement comprismg: a handle ; a head coupled to the handle; at least one bristle tuft extending from the head, the at least one bristle tuft comprising at least one mult-component bristle comprising coextiuded core and sheath components, the sheath component surrounding a first portion of the core component, and a second portion of the core component protruding from the sheath component at a tip portion of the multi-component bristle; the sheath component comprising a first plastic; the core component comprising a second plastic; and wherein one of the core and sheath compon nts comprises an oral care additive and the other one of the core and sheath components is free of an oral care additive.
  • the invention can be a multi-component bristle comprising: a core component; a sheath component, the sheath component surrounding a first portion of the core component ⁇ a second portion of the core component protruding from the sheath component at a tip portion of the multi-component bristle ; the sheath component comprising a first plastic and a first oral care additive; and the core component comprising a second plastic and a second oral care additive, wherein the first oral care additive is different than the second oral care additive.
  • Figure 1 is a front perspective view of an oral care implement livin multi-component bristles according to an embodiment of the pres nt invention
  • Figure 2 A is a front perspective view of a multi-component bristle in accordance with a first n ⁇ odiment of the present invention
  • Figure 2B is a cross-sec tional view taken along line IIB-IIB in FIG. 2A;
  • Figure 2C is a cross-sec tional view taken along line IIC-IIC in FIG. 2A;
  • Figure 3 A is a front perspective view of a multi-component bristle in accordance with a second en ⁇ odiment of the present invention.
  • Figure 3B is a cross-sec tional view taken along line IIIB-IIIB in FIG. 3A
  • Figure 3C is a cross-sec tional view taken along line IIIC-IIIC in FIG. 3A;
  • Figure 4A is a front perspective view of a multi-component bristle in accordance with a third embodiment of the present invention.
  • Figure 4B is a cross-sec tional vi w taken along line IVB-1VB of FIG. 4A;
  • Figure 4C is a cross-sec tional view taken along line IVC-IVC of FIG. 4A;
  • Figure 5 A is a first alternative mbodiment of FIG. 2B.
  • Figure 5B is a second alternative embodiment of FIG. 2B.
  • Relative terms such as “lower,” ''upper ' “horisDntaL” 'Vertical,” “above,” “below,” “up,” “down,” “top” and “bottom” as well as derivatives thereof (e.g., “horizontally” “downwardly” “upwardly,” et .) should be construed to refer to the orientation as then described or as shown in the drawing under discussion. These relative terms are for convenience of description only and do not require that the apparatus be constructed or operated in a particular orientation unless explicitly indicated as such.
  • an oral care implement 100 is illustrated in accordance with an embodiment of the present invention.
  • the oral care implement 100 is in the form of a manual toothbrush.
  • the oral care implement 100 can take on other forms such as b ing a powered toothbrush, a tongue scraper, a gum and soft tissue cleanser, a water pick, an interdental device, a tooth polisher, a specially design d ansate implement having tooth engaging elements or any other type of implement that is commonly used for oral care.
  • a spe ific type of oral care implement is spec ifie d in the claims .
  • the oral care implement 100 generally includes an elongated body 101 comprising a head 1 10, a neck 1 15 and a handle 120.
  • the handle 120 is an elongated structure that ptovides the mechanism by which the user can hold and manipulate the oral care implement 100 during use .
  • the handle 120 comprises a front surface 124 and an opposing rear surface 125.
  • the handle 120 is gen tically depicted having various contours for user comfort.
  • the handle 120 is bulbous shaped and has a larger diameter in a central region than near the proximal end 103 and neck 115. Specifically a region of the handle 120 that would normally be grippedbya user's thumb has a width that is greater than a width of the neck 1 15.
  • the handle 120 can take on a wide variety of shapes, contouis and configurations, none of which are limiting of the present invention unless so specified in the claims.
  • the handle 120 is formed of a rigid plastic material, such as for example without limitation polymers and copolymers of ethylene, propylene, butadiene, vinyl compounds and polyesteis such as polyethylene teiephthalate .
  • the handle 120 may include a resilient material, such as a thermoplastic elastomer, as a grip cover that is molded over portions of or the entirety of the handle 1 0 to enhance the gripabilityof the handle 120 during use.
  • a resilient material such as a thermoplastic elastomer
  • portions of the handle 120 that are typically gripped by a user's palm during use may be overmolded with a thermoplastic elastomer or other resilient material to further increase comfort to a user.
  • the head 110 of the oral care imple ment 100 is couple d to the handle 1 0 and comprises a front surface 112 and an opposing rear surface 113.
  • the head 110 is formed integrally with the handle 120 as a single unitary structure using a molding, milling, machining or other suitable process.
  • the handle 120 and the head 1 10 maybe formed as separate components which are operably connected at a later stage of the manufacturing process by any suitable technique known in the ait, including without limitation thermal or ultrasonic welding, a tight- fit assembl a coupling sleeve, threaded engagement adhesion, or fasteneis.
  • the head 1 10 of the oral care implement 100 is provided with a plurality of tooth cleaning elements 111 extending from the front surface 1 12.
  • the tooth cleaning elements 1 1 1 include at least one bristle tuft comprising at least one multi- component bristle comprising a core component and a sheath component. The details of various structural forms for a multi-component bristle will be described in more detail below with reference to FIGS . 2-5.
  • a bristle tuft is a collection of bristles that are positioned together into a single tuft hole formed on the head 110.
  • Each bristle tuft may include, for example without limitation, only multi-component bristles, a combination of multi-component bristles and single -component (i.e., tiaditional) bristles, or only single-component bristles.
  • the oial care implement 100 may include one or more bristle tufts that include exactly one multi-component bristle and a plurality of single -component bristles or one or more bristle tufts that include only multi-component bristles.
  • the tooth cleaning elements 111 may all be formed as bristle tufts that are formed solely of multi-component bristles. Furthermore, in some embodiments the tooth cleaning elements 111 may include some bristle tufts that are formed solely of single -component bristles and some bristle tufts that are formed solely of multi- component bristles, and the singl -component bristle tufts and multi-component bristle tufts may be positione d on the head 110 of the oral care implement 100 in an alternating or non-alternating fashion (i.e ., alternating or non-alternating transverse rows of bristle tufts, alternating or non- alternating longitudinal rows of bristles, or even alternating or non-alternating tufts in each row).
  • alternating or non-alternating fashion i.e ., alternating or non-alternating transverse rows of bristle tufts, alternating or non- alternating longitudinal rows of bristles, or even alternating or non-alternating tufts in each row.
  • tooth cleaning elements is used in a generic sense to refer to any structure that can be used to clean, polish or wipe the teeth and/or soft oral tissue (e.g. tongue, cheek, gums, etc.) through relative surface contact.
  • 'tooth cleaning elements include, without limitation, bristle tufts, filament bristles, fib r bristles, nylon bristles, spiral bristles, rubber bristles, elastomeric protrusions, flexible polymer protrusions, combinations there of and/or structures containing such materials or combinations.
  • Suitable elastomeric materials include any biocompatible resilient material suitable for uses in an oral hygiene apparatus.
  • the elastomeric material of the tooth or soft tissue engaging elements has a hardness property in the range of AS to A25 Shore hardness.
  • styrene-emylenertmtylene-styrene block copolymer
  • the tooth cteaning elements 111 of the present invention can be connected to the head 110 in any manner known in the art.
  • staples/anchors, in- mold tufting ( ⁇ ) or anchor free tufting (AFT) could be used to mount the cleaning elements/tooth engaging elements.
  • the invention can be practiced with various c ordinations of stapled, HVIT or AFT bristles.
  • AFT a plate or membrane is secured to the brush head such as by ultrasonic welding. The bristles extend through the plate or membrane. The free ends of the bristles on one side of the plate or membrane perform the cleaning function.
  • the ends of the bristles on the other side of the plate or membrane are melted together by he at to be anchored in place.
  • Any suitable form of cleaning elements may be used in the broad practice of this invention.
  • the bristles could be mounted to tuft blocks or sections by extending through suitable openings in the tuft blocks so that the base of the bristles is mounted witiun or below the tuft block.
  • one tuft of bristles may include one double strand multi-component bristle and a plurality of single strand bristles or only double strand multi-component bristles or only triple strand multi-component bristles or a combination of single strand bristles, double strand multi- component bristles and triple strand mult-component bristles.
  • a single tuft hole ma be filled with an elastomeric cle aning e lement or any of the other tjjp s of c leaning e leme nts noted above.
  • At least one bristle tuft includes at least one multi-component bristle, which may be a double, triple or otherwise strand multi-component bristle.
  • the details of the multi-component bristles will be discussed in more detail b w with reference to Figures 2-5.
  • the he d 110 may also include a soft tissue cleanser coupled to or positioned on its rear surface 113.
  • a soft tissue cleanser coupled to or positioned on its rear surface 113.
  • An example of a suitable soft tissue leans r that maybe used with the present invention and positioned on the rear surface of the head 1 10 is disclosed in U.S . Patent No. 7,143,462, issued December 5, 2006 to the assignee of the pre se nt applic ation, the entirety of whic h is he reby incorporated by re ferenc e .
  • the soft tissue cleanser may include protuberances, which can take the form of e longated ridge s, nubs, or c onitoinatons the reof .
  • the inve ntion is not to be so limited and in c rtain embodiments the oral are implement 100 may not include any soft tissue cleanser.
  • the multi-component bristle 200 extends from a base end 201 to a free end 202 along a longitudinal axis A- A.
  • the multi-component bristle 200 comprises a core component 210 and a sheath component 220 that are coextruded to form the multi-component bristle 200.
  • the multi- component bristle 200 comprises the coe truded core and sheath components 210, 220.
  • the sheath component 220 surrounds a first portion 215 of the core component 210 and a se ond portion 216 of the core omponent 210 protrudes from the sheath component 220 at a tp portion 230 of the multi-component bristle 200.
  • the second portion 216 of the core component 210 is therefore exposed whereas the first portion 215 of the core component 210 is not exposed.
  • each of the core and sheath components 210, 220 is visible from an exterior of the multi-component bristle 200, and more specifically an entirety of the sheath c omponent 220 is visible and the sec ond portion 21 of the core component 210 is visible from the exterior of the multi- omponent bristle 200.
  • each of the core and sheath components 210, 220 extend all the way to the base nd 201 of the multi-component bristle 200.
  • the core component 210 ex tends fiom the base end 201 of the multi -component bristle 200 to the free end 202 of the multi-component bristle 200.
  • the sheath component 220 extends from the base end 201 of the multi-component bristle 200 to a terminal end 203 of the sheath component 220.
  • the second portion 216 of the core component 210 makes up between approximately 15-20% of the total length of the multi- omponent bristle 200, more specifically betTM en approximately 17-23% of the total length of the multi-component bristle 200, and even moie specifically between approximately 20-22% of the total length of the multi-component bristle 200.
  • the exposed second portion 2 I D " of the core component 210 may make up between approximately 10-15%, and more spec ificaUybetwe en approximately 12- 13% of the total length of the multi-component bristle 200.
  • the sheath component 220 extends approximately 75-80% of the total length of the multi-component bristle 200, more specifically approximately 77-83% of the total length of the multi-component bristle 200, and even more specifically between approximately 78-80% of the total length of the multi- component bristle 200, or betwe n approximately 85-90% or 87-88% of the total length of the multi-component bristle 200.
  • the multi- omponent bristle 200 has a cylindrical cross- sectional shape .
  • the core component 210 has a cylindrical cross-sectional shape and the sheath component 220 has a ring-like shape that ircumferentially and con ntrically suiTounds the core component 210 for at least part of the length of the core component 210.
  • the invention is not to be so limited and the core component 210 can take on other polygonal shapes as desired and the shape of the sheath component 220 can likewise change so long as the sheath component 220 circumferentially surrounds the core component 210 for at least a portion of the length of the c ore component 210.
  • each of the core and sheath components 210, 220 can house the same oral care additive, a different oral care additive, or only one of the two or more components that forms the multi-component bristle 200 can contain an oral care additive while the other of the two or more components maybe devoid of an oral care additive.
  • two or more oral care additives can be housed separately on different components (i.e., core and sheath components) of a single multi - component bristle and can be made to internm during use of the multi-component bristle (or oral care impleme t on which the multi-component bristle is disposed).
  • Intermixing of two or more oral care additive s can be beneficial so that a che mical re action occ urs within a use r 's oral c avity and so that in some circumstances a third oral care additive or agent can be formed by the reaction of the first and second oral care additives within the user's oral cavity.
  • the core component 210 comprises a first plastic 21 1 and a first oral care additive 21 and the sheath component 220 comprises a second plastic 221 and a second oral care additive 222, the second oral care additive 222 b ing different than the first oral care additive 221.
  • the oral care additive 212 in the core compone nt 210 is illustrated as round dots and the oral c are additive 222 in the sheath component 220 is illustrated as square dots to schematically illustrate that each of the core and sheath components 210, 220 contains a different oral care additive .
  • each of the core and sheath components 210, 220 may have the same oral care additive, or one of the core and sheath components 210, 220 maybe devoid of an oral care additive while the other of the core and sheath components 210, 220 has an oral care additive.
  • a longitudinal ross-sectional view of a multi- component bristle 500 is illustrated that comprises a core component 510 and a sheath component 520.
  • the core component 510 is devoid or free of an oral care additive and the sheath component 520 comprises an oral care additive 522.
  • a longihidinal crass-sectional view of a multi-component bristle o ⁇ 00 is illustrated that comprises a core component o ⁇ 10 and a sh th component 620.
  • the core component o " 10 comprises an oral care additive 612
  • the sheath component o " 20 is devoid or free of an oral c are additive .
  • forming the core component 210 is achieved by melting the first plastic 21 1 and dispersing particles of the first oral care additive 212 within the melted first plastic 21 1 .
  • the particles of the first oral care additive 212 are thereby mined into the first plastic 211 so that the core component 210, when formed, will contain the first oral care additive 212.
  • forming the sheath component 220 is achieved by melting the second plastic 221 and dispersing particles of the second oral care additive 222 within the melted second plastic 221 .
  • the particles of the second oral care additive 222 are thereby mixed into the second plastic 221 so that the sheath component 220, when formed, will contain the second oral care additive 222.
  • the first and second oral care additives 212, 222 can be the same or different.
  • the first and second melted plastics 21 1, 221 will become hardened and the first and second oral care additives 212, 222 will be housed, contained or dispersed within the respective first and second plastics 21 1, 221 .
  • the first and se ond plastics 21 1, 221 can be coextruded to form the multi-component bristle 200 from the core and sheath components 210, 220.
  • first plastic 211 with the first oral care additive 212 therein can be formed into the core component 210 and the second plastic 221 with the second oral care additive 222 therein can be separately formed into the sheath component 220 (either by separate extrusion processes or any other bristle strand forming process now known or later developed), and then the core and sheath components 10, 220 can be coupled together to form the multi-component bristle 200.
  • the multi-component bristle 200 is formed from the core and sheath components 10, 220, each of which contains a different (or the same) oral care additive or agent therein.
  • one of the core and sheath components 210, 220 maybe formed without dispersing an oral care additive therein if desired.
  • the oral care additiv s need not be applied to the melted plasti s in particle form. Rather, in certain embodiments the oral care additives 212, 222 can be added to the respective core and sh ath components 210, 220 by forming the core and sheath compon nts 210, 220 with a tactile or sticky texture to hold the oral care additives 212, 222 thereon, or by forming the core and sheath components 210, 220 with grooves, ledges, holes, hollows or other features and or surface structure, shape or configuration that facilitates the housing of a powd r, liquid, gel, paste or other form of oral care additive .
  • the oral care additive can be attached to or otherwise interspersed within the core and sheath compon nts 210, 220 after formation thereof.
  • the oral care additives 1 , 222 are re leasable from the first and second plastics 21 1, 222 and from the core and sheath components 210, 220 of the multi- component bristle 200, particularly during use of the oral care implement 100 as will be described in more detail below, in orde r to provide oral he alth benefits to a user.
  • the oral care additives in any form (i.e., particle, powder, liquid, gel, paste etc.), maybe embedded or housed within or otherwise carried by one or more carrieis which are then formed into, housed or contained within the core and sheath components 210, 220.
  • the first oral care additive 212 maybe carried by a first carrier and the second oral care additive 222 ma be carried by a second carrier.
  • each of the first and second carriers maybe one or more water-soluble polymers.
  • the oral care additivies 212, 222 maybe carried by disposed within or embedded within the one or more water-soluble polym is, and then the water-soluble polymers can be adde d to the me lte d plastic that is used to form the core and she ath components 210, 220 as de sc ribed above .
  • the c arrie rs will be mixed or formed into the plastic material that forms the c ore and sheath compone nts 210, 220, the c arrie E C artying the oral c are additives .
  • the first carrier may have a higher melting point than the melting point of the fust plastic 211 and for the second carrier to have a higher melting point than the melting point of the second plastic 221 so that the carrier or water-soluble polymer maintains its structure and retains the oral care additive therein when being added to the melted plastic .
  • the c arrie rs may the n be containe d or dispe rse d within the plastic as the plastic is formed into the core and sheath components 210, 220.
  • an outer surface of the carriers may blend with the plastic material of the core and/or sheath components 210, 220 to ensure that the carriers are mamtained on the multi-component bristle 200 until use.
  • an outer surface of the carriers may partially melt along with the plastic so that when the plastic hardens, the carrier hardens along with it and the plastic and the carrieis be come at least partially integrally coupled together.
  • each of the first and second carriers can comprise one or more degradable or dissolvable capsules that carry, contain or encapsulate the first and second oral care additives 212, 222 the rein.
  • the capsules maybe soluble in liquid, sue h as saliva, to release the oral care additives 212, 222 contained therein during use of the oral care implement 100. Stated another way the c psules degrade when subj cted to moisture and thus dissolve when mixed with the saliva of the user to release its contents.
  • the capsules may have frangible, thin walls that break, rupture or burst to release the oral care additives 212, 222 contained therein during use due to being contacted by or rubbed against the user's teeth.
  • each of the first and second carriers can comprise one or more matric s that carry the first and second oral care additives 212, 222. Similar to the capsules, the matrices may also dissolve or break to release the oral care additives 212, 222 contained therein during use of the oral care implement 100.
  • one of the first and second carriers can comprise one or more capsules carrying the first oral care additive and the other of the first and second carriers can comprise one or more matrices earring the second oral care additive, or each of the fiist and second carriers may comprise a combination of capsules and matrices that cany the respective oral care additives.
  • Using the carriers to house the oral care additives may assist in erisuring that the oral care additives are properly retained on the core and sh ath components 10, 220 and released into a user's oral cavity during use of the oral care implement 100.
  • the carriers are water-soluble polymers, such carrie s/ ater-soluble polymers will degrade, shrink or dissolve in the user's saliva during use of the oral care implement thereby releasing the oral care additives from the carriers and into a user's oral cavity.
  • solubility of such water-soluble polymers can be selected as desired to create a multi-compon nt bristle having imme diate re lease of all of the oral c are additive s contained the rein or a time d release of the oral care additives contained therein.
  • the first and/or second carriers maybe formed for timed or slow release of the oral care additives contained therein so that the benefits of the oral care additives can be obtaine d by the user over many uses of the oral c are imple ment 100.
  • the carriers may degrade over a period of three months so that upon the entire oral care additive having been released into the user's oral cavity during brushing, the user will know that it is time to replace the toothbrush.
  • the core and sheath components 10, 220 of the multi-component bristle 200 may change cob r upon the oral care additive contained therein being depleted to visually communicate to a user that toothbrush replacement is needed.
  • the multi-component bristles 200 can serve as both oral care additive containment/dispensing structures and as a wear indie ator.
  • the core component 210 may include first carriers (i.e., water- soluble polymeis) that degrade or dissolve within a first temporal period of time and the sheath component 220 may include second carriers (water-soluble polymers) that degrade or dissolve within a second temporal period of time so that the oral care additives within the second carriers do not begin to be released until the entirety of the oral care additives within the first carriers have been released.
  • first carriers i.e., water- soluble polymeis
  • second carriers water-soluble polymers
  • the first and/or second arriers may completely erode, degrade, shrink or dissolve during a first use so that the entirety of the oral care additives contained therein is released into the user's oral cavity during a single use.
  • the oral care implement 100 maybe a disposable or single use toothbrush.
  • the first and second oral care additives 21 1, 221 can be any of a variety of oial care addiuves that provide proven benefits to a user's oral health.
  • Such oral care additives include, without limitation, lotus seed; lotus flower, bamboo salt; jasmine; com mint; camellia; aloe ; gingko; tea tree oil; xylitol; sea salt; vitamin C; ginger; cactus; baking soda; pine tree salt; green tea; white pearl; black pearl; charcoal powder; nephrite or jade and Ag/Au+.
  • the lotus seed is the extract from lotus seeds and is a natural herb for anti-heating and the prevention of gum bleeding.
  • the lotus flower is the extract from the lotus flower and is a natural herb for anti- heating and the prevention of gum bleeding.
  • bamboo salt is the combination of a bamboo extract and salt and is used to diminish irLflammation and has anti -bacterial effects.
  • Jasmine is an extract from the jasmine flower and is a natural herb for anti-heating, ptieve ting gum bleeding and for mouth freshening.
  • Com mint is an extract from a com mint leaf and is a natural herb for anti- heating, anti-bacterial uses and mouth frestening.
  • Camellia is an extract from the camellia flower and is a natural herb for anti- heating and the prevention of gum bleeding.
  • Abe is an extract from the aloe leaf and is a natural herb for inflammation reduction and has anti -bacterial effects.
  • Gingko is an extract from the gingko leaf and is a natural herb for inflammation reduction and has anti-bacterial effects.
  • Tea tree oil is an extract from a tea tree and is a natural herb for diminishing inflammation and has anti-bacterial effects.
  • Xy tol is an extract from plants such as com, sugar cane, oak, birc h, etc . and c an be used for preve nting tooth decay.
  • Se salt is an extra t from the sea and an be used to reduce inflammation and has anti -bacterial effects.
  • Vitamin C is an extract from food and can be used to prevent gum bleeding and as an antioxidant.
  • Ginger is an extract fiom ginger and is a natural plant for dintinishing inflammation and has anti-bacterial effects.
  • Cactus is an extract from a cactus and it a natural plant for reducing inflammation and can be used as an antiox idant .
  • Backing soda is a chemistry product and can be used as an enamel protectant.
  • Fine tie e salt is a mix ture of the ex tract from pine tre es and salt and is an ancient Chinese medicine for preventing inflammation and anti-heating.
  • Green tea is an extiact from the green tea leaf and is a natural herb to prevent halitosis and inhibit bacteria growth.
  • White pearl is a kind of pearl powder and can be used for teeth whitening and teeth health improvement by calcium absorption.
  • Black pearl is a kind of pearl powder that can be used for teeth whitening, cleaning and stain removal.
  • each of the first and s cond oral care additives are selected from a group consisting of a mi ture of pine tiee extract and sail, a tea leaf extract, a pearl powder, a nephrite powder, a charcoal powder, and an antibacterial material.
  • the oral care additives are natural ingredients.
  • the oral care additive is charcoal, particularly in the embodiments of FIGS . 5 A and 5B wherein one of the core and/or sheath components 210, 220 is free of an oral care additive .
  • each of the core and sheath components 210, 220 may have a different color to provide both a visual aesthetic and to communicate information about the oral care additive contained on that particular component to a user.
  • the core compone t 210 is illustrated as being white in color and the sheath component 220 is illustrated as being gray in color.
  • the white and gray colors are me rely used to indicate that each of the core and sheath components 210, 220 can be a different color, but are not intended to indicate a spec ific cobr.
  • the c ore component 10 c an be any color (e .g ., white, red, blue, green, yellow, orange, etc .) and the sheath component 220 can also be any color (e.g., white, red, blue, green, yellow, orange, etc .).
  • the sheath component 220 can also be any color (e.g., white, red, blue, green, yellow, orange, etc .).
  • the color of the core and/or sheath components 210, 220 of the multi-component bristle 200 can be used to indicate a flavor of that particular component or a trigeminal effect that will be imparted to the user by that particular component.
  • a multi-component bristle may include a core component that contains an orange flavored oral care additive and a sheath component that contains a lemon flavored oral care additive .
  • the core component ma e orange in color and the sheath component maybe yellow in color to visually communicate their respective flavoE to a user.
  • a multi -component bristle may 1 re hide a core component that has a green tea extract and a sheath component that includes black pearl.
  • the core component maybe green in cobr and the sheath component maybe black in olor to visually communicate their respective oral care additives to a user.
  • the cobr lue can be used to inform a user that a particular component will provide a cooling trigeminal effect to the user
  • the cobr red n be used to inform a user that a particular component ontains an oral care additive that will boost bbod circulatton
  • the cobr purple can be used to inform a us r that a particular component contains an anu-inflammatory oial care additive, etc .
  • Color-coding the strand components of the mult-component bristles provides a desirable visual aesthetic as well as being informative for the user or consumer.
  • the oral care implement on which the multi- component bristles are contained may include a color-coded key on its handle, head, packaging or on a s parate instructiorLinformation sheet that is provided with the oral care implement ta inform the user of the message that the various cofored components are intended to convey
  • any of one or more of the above oral care additives can be included into each of the core and sheath compone ts 210, 220 that are used to form the multi- component bristle 200.
  • one of the above oral caie additives is included into the core component 210 and a second one of the above oral care additives is included into the sheath component 220, the second one of the above oral care additives being different than the first one of the above oral care additives.
  • the fust and second oral care additives may each have an agent that is selected so that during brushing the age nts of the first and sec ond oral c are additives mix togethe r to form a Ihird oral care additive or ag nt.
  • the fust and second oral care additives may remain chemically isolated from the second oral care additive despite the fust and second oral care additives being on the same multi- omponent bristle 200 because the first oral care additive is formed into or carried by the core component 210 and the se cond oral c are additive is forme d into or c arrie d by the sheath component 220.
  • the core and sheath components 210, 220 will get wet, which enables the first oral care additive 212 (or a portfon thereof) to be released from the core component 210 and the second oral care additive 222 (or a portion thereof) to be released from the sheath component 220.
  • the agents within those oral care additives may intermix within the user's oral cavity to form a third agent in some embodiments.
  • Inte rmix ing of the first and sec ond oral care additive s within the user's oral cavity can b e beneficial in certain instances. Specifically certain agents, medicaments, anesthetics, antimicrobial agents, polishes, white ners and other misc llaneous agents, substances and chemicals lose effectiveness over time . Thus, it may be desirable to apply such substances substantially immediately after their formation. Using the ore and sheath components 210, 220 of the multi-component bristle 200 as the structures on which the oral care additives are housed fa ilitates this mtermixing within the user's oral cavity.
  • the two oral care additives c an b e selected so that the y form a third oral care additive or agent upon intermixing within a user's oral cavity.
  • Some reactions that may occur include : (1) mixing a base with an acid to form a neutral; (2) mixing a base with a curing agent to form an epoxyresin; (3) mixing Bisphenol F with Epichchlorhydin to form diglycidyi ether of bisphenoal A (epoxy resin); (4) mixing calcium carbonate with hydrogen peroxide to form peroxide ; (5) mixing water with hydrogen pe roxide to form peroxide; (6) mixing potassium nitrate with stannous fluoride to form a s nsitivity agent; (7) mixing cl ⁇ rliexadine with silica to form an antimicrobial agent; (S) mixing cetylpyridinium chloride witli silica to form an antimicrobial agent; (9) mixing tricolsan with pyrophosphate
  • the core component 210 is formed of the first plastic 21 1 and the sheath component 220 is formed of the second plastic 221 .
  • e ch of the first and second plastics 21 1, 221 is the same.
  • both of the first and second plastics 21 1, 221 maybe erodible by an etchant or neither of the first and second plastics 21 1, 221 maybe erodible b y the etchant .
  • Hb weve r in othe r embodiments the first and sec ond plastics 211, 221 are different.
  • the first plastic 21 1 is erodible by an etchant and true second plastic 221 is chemically resistant by the etchant.
  • the first plastic 211 is a polyester, such as polyjutylene tere hthalate (PBT), and the second plastic 2 1 is a polyamide, such as nylon.
  • PBT polyjutylene tere hthalate
  • the invention is not to be limited by the particular materials that are used to form the core and sheath components 210, 220 unless so specified in the claims.
  • both the core and sheath components 210, 220 of the multi-component bristle 200 are tapered.
  • the sheath component 220 has a tapered se tion 224 and the core component 10 has a tapered section 214.
  • the tip portion 230 of the multi -component bristle 200 has a conical shape that decreases in transverse cross-se tional area moving from a transition point TP1 to the free end 202 of the multi- component bristle .
  • the transition point TP1 is the point on the multi-component bristle where the sheath component 220 begins to taper.
  • the core component 210 begins to taper at the tentorial end 203 of the sheath component 220. This is because, in certdn enibodiments, the core component 210 cannot taper betTM en the terminal end 203 of the sheath component 220 and the base end 201 of the multi-component bristle 200 because the core component 210 is covered by the sheath component 220 in that area. Thus, in particular when chemical etching is used to taper the multi-component bristle 200, only the ex pose d sec ond portion 16 of the core component 210 will be tape red.
  • the taper is continuous from the transition point TP1 to the free end 202 of the multi-component bristle 200.
  • the reduction in cross-sectional area from the transition point TP 1 to the free end 202 is constant and continuous, which results in a smooth transition between the sheath component 220 and the core component 210.
  • the core component 210 begins to taper where the sheath component 220 ends so that there are no bumps, ridges, edges, points or grooves in the location between the core and sheath components 210, 220, but rather simply a smooth transition.
  • the transverse cross-se tional area of the sheath component 220 at the terminal end 203 of the sheath component 220 is identical to the cross-sectional area of the core component 210 at the terminal end 203 of the sheath compone nt 220. Due to the core compone nt 210 beginning to taper ex actly at the terminal end 203 of the sheath component 220, the tip portion 230 of the multi-component bristle 200 has a continuous, uninterrupted taper despite being formed partially by the sheath component 220 and partially by the core component 210.
  • the tip portion 230 of the multi-component bristle 200 is forme d by the tape red se ction 214 of the core component 210 and the tapered se ction 224 of the sheath component 220.
  • the core component 210 forms a larger part of the tip portion 230 of the multi-component bristle 200 than the sheath component 220.
  • the tapered section 214 of the core component 210 has a greater length than the tapered section 224 of the sheath component 220 (m as tted either vertically along the longitudinal axis A- A or measured along the outer boundary/ oute r surface of the multi-compon nt bristle 200).
  • the core and sheath components 210, 220 can each form the same amount (i.e., percentage of the l ngth) of the tip portion 230, or the sheath component 210, 220 can form a greater part of the tip portion 230 of the multi-component bristle 200 than the c ore component 210.
  • each of the first and second plastics are formed of a polyester so as to be erodible by n etchant such that the conical shape of the tip portion 230 of the multi-component bristle 200 is formed by chemical etching.
  • the multi-component bristle 200 will taper from the transition point TPl to the free end 202, and more specifically the sheath component 220 will taper from the transition point TPl to the terminal end 203 of the she th component 220 and the core component 210 will taper from the terminal end 203 of the sheath component 220 to the free end 202 of the multi- component bristle 200.
  • the core component 210 has a constant tiansverse cross-sectional area from the base end 201 of the multi-component bristle 200 to the terminal end 203 of the sheath component 220 and the sheath component 220 has a constant tiansverse cross-sectional area from the base end 201 of the multi-component bristle 200 to the tiansition point TPl .
  • other configurations are possible, such as varying transverse cross-s tional areas of each of the core and sheath c omponents 220, 320 along the length of the multi-component bristle 200.
  • each of the core and sheath components 210, 220 comprise a tapered portion that collectively form the conical shape of the tip portion 230 of the multi-component bristle 200.
  • the free end 202 of the multi- component bristle 200 is tapered to a tip or sharp point.
  • the invention is not to be so
  • the multi-component bristle 200 maybe taper d, but still have a slightly rounded free end.
  • each of the core and sheath components 210, 220 is x pose d and will c ontac t a user 's oral cavity during use of an oral care impleme nt comprising the multi-component bristle 200.
  • the oral care additive 212 on the core component 210 will be able to be released into the user's oral cavity due to the second portion 21 ⁇ " being exposed.
  • only the second portion 1 ⁇ " of the core component 210 that is e posed and not covered or sunounded by the sheath component 220 may have an oral care additive thereon while the first portion 215 of the core component 210 is devoid or free of the oral care additive.
  • a gre ter volume of the oral care additive 212 is able to be imparted to the user's oral cavity than would be possible if the core component 210 did not protrude from the sheath component 220.
  • a gr ater amount of the oral care additive 212 is able to be imparted onto the user's oral cavity to achieve desired benefits. Furthermore, tapering the ends of the multi- component bristle 200 enables a larger amount of the core component 210 to protrude from the sheath component 220 than would be possible with a rounded end, as seen in FIGS. 3A-3C and discussed directly bebw.
  • a multi-c omponent bristle 300 is illustrate d in ac cordanc e with another embodiment of the present invention.
  • the multi-component bristle 300 extends from a base end 301 to a free end 302 along a ngitudinal axis B-B.
  • the multi-component bristle 300 comprises a core component 310 and a sheath component 320 that are coextruded together to form the multi-component bristle 300.
  • the multi-component bristle 300 is similar to the multi-c omponent bristle 200 except for the shape of the free end 302 of the multi-component bristle 300.
  • the core component 310 comprises a fust plastic 311 and a first oral care additive 312 and the sheath component 320 comprises a s cond plastic 321 and a second oral care additive 322.
  • the discussion of the first and second plastics 211, 221 and the first and second oral care additives 212, 222 above with regard to the multi - omponent bristle 200 is applicable to the multi-component bristle 300.
  • the discussion of the different colors and the materials of the first and second plastics dis ussed above with regard to the multi- component bristle 200 are applicable to the multi-component bristle 300.
  • the multi- omponent bristle 300 has a differe t shape at its free end 302 than the multi-component bristle 200. Specifically, the free end 302 of the multi-component bristle 300 is rounded rather than tapered. In the exemplified embodiment, the multi-component bristle 300 begins to be rounded at a transition point TP2 such that a portion of each of the core and sheath components 310, 320 is rounded.
  • the sheath component 320 is rounded from the transition point TP2 to the terminal end 303 of the sheath c omponent 320 and the core component 310 is rounded from the terminal end 303 of the sheath component 320 to the free end 302 of the multi-component bristle 300.
  • the core compone t 310 has a constant transv se cross-sectional area from the base end 301 of the multi-component bristle 300 to the terminal end 303 of the sheath component 320 and the sheath component 320 has a constant transverse cross- sectional area from the base end 301 of the multi-component bristle 300 to the transition point TP2.
  • the multi-component bristle 400 comprises a core component 410, a sheath component 420 and an interme diary component 430.
  • the intent diary component 430 is positioned between the core component 410 and the sheath component 420. Specifically the sheath component 420 suriounds a fitist portion of the interna diary component 430, a second portion of the intermediary component 430 protruding from the sheath component 420.
  • the interme diary component 430 surrounds a first portion of the coie component 410, a second portion of the core component 410 protruding through the intermediary component 430.
  • the multi-compon nt bristle 400 is formed by coextruding the core, sheath and intermediary components 410, 420, 430.
  • the core component 410 is formed of a fust plastic 411 and comprises a first oral care additive 412.
  • the sheath component 420 is formed of a second plastic 41 1 and comprises a second oral care additive 422.
  • the intermediary component 430 is formed of a third plastic 431 and comprises a third oral care additive 432.
  • the invention is not to be so limited in all embodiments and in certain other embodiments any one of the core, sheath and/or interme diary components 410, 420, 430 can be free of an oral care additive while the other of the core, sheath and/or intermediary components 410, 420, 430 comprises an oral care additive.
  • only one of the core, sheath, and interme diary components 410, 420, 430 comprises an oral care additive
  • two of the core, sheath and intermediary components 410, 420, 430 omprises an oral care additive
  • all three of the core, sheath and intermediary components 410, 420, 430 comprises an oral care additive.
  • each of the first second and third plastics 41 1, 421, 431 can be the same, and in other embodiments each of the first, second and third plastics 41 1, 421, 431 can be different, and in still other en ⁇ odiments two of the first, second and third plastics 411, 421, 431 can be the same while the other of the first, second and I ird plastics 411, 421, 431 is different.
  • e ch of the first, second and third oral care additives 412, 422, 432 can be a different oral care additive, such as any of the oral care additives discussed above with reference to the multi-component bristle 200.
  • the multi-component bristle 400 extends from a base end 401 to a free end 402 along a longiftidinal axis C-C.
  • the core component 410 of the multi-component bristle 400 extends from the base end 401 to the free end 402
  • the mterme diary component 430 of the multi-component bristle 400 extends from the base end 401 to a terminal end 433 of the intermediary component 430
  • the sheath component 420 of the multi-component bristle 400 extends from the base end 401 to a terminal end 423 of the sheath component 420.
  • the core component 410 protrudes beyond the terminal end 433 of the intermediary component 430, and in the exemplified embodiment the core component 410 tapers from the terminal end 433 of the mtermediary compone t 430 to the free end 402 of the multi-component bristle 200.
  • the mtermediary component 430 protrudes beyond the terminal end 423 of the sheath component 420, and in the exemplified enitoodiment the mtermediary component 430 tapers from the terminal end 423 of the sheath component 420 to the terminal end 433 of the mtermediary component 430.
  • the sheath component 420 tapers from a transition point TP3 to the terminal end 423 of the sheath compon nt 420.
  • taper means that the transveise cross-sectional area of that component decreases from one point to another.
  • the taper of the multi-component bristle 400 is continuous in its decrease in cross- sectional area from the transition point TP3 to the free end 402 of the multi-component bristle 400.
  • the sheath component 410 tapers from the transition point TP3 to the terminal end 423 of the sheath component 410.
  • the sheath component 410 has a first transverse cross- sectional area at the terminal end 423.
  • the intermediary component 430 tapers from the terminal end 423 of the sheath component 420 to the terminal end 433 of the mtermediary component 430.
  • the mtermediary component 430 has the first transverse cross-s ctional area at the terminal end 423 and a second transverse cross-sectional area at the terminal end 433.
  • the intermediary component 430 begins to taper it has the same transverse cross-sectional area as when the sheath component 430 ends, thereby creating a continuous, smooth taper between the sheath and interm diary components 420, 430.
  • the core component 410 tapers from the terminal end 433 of the intermediary component 430 to the free end 402.
  • the core component 410 has the second transverse cross-sectional area at the terminal end 433 that is the same as the transverse cross-sectional area of the mtermediary component 430 at the terminal end 433.
  • the core component 410 begins to taper it has the same transverse cross- sectional ar as when the mtennediary component 430 ends, thereby creating a continuous, smooth taper b tween the interme diary and core components 430, 410.
  • the core component 410 has a substantially constant transverse cross-sectional area from the base end 401 to the terminal end 433 of the intermediary component 430
  • the intermediary component 430 has a substantially constant transverse cross-sectional area f om the base end 401 to the terminal end 423 of the sheath component 420
  • the sheath component 420 has a substantially constant transverse cross-sectional area from the base end 401 to the transition point TP3.
  • the core component 410 has a tapered section 414
  • the intermediary component 430 has a tapered section 434
  • the sheath component 420 has a tapered section 424.
  • the length of the tapered section 414 of the core component 410 is greater than the length of the tapered section 434 of the interme diary component 430 and the length of the tapered section 434 of the mtermediary component 430 is greater than the length of the tapered section 424 of the sheath component 420.
  • the ratio of the lengths of the tapered sections 424, 434, 414 is between 1.5:2:3 and 2.5:3:4, and more specifically is approximately 2:2.5:3.5
  • the tapered sections 414, 434, 424 of the core component 410, the intermediary component 430 and the sheath component 420 collectively form a tapered portion 440 of the multi-component bristle 400, the tapered portion 440 of the multi-component bristle 400 having a conical shape that decreases in transverse cross-sectional area from the transition point TP3 to the free nd 403 of the multi-compone nt bristle 400.
  • each one of the core, intermediary and sheath components 410, 430, 420 comprises an oral care additive 412, 432, 422.
  • any of one or more of the core, intermediary and sheath components 410, 430, 420 maybe free of an oral care additive .
  • the oral care additives 412, 432, 422 can be the same or different in different enitoodiments as desired.
  • each of the core component 410, the intermediary component 430 and the sheath component 420 is exposed both visibly from an exterior of the multi-component bristle 400 and for contact with a user's oral cavity during use of an oral care implement that contains the multi-component bristle 400.
  • the benefits of each of the oral care additives 412, 432, 422 can be provided to the user's oral cavity using the multi- omponent bristle 400.
  • the multi-component bristle 400 is described herein as having three different components, the invention is not to be so limited and in other embodiments, four, five or more different components flayers can be used, each of which has a different oral care additive or any combination of the same and different oral care additives and lack thereof.
  • an oral care implement can be created that can dispense/r lease many different oral care additives into a user's oral cavity simultaneously.
  • a combination of different two component (or mo re) multi-component bristle s can be utilised on the same oral care implement head wherein each component has different oral care agents/additives.
  • an oral care implement may include tooth cleaning elements disposed in transveise rows on the head.
  • Each transverse row may include bristle tufts including multi-component bristles in one transverse row include different oral care additives than the multi-component bristles in each other or each adjacent transverse row.
  • a virtually unlimited number of different combinations of the multi-compone nt bristles des ribed herein are possible.
  • the invention has been described herein with regard to an oral care impl ment having at least one bristle tuft having at least one multi-component bnstle, in certain embodiments the inventive concept described herein is the multi-component bristle itself.
  • the invention can simply be a multi-component bristle including coextruded core and sheath components wherein the core component comprises a first plastic and a first oral care additive and the sheath component comprises a second plastic and a second oral care additive, the second oral care additive being different than the first oral care additive.

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  • Physics & Mathematics (AREA)
  • Geometry (AREA)
  • Brushes (AREA)
  • Cosmetics (AREA)
PCT/CN2013/089206 2013-12-12 2013-12-12 Multi-component bristle having components with different oral care additives, and oral care implement comprising the same Ceased WO2015085536A1 (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
US15/102,817 US10299580B2 (en) 2013-12-12 2013-12-12 Multi-component bristle having components with different oral care additives, and oral care implement comprising the same
EP13899050.2A EP3068263B1 (en) 2013-12-12 2013-12-12 Multi-component bristle having components with different oral care additives, and oral care implement comprising the same
JP2016537985A JP2016539730A (ja) 2013-12-12 2013-12-12 異なる口腔ケア添加剤を備える構成部を含む複数構成部ブラシ毛、およびそれを含む口腔ケア器具
CN201380081417.9A CN105813504B (zh) 2013-12-12 2013-12-12 具有带有不同的口腔护理添加剂的部件的多部件式刷毛以及包括该多部件式刷毛的口腔护理器具
AU2013407533A AU2013407533B2 (en) 2013-12-12 2013-12-12 Multi-component bristle having components with different oral care additives, and oral care implement comprising the same
PCT/CN2013/089206 WO2015085536A1 (en) 2013-12-12 2013-12-12 Multi-component bristle having components with different oral care additives, and oral care implement comprising the same
MX2016007271A MX376267B (es) 2013-12-12 2013-12-12 Cerda multi-componentes que tiene componentes con diferentes aditivos de higiene oral, e implemento de higiene oral que comprende esta.
KR1020167014466A KR20160098211A (ko) 2013-12-12 2013-12-12 서로 다른 구강 관리 첨가제들을 갖는 구성요소들을 갖는 다중-구성요소 모, 및 이를 포함하는 구강 관리 장치
RU2016123145A RU2639640C1 (ru) 2013-12-12 2013-12-12 Многокомпонентная щетинка, содержащая компоненты с различными добавками для ухода за полостью рта, и приспособление для ухода за полостью рта, содержащее такую винтовую щетинку
BR112016012422-7A BR112016012422B1 (pt) 2013-12-12 2013-12-12 Cerda de múltiplos componentes que tem componentes com diferentes aditivos para cuidado oral e implemento para cuidado oral que compreende os mesmos
TW103142949A TW201534250A (zh) 2013-12-12 2014-12-10 具有含不同口腔保健添加物的組件之多組件刷毛及包含其之口腔保健器具
AU2017202293A AU2017202293B2 (en) 2013-12-12 2017-04-07 Multi-component bristle having components with different oral care additives, and oral care implement comprising the same
US15/595,640 US10477958B2 (en) 2013-12-12 2017-05-15 Multi-component bristle having components with different oral care additives, and oral care implement comprising the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2013/089206 WO2015085536A1 (en) 2013-12-12 2013-12-12 Multi-component bristle having components with different oral care additives, and oral care implement comprising the same

Related Child Applications (4)

Application Number Title Priority Date Filing Date
US15/102,817 A-371-Of-International US10299580B2 (en) 2013-12-12 2013-12-12 Multi-component bristle having components with different oral care additives, and oral care implement comprising the same
US15/102,754 Continuation-In-Part US9681743B2 (en) 2013-12-12 2013-12-12 Spiral bristle having strand components with different oral care additives, and oral care implement comprising the same
PCT/CN2013/089172 Continuation-In-Part WO2015085528A1 (en) 2013-12-12 2013-12-12 Spiral bristle having strand components with different oral care additives, and oral care implement comprising the same
US15/595,640 Continuation-In-Part US10477958B2 (en) 2013-12-12 2017-05-15 Multi-component bristle having components with different oral care additives, and oral care implement comprising the same

Publications (1)

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WO2015085536A1 true WO2015085536A1 (en) 2015-06-18

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PCT/CN2013/089206 Ceased WO2015085536A1 (en) 2013-12-12 2013-12-12 Multi-component bristle having components with different oral care additives, and oral care implement comprising the same

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Country Link
US (1) US10299580B2 (enExample)
EP (1) EP3068263B1 (enExample)
JP (1) JP2016539730A (enExample)
KR (1) KR20160098211A (enExample)
CN (1) CN105813504B (enExample)
AU (2) AU2013407533B2 (enExample)
BR (1) BR112016012422B1 (enExample)
MX (1) MX376267B (enExample)
RU (1) RU2639640C1 (enExample)
TW (1) TW201534250A (enExample)
WO (1) WO2015085536A1 (enExample)

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CN106073146A (zh) * 2016-07-13 2016-11-09 向南物产有限公司 一种含有天然绿茶的化妆刷毛丝
WO2017044361A1 (en) * 2015-09-08 2017-03-16 Colgate-Palmolive Company Oral care implement
EP3262974A1 (en) * 2016-06-27 2018-01-03 The Procter & Gamble Company Toothbrush heads comprising a two-component-cleaning element and method for producing the same
CN107835649A (zh) * 2015-07-07 2018-03-23 高露洁-棕榄公司 口腔护理器具和用于口腔护理器具的单丝刷毛
WO2019101711A1 (de) * 2017-11-21 2019-05-31 M+C Schiffer Gmbh Zahnbürste
US11197540B2 (en) 2016-06-28 2021-12-14 The Procter & Gamble Company Method of making a brush and brush
US20220211169A1 (en) * 2019-04-09 2022-07-07 M+C Schiffer Gmbh Oral Care Instrument
US11617432B2 (en) 2019-06-21 2023-04-04 The Procter & Gamble Company Hole perforation plate for manufacturing of a toothbrush head and part thereof
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US11844419B2 (en) 2019-06-21 2023-12-19 The Procter & Gamble Company Cleaning element carrier and toothbrush head comprising it
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EP3361904B1 (en) * 2015-11-03 2025-07-23 Colgate-Palmolive Company Bristle and toothbrush incorporating the same
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AU2017202293B2 (en) 2018-07-26
RU2639640C1 (ru) 2017-12-21
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US20170020278A1 (en) 2017-01-26
MX2016007271A (es) 2017-01-06
BR112016012422A2 (enExample) 2017-08-08
KR20160098211A (ko) 2016-08-18
BR112016012422B1 (pt) 2021-11-03
EP3068263A4 (en) 2017-11-15
CN105813504B (zh) 2018-05-08
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EP3068263A1 (en) 2016-09-21
EP3068263B1 (en) 2019-02-27

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