WO2015062820A1 - Scheibe mit mindestens zwei elektrischen anschlusselementen und verbindungsleiter - Google Patents
Scheibe mit mindestens zwei elektrischen anschlusselementen und verbindungsleiter Download PDFInfo
- Publication number
- WO2015062820A1 WO2015062820A1 PCT/EP2014/071395 EP2014071395W WO2015062820A1 WO 2015062820 A1 WO2015062820 A1 WO 2015062820A1 EP 2014071395 W EP2014071395 W EP 2014071395W WO 2015062820 A1 WO2015062820 A1 WO 2015062820A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- elements
- connection
- electrically conductive
- connection elements
- conductor
- Prior art date
Links
- 239000004020 conductor Substances 0.000 title claims abstract description 187
- 229910000679 solder Inorganic materials 0.000 claims abstract description 104
- 239000000758 substrate Substances 0.000 claims abstract description 43
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 40
- 229910052709 silver Inorganic materials 0.000 claims description 40
- 239000004332 silver Substances 0.000 claims description 40
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 36
- 239000010949 copper Substances 0.000 claims description 36
- 229910052802 copper Inorganic materials 0.000 claims description 36
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 28
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 18
- 229910052718 tin Inorganic materials 0.000 claims description 18
- 239000011135 tin Substances 0.000 claims description 17
- 229910052759 nickel Inorganic materials 0.000 claims description 15
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
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- 239000011651 chromium Substances 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 13
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- 229910052797 bismuth Inorganic materials 0.000 claims description 11
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 9
- 229910052750 molybdenum Inorganic materials 0.000 claims description 9
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- 229910052725 zinc Inorganic materials 0.000 claims description 9
- 239000011701 zinc Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 8
- 239000005361 soda-lime glass Substances 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 7
- 229910052758 niobium Inorganic materials 0.000 claims description 7
- 239000010955 niobium Substances 0.000 claims description 7
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 7
- 229910052738 indium Inorganic materials 0.000 claims description 6
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 5
- 229910000640 Fe alloy Inorganic materials 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005388 borosilicate glass Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000005357 flat glass Substances 0.000 claims description 2
- 239000005329 float glass Substances 0.000 claims description 2
- 239000011133 lead Substances 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229910000881 Cu alloy Inorganic materials 0.000 claims 1
- 229910001069 Ti alloy Inorganic materials 0.000 claims 1
- 210000002105 tongue Anatomy 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000005476 soldering Methods 0.000 description 49
- 239000000463 material Substances 0.000 description 38
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 10
- 239000010959 steel Substances 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
- 125000006850 spacer group Chemical group 0.000 description 8
- 238000003466 welding Methods 0.000 description 8
- -1 polytetrafluoroethylene Polymers 0.000 description 7
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 5
- 238000009736 wetting Methods 0.000 description 5
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- 239000004698 Polyethylene Substances 0.000 description 2
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
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- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
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- PYLYNBWPKVWXJC-UHFFFAOYSA-N [Nb].[Pb] Chemical compound [Nb].[Pb] PYLYNBWPKVWXJC-UHFFFAOYSA-N 0.000 description 1
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- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
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- 238000003475 lamination Methods 0.000 description 1
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- 229920005554 polynitrile Polymers 0.000 description 1
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Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/84—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/016—Heaters using particular connecting means
Definitions
- the invention relates to a disc with at least two electrical connection elements and a connecting conductor, an economical and environmentally friendly method for their production and their use.
- the invention further relates to a disc with at least two electrical connection elements and a connection conductor for vehicles with electrically conductive structures such as heating conductors or antenna conductors.
- the electrically conductive structures are usually connected via soldered electrical connection elements with the on-board electrical system.
- the aim is to maximize the transparent surface of the glazing.
- the usually applied at the edge of the glazing non-transparent black print is used to mask the bonding of the disc with the body and the bus bars.
- the width of the bus bars and the adhesive surface must be minimized.
- a smaller width of the bus bars results in a reduced current-carrying capacity, since the line cross-section is likewise reduced with the same thickness of the bus bars.
- a sufficient heating power of the heating elements can no longer be guaranteed.
- a simple contact with the connection elements described above is no longer sufficient in this case.
- This connecting conductor is mounted on the bus bar and connected at regular intervals with this electrically conductive.
- US 44151 16 discloses a bus bar on which an additional connection conductor is mounted, whose free end is connected to the on-board voltage.
- the connecting conductor consists of a braided copper cable, which is fixed at intervals of 50 mm by means of a soldering point on the bus bar.
- the connecting conductor minimizes undesirable voltage drop across the bus bars, which would result in undesirable heating of the bus bars.
- the solder joints between the common conductor and the connecting conductor which are applied within short distances, are necessary by the length of the current paths in the region of Minimize busbars. This is intended to further reduce the voltage drop across the bus bars and the associated heat loss, so that the heating power of the heating elements is optimized.
- soldering points are arranged within short distances of less than 60 mm.
- the object of the invention is to provide a disk with at least two electrical connection elements and a connection conductor as well as an economical and environmentally friendly method for the production thereof, wherein the connection elements with connection conductors are both cost-effective and easy to handle and automated.
- the object of the present invention is achieved by a disc having at least two electrical connection elements and a connecting conductor, a process for their preparation and their use according to the independent claims 1, 13 and 15. Preferred embodiments will become apparent from the dependent claims.
- the disc according to the invention with at least two connecting elements and a connecting conductor comprises at least
- a substrate having an electrically conductive structure on at least a portion of the
- connection element at least one contact surface on the underside of each connection element, a solder composition which connects the contact surfaces of the electrical connection elements in at least one subregion to the electrically conductive structure, and a connection conductor, which electrically conductively connects the connection elements to one another, wherein the closest contact surfaces of adjacent connection elements have a distance x of at least 70 mm.
- the distance x is measured between the closest edges of the nearest contact surfaces of adjacent connection elements.
- connection elements of the pane according to the invention have a spacing of at least 70 mm.
- the connecting conductor according to the invention where the connecting conductor is not fixed via a soldering point.
- the closest contact surfaces of adjacent connection elements have a distance of at least 100 mm, preferably at least 150 mm, particularly preferably at least 200 mm.
- These long distances are to be bridged by means of connecting elements according to the invention with connecting conductor without loss of heating power occurs in comparison to known in the prior art solutions.
- the arrangement according to the invention is particularly advantageous for long connecting conductors, since a reduction in the number of soldering points leads to a significant cost reduction. With the number of solder points to be applied, the production cost also increases. Furthermore, the method is no longer automated with a high number of soldering points feasible. The number of solder points should therefore be minimized as far as possible.
- the connection conductor comprises a conductive core and a non-conductive sheath.
- the conductive core is a metallic conductor.
- the conductive core of the connection conductor may contain, for example, copper, aluminum and / or silver or alloys or mixtures thereof.
- the conductive core can be designed, for example, as a wire stranded conductor or as a solid wire conductor.
- usable electrical conductors are the Expert sufficiently well known.
- the non-conductive sheath (insulation sheath) forms an electrical insulation of the conductive core.
- the non-conductive sheath is polymer-containing, more preferably containing polyvinyl chloride and / or polytetrafluoroethylene.
- the non-conductive sheath In addition to electrical insulation of the conductive core, the non-conductive sheath on the other hand also has the task of avoiding noise in the vehicle. Since the connection conductor is fixed only to the connection elements, the part located between them is free to move and can impact while driving on the underlying bus bar, which may lead to noise without appropriate countermeasures. The non-conductive sheath attenuates such an impact of the connecting conductor on the bus bar and thus avoids a disturbing noise.
- the non-conductive sheath of the connecting conductor additionally contains a foamed polymer, preferably polypropylene, polyethylene, polystyrene, polyethylene terephthalate and / or mixtures and / or copolymers thereof. This leads to a further improvement of the noise damping.
- the connecting conductor has a conductor cross-section of less than or equal to 6 mm 2 , preferably less than or equal to 4 mm 2 , particularly preferably less than or equal to 2.5 mm 2 .
- the cable cross-section of the connecting conductor is chosen as small as possible in order to achieve a material and weight savings. Even such small conductor cross-sections of the connecting conductor are surprisingly sufficient to achieve a sufficiently high heating power.
- the line cross section of the connecting conductor 1, 5 mm 2 to 2.5 mm 2 .
- the connecting elements are connected via their upper side to the connecting conductor.
- the upper side of the connection elements is the surface which faces away from the contact surfaces of the connection elements with the electrically conductive structure (soldering surfaces).
- the connection conductor is preferably mounted on the upper side of the connection elements.
- the electrically conductive structure can serve, for example, for contacting wires or a coating applied to the pane.
- the electrically conductive structure is mounted, for example in the form of bus bars on opposite edges of the disc.
- the electrically conductive structure comprises at least one bus bar with a conductor cross-section of less than 0.3 mm 2 , preferably less than 0.1 mm 2 , particularly preferably less than 0.06 mm 2 .
- a voltage may be applied across the headers mounted on the headers, thereby flowing current through the conductive wires or conductive coating from one bus bar to the other and heating the wafer.
- the pane according to the invention can also be used in combination with antenna conductors or also in any other embodiments.
- the bus bars have a width of less than or equal to 10 mm, preferably less than or equal to 8 mm, particularly preferably less than or equal to 6 mm.
- Such narrow busbars are particularly advantageous because the black print for lamination of the bus bars also has to have only a small width. As a result, the transparent portion of the glazing can be increased.
- the layer thickness of the bus bars is less than or equal to 16 ⁇ , preferably less than or equal to 12 ⁇ , more preferably less than or equal to 10 ⁇ .
- a reduction of the layer thickness of the bus bars leads to a saving of material and thus also a reduction in costs.
- the layer thickness of the bus bars is therefore to be kept as low as possible, wherein the connecting conductor according to the invention also allows the use of very thin layer thicknesses of, for example, 8 ⁇ m.
- the disc comprises two connecting elements, between which a connecting conductor with a length of less than or equal to 300 mm extends. In order to bridge this distance of a maximum of 300 mm, two connecting elements at the ends of the connecting conductor are thus sufficient, wherein no additional fixations of the connecting conductor are required. Also in terms of heating power, the use of two connection elements is sufficient.
- the disc comprises at least three connecting elements, wherein the connecting conductor has a length of greater than 300 mm.
- the connection conductor is divided into individual sections which each extend from one connection element to the nearest connection element.
- connection elements may contain a wide variety of materials and alloys known to those skilled in the art.
- the connecting elements preferably contain titanium, iron, nickel, Cobalt, molybdenum, copper, zinc, tin, manganese, niobium and / or chromium and / or alloys thereof.
- the material composition of the connection element can be adapted to the material composition of the solder used. In connection with lead-containing solders, connecting elements containing copper are preferably used. In a preferred embodiment, the connection element contains iron alloys or titanium and is therefore particularly suitable for combination with lead-free solder materials.
- the material thickness of the connecting element is preferably 0.1 mm to 2 mm, particularly preferably 0.2 mm to 1, 5 mm, very particularly preferably 0.4 mm to 1 mm.
- the material thickness of the connection element is constant in its entire area. This is particularly advantageous with regard to a simple production of the connection element.
- connection elements each have at least one contact surface, via which the connection element is connected over the whole surface to a subregion of the electrically conductive structure by means of the solder mass.
- the connection elements can be designed in a wide variety of geometries. In this case, simple shapes with only one contact surface, such as crimps, can be used as connecting elements. Further, the connection elements may also be formed bridge-shaped or in the form of a push button.
- connection element is bridge-shaped, wherein the connection element has two feet for contacting the electrically conductive structure, between which there is a raised portion which does not directly contact the electrically conductive structure.
- the connection element can both have a simple bridge shape and comprise more complex bridge shapes. In this case, for example, a dumbbell shape with rounded feet is conceivable, which both cause a uniform tensile stress distribution and also allow a uniform distribution of solder.
- the use of bridge-shaped connection elements is particularly advantageous because the applied current is divided into two partial flows, which in each case enter a soldering foot of the connection element in the electrically conductive structure and thus allow a uniform current distribution.
- connection conductor The electrical contacting of the connection conductor with the connection elements can be effected via a solder connection, a welded connection, a crimp connection or a plug connection.
- the connecting conductor may be attached to it at an angle of 45 ° to 180 °, relative to the longitudinal direction of the relevant connection element. At an angle of 180 °, the connection conductor extends over the contact surface in the direction of the nearest connection element. Thus, a required for resistance soldering for the electrode starting point is covered by the connecting conductor. This can be avoided for example by the use of connectors and the subsequent attachment of the connection conductor. If the contact between connecting conductor and connecting element is not reversible nature, as an alternative, the application by means of induction soldering is possible.
- connection conductor is attached to it at an angle of 90 ° relative to the longitudinal direction of the connection element. In practice, however, it has been shown that even an angle of 45 ° is sufficient to ensure sufficient accessibility of the electrode attachment points.
- At least one connecting element is connected via connecting cable with the on-board electronics of the motor vehicle.
- the electrical contacting of the connecting elements with the connecting cables can also be done via a solder joint, a welded joint, a crimped connection or a plug connection.
- connection element In the simplest conceivable embodiment, the connecting conductor and the connection cable are attached directly to the connection element, for example via a solder connection.
- connection conductor and / or the connection cable are contacted via contact elements on the connection element.
- connection conductor and the connection cable can be attached both together via a contact element as well as via different contact elements.
- the connecting conductor and the connecting cable are designed as a one-piece cable, wherein the non-conductive sheath of the cable is removed in the region of a connecting element and the conductive core, for example via a crimp, is contacted with the connecting element in an electrically conductive manner.
- connection elements are electrically conductively connected to the connection elements, wherein the elements can be connected by means of various soldering or welding techniques.
- the contact elements and the connection elements by means of electrode resistance welding, induction soldering, ultrasonic welding or Friction welding connected.
- a one-piece design of connection element and contact element is conceivable.
- contact elements for example, crimps or tabs can be used, which can be realized both in one piece with the connection element as well as in a multi-part embodiment.
- the upper female part of a push button used in this context as a contact element to which the connection conductor and / or the connection cable are fixed.
- connection elements are advantageous in terms of a standardization made possible thereby.
- the connecting elements and the connecting conductor are stored separately and only when needed, a mounting of the individual modules.
- connecting conductors of different lengths via contact elements with any connection elements can be combined in a simple manner.
- Such a modular design allows a high degree of flexibility and variety of variants with low production costs.
- the contact element is dimensioned so that standardized automotive flat plugs with a height of 0.8 mm and a width of either 4.8 mm, 6.3 mm or 9.5 mm can be plugged onto at least one free end of the contact element ,
- the embodiment of the contact element with a width of 6.3 mm is particularly preferably used, since this corresponds to the automotive flat connectors according to DIN 46244 commonly used in this field.
- the contact element is constructed symmetrically and has two tabs.
- a symmetrical shaping serves the homogeneous power consumption of the contact element during processing, for example a homogeneous heat distribution in soldering and welding processes.
- At such a contact element of the connecting conductor to a first tongue and a connecting cable to a second tongue are contacted.
- Such a structure is in Meaning of a standardization and a modular design also makes sense if only a single slot for a connection conductor is needed.
- connection element and the contact element are integrally formed.
- the electrical contacting of the contact element can also be effected via a solder connection or a crimp connection.
- connection cables are in principle all cables which are known to those skilled in the electrical contacting of an electrically conductive structure.
- the connection cable can comprise, in addition to an electrically conductive core (inner conductor), an insulating, preferably polymeric sheath, wherein the insulating sheath is preferably removed in the end region of the connection cable in order to allow an electrically conductive connection between the connection element and the inner conductor.
- the electrically conductive core of the connection cable can contain, for example, copper, aluminum and / or silver or alloys or mixtures thereof.
- the electrically conductive core can be designed, for example, as a wire stranded conductor or as a solid wire conductor.
- the cross-section of the electrically conductive core of the connection cable depends on the current carrying capacity required for the use of the pane according to the invention and can be suitably selected by the person skilled in the art.
- the cross section is for example from 0.3 mm 2 to 6 mm 2 .
- connection cable has at its free end, which is not connected to the contact element or connection element, via a plug connection, via which the connection to the on-board electronics of the vehicle takes place.
- the connecting cable is rigid in a particularly preferred embodiment.
- the end-side plug connection of the connection cable can be connected in a simple manner to the on-board voltage, without the force applied during attachment leading to undesired deformation of the connection cable.
- the connector is thus also one-hand install and therefore means a simplification of the production process.
- the stiffening of the cable is preferably carried out via a rigid sheath.
- the electrically conductive structure contains at least silver, preferably silver particles and glass frits.
- the electrically conductive structure is connected to the connecting elements in an electrically conductive manner via the solder mass.
- the solder mass is arranged at the on the contact surfaces, which are located on the underside of the connection elements. In this case, all soldering materials known to those skilled in the art, which are suitable for processing on glass, can be used.
- the solder mass preferably comprises tin, bismuth, indium, zinc, copper, silver, lead and / or mixtures and / or alloys thereof.
- the solder composition is lead-free.
- lead-free solder mass is a solder mass which, according to the EC directive "2002/95 / EC on the restriction of the use of certain hazardous substances in electrical and electronic equipment", has a content of less than or equal to 0.1% by weight.
- % Lead preferably contains no lead.
- connection element typically have a lower ductility than lead-containing solder materials, so that mechanical stresses between the connection element and the disk can be compensated less well.
- critical mechanical stresses can be avoided by a suitable choice of the material of the connection element.
- the material composition of the connection element is selected such that the difference between the thermal expansion coefficients of the transparent substrate and the connection element is less than 5 ⁇ 10 -6 / ° C. This reduces the thermal stresses of the pane and achieves better adhesion
- titanium and chromium-containing steel to name.
- connection elements which are used in conjunction with lead-free solder materials, are shown below.
- connection element contains a chromium-containing steel with a chromium content of greater than or equal to 5% by weight, preferably greater than or equal to 10.5% by weight.
- chromium content of greater than or equal to 5% by weight, preferably greater than or equal to 10.5% by weight.
- Other alloying constituents such as molybdenum, manganese or niobium lead to improved corrosion resistance or altered mechanical properties, such as tensile strength or cold workability.
- the connecting element preferably contains at least 49% by weight to 95% by weight of iron, 5% by weight to 30% by weight of chromium, 0% by weight to 1% by weight of carbon, 0% by weight to 10% by weight of nickel, 0% by weight to 2% by weight of manganese, 0% by weight to 5% by weight of molybdenum, 0% by weight to 2% by weight of niobium and 0% by weight. % to 1 wt .-% titanium.
- the connection element may additionally contain admixtures of other elements, including vanadium, aluminum and nitrogen.
- the connecting element furthermore preferably contains at least 57% by weight to 93% by weight of iron, 7% by weight to 25% by weight of chromium, 0% by weight to 1% by weight of carbon, 0% by weight. to 8% by weight of nickel, 0% by weight to 2% by weight of manganese, 0% by weight to 4% by weight of molybdenum, 0% by weight to 2% by weight of niobium and 0% by weight. % to 1% by weight of titanium.
- the connection element may additionally contain admixtures of other elements, including vanadium, aluminum and nitrogen.
- the connecting element particularly preferably contains at least 66.5% by weight to 89.5% by weight of iron, 10.5% by weight to 20% by weight of chromium, 0% by weight to 1% by weight of carbon , 0% by weight to 5% by weight of nickel, 0% by weight to 2% by weight of manganese, 0% by weight to 2.5% by weight of molybdenum, 0% by weight to 2% by weight of molybdenum % Of niobium and 0% to 1% by weight of titanium.
- the connection element may additionally contain admixtures of other elements, including vanadium, aluminum and nitrogen.
- the connecting element very particularly preferably contains at least 73% by weight to 89.5% by weight of iron, 10.5% by weight to 20% by weight of chromium, 0% by weight to 0.5% by weight.
- connection element may additionally contain admixtures of other elements, including vanadium, aluminum and nitrogen.
- the connecting element contains in particular at least 77 wt .-% to 84 wt .-% iron, 16 wt .-% to 18.5 wt .-% chromium, 0 wt .-% to 0.1 wt .-% carbon, 0 wt % to 1 wt.% manganese, 0 wt.% to 1 wt.% niobium, 0 wt.% to 1, 5 wt.% molybdenum and 0 wt.% to 1 wt. Titanium.
- the connection element may additionally contain admixtures of other elements, including vanadium, aluminum and nitrogen.
- Chromium-containing in particular so-called stainless or stainless steel is available at low cost.
- connecting elements made of chromium-containing steel have, in comparison to many conventional connecting elements, for example made of copper high rigidity, which leads to an advantageous stability of the connection elements.
- chromium-containing steel has improved solderability compared to many conventional terminal elements, for example, titanium, resulting from a higher thermal conductivity.
- Particularly suitable chromium-containing steels are steels of material numbers 1.4016, 1.41 13, 1.4509 and 1.4510 according to EN 10 088-2.
- the solder mass preferably contains tin and bismuth, indium, zinc, copper, silver or compositions thereof.
- the proportion of tin in the solder composition is 3% by weight to 99.5% by weight, preferably 10% by weight to 95.5% by weight, particularly preferably 15% by weight to 60% by weight.
- the proportion of bismuth, indium, zinc, copper, silver or compositions thereof in the solder composition according to the invention from 0.5 wt .-% to 97 wt .-%, preferably 10 wt .-% to 67 wt .-%, wherein the proportion may be 0 wt .-% of bismuth, indium, zinc, copper or silver.
- the solder composition may contain nickel, germanium, aluminum or phosphorus at a level of from 0% to 5% by weight.
- the solder composition most preferably contains Bi40Sn57Ag3, Sn40Bi57Ag3, Bi59Sn40Ag1, Bi57Sn42Ag1, ln97Ag3, ln60Sn36.5Ag2Cu1, 5, Sn95.5Ag3.8Cu0.7, Bi67ln33, Bi33ln50Sn17, Sn77.2ln20Ag2.8, Sn95Ag4Cu1, Sn99Cu1, Sn96.5Ag3.5, Sn96.5Ag3CuO, 5, Sn97Ag3 or mixtures thereof.
- the solder mass contains bismuth. It has been shown that a bismuth-containing solder composition leads to a particularly good adhesion of the connecting element according to the invention to the disk, wherein damage to the disk can be avoided.
- the proportion of bismuth in the solder composition is preferably from 0.5 wt% to 97 wt%, more preferably from 10 wt% to 67 wt%, and most preferably from 33 wt% to 67 Wt .-%, in particular from 50 wt .-% to 60 wt .-%.
- the solder mass preferably contains tin and silver or tin, silver and copper.
- the solder mass contains at least 35 wt .-% to 69 wt .-% bismuth, 30 wt .-% to 50 wt .-% tin, 1 wt .-% to 10 wt .-% silver and 0 wt % to 5% by weight of copper.
- the solder mass contains at least 49 wt .-% to 60 wt .-% bismuth, 39 wt .-% to 42 wt .-% tin, 1 wt .-% to 4 wt .-% silver and 0 Wt .-% to 3 wt .-% copper.
- the solder mass contains from 90% by weight to 99.5% by weight of tin, preferably from 95% by weight to 99% by weight, particularly preferably 93% by weight. % to 98% by weight.
- the solder mass preferably contains from 0.5% by weight to 5% by weight of silver and from 0% by weight to 5% by weight of copper.
- the layer thickness of the solder mass is preferably less than or equal to 600 ⁇ m, more preferably between 150 ⁇ m and 600 ⁇ m, in particular less than 300 ⁇ m.
- the solder mass emerges with an exit width of preferably less than 1 mm from the intermediate space between the soldering region of the connection element and the electrically conductive structure.
- the maximum exit width is less than 0.5 mm and in particular about 0 mm. This is particularly advantageous with regard to the reduction of mechanical stresses in the disc, the adhesion of the connecting element and the saving of the solder.
- the maximum exit width is defined as the distance between the outer edges of the soldering area and the point of Lotmasseübertritts, at which the solder mass falls below a layer thickness of 50 ⁇ . The maximum exit width is measured after the soldering process on the solidified solder mass.
- a desired maximum exit width is achieved by a suitable choice of Lotmassenvolumen and perpendicular distance between the connection element and electrically conductive structure, which can be determined by simple experiments.
- the vertical distance between the connection element and the electrically conductive structure can be predetermined by a corresponding process tool, for example a tool with an integrated spacer.
- the maximum exit width can also be negative, that is to say retracted into the intermediate space formed by the soldering area of the electrical connection element and the electrically conductive structure.
- the maximum exit width in the intermediate space formed by the soldering area of the electrical connection element and the electrically conductive structure is withdrawn in a concave meniscus.
- a concave meniscus is created by increasing the perpendicular distance between the spacer and conductive structure during the soldering process while the solder is still liquid.
- the advantage lies in the reduction of the mechanical stresses in the disc, in particular in the critical range, which is present at a large Lotmasseübertritt.
- connection elements on spacers preferably at least two spacers, more preferably at least three spacers.
- the spacers are preferably formed integrally with the connection element, for example by embossing or deep drawing.
- the spacers preferably have a width of 0.5 x 10 "4 m to 10 x 10" 4 m and a height of 0.5 x 10 "4 m to 5 x 10" 4 m, more preferably from 1 x 10 "4 m to 3 x 10 "4 m
- the spacers achieve a homogeneous, uniformly thick and evenly melted layer of the solder mass, which can reduce mechanical stress between the connection element and the pane and improve the adhesion of the connection element, which is particularly advantageous when using lead-free solder materials , which, due to their lower ductility, can compensate less well for mechanical stresses than leaded solder masses.
- At least one contact elevation is arranged on the surface of the connection elements facing away from the substrate, which serves for contacting the connection elements with the soldering tool during the soldering operation.
- the contact elevation is preferably convexly curved, at least in the area of the contacting with the soldering tool.
- the contact elevation preferably has a height of 0.1 mm to 2 mm, more preferably of 0.2 mm to 1 mm.
- the length and width of the contact elevation is preferably between 0.1 and 5 mm, very particularly preferably between 0.4 mm and 3 mm.
- the contact elevations are preferably formed integrally with the connection element, for example by embossing or deep-drawing. For soldering electrodes can be used, the contact side is formed flat.
- the electrode surface is brought into contact with the contact elevation.
- the electrode surface is arranged parallel to the surface of the substrate.
- the contact area between the electrode surface and contact elevation forms the solder joint.
- the position of the solder joint is determined by the point on the convex surface of the contact elevation, which has the greatest perpendicular distance from the surface of the substrate.
- the position of the solder joint is independent of the position of the soldering electrode on the connecting element. This is particularly advantageous in terms of a reproducible, even heat distribution during the soldering process.
- the heat distribution during the soldering process is determined by the position, the size, the arrangement and the geometry of the contact elevation.
- the electrical connection elements preferably have a coating (wetting layer) at least on the contact surface aligned with the solder mass, which contains nickel, copper, zinc, tin, silver, gold or alloys or layers thereof, preferably silver.
- connection elements according to the invention are preferably coated with nickel, tin, copper and / or silver.
- the connection elements according to the invention are particularly preferably with an adhesion-promoting layer, preferably of nickel and / or copper, and additionally provided with a solderable layer, preferably of silver.
- the connecting elements according to the invention are very particularly preferably coated with 0.1 ⁇ m to 0.3 ⁇ m nickel and / or 3 ⁇ m to 20 ⁇ m silver.
- the connection elements can be nickel-plated, tinned, copper-plated and / or silver-plated. Nickel and silver improve the current carrying capacity and corrosion stability of the connection elements and the wetting with the solder mass.
- the contact elements may optionally also have a coating. However, a coating of the contact elements is not necessary because there is no direct contact between contact elements and solder mass. Thus, there is no need to optimize the wetting properties of the contact elements.
- the contact elements have a coating which contains nickel, copper, zinc, tin, silver, gold or alloys or layers thereof, preferably silver.
- the contact elements are preferably coated with nickel, tin, copper and / or silver. Most preferably, the contact elements are coated with 0.1 ⁇ to 0.3 ⁇ nickel and / or 3 ⁇ to 20 ⁇ silver.
- the contact elements can be nickel-plated, tin-plated, copper-plated and / or silver-plated.
- the shape of the electrical connection element can form one or more solder deposits in the intermediate space of connection element and electrically conductive structure.
- the solder deposits and wetting properties of the solder on the connecting element prevent the escape of the solder mass from the intermediate space.
- Lotdepots can be rectangular, rounded or polygonal configured.
- the substrate preferably contains glass, particularly preferably flat glass, float glass, quartz glass, borosilicate glass and / or soda-lime glass.
- the substrate may also contain polymers, preferably polyethylene, polypropylene, polycarbonate, polymethyl methacrylate, polystyrene, polybutadiene, polynitriles, polyesters, polyurethane, polyvinyl chloride, polyacrylate, polyamide, polyethylene terephthalate and / or copolymers or mixtures thereof.
- the substrate is preferably transparent.
- the substrate preferably has a thickness of 0.5 mm to 25 mm, more preferably of 1 mm to 10 mm and most preferably of 1, 5 mm to 5 mm.
- a screen printing is applied to the substrate, which covers the contacting of the disc in the installed state of the disc, so that the connection elements with connecting conductors from the outside are not visible.
- the invention further comprises a method for producing a pane comprising the steps:
- connection elements b) applying a solder mass to at least one contact surface on the underside of the connection elements
- connection elements with the solder mass on the electrically conductive structure on the substrate
- connection elements soldering the connection elements with the electrically conductive structure
- step a) before, during or after steps b), c) and d) can take place.
- the electrically conductive structure can be applied to the substrate by methods known per se, for example by screen printing methods.
- the application of the electrically conductive structure can take place before, during or after method step b).
- the solder mass is preferably applied as platelets or flattened drops with a defined layer thickness, volume, shape and arrangement on the connection element.
- the layer thickness of the Lotmasseplättchens is preferably less than or equal to 0.6 mm.
- the shape of the Lotmasseplättchens preferably corresponds to the shape of the contact surface. If the contact surface is rectangular, for example, the solder mass platelet preferably has a rectangular shape.
- the introduction of the energy in the electrical connection of electrical connection element and electrically conductive structure is preferably carried out with stamp, thermodes, piston soldering, microflame soldering, preferably laser soldering, hot air soldering, induction soldering, resistance soldering and / or with ultrasound.
- connection elements are automatically soldered.
- the connection conductor is contacted via contact elements in an electrically conductive manner on the connection elements.
- These contact elements are attached to the connecting elements prior to the electrical contacting of connecting conductors and connecting elements.
- the contact elements can already be connected to the connection elements in preparatory fashion before the first method step, while the connection conductor is attached only before, during or after steps b), c) and d).
- the connecting conductor is preferably attached to the contact elements only after step d). In this case, first the connecting elements not yet connected to one another are soldered to contact elements, wherein there is no spatial obstruction through the connecting conductor, which is attached only in the further course of the method.
- the contact elements are welded or soldered on the top of the connection elements.
- the contact elements are fixed by electrode resistance welding, induction soldering, ultrasonic welding or friction welding on the connection element.
- the contact element and the connection element are integrally formed. In this case eliminates a connection of contact element and connecting element.
- the invention comprises the use of a pane having at least two connection elements and connecting conductors as a pane with electrically conductive structures, preferably with heating conductors and / or antenna conductors, for vehicles, aircraft, ships, architectural glazing and building glazing.
- the connecting elements serve the connection of electrically conductive structures of the disk, such as heat conductors or antenna conductors, with external electrical systems, such as amplifiers, control units or voltage sources.
- the invention comprises the use of the pane according to the invention in rail vehicles or motor vehicles, preferably as a windscreen, rear window, side window and / or roof window, in particular as a heatable pane or as a pane with an antenna function.
- Figure 1 is a schematic view of a disc according to the invention with two connecting elements and connecting conductors.
- Figure 2 shows another embodiment of the disc according to the invention with two connecting elements and connecting conductors.
- Figure 3 shows another embodiment of the disc according to the invention with two connecting elements and connecting conductors.
- Figure 4 shows another embodiment of the disc according to the invention with two connecting elements and connecting conductors.
- Figure 5 shows another embodiment of the disc according to the invention with two connecting elements and connecting conductors.
- Figure 6 shows another embodiment of the disc according to the invention with two connecting elements and connecting conductors.
- FIG. 7a shows a flow chart of the method according to the invention for producing a pane with connecting elements and connecting conductors.
- FIG. 7b shows a flow chart of a further embodiment of the method according to the invention for producing a pane with connecting elements and connecting conductors.
- Figure 1 shows a disc according to the invention with two connecting elements (4.1, 4.2) and connecting conductor (6).
- a Abdecksiebdruck (2) is applied on a substrate (1) made of a 3 mm thick thermally toughened safety glass of soda-lime glass .
- the substrate (1) has a width of 150 cm and a height of 80 cm, wherein on the shorter side edge in the region of Abdecksieb réelles (2) two connection elements (4) with connecting conductor (6) are mounted.
- an electrically conductive structure (2) is applied in the form of a Schuleiter Modell.
- the electrically conductive structure contains silver particles and glass frits, the silver content being greater than 90%.
- the electrically conductive Structure (3) In the edge region of the disc is the electrically conductive Structure (3) widened to 6 mm and serves as a bus bar.
- the bus bar has a layer thickness of 10 ⁇ .
- a solder mass (8) is applied, which connects the electrically conductive structure (3) with the contact surfaces (9) of the connection elements (4). The contact is obscured by the Abdecksieb réelle (2) after mounting in the vehicle body.
- the solder mass (8) ensures a permanent electrical and mechanical connection of the electrically conductive structure (3) with the connection element (4).
- the solder mass (8) is lead-free and contains 96.5% by weight of tin, 3% by weight of silver and 0.5% by weight of copper.
- the solder mass (8) has a layer thickness of 250 ⁇ .
- connection elements (4.1, 4.2) have a bridge shape.
- the connection elements comprise two feet, each with a contact surface (9) on its underside and a bridge-shaped section which extends between the feet.
- a contact element (5.1, 5.2) on the surface of the connecting elements (4.1, 4.2) is welded.
- the contact elements (5.1, 5.2) have a double bridge shape and are aligned parallel to the connection elements (4.1, 4.2).
- the contact elements (5.1, 5.2) each have two tabs, to which via connectors of the connecting conductor (6) or a connection cable can be connected.
- connection conductor (6) To the tongue of a respective contact element (5.1, 5.2) is connected via connectors (7.1, 7.2) of the connecting conductor (6), which thus connects the two connection elements (4.1) and (4.2) electrically conductive.
- connecting conductor (6) a copper round cable with a polymeric sheath and a conductor cross-section of 2.5 mm 2 is used.
- a connection cable (not shown) are plugged, which connects the connection elements (4.1, 4.2) with the on-board electronics.
- the current flowing via this connecting cable is split into two partial currents which enter the electrically conductive structure (3) via the soldering feet of the connecting element (4.1) and a partial current which is conducted via the connecting conductor (6) to the second connecting element (4.2). on.
- the embodiment shown here is particularly advantageous in terms of a modular construction of the system.
- the individual standardized elements can be assembled variably via plug connections according to a modular principle.
- the use of connectors is also advantageous in terms of the reversibility of the connection, so that in case of damage to the cable a simple exchange is possible.
- the electrical connection elements (4.1, 4.2) have a width of 4 mm and a length of 24 mm and consist of steel of material number 1 .4509 according to EN 10 088-2 (ThyssenKrupp Nirosta® 4509).
- the material thickness of the connection elements (4.1, 4.2) is 1 mm.
- the contact elements (5.1, 5.2) have a height of 0.8 mm, a width of 6.3 mm and a length of 27 mm.
- the contact elements (5.1, 5.2) consist of copper of material number CW004A (Cu-ETP).
- connection element has a substrate to the (1) matching thermal expansion coefficient, while the contact elements (5.1, 5.2) have a sufficiently high conductivity of 1, 8 ⁇ " ⁇ ⁇ ⁇ own The electrical resistance of the contact elements (5.1, 5.2) is thus selected such that a high voltage drop is avoided at the contact elements (5.1, 5.2) .
- the connection element itself is again made of a material with a suitable expansion coefficient (difference to the CTE of the substrate smaller than 5 x 10 "6 / ° C).
- connection elements (4.1, 4.2) and the contact elements (5.1, 5.2) Due to the different material compositions of the connection elements (4.1, 4.2) and the contact elements (5.1, 5.2), the advantageous properties of the materials used at the appropriate location are optimally utilized.
- the closest contact surfaces (9) of the first connection element (4.1) and the second connection element (4.2) have a distance x of 190 mm.
- the connecting elements (4.1, 4.2) according to the invention with connecting conductor (6) allow a significant improvement in the current carrying capacity, even when using bus bars with small cross-sections and only two terminal connection elements. Additional solder points are not required.
- FIG. 2 shows a further embodiment of the pane according to the invention with two connecting elements (4.1, 4.2) and connecting conductor (6).
- a substrate (1) made of a 3 mm thick thermally toughened safety glass of soda-lime glass a Abdecksieb whatsoever (2) is applied.
- the substrate (1) has a width of 150 cm and a height of 80 cm, wherein on the shorter side edge in the region of Abdecksieb réelles (2) two connection elements (4) with connecting conductor (6) are mounted.
- an electrically conductive structure (2) is applied in the form of a Schuleiter Modell.
- the electrically conductive structure contains silver particles and glass frits, the silver content being greater than 90%.
- the electrically conductive structure (3) is widened to 6 mm and serves as a bus bar.
- the bus bar has a layer thickness of 10 ⁇ .
- a solder mass (8) is applied, which connects the electrically conductive structure (3) with the contact surfaces (9) of the connection elements (4). The contact is obscured by the Abdecksieb réelle (2) after mounting in the vehicle body.
- the solder mass (8) ensures a permanent electrical and mechanical connection of the electrically conductive structure (3) with the connection element (4).
- the solder mass (8) is a lead-containing solder mass with the composition Pb70Sn27Ag3.
- the solder mass (8) has a layer thickness of 250 ⁇ .
- the electrical connection elements (4.1, 4.2) have a width of 4 mm and a length of 24 mm and are made of copper of material number CW004A (Cu-ETP).
- the material thickness of the connection elements (4.1, 4.2) is 0.8 mm.
- the contact elements (5.1, 5.2) have a height of 0.8 mm, a width of 6.3 mm and a length of 8 mm.
- the contact elements (5.1, 5.2) are made of copper of material number CW004A (Cu-ETP).
- the connection elements (4.1, 4.2) have a bridge shape.
- the connection elements comprise two feet, each with a contact surface (9) on its underside and a bridge-shaped section which extends between the feet.
- connecting elements (4.1, 4.2) and contact elements (5.1, 5.2) are integrally formed, wherein the first contact element (5.1) in the form of two tabs on the first connection element (4.1) is mounted, while the second connection element (4.2) also via has two tabs that form the second contact element (5.2).
- the contact elements (5.1, 5.2) extend the connecting elements (4.1, 4.2) in the longitudinal direction and are upwards, facing away from the substrate, bent.
- connecting elements (4.1, 4.2) and contact elements (5.1, 5.2) together form a double bridge shape.
- connection conductor (6) To the tongue of a respective contact element (5.1, 5.2) is connected via connectors (7.1, 7.2) of the connecting conductor (6), which thus connects the two connection elements (4.1) and (4.2) electrically conductive.
- connecting conductor (6) a copper round cable with a polymeric sheath and a conductor cross-section of 2.5 mm 2 is used.
- a connection cable (not shown) are plugged, which connects the connection elements (4.1, 4.2) with the on-board electronics.
- the current flowing via this connecting cable is split into two partial currents which enter the electrically conductive structure (3) via the soldering feet of the connecting element (4.1) and a partial current which is conducted via the connecting conductor (6) to the second connecting element (4.2). on.
- This embodiment is particularly advantageous in the case of integrally formed connecting elements (4.1, 4.2) with contact elements (5.1, 5.2), since these can be embossed from a single sheet in one step.
- the closest contact surfaces (9) of the first connection element (4.1) and the second connection element (4.2) have a distance x of 190 mm.
- the connecting elements (4.1, 4.2) according to the invention with connecting conductor (6) allow a significant improvement in the current carrying capacity, even when using bus bars with small cross-sections and only two terminal connection elements. Additional solder points are not required.
- FIG. 3 shows a further embodiment of the pane according to the invention with two connecting elements (4.1, 4.2) and connecting conductor (6).
- a substrate (1) made of a 3 mm thick thermally toughened safety glass of soda-lime glass a Abdecksieb whatsoever (2) is applied.
- the substrate (1) has a width of 150 cm and a height of 80 cm, wherein on the shorter side edge in the region of Abdecksieb réelles (2) two connection elements (4) with connecting conductor (6) are mounted.
- an electrically conductive structure (2) is applied in the form of a Schuleiter Modell.
- the electrically conductive structure contains silver particles and glass frits, the silver content being greater than 90%.
- the electrically conductive structure (3) is widened to 6 mm and serves as a bus bar.
- the bus bar has a layer thickness of 10 ⁇ .
- a solder mass (8) is applied, which connects the electrically conductive structure (3) with the contact surfaces (9) of the connection elements (4).
- the contact is obscured by the Abdecksieb réelle (2) after mounting in the vehicle body.
- the solder mass (8) ensures a permanent electrical and mechanical connection of the electrically conductive structure (3) with the connection elements (4).
- the shape and material composition of the connecting elements (4.1, 4.2) and the solder mass (8) corresponds to FIG. 1.
- the contact elements (5.1, 5.2) consist of crimps, which are fastened at the ends of the connecting conductor (6) by means of a crimped connection and are welded onto the bridge-shaped section of the connecting elements (4.1, 4.2).
- the connecting conductor (6) thus constitutes an electrically conductive connection of the first connecting element (4.1) and the second connecting element (4.2).
- the connecting conductor (6) used is a round copper cable with a polymeric sheath and a conductor cross-section of 2.5 mm 2 .
- the contact elements (5.1, 5.2) consist of copper of material number CW004A (Cu-ETP).
- the first contact element (5.1) in this case comprises a tongue, to which by means of a plug connection cable (not shown) can be plugged, which connects the connection elements (4.1, 4.2) with the on-board electronics.
- the closest contact surfaces (9) of the first connection element (4.1) and the second connection element (4.2) have a distance x of 190 mm.
- the connecting elements (4.1, 4.2) according to the invention with connecting conductor (6) allow a significant improvement in the current carrying capacity, even when using bus bars with small cross-sections and only two terminal connection elements. Additional solder points are not required.
- the use of crimp connections is advantageous above all with regard to cost-effective production of the pane according to the invention.
- FIG. 4 shows a further embodiment of the pane according to the invention with connecting elements and connecting conductors.
- a substrate (1) made of a 3 mm thick thermally toughened safety glass of soda-lime glass a Abdecksieb whatsoever (2) is applied.
- the substrate (1) has a width of 150 cm and a height of 80 cm, wherein on the shorter side edge in the region of Abdecksieb réelles (2) two connection elements (4) with connecting conductor (6) are mounted.
- an electrically conductive structure (2) is applied in the form of a Schuleiter Modell.
- the electrically conductive structure contains silver particles and Glass frits, wherein the silver content is greater than 90%.
- the electrically conductive structure (3) is widened to 6 mm and serves as a bus bar.
- the bus bar has a layer thickness of 10 ⁇ .
- a solder mass (8) is applied, which connects the electrically conductive structure (3) with the contact surfaces (9) of the connection elements (4).
- the contact is obscured by the Abdecksieb réelle (2) after mounting in the vehicle body.
- the solder mass (8) ensures a permanent electrical and mechanical connection of the electrically conductive structure (3) with the connection elements (4).
- the connecting elements (4.1, 4.2) each have a contact surface (9), via which they are soldered by means of the solder mass (8) on the electrically conductive structure (3).
- the material composition of the connecting elements (4.1, 4.2) and the solder mass (8) corresponds to Figure 1.
- the contact elements (5.1, 5.2) consist of crimps, which are attached to the ends of the connecting conductor (6) by means of a crimped connection and on a higher-lying portion of Connection elements (4.1, 4.2) are welded.
- the connecting conductor (6) thus constitutes an electrically conductive connection of the first connecting element (4.1) and the second connecting element (4.2).
- the connecting conductor (6) used is a round copper cable with a polymeric sheath and a conductor cross-section of 2.5 mm 2 .
- the first connection element (4.1) has a third contact element (5.3) which is likewise mounted on the higher-lying section of the connection element (4.1) and connects a connection cable (10) in an electrically conductive manner to the connection element (4.1).
- the third contact element (5.3) is also a crimp, which surrounds the connection cable (10) and is welded to the first connection element.
- the contact elements (5.1, 5.2, 5.3) consist of steel of material number 1.4016 according to EN 10 088-2 (ThyssenKrupp Nirosta® 4016).
- the closest contact surfaces (9) of the first connection element (4.1) and the second connection element (4.2) have a distance x of 190 mm.
- connecting elements (4.1, 4.2) according to the invention with connecting conductor (6) allow a significant improvement in the current carrying capacity, even when using bus bars with small cross-sections and only two terminal connection elements. Additional solder points are not required.
- the use of crimp connections is advantageous above all with regard to cost-effective production of the pane according to the invention.
- FIG. 5 shows a further embodiment of the pane according to the invention with connecting elements and connecting conductors.
- a substrate (1) made of a 3 mm thick thermally toughened safety glass of soda-lime glass a Abdecksieb whatsoever (2) is applied.
- the substrate (1) has a width of 150 cm and a height of 80 cm, wherein at the shorter side edge in the region of Abdecksieb réelles (2) two connection elements (4) with connecting conductor (6) are mounted.
- an electrically conductive structure (2) is applied in the form of a Schuleiter Modell.
- the electrically conductive structure contains silver particles and glass frits, the silver content being greater than 90%.
- the electrically conductive structure (3) is widened to 6 mm and serves as a bus bar.
- the bus bar has a layer thickness of 10 ⁇ .
- a solder mass (8) is applied, which connects the electrically conductive structure (3) with the contact surfaces (9) of the connection elements (4).
- the contact is obscured by the Abdecksieb réelle (2) after mounting in the vehicle body.
- the solder mass (8) ensures a permanent electrical and mechanical connection of the electrically conductive structure (3) with the connection elements (4).
- the connecting elements (4.1, 4.2) each have a contact surface (9), via which they are soldered by means of the solder mass (8) on the electrically conductive structure (3).
- FIG. 4 corresponds to the material composition of the connection elements (4.1, 4.2) and the solder composition (8).
- connection elements (4.1, 4.2) consist of crimps, which are fastened at the ends of the connection conductor (6) by means of a crimp connection and by means of the solder composition (8 ) are soldered directly on the electrically conductive structure (3).
- the connecting conductor (6) thus constitutes an electrically conductive connection of the first connecting element (4.1) and the second connecting element (4.2).
- the connecting conductor (6) used is a round copper cable with a polymeric sheath and a conductor cross-section of 2.5 mm 2 .
- the connection elements (4.1, 4.2) consist of steel of material number 1.4016 according to EN 10 088-2 (ThyssenKrupp Nirosta® 4016).
- the closest contact surfaces (9) of the first connection element (4.1) and the second connection element (4.2) have a distance x of 190 mm.
- the first connection element (4.1) has a tongue which serves as a contact element (5.1).
- a connecting cable (not shown) is connected, which connects the connecting elements (4.1, 4.2) with the on-board electronics.
- the connecting elements (4.1, 4.2) according to the invention with connecting conductor (6) allow a significant improvement in the current carrying capacity, even when using bus bars with small cross-sections and only two terminal connection elements. Additional solder points are not required.
- the use of crimp connections is advantageous above all with regard to cost-effective production of the pane according to the invention.
- FIG. 6 shows a further embodiment of the pane according to the invention with connecting elements and connecting conductors.
- a substrate (1) made of a 3 mm thick thermally toughened safety glass of soda-lime glass a Abdecksieb whatsoever (2) is applied.
- the substrate (1) has a width of 150 cm and a Height of 80 cm, wherein at the shorter side edge in the region of Abdecksieb réelles (2) two connection elements (4) with connecting conductor (6) are mounted.
- an electrically conductive structure (2) is applied in the form of a Schuleiter Modell.
- the electrically conductive structure contains silver particles and glass frits, the silver content being greater than 90%.
- the electrically conductive structure (3) is widened to 6 mm and serves as a bus bar.
- the bus bar has a layer thickness of 10 ⁇ .
- a solder mass (8) is applied, which connects the electrically conductive structure (3) with the contact surfaces (9) of the connection elements (4).
- the contact is obscured by the Abdecksieb réelle (2) after mounting in the vehicle body.
- the solder mass (8) ensures a permanent electrical and mechanical connection of the electrically conductive structure (3) with the connection elements (4).
- the connecting elements (4.1, 4.2) each have a contact surface (9), via which they are soldered by means of the solder mass (8) on the electrically conductive structure (3).
- the connecting elements (4.1, 4.2) are designed in the form of snubbing, wherein the lower male part of the push button serves as a connection element (4.1, 4.2) and the upper female part of the push button acts as a contact element (5.1, 5.2).
- the material composition of the connection elements (4.1, 4.2) and the solder mass (8) corresponds to FIG. 1.
- the contact elements (5.1, 5.2) consist of the same material as the connection elements (4.1, 4.2).
- At the contact elements (5.1, 5.2) one end of the connecting conductor (6) is electrically conductively contacted so that it represents an electrically conductive connection of the two connecting elements (4.1, 4.2).
- the closest contact surfaces (9) of the first connection element (4.1) and the second connection element (4.2) have a distance x of 190 mm.
- a connecting cable (10) is applied, which connects the connecting elements (4.1, 4.2) with the on-board electronics.
- the connecting elements (4.1, 4.2) according to the invention with connecting conductor (6) allow a significant improvement in the current carrying capacity, even when using bus bars with small cross-sections and only two terminal connection elements. Additional solder points are not required.
- the use of connecting elements in the form of push buttons is particularly advantageous in terms of a reversible attachment of the connecting conductor and the connecting cable. In the event of a cable break, the solder connection does not have to be loosened and the affected cables can be easily replaced.
- FIG. 7a shows a flow chart of the method according to the invention for producing a pane with connecting elements and connecting conductors.
- contact elements (5) are electrically conductively attached to the connection elements (4).
- connection elements are soldered in the subsequent steps by means of a solder mass (8) on the electrically conductive structure (3).
- the connection elements (4) are contacted with each other in an electrically conductive manner by attaching a connection conductor (6) to the contact elements (5).
- the embodiment of the method according to the invention shown here is particularly suitable for reversibly attached connecting conductors, such as connecting conductors contacted via plug-in connections.
- connection conductor and the further connection elements form a disturbing mass, whereby the forces acting on the first connection element thereby lead to a slippage of the first connection element during the soldering process. By subsequently connecting the connection elements via connectors, this can be prevented.
- FIG. 7b shows a flow chart of a further embodiment of the method according to the invention for producing a pane with connecting elements and connecting conductors.
- a connecting conductor (6) is first electrically conductively contacted to the connecting elements (4.1, 4.2). This can be done either directly, for example by soldering the conductor directly to the connection element, or indirectly, for example via contact elements. In the subsequent steps, this arrangement is soldered via the contact surfaces (9) of the connection elements (4) by means of a solder mass (8) on an electrically conductive structure (3).
- This embodiment of the method according to the invention is preferably used if the connection between the connecting conductor and the connecting element, or between the connecting element and contact element is not reversibly solvable.
- the invention is compared below on the basis of a test series of disks with connecting elements and connecting conductors according to the prior art and the disk according to the invention with connecting elements and connecting conductors.
- connection conductor with 6 connecting elements at a distance of 57 mm and a total length of 285 mm was soldered analogously to Example 1 to the arrangement of substrate and electrically conductive structure described in Figure 1.
- the connection conductor consists of an uninsulated braided and nickel-plated copper conductor with a conductor cross-section of 3 mm 2 , whereby the connection elements are formed by crimps.
- Each of the connecting elements was soldered to the electrically conductive structure by means of a lead-free solder mass containing 65% by weight of indium, 30% by weight of tin, 4.5% by weight of silver and 0.5% by weight of copper.
- a connection conductor is commercially available from Antaya.
- Table 1 shows the result of a series of experiments of the inventive connecting conductor (Example 1) and the connecting conductor according to the prior art (Comparative Example 2).
- Example 1 shows the result of a series of experiments of the inventive connecting conductor (Example 1) and the connecting conductor according to the prior art (Comparative Example 2).
- Comparative Example 2 shows the result of a series of experiments of the inventive connecting conductor (Example 1) and the connecting conductor according to the prior art (Comparative Example 2).
- a sufficient current carrying capacity and the maximum temperature increase of the busbar is of crucial importance. This is set by many car manufacturers to a maximum limit of 60 ° C.
- the costs of the different connection conductors are compared.
- connection conductor according to the invention adheres to the limit value for the maximum temperature increase of the busbar.
- the connecting conductor according to the invention is much cheaper. This is mainly due to the material-intensive design of the connecting conductor according to the prior art. According to the state of the art, a substantially more massive conductor with a slightly higher conductor cross-section is required to maintain the temperature limit and to achieve sufficient current carrying capacity.
- the high number of connection elements also serves to achieve a sufficiently high current carrying capacity and to avoid noise in the moving automobile.
- a correspondingly high current carrying capacity can also be achieved by means of the connecting conductor according to the invention with only two connecting elements.
- connection conductor according to the invention can be soldered to connection elements within a shorter period of time. This time savings goes hand in hand with a further reduction in production costs. Furthermore, automation of the soldering process is enormously simplified by a smaller number of soldering points. The solution according to the invention also leads to a significant reduction in the cost of material, since the connecting conductor according to the invention is less solid worked with connecting elements.
- the connecting conductor according to the prior art has a much higher total material consumption due to the large number of connection elements (6 crimps) and solder deposits.
- inventive connecting conductor (Example 1) compared to the prior art (Comparative Example 2), both in terms of production, as well as with respect to further processing, far cheaper and more economical.
Landscapes
- Connections Effected By Soldering, Adhesion, Or Permanent Deformation (AREA)
- Multi-Conductor Connections (AREA)
- Combinations Of Printed Boards (AREA)
- Surface Treatment Of Glass (AREA)
- Surface Heating Bodies (AREA)
- Resistance Heating (AREA)
- Coupling Device And Connection With Printed Circuit (AREA)
Abstract
Description
Claims
Priority Applications (15)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/031,712 US10609768B2 (en) | 2013-10-29 | 2014-10-07 | Disc having at least two electrical connection elements and connecting conductors |
KR1020167010926A KR101970389B1 (ko) | 2013-10-29 | 2014-10-07 | 적어도 2개의 전기 연결 요소 및 연결 도체를 갖는 디스크 |
AU2014344091A AU2014344091B2 (en) | 2013-10-29 | 2014-10-07 | Disc having at least two electrical connection elements and connecting conductors |
JP2016527420A JP6290401B2 (ja) | 2013-10-29 | 2014-10-07 | 少なくとも2つの電気的な接続部材と1つの接続導体とを備えた板ガラス |
BR112016006435-6A BR112016006435B1 (pt) | 2013-10-29 | 2014-10-07 | Painel com pelo menos dois elementos de conexão elétrica, método para produzir um painel e uso do mesmo |
DK14783590.4T DK3064034T3 (da) | 2013-10-29 | 2014-10-07 | Rude med mindst to tilslutningselementer (4) og forbindelsesleder (6) |
MX2016005460A MX355765B (es) | 2013-10-29 | 2014-10-07 | Cristal con al menos dos elementos de conexión eléctrica y un conductor de conexionó. |
CA2924262A CA2924262C (en) | 2013-10-29 | 2014-10-07 | Pane with at least two electrical connection elements and a connecting conductor |
MA38983A MA38983B1 (fr) | 2013-10-29 | 2014-10-07 | Disque pourvu d'au moins deux éléments de connexion électrique et d'un conducteur de liaison |
CN201480059887.XA CN105659695B (zh) | 2013-10-29 | 2014-10-07 | 具有至少两个电连接元件和连接导体的窗格 |
EP14783590.4A EP3064034B1 (de) | 2013-10-29 | 2014-10-07 | Scheibe mit mindestens zwei elektrischen anschlusselementen und verbindungsleiter |
ES14783590T ES2725895T3 (es) | 2013-10-29 | 2014-10-07 | Luna con al menos dos elementos de conexión eléctricos y conductor de conexión |
EA201690890A EA030934B1 (ru) | 2013-10-29 | 2014-10-07 | Стекло по меньшей мере с двумя электрическими присоединяющими элементами и соединительным проводником |
PL14783590T PL3064034T3 (pl) | 2013-10-29 | 2014-10-07 | Szyba z co najmniej dwoma elektrycznymi elementami przyłączeniowymi i przewodem łączącym |
ZA2016/01896A ZA201601896B (en) | 2013-10-29 | 2016-03-17 | Disc having at least two electrical connection elements and connecting conductors |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13190646.3 | 2013-10-29 | ||
EP13190646 | 2013-10-29 |
Publications (1)
Publication Number | Publication Date |
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WO2015062820A1 true WO2015062820A1 (de) | 2015-05-07 |
Family
ID=49546246
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2014/071395 WO2015062820A1 (de) | 2013-10-29 | 2014-10-07 | Scheibe mit mindestens zwei elektrischen anschlusselementen und verbindungsleiter |
Country Status (22)
Country | Link |
---|---|
US (1) | US10609768B2 (de) |
EP (1) | EP3064034B1 (de) |
JP (1) | JP6290401B2 (de) |
KR (1) | KR101970389B1 (de) |
CN (1) | CN105659695B (de) |
AR (1) | AR097558A1 (de) |
AU (1) | AU2014344091B2 (de) |
BR (1) | BR112016006435B1 (de) |
CA (1) | CA2924262C (de) |
DE (1) | DE202014010271U1 (de) |
DK (1) | DK3064034T3 (de) |
EA (1) | EA030934B1 (de) |
ES (1) | ES2725895T3 (de) |
HU (1) | HUE044476T2 (de) |
MA (1) | MA38983B1 (de) |
MX (1) | MX355765B (de) |
MY (1) | MY177667A (de) |
PL (1) | PL3064034T3 (de) |
PT (1) | PT3064034T (de) |
TR (1) | TR201906817T4 (de) |
WO (1) | WO2015062820A1 (de) |
ZA (1) | ZA201601896B (de) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR112017021128A2 (pt) * | 2015-05-05 | 2018-07-03 | Saint-Gobain Glass France | vidraça com elemento de conexão elétrica e elemento conector anexado a ele |
JP6725971B2 (ja) * | 2015-07-14 | 2020-07-22 | 日本板硝子株式会社 | ガラス板モジュール |
JP6680481B2 (ja) * | 2015-07-22 | 2020-04-15 | 日本板硝子株式会社 | ガラス板モジュール |
JP6613920B2 (ja) * | 2016-01-22 | 2019-12-04 | セントラル硝子株式会社 | 車両用窓ガラス及び車両用窓ガラスの製造方法 |
FR3054403B1 (fr) * | 2016-07-22 | 2019-10-18 | Saint-Gobain Glass France | Vitrage avec element electriquement conducteur et sa connexion electrique |
DE102016219224A1 (de) * | 2016-10-05 | 2018-04-05 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren und Widerstandslötvorrichtung zum Verlöten eines Stromanschlusselements auf einer Fahrzeugscheibe |
WO2020016010A1 (de) * | 2018-07-20 | 2020-01-23 | Saint-Gobain Glass France | Vorrichtung zur herstellung von gelöteten verbindungen auf glasscheiben und verfahren hierzu |
JP2020074303A (ja) * | 2019-12-24 | 2020-05-14 | 日本板硝子株式会社 | ガラス板モジュール |
WO2024017966A1 (en) * | 2022-07-19 | 2024-01-25 | Agc Glass Europe | An electrically conductive connector for a window pane |
Citations (4)
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US4023008A (en) * | 1972-12-28 | 1977-05-10 | Saint-Gobain Industries | Terminal connection for electric heaters for vehicle windows |
GB2068715A (en) * | 1980-02-07 | 1981-08-19 | Saint Gobain Vitrage | Vehicle windows |
US6406337B1 (en) * | 2000-09-27 | 2002-06-18 | Antaya Technologies Corporation | Glass mounted electrical terminal |
US20060102610A1 (en) * | 2004-11-12 | 2006-05-18 | Agc Automotive Americas R&D, Inc. | Electrical connector for a window pane of a vehicle |
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US4415116A (en) | 1981-08-06 | 1983-11-15 | Ppg Industries, Inc. | Soldering tool with resilient hold-down attachment and method of using same |
JPS60144813U (ja) * | 1984-03-06 | 1985-09-26 | 井関農機株式会社 | 一輪型水田作業機 |
JPH0610912B2 (ja) * | 1987-12-16 | 1994-02-09 | 松下電器産業株式会社 | センタコア装着装置 |
JPH01158662U (de) | 1988-04-21 | 1989-11-01 | ||
JPH0644031Y2 (ja) | 1991-12-25 | 1994-11-14 | セントラル硝子株式会社 | 防曇用ガラスの導電端子 |
JPH08162260A (ja) * | 1994-12-02 | 1996-06-21 | Toyo Ink Mfg Co Ltd | 発熱体ユニット |
DE19751423A1 (de) * | 1997-11-20 | 1999-06-02 | Bosch Gmbh Robert | Scheibenheizung |
JP2004189023A (ja) * | 2002-12-09 | 2004-07-08 | Asahi Glass Co Ltd | 自動車用窓ガラスの端子及びその取付け方法 |
DE102006016566B4 (de) * | 2005-09-22 | 2008-06-12 | Beru Ag | Zusammengesetzter Leiter, insbesondere für Glühkerzen für Dieselmotoren |
CN101500347B (zh) | 2009-03-03 | 2012-10-31 | 深圳市格普斯纳米电热科技有限公司 | 电热膜接电方法 |
EP2408260A1 (de) * | 2010-07-13 | 2012-01-18 | Saint-Gobain Glass France | Glasscheibe mit einem elektrischen Anschlusselement |
ES2614714T3 (es) | 2011-04-12 | 2017-06-01 | Saint-Gobain Glass France | Soporte eléctricamente calefactable y cuerpo calefactor de superficie, así como procedimiento para su fabricación |
ES2773257T3 (es) * | 2011-05-10 | 2020-07-10 | Saint Gobain | Placa que comprende un elemento de conexión eléctrica |
-
2014
- 2014-09-04 AR ARP140103311A patent/AR097558A1/es active IP Right Grant
- 2014-10-07 JP JP2016527420A patent/JP6290401B2/ja active Active
- 2014-10-07 AU AU2014344091A patent/AU2014344091B2/en active Active
- 2014-10-07 PL PL14783590T patent/PL3064034T3/pl unknown
- 2014-10-07 MX MX2016005460A patent/MX355765B/es active IP Right Grant
- 2014-10-07 WO PCT/EP2014/071395 patent/WO2015062820A1/de active Application Filing
- 2014-10-07 MA MA38983A patent/MA38983B1/fr unknown
- 2014-10-07 BR BR112016006435-6A patent/BR112016006435B1/pt active IP Right Grant
- 2014-10-07 CN CN201480059887.XA patent/CN105659695B/zh active Active
- 2014-10-07 MY MYPI2016701530A patent/MY177667A/en unknown
- 2014-10-07 PT PT14783590T patent/PT3064034T/pt unknown
- 2014-10-07 CA CA2924262A patent/CA2924262C/en active Active
- 2014-10-07 DK DK14783590.4T patent/DK3064034T3/da active
- 2014-10-07 US US15/031,712 patent/US10609768B2/en active Active
- 2014-10-07 DE DE201420010271 patent/DE202014010271U1/de not_active Expired - Lifetime
- 2014-10-07 EP EP14783590.4A patent/EP3064034B1/de active Active
- 2014-10-07 ES ES14783590T patent/ES2725895T3/es active Active
- 2014-10-07 EA EA201690890A patent/EA030934B1/ru not_active IP Right Cessation
- 2014-10-07 HU HUE14783590 patent/HUE044476T2/hu unknown
- 2014-10-07 TR TR2019/06817T patent/TR201906817T4/tr unknown
- 2014-10-07 KR KR1020167010926A patent/KR101970389B1/ko active IP Right Grant
-
2016
- 2016-03-17 ZA ZA2016/01896A patent/ZA201601896B/en unknown
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US4023008A (en) * | 1972-12-28 | 1977-05-10 | Saint-Gobain Industries | Terminal connection for electric heaters for vehicle windows |
GB2068715A (en) * | 1980-02-07 | 1981-08-19 | Saint Gobain Vitrage | Vehicle windows |
US6406337B1 (en) * | 2000-09-27 | 2002-06-18 | Antaya Technologies Corporation | Glass mounted electrical terminal |
US20060102610A1 (en) * | 2004-11-12 | 2006-05-18 | Agc Automotive Americas R&D, Inc. | Electrical connector for a window pane of a vehicle |
Also Published As
Publication number | Publication date |
---|---|
KR101970389B1 (ko) | 2019-04-18 |
CA2924262C (en) | 2018-02-27 |
AU2014344091B2 (en) | 2017-07-13 |
EP3064034B1 (de) | 2019-02-13 |
MA38983A1 (fr) | 2016-12-30 |
US10609768B2 (en) | 2020-03-31 |
US20160270159A1 (en) | 2016-09-15 |
TR201906817T4 (tr) | 2019-05-21 |
EP3064034A1 (de) | 2016-09-07 |
MX2016005460A (es) | 2016-07-12 |
BR112016006435B1 (pt) | 2023-01-10 |
MA38983B1 (fr) | 2017-10-31 |
MY177667A (en) | 2020-09-23 |
ES2725895T3 (es) | 2019-09-30 |
KR20160061403A (ko) | 2016-05-31 |
PL3064034T3 (pl) | 2019-08-30 |
AU2014344091A1 (en) | 2016-05-19 |
JP6290401B2 (ja) | 2018-03-07 |
DK3064034T3 (da) | 2019-05-20 |
HUE044476T2 (hu) | 2019-10-28 |
ZA201601896B (en) | 2017-06-28 |
EA030934B1 (ru) | 2018-10-31 |
JP2017502451A (ja) | 2017-01-19 |
CN105659695A (zh) | 2016-06-08 |
CA2924262A1 (en) | 2015-05-07 |
AR097558A1 (es) | 2016-03-23 |
MX355765B (es) | 2018-04-30 |
PT3064034T (pt) | 2019-05-31 |
EA201690890A1 (ru) | 2016-08-31 |
CN105659695B (zh) | 2019-05-21 |
BR112016006435A2 (pt) | 2017-08-01 |
DE202014010271U1 (de) | 2015-03-05 |
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